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Isolation, characterisation of terpenoids and biosynthesis of silver nanoparticles of acacia mearnsii de wild and acacia Karroo Hayne and their Bioassays

  • Authors: Avoseh, Opeyemi Nudewhenu
  • Date: 2015
  • Language: English
  • Type: Thesis , Doctoral , PhD (Chemistry)
  • Identifier: vital:11355 , http://hdl.handle.net/10353/d1021292
  • Description: Great wealth of traditional knowledge about the use of plants had been transferred from generation to generations leading to the present day drug discovery and invention of new scientific methods of isolation, purification and identification. With the discovery of new diseases and drug-resistant organisms, there is no other source or deposit of lead compounds or drugs than the plant kingdom. As a result of this, about 25% of the current drug administered owe their origin to plant sources with the view to reduce the carcinogenic effect of synthetic drugs. Volatile terpenoids among other broad spectrum of natural product had been implicated to show high therapeutic properly. In the present study, selected locally-used medicinal plants were exploited for the presence of potent bioactive compounds and ability to form nanoparticles with distinctive property for use as chemoprotective agent against inflammation, tumors, cancer and other chronic diseases. Acacia mearnsii De Wild and Acacia karroo Hayne studied in this report are known to be invasive species with no proper regulation to conserve and preserve them. However, ethnopharmacology report of these plant species in the Southern Africa region reveals that they are good antiseptic, anti-diarrhea, anti-inflammation and a forage for livestock. These plants were subjected to volatile extraction protocol of some parts of the plants (stem and leaves) followed by examination of the anti-inflammation capacity of the extracts using an animal model. In addition, the bye-product (hydrosol) from the stem bark of each species possess a high reducing and stabilizing property leading to synthesis of silver nanoparticles, followed by investigation of the anti-inflammation potential of the synthesized silver nanoparticles using animal model. The volatile oils of the leaves and stem bark of Acacia mearnsii De Wild obtained by hydro-distillation were analyzed by Gas Chromatography-Mass Spectrometry (GC-MS). Twenty, Thirty-Eight, Twenty-nine and Thirty-Eight components accounting for 93.8%, 92.1%, 78.5% and 90.9% of the total oils of the fresh, dry leaves and fresh, dry stem bark respectively. The major components of the oil were octadecyl alcohol (25.5%) and phytol (10.5%); cis-verbenol (29.5%); phytol (10.1%) and phytol (23.4%) for the fresh leaves, dried leaves, and fresh stem, dry stem bark respectively. Oral administration of essential oils at the dose of 2% showed significant (p<0.05) anti-inflammatory properties in the albumin induced test model in rats. Oils from the fresh leaves and dry stems inhibited inflammation beyond 4 h post treatment. Furthermore, the chemical composition of the essential oils obtained by hydro-distillation from the leaves and stem bark (dry and fresh) of Acacia karroo Hayne, analysed by GC-MS, shows that hexanal (10.67%) and ß-ionone (9.74%) were dominant in the dried leaves, β-pinene (14.30%), and (Z)-2-Hexen-1-ol (10.21%) in the fresh leaves while Octacosane (10.59%) and phytol (23.38%) were dominant in the dry and fresh stem respectively. The anti-inflammation ability of these oils after an albumin-induced inflammation on wistar rats, shows a significant effect at the 1st h of treatment with a significance of P< 0.01 for all part plants, while the fresh leaves shows further inhibitory activities at the 2nd h of analysis. Silver nanoparticles (AgNPs) were successfully synthesized from AgNO3 through a green route using the aqueous extract (hydrosols) of Acacia mearnsii De Wild and Acacia karroo Hayne as reducing agent and as well as capping agent. The Acacia-mediated AgNPs were characterized with the use of UV-vis absorption spectroscopy, Fourier Transform Spectroscopy (FT-IR), Transmission electron microscope (TEM), Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDX), and X-ray Diffractometry (XRD). A spherical, 10-40 nm diameter silver nanoparticles were synthesized with very low level of stability for the AMDS and the AKDS-AgNPs. In addition, nociceptive activity with a mice rat reveals higher inhibition at the neurogenic phase for the AKDS-AgNPs, while AMDS-AgNPs exhibited a high inhibition at the inflammatory phase. The potent anti-inflammatory activity of essential oils of A. mearnsii De Wild and A. karroo Hayne hereby confirmed its traditional use in treating various inflammatory diseases, while the inflammatory studies on the synthesized AgNPs reveals a very active compound which can be used as a potent opioid or non-steroidal anti-inflammatory drug (NSAID).
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  • Date Issued: 2015

Survival of women in law enforcement

  • Authors: Badi, Yvonne Tankiso
  • Date: 2015
  • Subjects: Policewomen -- South Africa -- Eastern Cape , Women police chiefs -- South Africa -- Eastern Cape
  • Language: English
  • Type: Thesis , Masters , MBA
  • Identifier: vital:8860 , http://hdl.handle.net/10948/d1020179
  • Description: This study seeks to investigate the underlying ideologies and practices behind the perception that women who are in command positions are unable to command and control, especially those who are in the operational environment. The study was executed in the Eastern Cape Province (Eastern Cape), in Buffalo City Metropolitan Municipality (BCM). The research participants (respondents) were constituted by 33 police officers from diverse police stations within the BCM. The participants were divided according to gender, i.e. 24 females and 9 males. With regards to objectives of the study, the aim was to investigate the following issues: i) to understand factors that make women not to be accepted in their positions as SAPS' operational commanders, by their male subordinateslcolleagues and community members. ii) To understand factors that make women not to be accepted in their positions as SAPS' operational commanders, by their male subordinates/colleagues and community members, and iii) to explore strategies to utilize in making SAPS' women operational commanders, survive while managing their day-te-day respective units/components effectively and efficiently. Regarding research design, this study mainly used a qualitative research method combined with a bit of a quantitative approach. And then the data collection method involved making use of semi structured interviews to all the respondents. The results of this study show that there is still a huge difference in the number of women who are commanders compared to their male counterparts, especially in those environments that were previously regarded as male dominated. Further, despite the necessary training being provided by the SAPS to women officers, the necessary support in particular from management is still a challenge. Lastly, the argument of this study is that there is still not a fair representation of women in command positions within the SAPS, especially, in the previously male dominated environments.
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  • Date Issued: 2015

Regolith mapping and gold geochemical anomalies in the Siguiri Gold Mine of AngloGold Ashanti, Guinea, West Africa

  • Authors: Bah, Boubacar
  • Date: 2015
  • Subjects: AngloGold Ashanti Ltd. , Regolith -- Guinea -- Siguiri (Region) , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Soil surveys -- Geochemical methods -- Guinea -- Siguiri (Region) , Kriging
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5090 , http://hdl.handle.net/10962/d1019878
  • Description: Gold exploration in the laterite terrains of the Siguiri basin (Guinea-West Africa) is discussed in this thesis. It seeks to propose and develop effective and reliable geochemical exploration techniques applied in such laterite terrains. The study is also intended to investigate and provide some geological clues as to why, in some target areas, the reconnaissance test drilling across the geochemical anomalies couldn’t intersect economic gold mineralisation. Targets were generated based on soil geochemical results, some of which were drilled without delivering economic discoveries even on areas with strong and consistent geochemical signatures. To find the failure and define the appropriate methods to be used is the core of the thesis. More importantly, the geological observation is aimed at sourcing and establishing the nature and validity of geochemical anomalies within the license area and their relationship with the underlying lithologies and structural networks. The geological field work conducted during this study is mostly based on regolith and surface geological mapping. The thick laterite cover, deep weathering, bedrock geology, gold geochemistry (the gold geochemical anomalous results are defined according to historical data before 2007), soil formations and variations in climate conditions are emphasized to illustrate the importance of mineral element mobility and dispersion in the weathering profiles. The knowledge and experience in regolith geochemistry and regolith mapping provide the advantage to exploration geologists. The depletion of ore resources and reserves in Siguiri and the continuous decline of the gold price in comparison to the complexity of exploring for gold are demanding more scientific-related thoughts and techniques to be integrated in the available geological, geochemical and geophysical information so as to reduce costs. The integration of good exploration strategy and technique may result in the possibility of making viable discoveries in this highly competitive geological environment where the mineral resources become depleted every day.
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  • Date Issued: 2015

Geological and geophysical investigation of the South Eastern Karoo Basin, South Africa

  • Authors: Baiyegunhi, Christopher
  • Date: 2015
  • Language: English
  • Type: Thesis , Masters , MSc (Geology)
  • Identifier: vital:11532 , http://hdl.handle.net/10353/d1021280
  • Description: Geological and geophysical methods were used to investigate the southeastern Karoo Basin of South Africa in an area extending from longitudes 24 o E to 29o E and latitudes 32o S to 35o S. This was undertaken in order to reveal geologic structures, isochore thicknesses of the geologic sequence and their variations across the study area, proffer the possible provenance of the sediments and assess the potential of oil and gas accumulation. The methodology used includes field investigation, rock sampling, preparation of thin sections, petrographic studies, X-ray diffraction analysis, density measurements, porosity calculations, extraction of elevation data from Google Earth, 2½ D gravity profile modelling, generating of isochore (true vertical) thicknesses and depositional surfaces maps from the models, PetroMod 1D modelling and qualitative interpretation of magnetic, gravity and radiometric maps.Petrographic study was carried out on twenty six thin sections of rocks from the eleven geologic formations that cover the study area. Petrographic studies on the diamictite of the Dwyka Group shows abundance of monocrystalline quartz, granite and quartzite components in the breccias which possibly indicate the existence of granitic and metamorphic rocks in the source areas. The sandstones of the Ecca and Beaufort Groups are immature, greywacke and the heavy mineral assemblages signify that the minerals are of granitic, volcanic and metamorphic origin. The magnetic maps show two main magnetic anomalies, a major one trending in a northeast to southwest direction which is part of the Beattie magnetic anomaly and another that is a “bean-shaped” anomaly. The radially averaged power spectrum shows two depths to magnetic sources. The first depth is about 0.6 km which is the average depth to the top of the shallow sources, while the average depth to the top of the deep sources is about 15 km. The shallow sources are connected to magnetic minerals within the Beaufort Group while deep magnetic sources were inferred to be in the basement. The gamma ray spectrometric map shows areas with relatively high gamma radiation count. The high radiation count is possibly due to the uranium and thorium in the detrital materials, as well as the enrichment of radioelements in the feldspars (k-feldspar), calcite, quartz, zircon and clay minerals in the fluvial channel sandstones of the Beaufort Group. A total of two hundred and fifty-eight (258) rock samples were collected in the field and densities (dry, wet and grain densities) and porosities were determined in the laboratory. The Karoo Supergroup density values range from 2.526 – 2.828 g/cm3. The average porosities range from 0. 49 – 3.31 %. The dry densities and porosities of all the formations are inversely correlated with correlation coefficient values (R) that range from 0.9491 - 0.9982. The density of the dolerite intrusions (mostly sill) ranges from 2.700 – 2.837 g/cm3 whilst the porosity range from 0.1118 – 0.3868 %. The Bouguer anomaly map shows an increase in gravity values from -140.7 mGal in inland to about 60.1 mGal in coastal areas. This dominant gravity variation is inferred to be due to a deeper basement and/or Moho that get shallower from inland towards the coast. The Moho is at about 45 km depth inland and shallows to about 42 km at the coast. The 2½ D gravity modelling was done for fourteen (14) profiles with each profile having three (3) models corresponding to minimum, average and maximum densities to obtain the thicknesses of the geologic sequence. The current isochore thicknesses extracted from the gravity models show that the Beaufort Group is the thickest of all the groups that make up the Karoo Supergroup with maximum vertical thickness of up to 634 m, followed by the Ecca and Dwyka Groups with maximum vertical thicknesses of about 3207 m and 727 m, respectively. The maximum elevation for the Dwyka, Ecca and Beaufort sediments are about 500 m, 400 m and 285 m, respectively, whilst the maximum depth below sea level are around 8500 m, 7000 m and 5500 m, respectively. The PetroMod1D model result yield average vitrinite reflectance and temperature values of about 6 % and 500 ℃ respectively for the lower Ecca Group which belong to the dry gas window based on classification by several authors. Thus the rocks of the lower Ecca Group are thermally matured for hydrocarbon (shale gas) generation that can merit gas exploration in the Karoo Basin.
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  • Date Issued: 2015

Beneficiary perceptions of a low income housing scheme: Mdantsane township

  • Authors: Bandile, Unathi Cordelia
  • Date: 2015
  • Subjects: Low-income housing -- South Africa -- Eastern Cape , Public housing -- South Africa -- Eastern Cape , Housing development -- South Africa
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: vital:9719 , http://hdl.handle.net/10948/d1021137
  • Description: The aim of this study was to investigate the socio-economic perceptions of the beneficiaries of the low income housing scheme in Unit P, of Mdantsane Township, under Buffalo City Metropolitan Municipality. Both quantitative and qualitative approaches were utilised in this study. For instance, questionnaires on the perceptions were administered amongst twenty (20) beneficiaries of this low housing scheme. Semi structured interviews were conducted amongst five (5) respondents who participated in the survey design. The study found that the intervention of providing poor people with houses was not appropriately done as these houses are too small and therefore fail to consider the families of the beneficiaries although the South African government seems to have succeeded to some extent in providing low income housing for the unemployed and those that belong to the low income category. The study also found that the location of Unit P poses a threat because it is located away from all the amenities compelling the beneficiaries to travel more than 5km to the amenities and essential services. The study therefore recommends that the government employs competent contractors that would do a proper job. State officials, tasked with overseeing the various state funded housing projects, have to ascertain the success of these projects by making sure that the contractors do not lack skills such as the ability to facilitate projects of a high magnitude as that could lead to flawed projects. They should be constantly monitored and post evaluated. This will help to minimize the wasting of state resources.
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  • Date Issued: 2015

Determinants of internet banking adoption by banks in Ghana

  • Authors: Bart-Williams, Edem
  • Date: 2015
  • Subjects: Internet banking -- Ghana , Banks and banking -- Ghana , Banks and banking -- Automation
  • Language: English
  • Type: Thesis , Doctoral , DPhil
  • Identifier: http://hdl.handle.net/10948/3715 , vital:20457
  • Description: Growth in information and communication technology (ICT) is drastically changing the way businesses, especially in the service industries, are conducted. The financial services industry and banking in particular, is not excluded from this technology explosion. Internet banking, even though not new in advanced countries, is a new transaction channel being used by banks in some parts of Africa, especially Ghana, to offer various products and services to their customers. However, this medium has not been fully exploited by these banks as there are many hurdles the banks must triumph over. In deploying this technology and these systems, there are several factors which banks must take into consideration before fully deploying such a system to their customers, hence the motivation for this study. The absence of suitable and sufficient knowledge on this topic also exposes a “rhetoric versus reality” argument of whether the intention to adopt Internet banking is critical to the strategies and ultimate success of banks in Ghana. For banks to stay ahead of competition as well as to attract and maintain their clientele, it is of paramount importance to gather and link the perspectives of both clients and bank managers in order for banks to ensure that they perform according to the needs and expectations of their clients. In order to achieve the intended results, an empirical study was conducted by taking into consideration the viewpoints of both bank clients and bank managers in determining the factors that customers take into consideration before adopting the Internet banking medium. The primary aim of this study was to quantify significant relationships between the selected variables. Therefore the positivism research paradigm was used, while the phenomenological paradigm was employed for the measuring instruments. Because multiple sources of data were used, from the perspectives of banking clients and managers in Ghana, methodological triangulation was adopted for this study. The results of the empirical investigation showed that both groups (clients and managers) considered the variables of market share, technology acceptance, diffusion of innovation, organisational variables, organisational efficiency, and business strategy to have direct influence on the adoption of Internet banking. However, they differed in opinion concerning the degree of influence of these variables. The bank managers’ responses leaned more towards strong agreement with the importance of these variables than did those of the bank clients. Thus, for bank clients to readily adopt the Internet banking medium for their banking transactions, bank managers must take a closer look at these determinant factors described in the study. The study showed that the population group, educational and income levels exerted an influence on the perceptions clients have regarding Internet banking adoption factors. It was found that the higher the education and income levels of the clients, the easier it was for them to adopt Internet banking. Also, the male group dominated the use of the Internet banking. This is supported by the fact that there is a growing middle class in Ghana that falls within this category of banking clients.
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  • Date Issued: 2015

Sustainable training support framework for the wind power industry in South Africa

  • Authors: Barton, Cayleigh Ann
  • Date: 2015
  • Subjects: Wind power industry -- South Africa Wind power industry -- Technological innovations , Energy development Renewable energy sources
  • Language: English
  • Type: Thesis , Masters , MBA
  • Identifier: http://hdl.handle.net/10948/50020 , vital:41985
  • Description: South Africa has emerged as one of the most important renewable energy markets as reflected by the USD 5.5 billion invested in South Africa in 2014 (Merger’s Alliance, 2015). As the opportunity exists for South Africa to take advantage of its above average natural wind resources, the main purpose of the case study research effort was therefore to develop a theoretical sustainable training framework in support of the rapidly growing wind power industry in South Africa. The proposed location for a sustainable training support framework is at the NMMU Business School and Leadership Academy, strategically located in the Eastern Cape. In addition, the NMMU Business School and Leadership Academy has satellite offices all around South Africa, thus creating accessible training and education solutions to most parts of the country. The case study research approach was qualitative in nature, thus providing valuable insight into the case study phenomenon. The researcher focused on a single context, namely the wind power industry in South Africa, and within a single case of the establishment of a sustainable training support framework at the NMMU Business School and Leadership Academy. The embedded, multiple units of analysis comprised of a purposive sample of strategic individuals operating within the South African wind power sector, socio-economic development, education and training industries. In staying within the research design, the case study made use of an in-depth interview process in order to address the research propositions of the case study. The investigative interview questions were fully supported by secondary sources of information. The case study provided valuable insight into the unique South African wind power industry setting, with a focus on education and training in line with the REIPPPP minimum threshold and targets for socio-economic development and job creation. The researcher experienced a lack of responses from industry experts who were contacted for interviews. This lack of response could be considered as a limitation in validating the outcome of the study. The South African wind power industry is one of the most thriving markets in the world (Merger’s Alliance, 2015) and due to its fledging nature; research on the topic under discussion is not readily available. Thus, the research effort provided relevant information regarding the unique setting of the South African wind power industry and added value through the proposition of a sustainable training support framework strategically located at the NMMU Business School.
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  • Date Issued: 2015

An ergonomics intervention study into the physiological, perceptual and productivity effects of three citrus harvesting bag designs in the Eastern Cape of South Africa : a combined laboratory and field approach

  • Authors: Bassey-Duke, Elizabeth Misan
  • Date: 2015
  • Subjects: Citrus -- Harvesting -- South Africa -- Eastern Cape , Lifting and carrying -- South Africa -- Eastern Cape , Manual work -- South Africa -- Eastern Cape , Blue collar workers -- South Africa -- Eastern Cape , Work -- Physiological aspects , Human mechanics
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5176 , http://hdl.handle.net/10962/d1018908
  • Description: Background: Agriculture plays a vital role in the economy of any industrially developing country, including South Africa. In the Eastern Cape of South Africa citrus farming is a significant contributor to the local economy (Johnson et al., 2005). The harvesting phase of citrus farming is performed manually and exposes workers to physical risks, which can lead to the development of musculoskeletal disorders. In particular, the standard harvesting bag comprises of a single shoulder strap and promotes asymmetrical load carriage which results in shoulder and lower back pain complaints. The current study compared the physiological (EMG), perceptual (RPE), usability (PUEU) and productivity effects of two new harvesting bag designs (a hip belt and a backpack bag design) to the standard harvesting bag design. This was performed in a laboratory as well as a field setting. Methods (Laboratory phase): 36 participants (12 males and 24 females) were assigned to one worker group. The “tall ladder worker” group was comprised of only males and the “step ladder worker” and “ground worker” group of females. Each participant was required to simulate a citrus harvesting task while utilizing each of the bag designs on different days. On each day/test session, participants performed three harvesting cycles. Muscle activity was measured throughout the entire testing session and RPE were recorded at the end of each cycle. Results (Laboratory phase): The EMG and RPE results indicate that the backpack design was the most ideal design to reduce asymmetry, while the standard harvesting bag design was the worst. Although not significant, there was greater muscle asymmetry (p=0.109) and a significantly higher perceived exertion when using the standard bag (p=0.0004), in comparison to using the backpack. Methods (Field phase): 17 Xhosa-speaking citrus harvesters (6 females and 11 males) participated in this study. Each harvester worked with one of the three bag designs on a different day. Productivity of each worker was assessed every hour by recording the number of bags filled with fruit and at the end of the shift. A Perceived Usefulness & Ease of Use questionnaire was presented to each participant to obtain feedback on worker acceptance to the new bag designs. Results (Field phase): A general trend in support of the hip belt bag design over the other two bag designs were found, even within the different worker demographic groups (age, sex and worker experience). The workers perceived less exertion (7.98 ± 1.86) and were more productive (9.90 ± 2.11 bags/hour) when using the hip belt design; they also found this bag the most useful (1.02 ± 0.09) and easy to use (1.07 ± 0.25). In contrast, the backpack bag design had significantly poorer responses when compared to the other two bag designs and this was evident in all the dependent variables assessed (RPE, productivity and PUEU). Conclusion: The results from the laboratory phase supported the expectation that the backpack bag design reduces asymmetry and hence, is more suitable than the standard harvesting bag. However, results from the field show that the hip belt bag design was the most preferred and the backpack was the least preferred. Bao & Shahnavaz (1989) highlight the need for ergonomics researcher to convey laboratory findings into the field context. However, as shown by the current study, there are numerous challenges associated with field work, making it difficult for laboratory findings to be successfully conveyed to the field. Limitations and Recommendations: For the laboratory phase of the project, no biomechanical and cardiovascular responses were assessed. However, for a holistic approach, these variables should be considered in future studies. Due to high variability from one harvesting cycle to another, more than three harvesting cycles should also be performed to accurately replicate the harvesting process as done in the field over extended durations of time. For the field phase, data should be collected from more than one citrus farm and thus a larger sample size could be obtained. This would improve the validity of the study. In addition to this, data should be collected for a full working day, especially if environmental conditions are not a hindrance, as well as for a whole season, since workloads vary, depending on the time of the harvesting season. , Name on Graduation Programme: Bassey-Duke, Elizabeth Missan
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  • Date Issued: 2015

The cognitive rehabilitation of a sample of children living with HIV : a specific focus on the cognitive rehabilitation of sustained attention

  • Authors: Basterfield, Candice
  • Date: 2015
  • Subjects: HIV-positive children -- Rehabilitation , Antiretroviral agents , HIV (Viruses) -- Side effects , Brain damage -- Patients -- Rehabilitation , Cognition disorders -- Patients -- Rehabilitation
  • Language: English
  • Type: Thesis , Masters , MSocSc
  • Identifier: vital:3258 , http://hdl.handle.net/10962/d1017881
  • Description: Pharmacological interventions to treat Human Immunodeficiency Virus (HIV) with antiretrovirals (ARVs), have dramatically improved the survival rates of HIV positive children maturing into adulthood. However, HIV-associated neurocognitive decline still persists in the era of ARVs. Within the framework of brain plasticity, a number of researchers have begun to assess the feasibility of cognitive rehabilitation therapy as a complement to ARVs to reverse neurocognitive decline as a result of HIV (e.g., Becker et al., 2012). Only one study has been conducted in South Africa, by Zondo & Mulder (2014), assessing the efficacy of cognitive rehabilitation in a paediatric sample. The current research builds on the above mentioned study by implementing an experimental approach to examine the effect of cognitive rehabilitation in a sample of both HIV positive and HIV negative children. Five HIV positive and six HIV negative children were assigned to either an experimental or control group. The experimental group underwent two months of cognitive rehabilitation therapy remediating sustained attention, whereas the control group took part in placebo activities. Sustained attention measures were taken before and after the intervention training sessions, using a sustained attention subtest from the Test of Everyday Attention for Children (TEA-CH). A Mann Whitney U Test revealed that the experimental group (Mdn=38.50) did not differ significantly from the control group (Mdn = 37.00) after the cognitive rehabilitation intervention, U=12.00, z= -.55, p= .66, r= -.17. But a Wilcoxon Signed Rank Test found that there was a significant improvement from pretest scores (Mdn=31.00) to posttest scores (Mdn=38.00) following the rehabilitation for HIV positive participants in the sample, T=15.00, z = -2.02, p= .04, r= -.90. This raises the possibility that cognitive rehabilitation could be used as a low cost intervention in underdeveloped contexts
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  • Date Issued: 2015

Case study : profitability drivers in the South African airline industry : a comparative analysis of SAA and Comair

Short-term changes to the life history of shad, Pomatomus saltatrix (Perciformes: Pomatomidae), in Southern Angola

  • Authors: Bealey, Roy Steven John
  • Date: 2015
  • Subjects: Shad -- Angola , Bluefish -- Angola , Bluefish -- Climatic factors -- Angola , Bluefish -- Effect of temperature on -- Angola , Bluefish -- Effect of global warming on -- Angola , Bluefish -- Effect of fishing on -- Angola , Bluefish -- Life cycles , Pomatomidae -- Angola , Fishery management -- Angola , Climatic changes -- Angola
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5379 , http://hdl.handle.net/10962/d1017211
  • Description: A general lack of biological information is hampering the effective management of Angola’s fisheries. While this lack of information is largely a result of the country’s extended civil war that ended in 2002, the subsequent rapid expansion of fisheries is most likely impacting fish abundance and influencing the biology of this regions fishes. Besides the influence of fisheries, the southern Angolan coastal region is considered to be a climate change “hotspot” due to rapidly (>0.8°C/decade) increasing water temperatures. These changes are thought to drive further changes to the biology of fishes. It is therefore critical to provide baseline biological information and to identify the impacts of exploitation and warming on the biology of southern Angolan fishes. Pomatomus saltatrix is a warm-temperate marine fish species that forms an important component of fisheries throughout its broad distribution. P. saltatrix is a migratory predator that displays variable growth and maturity schedules. Typically it is heavily targeted in a range of coastal fisheries of Angola and is therefore an ideal candidate to study the biological impacts of exploitation and climate change. The aim of this study was to provide the first description of P. saltatrix biology in Angola and examine recent changes of the species biological parameters in an attempt to uncouple fishery driven from climate driven changes. Samples of P. saltatrix were collected monthly using standardised biological methods from June 2005 to December 2006 (period 1) and from June 2012 to February 2013 (period 2). The average (508mm – 1st period, 462mm – 2nd period) and maximum (760mm – 1st period, 746mm – 2nd period) size of P. saltatrix was smaller during the second period to suggest selective overharvesting of large individuals by developing fisheries. Angolan P. saltatrix grew very rapidly in their first year and thereafter, relatively slowly when compared to other populations globally. However, fish grew faster (ω = 103 – 1st period, ω = 124 – 2nd period), matured at a larger size (303mm - 1st period, 336mm - 2nd period) and younger age (0.83 years - 1st period, 0.67 years – 2nd period) during the second period. Peaks in reproductive activity remained similar (November) during both periods but a temperature anomaly appears to have influenced spawning during period 2. Sardinella aurita was the dominant prey during both periods but a greater dependence upon mugilids was observed during the second period. Although the changes in life history were not statistically significant, the faster growth observed during period two could be attributed to both increasing temperature and/or exploitation. Fishes generally grow faster, mature smaller and attain a smaller maximum size in warmer temperatures. Fisheries targeting small and large specimens of a species (as observed in this study) largely have the same impacts as ocean warming. With rapidly increasing water temperatures and exploitation rates, faster growth and earlier maturation of P. saltatrix populations will mitigate the impacts of exploitation in the short-term. However, the sustainability of Angola’s P. saltatrix stock is questionable as phenotypic adaptation will have a limited thermal scope and overexploitation will, like in all fisheries, negatively influence recruitment. Ultimately, strict monitoring, regulation and control will be necessary to ensure the sustainability of the P. saltatrix resource in Angola as it continues to face increasing anthropogenic and environmental pressures. Management guidelines and future research suggestions are therefore outlined with reference to the results of analyses conducted during this study.
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  • Date Issued: 2015

Appraising the appraisal framework: evidence from Grahamstown property advertisements

  • Authors: Beangstrom, Tracy
  • Date: 2015
  • Language: English
  • Type: text , Thesis , Masters , MA
  • Identifier: http://hdl.handle.net/10962/54744 , vital:26608
  • Description: This thesis considers how interpersonal meaning choices in property advertisements are best reflected in a context of constraint in Grahamstown, South Africa, using and appraising Martin & White’s (2005) APPRAISAL Framework. The study is comparative in two senses since the data is analysed using Martin & White’s (2005) APPRAISAL Framework and a revision to it, and property advertisements from two competing estate agencies are analysed: Remax Frontier Properties and Pam Golding Properties. An initial strict application of Martin & White’s (2005) framework is followed by a second, based on analyst difficulties and framework limitations experienced in the first analysis, as well as those experienced by other researchers. Revisions to the original framework include added ‘local’, context-driven features and sub-categories: Exclusivity and Convenience in Attitude, a Scale of Intensity in Graduation, and a category ‘Invite’ in Engagement. These enable a richer, more detailed account of the alignment strategies and interpersonal micro-politics at play in the property advertisements than is possible using the original framework. Findings from the analyses reveal four facts of note. Firstly, that while the original Martin & White (2005) APPRAISAL Framework captures a general level of interpersonal meaning in the data, it does so more fully when it includes contextual and contextually-driven categories that are informed by local knowledge. Secondly, two levels of meaning are expressed in the data. One is aimed at an ‘external’ audience; the other, truer, fuller and more contentious, is aimed at what appears to be the intended audience only. Thirdly, and relatedly, specific contextual and cultural knowledge is needed by the intended audience to access the intended meaning. Fourthly, both estate agencies promote values of high prestige, exclusivity, elitism and wealth as their intended meaning to align a like-minded audience, although Remax Frontier Properties attribute these values to location and features of the home to a greater extent than Pam Golding Properties, who place greater emphasis on the size of the home. The thesis suggests further avenues for research into the discourse of property advertising, as well as into overcoming certain context-specific limitations of the APPRAISAL Framework.
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  • Date Issued: 2015

Structural controls of gold mineralisation in Seguelen pit of Siguiri gold mine, Guinea

  • Authors: Beavogui, Massa
  • Date: 2015
  • Subjects: AngloGold Ashanti Ltd. , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Geology, Structural -- Guinea -- Siguiri (Region) , Faults (Geology) -- Guinea -- Siguiri (Region) , Folds (Geology) -- Guinea -- Siguiri (Region) , Turbidites -- Guinea -- Siguiri (Region) , Metamorphism (Geology) -- Guinea -- Siguiri (Region) , Hydrothermal alteration -- Guinea -- Siguiri (Region)
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5091 , http://hdl.handle.net/10962/d1019879
  • Description: The present study provides the results of detailed mapping and analysis of structures encountered in Seguelen pit of Siguiri gold mine, Guinea, where the Siguiri mine is geo-tectonically located in the Baoulé-Mossi domain of Man Shield in West African craton. The gold deposit is hosted in low-grade metamorphic sediments of turbidites sequences which form part of the Lower Proterozoic of Birimian Super group. Three rock formations of Balato, Fatoya and Kintinian underlay the overall pits. The Siguiri gold mine is characterized by the deep weathering profile, developed over the rocks reaching 200 m below the surface in some areas and often capped by the lateritic gravel or duricrust. The rock formations at Seguelen area are characterised by strong bedding monotonously dipping towards SW and trending NW-SE. The lithology of the host rocks has strong control on the disseminated mineralisation throughout the deposit. Two domains of rock formations are clearly distinguished at Seguelen:  Fatoya Formation(Ffm) domain ; and  Kintinian Formation (Kfm) domain. The two domains are separated by a contact zone of 1.7 m wide parallel to bedding and characterised by the presence of quartz fragments as well as thinly sheeted shale and black shale. This contact zone is identified as disconformity. The major tectonic deformation which has affected the region is known as D2 corresponding to the Eburnean orogeny. The major D2 related structures is the regional thrust striking N-S over an area of 12 km long and 3 km wide and within which corridors all Siguiri gold Mine open pits are located. In the N-S trending structures, there is east-northeast shortening and north-northwest extension. There is pervasive hydrothermal alteration (carbonatization and sideritization) and supergene alteration in the all pits. The hydrothermal alteration attests the intensity of hydrothermal fluid-flow over the host rocks. The hydrothermal fluids flowed along the fractures and within the wall rocks through bedding plans to form numerous auriferous quartz veins bearing disseminated sulphides through chemical reaction between fluids and wall rocks, which are remarkable at Seguelen pit. Three quartz vein sets are distinguished at Seguelen:  NNE-SSW quartz vein set  NE-SW quartz vein set  NW-SE quartz vein set The NE-SW and NNE-SSW quartz veins are often lenticular and associated with the bulk mineralisation.
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  • Date Issued: 2015

Music education in the foundation phase

  • Authors: Beer, Luzaan
  • Date: 2015
  • Subjects: Music -- Instruction and study -- South Africa , Education -- Curricula -- South Africa
  • Language: English
  • Type: Thesis , Masters , MMus
  • Identifier: vital:8525 , http://hdl.handle.net/10948/d1020302
  • Description: Music education is an essential aspect of education. The South African school curriculum for the Creative Arts combines dance, drama, music and the visual arts. The curriculum uses a combination of the theories of Carl Orff, Emile Jaques-Dalcroze and Zoltán Kodály. Each of these music theorists and educationists have their own distinctive approach to teaching music. This study explores the theories of music education of Carl Orff, Emile Jaques-Dalcroze and Zoltán Kodály. These theories are applied in a critical analysis of both the South African curriculum and the curriculum of New South Wales. The researcher developed music activities to address the shortcomings of both the South African curriculum and the music texts.
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  • Date Issued: 2015

Conditions enabling or constraining the exercise of agency among new academics in higher education, conducive to the social inclusion of students

  • Authors: Behari-Leak, Kasturi
  • Date: 2015
  • Subjects: Social integration -- South Africa , Students -- South Africa -- Social conditions , Educational change -- South Africa , College teachers -- South Africa , Education, Higher -- South Africa , Critical realism , Social realism , Agent (Philosophy)
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:1333 , http://hdl.handle.net/10962/d1020295
  • Description: This study, which is part of a National Research Foundation project on Social Inclusion in Higher Education (HE), focuses on the exercise of agency among new academics, conducive to the social inclusion of students. Transitioning from varied entry points into higher education, new academics face numerous challenges as they embed themselves in disciplinary and institutional contexts. Given the complexity and contested nature of the current higher education landscape, new academics are especially vulnerable. Using Roy Bhaskar’s critical realism as meta-theoretical framing and Margaret Archer’s social realist theory, with its methodological focus on analytical dualism and morphogenesis, this study offers a social realist account of how new academics engage with enabling and constraining conditions at institutional, faculty, departmental and classroom levels. Through an analysis of six individual narratives of mediation, this study explicates and exemplifies the range of agential choices exercised by new academics to mediate their contested spaces. A nuanced social and critical account of the material, ideational and agential conditions in HE shows that the courses of action taken by these new academics are driven through their concerns, commitments and projects in higher education. Yet, despite the university’s espousal of embracing change, the current induction and transition of new academics is inadequate to the task of transformation in higher education. Systemic conditions in HE, conducive to critical agency and social justice, are not enabling. Bhaskar’s Seven Scalar Being, used as an analytical frame and heuristic, guides the cross-case analysis of the six narratives across seven levels of ontology. The findings highlight that, despite difficult contextual influences, the positive exercise of agency is a marked feature of new participants in HE in this study. This has immediate implications for ways in which professional and academic development, and disciplinary and departmental programmes, could create and sustain conducive conditions for the professionalisation of new academics through more sensitised practices. Using alternative research methods such as photovoice to generate its data, this doctoral study proposes that new research methodologies, located in the third space, are needed now more than ever in HE sociological research, to recognise the researcher and the research participants as independent, autonomous and causally efficacious beings. To this end, this study includes a Chapter Zero, which captures the narrative of the doctoral scholar as researcher, who, shaped and influenced by established doctoral practices and traditions in the field, exercises her own doctoral agency in particular ways.
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  • Date Issued: 2015

An indirectly controlled high-speed servo valve using piezo actuators

  • Authors: Behre, Leander
  • Date: 2015
  • Subjects: Piezoelectric materials Piezoelectric devices -- Materials , Internal combustion engines Mechatronics Automation
  • Language: English
  • Type: Thesis , Masters , MEng
  • Identifier: http://hdl.handle.net/10948/50099 , vital:42040
  • Description: Since the exhaust emissions legislation for motor vehicles with combustion engines is complicating the manufacturing of environmental yet powerful engines more than ever, automobile manufacturers have approached this challenge by means of downsizing, hybridization of combustion and electric engines and variable valve opening times. In these cases conventional, mechanical valve trains are still used. The subject of this master thesis is the development of a mechatronic control unit as replacement for the camshaft driven valve train of common combustion engines. The system’s aim is a contribution to the progression of the development of modern combustion engines satisfying current demands in terms of economy and efficiency. The developed system is based on the “Full Variable Valve Train” project, founded at the “Institute of Vehicle Construction Wolfsburg” at the “Ostfalia University of Applied Sciences”. An indirectly controlled high speed servo valve that is actuated by a piezoelectric actuator and pressurized hydraulic fluid is being developed. The overall aim is to obtain advantages from a control engineering perspective, being able to reduce the size of the used piezo actuator and hence solve the packaging and regulation issues of the overall system. After manufacturing and improvement activities, a system could be developed that allows a variable control of the engine valve movement. The best results are achieved using a rectangular function for the engine valve actuator. The system allows engine valve operation independent from the crankshaft position and shows the potential to generate higher engine torque and power output while decreasing fuel consumption and emissions at the same time.
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  • Date Issued: 2015

The antifungal activity of an aqueous Tulbaghia violacea plant extract against Aspergillus flavus

  • Authors: Belewa, Xoliswa Vuyokazi
  • Date: 2015
  • Subjects: Medicinal plants , Antifungal agents , Fungi -- Biotechnology
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: http://hdl.handle.net/10948/5858 , vital:21001
  • Description: Phytochemical analysis of both HEA1 and the crude plant extract showed the presence of phenolics, tannins and saponins. Saponins were the predominant secondary metabolites and were mostly abundant in the plant extract and to a lesser extent in the active compound. Steroidal saponins, tannins and phenolics were also detected in the plant extract, but only the phenolics were detected in the active compound. The results of the phytochemical analysis showed that those compounds that were not present in the active compound could be removed from the crude extract during the TLC purification process. Investigation on the mechanism of action of the crude plant extract on the sterol production by A. flavus showed that the plant extract affected ergosterol biosynthesis by causing an accumulation of oxidosqualene in the ergosterol biosynthetic pathway resulting in a decline in ergosterol production. An oscillatory response in lanosterol production was observed in the presence of the plant extract, which may be an adaptation mechanism of A. flavus to unfavourable conditions and compensation for the loss of enzyme activity which may have occurred as a result of the accumulation of oxidosqualene. The antifungal activity of the plant extract on ergosterol production by A. flavus may also be due to saponins which target the cell membrane and ergosterol production in fungi. The effect of the plant extract on the fungal cell wall of A. flavus also showed that the plant extract caused a decline in β-(1, 3) glucan production by inhibiting β-glucan synthase. The plant extract also affected the chitin synthesis pathway of A. flavus, by causing a decline in chitin production, which was due to the inhibition of chitin synthase. Investigation of chitinase production using 4MU substrates showed that the plant extract caused an accumulation of chitobioses, by activating chitobiosidases and endochitinases. A decline in N-acetylglucosaminidase activity in the presence of the plant extract was observed and this prevented the formation of N-acetylglucosamine. The accumulation of chitobiosidase and endochitinase may be as a result of autolysis that may be triggered by A. flavus as a survival mechanism in the presence of the plant extract and as a compensatory mechanism for the loss of β-glucans and chitin. The antifungal effect of the plant extract on various components of the cell wall of A. flavus, makes T. violacea aqueous plant extract an ideal chemotherapeutic agent against both human and plant pathogens of Aspergillus. The broad spectrum of antifungal activity of T. violacea against A. flavus also eliminates any chances of the fungus developing resistance towards it and would make it a candidate for use as a potential antifungal agent. Further identification and possible chemical synthesis is needed to shed light on the safety and efficacy of the active compound for further development as a chemotherapeutic agent.
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  • Date Issued: 2015

Articulating the nature of clinical nurse specialist practice

  • Authors: Bell, Janet Deanne
  • Date: 2015
  • Subjects: Nurse practitioners , Intensive care nursing
  • Language: English
  • Type: Thesis , Doctoral , DPhil
  • Identifier: vital:10057 , http://hdl.handle.net/10948/d1018623
  • Description: Critical care nursing is a clinical specialist nursing practice discipline. The critical care nurse provides a constant presence in the care of a critically ill patient. She/he creates a thread of continuity in care through the myriad of other health care professionals and activities that form part of a patient’s stay in the critical care environment (World Federation of Critical Care Nurses [WFCCN], 2007). During conversations with people who have had intimate experience of the critical care environment, they have offered anecdotes that describe their interaction with critical care nurses who they perceive to be different from and better than other critical care nurses they encountered. Despite having met common professional requirements to be registered as a clinical specialist nurse, these distinctive, unique abilities that seem to be influential in meeting the complex needs and expectations of critically ill patients, their significant others as well as nursing and medical colleagues, are not displayed by all critical care nurses. While students of accredited postgraduate nursing programmes are required to advance their nursing knowledge and skill competence, many students do not seem to develop other, perhaps more tacit, qualities that utilisers characterise in their anecdotes of ‘different and better’ nursing practice. The overarching research question guiding this study was how can ‘different and better’ critical care nursing practice as recognised by a utiliser be explained? The purpose of this study was to develop an understanding of the qualities that those people who use critical care nursing practice recognise as ‘different and better’ to the norm of nursing practice they encounter in this discipline. The participant sample included patients’ significant others, nursing colleagues and medical colleagues of critical care nurses, collectively identified as utilisers. The stated aim of this work was to construct a grounded theory to elucidate an understanding of the qualities that a utiliser of critical care nursing recognises as ‘different and better’ critical care nursing practice in order to enhance the teaching and learning encounters between nurse educators and postgraduate students in learning programmes aiming to develop clinical specialist nurses. The method processes of grounded theory are designed to reveal and confirm concepts from within the data as well as the connections between these concepts, supporting the researcher in crafting a substantive theory that is definitively grounded in the participants’ views and stories (Streubert & Carpenter, 2011: 123, 128-129). Two data collection tools were employed in this study, namely in-depth unstructured individual interviews and naïve sketch. Constant comparative analysis, memo-writing, theoretical sampling, theoretical sensitivity and theoretical saturation as fundamental methods of data generation in grounded theory were applied. The study unfolded through three broad parts, namely: Forming & shaping this grounded theory through exploration and co-creation; Assimilating & situating this grounded theory through understanding and enfolding; Reflecting on this grounded theory through contemplating and reconnecting. The outcome of the first part of the study was my initial proposition of a grounded theory co-created in the interactions between the participants and myself. This was then challenged, developed and assimilated through a focussed literature review through the second part of the study. Through these two parts of this study, an inductively derived explanation was formed and shaped to produce an assimilated and situated substantive grounded theory named Being at Ease. This grounded theory articulates how ‘better and different’ nursing is recognised from the point of view of those who use the nursing ability of critical care nurses through the core concern ‘being at ease’ and its four categories ‘knowing self’, ‘skilled being’, connecting with intention’ and’ anchoring’. The final part of this study unfolded in my reflections on what this grounded theory had revealed about nurses and elements of nursing practice that are important to a utiliser in recognising ‘different and better’ critical care nursing. I suggest that as nurses we need to develop a language that enables us to reveal with clarity these intangible and tacit elements recognised within the being and doing of ‘different and better’ nursing. I reflected on the pivotal space of influence a teacher has with a student, and on how the elements essential in being and doing ‘different and better’ nursing need to be evident in her/his own ways of being a teacher of nursing. Teaching and learning encounters may be enhanced through drawing what this theory has shown as necessary elements that shape ‘different and better’ nurses through the moments of influence a teacher has in each encounter with a student.
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  • Date Issued: 2015

Entrepreneurial intention among Rhodes University undergraduate students

  • Authors: Bell, Jonathan Andrew
  • Date: 2015
  • Subjects: Rhodes University -- Undergraduates , Entrepreneurship -- South Africa -- Grahamstown , Social cognitive theory , Intention , Attitude (Psychology) , Influence (Psychology) , South Africa -- Economic conditions -- 1991-
  • Language: English
  • Type: Thesis , Masters , MSocSc
  • Identifier: vital:3267 , http://hdl.handle.net/10962/d1020011
  • Description: The entrepreneurial intentions of university students are important factors to consider when developing entrepreneurship offerings at tertiary level institutions. This research study reports on pertinent findings from a study which set out to determine Rhodes university undergraduate students‟ entrepreneurial intentions and their pull and push factors that have brought them to the decision to become entrepreneurs. A survey, using a 43 question structured web-based instrument was used to capture the responses from undergraduate students across different departments at Rhodes University, Grahamstown. Key findings suggest that few undergraduate students intend to enter into an entrepreneurship career immediately after completion of their studies, whereas many of the respondents were more interested in doing so five years after graduation. The vast majority of students were satisfied without having formal entrepreneurial education and factors such as previous employment in entrepreneurial activities, and family influence had a statistical significant relationship with entrepreneurial intention.
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  • Date Issued: 2015

Drivers and consequences of residents' satisfaction with off-campus student housing in South-South, Nigeria

  • Authors: Bella-Omunagbe, Ojo Cyprain
  • Date: 2015
  • Subjects: Student housing -- Nigeria , Housing -- Resident satisfaction , Residence and education , Universities and colleges -- Nigeria -- Administration
  • Language: English
  • Type: Thesis , Doctoral , DPhil
  • Identifier: vital:9720 , http://hdl.handle.net/10948/d1021198
  • Description: The student housing system worldwide and South-South Nigeria in particular has witnessed an unprecedented transformation, such that private off-campus student housing facilities (SHFs) are now the primary source of accommodation for students in tertiary institutions. A considerable gap exists between the supply and demand for on-campus student housing and the quest to fill this gap has stimulated the creation of a significant student housing market in the areas where these tertiary institutions are located. The prospect for economic investments in the student housing sector is high and private investors are involved in the provision and management of offcampus student housing. The main consequence of this practice in South-South, Nigeria is the delivery of low-quality buildings that are not able to meet the needs and expectations of residents. SHFs that are constructed without due regard to residents needs are characterised by dissatisfaction with attributes of housing and low investment performance. The implication is that residence users are often not satisfied with the attributes of the residential environment that are provided; thus their behaviours often impose some consequences on investors gains and objectives.Therefore, understanding the dynamics among attributes that are important to students, that give the required satisfaction, and the impact of the availability or lack-of on behaviour such as loyalty, willingness to pay for attributes and word of mouth behaviour are critical to profitability. Most often, the relationship among these attributes are treated as linear and symmetrical with the assumed implication that better attributes produce improved behaviours. However, this may not always be the case. This approach is rarely addressed and is little understood in student housing studies. Therefore, the aim of this study was to identify student housing attributes that act as drivers of resident atisfaction and the consequences/effects of these drivers on student behaviour in order to determine appropriate measures that could be used to develop, maintain and upgrade student accommodation. The methodology of the study included an extensive literature review and a field study conducted to obtain the perceptions of students in seven tertiary institutions located in South-South, Nigeria. The main task was to define attributes of student housing facilities based on the symmetric and asymmetric impact of the performance of attributes on satisfaction with residence. The Kano model and importance-performance analysis (IPA) were used to establish sets of criteria that could be used to prioritise attributes that are required in student housing for optimal investor gains. Analysis of the findings lead to the conclusions that different degrees of behaviour were associated to the perception of importance that is attached to attributes by residents and the satisfaction that is derived from the use of such attributes. The implication of the conclusions is that to meet users satisfaction needs, varied improvement strategies are required for different attributes in order to maximise the use of resources for maximum gains. The recommendations for investors in SHFs include among others to segment the SHFs market based on demographic characteristics, prioritise and provide only attributes that add-value to identified groups. Emphasis should also be placed on providing attributes that are not only satisfactory, but with capacity to improve loyalty/retention, willingness to pay and positive word of mouth behaviour. It is also recommended that the local authority should improve critical attributes that are deemed to be outside the scope of the investors.
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  • Date Issued: 2015
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