The influence of dopants on thermoluminescence of Sr2MgSi2O7
- Authors: Thomas, Sunil , Kalita, Jitumani M , Chithambo, Makaiko L , Ntwaeaborwa, Odireleng M
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105148 , vital:32469 , https://doi.org/10.1016/j.jlumin.2018.12.035
- Description: We report the influence of dopants on the thermoluminescence of Sr2MgSi2O7. Samples studied comprise undoped Sr2MgSi2O7 and doped versions, namely, Sr2MgSi2O7:Dy3+, Sr2MgSi2O7:Eu3+, Sr2MgSi2O7:Tb3+ and Sr2MgSi2O7:Tb3+,Eu3+ phosphors. All samples show a broad glow peak near 60 °C when measured at 1 °C/s after irradiation to 10 Gy. The peak changes with partial heating, irradiation and fades between irradiation and measurement in a manner expected of a composite one. The behaviour is used to exemplify the analysis of a composite peak on the basis that particular features reflect those of the dominant component.
- Full Text: false
- Date Issued: 2019
Photoluminescence and thermoluminescence properties of BaGa2O4
- Authors: Noto, L L , Poelman, D , Orante-Barrón, V R , Swart, H C , Mathevula, Langutani E , Nyenge, R , Chithambo, Makaiko L , Mothudi, B M , Dhlamini, M S
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/116037 , vital:34292 , https://doi.org/10.1016/j.physb.2017.07.059
- Description: Rare–Earth free luminescent materials are fast becoming important as the cost of rare earth ions gradually increases. In this work, a Rare–Earth free BaGa2O4 luminescent compound was prepared by solid state chemical reaction, which was confirmed to have a single phase by X-ray Diffraction. The Backscattered Electron image and Energy Dispersive X-ray spectroscopy maps confirmed irregular particle and homogeneous compound formation, respectively. The Photoluminescence spectrum displayed broad emission between 350 to 650 nm, which was deconvoluted into two components. The photoluminescence excitation peak was positioned at 254 nm, which corresponds with the band-to-band position observed from the diffuse reflectance spectrum. The band gap was extrapolated to 4.65 ± 0.02 eV using the Kubelka-Munk model. The preliminary thermoluminescence results indicated that the kinetics involved were neither of first nor second order. Additionally, the activation energy of the electrons within the trap centres was approximated to 0.61 ± 0.01 eV using the Initial Rise model.
- Full Text: false
- Date Issued: 2018
Employment and diversity in the cultural and creative industries in South Africa: research note
- Authors: Snowball, Jeanette D
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/71493 , vital:29858 , https://hdl.handle.net/10520/EJC188591
- Description: The publication of Richard Florida's (2002) The Rise of the Creative Class marked a growing international interest in the creative economy. There are several ways of understanding the creative economy, often divided into the cultural and creative industries. Cultural industries are those whose major outputs have some symbolic value, such as fine arts, film and craft, jewelry design, publishing and fashion. Creative industries are defined more broadly as those that have knowledge as their major input. In addition to cultural goods and services, these include things like software design and internet services. UNESCO (2009) provides guidelines for defining the cultural and creative industries and the ways in which they can be measured, but there is currently no international consensus. Nor is there likely to be, since different countries will have very different levels of involvement and focus that may shape what information is useful, for example, for shaping policy.
- Full Text: false
- Date Issued: 2016
On luminescence stimulated from deep traps using thermally-assisted time-resolved optical stimulation in α-Al2O3: C
- Authors: Nyirenda, Angel N , Chithambo, Makaiko L , Polymeris, G S
- Date: 2016
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124627 , vital:35639 , https://doi.org/10.1016/j.radmeas.2016.01.016
- Description: We report a study of charge transfer mechanisms of electrons stimulated optically from very deep traps, also known as donor traps, in α-Al2O3:C. The investigations were carried out using thermally-assisted time-resolved optical stimulation, thermoluminescence and by way of residual thermoluminescence from the main electron trap. When the charges are optically stimulated from the deep traps, they are redistributed via the conduction band to the main electron trap and the shallow trap from where they are optically or thermally released for recombination at luminescence centres. The luminescence is strongly quenched at high measurement temperature as evident by very short luminescence lifetimes at these temperatures. The main peak due to residual thermoluminescence is located at a higher temperature than the conventional main peak.
- Full Text: false
- Date Issued: 2016
Spawning and nest guarding of the river goby (Glossogobius callidus) from the Eastern Cape province of South Africa
- Authors: Wasserman, Ryan J , Vink, Tim J F , Woodford, Darragh J , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68144 , vital:29203 , https://doi.org/10.1111/aje.12228
- Description: Publisher version , Introduction: The River goby, Glossogobius callidus (Smith 1937), occurs naturally in rivers and the upper reaches of estuaries along the eastern seaboard of southern Africa (Whitfield, 1998; James et al., 2007; Wasserman, Strydom & Wooldridge, 2010). This fish species is among the most abundant of fishes in many river systems of the region and is considered an important predator in these habitats, feeding on invertebrates and small fish (Whitfield, 1998; Strydom & Neira, 2006; Wasserman, 2012; Wasserman et al., 2014). Despite this, ecological information on this goby is sparse and to date, no published records on the biology of the species exist. The urgent need for such information was recently highlighted in a study that identified G. callidus as a potentially invasive species, given its ability to rapidly establish in novel environments (Woodford et al., 2013). The present study therefore endeavoured to determine the reproductive guild to which G. callidus belong and describe aspects of their spawning. This was performed by closely observing wild caught, mature G. callidus in aquaria over a 25-day period.
- Full Text: false
- Date Issued: 2015
Isn’t it time to start thinking about ‘developing’ academic developers in a more systematic way?
- Authors: Quinn, Lynn , Vorster, Jo-Anne
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/66546 , vital:28961 , https://doi.org/10.1080/1360144X.2013.879719
- Description: publisher version , There is no defined route to becoming an academic developer. The research on pathways into the field (e.g. Kensington-Miller, Brailsford, and Gossman, 2012; McDonald, 2010; McDonald and Stockley, 2008) shows that in most cases ‘serendipity and chance played a role’ (McDonald, 2010, p. 40). Moreover, induction into academic development (AD) is often ad hoc, haphazard, and informal. Due to the changing higher education (HE) context, the field has grown exponentially and in many countries now plays a central role in institutions. This has generated increased demand for knowledgeable and competent developers that are able to contribute towards solving some vexing problems in contemporary HE. Current recruitment and induction processes of new developers do not necessarily meet this demand. In light of the above, we pose the question: given the changing context of HE and the field of AD, is it not time for us to induct newcomers into the field more systematically? As Kensington-Miller et al. (2012) suggest, we should not leave the induction of the next generation of developers to chance. We suggest that one way of ensuring appropriate induction is through a formal course for developers. Difficulties for newcomers to the field are illustrated by Kensington-Miller et al. (2012) when they report seeking ‘top tips’ at a HERDSA conference. We do not dismiss informal learning at conferences or the role of mentoring, coaching, apprenticeship, and so on, in inducting developers, nor do we minimise the benefits of relatively structured processes such as fellowship programmes, workshops, and postgraduate qualifications in related fields. However, these ways of induction may not offer novices the structured and systematic developmental opportunities needed to become developers able to fulfil varied, complex, and sometimes contradictory roles.
- Full Text: false
- Date Issued: 2014
Dedication of Jo'burg's new ring
- Authors: Lewis, Colin A
- Date: 2009
- Language: English
- Type: Article
- Identifier: vital:6189 , http://hdl.handle.net/10962/d1012395 , http://www.ringingworld.co.uk
- Description: Five years of planning, fund raising and hard work came to fruition in November 2008 when Africa's newest ring of bells was dedicated, bringing the first part of the Jo'burg Project to a successful conclusion.
- Full Text:
- Date Issued: 2009
Bells and bell ringers in South Africa, 1835-2000. Part I
- Authors: Lewis, Colin A
- Date: 2001
- Language: English
- Type: Article
- Identifier: vital:6164 , http://hdl.handle.net/10962/d1012352 , http://www.ringingworld.co.uk/
- Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa. , The first ring of bells in Africa was installed in Grahamstown Cathedral in 1879 at the instigation of Frederick Henry Williams. Williams was Dean of Grahamstown from 1865 until his death in 1885. He was born in County Fermanagh, Ireland, not far from Enniskillen, where an octave was installed in the Cathedral when Williams was an impressionable 12-year old. Grahamstown's bells were also an octave, cast by John Warner and Sons of London. They were hung in the newly built tower, designed by the English architect, George Gilbert Scott.
- Full Text:
- Date Issued: 2001