Phototransferred thermoluminescence and thermally-assisted optically stimulated luminescence dosimetry using α-Al2O3:C,Mg annealed at 1200°C
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105422 , vital:32511 , https://doi.org/10.1016/j.jlumin.2018.08.085
- Description: We report phototransferred thermoluminescence (PTTL) and thermally-assisted optically stimulated luminescence (TA-OSL) of α-Al2O3:C,Mg annealed at 1200 °C. PTTL is TL measured from an irradiated phosphor after its exposure to light. The other theme of this study, TA-OSL is the additional amount of luminescence optically stimulated from a sample over and above the amount that would be measured at room temperature. A sample irradiated to 10 Gy and preheated to 230 °C at 1 °C/s followed by illumination by 470 nm blue light produced four PTTL peaks at 53, 80, 102 and 173 °C. The PTTL peaks occur at the same positions as the corresponding conventional TL peaks. Their kinetic parameters are also similar. The intensity of the PTTL peaks increased with duration of illumination to a maximum within 200 s for doses between 1 Gy and 10 Gy. The dose response of each of the PTTL peaks at 80, 102 and 173 °C is linear within 1–15 Gy. The rate of fading is low and the peaks are reproducible. When the irradiated sample is optically stimulated at temperatures between 30 °C and 300 °C, after preheating to 500 °C, the intensity of its TA-OSL goes through a peak with temperature at 200 °C. Using the rising edge of the plot, activation energy of thermal assistance for a deep electron trap was estimated as (0.21 ± 0.02) eV. The TA-OSL dose response is sublinear from 10–250 Gy and saturates thereafter. The PTTL and TA-OSL analyses signify that the concentration of deep traps in α-Al2O3:C,Mg increased after annealing at 1200 °C. As a result, the sample produced better PTTL and TA-OSL response than when annealed at lower temperature.
- Full Text: false
- Date Issued: 2018
The effect of annealing and beta irradiation on thermoluminescence spectra of α-Al2O3: C, Mg
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2018
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/112875 , vital:33669 , https://doi.org/10.1016/j.jlumin.2017.12.036
- Description: The effect of annealing on thermoluminescence spectra of beta irradiated α-Al2O3:C,Mg has been studied. Measurements were made on an un-annealed sample and samples annealed at 600, 700 and 900 °C. A glow curve measured at 1 °C/s from samples irradiated to 1 Gy shows a high intensity peak at 163 °C and six secondary peaks of weaker intensity at 43, 73, 195, 280, 329 and 370 °C. When the samples are annealed at 700 or 900 °C, an additional secondary peak appears at 100 °C. The thermoluminescence spectrum of an un-annealed sample measured at 1 °C/s between 300 and 700 nm shows the main emission band at ~ 410 nm and subsidiary emission bands at ~ 325 and 485 nm. The emission from samples annealed at 700 and 900 °C show similar bands except for a decrease in intensity of the emission at 485 nm. The emission bands at 325, 410 and 485 nm are attributed to F+, F and F22+(2Mg) -centres respectively. The decrease of the emission band at 485 nm is deduced to be due to the destruction of the F22+(2Mg) centre at 700 °C. The emission bands are unaffected by irradiation dose between 10 and 320 Gy. However, when the sample is annealed at or beyond 700 °C, any effects on the F+ and F centres emission can be easier distinguished particularly for doses greater than 10 Gy.
- Full Text: false
- Date Issued: 2018
Thermally and optically stimulated luminescence of natural red and blue corundum (Al2O3)
- Authors: Kalita, Jitumani M , Thomas, Sunil , Chithambo, Makaiko L
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105177 , vital:32472 , https://doi.org/10.1016/j.jlumin.2018.09.058
- Description: We report the thermoluminescence (TL) and optically stimulated luminescence (OSL) of natural corundum (Al2O3) of two varieties; one red and the other blue. X-ray fluorescence spectroscopy of the samples show that the concentration of Al2O3 in the red corundum is 43.05% and 46.87% in the blue corundum. TL measurements carried out on un-annealed samples and samples annealed at 700 °C, 900 °C and 1200 °C show that the TL sensitivity increases with annealing. The sensitivity of the red corundum reaches a maximum after annealing at 900 °C whereas that of the blue corundum increases with annealing up to the maximum annealing temperature of 1200 °C used in this study. Both samples have a complex glow curve between 30 °C and 500 °C. The composite nature of the glow curves is deduced to be due to a continuum in the trap distribution in the crystal. The activation energy of the traps vary between 0.70 eV and 1.15 eV. The dose response of the red corundum under TL is linear within 100‒1000 Gy whereas that of the blue corundum is superlinear for the same dose range. The TL of both samples is reproducible but the signal fades with time between irradiation and measurement. Both samples produce OSL under 470 nm blue light stimulation. The dose response of the OSL is superlinear within 100‒1000 Gy. It is found that the samples also produce thermally-assisted OSL (TA-OSL) at elevated temperature. The TA-OSL intensity of the red corundum increases with dose up to 400 Gy and saturates thereafter. On the other hand, the intensity of the blue corundum increases consistently with dose from 100 Gy to 1000 Gy.
- Full Text: false
- Date Issued: 2019
Temperature dependence of persistent luminescence in CaAl2O4: Eu2+, Nd3+ related to beta irradiation and optical excitation
- Authors: Kalita, Jitumani M , Chithambo, Makaiko L
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/105158 , vital:32470 , https://doi.org/10.1016/j.jlumin.2018.10.062
- Description: Mechanisms responsible for the emission of persistent luminescence in CaAl2O4:Eu2+,Nd3+ are typically studied following excitation by ultraviolet or visible light. In contrast, we have studied the persistent luminescence from this material after beta irradiation and optical excitation. These studies have been carried out at 25 °C as well as at various temperatures up to 100 °C. A thermoluminescence (TL) glow curve measured at 1 °C/s following beta irradiation showed a glow peak at 63 °C. On the other hand, a glow curve measured after 15 s of optical excitation by polychromatic white light shows a peak at 102 °C. The partial heating procedure reveals that each of the TL peaks consist of several overlapping components. The TL in each case was analysed for kinetic parameters. The initial rise analysis carried out on the rising edge of the overlapping components shows that the activation energy of the component peaks corresponding to beta irradiation is consistent at (0.59 ± 0.01) eV. In comparison, activation energies corresponding to optical excitation increases with the partial heating temperature from (0.71 ± 0.01) eV to (0.76 ± 0.01) eV. The activation energy of (0.59 ± 0.01) eV is ascribed to an oxygen vacancy whereas the range of activation energies between (0.71 ± 0.01) eV and (0.76 ± 0.01) eV is ascribed to the 4 f levels of the Nd dopant.
- Full Text: false
- Date Issued: 2019