Showing items 141 - 160 of 530

Your selections:

Book review: Derek Barker: English Academic Literary Discourse in South Africa 1958-2004: A Review of 11 Academic Journals

  • Authors: Wright, Laurence
  • Date: 2006
  • Language: English
  • Type: Article
  • Identifier: vital:7044 , http://hdl.handle.net/10962/d1007386
  • Description: Barker’s book concerns the evolution and publishing trajectories of South African journals devoted to English literary studies between the years 1958 (when the first such journal, English Studies in Africa, came into being) and 2004, the end-date of the survey. In other words, his work coincides with the period in South African history when apartheid’s protagonists were pushing for total political and social ascendancy through to the nation’s emergence into the arena of democratic possibility.
  • Full Text:
  • Date Issued: 2006

Building cultural capital through value-driven leadership: a case study in an international finance company

  • Authors: Ackerman, Mariana
  • Date: 2006
  • Subjects: Financial institutions, International -- Namibia Case studies , Leadership -- Namibia Case studies , Corporate culture -- Namibia Case studies , Organizational change -- Namibia Case studies , Organizational effectiveness -- Namibia Case studies
  • Language: English
  • Type: Thesis , Masters , MCom
  • Identifier: vital:2919 , http://hdl.handle.net/10962/d1002428 , Financial institutions, International -- Namibia Case studies , Leadership -- Namibia Case studies , Corporate culture -- Namibia Case studies , Organizational change -- Namibia Case studies , Organizational effectiveness -- Namibia Case studies
  • Description: Today, organizations are placed under extreme pressure to adapt to the ever-increasing changes in their environments in order to survive. Research proves that corporate culture has the ability to either blunt or aid change. Past research conducted in Z-Nam, a subsidiary of an international finance company situated in Namibia, indicated that a divided culture resulted in limitations in their functioning, including their adaptability. Pressure was placed on Z-Nam by its majority shareholder to internalise a set of core values into its daily functioning in order to build a strong adaptable culture. This objective called for values-driven leadership. The four core values identified by Head Office were integrity, respect, accountability and pushing beyond boundaries. In becoming more values-driven, values theory posits that Z-Nam will build its cultural capital and so reap the benefits of higher performance, talent retention and adaptability. In this way Z-Nam will be able to combat the weaknesses in its current culture. Leadership adaptability and the capacity to lead change were seen to distinguish cultural changes that succeed from those that do not. Principles inherent in the field of OD were also considered, as they are seen to assist in the effective management of change. The methodology involved a purposive sample being drawn that included the top leadership team and internal OD consultant. Semi-structured interviews were conducted and thematic analysis employed in analysing the resultant data with three main aims in mind. Firstly, to assess Z-Nam's top management's perception of the current set of values being lived in the organization, to establish their level of support for the desired set of values proposed by Head Office and lastly to establish whether the leadership team is ready to promote the adoption of a new set of core values. Through comparing the themes that emerged from the data with literature on OD, values, culture and change, the researcher was able to make inferences as to the leadership's readiness and capacity to successfully lead cultural change. These findings were substantiated with secondary data from previous research activities. It was found that Z-Nam was not utilising its culture as an asset and that several barriers existed to adopting and implementing the desired values. It was concluded that Z-Nam will not be able to successfully embark on cultural change until its leadership recognises the importance of culture and their personal responsibility in bringing about the desired change, adequately assimilates information from past research and comes to a consensus as to the necessary accommodations that need to be made.
  • Full Text:
  • Date Issued: 2006

Cases of recontextualising the environmental discourse in the National Curriculum Statement (R-9)

  • Authors: Ramsarup, Presha
  • Date: 2006
  • Subjects: Education -- South Africa -- Curricula Environmental education -- Curricula -- South Africa
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: vital:1444 , http://hdl.handle.net/10962/d1003325
  • Description: With an intention of opening a vantage point on the story of how curriculum is actually created, this study follows the recontextualising of the environmental discourse of the National Curriculum Statement (R-9) in three case sites. These are: Grade seven Department of Education training material developed to introduce educators to the NCS (R-9), Delta Environmental Centre an environmental education non-governmental organisation, a rural primary school situated south of Durban. Using elements of the Bernstein’s (1990) framework of pedagogic discourse, the study traces how the environmental discourse was de-located from the field of production and relocated into the pedagogic practice of each case. In trying to follow the continuity, changes and discontinuities in the official [environmental] discourse as it is recontextualised, the study utilises Bernstein’s conceptual constructs of selective appropriation and ideological transformation. These constructs of selective appropriation and ideological transformation enabled me to ‘look into’ each case and get a perspective of how to explain the recontextualising processes. The study acknowledged that discourses are shaped and steered by historical, political and economic realities and begins by tracing the genesis of the environmental discourse within formal curriculum policy in South Africa. This socio-historical review highlights the main factors and happenings that shaped the present curriculum discourse and its production as official policy discourse. The study highlighted that within each case the recontextualising story is unique but some clear patterns emerged as factors that impacted on recontextualising processes. These were the role of history and context, knowledge and experience of the discourse, ideology and emphasis, and the depth with which the discourse was engaged. The discussion of these factors gave valuable insights into the recontextualising of curriculum discourses. The study comments on the need to clarify the environmental focus in the Learning Areas and to actualise this into practice so that the discourse becomes an integral part of teaching, learning and assessment. The study also highlights the need for professional development opportunities that will enable educators to clarify the nature and focus of the environmental discourse in the NCS (R-9), and its articulation in Learning Area in context. In particular, the environment and social justice relationships appear to require greater clarity of focus and interpretation in recontextualising processes. There also appears to be a need to develop educators’ foundational knowledge of environmental issues to strengthen the recontextualising of this discourse.
  • Full Text:
  • Date Issued: 2006

Cellulases (CMCases) and polyphenol oxidases from thermophilic Bacillus spp

  • Authors: Mayende, Lungisa , Wilhelmi, Brendan S , Pletschke, Brett I
  • Date: 2006
  • Language: English
  • Type: Article
  • Identifier: vital:6462 , http://hdl.handle.net/10962/d1005791 , http://dx.doi.org/10.1016/j.soilbio.2006.03.019
  • Description: In composting, organic matter is degraded by cellulases and ligninolytic enzymes at temperatures typically above 50 °C. This study isolated thermophilic microorganisms from a compost system that were then screened for cellulase and polyphenol oxidase activity. Temperature optima for the cellulases and polyphenol oxidases were determined as 70 and 40 °C, respectively. Maximal cellulase activity was determined as 1.333 mg glucose released ml[superscript −1] min[superscript −1]. Maximal polyphenol oxidase activity attained was 5.111 nmol phenol ml[superscript −1] min[superscript −1]. Cellulases were found to be stable over a period of 1 h. The isolated compost microorganisms were identified as strains of Bacillus using 16S ribosomal DNA sequence analysis.
  • Full Text:
  • Date Issued: 2006

Ceropegia macmasteri (Apocynaceae-Asclepiadoideae-Ceropegieae), a new species from Eastern Cape, South Africa

  • Authors: Dold, Anthony P
  • Date: 2006
  • Language: English
  • Type: Article
  • Identifier: vital:6515 , http://hdl.handle.net/10962/d1005943 , http://dx.doi.org/10.1016/j.sajb.2005.06.005
  • Description: Ceropegia macmasteri, a new species from Cathcart in the Eastern Cape Province of South Africa, is only known from a single population in Dohne sourveld grassland where it occurs with another rare local endemic species of the Ceropegieae, Brachystelma cathcartense R.A.Dyer. The new species, an herbaceous grassland plant with a tuberous rootstock, most closely resembles C. stentiae E.A.Bruce, but is distinguished by its linear-erect corona lobes and inner corona conniving to form a central column.
  • Full Text:
  • Date Issued: 2006

Changes in English writing in computer mediated communication a case study

  • Authors: Yang, Ranran
  • Date: 2006
  • Subjects: Telematics -- South Africa , English language -- Written English
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: vital:8475 , http://hdl.handle.net/10948/452 , Telematics -- South Africa , English language -- Written English
  • Description: This research study aims to identity the shifts in form and function of English writing in Computer Mediated Communication (CMC) and determine whether writing changed through CMC. It critically evaluates English writing in CMC in South Africa, and includes a case study of both synchronous and asynchronous forms of CMC. Chapter 1, outlines the problem concerning the changes of writing in both form and function in the present age of CMC. This chapter, also gives a detailed description and outlines the methodology of this study. Chapter 2, centres on the historical and theoretical aspects of writing using the work done by scholars such as McLuhan, Shlain and Baron. The literature is divided into two subsections. The research and theories highlights the importance and complexity of writing in human history. It also gives insight into understanding the impacts of different mediums on writing. This chapter similarly depicts an understanding in the use of writing to represent language, and in particular, how speech and writing divvied up communication functions in literature societies. Chapter 3, gives a detailed theoretical and critical outline of writing in the present age of CMC. Based on the nature of the computer medium, writing in CMC often has its own characteristics which can serve both developmental and social purposes. The aim of this chapter is to grasp an appropriate analogy through which to capture the changes the computer technology would engender in writing communication, and re-examine the relationship between writing and speech in CMC. Chapter 4, comprises of an empirical research study done in South African on-line discourse, focusing on the changes of writing in CMC. The hypothesis of this case study is that writing in CMC differentiates the conventional writing in a variety of ways. Therefore, the study looks at the particular writing style in CMC and determines whether computer-mediated writing is gradually becoming a mirror of speech. This chapter explains methodology and the process of data coding in this case study. It also includes a summary of the survey results, as well as a discussion of the findings from this case study. Chapter 5, includes a conclusion of this study and suggestions for further research. It is the hope of the researcher that this study will provoke questions and thoughts for further inquiries.
  • Full Text:
  • Date Issued: 2006

Changes in the anthropometric, physical and motor characteristics of elite soccer players aged 15 to 18 years within a training year

  • Authors: Baatjes, Sherman Gerard
  • Date: 2006
  • Subjects: Soccer -- Training -- South Africa -- Port Elizabeth , Soccer players -- South Africa -- Port Elizabeth
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: vital:10100 , http://hdl.handle.net/10948/472 , http://hdl.handle.net/10948/d1011990 , Soccer -- Training -- South Africa -- Port Elizabeth , Soccer players -- South Africa -- Port Elizabeth
  • Description: The primary aim of this study was to investigate the seasonal changes that occur in the anthropometric, physical and motor characteristics of elite junior soccer players over the course of a training year. The participants targeted were elite soccer players from the NMMU-FCK Soccer School of Excellence and a total of 18 players between the ages of 15 to 18 years were recruited to comprise the sample for the study. The participants in the sample were assessed on four separate occasions. Each testing period was separated by a three month interval with the first testing period taking place in June 2005, at the start of their pre-season period, and the last testing session taking place in March of the following year, at the end of their playing season. In order to determine which specific characteristics of soccer were to be tested, the relevant literature was reviewed to establish the requirements, attributes and indicators of success in elite soccer. Therefore the test battery used was compiled in an attempt to address each of the identified physical attributes that contributes to successful soccer play. The battery included the following tests: weight, height and percentage body fat to represent the anthropometric characteristics. The physical characteristics were assessed by testing flexibility, anaerobic speed endurance, aerobic endurance, and muscular strength tests (1 RM bench and leg press, grip strength, and isokinetic knee strength). The motor assessments comprised of tests for speed (10-m, 20-m, and 40-m), explosive leg power (vertical jump), agility, and soccer-specific tests (dribbling and shooting at goal). In addition maturity status during the study was assessed using grip strength and height scores. All of the participants within the study sample were assessed on each day of the testing period, in alphabetical order, and this order was maintained during each testing period. Each of the four testing sessions lasted three days. On entering the Nelson Mandela Metropolitan University-Biokinetics and Sport Science Centre (NMMU-BSSC) laboratory on day 1, the participants completed the test battery in the following order: anthropometric measurements (weight, height, skinfolds), flexibility test (sit and reach), leg power test (vertical jump), muscular strength tests (1RM bench press, 1RM leg press, grip strength), and an aerobic endurance test (Multi-Stage Shuttle Run). The tests conducted on day 2 of the test battery were conducted as field tests at the NMMU-FCK soccer playing fields and the participants completed the tests in the same alphabetical order as day 1. The testing battery was conducted in the following order: speed tests (10m, 20m, and 40m sprinting), agility test (Illinois agility run), soccer-specific tests (dribbling and accuracy tests), speed endurance test (Yo-Yo intermittent recovery test). Testing on day 3 consisted of Isokinetic dynamometry strength testing and was conducted at the NMMU-BSSC. Each participant completed the testing protocol according to the same alphabetical order as was used on days 1 and 2. In order to achieve the aim of the study, the following objectives were set: to determine the anthropometric, physical and motor characteristics of the participants at the pre-season, start of season, mid-season and end of season stages of the training year and to identify the peak scores achieved for each variable tested; to compare the variables tested at each of the four testing sessions to determine the progression of each variable tested and to identify at which testing session peak performance related fitness was achieved; to compare the results obtained with relevant data from other research literature; and to monitor the maturation status of the participants. Based on the results achieved it can be concluded that the participants achieved peak physical fitness at the mid-season period (testing session 3). It would appear that the attainment of these results was determined by the participants being exposed to both a pre-season and an in-season training period. It seems that both the completion of the specific types of training that occurred during these two periods, as well as the competitive matches played, elevated the participants physical fitness to the levels required for success at the elite level.
  • Full Text:
  • Date Issued: 2006

Changing energy profiles and consumption patterns following electrification in five rural villages, South Africa

  • Authors: Madubansi, Mainza , Shackleton, Charlie M
  • Date: 2006
  • Language: English
  • Type: Article
  • Identifier: vital:6640 , http://hdl.handle.net/10962/d1006866
  • Description: Following the democratic transition in South Africa in the early 1990s the government has implemented a widespread electrification programme, as well as introduced a free basic electricity allowance as a means of poverty alleviation. Yet there are limited longitudinal studies on the impacts of the introduction of electricity on the patterns of household energy use, and even more so in the neglected rural sector. This study reports on the patterns of household energy use in five rural settlements in 1991 and again in 2002. Results indicate a changing pattern of energy use for lighting and powering entertainment appliances, more specifically from dry-cell batteries and paraffin to electricity. Yet for thermal needs, most notably cooking, fuelwood has remained the most widespread fuel, and the amount used per month has not changed, despite increasing scarcity of wood in the local environment. There has been an increase in the proportion of households purchasing fuelwood as opposed to collecting their own. Overall, the mean total number of fuel types used per household has increased, indicating that electricity is simply viewed as an additional energy, rather than an alternative. Yet, electricity accounted for approximately 60% of expenditure on energy sources in 2002, despite the government's policy of a free basic allowance of 5–6 kWh per month. This has implications for energy supply costing, as well as the poverty alleviation dimensions of the whole programme.
  • Full Text:
  • Date Issued: 2006

Codeswitching, borrowing and mixing in a corpus of Xhosa English

  • Authors: De Klerk, Vivian A
  • Date: 2006
  • Language: English
  • Type: Article
  • Identifier: vital:6130 , http://hdl.handle.net/10962/d1011582
  • Description: The paper analyses selected aspects of the codeswitching behaviour in a spoken corpus of the English of 326 people, all of them mother-tongue speakers of Xhosa (a local African language in South Africa), and all of whom would see themselves as Xhosa/English bilinguals. The corpus comprises approximately 550,000 transcribed words of spontaneous, relaxed, oral discourse in English between pairs of Xhosaspeaking interlocutors, discussing a wide range of topics. While the usual pattern in bilingual speech is to use the L1 as matrix language and the L2 as embedded language, in this corpus the opposite is the case, as interlocutors were interviewed in English (the L2). The corpus therefore offers a ‘mirror image’, in a sense, of normal codeswitching behaviour. Using Wordsmith (a concordancer programme), all incidences of codeswitching into Xhosa during these conversations were identified and analysed in an effort to reveal underlying patterns. Examination of the amount and nature of codeswitching in the corpus promised to throw some light on the extent to which participants are genuinely bilingual, in terms of their ability to converse comfortably in English.
  • Full Text:
  • Date Issued: 2006

Cognitive pharmaceutical services and the community pharmacist: are South African patients receiving them and are they willing to pay?

  • Authors: Hill, Peter W , Dowse, Roslind
  • Date: 2006
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/156829 , vital:40054 , DOI 10.1211/ijpp.15.2.0007
  • Description: The objectives of this study were to ascertain the opinions of randomly selected South African medical aid members regarding the provision by community pharmacists of patient counselling and information; member satisfaction with pharmacist services; their rating of pharmacist accessibility; and if pharmacists should be reimbursed for providing cognitive pharmaceutical services. Setting A South African private healthcare insurance company.
  • Full Text:
  • Date Issued: 2006

Commentary: Negotiating distant influences: globalization and broadcasting policy reforms in Zambia and South Africa

  • Authors: Banda, Fackson
  • Date: 2006
  • Language: English
  • Type: text , article
  • Identifier: vital:6325 , http://hdl.handle.net/10962/d1008299 , https://doi.org/10.22230/cjc.2006v31n2a1785
  • Description: preprint , This commentary looks at the influences of globalisation on broadcasting policy reforms in Zambia and South Africa, with specific focus on such processes as deregulation, privatisation, commercialisation, communitarianism and technological convergence. It concludes that globalisation does not affect southern African countries uniformly; rather, it is refracted in accordance with the different cultural and political experiences of such countries.
  • Full Text:
  • Date Issued: 2006

Communication strategies in management: a case study of interpersonal manager-staff communication at a South African university

  • Authors: Balarin, Megan Georgina
  • Date: 2006
  • Subjects: Communication in management -- South Africa Interpersonal communication -- South Africa Communication -- Education College personnel management -- South Africa Universities and colleges -- South Africa Education, Higher -- South Africa -- Management
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: vital:1452 , http://hdl.handle.net/10962/d1003333
  • Description: Communication is a central feature of human life. The ability to talk is the very feature that distinguishes us from our primate ancestors. Knowing how to use language effectively gives the bearers of this knowledge power over their environment and an upper hand in their dealings with others. Thus, understanding the importance of communication in management is an essential tool for managers who wish to build and develop their organisations and their staff within these organisations. This thesis takes a case study view of manager-staff communication at a South African university. In this study managers and staff members contribute their feelings on current communication practices at this organisation through an online questionnaire and in-depth interviews. In an interpretive paradigm this thesis answers three central questions: 1) what role do managers and staff think communication plays in their working relationships, 2) what do they perceive to be effective and ineffective communication strategies and 3) What strategies can they suggest to enhance effective communication? Through in-depth qualitative research and numerical data analysis this thesis discovers central themes that pertain to the effective flow of communication in this organisation. These themes include: motivation and praise, the role of listening, building relationships, respect, acknowledging others’ languages and cultures, building teams, communicating frequently and using email and technology effectively, as well as keeping notes of meetings and discussions. Challenges to effective communication include not having enough time, suffering from stress, and the challenges of physical space and distance. By paying attention to basic human principles, such as the fact that acknowledging people for a job well done encourages them to perform well in future, this thesis relates the general concepts of communication and management theory to the specific realities and individual, personal experiences of manager-staff communication. In this way it sheds a beam of light on management communication practices and points the way towards an ideal where managers and staff members use communication as a tool of empowerment and understanding.
  • Full Text:
  • Date Issued: 2006

Community structure and predation impact of carnivorous macrozooplankton in the polar frontal zone (Southern Ocean), with particular reference to chaetognaths

  • Authors: Lukáč, Danica
  • Date: 2006
  • Subjects: Zooplankton -- Antarctic Ocean , Chaetognatha
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5653 , http://hdl.handle.net/10962/d1005336 , Zooplankton -- Antarctic Ocean , Chaetognatha
  • Description: The community structure and predation impact of carnivorous macrozooplankton (>2 cm; chaetognaths, medusae, ctenophores and mysids), with particular emphasis on the chaetognaths Eukrohnia hamata and Sagitta gazellae, were investigated during three surveys conducted in late austral summer (April/May) of 2001, 2004 and 2005 in the Polar Frontal Zone in the vicinity of the Prince Edward Islands (46º45’S, 37º50’E), Southern Ocean. The 2001 survey formed part of the Marion Offshore Variability Ecosystem Study (MOVES II), while the 2004 and 2005 surveys formed part of the Dynamics of Eddy Impacts on Marion’s Ecosystem study (DEIMEC III and IV respectively). Macrozooplankton samples were collected using WP-2, RMT-8 and Bongo nets. Results of the hydrographic survey indicated that the region of investigation, the Polar Frontal Zone (PFZ), is an area of high mesoscale variability. During the 2004 survey the Antarctic Polar Front (APF) and the Subantarctic Front (SAF) merged to form an intense frontal feature with subsurface temperature and salinity ranging from 8.5-7.5ºC and 34.15-33.88, respectively. A cyclonic cold core eddy, believed to have been spawned from the APF, was observed during the 2005 survey. Macrozooplankton abundance and biomass ranged from 0 to 43.731 ind. m⁻³, and from 0 to 41.55 mg wwt m⁻³ respectively, during the three surveys. Among the carnivorous macrozooplankton, chaetognaths (Eukrohnia hamata and Sagitta gazellae) were most prominent, contributing up to 85% of the total biomass during all three surveys. Elevated biomass values were found near and within the frontal feature during the 2004 survey, and also along the eddy edge during the 2005 survey. However, hierarchical cluster analysis did not reveal the presence of distinct zooplankton groupings associated with the various water masses encountered during the surveys and this is probably due to the high mesoscale variability in oceanographic conditions that are characteristic of the PFZ. The total average predation impact of the selected carnivorous macrozooplankton during the 2001, 2004 and 2005 surveys accounted for 4.93 ± 6.76%, 0.55 ± 0.51% and 4.88 ± 4.45 of the mesozooplankton standing stock, respectively. S. gazellae had the highest consumption rate in all three surveys, consuming up to 800 g Dwt 1000m⁻³d⁻¹ during the study. Of the two chaetognaths, E. hamata dominated the chaetognath standing stock. The combined abundance and biomass values of E. hamata and S. gazellae ranged from 0 to 43.73 ind. m⁻³ and from 0 to 41.551 mg wwt m⁻³ respectively, during the three surveys. Inter-annual variability in the chaetognath densities was apparent. Highest abundances and biomasses tended to be associated with specific water masses, confirming the existence of a relationship between zooplankton community structure and hydrographic conditions. Generally, about 90% of the chaetognaths contained no food in their guts. S. gazellae consumed a wider variety of prey. Oil droplets occurred in the guts of ≈ 51% of E. hamata. Cannibalism was low in both species, but greater in S. gazellae than E. hamata. During the three surveys, the feeding rate values of E. hamata and S. gazellae went up to 0.48 and 2.099 prey d⁻¹ respectively. S. gazellae also had a greater predation impact on the mesozooplankton standing stock than E. hamata. The mean predation impact of the chaetognaths combined was 0.31 ± 0.291%, 0.52 ± 0.28% and 0.53 ± 0.56% of the mesozooplankton standing stock during the 2001, 2004 and 2005 surveys, respectively. During all three surveys, the majority of individuals (≈ 76%) of the chaetognaths were at stage I maturity, suggesting that during the time of study the chaetognaths were not reproducing. In both species a significant difference (log-linear analysis, p < 0.05) in maturities between the years investigated was observed. In general, there were no differences in lengths and maturities between the different water masses encountered during the surveys. The lengths of E. hamata and S. gazellae ranged from 5 to 24 mm and from 9.4 to 63.6 mm, respectively.
  • Full Text:
  • Date Issued: 2006

Comparative efficiency of immobilized non-transition metal phthalocyanine photosensitizers for the visible light transformation of chlorophenols

  • Authors: Agboola, Bolade , Ozoemena, Kenneth I , Nyokong, Tebello
  • Date: 2006
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/286043 , vital:56233 , xlink:href="https://doi.org/10.1016/j.molcata.2005.12.009"
  • Description: Photolysis of aqueous solutions of chlorophenols (4-chlorophenol, 2,4-dichlorophenol, 2,4,5-trichlorophenol and pentachlorophenol) in the presence of immobilized non-transition metal phthalocyanine photosensitizers onto Amberlite® is presented. The photosensitizers studied are: Al (AlOCPc) and Zn (ZnOCPc) octacarboxyphthalocyanines; Al (AlPcS4) and Zn (ZnPcS4) tetrasulfophthalocyanines; sulfonated phthalocyanine complexes (containing mixtures of differently substituted derivatives) of Al (AlPcSmix), Zn (ZnPcSmix), Ge (GePcSmix), Si (SiPcSmix) and Sn (SnPcSmix). Photolysis of the chlorophenols resulted mainly in the formation of chlorobenzoquinone derivatives. The complexes showed order of activity towards the transformation of pentachlorophenol as follows: ZnOCPc > SiPcSmix > SnPcSmix > ZnPcSmix > GePcSmix > ZnPcS4 > AlPcSmix > AlOCPc > AlPcS4. The generation of singlet oxygen (1O2) by these immobilized MPc photosensitizers was found to play a major role in their photoactivities towards the transformation of these chlorophenols. Langmuir–Hinshelwood (L–H) kinetic model studies showed that the ZnOCPc, GePcSmix and ZnPcSmix photocatalysis occurred on the catalysts surface. © 2005 Elsevier B.V. All rights reserved.
  • Full Text:
  • Date Issued: 2006

Comparative electrochemistry and electrocatalytic activities of cobalt, iron and manganese phthalocyanine complexes axially co-ordinated to mercaptopyridine self-assembled monolayer at gold electrodes

  • Authors: Ozoemena, Kenneth I , Nyokong, Tebello
  • Date: 2006
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/286054 , vital:56234 , xlink:href="https://doi.org/10.1016/j.electacta.2005.08.007"
  • Description: Comparative surface electrochemistry and electrocatalytic properties of solid ultrathin monolayer films of metallophthalocyanine (MPc) complexes of cobalt (CoPc), iron (FePc) and manganese (MnPc) self-immobilised, via axial ligation reaction, onto preformed 4-mercaptopyridine self-assembled monolayers (SAMs) on gold electrodes have been described. Surface electrochemical parameters of the modified electrodes showed that these MPc-SAMs are densely packed with flat orientations. The electrochemical, electrocatalytic and stability properties of these MPc complexes follow this order: FePc > MnPc > CoPc. This finding is remarkable as it suggests that the success of using this method of self-assembling of MPc onto gold electrode is largely dependent on the bond distance between the pyridine linker and the central metal of the MPc; the shorter the distance, the faster the co-ordination and the better the electrocatalytic properties towards L-cysteine and thiocyanate. Thus, the superiority of FePc-based SAM over those of the MnPc and CoPc, has been proposed to be the result of the more favorable axial co-ordination properties of FePc with pyridine (i.e. shorter Fe–N(pyridine) bond length.
  • Full Text:
  • Date Issued: 2006

Comparison of satellite rainfall data with observations from gauging station networks

  • Authors: Hughes, Denis A
  • Date: 2006
  • Language: English
  • Type: text , Article
  • Identifier: vital:7079 , http://hdl.handle.net/10962/d1009748
  • Description: Networks of ground-based hydro-meteorological observations are frequently sparse in developing countries and the situation is not improving. Part of the reason is the lack of resources available in countries which have more pressing economic and social issues. However, these are also the very countries where improved estimates of water resource availability are required. While hydrological models have the potential to provide the necessary information, without adequately accurate climate (rainfall, evaporation, etc.) input information, it is extremely difficult to establish models and generate representative water resource availability information. This paper reports on a preliminary analysis of the potential for using satellite derived rainfall data through a comparison with available gauge data for four basins in the southern Africa region. It is clear that the satellite data cannot be used directly in conjunction with historical gauge data. Specifically, the satellite data do not reflect the strong influences on precipitation of topography in some of the basins. However, the prospects of applying relatively straightforward adjustments are promising and further assessments appear to be justified.
  • Full Text:
  • Date Issued: 2006

Comparitive study of automation strategies at VW Germany and South Africa

  • Authors: Wessel, Oliver
  • Date: 2006
  • Subjects: Volkswagen (Firm) , Motor vehicle industry -- Automation Comparative studies
  • Language: English
  • Type: Thesis , Masters , MTech
  • Identifier: vital:9607 , http://hdl.handle.net/10948/823 , Volkswagen (Firm) , Motor vehicle industry -- Automation Comparative studies
  • Description: This master thesis analyses the Volkswagen assembly lines of the Golf A5 manufacture in the mother plant in Wolfsburg, the Touran manufacture in the Auto 5000 GmbH in Wolfsburg as well as the Golf A5 manufacture in Uitenhage in South Africa - all with regard to the level of automation. The target of the analysis is the determination of the optimal level of automation in the three production sites and therefore, the investigation of the potential to automate, or rather to deautomate in particular sections of the assembly in the prevailing production locations. The three production sites are to be investigated with regard to costs, quality and quantity.
  • Full Text:
  • Date Issued: 2006

Competing interests and change within the pharmacy education system in South Africa

  • Authors: Allan, Lucie
  • Date: 2006
  • Subjects: Pharmacy -- South Africa Pharmacy -- Study and teaching -- South Africa Pharmacy -- Practice -- South Africa Community pharmacy services -- South Africa Community health services -- South Africa
  • Language: English
  • Type: Thesis , Masters , MPharm
  • Identifier: vital:3741 , http://hdl.handle.net/10962/d1003219
  • Description: This thesis provides a historical account of the emergence of the pharmacy education system in South Africa, and an analysis of the influence of competing interest groups over the pharmacy education curriculum. It provides a critical evaluation of structural-consensus and micro-interpretive approaches to medical and pharmacy education, and sets out a macrointerpretive account of pharmacy education in South Africa. Following Margaret Archer (1979) it analyzes three forms of negotiation between competing interest groups in their efforts to change the pharmacy curriculum; these are political manipulation, external transaction and internal initiation. The thesis argues that whilst the private sector interest group (comprising of retail, wholesale and manufacturing pharmacy) dominated the pharmacy education system until 1994, since then a newly emerged government interest group has begun to compete for educational control. The priorities pursued by this interest group have consistently reflected the objectives set out in the ANC National Health Plan of 1994. The thesis maintains that given its frustration over the non-implementation of the ANC’s health policy objectives, the government interest group is likely to resort to direct political manipulation by passing legislation to alter the content of the current pharmacy curriculum. Such changes would seek to ensure that the syllabus more accurately reflects the ANC Plan’s community health and primary health care objectives. The thesis asserts that such an outcome (of direct political manipulation of the curriculum) is not inevitable, and can be avoided through a process of internally initiated change. It presents the findings of an interpretive case study into how the Rhodes University Community Experience Programme (CEP) influenced final year pharmacy students’ perceptions of the role of the pharmacist. The students’ comments were collected by means of focus group interviews, participant observation and documentary analysis. Whilst the CEP did not successfully transform their concept of the pharmacist’s role, it did succeed in influencing students’ understanding of the notions of community pharmacy and primary health care in line with the government interest group’s health objectives. This thesis concludes that internally initiated change within the pharmacy education system, would be preferable to that imposed through external political manipulation, as such change would be more likely to preserve the independent professional interests of pharmacy academics.
  • Full Text:
  • Date Issued: 2006

Composition portfolio

  • Authors: Wynne, Donovan
  • Date: 2006
  • Subjects: Music -- South Africa Composition (Music) String quartets -- Scores
  • Language: English
  • Type: Thesis , Masters , MMus
  • Identifier: vital:2658 , http://hdl.handle.net/10962/d1003121
  • Description: Introductory remarks: Being a middle-class white South African, I grew up on a diet of predominantly "white" music: rock, pop and Western classical music. I was later introduced to a broader range of musics: blues, jazz, kwaito and traditional Southern African idioms. I found myself particularly attracted to the traditional music of the amaXhosa (especially that of the uhadi bow), possibly due to the fact that this music is hexatonic (that is, based on two major triads whose tonics are one tone apart), a system that bears certain resemblances to the Western tonal idiom. However, much of my musical experience tended to be entrenched in the piano and flute music I played: mostly works by composers who were neatly ensconced in the traditional Western canon. Therefore, despite the broad range of musics with which I was familiarisedduring my tertiary studies, I feel that this early experiential background is the reason I feel most comfortable with Western-influenced music. More recently, I discovered a whole new genre to explore: film music, particularly the work of Elliot Goldenthal, Danny Elfman, John Williams and Philip Glass, whose unique brand of minimalism has extended from the concert hall to thefilm theatre. I am fascinated by the ways in which film scores function. A "main titles" theme usually appears as the film opens, upon which most of the subsequent music is based. This is not a linear process, like a theme and its variations, but a lateral, where the main titles theme is the core that engenders other themes that all share a familial resemblance.
  • Full Text:
  • Date Issued: 2006

Composition portfolio

  • Authors: Webb, Cassidy Frank
  • Date: 2006
  • Language: English
  • Type: Thesis , Masters , MMus
  • Identifier: vital:2659 , http://hdl.handle.net/10962/d1003729
  • Description: Introduction: This portfolio consists of musical ideas which I have had for some time now. I have attempted to capture these ideas throughout the portfolio, starting with the smaller works (Brumes et Pluies) and building up to the larger works (James Tiberius, The tide). Brumes et Pluies is minimalistic in style. The interlocking of the two pianos plays an important role in the texture of the piece. The rhythms are repetitive throughout, with only slight variations. Kalahari is more idiomatic, rhythmical and has a main theme which recurs throughout the piece. Melodic fragments are used, sometimes with slight variations. This piece was inspired by the Kalahari desert, with its abundance of life. I enjoy the string quartet because of the homogeneity of sound on the one hand, and the diversity possible by using different techniques and effects on the other. James Tiberius is a work for chamber orchestra. Motifs in the music resemble certain animals. The rhythm is unstable, as is the harmony. There are many melodic fragments throughout. The texture is thin in certain areas (at the beginning) and dense in others (the waltz). The harmony is sometimes unconventional. The Tide was written in response to a memory of a drowning incident I experienced when I was a child. This orchestral piece is strong in form. The opening, for example, is tense and slightly atonal in harmony. The pomposo section tends to utilise most of the orchestra, so the texture is a lot denser here and the harmony is more conventional. I try not to use traditional forms in my composition. Rather, I prefer to compose by re-using and re-introducing ideas as I proceed.
  • Full Text:
  • Date Issued: 2006
  • Disclaimer
  • Privacy
  • Copyright
  • Contact