The establishment of a Lidar facility at Rhodes University
- Authors: Grant, Richard Peter James Seton
- Date: 1988
- Subjects: Optical radar , LIDAR , Receiver , Transmitter , Photon counting electronics , Aerosol scattering , Temperature profiles , Stratosphere
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5445 , http://hdl.handle.net/10962/d1001998
- Description: LIDAR is the optical equivalent of RADAR. A LIDAR facility has been established at Rhodes University using a flashlamp-pumped dye laser as the transmitter and a photomultiplier tube at the focus of a searchlight mirror as the receiver. The setting up of the receiver and transmitter as well as the design and construction of the photon counting electronics is described. The LIDAR has been used to measure aerosol scattering ratios and temperature profiles in the stratosphere and these results are presented with the algorithms and software used to reduce the data. Finally some recommendations are made for future work
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- Date Issued: 1988
Morphology, patterns and processes in the Oyster Bay headland bypass dunefield, South Africa
- Authors: McConnachie, Lauren Bernyse
- Date: 2013
- Subjects: Sand dune conservation -- South Africa -- Eastern Cape Sand dune ecology -- South Africa -- Eastern Cape Coastal ecology -- South Africa -- Eastern Cape Sedimentation and deposition -- South Africa -- Eastern Cape Beach erosion -- South Africa -- Eastern Cape Coastal zone management -- South Africa -- Eastern Cape Shore protection -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4804 , http://hdl.handle.net/10962/d1001904
- Description: Studies of the dunefield systems crossing the Cape St. Francis headland in the Eastern Cape have focused on the role that wind plays in sediment transfer in coastal dunefield systems, with limited consideration of the role of water. The aim of this study was to improve understanding of the morphology, processes and patterns within the Oyster Bay HBD system, focussing particularly on surface water and groundwater interactions and the role of surface water in sediment transfer across the dunefield system. An extensive field survey was conducted, to collect related data, complimented by spatial and temporal analysis of the study area using GIS. The key findings from this research were the apparent differences between the western and eastern regions of the dunefield with regard to specific drivers and the respective processes and responses. Wind is the major driver of change up to and across the crest of the dunefield. In the eastern region water (ground water, surface water and the Sand River System) is the primary agent of sediment flux through processes of aggregation and slumping as well as episodic events including debris flows. This study has highlighted a need for further quantitative studies that investigate the movement of sediment through dunefield systems such as this (where water is at or near the land surface). The paradigm that sediment flux is entirely due to wind is almost certainly simplistic, and deeper understanding of these systems is needed , Maiden name: Elkington, Lauren
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- Date Issued: 2013
Morphology, patterns and processes in the Oyster Bay headland bypass dunefield, South Africa
- Authors: Elkington, Lauren
- Date: 2013
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:20984 , http://hdl.handle.net/10962/5879
- Description: Studies of the dunefield systems crossing the Cape St. Francis headland in the Eastern Cape have focused on the role that wind plays in sediment transfer in coastal dunefield systems, with limited consideration of the role of water. The aim of this study was to improve understanding of the morphology, processes and patterns within the Oyster Bay HBD system, focussing particularly on surface water and groundwater interactions and the role of surface water in sediment transfer across the dunefield system. An extensive field survey was conducted, to collect related data, complimented by spatial and temporal analysis of the study area using GIS. The key findings from this research were the apparent differences between the western and eastern regions of the dunefield with regard to specific drivers and the respective processes and responses. Wind is the major driver of change up to and across the crest of the dunefield. In the eastern region water (ground water, surface water and the Sand River System) is the primary agent of sediment flux through processes of aggregation and slumping as well as episodic events including debris flows. This study has highlighted a need for further quantitative studies that investigate the movement of sediment through dunefield systems such as this (where water is at or near the land surface). The paradigm that sediment flux is entirely due to wind is almost certainly simplistic, and deeper understanding of these systems is needed.
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- Date Issued: 2013
Thermoluminescence characteristics of synthetic quartz
- Authors: Niyonzima, Pontien
- Date: 2014
- Subjects: Thermoluminescence , Quartz , Emission spectroscopy
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5538 , http://hdl.handle.net/10962/d1013190
- Description: Quartz is one of the most abundant natural minerals in the crust of the earth. Due to its dosimetric luminescence properties, it is employed in retrospective dosimetry, archaeological and geological dating. The intensity and the structure of the TL glow curves of quartz are strongly dependent upon the origin, impurity content, formation condition and pre-irradiation heat treatment. The aim of this project is to study the mechanisms of thermoluminescence (TL), Phototranssferred thermoluminescence (PTTL) and radioluminescence (RL) in synthetic quartz and to discuss the results in terms of physical characteristics of point defects involved. Thermoluminescence measurements were made on a sample of synthetic quartz in its as-received state (unannealed) synthetic quartz annealed at 500˚C for 10 minutes. The unannealed sample shows six TL glow peaks located at 94, 116, 176, 212, 280 and 348˚C at a heating rate of 5˚Cs⁻¹. The annealed sample shows seven TL peaks at 115, 148, 214, 246, 300, 348 and 412˚C at a heating rate of 5˚Cs⁻¹. The intensity of peak I, at 94 and 115˚C for the unannealed and annealed samples respectively, increases with irradiation. Peak I has an activation energy of approximately 0.90 eV and a frequency factor of the order of 10¹¹ s⁻¹. The order of kinetics is between 0.9 and 1.2. The unannealed synthetic quartz shows phototransferred thermoluminescence (PTTL) at the position of peak I after removal of the first three peaks followed by illumination. The PTTL intensities show peak shaped behaviour when plotted against illumination time. The PTTL showed a quadratic increase with dose. The material exhibits fading of PTTL intensity with delay time. Radioluminescence was measured on synthetic quartz unannealed and annealed annealed at 500, 600, 700, 800, 900 and 1000˚C for 10 to 60 min. The emission spectra of synthetic quartz show seven emission bands. The effect of irradiation on the RL spectra is to increase the intensity of all emission bands for samples annealed at temperatures less than or equal to 700˚C. The effect of annealing time is to increase the RL amplitude for the samples annealed at temperatures greater than 700˚C. The annealing temperature increases the RL amplitude of all emission bands of the spectrum for all samples.
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- Date Issued: 2014
Active Layer Dynamics at Four Borehole Sites in Western Dronning Maud Land, Antarctica
- Authors: Kotzé, Camilla
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4894 , http://hdl.handle.net/10962/d1021295
- Description: Permafrost and active layer dynamics in the Antarctic play an important role within terrestrial landscapes and ecosystems and as a climate change indicator. However, they remain less thoroughly researched than their Northern-Hemispheric counterpart. Despite advancements made by ANTPAS on the permafrost and active layer monitoring network in the Antarctic, observational gaps still exist. Western Dronning Maud Land (WDML) has been identified as one of these gaps, necessitating further research on permafrost dynamics and the influence of climate parameters thereon. Such elucidation is critical to both the cryospheric and life sciences. Variations in the surface climate of Antarctica can be seen as a result of inter-annual variations in atmospheric circulation, enhancing permafrost degradation and active layer thickening which directly affects soil processes, such as sorting and cryoturbation. Ground temperatures from four permafrost boreholes from WDML were analysed from 2007 to 2014. The study sites exhibit seasonal freezing, periglacial landforms, and altitudinal variation, ranging between ca. 450masl to ca. 1300masl. Using ground thermal regime and regional climate data, the spatial and temporal variability of the active layer in the Ahlmannryggen and Jutulsessen areas of WDML were characterised. 137 Cs tracing has revealed that the active layer and associated landforms have been active over the past half century. Further results show that active layer depths at each site vary inter-annually and are particularly influenced by snow cover, altitude and distance to the ice-shelf. Moreover, a correlation between the SAO (Semi-Annual Oscillation) and measured ground temperatures was found, principally during the transitional season of the SAO in May and September. The relationship between climate and ground thermal regimes, especially the influence of teleconnections thereon, is essential to improving the understanding of permafrost dynamics and landform morphology in continental Antarctica.
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- Date Issued: 2016
Assessing the physical fitness level of children with intellectual disability in the Grahamstown region of the Eastern Cape, and subsequently designing, implementing and evaluating the efficacy of an exercise intervention
- Authors: Parsons, Samantha Lee
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/19723 , vital:22478
- Description: Background: Extensive research has addressed physical fitness as an agent in promoting health and well-being; however, there is little research on this topic for special populations, such as individuals with intellectual disability and even less relating to the South African context. Children with intellectual disability attending special need schools in disadvantaged communities in the Eastern Cape have lacked the opportunity to participate in structured physical education programs. Implementing a solution to this problem was seen to be a challenge, due to the lack of informative research and available data. Aims: The purpose of this research was two-fold; firstly, it aimed to identify the physical fitness levels of the intellectually disabled children in the Grahamstown region of the Eastern Cape province of South Africa; and secondly, it aimed to implement and evaluate the efficacy of an exercise intervention programme on physical fitness in a local school for children with intellectual disability. Phase 1: The descriptive study compared basic anthropometric as well as physical fitness measures from a sample of participants with intellectual disability (n=29) with a comparable sample of typically developed children (n=25). There were 15 males and 14 females in the intellectually disabled sample group, with an average age of 10.69 ± 1.26 years, and the typically developed sample had 13 males and 12 females, with an average age of 10.51 ± 0.74 years. The anthropometric measures included stature and mass; while the health-related physical fitness components included cardiorespiratory endurance, muscular endurance, strength, body composition, and flexibility; and the skill-related physical fitness components were balance, agility, speed, power, coordination and reaction time. The results revealed that the children with intellectual disability were significantly shorter in stature and lighter in mass (p <0.001) compared to their typically developed peers. Muscular endurance and strength, balance, speed, power, coordination and reaction time were poorer among those with intellectual disabilities (p <0.05). Cardiorespiratory endurance, flexibility and agility were similar between groups. Results of the correlation analyses determined significant (p <0.05) relationships between certain health-related and/or skill-related physical fitness components, which were instrumental for selecting measures for Phase 2. The physical fitness components that had the most significant (p <0.05) correlations were speed with five significant correlations, both muscular endurance and balance with six, coordination with seven, and power with eight significant correlations of the eleven physical fitness components. The comparative results, in conjunction with the correlations, determined that the most suitable physical fitness components to be implemented in the exercise intervention for Phase 2 were muscular endurance, balance, and power. Phase 2: The intervention study was a case-control study (intervention group: n = 16; control group: n = 15), whereby the intervention group was exposed to an 8-week multi-modal exercise intervention training muscular endurance, balance and power. Pre-and post-intervention measures were performed using the same eleven physical fitness tests as in Phase 1. The interaction effects and effect sizes were determined and the results showed significant improvements and large effect sizes for the intervention group’s performance of muscular endurance (p=0.026; d=0.617) and power (p<0.000; d=0.999), whereas no significant changes were found for balance. Furthermore, the exercise intervention also impacted the overall level of physical fitness, as significant changes were found for cardiorespiratory endurance (p<0.001; d=0.98), strength (p=0.021; d=0.654) and flexibility (p=0.032; d=586). In conclusion, the exercise intervention was effective for improving the intellectually disabled participants’ muscular endurance and power but not found effective for balance.
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- Date Issued: 2017
Performance evaluation of an off-grid building integrated photovoltaic system in Alice, Eastern Cape province, South Africa
- Authors: Buma, Carine Lethem
- Date: 2018
- Subjects: Building-integrated photovoltaic systems Buildings -- Energy conservation Performance -- Evaluation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/13227 , vital:39623
- Description: The constant increase in the global demand for energy and the current crisis on global warming and climate change has prompted a dying quest for clean, sustainable and reliable sources of energy. Amongst numerous renewable energy technologies, harnessing energy from the sun is the most viable way of guaranteeing a clean and sustainable supply of energy. Also, photovoltaic energy is one of the ways of using energy from the sun, where sunlight is converted to electricity using photovoltaic panels. Furthermore, the integration of photovoltaic modules into buildings is one of the most elegant innovations of this technology, as it plays the dual role of supplying energy to the building as well as protecting the building from outdoor weather conditions. Moreover, operating off the grid offers the possibility of energy access to locations far off from the grid and individuals willing to gain some degree of energy independence. Evaluating the performance of existing off grid and/or building integrated photovoltaic systems is the key to guaranteeing sustainable development and advancement in the technology. Thus, the aim of this work was to evaluate the performance of an off-grid building integrated photovoltaic system that was installed at the Fort Hare Institute of Technology. This entailed performing an in-depth characterisation of the solar resource at this location, evaluating the performance of the modules under outdoor weather conditions and also evaluating the performance of the balance of system (BOS) components. The system was monitored for a period of nine months (between February and October 2017). A data acquisition system was designed for measuring and recording both electrical system parameters and meteorological parameters affecting the performance of the system. These meteorological parameters include; solar irradiance, ambient temperature, cell temperature, relative humidity, wind speed and direction. A detailed characterisation of the solar resource at this location was carried out. It was observed that the solar declination angle varied from -23.5o on the summer solstice to 23.5o on the winter solstice. Also, the solar altitude angle (at solar noon) which is a complementary angle to the zenith angle varied from 33.7o in June to 80.65o in December. During the summer months, longer day lengths were experienced because the sun traversed the sky over a longer time, rising south of east and setting south of west. Whereas, in the winter months, the path length of the sun was shorter, with the sun rising north of east and setting north of west, hence, shorter day lengths. The solar radiation incident on a 25o north facing solar collector was found to be in three components; beam, diffuse and reflected. The beam component was higher in summer whereas the diffuse component was higher in winter due to an increase in the air mass ratio. However, the total daily average radiation was highest in January (7.12 peak sun hours) and least in June (3.04 peak sun hours). Finally, a comparison between the calculated and measured values of solar radiation showed just a 1.1percent difference over the year with disparities being in the individual months.m The influence of outdoor weather conditions on the performance of the system was also evaluated. Operating temperatures were noticed to have a great impact on the output voltage and power of the PV array. Significant correlations existed between various meteorological parameters. Also, a multiple linear regression model was developed to ascertain the dependence of module temperature on solar irradiance, ambient temperature, relative humidity, wind speed and wind direction. The coefficient of determination for the model was 0.928, showing a strong relationship between cell temperature and the chosen predictors. Also, the six thermocouples installed at various locations of the PV array revealed variations in the operating temperatures of the modules. The modules on the east side of the array recorded relatively lower temperatures because of the ceiling that had been removed beneath one of the modules on this side of the array, which permitted the free flow of air. Furthermore, I-V measurements conducted on various strings of the array revealed so many steps (hotspots), indicative of module (or cell) mismatch on almost all the cell strings.
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- Date Issued: 2018
Extraction, isolation and characterization of oleanolic acid and its analogues from Syzygium aromaticum (cloves) and evaluation of their biological activities
- Authors: khwaza, Vuyolwethu
- Date: 2019
- Subjects: Antibacterial agents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/19076 , vital:39882
- Description: Pathogenic microorganisms have serious impact on people's lives. Every year, millions of people around the world die of bacterial infections. Resistance to common antibacterial drugs has proven to be a challenging problem in control of bacterial infections. In an attempt to develop an effective and affordable treatment for bacterial infections, oleanolic acid isolated from syzygium aromaticum conjugates incorporating other pharmaceutical scaffolds such as chloroquine derivatives, curcumin, and ergocalciferol etc have been developed. Based on the previous successes of testing combination of antimicrobial drugs and pharmaceutical drugs which appeared to be the promising strategy to overcome treatment failure; a series of hybrid compounds containing oleanolic acid and other pharmaceutical scaffolds were synthesized. 4- Aminoquinoline derivatives were first hybridized with selected organic compounds to form a class of hybrid compounds containing either amide bond or ester bond as a linker between the precursor molecules. Analogues/hybrid compounds can overcome the disadvantages of combination therapy such as drug-drug interaction. The structural effects of this type of conjugation of oleanolic acid and other pharmaceutical scaffolds were characterised by FTIR, Mass Spec and NMR spectroscopy. These compounds were studied along with the monosubstituted oleanolic acid analogues and the organic components in order to compare the effects of the substitution on their biological response.‖ All the synthesized analogues were tested against 11 bacterial strains on both Gram-positive and Gram-negative bacteria. The synthesized compounds showed selectivity and higher activity against Enterococcus faecalis (EF), Klebsiella oxytoca (KO), Escherischia coli (EC), Staphylococcus aureous (SA), Proteus vulgaris (PV) and Bacillus subtilis (BS) with MIC values; ranging between of 1.25 mg/mL to 0.072 mg/mL
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- Date Issued: 2019