A raman spectroscopy study of semiconducting thin films
- Authors: Goosen, William Edward
- Date: 2006
- Subjects: Raman spectroscopy , Semiconductor films , Thin films
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10514 , http://hdl.handle.net/10948/426 , Raman spectroscopy , Semiconductor films , Thin films
- Description: A home-built Raman system, utilizing a pseudo-backscattering geometry, was built in the Physics Department at the Nelson Mandela Metropolitan University (NMMU). The system was then used to analyse a variety of bulk and thin film semiconducting materials currently being studied in the Physics Department. Silicon wafers were exposed to hydrogen plasma. Raman analysis of hydrogen induced platelets (HIPs), resulting from hydrogen plasma treatment of silicon, is reported. ZnO layers were deposited on glass, GaAs, Si, sapphire and SiC-Si substrates by metalorganic chemical vapour deposition (MOCVD) in the Physics Department at the NMMU. It was found that the ZnO layers grown by MOCVD all exhibited a strong E2 (high) phonon mode that dominated the Raman spectra. Furthermore, the spectra lacked the A1 (LO) phonon mode which is usually associated with the O-vacancy, the Zn-interstitial, or complexes of the two, indicating that the layers were all of good quality. The influence of depositing the ZnO thin film on a 3 mm thick SiC layer was also investigated and compared with the deposition of ZnO on Si substrate, in order to reduce the lattice mismatch between ZnO and the Si substrate. The possible shift of the Raman peaks due to the residual strain in the film, if present, could not be resolved. Characterization of GaN and AlxGa1-xN produced by MOCVD at the CRHEA laboratory of the CNRS in Valbonne, France is reported. A sharp peak at 567 cm-1 corresponding to the E2 (high) mode of GaN broadens and shifts to higher wavenumbers as the aluminium content of the AlxGa1-xN is increased. The shift is accompanied by a decrease in the intensity and a broadening of this peak. The broadening was attributed to a general decrease in the quality of the layers which accompanies increased aluminium content in AlxGa1-xN.
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- Date Issued: 2006
Development of a computational chemistry scheme for testing the utility of synthetic bacteriochlorin in dye-sensitized solar cells
- Authors: Kota, Ntsika
- Date: 2018
- Subjects: Dye-sensitized solar cells , Computational chemistry , Density functionals , Electronic excitation , Molecular orbitals , Oscillator strengths , Bacteriochlorin
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/62327 , vital:28155
- Description: A computational chemistry scheme, based on density functional theory, was developed for in silico testing of a few bacteriochlorin properties relevant to dye-sensitized solar cells. These properties included electronic excitation wavelengths, molecular orbital energy levels, and oscillator strengths among others. Comparisons were made among four species, using computational proxies for electron injection quantum yield and photo-induced current production. The proxy measures for current production (frontier orbital energy level and short circuit current) made consistent, though qualitative, predictions about the ranking of the four dyes. The proxy measures for electron injection quantum yield (change in planar dipole moment and density of states) made less categorical predictions about the ranking. Overall, the scheme singled out one dye as the worst, but made no conclusive predictions about the relative ranking of the other three. There was insufficient data for comparison of the ranking predictions with experiment.
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- Date Issued: 2018
A real time HF beacon monitoring station for South Africa
- Authors: Mudzingwa, Courage
- Date: 2009
- Subjects: Radio , Shortwave radio , Radio and television towers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5486 , http://hdl.handle.net/10962/d1005272 , Radio , Shortwave radio , Radio and television towers
- Description: High frequency, HF (3 - 30 MHz), radio communications are greatly affected by ionospheric conditions. Both civilian and military users need reliable, real time propagation information to show at any time the feasibility of communicating to any part of the world on a particular frequency band. For this thesis, an automated receiving/monitoring station for the Northern California DX Foundation (NCDXF)/ International Amateur Radio Union (IARU) International Beacon Project was setup at the Hermanus Magnetic Observatory, HMO (34.42oS, 19.22oE) to monitor international beacons on 20 m, 17 m, 15 m, 12 m and 10 m bands. The beacons form a world wide multiband network. The task of monitoring the beacons was broken down into two steps. Initially the single band station, at 14.10 MHz, was installed and later it was upgraded to a multiband station capable of automatically monitoring all the five HF bands. The single band station setup involved the construction and installation of the half-wave dipole antenna, construction and installation of an HF choke balun; and the choice of Faros 1.3 as the appropriate monitoring software. The multiband monitoring station set-up involved the installation of an MFJ-1778 G5RV multiband antenna, construction and installation of a Communication Interface - V (CI-V) level converter and configuring the Faros 1.3 software to monitor the beacons on all five HF bands. Then a web page was created on the HMO space weather website (http://spaceweather.hmo.ac.za). Here, the real-time signal to noise ratio (SNR) and short path (SP)/long path (LP) plots are uploaded every 3 minutes, showing real time HF propagation conditions on the five HF bands. Historical propagation data are archived for later analysis. A preliminary data analysis was done to confirm the peration of the monitoring station. The archived data were analysed and compared to ICEPAC (Ionospheric Communications Enhanced Profile Analysis and Circuit) predictions. Results show that the real-time signal plots as well as the archive of historical signal plots, convey information on ropagation conditions to users in terms that are easy to interpret and understand.
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- Date Issued: 2009