Health Psychology and the framing of abortion in Africa: a critical review of the literature
- Authors: Macleod, Catriona I , Chiweshe, Malvern T , Mavuso, Jabulile
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143871 , vital:38290 , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: Despite 97% of abortions performed in Africa being classifiable as unsafe, there has been virtually no engagement in knowledge production about abortion in Africa from psychologists, outside of South Africa. Taking a feminist health psychology approach, we conducted a systematic review of published research on this topic featured in PsycINFO over a six year period. We analysed the 39 articles included in the review in terms of countries in which the research was conducted, types of research, issues covered, framings, and main findings. The results show that apart from a public health framing, perspectives that foreground contextual, social, cultural, gendered perspectives dominate. While abortion services, unsafe abortion and the incidence of abortion were well researched, so too were attitudes and public discourses on abortion. Clinical psychological, reproductive justice or rights and medical framings received little attention. We outline the implications of this knowledge base for feminist health psychology in Africa.
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- Date Issued: 2015
Pecha Kucha 1: Critical Studies in Sexualities and Reproduction
- Authors: Macleod, Catriona I
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143915 , vital:38294 , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: Despite enabling legislation and policies in the areas of sexualities and reproduction in South Africa, multiple challenges persist, including: forced sexual debut, sexual coercion and violence; HIV infection; hate crimes against lesbian women and gay men; unwanted and unsupportable pregnancies. While it is acknowledged that interventions (e.g., sexuality education programmes, the promotion of antenatal care use and the promotion of non-discrimination) have the potential to improve men’s and women’s sexual and reproductive lives. There are also multiple ways in which such programmes and the surrounding public discourses concerning sexuality and reproduction can serve in often unintended and unwitting ways to perpetuate oppressive heteronormative, gendered, racialised and class-based power relations. The Critical Studies in Sexualities and Reproduction research programme focuses on how particular discourses, narratives, and practices promote inclusion or exclusion, belonging or marginalisation, equity or inequity, justice or injustice, access to, or denial of, sexual and reproductive rights.
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- Date Issued: 2015
Water, water everywhere: is Integrated Water Resource Management the right institutional prescription for South Africa's water management challenges?
- Authors: Madigele, Patricia K , Snowball, Jeanette D , Fraser, Gavin C G
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68555 , vital:29282 , http://2015.essa.org.za/fullpaper/essa_2849.pdf
- Description: Publisher version , Ostrom (2007) and Ostrom and Cox (2010) argue that natural resource management has been plagued by the “panacea problem": that one-size-fits-all solutions to allocation and management problems have been applied without due consideration of the specific context. The outcome has been the disappointing results of many development and management programs. Integrated Water Resource Management (IWRM) has been recognised as a potentially effective way of allocating water where there are multiple, sometimes competing, users (Saravanan et al. 2009). It has been used successfully in a number of other developing country contexts, including Mexico, Brazil, India and Thailand (Orne-Giliemann 2008; Meinzen-Dick 2007). The principles of IWRM were also adopted in South Africa under the National Water Act (1998). Water User Associations (WUA) are seen as one of the key institutions driving IWRM, since they are designed to allow stake-holders at local level a say in the allocation and management of this important public good (Aoki 2001). However, WUAs in South Africa have mostly not been a success and are currently being reviewed at national level. For the most part, emerging black farmers and rural communities still do not have equal access to water, or a meaningful role in decision-making, and there are significant security of supply and allocation issues with regard to municipal users as well. Using the AID (Institutional Analysis and Development) framework (Ostrom 2007), with particular reference to economic theory relating to incentives and transactions costs, this paper asks if IWRM is a panacea treatment that does not fit the diagnosis of South Africa's water management problems. A case study approach is used, focusing on one of the few established WUAs in the Sundays River Valley Municipality in a rural area of South Africa.
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- Date Issued: 2015
The economics of institutions, institutional governance and efficiency: the case of water distribution in Lower Sundays River Valley
- Authors: Madigele, Patricia Kefilwe
- Date: 2015
- Language: English
- Type: text , Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10962/54777 , vital:26611
- Description: The institutional dynamics, policies and legislation that were prevalent during the apartheid era have left imprints that are difficult to ignore as they still dictate the interaction between different elements in the water sector to date. During the apartheid era, the formulation of policies was informed by racial segregation, resulting in a socio-economic pattern that dictated the distribution and access of resources for the people of different races in the country. Post-apartheid, the National Water Act has established the basis for management of water resources on a catchment basis (for equity, efficiency and sustainability), and the Water Services Act aims to ensure everybody has access to basic water supply and sanitation services. Regardless of the improvements in water supply to the rural sector made by the South African government, many of the current patterns of water use are still characterised by inequality, inefficiency, and inadequacy. The poor remain marginalised, and emerging farmers and poor rural communities have limited access to water resources while water continues to be used inefficiently by some farmers in the agricultural sector with few incentives to improve its water use efficiency. Despite the existence of the thriving citrus industry in the area, around 60% of people in the Sundays River Valley Municipality (SRVM) live below the poverty datum line. The inequality between the municipal populace and the commercial citrus industry is noticeable and the inequitable water redistribution is prevalent in the Lower Sundays River Valley (LSRV). The problem of disrupted water supply is prevalent in the catchment. However, there is also currently no physical shortage of water in the catchment. Therefore, the currently experienced problems with water supply in the LSRV are consequence of a lack of effective institutions and infrastructure, not of physical water scarcity. It is argued in this paper that there is a notable lack of understanding about the design of institutions for water management in developing countries. The vast majority of research on water management and access is premised on neoclassical economics ideas related to water markets and pricing among others. The neoclassical economics approach, however, does not adequately define the role of institutions in shaping the direction of water access and supply. This study uses new institutional economics (NIE) arguments to define the institutional arrangements and dynamics defining the water sector in South Africa, using the Lower Sunday River Water Users Association (LSR-WUA) as the case study. It aims at analysing the institutional governance and performance of the using equity, efficiency and effectiveness as key indicators. The various research methods employed in this study include; interpretive and post-positivist paradigms, quantitative and qualitative research, the case study research method and in-depth key informant interviews. It is concluded that that the current and future decisions made by the LSR-WUA are not entirely independent of those made in the past under Sundays River Irrigation Board (SRIB). The thesis argues that such factors as old effective networks, vested interests of commercial farmers, sunk costs towards the building of canals, among other factors, may have influenced the dependence of the LSR-WUA on the SRIB’s set path. It is further concluded that the absence of contractual agreement between the LRS-WUA which acts as the bulk water supplier, and the SRVM which acts as both the water services authority (WSA) and the water service provider (WSP) creates an institutional arrangement deficiency. Such an institutional arrangement vacuum can lead to a failure of the water institutions in the catchment to provide water resources effectively. The study further argues that because the post-apartheid National Water Policy of South Africa is largely influenced by neoclassical economics foundations, the desired results in the water sector, such as equitable distribution of water resources, have not yet been fulfilled completely.
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- Date Issued: 2015
Book Review: Global Governance and the New Wars
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298640 , vital:57723 , xlink:href="https://doi.org/10.1080/02589346.2015.1008676"
- Description: Mark Duffield's second edition of ‘Global Governance and the New Wars’ offers an important and biting critique of how different actors within the security and development discourse have adapted to the various transformations of war in the post-cold war era. In this picture drawn by Duffield, the power of states in the South continues to be eroded by an exclusionary market that is driven by the global political economy wherein state's development and security responsibilities are increasingly assumed by non-state actors (predominately constituted by Western aid agencies). Those who fall outside the bounds of the state, development and humanitarian aid agencies can be found operating in an expanding shadow economy that is also shaped by a global dynamics which make the conditions for ‘network war' possible. In this context, the lines between ‘war' and peace” are difficult to distinguish. Overall, the book paints a depressing picture on the lack of substantive changes in the livelihoods of the poor as attention has been directed to discussions about ‘new wars' or altered forms of violence that have characterized the post-cold war era. The book unforgivingly exposes the failures of the discursive changes post-cold war to reconceptualize development and security in terms that move beyond description and into substantive change especially regarding shifting the development discourse from its historic modernizing impulses.
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- Date Issued: 2015
Women combatants and the liberation movements in South Africa
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298584 , vital:57718 , xlink:href="https://doi.org/10.1080/10246029.2015.1088645"
- Description: This article examines women's role as combatants in national liberation forces in South Africa. Three categories – guerrilla girls, combative mothers and the in-betweeners – are introduced to underscore the varied ways in which women have participated in combat within the national liberation movements. Factors such as age and one's ability to leave the country affected whether women could participate in combat as ‘guerrilla girls’ or if it limited them to fighting apartheid violence from home, or if there were women who can be defined as having fallen somewhere in between these categories. These categories are used to theorise women's combat roles in the anti-apartheid struggle, thus broadening and challenging the dominant notions of combat that often hide women's contributions in war. In this regard, different periods of struggle, physical location, as well as age, determined the methods of activism available to men and women.
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- Date Issued: 2015
Book Review: A Renegade called Simphiwe
- Authors: Magadla, Siphokazi
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/298595 , vital:57719 , xlink:href="https://doi.org/10.1177/0021909614533638"
- Description: A Renegade called Simphiwe is a “creative-intellectual portrait” of the public (and private) life of the musician Simphiwe Dana (p. 150). Gqola defines the book as “one writer’s engagement with the Simphiwe Dana of the South African public imagination [who]… troubles many categories of belonging in the South African public imagination in remarkable ways” (pp. 17, 32). The book comes at a poignant time as South Africa reflects on the success and challenges of the first 20 years of democracy. Fittingly, Gqola positions Dana within a long tradition of griots in Africa whose art always spoke truth to power.
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- Date Issued: 2015
Synthesis, characterization and photophysical properties of an acenaphthalene fused-ring-expanded NIR absorbing aza-BODIPY dye
- Authors: Majumdar, Poulomi , Mack, John , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189763 , vital:44929 , xlink:href="https://doi.org/10.1039/C5RA14916A"
- Description: The synthesis and characterization of an NIR absorbing acenaphthalene fused-ring-expanded aza-BODIPY dye are reported. In contrast with its naphtho-fused analogue, a stable complex is obtained when the corresponding phthalonitrile is used as the precursor. A comparison is made with the photophysical properties of 3,5-diphenyl-aza-dibenzoBODIPY.
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- Date Issued: 2015
Being a Born Free: the misunderstandings and missed opportunities facing young South Africans
- Authors: Malila, Vanessa
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158680 , vital:40220 , https://hdl.handle.net/10520/EJC175765
- Description: Young South Africans are often referred to as the Born Frees - a term which sometimes means people born after 1994, sometimes people born after 1990, or young people who came of age politically after 1994. I've come to really dislike the term Born Frees and particularly the way it is used by the media and the politicians. By calling young people Born Frees, society is using apartheid as a reference point to identify a post-apartheid generation. This reference point (the transition to a 'free' society) unfortunately does not resonate with many of the young people that I've encountered in my research and many feel insulted by the implications of this term, which does not apply to them in any way. Should South African society really be using the transition from apartheid to define its young people and how does it relate to the lives of real young people in South Africa today? Are they really Born Free, free from what, free to do what, free individuals or free as a collective? I will look at some of the stereotypes being used in the mainstream media of Born Frees, and then look at the reaction to this term by some real young South Africans.
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- Date Issued: 2015
Photodynamic antimicrobial chemotherapy activity of (5, 10, 15, 20-tetrakis (4-(4-carboxyphenycarbonoimidoyl) phenyl) porphyrinato) chloro gallium (III)
- Authors: Managa, Muthumuni , Amuhaya, Edith K , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189043 , vital:44811 , xlink:href="https://doi.org/10.1016/j.saa.2015.06.088"
- Description: (5,10,15,20-Tetrakis(4-(4-carboxyphenycarbonoimidoyl)phenyl)porphyrinato) chloro gallium(III) (complex 1) was conjugated to platinum nanoparticles (PtNPs) (represented as 1-PtNPs). The resulting conjugate showed 18 nm red shift in the Soret band when compared to 1 alone. Complex 1 and 1-PtNPs showed promising photodynamic antimicrobial chemotherapy (PACT) activity against Staphylococcus aureus, Escherichia coli and Candida albicans in solution where the log reductions obtained were 4.92, 3.76, and 3.95, respectively for 1-PtNPs. The singlet oxygen quantum yields obtained were higher at 0.56 for 1-PtNPs in DMF while that of 1 was 0.52 in the same solvent. This resulted in improved PACT activity for 1-PtNPs compared to 1 alone.
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- Date Issued: 2015
Photodynamic antimicrobial chemotherapy activity of gallium tetra-(4-carboxyphenyl) porphyrin when conjugated to differently shaped platinum nanoparticles
- Authors: Managa, Muthumuni , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189088 , vital:44815 , xlink:href="https://doi.org/10.1016/j.molstruc.2015.06.077"
- Description: This work reports on the conjugation of differently shaped Pt nanoparticles (PtNPs) with ClGa(III) 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin (ClGaTCPP). The resulting conjugates were used for photodynamic antimicrobial chemotherapy against Staphylococcus aureus. The degree of photoinactivation is dependent on concentration of the conjugates, light dose (fluence) and illumination time. The log reduction obtained for ClGaTCPP when conjugated to cubic PtNPs was 4.64 log (which indicate 99.99% of the bacteria have been killed), which is much higher than 3.94 log unit for ClGaTCPPHexagonal PtNPs and 3.31 log units for ClGaTCPP-Unshaped PtNPs. ClGaTCPP alone gave a log unit reduction of less than 3, showing the importance of conjugation to PtNPs.
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- Date Issued: 2015
The time of hospitality in Samuel Beckett's Murphy, Michael Ondaatje's The English Patient and Damon Galgut's The Good Doctor:
- Authors: Marais, Mike
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144106 , vital:38312 , DOI: 10.1080/00138398.2015.1083193
- Description: In this article, I focus on the temporal dimension of the differential process through which community constitutes itself. If community is premised on the sameness that is enabled by that which it excludes, and sees as a threat, then it must seek always to conserve itself and to render the future – which is hazardous in its uncertainty – calculable, predictable and determinable. In its search for stability and permanence, community must dominate time in such a way that it is overcome, that it withdraws from itself. Arguably, though, we would view time less teleologically and programmatically, if we could relate differently to the difference on which community depends. A form of hospitality that is predicated on an acceptance of otherness – not only that of a community's outsiders, but also the ‘common strangeness’ of its insiders – would alter the ways in which being-in-common is conceived, and would also change our experience of belonging.
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- Date Issued: 2015
Electrocatalytic activity of bimetallic Au–Pd nanoparticles in the presence of cobalt tetraaminophthalocyanine
- Authors: Maringa, Audacity , Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189719 , vital:44925 , xlink:href="https://doi.org/10.1016/j.jcis.2014.10.056"
- Description: Au and Pd nanoparticles were individually or together electrodeposited on top of polymerized cobalt tetraaminophthalocyanine (poly-CoTAPc). When Pd and Au nanoparticles are co-deposited together, the electrode is denoted as Au–Pd (co-deposited)/poly-CoTAPc-GCE. X-ray photoelectron spectroscopy (XPS) was used to show the successful deposition of AuNPs, PdNPs and Au–Pd (co-deposited). The scanning electrochemical microscopy showed that Au–Pd (co-deposited)/poly-CoTAPc-GCE (with current range of 9.5–13.5 lA) was more conducting than Au–Pd (co-deposited)-GCE (with current range of 8–12 lA). Electrochemical impedance spectroscopy (EIS) showed that there was less resistance to charge transfer for Au–Pd (co-deposited)/poly-CoTAPc-GCE compared to the rest of the electrodes. Au–Pd (co-deposited)/poly-CoTAPc-GCE showed the best activity for the electrooxidation of hydrazine in terms of limit of detection (0.5 lM), hence shows promise as an electrocatalyst for electrooxidation of hydrazine.
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- Date Issued: 2015
Making rules to live by: Was the proposed regulatory regime for invasive species reasonable? Perceptions of the South African trout industry
- Authors: Marire, Juniours , Snowball, Jeanette D , Fraser, Gavin C G
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68566 , vital:29285 , http://2015.essa.org.za/fullpaper/essa_2938.pdf
- Description: Publisher version , Despite considerable economic impact of trout-based aquaculture and recreational fishing, the Department of Environmental Affairs has been focusing almost entirely on ecological criteria in deciding the regulatory regime for trout. We examined whether the proposed regulatory regime for alien and invasive species that was published by the Department of Environmental Affairs in 2014 for public comment was reasonable. The analysis produced factors that might matter in the design of reasonable institutional arrangements that impose a reasonable regulatory burden on economic sectors utilising invasive species. We conducted factor analysis using an online survey that we conducted between May and July 2014. We obtained four clusters of factors: participatory policymaking, people-centeredness, credible scientific evidence for listing species as invasive and contextualisation of international evidence. We then utilised the factors in a logistic regression framework to assess their influence on the probability of perceiving the regulations to be reasonable. The likelihood of a trout sector player perceiving the regulations to be reasonable was 1.2%. We found that a one standard deviation increase in the “credibility of scientific evidence” increased the odds of perceiving the regulations to be reasonable by 1645%. A one standard deviation increase in “participation” increased the odds of perceiving the regulations to be reasonable by 410%. A one standard deviation increase in “people-centeredness” increased the odds of perceiving the regulations to be reasonable by 600%. Lastly, a one standard deviation increase in the variable “contextualising international evidence” increased the odds of perceiving the regulations to be reasonable by 415%. This research demonstrates that properly addressing the socioeconomic aspects of new policies in addition to ecological criteria makes it far more likely that stakeholders will regard them as reasonable, even if the new policies impose increased regulatory transaction cost burden on users or reduced access to a resource.
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- Date Issued: 2015
The impact of globalization on economic growth in South Africa
- Authors: Maronga, Vimbai Linah
- Date: 2015
- Subjects: Economic development -- South Africa , International economic integration , International trade
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10353/25861 , vital:64552
- Description: The dissertation investigated the impact of globalization on the economic growth of South Africa using annual South African data covering the period 1975 to 2011. The study used Johansen cointegration and vector error correction model to determine the impact of globalization on economic growth in South Africa. The VECM model with South African variables was specified and used to assess the effects of globalization on South Africa’s economic growth. Results of the study suggested that the South African economic growth was negatively impacted by globalization in the long run. Using the results conclusions and policy recommendations were made using these results. , Thesis (MCom) -- Faculty of Management and Commerce, 2015
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- Date Issued: 2015
DNA-based identification of Lepidoptera associated with citrus in South Africa
- Authors: Marsberg, Tamryn , Hill, Martin P , Moore, Sean D , Timm, A E
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/405782 , vital:70205 , xlink:href="https://hdl.handle.net/10520/EJC167513"
- Description: A number of insects, primarily Lepidoptera, cause damage to citrus in South Africa. A major limitation to the management and control of these pests is their correct identification. The aim of this study was to develop a database of gene sequences to aid in the identification of these Lepidoptera. Multiple specimens of 12 species were sequenced for the ~650 bp of the cytochrome oxidase I gene. These sequence data were supplemented and validated using sequences available in public databases. Results showed that each species could be unambiguously identified, and neighbour-joining analysis based on K2P distances formed highly supported, distinct clusters for each species, i.e. the maximum intraspecific genetic distance was less than that of the minimum interspecific genetic distances. Thus, this data set provides a molecular means to successfully identify the most important Lepidoptera associated with citrus in South Africa.
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- Date Issued: 2015
The politics of erasure: thinking critically about anonymity and confidentiality
- Authors: Marx, Jacqueline , Macleod, Catriona I
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143827 , vital:38286 , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: Anonymity and confidentiality are prominent features in research ethics codes. In this paper we critically examine the ethical imperative to change or eradicate research participant’s names and the distinctive, individually identifying characteristics of their lives. Drawing on examples from a research ethics application for a project involving women who had extricated themselves from relationships in which they had experienced intimate partner violence, and an ethnographic case study of cross-dressing and drag, consideration is given to the multiple ways in which anonymity and confidentiality can be put to work, both promoting and undermining what it means to do ethical research. We argue that the requirement for anonymity and confidentiality cannot be assessed without taking into account historicity and the socio-political contexts in which a study and its participants are located. The paper concludes with some consideration of the implications of a situated ethics approach for institutional review board protocols.
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- Date Issued: 2015
Pecha Kucha 2: Race and gender politics in cross-dressing, dressing-up, and drag
- Authors: Marx, Jacqueline
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143926 , vital:38295 , https://ischp.files.wordpress.com/2015/08/ischp_2015_abstract_booklet.pdf
- Description: Sexuality is often less discernible than other markers of identity such as race and gender, which means that its perceptibility is often contingent on strategies that make it visible. Visibility is an especially important dimension in the shaping of lesbian and gay identities because people are generally assumed to be heterosexual. Making gay and lesbian identities visible is also an important political issue for people who have, historically, been threatened by the violence of public erasure. It is this aspect of gay and lesbian subjectivity – the politics of visibility – that is the topic of this presentation. We focus on gender and race politics in dressing-up, cross-dressing and drag performances - practices which make gay and lesbian sexualities visible, and consider the role that race and gender play in diminishing and exacerbating visibility.
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- Date Issued: 2015
Constructing sexualities: a critical overview of articles published in Feminism and Psychology
- Authors: Marx, Jacqueline , Donaldson, Natalie
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142040 , vital:38044 , DOI: 10.1177/0959353515572704
- Description: How have sexualities been dealt with in articles published in Feminism and Psychology since the inception of the journal in 1991? The idea for this overview arose from our experience of designing a critical sexualities course for graduate students in psychology. The articles featured in this overview form part of a Virtual Special Issue that can be located on the Feminism and Psychology website. Virtual Special Issues (VSI) are collections of previously published articles, which have been compiled by guest editors who are experts in the field. VSIs provide readers with an overview of feminist thought about a topic or theme, as well as an easy way to locate pertinent articles. Scholars who are approaching a new topic may find a VSI especially useful, as will instructors who are preparing course syllabi. This article introduces the Constructing Sexualities VSI.
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- Date Issued: 2015
Electrocatalytic studies of covalently immobilized metal tetra-amino phthalocyanines onto derivatized screen-printed gold electrodes
- Authors: Mashazi, Philani N , Nyokong, Tebello
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249059 , vital:51774 , xlink:href="https://doi.org/10.1007/s00604-010-0438-6"
- Description: Metal tetra-amino phthalocyanine complexes (MTAPc; where M is Co or Mn) were immobilized on screen-printed gold electrodes pre-modified with monolayers of benzylamino groups. The functionalized electrodes were then activated using benzene-1,4-dicarbaldehyde as a linker before MTAPc complexes were immobilized. The surface coverages for the modified electrodes confirmed the perpendicular orientation of the MTAPcs. The apparent electron transfer constant (kapp) for the electrodes is 2.2 × 10−5 cm.s−1 for both CoTAPc and MnTAPc modified electrodes as calculated with data from impedance measurements. The kapp values for the bare and benzylamino modified electrodes were found to be 1.2 × 10−4 cm.s−1 and 4.9 × 10−6 cm.s−1, respectively. The electrocatalysis of the modified electrodes towards detection of H2O2 gave significant peak current densities and electrocatalytic potentials at −0.28 V and −0.31 V for the MnTAPc and CoTAPc modified electrodes, respectively.
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- Date Issued: 2015