The labour market drop-out rate : a new approach to estimating the returns to government investment in higher education : the case for marine science in South Africa
- Authors: Grootes, Pieter Brian
- Date: 2005
- Subjects: Labor market Marine scientists -- South Africa Education -- Economic aspects -- South Africa Higher education and state -- South Africa Education -- Social aspects Human capital -- South Africa Education, Higher -- Economic aspects -- South Africa
- Language: English
- Type: Thesis , Masters , MEcon
- Identifier: vital:950 , http://hdl.handle.net/10962/d1002684
- Description: The private and social returns to education literature share the same conclusion: that education is beneficial for both the individual and society. However, the theoretical underpinnings are flawed as the literature does not account for the main feature that leads to the acquisition of education: the private demand for education. An understanding of the factors that motivate the individual to invest in education would lead to a deeper insight as to why both private and social returns to education exist, and would provide a clearer framework on which to base the government funding of education. This thesis provides a first attempt at filling this gap by introducing a method of estimating the returns to government investment in education, which is labelled the ‘labour market drop-out rate approach’. The approach focuses on the social return to education, not in terms of graduate earnings, but in terms of the interaction of the graduate with the economy. The approach introduces a measure of expertise utilisation, based on the premise that there is no social return to an individual acquiring education if he or she does not utilise the acquired knowledge base on entering the labour market. The approach is tested using the labour market for marine scientists in South Africa as a case study. In this case the private demand for education is found to be heavily influenced by the provision of student bursaries from the National Research Foundation, with a resulting estimate of the social return to a degree in marine science being a mere 20% to 25%. Owing to this, a new approach to government investment in marine science is introduced, that of graduate contribution schemes. Of broader significance is the ease of application of this approach, it may be adopted to analyse any funding programme in which a government may decide to invest. As such, the labour market drop-out rate provides an extension to the returns to education literature through its theoretical dealings of the private demand for education, as well as a practical tool which government agencies can use to evaluate the efficacy of any government funding of education.
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- Date Issued: 2005
Interacting effects of wave exposure, tidal height and substratum on spatial variation in densities of mussel Perna perna plantigrades
- Authors: McQuaid, Christopher D , Lindsay, Justin R
- Date: 2005
- Language: English
- Type: Article
- Identifier: vital:6879 , http://hdl.handle.net/10962/d1011635
- Description: A fine time-scale study was undertaken on the effects of wave exposure, tidal height and substratum type on mussel recruit densities on the south coast of South Africa. Prior to sampling, an exposed and a sheltered shore were identified at each of 2 sites (Diaz Cross and High Rocks) 7 km apart. Each shore was divided into 3 shore levels (termed zones) within which 3 substrata (adult mussels, coralline and non-coralline macroalgae) were sampled. Destructive sampling of early (<1 mm) and late (1 to 5 mm) plantigrades was performed daily over 30 d during a period of comparatively high recruitment. Recruitment was synchronised among substrata within zones, but not among zones or between sites. This suggests that larvae will settle on all substrata within a zone, but will prefer some substrata over others. They will not, however, search among zones for favoured substrata. Densities of early (but not late) plantigrades were consistently greater at Diaz Cross than High Rocks, indicating important differences in post-settlement mortality between sites. At both sites, densities of both recruit classes were greater on the low and mid shore than on the high shore. Generally (18 out of 20 comparisons), plantigrade densities within each zone were greater on algae than on adult mussels. Approximately 45% of all recruits collected were found on the foliose coralline alga Corallina, 37% on adult mussels and 18% on the rhodophyte Gelidium pristoides. Without secondary relocation from macroalgae to adult mussel beds, juveniles recruiting onto algae are likely to be lost. On low shore algae, densities of both early and late plantigrades were greater for exposed shores. Densities of plantigrades on the mussel bed and on algae on the mid and high shore were not correlated with exposure. Thus, site, substratum and zone all had significant and interacting effects on the density of recruits on both exposed and sheltered shores. The effect of wave exposure on recruitment, at least on the low shore, suggests that spatial subsidies not only in the form of food supply, but also in the form of larval transport, have a role in structuring mussel populations.
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- Date Issued: 2005
"The French Imperial Nation-State":
- Authors: Bischoff, Paul, 1954-
- Date: 2005
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161376 , vital:40621
- Description: Book Review. The French Imperial Nation-State. By G Wilder (2005).
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- Date Issued: 2005
A SOAP-based Model for secure messaging in a global context
- Authors: Van Eeden, Johannes Jurie
- Date: 2005
- Subjects: Telecommunication systems -- Security measures
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9777 , http://hdl.handle.net/10948/817 , Telecommunication systems -- Security measures
- Description: For integration between application-systems in a global context, interoperability needs to be established on a global level; global interoperability, in turn, is based on a global common application-interface. This is achieved through resolving differences in, inter alia, protocol profiles, among participants in the global network. ebXML is used as the point of departure. A messaging framework, which is based on existing Web technology and standards, is proposed. Certain security and Web service standards are examined to determine specific parameters for an interoperable secure messaging environment. A security based framework comprising a predefined message format and architecture is investigated for a secure interoperable global electronic marketspace.
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- Date Issued: 2005
A decade of changes Eastern Cape white commercial farmers' discourses of democracy
- Authors: Böhmke, Werner
- Date: 2005
- Subjects: Farmers -- Psychology , Agriculture -- South Africa -- Eastern Cape , Agriculture -- Economic aspects -- South Africa -- Eastern Cape , Democracy -- South Africa -- Eastern Cape , Political culture -- South Africa -- Eastern Cape , Social psychology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MA
- Identifier: vital:2934 , http://hdl.handle.net/10962/d1002443 , Farmers -- Psychology , Agriculture -- South Africa -- Eastern Cape , Agriculture -- Economic aspects -- South Africa -- Eastern Cape , Democracy -- South Africa -- Eastern Cape , Political culture -- South Africa -- Eastern Cape , Social psychology -- South Africa -- Eastern Cape
- Description: This paper deals with an analysis of the discursive accounts of Eastern Cape white commercial farmers on the subject of Democracy. Drawing on the theoretical perspectives of Social Constructionism and Discourse Analysis – which view individuals’ accounts of their realities as produced and informed by their particular social and historical context – the paper seeks to provide an analysis of the content of, and rhetorical strategies within the participants’ accounts and explanations. Such accounts of the social, historical and political circumstances in which Eastern Cape commercial farmers find themselves are thought to provide valuable insights into the manner in which the process of democratisation has been received by members of the agricultural sector. Data collection was conducted via brief, audio taped, semi-structured interviews. The participants were all white men and women, living in a commercial farming region of the Eastern Cape Province. Responses to the interviews were subjected to the Discourse Analytical procedure advanced by Ian Parker. Analyses reveal that participants are critical of the notion of democracy; utilize specific rhetorical and argumentation strategies; make use of notions and techniques of ‘Othering’; and subscribe to a colonial / patriarchal ideology which attempts to idealize pre-democratic South Africa. These findings illustrate what is in many ways still an ongoing political and ideological struggle in the rural regions of the country.
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- Date Issued: 2005
An investigation into the possible neuroprotective or neurotoxic properties of metrifonate
- Authors: Ramsunder, Adrusha
- Date: 2005 , 2013-06-11
- Subjects: Nervous system -- Degeneration -- Treatment , Neurotoxic agents , Alzheimer's disease -- Treatment , Metrifonate
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3833 , http://hdl.handle.net/10962/d1007560 , Nervous system -- Degeneration -- Treatment , Neurotoxic agents , Alzheimer's disease -- Treatment , Metrifonate
- Description: Alzheimer's disease is a progressive neurodegenerative disorder, in which there is a marked decline in neurotransmitters, especially those of the cholinergic pathways. One of the approaches to the symptomatic treatment of Alzheimer's disease is the inhibition of the breakdown of the neurotransmitter acetylcholine, using an acetylcholinesterase inhibitor. One such drug tested, is the organophosphate, metrifonate. Any drug used for the treatment of neurodegenerative disorders should preferably not induce further neurological damage. Thus, in the present study, we investigated whether or not metrifonate is neuroprotective. The in vivo and in vitro effect of this drug on free radicals generation shows that metrifonate increases the level ofthese reactive species. Lipid peroxidation induced using quinolinic acid (QA) and iron (II) and show that metrifonate increased the peroxidative damage induced by using quinolinic acid. Metrifonate is also able to induce lipid peroxidation both in vivo and in vitro. This was reduced in vitro in the presence of melatonin. Using iron (II), in vi/ro, there was no significant difference in the level of lipid peroxidation in the presence of this drug. An investigation of the activity of the mitochondrial electron transport chain and complex I of the electron transport chain in the presence of metrifonate revealed that metrifonate reduces the activity of the electron transport chain at the level of complex I. The activity of the mitochondrial electron transport chain was restored in the presence of melatonin. Pineal organ culture showed that metrifonate does not increase melatonin production. Histological and apoptosis studies show that tissue necrosis and apoptosis respectively, occur in the presence of this agent, which is reduced in the presence of melatonin. Metal binding studies were performed USing ultraviolet spectroscopy, and electrochemical analysis to examine the interaction of metrifonate with iron (II) and iron (III). No shift in the peak was observed in the ultraviolet spectrum when iron (ll) was added to metrifonate. Electrochemical studies show that there may be a very weak or no ligand formed between the metal and drug. This study shows that while drugs such as metrifonate may be beneficial in restoring cognitive function in Alzheimer's disease, it could also have the potential to enhance neurodegeneration, thus worsening the condition, in the long term. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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- Date Issued: 2005
Study of the skincalm filling process at Aspen Pharmacare applying some six sigma principles
- Authors: Marx, Johannes
- Date: 2005
- Subjects: Ointments -- Packaging , Six sigma (Quality control standard)
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10369 , http://hdl.handle.net/10948/184 , Ointments -- Packaging , Six sigma (Quality control standard)
- Description: Aspen Pharmacare is listed on the Johannesburg Securities Exchange South Africa (JSE) and is Africa’s largest pharmaceutical manufacturer. The company is a major supplier of branded pharmaceutical and healthcare products to the local and selected international markets. For decades, Aspen has manufactured a basket of affordable, quality, and effective products for the ethical, generic over-the-counter (OTC) and personal care markets. Aspen is also the leading supplier of generic medicines to the public sector, providing comprehensive coverage of the products on the Essential Drug List. Aspen continues to deliver on its commitment toward playing a role in social responsibility diseases such as HIV/AIDS, tuberculosis and malaria. In August 2003 Aspen developed Africa’s first generic anti-retroviral drug, namely Aspen-Stavudine. Aspen’s manufacturing facilities are based in Port Elizabeth (PE) and East London. Aspen has recently completed an Oral Solid Dosage (OSD) manufacturing facility worth approximately R150 million in PE. The Group manufactures approximately 20 tons of product daily and in excess of 400 tons of solid dosage pharmaceuticals, which equates to more than 2 billion tablets. In addition, more than 3 million litres of liquid pharmaceuticals and over 200 tons of pharmaceutical creams and ointments are produced per year [1]. Aspen excels at delivering quality products and services, exceeding customer expectations, complying with international standards in an environment that cultivates technical expertise and innovation. Following this philosophy through to the shop floor areas mean that there are always initiatives in continuous production improvement. One of these improvement projects introduced is called Six Sigma. 8 Ten members of the staff, selected from different expertise fields in the company were trained in Six Sigma. Knowledge gained from the two week training course were applied to different areas in the factory using Six Sigma principles. This dissertation focuses on the study undertaken in one of production areas, namely the filling process of the ointments and creams at the Aspen Port Elizabeth facility.
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- Date Issued: 2005
Procedural meanings of well in a corpus of Xhosa English
- Authors: De Klerk, Vivian A
- Date: 2005
- Language: English
- Type: Article
- Identifier: vital:6128 , http://hdl.handle.net/10962/d1011579
- Description: This article explores the use of the pragmatic marker well in a large corpus of the discourse of non-mother tongue speakers of Xhosa English, which is a sub-variety of Black South African English. A brief overview of discourse markers in general and of well in particular is provided, and the problems they pose to linguists in terms of difficulties in defining their syntactic, semantic and pragmatic properties are examined. After a brief description of the nature of the corpus of Xhosa English on which the study is based, and of the methodological approach which was followed, the rest of the article focuses on a fairly detailed exposition of the overall trends in contextualised uses and procedural meanings of well in the corpus, along with examples. Some (limited) parallels are drawn between the use of well in XE and other English corpora, in order to highlight the problems experienced by L2 learners in acquiring discourse markers.
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- Date Issued: 2005
Optimising the material distribution process for the southern region of Telkom SA
- Authors: Naicker, Kosalin Ganasen
- Date: 2005
- Subjects: Business logistics -- South Africa , Telecommunication -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8547 , http://hdl.handle.net/10948/407 , Business logistics -- South Africa , Telecommunication -- South Africa
- Description: Most government owned telecommunication operators across the world have to deal with a number of regulatory, technology and service challenges, as the industry is liberalised in co-ordinance with worldwide trends. Telkom SA will be facing a number of strategic challenges that will test its ability to survive as a telecommunications company over the next number of years. To remain competitive, Telkom must develop strategies to assure survival in a competitive environment. To assure the long-term survival of Telkom SA when moving into a competitive environment, the organisation must build a sustainable competitive advantage. In the face of increasingly fierce competition, the adoption of collaborative alliances between firms is becoming more and more common and the adoption of a world-class supply chain will be an ideal scenario for Telkom SA. A worldclass supply chain goes beyond the scope of the internal operations of an organisation, therefore the material distribution process was chosen for this study, which involved the internal operations in the organisation. The study included the availability of material up to the transportation of the material to the staging areas. The aim of this research was to identify the inefficiencies of the material distribution process of the Southern Region of Telkom SA to become worldclass. A quantitative technique was used to identify the inefficiencies. It was found that the availability and transportation of material were the inefficient categories, preventing the customer to receive the product or service on time. Communication, inaccurate forecasting and inefficient transportation of material were some of the reasons for not delivering material on time. Some of the recommendations included developing a model that could overcome the current inefficiencies in transportation, improving the communication channels, training and the development of employees at all levels.
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- Date Issued: 2005
The feeding ecology, habitat selection and hunting behaviour of re-introduced cheetah on Kwandwe Private Game Reserve, Eastern Cape Province
- Authors: Bissett, Charlene
- Date: 2005
- Subjects: Kwandwe Game Reserve (South Africa) , Cheetah -- Behavior -- South Africa -- Eastern Cape , Cheetah -- Nutrition -- South Africa -- Eastern Cape , Cheetah -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5698 , http://hdl.handle.net/10962/d1005384 , Kwandwe Game Reserve (South Africa) , Cheetah -- Behavior -- South Africa -- Eastern Cape , Cheetah -- Nutrition -- South Africa -- Eastern Cape , Cheetah -- South Africa -- Eastern Cape
- Description: The re-introduction of cheetah onto small reserves in the Eastern Cape Province has created the opportunity to study this species in an environment (Valley Bushveld) in which it has not previously been studied and which is quite different from the less wooded habitats in which previous studies have occurred. Thus the aim of this study is to add to the growing number of studies of cheetah in more wooded habitats and to contribute a better understanding of the level of specialization or adaptability in space use, habitat selection, diet and hunting behaviour that the cheetah possesses. The research was conducted on Kwandwe Private Game Reserve from February 2003 to August 2004. Direct observations, scat analysis and continuous observations were used to avoid bias towards large sized prey found when only using direct observations to study diet. The cheetah killed 15 species and four of the five most important prey species (kudu, springbok, grey duiker and bushbuck) were hunted according to their abundance on the reserve, while impala, the fifth most important prey species, was avoided (i.e. preference index less than one) by the cheetah. The cheetah’s main prey was medium sized ungulates, although the three male coalition killed larger prey than females and females with cubs. The daily food intake per cheetah per day was calculated to range from 5.3kg/cheetah/day for the coalition to 8kg/cheetah/day for a solitary female. Home range areas ranged from 11.1 km² for female cheetah with cubs in a den to 65.6 km² for single female cheetah and core areas ranged from 6 km² for the three male coalition to 26.5 km² for independent cubs. Habitat selection by cheetah on Kwandwe varied between the social groups depending on their susceptibility to predation by lions, their need for cover and need for water, and was similar to what has been previously reported. The home range of the coalition incorporated the most open vegetation type (karroid shrubland) with surrounding denser vegetation, while females occupied areas of denser vegetation. Activity patterns and hunting behaviour varied between different cheetah social groups with female cheetah being more active during day light hours compared to males which made 38% of their kills after dark. The average chase distances for the various cheetah groups varied considerably, and the chase distance for successful hunts was longer than for unsuccessful for all groups except single female cheetah. The percentage of kills’ kleptoparasitised on Kwandwe was very low compared to other studies possibly due to the low density of direct competitors, which in turn lead to longer mean kill retention times. These results suggest that cheetah are more adaptable than previously thought and this adaptability may have important implications for their conservation.
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- Date Issued: 2005
Critical analysis of a performance management system used by a tertiary education institution in the Eastern Cape
- Authors: Mkovane, Zenephone Bhekuyise
- Date: 2005
- Subjects: Performance -- Management -- Evaluation , Performance -- Measurement -- Evaluation , Universities and colleges -- Employees -- Rating of -- South Africa -- Eastern Cape , Border Technikon -- Employees -- Rating of
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8567 , http://hdl.handle.net/10948/412 , Performance -- Management -- Evaluation , Performance -- Measurement -- Evaluation , Universities and colleges -- Employees -- Rating of -- South Africa -- Eastern Cape , Border Technikon -- Employees -- Rating of
- Description: As argued by authors like Franzen on whose work the greater part of the introduction, the main problem and sub-problem has been based, the objective of this study was to establish the extent to which the performance evaluation system currently in use at the subject Institution conforms to the benchmark performance management systems as espoused in literature. Further, the objective was to establish the differences and commonalities between the performance management systems practiced in the corporate sector and current practice at the subject Institution. Best practice was thus lifted to form part of the recommendation of this study. A questionaire was designed based on the guidelines in the literature study in order to determine how the subject Institution conducts its performance appraisal and how this relates to the four general purposes of performance management mentioned in the study. The respondents' opinion obtained from the questionaire were compared with the guidelines in literature and clustered around the four identifiable general purposes of performance management. The study concludes with a statement of current practice at the subject Institution, and outlines the extent of conformance to benchmark practice on performance management systems. Recommendations are made based on best practice and direction is given to future research into contemporary practices with the express aim of enhancing quality in higher education applying the quality-related procedures of industry and commerce, where quality is crucial to success (Winch, 1996: 9-13). The current performance management system at the subject Institution proves to be largely conforming to the benchmark. However it should require comments made by the respondents that pertain to improvement.
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- Date Issued: 2005
A study of the use of value based management (VBM) by multinational entities in the Eastern Cape motor industry cluster (ECMIC)
- Authors: Blouw, Mbuyiselo Edwin
- Date: 2005
- Subjects: Corporations -- Valuation , Automobile industry and trade -- South Africa
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: vital:8550 , http://hdl.handle.net/10948/421 , Corporations -- Valuation , Automobile industry and trade -- South Africa
- Description: Management’s response to shareholders’ return on investment as a priority occurs in an increasingly dynamic environment. Accompanying these activities is the need to realign responsibilities and to allocate scarce resources effectively. This is done in order to ensure that companies achieve global competitiveness and increase shareholders’ return on investment. Against this backdrop, local industry needs to find new methods or strategies in order to achieve world-class competitiveness, and to be able to access foreign investment. One way to achieve these goals is through Value Based Management (VBM). The objective of this study is to evaluate the strategic intent of Multinational Entities in applying VBM to increase shareholders’ return on investment. Based on the study, certain factors are critical to ensure the success of VBM. A postal survey to managers in the motor manufacturing and component manufacturing companies was conducted to check the managers’ familiarity with VBM, and their scope, and usage of VBM; and, based on the finding, to evaluate the impact of VBM on companies’ results. The empirical finding was compared with a literature review, and the following findings were made: There is a strong understanding and application of the VBM principle on the part of local entities with Foreign Direct Investment (FDI); Departmental performance is critical to an entity’s overall performance; Based on the study, 23 per cent of the respondents use Economic Value Added (EVA) as an internal reporting measure, and an average of 19 per cent use other metrics; A total of 89 per cent of respondents indicated that they strongly agree with the use of incentives for motivation. The above-mentioned points were covered by means of 4-M framework ― that is: Measurement, Management, Motivation, and Mindset.
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- Date Issued: 2005
Effective management of an information technology professional's career
- Authors: Tedder, Derek
- Date: 2005
- Subjects: Information technology -- Vocational guidance , Information technology -- Management , Knowledge management , Career development , Computer Science -- Vocational guidance , System analysis -- Vocational guidance
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: vital:1148 , http://hdl.handle.net/10962/d1004543 , Information technology -- Vocational guidance , Information technology -- Management , Knowledge management , Career development , Computer Science -- Vocational guidance , System analysis -- Vocational guidance
- Description: The human resource is constantly cited as an organisation's greatest asset. In a rapidly changing technological environment this is most applicable to the Information Technology (IT) function. Organisations are experiencing IT human resource problems such as low satisfaction, early plateauing, high turnover, burnout, limited advancement potential, nominal corporate commitment, supervisory aversion, poor organisational culture, and exceptional compensation. These problems are directly related to the IT professional's career. There is a lack of information and awareness surrounding IT careers to deal effectively with these problems. The research aims to create increased awareness of IT careers and the inherent problems through the development of a career management model. The research aims to identify the factors that influence IT careers, provide career management with a means to measure compatibility of the factors, and suggest solutions to incompatibility. The solving of this problem will be of mutual benefit to both organisations and individuals as they seek to better manage IT careers. After reviewing research literature relating to career anchors, IT job types, IT skills portfolios, and career dynamics a model for Effective IT Career Management (EITCM) has been constructed. The model represents the dynamic interactions between individual, organisational, and dependent factors. The model examines the compatibility of these interacting factors by measuring the levels of relevant career variables. The model suggests appropriate career management techniques to increase the compatibility of the interacting factors. An empirical study was designed and launched online to provide data that would confirm the seven Critical Success Factors (CSF) relating to the proposed model. The responses from the members of the Computer Society of South Africa (CSSA) allowed the seven hypotheses derived from the CSFs to be tested. The results of the empirical study were positive but required modification to five of the CSFs before they could be confirmed. The EITCM model was modified to reflect the improved CSFs. An awareness of career influencing factors combined with active career management is advantageous to both IT professionals and their organisations.
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- Date Issued: 2005
Trade and the environmental Kuznets curve: is Southern Africa a pollution haven?
- Authors: Nahman, Anton , Antrobus, Geoffrey G
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143202 , vital:38210 , DOI: 10.1111/j.1813-6982.2005.00055.x
- Description: Evidence that the environmental Kuznets curve (EKC) may be explained by trade patterns casts doubt on the oft‐stated conclusion that economic growth automatically leads to environmental improvement. Trends in net exports as a proportion of consumption for both USA and UK trade with SACU were examined for various dirty industries. Some evidence of pollution haven effects is found, although a similar trend for clean industries suggests that this effect is weak. However, even a general shift in manufacturing industries from North to South (as opposed to a shift in specifically dirty industries) may explain the EKC to some extent.
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- Date Issued: 2006
Synthesis and electrocatalytic properties of polymerizable metallophthalocyanines
- Authors: Obirai, Joseph Chinye
- Date: 2005
- Subjects: Phthalocyanines Electrochemistry
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4447 , http://hdl.handle.net/10962/d1007733
- Description: The syntheses, spectral and electrochemical characterization of new family electropolymerizable pyrrole, thiophene and mercaptopyrimidin substituted metallophthalocyanine (MPc) complexes are described. Tetraamino substituted chromium and manganese phthalocyanine complexes were also synthesized and characterized. The spectral and electrochemical results are comparable to literature reports. The complexes formed stable films when deposited on electrode surfaces. The MPc films were formed by electropolymerization, drop-dry method and self-assembling. Nickel hydroxide-like electrodes were formed by electrotransformation of nickel-tetra-4- (pyrrol-1-yl)phenoxy phthalocyanine polymer films to the corresponding PcNi-O-NiPc modified electrodes in alkaline solution. The thiophene, mercaptopyrimidine functionalized MPcs and amino group containing complexes formed good self-assembled monolayers (SAMs) on gold electrode. The electrode modification processes were reproducible. The conductivities of the electrode were dependent on the surface concentrations of the complexes as a function of electropolymerization scan numbers. The electrodes showed good catalytic responses toward L-cysteine, nitrite, nitric oxide (NO), glycine, phenol and its derivative and oxygen. The results also suggest that the presence of thio groups on the ring substituents lowers the oxidation potential of Lcysteine more compared to literature values. The stability of the amperometric responses toward the various analytes is used to diagnose the applicability of the materials for electroanalytical purposes. The limits of detection for L-cysteine, nitrite, NO and glycine were in the range of ~10⁻⁷ to 10⁻⁵ mol dm⁻³.
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- Date Issued: 2005
Evaluating parts-of-speech taggers for use in a text-to-scene conversion system
- Authors: Glass, Kevin R , Bangay, Shaun D
- Date: 2005
- Language: English
- Type: Conference paper
- Identifier: vital:6603 , http://hdl.handle.net/10962/d1009323
- Description: This paper presents parts-of-speech tagging as a first step towards an autonomous text-to-scene conversion system. It categorizes some freely available taggers, according to the techniques used by each in order to automatically identify word-classes. In addition, the performance of each identified tagger is verified experimentally. The SUSANNE corpus is used for testing and reveals the complexity of working with different tagsets, resulting in substantially lower accuracies in our tests than in those reported by the developers of each tagger. The taggers are then grouped to form a voting system to attempt to raise accuracies, but in no cases do the combined results improve upon the individual accuracies. Additionally a new metric, agreement, is tentatively proposed as an indication of confidence in the output of a group of taggers where such output cannot be validated.
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- Date Issued: 2005
Implementing an EPrints repository system at a small South African university
- Authors: Vermaak, Irene
- Date: 2005
- Language: English
- Type: Text
- Identifier: vital:6980 , http://hdl.handle.net/10962/d1012408
- Description: This presentation gives a descriptive and analytical overview of the implementation of the Rhodes eResearch Repository system at Rhodes University, building on an ETD programme started in 1998. This project involves staff from Rhodes University Library and the Information Technology Division, with the approval of the Dean of Research. With the support of Management and a strong university IT culture of using open source software, Rhodes University Library planned the implementation of the system without major bureaucratic obstacles. We did, however, experience limited budgetary support and severe staff constraints. This poster aims to encourage institutions with limited resources to start IR programmes and emphasizes the short space of time required “to get up and go”.
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- Date Issued: 2005
Learning science through two languages in South Africa
- Authors: Probyn, Margie J
- Date: 2005
- Language: English
- Type: Conference paper
- Identifier: vital:7015 , http://hdl.handle.net/10962/d1007208
- Description: [From the introduction]: South Africa is a multilingual country with eleven national languages - nine indigenous languages and the two former colonial languages of English and Afrikaans1 - recognised as official languages in the Constitution of 1996 (Constitution of the Republic of South Africa, 1996). Despite these provisions, since the democratic elections of 1994 English has expanded its position as the language of access and power with the relative influence of Afrikaans shrinking, and African languages effectively confined to functions of ‘home and hearth’. McLean and McCormick (1996: 329 in Mazrui 2002: 269) suggest that the constitutional recognition of 11 official languages in South Africa is largely 'intended and perceived as a symbolic statement and that for instrumental purposes, English remains the dominant language in South Africa'.
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- Date Issued: 2005
Developing strategies for creating an environmental focus in a school: narrating the change process
- Authors: Hope, Megan Samantha
- Date: 2005
- Subjects: Environmental education Educational change School environment
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: vital:1946 , http://hdl.handle.net/10962/d1008093
- Description: Effective environmental education goes beyond raising environmental awareness and developing positive environmental values, to the encouragement of personal responsibility and action in response to contextual environmental issues in particular. The whole school approach has been advocated as the best approach to environmental education, based on the assumption that the values and attitudes espoused in the classroom need to be reflected in the day-to-day school practice. By practising what they teach, schools reinforce values with action. In contrast, inconsistencies between the formal and non-formal curriculum may lead young people to question the integrity of their teachers or condition them to accept such inconsistencies as cultural and social norms, which in turn may lead to apathy about the environment. Adjustments to the ethos of a school to foreground the environment, both within the curriculum , the management of the school and the behaviour of teachers, pupils and support staff, is not a straightforward undertaking. Institutional factors influence the change process in schools and each school presents a unique context. It is, therefore, difficult to develop a general strategy for the evolution of an environmental ethos. This case study narrates an attempt to implement a change towards an improved environmental focus in a school, and focuses on developing an understanding of how available resources can assist this process while engaging with complexity of change.
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- Date Issued: 2005
Imbhola yesiXhosa traditional Xhosa cosmetics:
- Authors: Cocks, Michelle L , Dold, Anthony P
- Date: 2005
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141370 , vital:37966 , http://pza.sanbi.org/sites/default/files/info_library/imbhola_yesixhosa_pdf.pdf
- Description: Plants have been used for cosmetic purposes since time immemorial. The earliest known cosmetics come from the First Dynasty of Egypt, about 3100-2907 BC. Since the ancient Egyptians who used olive oil perfumed with aromatic plants to keep their skin supple, humans have been using plant extracts for cleansing and beautifying purposes.
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- Date Issued: 2005