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The Sacred Door and other Stories: Cameroon Folktales of the Beba (Makuchi)

  • Authors: Kaschula, Russell H
  • Date: 2008
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/175177 , vital:42550 , https://doi.org/10.17159/2309-9070/tvl.v.45i2.4743
  • Description: In The Sacred Door and Other Stories: Cameroon Folktales of the Beba, Makuchi has collected thirty-three folktales of the Beba people. These stories are presented in English only. The book contains a foreword by well-known oral literature scholar, Isidore Okpewho and a preface by the author. In the foreword, Okpewho states that:“Tales like these need to be retold again and again, because the lessons they yield belong not merely to a long-forgotten historical or so-called primitive past but very much to the present times in which we live”(xi). The book therefore represents a sense of continuity between past and present. Although the tales may no longer be told in the same way that they were many years ago, the messages contained in the tales remain as relevant today as they did in the past.
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  • Date Issued: 2008

The environmental Kuznets curve: a literature survey

  • Authors: Nahman, Anton , Antrobus, Geoffrey G
  • Date: 2005
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/143191 , vital:38209 , DOI: 10.1111/j.1813-6982.2005.00008.x
  • Description: Literature on the environmental Kuznets curve (EKC) is examined, focussing on the possibility that the EKC may be explained by trade patterns. If significant, this trade effect would cast doubt on the oft‐stated conclusion that economic growth automatically leads to environmental improvement. Research has been insufficient, although a number of promising approaches have been developed. Although evidence on the pollution‐haven hypothesis is mixed, there is enough to suggest that the EKC development path may not be available to today's developing countries. Other problems cast doubt on whether the EKC exists in any relevant sense at all.
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  • Date Issued: 2005

The Cohen and Kuttel stories: is the place where I hang my hat still relevant to determine my residence for tax purposes?

  • Authors: Arendse, Jacqueline A , Stark, Karen , Renaud, Craig
  • Date: 2015
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/131285 , vital:36549 , DOI: 10.25159/1998-8125/5779
  • Description: Determining the residence of a taxpayer is one of the most important aspects of modern tax systems. For an individual taxpayer who migrates, a common trend in the modern world, the questions are where the person is ordinarily resident and whether the place of ordinary residence can change.
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  • Date Issued: 2015

Before you arrive We Are Here: Shuma Sopotela’s ‘Indlulamthi’

  • Authors: Makandula, Sikhumbuzo
  • Date: 2018
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/147248 , vital:38608 , https://artthrob.co.za/2018/08/03/before-you-arrive-we-were-here-shuma-sopotelas-indlulamthi/
  • Description: Chuma Sopotela’s multimedia performance ‘Indlulamthi’ at the National Arts Festival proposes a healing of the ‘Settler Frontier’ through a sonicscape. This production was realized with Lulamil Nikani, the Palestinian actor Ahmad Tobasi and Makhanda-based children from Ntsika High School and several other children groups she invited.
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  • Date Issued: 2018

The impact of geographical origin of two strains of the herbivore, Eccritotarsus catarinensis, on several fitness traits in response to temperature

  • Authors: Ismail, Mohannad , Brooks, Margot
  • Date: 2016
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/66914 , vital:28999 , ISSN 0306-4565 , https://doi.org/10.1016/j.jtherbio.2016.07.008
  • Description: Publisher version , Adaptation to temperature changes is vital to reduce adverse effects on individuals, and some may present phenotypic changes, which might be accompanied with physiological costs in fitness traits. The objective of this study was to determine whether the two strains of the herbivore Eccritotarsus catarinensis, a biological control agent against water hyacinth in South Africa, differ in their responses to temperature according to their geographical origin. We experimentally quantified the responses of the two strains, at three constant temperatures: 20 °C, 25 °C and 30 °C, using laboratory cultures that originated from Brazil and Peru, where climates differ. Reproductive output, egg hatching rate, sex ratio and longevity were recorded at each temperature. Fitness traits for both strains were significantly reduced at 30 °C compared with 25 °C and 20 °C in two successive generations. Nonetheless, Peruvian individuals continued their development at 30 °C, whereas Brazilian individuals that succeeded in emerging did not continue their development. In contrast, sex ratio was unaffected by temperature. The Peruvian strain of E. catarinensis presented different phenotypes depending on temperature and was more adapted to extreme high temperature than the Brazilian strain. The tropical origin of the population induces the insect to tolerate the extreme high temperature. We suggest that the Peruvian strain could be better suited for release to control water hyacinth in nature, particularly in regions where temperature is high.
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  • Date Issued: 2016

You can’t be serious:

  • Authors: Strelitz, Larry N , Steenveld, Lynette N
  • Date: 2005
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/159215 , vital:40278 , https://hdl.handle.net/10520/EJC146377
  • Description: As well as pandering to the lowest common denominator and simplifying complex issues, tabloids are also condemned for generally failing to provide information that citizens need in order to make informed political judgements - the latter being the raison d'etre of serious newspapers. In summary, tabloids "lower the standards of public discourse" (Ornerbring and Jonson, 2004: 283).
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  • Date Issued: 2005

Structural modification of RhIIItriarylcorroles for enhanced electrocatalyzed hydrogen evolution reactions

  • Authors: Zhu, Weihua , Li, Lihua , Wang, Yu , Mack, John , Dingiswayo, Somila , Nyokong, Tebello , Liang, Xu
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/229933 , vital:49724 , xlink:href="https://doi.org/10.1016/j.dyepig.2021.110046"
  • Description: A series of A3 type RhIIItriarylcorroles 2a-c with different meso-substituents with differing electron-donating and withdrawing properties and two A2B type RhIIItriarylcorroles 4a-b with meso-methylthiophenyls at the B position have been prepared and characterized. An analysis of structure-property relationships of 2a-c and 4a-b has been carried out by comparing the optical spectroscopy and electrochemistry of the dyes to trends predicted in DFT and TD-DFT calculations. Rational structural modification strategies that enhance the suitability of 2a-c for use as highly efficient catalysts for hydrogen evolution reactions on glassy carbon electrodes coated with 2a-c/reduced graphene oxide composites and of 4a-b in surface-modified Au electrodes are explored.
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  • Date Issued: 2022

New Unity Movement Bulletin

Spectroscopic studies of nanostructures of negatively charged free base porphyrin and positively charged tin porphyrins

  • Authors: George, Reama C , Egharevba, Gabriel O , Nyokong, Tebello
  • Date: 2010
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/261661 , vital:53432 , xlink:href="https://doi.org/10.1016/j.poly.2010.01.028"
  • Description: Spectroscopic studies were carried out on the homoaggregates of negatively charged free base meso-tetraphenylsulfonated porphyrin ([H2TPPS4]4−) and heteroaggregates of a mixture of protonated ([H4TPPS4]2−) and tin meso-tetra (N-methyl-4-pyridyl) porphyrin ([SnTMPyP]4+). The spectroscopic studies were done to determine the optimal conditions required for the fabrication of porphyrin nanorods by ionic self assembly of two oppositely charged porphyrins. In addition, the various spectral changes of [H4TPPS4]2− with concurrent change in pH and concentration are also investigated. In acid media at pH more than 3, and at concentrations less than 1 × 10−5 M, [H4TPPS4]2− molecules form J aggregates. A mixture of [H4TPPS4]2− and [SnTMPyP]4+ forms heteroaggregates of the J type in acid media. At pH’s 2 to 3, the optimum ratio for the formation of J aggregates is 3:1 and for pH 1, the optimum ratio is 2:1. Transmission electron microscope images of the nanostructures formed show that they are of cylindrical shape.
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  • Date Issued: 2010

Disclaiming/denigrating/dodging: white South African academics’ everyday racetalk

  • Authors: Vincent, Louise , Idahosa, Grace E , Msomi, Zuziwe
  • Date: 2017
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/141900 , vital:38014 , DOI: 10.1080/14725843.2017.1292119
  • Description: The call for the ‘transformation’ of higher education in South Africa is one instance of a wider effort, since the country’s first democratic election in 1994, to surmount an apartheid and colonial legacy of institutionalised racism. In 2015 and 2016 nationwide protests led to universities being shut down as students and staff expressed frustration institutions that continue to be experienced as racist and ‘untransformed’. In this study we report on interviews conducted with senior white academics at one South African university shortly before these protests began. Given that our participants are people of influence in their respective university departments, we asked, in in-depth open-ended interviews, what contribution they saw themselves making to ‘transformation’. We argue that the talk of these participants could be described as what authors in the field call 'racetalk', Talk is understood here as a form of social practice, the analysis of which helps us to understand how racism is reproduced in mundane ways which, taken together, account for the persistence of pervasive institutionalised racism in South African higher education that appears impervious to policy and regime change.
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  • Date Issued: 2017

Substituted catechols as complexing agents for the determination of bismuth, lead, copper and cadmium by adsorptive stripping voltammetry

  • Authors: Limson, Janice , Nyokong, Tebello
  • Date: 1997
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/293311 , vital:57074 , xlink:href="https://doi.org/10.1016/S0003-2670(96)00585-5"
  • Description: Copper, cadmium, lead and bismuth (> 5 μg ml−1) are determined by adsorptive cathodic stripping voltammetry (AdCSV) on a mercury film glassy carbon electrode, using catechol, 4-methylcatechol, 4-t-butylcatechol and resorcinol as complexing ligands. Complexes of lead, copper and bismuth with resorcinol showed the largest increase in current with increase in metal concentration, whereas complexes of these metals with 4-t-butylcatechol showed the lowest current response. Cadmium showed a different behaviour from the other three metals in that the highest current response was observed with 4-methylcatechol. The four metals could be determined simultaneously in the presence of resorcinol, although considerable interference was observed between bismuth and copper.
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  • Date Issued: 1997

Substantive second-level reasoning and experiential learning in legal ethics

  • Authors: Kruuse, Helen
  • Date: 2012
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/68983 , vital:29345 , https://hdl.handle.net/10520/EJC127082
  • Description: Publisher version , This article takes a critical look at law teaching in South Africa and seeks to consider how the application of experiential learning theory may assist law students in gaining a deeper understanding of the law in general, and the complexities of real life practice in particular. While clinical legal education is often seen as the locus of experiential learning in law, the author proposes that well-structured simulations in class can achieve similar goals. The article comprises a description of the nature of experiential learning and a further description of the application of the principles of experiential learning in a particular simulation exercise in a Legal Ethics course (using the US case of Wash St Phys Ins Exch v Fisons Corp 858 P2d 1054 (Wash 1993) as a basis). The author posits that the so-called experiential learning "cycle" or "process" enables a process of learning which draws out the students' beliefs and ideas about a topic so that it can be examined, tested and integrated with new, more refined ideas. This notion is then in keeping with the expectation that students who emerge from higher education institutions have developed meta-cognitive skills. Essentially then, it is hoped that, by using the methods proposed in this article, students can then manage their own development and learning throughout life.
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  • Date Issued: 2012

Physicochemical and photodynamic antimicrobial chemotherapy activity of morpholine-substituted phthalocyanines: Effect of point of substitution and central metal

  • Authors: Sindelo, Azole , Kobayashi, Nagao , Kimura, Mutsumi , Nyokong, Tebello
  • Date: 2019
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/187438 , vital:44652 , xlink:href="https://doi.org/10.1016/j.jphotochem.2019.01.025"
  • Description: In this study, novel metal-free, zinc and indium 1(4),8(11),15(18),22(25)-tetramorpholine (1a, 2a, 3a respectively) and 2(3), 9(10), 16(17),23(24)-tetramorpholine (1b, 2b, 3b respectively) phthalocyanines were synthesized and complexes 2 and 3 were quaternized. The photophysical and photochemical properties were investigated in dimethylsulfoxide. The non-peripherally substituted phthalocyanines generated higher singlet oxygen than the peripherally substituted phthalocyanines. Photodynamic antimicrobial chemotherapy activities towards inactivation of Escherichia coli, Staphylococcus aureus and Candida albican were evaluated, where all the quaternized Pcs showed total elimination of the micro-organism with log reductions greater than 9. Though the neutral Pcs had log reductions less than 2, for C. albican the percentage reduction was 68.5% for 2b showing the antifungal properties of the morpholine group.
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  • Date Issued: 2019

Naked Eye and Colorimetric Detection of Cyanide with a 1, 3‐Diethyl‐2‐thiobarbituric Acid Substituted Ferrocene Chemosensor

  • Authors: Babu, Balaji , Mack, John , Nyokong, Tebello
  • Date: 2021
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/190567 , vital:45006 , xlink:href="https://doi.org/10.1002/slct.202100163"
  • Description: A 1,3-diethyl-2-thiobarbituric-acid-substituted ferrocene (FET) has been evaluated for its cyanide sensing ability by UV-visible absorption spectroscopy and other characterization methods. FET provides a ratiometric colorimetric chemosensor for the CN− anion detection in 1 : 1 DMSO/H2O (v/v) solution. The addition of CN− results in an immediate color change from dark blue to pale orange that is visible to the naked eye. Mechanism studies and molecular modelling with TD-DFT calculations demonstrate that nucleophilic addition of CN− to an electrophilic sp2-hybridized carbon atom blocks charge transfer from the ferrocene ring complex to the thiobarbituric acid moiety. The FET sensor exhibits excellent selectivity for CN− and a limit of detection of 0.2 μM.
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  • Date Issued: 2021

Application of graphene quantum dots functionalized with thymine and thymine-appended zinc phthalocyanine as novel photoluminescent nanoprobes

  • Authors: Achadu, Ojodomo John , Nyokong, Tebello
  • Date: 2017
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/188508 , vital:44760 , xlink:href="https://doi.org/10.1039/C6NJ03285K"
  • Description: Graphene quantum dots (GQDs) and zinc phthalocyanine (ZnPc) were separately modified with thymine to obtain thymine-functionalized GQDs (T-GQDs) and ZnPc (T-ZnPc). T-GQDs and nanoconjugates of T-ZnPc with pristine GQDs (represented as pristine GQDs–T-ZnPc) or T-GQDs (represented as T-GQDs–T-ZnPc) were employed as fluorescent probes for the detection of mercury(II) ions (Hg2+). The as-synthesized T-GQDs alone demonstrated a highly sensitive and selective fluorescence “turn-OFF” process for Hg2+ detection due to the specific interaction between the thymine functionality on the T-GQDs with Hg2+. On the other hand, the fluorescence of pristine GQDs and T-GQDs was quenched (“turn-OFF”) upon coordination with T-ZnPc. However, the fluorescence emission was selectively restored (“turn-ON” process) in the presence of Hg2+ resulting in the sensitive detection of Hg2+ in the nanomolar concentration range (limit of detection = 0.05 nM, for the pristine GQDs–T-ZnPc probe). The probe containing pristine GQDs and the T-ZnPc complex demonstrated a higher specific and sensitive recognition of Hg2+ as compared to the T-GQDs alone or T-GQDs–T-ZnPc probes which are ascribed to the fluorescence “turn-ON” process of the former. Screening of different metal ions and counter ions proved that the probes are specifically suited for Hg2+ detection.
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  • Date Issued: 2017

Higher education studies as a field of research

  • Authors: McKenna, Sioux
  • Date: 2014
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/187405 , vital:44631 , xlink:href="https://hdl.handle.net/10520/EJC161436"
  • Description: The field of Higher Education Studies is a rapidly growing one in South Africa and abroad but there has been little systematic review of the form this growth is taking. This article presents a case study of higher education research by considering a newly formed Higher Education Studies doctoral programme. The programme comprises 29 PhD scholars in 2014, all engaged in research on some aspect of higher education. The description of the PhD programme, the PhD scholars and what their research topics are, reveals a picture of the broad range of concerns within the field of Higher Education Studies and suggests that the field is a region, in Bernstein's terms. This means that it draws on multiple disciplines and looks both to the values and structures of those disciplines and to the professional world of work. It is argued that the strengthening of the epistemological base of Higher Education Studies is necessary for higher education research to move forwards with enhanced relational and positional autonomy.
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  • Date Issued: 2014

Dangers of generic pedagogical panaceas: implementing sevice-learning differently in diverse disciplines

  • Authors: Hlengwa, Amanda I , McKenna, Sioux
  • Date: 2017
  • Language: English
  • Type: article , text
  • Identifier: http://hdl.handle.net/10962/61051 , vital:27933 , http://joe.ukzn.ac.za/Libraries/No_67_2017/Dangers_of_generic_pedagogical_panaceas_Implementing_service-learning_differently_in_diverse_disciplines.sflb.ashx
  • Description: Descriptions of service-learning in the literature tend to position it as a powerful pedagogic tool as well as an exemplar of ‘best practice’ applicable across all disciplines and institutional contexts. Furthermore service-learning is couched as a moral imperative. In the South African context, this moral imperative is translated into policy pronouncements driving institutions of higher education to demonstrate responsiveness to the transformation needs of broader society. In this article, two departments, Philosophy and Environmental Science, at one university are used as case studies to interrogate what enables the uptake of service-learning as a pedagogic tool. Drawing on the work of Fairclough, this paper identifies the dominant discourses at play and considers how they constrain or enable the uptake of service-learning. We advocate for the infusion of service-learning in curricula, but argue that institutional culture, disciplinary values and the structure of knowledge impact on its uptake and should not be dismissed in the implementation process.
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  • Date Issued: 2017

Children navigating rural poverty: Rural children's use of wild resources to counteract food insecurity in the Eastern Cape, South Africa

  • Authors: McGarry, Dylan K , Shackleton, Charlie M
  • Date: 2009
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/372724 , vital:66617 , xlink:href="https://doi.org/10.1080/10796120802677594"
  • Description: This paper analyzes the role of natural resources in the lives of rural children experiencing heightened vulnerability to poverty and the impact of HIV/AIDS, a subject that previously has been unexplored. The authors highlight wild-food use by rural children as a regular activity that supplements their domestic diets. Over the course of 18 months in the Eastern Cape of South Africa, the authors used a broad quantitative and qualitative methodology to explore the food acquisition and consumption patterns for 850 children. They found that the quality of children’s domestic diets was, on average, 60% lower than the Food and Agricultural Organization (FAO) guidelines. This occurred in a population where 62% of the children surveyed were supplementing their diets with wild foods; and 30% with over half their diet supplemented in this way. Significantly, dietary diversity increased by 13% when wild food supplementation occurred. Another result was the commercialization of wild foods (observed among 47% of the children), wherein significantly more vulnerable children sold these foods. Considering the heightened nutritional and energy needs of children, combined with the impact of poverty and HIV/AIDS on household food access, wild foods represent the last freely attainable food sources available to them.
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  • Date Issued: 2009

Integrating stomach content and stable isotope analyses to elucidate the feeding habits of non-native sharptooth catfish Clarias gariepinus

  • Authors: Kadye, Wilbert T , Booth, Anthony J
  • Date: 2012
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/124843 , vital:35703 , https://doi.10.1007/s10530-011-0116-6
  • Description: Sharptooth catfish Clarias gariepinus was introduced into the Eastern Cape Province, South Africa, in 1976 and there are concerns about its possible negative impacts on native biota. This study investigated its trophic impact by examining its feeding habits. Stomach content and stable isotope analyses were compared from three localities—the Great Fish River, Sundays River and Glen Melville Dam. Stomach content analysis indicated a catholic diet dominated by fish particularly in all localities.Spatially, however, the diets revealed differences based on the dominance of macrophytes that were only present in the rivers, and aquatic invertebrates that appeared more diverse within the Great Fish River compared to other localities. By contrast, stable isotopes revealed a more generalised feeding pattern with no clear dominance of particular prey. Stable isotopes further showed that the catfish was a complex predator, with large catfish being top predators whereas smaller size groups appeared to feed lower in the food chain. An ontogenetic shift in diet was evident, with small fish predominantly consuming aquatic invertebrates and shifting towards fish with increasing size. High dietary overlap suggests the potential risk associated catfish feeding, especially the potential of piscivory by small catfish that are more likely to persist in shallow and marginal where endangered indigenous minnows occur. The alteration of environmental conditions, especially flow by inter basin water transfer (IBWT) schemes, was inferred to have had a probable influence its invasion success. Occurrence of other invaders, which was facilitated by the IBWT together with the catfish, posits the risk of invasion meltdown within the study systems.
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  • Date Issued: 2012
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