Synthesis and characterization of group 12 dithiolate complexes as single source precursors for the preparation of hexadecylamine capped metal sulfide nanoparticles and polymer
- Authors: Osuntokun, Jejenija
- Date: 2016
- Subjects: Nanotechnology Nanoparticles Semiconductors
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10353/14060 , vital:39801
- Description: A series of heteroleptic mixed ligand complexes of some alkyl substituted thiourea, tetramethyl thiuram disulfide and 1-cyano-1-carboethoxy-2,2 ditholate of Zn(II) Cd(II) and Hg(II) have been synthesized by stoichiometry reactions of the ligands with respective metal salts. They have been characterized with analytical and spectroscopic techniques. Seven out of the 19 complexes synthesized are pyridine 2, 2 bipyridine and 1, 10 phenanthroline adducts of dissopropyl parent adducts of Zn(II) and Cd(II) complexes. All the complexes are proposed as four coordinate except the pyridine adducts, 2, 2’ bipyridine and 1, 10 phenanhroline adducts that are proposed as five and six coordinate respectively. All the complexes are solid, air stable and moisture stable for a many months. They are not soluble in common organic solvents but partially soluble in coordinating solvents like DMF and DMSO and due to their insolubility problems all attempts to grow single crystal of the complexes proved abortive. The complexes gave respective metal sulfide on thermal decomposition in TGA and this makes them to be potentially useful single source precursor for the synthesis of metal sulfide. All the complexes were invariably thermolysed in HDA to synthesis a series of HDA-capped ZnS, CdS and HgS nanoparticles. The optical properties of the nanoparticles reveal that they are all blue-shifted from the absorbance edge and this confirms quantum confinement of the nanoparticles. The transmittance electron microscope showed that the nanoparticles are in nanodimension. ZnS nanoparticles from the pyridine adducts gave HDA-capped ZnS nanoparticles with a mixture of hexagonal and cubic phases while the HDA capped CdS from the 2, 2 bipyridine and 1,10 phenanthroline gave anisotropic nanoparticles. The sizes of the CdS from the 1,10 phenanthroline adducts were also found to be biggest while CdS nanoparticles from 2,2 bipyridine adduct were also revealed to be bigger than the particle sizes obtained from the parent complex, (1-cyano-1 carboethoxyethylene-2,2-dithiolato- κ,S’S)-bis(N, N’-diisopropylthiourea -κS)cadmium(II). ZnS and CdS polymer encapsulated nanocomposites were also synthesized using a solution casting method. The polymers employed were; Polymethyl metharcrylate (PMMA), Poly(vinly alcohol) (PVA), and poly vinyl pyrrolidone (PVP). The structural and thermal properties of the pure polymers and the respective nanocomposites were investigated. It was observed that the ZnS/PVA and CdS/PVA were the most thermally stable composites when the thermal stability of the pure polymers were compared relative to the nanocomposites using data obtained from thermal decomposition results of the TGA.
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- Date Issued: 2016
Synthesis and structural studies of NiS and PdS nanoparticles/nanocomposites from dithiocarbamates single source precursors
- Authors: Nqombolo, Azile
- Date: 2016
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11359 , http://hdl.handle.net/10353/d1021326
- Description: The main aim of this research is to synthesize Ni(II) and Pd(II) dithiocarbamate complexes and use them as single source precursors for the synthesis of NiS and PdS nanoparticles and metal sulphides potato starch nanocomposites. Four dithiocarbamate ligands were synthesized and characterized using elemental analysis and spectroscopic techniques. The ligands were used to prepared homoleptic Ni(II) and Pd(II) complexes of the dithiocarbamate ligands. The metal complexes were characterized with elemental analysis, UV-Vis, FTIR and 1H-NMR spectroscopic techniques. Conductivity measurements indicate that all the complexes are non-electrolytes in solution and results from the electronic spectra studies confirmed the proposed 4-coordinate square planar geometry around the metal ions. The nickel complexes showed d-d transitions around 477 nm while in the palladium complexes, no d-d transitions were observed but the compounds showed strong metal to ligand charge transfer transitions. From the FTIR spectra studies, it can be confirmed that the complexes were successfully synthesised because all peaks of interest were observed at expected regions from the literature. The νC-N was observed around 1469-1495 cm-1, νC=S around 1101-1188 cm-1 and νC-S around 738-1060 cm-1 for both Ni(II) and Pd(II) complexes. νNi-S was observed around 375-543 cm-1 and νPd-S around 529-545 cm-1. The FTIR also confirmed that the dithiocarbamate ligands act as bidentate chelating ligands through the sulfur atoms. The complexes were used as single source precursors and thermolysed in hexadecylamine (HDA) at 220 °C to prepare four HDA-capped nickel sulfide nanoparticles and four palladium sulfide nanoparticles. The as-prepared nanoparticles were studied with optical absorption spectra, photoluminescence, powder X-ray diffraction (PXRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The optical studies results showed that NiS have large band gaps that are greater than that of the bulk, therefore they are found to be blue shifted relative to the bulk, which shows that they have small particle size and thus confirming their quantum confinement effect. PL spectra reveal that the emission peaks are red shifted compared to the absorption band edges of the nanoparticles. The XRD patterns confirmed the formation of cubic and rhombohedral phase for NiS nanoparticles and cubic phase for PdS nanoparticles. SEM images of both NiS and PdS show uniform surface morphology at low and high magnification with different shapes. EDS analyses confirmed the presence of Ni, S, and Pd in each of the spectrum indicating that the nanoparticles were successfully synthesized. TEM images showed that the synthesised nanoparticles have uniform and narrow size distribution with no agglomeration. The sizes of the NiS nanoparticles were found to be in the range of 12-38 nm for NiS1, 8-11 nm for NiS2, 9-16 nm for NiS3 and 4-9 nm for NiS4. The TEM images for the as-prepared PdS nanoparticles showed that the average crystallite sizes are 6.94-9.62 nm for PdS1, 8-11 nm for PdS2, 9-16 nm for PdS3 and 4-9 nm for PdS4 respectively. The nanoparticles were used to prepare potato starch nanocomposites and SEM images indicate that the surface morphology of starch polymer nanocomposites compose of potato starch and few particles in between the pores of the matrix, this is due to the small ratio of nanoparticles used.
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- Date Issued: 2016
Taking gendered harms seriously : the utility of rape trauma syndrome evidence in dispelling rape myths in criminal trials
- Authors: Nkala, Amanda Nothabo
- Date: 2016
- Subjects: Rape trauma syndrome Women -- Crimes against Rape -- Psychological aspects
- Language: English
- Type: Thesis , Masters , LLM
- Identifier: http://hdl.handle.net/10353/13458 , vital:39668
- Description: Rape is a violent crime marked by underreporting and low conviction rates. Notwithstanding the fact that most rape laws have been made to be gender-neutral, the statistics of rape are still devastatingly high even on a global scale. The majority of the victims are still predominantly females especially in the context of acquaintance rape. It is an uncontestable fact that rape usually occurs in secret making it possible for one to falsely accuse another and effectively rendering it difficult to refute. In light of this, victims who have managed to reach the courts have come face to face with a myriad of stereotypical beliefs and rape myths about rape victims. These have dealt a blow to their cases once their credibility is doubted because they may have exhibited behaviour that does not match with the classic or real rape victim as expected by the society. However rape is an egregiously unique crime that presents with serious psychological issues for the victim. As such it is possible for a rape victim to exhibit counterintuitive behaviour that can only be sensibly explained by an expert who has delved in human behavioural sciences. The alleged victim will be questioned on things like lengthy delay in reporting, returning to the scene of the crime, asking for taxi money the morning after the rape or even failing to scream and fight off the alleged assailant. Unfortunately, the psychological effects of rape have more often than not been overlooked in our criminal justice system giving way for blame shifting in that the female victim is called upon to account for why the rape may have happened to her. These psychological reactions, responses and counterintuitive behaviour have been characterized as Rape Trauma Syndrome by specialists in psychology and psychiatry. In the context of this study, Rape Trauma Syndrome is a form of expert opinion evidence which is relevant, helpful and necessary because it can dispel rape myths and stereotypical beliefs about rape victims by educating the courts about the psychological reactions of rape victims. Against this backdrop, this research project investigates the utility of Rape Trauma Syndrome evidence in dispelling rape myths in rape trials, focusing especially on the admissibility and use of that syndrome as evidence in other jurisdictions at the level of comparative analysis in order to establish whether it can be utilised in the South African context.
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- Date Issued: 2016
Tanzania's development agenda and poverty reduction : a case of Mkukuta I1
- Authors: Mandalu, Martin Petro
- Date: 2016
- Subjects: Poverty--Tanzania Tanzania--Economic conditions
- Language: English
- Type: Thesis , Doctoral , Development Studies
- Identifier: http://hdl.handle.net/10353/15616 , vital:40487
- Description: Poverty reduction has always been part of Tanzania‘s development agenda since independence in 1961. Despite wealth of natural resources, peace and political stability, the country has continued to be poor for decades. A number of strategies have been employed to address the problem; however, they have not been so successful. Studies have explored the problem and came up with explanations that are insufficient. In recent years, more studies on poverty reduction increased, following the country‘s magnificent economic growth which, however, fails to alleviate poverty in the country. Recent literature on poverty reduction calls for improvement in the productive sectors such as agriculture and construction to increase their contribution in poverty reduction. However, most studies did not pay attention to the development model/s that led the economy since independence. Motivated by the unsatisfactory results of the previous poverty reduction strategies, and lacunas of the preceding studies, this research, through MKUKUTA I, examines factors affecting the development agenda in Tanzania and their influence on poverty reduction. It investigates, as well, the development models employed in the country since independence. The study is guided by the change of development theories: from socialism to neo-liberalism. Furthermore, the study proposes an alternative development model beyond dependency and neo-liberalism schools of thoughts that have been struggling to influence development in the country for over five decades. The study employs mainly secondary data and primary data as supplementary methods to analyse and explain the mismatch between economic growth and poverty reduction in the country. The study argues that the productive sectors fail to produce sufficiently and contribute to poverty reduction since they are not guided by any specific development model. Findings suggest that failure in poverty reduction despite remarkable economic growth is caused by failure of growth in the agriculture sector which employs the largest part of the workforce in the country. Economic transformation in the country, which contributed to economic growth, failed to generate more jobs in the productive sectors. Incorrect methodologies used for obtaining economic data are alleged as possible logical explanation for the mismatch between economic growth and failure in poverty reduction. Failure in poverty reduction had a negative impact on human development as the poor, especially in the rural areas, had limited access to quality services of education, health care, water and sanitation. Moreover, findings revealed that neoliberal policies in the country are not effective enough in guiding the development agenda and poverty reduction. Despite the rule of law, peace, political stability and favourable conditions for capitalism in the country, significant features of a neoliberal economy have not been effectively developed. The local private sector is still weak at the embryonic stage, and the market is weakened by corruption and poor infrastructure for doing business. Moreover, findings suggest that for about three decades, Tanzania has not had a clear and distinct development model to guide its development agenda in poverty alleviation. The constitution suggests that the country is guided by a socialist development philosophy whereas the official government website and practices indicate that the country is run by neoliberal policies. To resolve the matter and in view of attaining the TDV 2025 and poverty reduction, this study proposes that Tanzania becomes a democratic developmental state while governed by a dependency-neoliberal theory from the amalgamation of reviewed dependency and neo-liberal schools of thoughts as a guiding principle since all developmental states need guiding philosophies to lead them. Moreover, the study proposes pragmatic interventions to implement the development model.
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- Date Issued: 2016
Teacher's views on the implementation of HIV/AIDS policies in schools: a case study of four high schools in Fort Beaufort Education District
- Authors: Koza, Rebecca
- Date: 2016
- Subjects: HIV infections -- Government policy -- South Africa -- Eastern Cape AIDS (Disease) -- Government policy -- South Africa -- Eastern Cape HIV infections -- Study and teaching -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Ed
- Identifier: http://hdl.handle.net/10353/2105 , vital:27610
- Description: HIV/AIDS is reducing the hard-won returns on investment in education in South Africa.
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- Date Issued: 2016
Teachers' experiences of teacher-led professional development programs :an exploratory study of two clusters in the Mthatha district
- Authors: Zide, Lulama
- Date: 2016
- Subjects: Teachers -- In-service training -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD (Education)
- Identifier: http://hdl.handle.net/10353/10394 , vital:35444
- Description: Professional growth of teachers is not new, but in recent years, the way in which it is structured and delivered has been reconceptualised. As part of the education reform process, many nations are investing in teacher education as a major engine for driving the changes in the classrooms to ensure learners’ academic success. South Africa is no exclusion to this trend of education reforms, hence, the founding of many professional growth initiatives. Most of these initiatives are aimed at Science and Maths teachers. This was mostly because the majority of Science and Maths teachers in South Africa are considered either under-qualified or not qualified to teach the subject. Yet, despite the efforts and enthusiasm, very little seems to have shifted in the teachers’ practices. Much of the literature still shows that even clusters are not effective in changing the situation completely. Using a qualitative case study design, the researcher explored teachers’ views on their clustering experience, and the benefits such participation and experience brings to their classroom instruction. The major findings of the study show that teachers find clustering as a tool that enriches their teaching, thus, both the content knowledge as well as their pedagogical strategies. The findings also show a consensus of teachers who need the cluster programs done continuously. The researcher concludes that teachers are still not happy with the professional development that is offered to them, and therefore recommends that such programs be offered according to teacher’s need.
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- Date Issued: 2016
Teachers' perceptions on the effects of frequent change in curriculum on effective teaching in junior secondary schools at Libode Education District, Eastern Cape
- Authors: Ngibe, Nondwe Cynthia Phelokazi
- Date: 2016
- Subjects: Curriculum change -- South Africa -- Eastern Cape Educational change Education -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Degree
- Identifier: http://hdl.handle.net/10353/5587 , vital:29349
- Description: Worldwide educational change has been a topic of discussion. South Africa is among the countries having issues with the implementation of a new curriculum and its impact on effective teaching and learning in junior secondary schools. The country (South Africa) experienced frequent changes in education curriculum. The new curriculum was seen as the means to address poor state of education. It is common knowledge that teachers were and are presently still confused and stressed being unsure on how to apply some techniques to meet the requirements of the new curriculum. That led to underperformance of learners in their work at school. Hence, this study was conducted to explore the perceptions of teachers in South Africa regarding the effects that frequent changes in curriculum has on the effective teaching and learning in junior secondary schools. The change in curriculum is frequent in the sense that, from 1997 to 2016, the curriculum in South Africa was revised four times: Curriculum 2005 (C2005) in 1997, Revised National Curriculum Statement (RNCS) in 2002, National Curriculum Statement (NCS) in 2007 as well as Curriculum and Assessment Policy Statement (CAPS) in 2012. The study does not leave behind some literatures on concept of education, teaching and learning in junior secondary schools, curriculum in South Africa, an overview of curriculum policy in South Africa, curriculum changes to mention a few. Qualitative research methodology was used by the researcher so as interview participants (teachers) in their workplace. The case study was chosen as the design, whereby two junior secondary schools from the population of schools in Libode district were purposely sampled. Data was collected from teachers in these schools, that is, six teachers from each school. Four teachers from each phase were targeted, that is, (four from foundation phase, four from intermediate phase and four from senior phase). Semi-structured interviews were used as the instrument to collect information from the participants. From the study, the researcher found confusion and frustration due to the frequent changes in curriculum; negative influence on effective teaching and learning, by the fact that teachers ultimately do not know what to do to meet the requirements of the curriculum; and not much continuity or links between phases in as far as content and subjects are concerned. The study recommended the appointment of professional facilitators, revisiting of the language policy in GET band (with focus in LOLT in foundation phase), encouraging continuity across phases, actively involvement of teachers in formulating or drafting of any policy that will affect curriculum since they are the implementers of curriculum. The study established that frequent change in curriculum had negative effects on teaching and in junior secondary schools. This is the perception of the majority of participants. As far as literature regarding teachers is concerned, changing curriculum without changing teachers’ understanding and attitude has negative impact on learning especially in South Africa, with special focus on rural schools such as those of Libode district in the Eastern Cape Province.
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- Date Issued: 2016
Technical and institutional constraints faced by vegetable co-operatives in the Buffalo City Metropolitan Municipality in Eastern Cape Province, South Africa
- Authors: Madlodlo, Sinazo
- Date: 2016
- Subjects: Agriculture, Cooperative -- South Africa -- Eastern Cape Vegetable trade -- South Africa -- Eastern Cape Cooperative marketing of farm produce -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1497 , vital:27396
- Description: This study focused on the technical and institutional constraints faced by the vegetable co-operatives with regard to the impact on productivity. Vegetable co-operatives have no access to markets due to their poor performance on productivity and poor quality produce resulting to low prices for the produce such that they cannot compete in a market economy. In this study, the data was drawn from a sample of thirty vegetable co-operatives in the Buffalo City Metropolitan Municipality (BCMM) of the Eastern Cape; obtained through focus group discussions and interviews from each cooperative. The objectives of the study are to measure the productivity of vegetable co-operatives using Total factor productivity analysis (TFP) and profitability of vegetable co-operative using Gross Margin (GM). Followed by the descriptive statistics in identifying and assessing the socio-economic characteristics as well as coping strategies adopted by vegetable co-operatives in BCMM where percentages, means and tables are used looking at the highest frequency. The results show that the vegetable co-operatives in the BCMM are not productive and profitable due to major constraints experienced by co-operatives such as lack of market, information, trainings and business skills, capital, infrastructural facilities, effective extension services that all leads to poor produce quality. Co-operative is said to be profitable and viable if total revenue is greater than the total variable cost which makes the gross margin positive. In this case, the total gross margin is negative. The results showed that the production costs, maintenance (tractor hire, generator hire and servicing) and electricity costs were the major costs incurred in the production of vegetable by the co-operatives.
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- Date Issued: 2016
Terrorism as a contributory factor to state failure in Somalia: a case study of Al- Shabaab
- Authors: Ndlovu, Sitembiso Irene
- Date: 2016
- Subjects: Terrorism -- Somalia Terrorism -- Government policy -- Somalia
- Language: English
- Type: Thesis , Masters , M Soc Sci
- Identifier: http://hdl.handle.net/10353/2458 , vital:27843
- Description: This study is an investigation of terrorism as a contributory factor to state failure in Somalia with specific reference to Al-Shabaab, using Huntington‟s Clash of Civilizations theory. It utilises both primary and secondary sources of data. The study found out that Somalia had been a failed state even before the birth of Al-Shabaab. However, the activities of Al-Shabaab perpetuated state failure in Somalia. These activities included bombings, small arms attacks, executions, siege, kidnappings, hijackings and looting. The study also found out that Al-Shabaab regularly conducted incursions in neighbouring countries and all these activities destabilised Somalia politically and perpetuated state failure. However, the study also found out that there were other factors that contributed to Somalia‟s state failure some of which were clan rivalry, civil war, warlordism, piracy, poverty and religion. Despite all these, the study noted that there were various actors involved in containing the terrorist activities of Al-Shabaab. These actors included the Transitional Federal Government, Kenya, the African Union, the United Nations and the United States. The study recommends that dialogue between the TFG, the clan structures and Al-Shabaab is the most viable path to sustainable peace in Somalia.
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- Date Issued: 2016
Terrorism as a contributory factor to state failure in Somalia: A case study of Al-Shabaab
- Authors: Ndlovu, Sitembiso Irene
- Date: 2016
- Subjects: Terrorism -- Somalia
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/2656 , vital:27979
- Description: This study is an investigation of terrorism as a contributory factor to state failure in Somalia with specific reference to Al-Shabaab, using Huntington‟s Clash of Civilizations theory. It utilises both primary and secondary sources of data. The study found out that Somalia had been a failed state even before the birth of Al-Shabaab. However, the activities of Al-Shabaab perpetuated state failure in Somalia. These activities included bombings, small arms attacks, executions, siege, kidnappings, hijackings and looting. The study also found out that Al-Shabaab regularly conducted incursions in neighbouring countries and all these activities destabilised Somalia politically and perpetuated state failure. However, the study also found out that there were other factors that contributed to Somalia‟s state failure some of which were clan rivalry, civil war, warlordism, piracy, poverty and religion. Despite all these, the study noted that there were various actors involved in containing the terrorist activities of Al-Shabaab. These actors included the Transitional Federal Government, Kenya, the African Union, the United Nations and the United States. The study recommends that dialogue between the TFG, the clan structures and Al-Shabaab is the most viable path to sustainable peace in Somalia.
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- Date Issued: 2016
The biomass production, nutrient content and silage quality of Perennial ryegrass (Lolium perenne (L)) Cocksfoot (Dactylis glomerata (L)) and Tall fescue (Festuca arundinacea (Schreb)) varieties grown under irrigation in Alice, South Africa
- Authors: Tikwayo, Sizwe Edward
- Date: 2016
- Subjects: Ryegrasses -- Varieties -- South Africa -- Eastern Cape Ryegrasses -- Irrigation -- South Africa -- Eastern Cape Biomass energy -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/1796 , vital:27560
- Description: The study aims to evaluate the biomass production and nutrient content and silage quality of perennial ryegrass (Lolium perenne (L)), cocksfoot (Dactylis glomerata (L)) and tall fescue (Festuca arundinacea (Schreb)). Six varieties were used, two for each species. A completely randomized block designed replicated three times was conducted at University of Fort Hare Research Farm during 2014-2015 growing season. The plots were harvested at four-week interval (post emergency) for one year. Biomass yields were measured for fresh forage and dry matter yield. Duplicated samples were then dried, milled and analyzed for chemical and mineral composition (CP, NDF, ADF, and ash, Ca, P, K, Na, Mn, Cu, Zn and Fe) for only winter season. In addition the grasses were ensiled and the silage was analyzed for its fermentation parameters and nutrient content (lactic acid, pH, DM, CP, NDF, ADF, and ash, Ca, P, K, Na, Mn, Cu, Zn and Fe). Biomass results showed significant differences (P < 0.05) between season and varieties. On average Tall fescue varieties Jessup (13741.67 FM kg/ha), Alix (12007.78 FM kg/ ha) and Ryegrass varieties Samson (11597.22 FM kg/ha) and Nui (10591.67 FM kg/ha) had the highest fresh biomass yield. Similarly, Tall fescue varieties Jessup (2833.06 DM kg/ha) and Alix (2708.3 DM kg/ ha) and Ryegrass varieties Samson (2169.44 DM kg/ha) and Nui (2169.67 kg/ha) had the highest dry biomass yield. Throughout the year the average biomass yield was significantly different among species (P< 0.05). During summer and autumn Tall fescue varieties Jessup and Alix gave the highest dry matter yields of 3855.5 to 1977.8 DM kg/ha, and 3877.8 to 1900 DM kg/ha, respectively, and followed by Cocksfoot 2400 DM kg/ha. Ryegrass had the highest dry matter biomass yield in winter (2975 DM kg/ha) and the least in summer (977.75 DM kg/ha). There were no significant (P>0.05) differences on the chemical composition (CP, NDF, ADF, and ash) and mineral composition (Ca, P, K, Na, Mn, Cu, Zn and Fe) of the six varieties. The grass silage results showed significant differences (P< 0.05) among the six varieties for moisture content. Perennial ryegrass variety Nui (66.76 percent) had low moisture content than the other grass silages. The different varieties had no significant effects (P>0.05) on chemical composition (CP, NDF, ADF, and ash) and mineral composition (Ca, P, K, Na, Mn, Cu, Zn and Fe). It is concluded that the biomass production of the six varieties of three grass species was different throughout the year under irrigation hence Ryegrass and Tall fescue are recommended for dairy farmers in the region for all seasons. It can be concluded that there is no difference with respect to fermentation characteristics and nutrient content among the varieties of the grass species.
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- Date Issued: 2016
The classsification of fuzzy subgroups of some finite Abelian p-groups of rank 3
- Authors: Appiah, Isaac Kwadwo
- Date: 2016
- Subjects: Fuzzy sets Abelian groups Finite groups
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2468 , vital:27845
- Description: An important trend in fuzzy group theory in recent years has been the notion of classification of fuzzy subgroups using a suitable equivalence relation. In this dissertation, we have successfully used the natural equivalence relation defined by Murali and Makamba in [81] and a natural fuzzy isomorphism to classify fuzzy subgroups of some finite abelian p-groups of rank three of the form Zpn + Zp + Zp for any fixed prime integer p and any positive integer n. This was achieved through the usage of a suitable technique of enumerating distinct fuzzy subgroups and non-isomorphic fuzzy subgroups of G. We commence by giving a brief discussion on the theory of fuzzy sets and fuzzy subgroups from the perspective of group theory through to the theory of sets, leading us to establish a linkage among these theories. We have also shown in this dissertation that the converse of theorem 3.1 proposed by Das in [24] is incorrect by giving a counter example and restate the theorem. We have then reviewed and enriched the study conducted by Ngcibi in [94] by characterising the non-isomorphic fuzzy subgroups in that study. We have also developed a formula to compute the crisp subgroups of the under-studied group and provide its proof. Furthermore, we have compared the equivalence relation under which the classification problem is based with various versions of equivalence studied in the literature. We managed to use this counting technique to obtain explicit formulae for the number of maximal chains, distinct fuzzy subgroups, non-isomorphic maximal chains and non-isomorphic fuzzy subgroups of these groups and their proofs are provided.
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- Date Issued: 2016
The contribution of smallholder agriculture production to food security in rural Zimbabwe : a case study of Masvingo Province
- Authors: Toringepi, Godfrey
- Date: 2016
- Subjects: Farms, Small -- Zimbabwe Agricultural productivity -- Zimbabwe Sustainable agriculture -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5598 , vital:29350
- Description: Agricultural development is back on the development agenda. Even though the smallholder farmers are in the majority and at the forefront in terms of food production and agriculture being the backbone of the economy of Zimbabwe, there is no clearly defined policy on smallholder agriculture in Zimbabwe. The food insecurity has remained a continuous challenge for the rural poor in Zimbabwe. This study investigated the contribution of smallholder agriculture to food security with particular reference to the Masvingo province. The study employed qualitative method of research entailing extensive review of literature as a method of data collection. The study utilized the modernisation theory and sustainable livelihoods framework to illustrate smallholder agriculture and food security nexus. The study revealed that smallholder agriculture is the best option for addressing food security since agriculture is considered the main livelihood strategy for small scale farmers in Zimbabwe. There is general scholarly consensus that the main cause of food insecurity in Zimbabwe is a decrease in smallholder agriculture productivity. The study revealed that poor infrastructure , limited access to credit, limited access to inputs, poor investment in human development, limited access to markets and harsh climatic conditions weaken the capacity of small scale farmers to improve food security. Key recommendations are that supportive institutions need to be put in place to strengthen the smallholder farmer’s capacity to improve food security in Zimbabwe.
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- Date Issued: 2016
The cultural practice of child marriage as a challenge to the realisation of the human rights of the girl –child: a comparative study of South Africa and Nigeria
- Authors: Olaborede, Adebola Olufunmi
- Date: 2016
- Subjects: Forced marriage Teenage marriage Children's rights Rites and ceremonies
- Language: English
- Type: Thesis , Doctoral , Law
- Identifier: http://hdl.handle.net/10353/2578 , vital:27898
- Description: This study primarily sets out to examine the cultural practice of child marriage in Africa with a focus on the comparative study of South Africa and Nigeria. This practice has been prohibited in a number of international human rights instruments such as the African Charter on the Rights and Welfare of the Child, and the Protocol to the African Charter on Human and Peoples’ Right on the Rights of Women in Africa. However, overwhelming statistics show that the overall prevalence of child marriage in Africa is still very high and if current trends continue, Africa will become a region with the largest number of the global share of child marriages, by 2050. Different interconnecting factors promote and reinforce child marriage which makes this practice very complex. The challenge of cultural traditional practices and religious beliefs that promote child marriage in Africa are evaluated in this study. The complexities surrounding these cultural practices mainly relate to the conflict that exists between adhering to customs and traditional practices, and promoting the practical implementations and enforcement of human rights standards within communities. In particular, the age at which most girls are given out in marriage conflicts with the minimum legal age of marriage, lack of free and full consent to marriage and the mixed legal system, which mainly comprises of customary law, Islamic law and common or civil law and legislation, that often conflict with one another in most African States. Discussions on these contradictions, as in the case of child marriage, often lead to a seemingly endless debate between the universality of human rights and cultural relativism within African societies. Therefore, this study bears heavily on the debate and relationship between culture and human rights, and the extent to which they can be reconciled in order to achieve a realisation of the fundamental rights of the girl-child. A qualitative research method based on an extensive literature analysis from different disciples is adopted. In addition, is a comparative study of South Africa and Nigeria which seeks to provide insight into the nature and extent of the practice of child marriage, as well as evaluate the adequacy, effectiveness and shortcomings of national legislations that relate to the rights of a girl-child in the context of child marriage, in both jurisdictions.
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- Date Issued: 2016
The effectiveness of internal financial controls with specific reference to the Eastern Cape Provincial Department of Basic Education
- Authors: Tini, Sabelo
- Date: 2016
- Subjects: Education -- Finance School management and organization -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/1896 , vital:27577
- Description: The purpose of this study was to assess the effectiveness of internal financial controls with specific reference to the Eastern Cape provincial department of basic education. A self-administered questionnaire was used to collect data. The questionnaire was filled by the respondents who are directly involved in processing payments and procuring for the departments. The findings have shown that Internal control system does exists within the department however the implementation and monitoring of its effectiveness needs to be strengthened. The findings show that the internal control system have an important role to play in attaining desired positive results within the department. Internal control effectiveness is one of the most important aspects in any organisation, whether in a private sector or in the public sector. It determines the stewardship of an entity’s management. The PFMA states that the accounting officer of a department must ensure that that department has and maintains effective, efficient and transparent systems of financial and risk management and internal control. If public officials could strictly adhere to the stipulated internal controls, there will be a positive response to accountability and also in service delivery as expected by the citizens. Public accountability gives a reflection on how does the entity conducts its business affairs in terms of adhering to the norms and standards as prescribed by the law and whether there are any strong controls to prevent acts of fraud and corruption.
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- Date Issued: 2016
The effectiveness of school nutrition programme of the Eastern Cape Department of Education
- Authors: Ndilele, Theodora Zola
- Date: 2016
- Subjects: School children -- Food -- South Africa -- Eastern Cape Children -- Nutrition -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/2005 , vital:27593
- Description: This dissertation is about the National School Nutrition Programme (NSNP) in South Africa. This Programme was introduced by government in 1994 with the aim of alleviating poverty; unemployment and improving learning capacity of children. Specifically, it is intended to help poor children and to empower poverty-stricken communities, particularly in the rural areas across all the nine provinces. The focus of this study is on the investigation of effectiveness and efficient management of the Programme in the Eastern Cape Province, with specific reference to Mhlontlo District. Mhlontlo district is one of the predominantly rural areas in the province of the Eastern Cape, a remote area characterized by high levels of poverty and unemployment, and low levels of infrastructural developments. Surrounding Schools in the area are also affected by these problems. Learners at these schools are from poor families. It is for this reason that this scheme becomes important as it is most needed and, to effectively and efficiently realise its intended objectives, it must be properly managed. The main theme of the study revolves around effective and efficient service delivery that must be taken as the first priority in the management of NSNP. Factors that contribute to efficiency and effectiveness must be taken into consideration by all stakeholders and are outlined as follows: The aims in this study is to assess the effectiveness of management of the National School Nutrition Programme at Mhlontlo district in the eastern Cape, to identity shortcomings in the management of the Programme and to suggest possible remedies to improve the management of the Programme to effective service delivery. Against the background of the problem statement, the following questions were posited. How can the management of the National School Nutrition Programme with specific reference to Mhlontlo district be enhanced to ensure that its intended objectives are realized? What effect will improved management have on service delivery in the National School Nutrition Programme? And how will adherence to the Batho Pele Principles improve service delivery in schools with regard to the National School Nutrition Programme? The target population in this study was the learners, teachers and community of Schools around Mhlontlo District whose children are being catered for at school as respondents. Statistics of learners who are beneficiaries of this programme were obtained from surrounding Schools. The percentage of the response to the questions led to the results that services are not delivered as effectively as expected. The study concluded by recommendations of what national and provincial department of Education are required to do together with the school, service providers and the community in order to improve service delivery in schools that participate in the NSNP. Finally, the NSNP is for the deprived citizens of South Africa. The onus is on the community of Mhlontlo District, service providers, teachers and education authorities responsible for the NSNP to work together to make the programme effective for advancing the development of young people.
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- Date Issued: 2016
The effectiveness of the concrete / semi-concrete / abstract (CSA) appoach and drill- practice on grade 10 learners' ability to simplify addition and subtraction algebraic fractions
- Authors: Awuah, Bernard Prince
- Date: 2016
- Subjects: Algebra, Abstract
- Language: English
- Type: Thesis , Masters , Degree
- Identifier: http://hdl.handle.net/10353/5105 , vital:29076
- Description: This study was conducted in one of the education districts in the Eastern Cape Province of South Africa. The purpose was to analyse the effectiveness of the concrete/semi-concrete/abstract (CSA) approach and drill-practice instructional strategies on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. The following two objectives were set. First, to identify the learners’ challenges in studying addition and subtraction of algebraic fractions in grade 10; and second to analyse the effectiveness of the CSA approach and drill-practice instructional strategies on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. Both threshold concepts and troublesome knowledge, Polya’s problem-solving techniques, CSA Approach theory and Drill-practice theory were all pertinent as a theoretical framework for the study. Positivism research paradigm was adopted for the study and it afforded the researcher opportunity to employ quantitative research approach. Based on the research question of this study, an experimental design was chosen as a suitable descriptive design. Purposive sampling method was used to select three schools which involved 135 grade 10 mathematics learners. Stratified random sampling method was thereafter employed to select 45 learners from each school for the study. The learners were grouped in each school as top, average and weak based on their performance in Algebra in term one. Pre-questionnaire and post-questionnaire were used to obtain data regarding challenges learners experience in simplifying addition and subtraction of algebraic fractions. Ethical clearance from the relevant school and university authorities were obtained. On the first two days, the researcher briefed the school authorities and learners and explained to them the purpose and details of the study. Day three was used to administer the pre-questionnaire test, thereafter, the next ten days were used to teach addition and subtraction of both numeric and algebraic fractions with same and different numerators and denominators. The next two days were used for revision and the last day was used to administer the postquestionnaire test out 25 marks. The respondent rate was 98.5%. The data collected were analysed by using SPSS version 16.10. Both descriptive and inferential statistics were used to analyse the data. The pre-questionnaire scores revealed that majority of the learners’ perceived fractions as two separate entities and as a result add or subtract numerator to numerator and denominator to denominator. It was also discovered that learners had a challenge in finding LCM of algebraic fractions. A t-Test for independent means was used to test the following hypotheses at 𝛼 = 0.05: 𝐇𝟎: The CSA approach and drill-practice intervention has no significant effect on Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions; 𝐇𝟏: The CSA approach and drill-practice will significantly enhance Grade 10 learners’ ability to simplify addition and subtraction of algebraic fractions. The t-Test revealed a p-value of 0.139 which was statistically significant at 𝛼 = 0.05. Therefore, the researcher rejected the null hypothesis and concluded that the CSA approach and drill-practice have significantly enhanced the Grade 10 learners’ ability to simplify algebraic fractions.
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- Date Issued: 2016
The effects of emotional intelligence on entrepreneurial intention of university students in the Eastern Cape Province
- Authors: Kanonuhwa, Michelle
- Date: 2016
- Subjects: Entrepreneurship -- Psychological aspects Emotional intelligence Businesspeople -- Psychology
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10353/8451 , vital:32833
- Description: Prompted by the various advantages presented by entrepreneurship, there has been an increase in studies investigating the factors that could influence entrepreneurial establishment and success. The purpose of this study was to determine whether emotional intelligence could stimulate entrepreneurial interest, thereby contributing to the literature on antecedents of entrepreneurship. This study tested the various socio-demographic characteristics of the sample and how each variable influenced entrepreneurial intent and emotional intelligence. A self-administered questionnaire was distributed to 385 students in the Eastern Cape Province using the purposive sampling method. Correlations, simple linear regression and multiple regressions were computed to test the hypotheses using the SPSS data analysis package. The findings of the study showed that there is a direct relationship between emotional intelligence and intention to become an entrepreneur. Furthermore, socio-demographic factors examined showed immense relevance to the development of entrepreneurial intent. As such the study suggested that apart from developing an effective entrepreneurship education program open to all individuals with a keen interest in the subject irrespective of academic merit; educators should create a learning environment that encourages effective expression and use of emotions to nurture the emotional intelligence of students. Moreover, mentorship relationships between students and local entrepreneurs should be highly encouraged.
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- Date Issued: 2016
The impact of human capital investment on economic growth : the case of South Africa
- Authors: Mutambirwa, Edward
- Date: 2016
- Subjects: Human capital -- South Africa Economic development -- South Africa
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10353/8272 , vital:32155
- Description: A country which prioritises in investing in human capital is believed to be a wealthy nation, meaning that the amount devoted to education and health sectors cannot be considered too much. The purpose of the study is to investigate the impact of human capital investment on economic growth, the case of South Africa. The study used time series data covering the period 1984-2014 to assess the impact of human capital investment on the economic growth of South Africa. The autoregressive distributed lag (ARDL) model and the error correction model (ECM) were employed in estimating the long run and short run relationship among variables of the study. The results of the study concluded that there is a positive long run relationship between total human capital investment (THCI) and South African economic growth. The results were in line with the hypothesis of the study and some empirical literature used. However, in the short run the results proved that there is no relationship between total human capital investment and economic growth in South Africa. Moreover, FDI and gross fixed capital formation proved to have a long run relationship with economic growth except exchange rate. The study recommends that the government should continue to devote most of its budget to human capital investment as it positively accelerates the economic growth of the country.
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- Date Issued: 2016
The impact of inflation on financial development in South Africa
- Authors: Muzvanya, Kudzai Fungai
- Date: 2016
- Subjects: Economic development Monetary policy Consumer price indexes
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10353/13045 , vital:39440
- Description: Growing theoretical and empirical studies have predicted different influences that inflation has on financial development in different economies. This dissertation observes the impact South Africa’s inflation has on financial development over the period between 1990 and 2012. Monetary policy framework in South Africa has, to a greater extent, assisted in monitoring the movement of the consumer price index. Although inflation does affect financial sector performance, the study also looked into other variables that have an effect like private credit, money supply and gross domestic product. To test for stationarity to avoid spurious regression, the ADF test and the PP test were used. To determine the long- and short-run relationship, the Johansen Maximum Likelihood test and VECM models were used. Results of the study indicated that money supply and inflation have a negative effect on financial development. In addition, apart from money supply and inflation the findings revealed that private credit and gross domestic product play a significant part in financial sector performance. The study recommends that the South African Reserve Bank should keep the inflation rate within its target range (3-6percent). This would ensure price stability and restore investor confidence in the financial sector, which then improves financial sector development.
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- Date Issued: 2016