A mineralogical investigation of co-existing iron-titanium oxides from various igneous rocks with special reference to some South African titaniferous iron ores
- Authors: Reynolds, Ivan Melvin
- Date: 1979
- Subjects: Igneous rocks Mineralogy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4926 , http://hdl.handle.net/10962/d1004589
- Description: Part I consists of a detailied review of the available literature on the Fe- Ti oxides and their solid solution relationships. Particular attention is glven to the microstructures exhibited by these oxides and the hypotheses put forward to explain them. These data are synthesised and models are presented in which the microstructural developments in titaniferous magnetites amd ilmenites are explained in terms of current ideas on the influence of oxygen fugacity, exsolution mechanisms and crystal chemistry. These models have direct application to the microintergrowths observed in the naturally occurring Fe-Ti oxides from a wide range of igneous rocks. The available data on the minor and trace element chemistry of the Fe-Ti oxides are reviewed with particular reference to their variation in these minerals from different host rocks. The behaviour of the Fe-Ti oxides during secondary oxidation is discussed with particular reference to the oxidation of titaniferous magnetite and the weathering of ilmenite. The results of a mineralogical investigation into the co-existing Fe-Ti oxides from a range of igneous rocks including kimberlites, gabbros, dolerites, diabases, syenites, granophyres, granites and pegmatites are presented in Part 2 together with data on the ilmenites present in certain Eastern Cape beach sands. The kimberlite ilmenites are chemically distinct and can be readily distinguished on the basis of their relatively high MgO, Fe₂0₃ and Cr₂O₃ contents. They can also be distinguished from ilmenites from other igneous rocks on the basis of unit cell dimensions, d-spacings, reflectivities and micro-indentation hardness. The ilmenites from a wide range of basic to granitic igneous rocks exhibit a limited compositional range in which the MnO content appears to increase with increasing Si0₂ content. Relatively insensitive indirectly determined parameters such as unit cell dimensions, reflectivities and micro-indentation hardnesses cannot be used to distinguish between the ilmenites from the different rock types in these classes. The titaniferous magnetites exhibit progressively decreasing Ti0₂ contents from a maximum in the basic igneous rocks to a minimum in the granitic types. The titaniferous magnetite typically exhibits varying degrees of deuteric alteration, while the microstructures developed can be interpreted 1n terms of the models presented in Part 1. Part 3 represents an extension of Part 2 and deals with a mineralogical investigation of the titaniferous iron ores in five South African basic intrusions. The Bushveld and Kaffirskraal ores consist of multi-phase titaniferous magnetite grains containing crystallographically oriented ilmenite, ulvospinel and pleonaste microintergrowths. Minor coarser-grained ilmenite is also present. The Usushwana ores are texturally similar but contain abundant lamellar ilmenite in place of the ulvospinel. The primary features are well preserved in the unmetamorphosed Bushveld and Kaffirskraal ores. The Usushwana ores have been slightly metamorphosed resulting in the extensive replacement of the titaniferous magnetites by sphene and chlorite aggregates. The ores from these three complexes cannot be beneficiated by conventional ore-dressing techniques and require direct metallurgical treatment for the recovery of Fe, Ti0₂ and V₂O₅. The metamorphosed Mambula and Rooiwater ores have been recrystallised to a varying degrees and consist of multi-phase titaniferous magnetite grains containing modified ilmenite and pleonaste microintergrowths. These modified microstructures differ from those encountered in titaniferous magnetites from unmetnmorphosed basic rocks and their degree of modification can be related to the degree of met amorphism. Variable amounts of coarse granular ilmenite are also present and their development is related to the metamorphic grade and degree of recrystallisation. These ores can be partially beneficiated to yield ilmenite- and lower-Ti0₂ magnetite concentrates in which V₂O₅ contents of the magnetic fractions are higher than those of the original ores. The Trompsburg ores differ from those of the other complexes in that they are Mg-rich and are characterised by the presence of abundant olivine. The titaniferous magnetites typically exhibit well-defined ulvospinel cloth textures and are often surrounded by small amounts of graphite. They show evidence of a variety of extensive late-stage alteration features. The ores from the five investigated complexes are compared with similar ores from the Bushveld Complex. The ores from each complex can be readily distinguished on the basis of their chemical compositions and textural relationships. These features can be related to their crystallisation his tories and, in some cases, to post-crystallisation processes. The microstructural evolution of the ores from each complex is interpreted in terms of the models developed in Part I.
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- Date Issued: 1979
A review of landscape development and erosion cycles in southern Africa
- Authors: Corbett, Dudley Harold
- Date: 1979
- Subjects: Landscape changes -- Africa, Southern Erosion -- Africa, Southern
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4899 , http://hdl.handle.net/10962/d1001558
- Description: The study of landforms has, to a large extent been neglected by exploration geologists. This is surprising because field geology is intimately related with landforms of one type or another. An understanding of the geomorphological history of a particular area will assist in the appreciation of the surficial environment, the processes of weathering, soil formation and duricrust (calcrete , ferricrete silcrete) formation. This has direct application in planning and interpreting geochemical sampling programmes. In order to understand the evolution of landforms it is necessary to study slope development in some detail. Agents of erosion and denudation constantly at work, remove detritus from hillcrests down to the drainage lines which form the local base level from whence material is transported down to the sea. The system is one of dynamic equilibrium, and the concept of grade is important in understanding hillslope evolution. Thus Section (1) of this discussion deals with past and present theories of hillslope evolution. Very little work has been done recently on the geomorphology of Southern Africa and the presently accepted classification of land surfaces is based on the work of Prof. L.C. King (numerous publications). However, through the more recent work of De Swardt and Bennet (1974) on the geomorphology of Natal, it is apparent that the present system of landform classification in Southern Africa requires widespread revision. The relationship of erosion cycles in Southern Africa to the late Jurassic-early Cretaceous break-up of Gondwanaland has received insufficient attention in the past. Erosion cycles bear an intimate relationship to offshore Cretaceous and Tertiary-Recent sedimentation. Valuable information on these sediments has only recently become available as a result of offshore exploration for oil. The findings of De Swardt and Bennet (1974) are summarized in Section (2) and the present land surface classification of Southern Africa is reviewed. Finally, some suggestions on a new interpretation of land surfaces in Southern Africa are given.
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- Date Issued: 1979
A review of the economic geology of tungsten
- Authors: Bowles, Michael
- Date: 1979
- Subjects: Tungsten Geology, Economic
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4897 , http://hdl.handle.net/10962/d1001556
- Description: A description of the geochemistry of tungsten is given. The geochemical properties of tungsten have a strong influence on its mineralogy, distribution and abundance in crustal rocks and rock-forming minerals , and its migration/deposition within the ore-forming and supergene environments. The behaviour of tungsten during migration, from source to site of deposition, within the crust is discussed in some detail and environments considered favourable to the concentration of tungsten ore minerals are suggested. All major types of tungsten ore deposit are described with emphasis placed on those of greater economic importance. Characteristic features of each type of deposit are particularly emphasized in order to provide clear guidelines to exploration. Hydrothermal, pyrometasomatic and stratabound tungsten deposits present themselves, economically, as the most important exploration targets. The recently developed concept of syngenetic stratabound tungsten mineralisation is outlined. Exploration for deposits of this type should be aimed predominantly, but not exclusively, at volcano-sedimentary sequences of Lower Palaeozoic age, particularly within regions known to contain occurrences of Sb and Hg. Tungsten deposits commonly contain concentrations of one or more of the following metals: Sn, Sb, Bi, Mo, Au and Ag. The presence and possible extractive value of these metals, together with commonly associated metal impurities such as As, must always be taken into account in a feasibility study , Adobe Acrobat 9.53 Paper Capture Plug-in
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- Date Issued: 1979
Gold mineralization in archaean cherts and iron-formations a review of the economic geology
- Authors: Bellamy, R E S
- Date: 1979
- Subjects: Gold ores -- Geology -- South Africa , Gold mines and mining -- South Africa , Greenstone belts -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4968 , http://hdl.handle.net/10962/d1005580 , Gold ores -- Geology -- South Africa , Gold mines and mining -- South Africa , Greenstone belts -- South Africa
- Description: The distribution of gold in igneous rocks and minerals is described and discussed. Not all the gold in igneous rocks is contained within early formed crystal lattices. Evidence that gold can be associated with late stage crystallizing phases is described. It is concluded that some of the gold in hydrothermal and volcanogenic deposits may have come from a primary magmatic source rather than having been leached from solid country rock. Gold is probably transported as chloride complexes at temperatures greater than about 300°C. At lower temperatures it is probably transported with other metals as sulphide and thio-sulphide complexes. The precipitation of gold from the transporting medium is brought about by changes in the physico-chemical conditions within that medium. Decrease in pressure is probably not a major cause of precipitation in volcanogenic environments. The geology of volcanogenic iron-formations is described and discussed, relative to the development of greenstone belts. Oxide facies iron-formations were formed in shallow oxidizing environments. They are associated with volcanogenic and clastic sediments. Sulphide facies iron-formations were precipitated in the deeper parts of geosynclinal structures. They are associated with mafic and ultramafic rocks similar to modern oceanic volcanic assemblages. Carbonate facies iron-formations were deposited in the regions between oxide facies and sulphide facies. Other banded iron-formations are found associated with base metal massive sulphide deposits related to arctype volcanic centres. These deposits are found in the regions where carbonate facies iron-formations were formed. Exploration for and exploitation of gold deposits in Archaean iron-formations are discussed. Geochemical exploration programmes are aided by the association of gold with trace amounts of base metals. Geophysical exploration methods that can be employed include magnetometer, I.P. and E.M. surveys. The metallurgical treatment of the ores should include "roasting" because a large proportion of the gold occurs as submicroscopic grains within sulphide mineral crystals.
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- Date Issued: 1979
Sedimentology of the Katberg sandstone in the Eastern Cape Province
- Authors: Stavrakis, Nicholas
- Date: 1979 , 2013-10-16
- Subjects: Sedimentology -- South Africa -- Eastern Cape , Geology, Stratigraphic -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5034 , http://hdl.handle.net/10962/d1007355 , Sedimentology -- South Africa -- Eastern Cape , Geology, Stratigraphic -- South Africa -- Eastern Cape
- Description: The Katberg Sandstone is an arenaceous formation occuring stratigraphically three querters of the way up in the Beaufort Group in the south-eastern part of the main Karoo basin. A sedimentological study was carried out on the Katberg Sandstone and adjacent formations, in a 2 000 km² area south of Queenstown. Stratigraphic sections were measured and lithofacies based on the style of Miall (1977) were established for the Katberg Sandstone, Balfour and Burgersdorp Formations. Stratigraphic relationships show that the Burgersdorp Formation in the study area, is the lateral (distal) equivalent of the Katberg Sandstone. The changeover from sandstone to predominantly shale lithology occurs roughly east-west between Cathcart and Whittlesea. Stream hydraulic theory is discussed and the sedimentary structures of the various lithofacies are explained in terms of this theory. An analysis was done of thirty-four palaeochannels, and their various ancient flow characteristics were derived via multiple regression equations and a FORTRAN computer program. A statistical analysis of bedform structures, showed that flat-bedding of the upper flow regime is the dominant sedimentary structure of the Katberg Sandstone. Trough cross-bedding originating in aqueous dunes and planar cross-bedding of transverse bars, are fairly well represented while ripples are virtually absent. The opposite applies to the Balfour Formation where lower flow regime structures, viz., ripple cross-lamination and trough cross-bedding predominate. There is an even spread of (upper) flat-bedding, trough cross-bedding and ripple cross-lamination in the Burgersdorp Formation. Detailed measurement of typical short sequences from sections of the three formations, and transition matrix analyses, showed the facies assemblages to be of three stream types: (i) Katberg type: similar to Platte type of Miall (1977). Sediments were deposited by swiftly flowing, low sinuosity, braided, ephemeral streams with a predominantly sand bedload. Each flow started with preconsolidated silt and mud (flakes), and movement of exogenetic pebble lags. Channel avulsion and deposition of mud drapes in higher topographic levels of the stream were common phenomena. (ii) Balfour type: characterised by lateral accretion point bar type sequences of high sinuosity streams, and vertical accretion floodplain deposits. Lower flow regime dune and ripple bedform structures overlying (upper) flat-beds indicate a loss of stream power with channel migration. (iii) Burgersdorp type: similar to Katberg type for sandstone units, also crevasse-splays onto thick subaerially exposed floodplain aggradation reddish shales. Conventional microscopy and SEM studies showed tremendous diagenetic effects mostly in the form of secondary quartz growth in the sandstones of the three formations. Electron microprobe analyses were done on titanomagnetite grains from heavy mineral layers of the Katberg Sandstone, so that thermometric predictions could be made on provenance rocks. Palaeocurrents of the Katberg Sandstone are mostly Rank 4 and 5 types (Miall, 1974), i.e., they were generated within bars with not much change in stream orientation. Burgersdorp and Balfour formation palaeocurrents are Rank 1 - 3 types. In the case of the former this is owing to directional changes in channels as a result of frequent crevasse-splays, and in the case of the latter owing to differences in orientation between entire tracts of highly sinuous palaeostreams. Palaeocurrent directions in the Katberg Sandstone indicate a southeasterly provenance which accords with the findings of other Beaufort Group workers. Bed relief index calculations (Smith, 1970), made on Katberg rocks, considered together with the abundance of planar cross-bedding (of transverse bars) and apparent absence of longitudinal bars, testify to the deposition of the Katberg Sandstone in the distal parts of the braided stream environment. The Beaufort sediments of the study area have the sedimentological characteristics of a molasse sequence, but a different implied tectonogenesis. During Balfour sedimentation the equilibrium base was being raised very slowly at the source and complete fluvial sequences were deposited under a humid temperate climate, on a slowly subsiding plain. During Katberg/Burgersdorp times, source area tectonism was pronounced but interrupted and incomplete sequences were deposited under an arid climate. Provenance rocks for the formations studied included biotite mesoperthitic granite, granulite, charnockite, granite porphyry, granophyre, metaquartzite, greenschist and possibly diorite, epidosit e and alkaline volcanic rocks. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
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- Date Issued: 1979
The behaviour of the elements Ni, Co, Cu, Pb, Zn, Au, Ag, Mo, Sn, W and U in the magmatic, hydrothermal, sedimentary and weathering environments
- Authors: Anderson, J R
- Date: 1979
- Subjects: Elements , Environment , Ore deposits , Classification , Geochemistry , Crystal chemistry
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4896 , http://hdl.handle.net/10962/d1001555
- Description: In the last two decades much has been published on the behaviour of certain elements in the magmatic , hydrothermal, sedimentary and weathering environments , but the information is scattered throughout the literature . This situation prompted the present study on the elements Ni, Co, Cu, Pb , Zn , Au, Ag , Mo , Sn, W and U. The behaviour of the elements Ni, Cu, Pb , ZN, Au, Sn , W and U has been studied experimentally in some depth. Ag has been moderately studied, but there is very little information about Co and Mo. Studies on the complexes formed by the elements within the hydrothermal and aqueous environment are often inconclusive and controversial , but conclusions are drawn as to the more likely complexes formed . A genetic classification of ore deposits is used as a framework for the discussion . The source of the elements is regarded as being the mantle, and therefore discussion on other possible sources is beyond the scope of this dissertation. The crystal chemistry and geochemistry of the elements are presented and the essay concludes with a discussion on the elements within their depositional environments
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- Date Issued: 1979
The geochemistry and petrology of the Karoo andesites and associated basalts of the north-eastern Cape Province
- Authors: Rumble, Keith Christopher
- Date: 1979 , 2013-02-11
- Subjects: Basalt , South Africa , Cape of Good Hope , Geochemistry , Petrology , Andesite
- Language: English
- Type: Thesis , Masters , M.Sc
- Identifier: vital:4902 , http://hdl.handle.net/10962/d1001562
- Description: New geochemical data consisting of major and 15 trace element analyses are presented for 41 rocks from three andesitic and associated basaltic rock occurrences in the North Eastern Cape Province. These include the Pronksberg, Belmore and Roodehoek localities. Field evidence suggests that the three andesites were emplaced during the early stages of Karoo volcanicity. Geochemical variations within the Pronksberg and Roodehoek andesite are small, manifesting the undifferentiated nature of the magmas. Variations within the Belmore andesite are interpreted as representing fractionation of orthopyroxene, accompanied by only minor plagioclase fractionation. Differences in trace element concentrations and inter-element ratios between the andesites and associated basalts of the Pronksberg and Belmore volcanic suites precludes the possibility of the two rock types being genetically related. Geochemical differences constrain the possibility of the three andesites being cogenetic. Magmatic processes resulting in their formation are, however, thought to be similar. The differences in chemistry between the Pronksberg Basalt (High K Type) and Pronksberg Basalt (Drumbo Type) are interpreted as representing the combined influence of weathering, the presence of amygdales and the within-flow variations of alkali elements on the Pronksberg Basalt (High K Type). Similarities in petrography and chemistry justifies a correlation of the Pronksberg Basalt (Drumbo Type) with the Drumbo Basalt Member in the Barkly East area. Data for the Drumbo Basalt (This study) in the Barkly East area confirms and complements previously presented data. Normative chemistry and strontium isotope data indicate a process involving crustal assimilation or melting of crustal rocks as being the most likely explanation for the genesis of the Karoo andesites , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
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- Date Issued: 1979