A narrative biography of sexual trauma and subsequent substance abuse
- Authors: Jansen, Tazminne
- Date: 2021-04
- Subjects: Sexual abuse victims -- South Africa -- Biography , Substance abuse -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/51231 , vital:43234
- Description: In South Africa, substance abuse and sexual assault and/or abuse are major concerns. Society has become desensitised to these topics because of its high prevalence rate. Substance abuse is often greeted with stereotypes and prejudices that view individuals as a problem to society. The proposed research employed a qualitative, exploratory, and descriptive strategy of inquiry, guided by narrative biographical research design. Social constructionism was employed as a theoretical framework to explore how an individual had constructed her life story, with a specific focus on her experience of sexual trauma and subsequent substance abuse. A non-probability purposive sampling method was used to recruit a research participant who was in the public domain as a motivational speaker in an attempt to guard against retraumatisation. Two data collection methods were employed, namely one-on-one semi-structured interviews and an invitation to the participant to journal about her experience, guided by specific stimulus questions. Thematic narrative analysis was employed as a method of data analysis. The outcome of the investigation had provided a narrative account of the research question at hand with the following themes coming to the forefront:- Early childhood experiences ( pre-sexual abuse), sexual trauma, recovery and meaning making. , Thesis (MA) -- Faculty of Health Sciences, 2021
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- Date Issued: 2021-04
A narrative study of students’ and staff’s experiences of living with HIV and AIDS at Rhodes University
- Authors: Tsope, Lindiwe
- Date: 2021-04
- Subjects: AIDS (Disease) South Africa Makhanda , HIV infections South Africa Makhanda , College students Health and hygiene South Africa Makhanda , Universities and colleges South Africa Makhanda Employees Health and hygiene , Stigma (Social psychology) , AIDS (Disease) Social aspects South Africa Makhanda , HIV infections Social aspects South Africa Makhanda , AIDS (Disease) Psychological aspects , HIV infections Psychological aspects , Health counseling South Africa Makhanda , Discourse analysis, Narrative
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/176894 , vital:42769 , 10.21504/10962/176894
- Description: A narrative study of students’ and staff’s experiences of living with HIV and AIDS at Rhodes University Research on HIV and AIDS in university settings, especially research exploring the experience of living with the disease, has been minimal. As a response to the knowledge and research gaps, this thesis is a qualitative study involving students and staff living with HIV (LWH) and accessing treatment (ART) at the Rhodes University Health Care Centre. This study explored the personal and social symbolisms as well as meanings attached to living with HIV, through in-depth interviews with ten students and staff living with HIV, all purposively sampled and recruited through the Rhodes University Health Care Centre. Using social constructionism, symbolic interactionism and the theory of biographical disruption, the narratives revealed a positive and inspirational side of living with HIV and AIDS – especially emphasizing that PLWHA do not have to surrender to the deadly narrative of the disease. It became evident that stigma, both internal and external, largely influences illness narratives. Furthermore, the study revealed the social reconstruction of life narratives both in order to understand the illness in terms of past social experiences and to reaffirm the impression that life has a course and the self has a purpose. All participants found that accessing treatment from the Rhodes University Health Care Centre positively influenced their experiences of adherence and reconstruction of narratives. The study indicates that HIV-related interventions in place at the university need to pay more attention to the psychosocial needs of PLWH, involvement of PWLH, as well as keeping up with the continuously changing global HIV narrative. The study argues for more attention to in-depth experiences and personal narratives in HIV and AIDS, and PLWHA education at Rhodes University. , Thesis (PhD) -- Humanities, Department of Sociology, 2021
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- Date Issued: 2021-04
A novel Arf GTPase assay for antimalarial drug discovery
- Authors: Swart, Tarryn
- Date: 2021-04
- Subjects: To be added
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/178558 , vital:42950
- Description: Access restricted until April 2022. , Thesis (PhD) -- Faculty of Science, Biochemistry and Microbiology, 2021
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- Date Issued: 2021-04
A problematisation of Afrikaner identity subject positions as found in the coverage of contemporary Afrikaans music in HUISGENOOT magazine discourse
- Authors: Hughes, Lestie
- Date: 2021-04
- Subjects: Afrikaners -- South Africa -- Music -- History and criticism , Multimedia (Art)
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/52558 , vital:43686
- Description: Through the lens of Foucauldian genealogy, this thesis problematises the subject positions towards Afrikaner identity reflected in contemporary Afrikaans songs covered by Huisgenoot magazine. Such a genealogical exploration thematises the games of truth underpinning the formation of Huisgenoot, highlights its role in solidifying white Afrikaner Nationalist discourse of apartheid, observes its more populist, profit-oriented approach from the 1970s onwards and considers the residual echoing of its former discursive orientation. The song analysis of selected Afrikaans songs/music videos covered in Huisgenoot is guided by the semiotics of Nicholas Cook, such that it frames the analytical question of how such music is driven by conformance, contest and complementation between multi-media elements in ways that make meaning possible. Accordingly, this methodology resonates with the non-essentialising focus of Foucauldian problematisation, premised on critical resistance that makes new responses simultaneously possible. The self-reflexive autoethnographical approach employed, entailing the author’s dialogical engagement with her own ‘Afrikaner self’, similarly facilitates the dynamic interplay between multiplicities. Correlatively, on the one hand, more ‘closed’ and more ‘open’ Afrikaner identity positions reflected within the songs are analysed, as well as seemingly ‘reconciliatory’ / collaborative’ musical manifestations which ultimately revert back to more ‘closed’ identity constructs. But on the other hand, observation of adherence to a ‘white-black’ dichotomy within songs that manifest more ‘closed’ identity positions also leads to consideration of the parallels between the goals of white Afrikaner Nationalism and the current Decolonisation narrative, which is informed by Black Consciousness thought and generated by the ‘Colonisation of a Special Kind’ ANC policy. Both such Decolonisation rhetoric and the countering rhetoric of the Neo-Afrikaner Protest Movement (NAP) are thus identified as metanarratives, underpinned by a ‘white-black’ dichotomy. In this regard, while Huisgenoot’s predisposition towards songs manifesting more ‘closed’ Afrikaner identity positions is considered in terms of its aforementioned profit-oriented endeavour to appeal to its ostensible primary readership, an encouraging increase in coverage of coloured artists is both noted and occasionally seen to overlap with its coverage of songs manifesting more ‘open’ Afrikaner identity positions. Among the latter one may – again in Foucauldian terms – differentiate between songs focussed on an engagement in cross-cultural relations of power, and songs intent on shattering states of domination of power blocks, often through shocking juxtaposition of disparate elements. These more violently dismantling endeavours, it is argued, comprise examples of Foucauldian transversal struggles, although their coverage in Huisgenoot is also attributed to their shock value and/or record sales, rather than their transformational potential. Furthermore, such Huisgenoot coverage is also seen to place more transformationally oriented artists at risk of media ‘domestication’, with its concomitant inhibiting of creativity. Finally, the researcher’s commitment to creative problematisation of her own Afrikaner identity, coupled with acknowledgement of her inescapable textual entrapment, culminates in her acceptance of the continual flux characterising dialogical power relations, before she – in accordance with the Foucauldian methodology employed – presents all ‘conclusions’ in a non-dictatorial spirit of ‘truth creation’, desirous of continual self/other dialogue. , Thesis (PhD) -- Faculty of Humanities, 2021
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- Date Issued: 2021-04
A project delivery framework within the Construction Industry
- Authors: Chikandiwa,Yeaukai Memory
- Date: 2021-04
- Subjects: Construction --Management -- South Africa , Project Management , Communication
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52594 , vital:43692
- Description: A lack of effective communication has often resulted in information bottlenecks and conflicts in the execution of construction projects and is the primary cause of problems such as delays, increased project cost, reduced roductivity, loss of profit, or damaged professional or business relationships within the construction Industry. Despite all the advancement in the communication and integration tools in a drive to optimize the construction industry, this challenge still remains. In order to address this problem, this research project sought to determine the key elements that constitute effective communication and its importance to the successful projects delivery within the construction industry. A survey design which involved a sample study of a representative population through the use of a questionnaire was used. The research population comprised of all design consultants. The research found that, Common tools and processes, Good change management, PM best practices & Performance KPIs and resources are the main missing elements respectively for effective communication, which foster the conflicts inherent within the industry. The following key factors are however mostly present in project team; well-articulated project scope, quality information exchange and commendable people, cultures and behaviour. Informational asymmetries, misrepresentation, poor PM skills hinders effective communication and often results in project failure. There is therefore need to concertize the design professionals on the importance of effective communication and enlighten them on the dynamics involved. The construction industry is inherently complex, multi-disciplinary, fragmented, sporadic, dynamic and generally resistant to change. Hence, the need for rigorous research and feed back to the design professionals on effective communication especially during the changing times driven by technology, dubbed the 4th revolution. More work is to be done in order to achieve the effective communication, in the following study research area for the construction industry; the alignment of tools and processes, change management and Performance KPIs for the construction industry. These factors present a huge challenge in a fragmented and adversarial industry which is inherently resistant to change. , Thesis (MSc) -- Faculty of Engineering,the Built Environment and Information technology,2021
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- Date Issued: 2021-04
A proposed framework for the development of urban agriculture in South African cities
- Authors: Brown, Nicola Jayne
- Date: 2021-04
- Subjects: Urban agriculture -- South Africa , Sustainable development -- South Africa , Food security -- Climatic factors -- South Africa , Resilience (Ecology)
- Language: English
- Type: text , Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10962/174413 , vital:42475
- Description: While climate change and rapid urbanisation are impacting our cities and existing infrastructure, population growth and resource scarcity are placing unprecedented pressure on our food systems. In light of such challenges and the Sustainable Development Goals, resilient solutions are being sought to move both urban development and food production towards a more sustainable future. In this context, Urban Agriculture (UA) has been identified as a possible mechanism to complement rural food production with many associated social, economic and environmental benefits for urban communities. Some of these benefits include increased food system resilience, better urban environmental management, circular and productive reuse of urban wastes, employment opportunities, reduced food miles and the promotion of social inclusivity. Through a sustainable food system lens and underpinned by Resilience Theory, this research study sets out to investigate and explore the considerations for UA development. The research study reviews UA literature to identify and analyse the common challenges which act as barriers to implementation, as well as the current or potential opportunities which could be leveraged to drive UA development. The insights gained from literature on UA and UA development frameworks; and the data gathered from qualitative interviews with experts working in UA-related fields in South Africa (SA), were used to build a conceptual framework for UA development in SA. The conceptual framework developed is intended to be used as a guide for local municipalities, urban planners, urban farmers, urban communities and UA support organisations in their approach to developing UA initiatives. The findings from this research study reveal that UA development in SA involves numerous actors at both provincial and municipal levels; and within private institutions, businesses, universities, farmer organisations and society. The findings also reveal that UA currently occurs at many levels in SA, with each level drawing a particular range of participants due to the various social, economic and/or environmental features of the initiative. Along with challenges associated with land access, the lack of UA-related knowledge, the threat of theft, vandalism and soil contamination (to name a few); a lack of understanding of how agriculture can fit into urban spaces was found to be a major obstacle. The findings suggest that this lack of understanding has led to an under-realisation of the full potential of UA in South African towns and cities; and an inability to incentivise and optimise the development of UA. Considering the findings derived from the investigation, the study proposes five major considerations for UA development in SA, all of which are unpacked in the conceptual framework. The study concludes by making recommendations for UA decision-makers and UA organisations to consider for future developments.
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- Date Issued: 2021-04
A Psychobiographical Study of Charles Manson
- Authors: Flatela, Sambesiwe
- Date: 2021-04
- Subjects: Psychology -- Biographical methods , Personality development -- Psychological aspects , Criminals -- United States -- Biography
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/51021 , vital:43201
- Description: Charles Manson was notorious for his antisocial behaviour and influence; through his charisma, he formed a group of followers known as the Manson family. Manson and his followers became involved in various criminal activities which culminated in the murder of 7 people. These murders were not committed by Manson per say, but he planned them, and incited his followers to commit them; this resulted in a trial and Manson going to prison, being given a life sentence. He continued to influence people while he served his sentence in prison. Manson died of natural causes in November 2017. The research study explores and describes the life of Manson in the form of a psychobiography. The aim of the study was to gain insight into the personality development of Charles Manson. This was achieved by applying Otto Kernberg’s Object Relations Theory to Manson’s known life experiences. Various data was collected and triangulated, using primary and secondary sources. Miles, Huberman, and Saldana’s (2013) three step procedure was used to analyse the data. The findings highlight the influence of genetics and rejection as pivotal to the unfolding of Manson’s personality, and provide insight into how his antisocial patterns unfolded. They highlight, in particular, his use of control, dominance and devaluation to protect his positive experience of self. , Thesis (MA) -- Faculty of Health Sciences, Department of Psychology, 2021
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- Date Issued: 2021-04
A psychobiographical study of Gavin Maxwell: a Kernberg object relations approach
- Authors: Walters, Jacqueline
- Date: 2021-04
- Subjects: Personality development -- Psychological aspects , Psychology -- Biographical methods
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52363 , vital:43619
- Description: Gavin Maxwell was an author and naturalist. He published a memoir called A Ring of Bright Water, which shaped the way millions of readers viewed nature. Maxwell wrote simple prose which paints an idyllic and moving picture of his time spent in his “lost paradise”, alongside his beloved animals, most notably his otters. However, in reality Maxwell was a man in conflict, seen in volatile relationships, financial recklessness, and the preference for the company of animals over people. The aim of this study was to explore Maxwell’s life to gain insight into his personality development. This was achieved by applying Otto Kernberg’s Object Relations Theory to his life experiences. In doing so the author hoped to gain an understanding of the personality dynamics that led to Maxwell’s relational difficulties and eccentricities. Data was collected by triangulating multiple sources of information on his life. Miles and Huberman’s (1994) three step approach was used to analyse data collected. These steps are: data reduction, data display, and conclusion drawing and verification. The research study found that Maxwell’s personality development was likely arrested at the third stage of Kernberg’s model. Maxwell relied primarily on immature defence mechanisms based in splitting and possessed a fragile ego structure which he protected through grandiosity. The findings indicated that Maxwell’s personality falls in the borderline level of functioning with a strong likelihood of pathological narcissism. , Thesis (MA) -- Faculty of Health Sciences, 2021
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- Date Issued: 2021-04
A psychobiographical study of Harvey Milk
- Authors: Pretorius, Neil Zietsman
- Date: 2021-04
- Subjects: Gay rights , Psychology -- Biographical methods
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/51600 , vital:43321
- Description: The aim of the study was to explore and describe Harvey Milk’s identity development and performance from the theoretical perspective of Narrative Therapy. Harvey (1930-1978), was an American Gay Rights activist who became one of the first openly gay political candidates to be elected to public office in the United States in 1977, before being assassinated in 1978. The study was conducted within a postmodern Social Constructionist epistemology which applied Michael White and David Epston’s (1990) Narrative Therapy as a particular theoretical lens to understand Harvey’s lived experiences. Harvey was chosen as the research subject based on his ability to construct his public identity as an openly gay politician and activist in defiance of the contemporarily dominant heteronormative discourse, despite the danger this posed to his personal safety. His selection was made through purposive sampling which facilitated a qualitative, single case psychobiographical study. Data on Harvey was obtained from both primary and secondary sources available in the public domain, and was analysed using Narrative Therapy concepts that describe individual identity. The study’s findings detail the narrative processes Harvey underwent and the discursive influences he experienced to move from being a closeted gay man, who hid his sexuality from public view, to an openly gay trailblazing Gay Rights activist, who fiercely challenged the norms and effects of heteronormativity on both his own life and that of his gay community. The study emphasises the value of psychobiography and Narrative Therapy to understand individual identity construction and performance. , Thesis (MA) -- Faculty of Health Sciences, 2021
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- Date Issued: 2021-04
A sociological investigation of child labour in the fishing communities of Kalangala, Uganda
- Authors: Majanja, Zaaly’embikke Irene Margaret
- Date: 2021-04
- Subjects: Child labor -- Uganda -- Sociological aspects
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/53428 , vital:45153
- Description: The researcher conducted a sociological investigation into the persistence of child labour in the fishing communities of Uganda, specifically in the Ssese Islands, Kalangala District, on the Kisaba and Nakibanga landing sites situate in Bukasa. The study aimed at investigating the sociological aspects of persistent child labour practices in the fishing communities. The study employed a qualitative research method with a descriptive case study design, utilising an interpretive paradigm. The case study design facilitated the researcher’s investigation into child labour practices in their natural settings. The study employed mainly in-depth interviews, focus group discussions and observations for data collection. Data analysis was performed utilising the ATLAS.ti computer software package to identify the sociological factors involved with employing child labour. The Various themes emerged from the data analysis. The study established that despite the Ugandan Government domesticating all the UN/ILO Conventions on Rights of a Child and Worst Forms of Child Labour, the OAU Charter on Child Rights and Welfare and also instituting legal frameworks at national level, the practice of using child labour persists. The findings disclosed that economic, sociological and structural factors appear to perpetuate child labour in the fishing communities. Economic factors such as poverty, unemployment or underemployment, then sociological aspects such as men abandoning their helpless families on landing sites as they follow the fish according to seasons. Furthermore, the community attitudes such as low value for education, child labour being a normal trend and part of apprenticeship for the children. Again, there are structural issues such as the inadequate implementation and the weak enforcement of the legal frameworks, including insufficient infrastructures such as schooling facilities. These factors appear to perpetuate child labour in the fishing communities. The study concluded that there is an urgent need to address the issues associated with the persistence of child labour in the fishing communities. The study recommends employing a holistic multipronged approach through bottom-up participatory planning and integrating stakeholders at various levels. This could enhance efforts and share ideas and resources that can result in effective operations in order to eliminate child labour in the fishing communities. , Thesis (DPhil) -- Faculty of Humanities, 2021
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- Date Issued: 2021-04
A study of the airflow on the windward slope of a transverse dune in the Alexandria coastal dunefield
- Authors: Burkinshaw, Jennifer Ruth
- Date: 2021-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52734 , vital:43883
- Description: Our understanding of the evolution of dune morphology has been hampered by a lack of empirical observations of airflow behaviour over dune forms. Sand dunes intrude into the atmospheric boundary layer and convergence of streamlines results in an acceleration of airflow up the windward slopes of dunes. This study examines the airflow structure and corresponding bedform development on the windward slope of a 7 m high transverse dune on the edge of the Alexandria coastal dunefield, Algoa Bay, South Africa. The Alexandria dunefield is subjected to a trimodal wind regime, consisting of the dominant south-westerly which blows all year round, summer easterlies and winter northwesterlies. The morphology of the study dune, Dune13, is controlled by the easterlies and north-westerlies, and reverses seasonally with respect to these two winds. Seven section lines 30 m apart and normal to the dune crest were surveyed regularly over the period of a year to monitor the reversal process. Three detailed topographic surveys were also done during this period. Airflow behaviour was monitored during the year. Wind speed profiles on the windward slope of the dune were measured using 4 to 5 vertical arrays of anemometers positioned from the base of the dune to the crest on a 1 selected section line. Usually 4 to 5 anemometers were deployed in each vertical array, from a height of 6 to 10 cm above the surface, up to a height of 150 cm above the surface. Initially 8 microanemometers were available; ultimately 28 anemometers were run simultaneously. An independent weather station at an elevation of 6 m recorded the unaccelerated flow. Local gradient measurements and erosion and deposition rates were recorded along selected section lines. Strong summer easterly winds (14 m/sec at 1.4 m above the dune crest) were measured on a dune slope in the process of being transformed from a slipface to a stoss slope. The following winter, light north-westerly winds (typically B m/sec at 1.6 m above the dune crest) were measured on the new windward slope already reversed by the prevailing winter wind. Airflow data confirm the compression of airflow against the windward slope resulting in a non-logarithmic wind speed profile. Compression results in an increased shear velocity within 30 cm of the dune surface, and the dune slope is eroded. Higher up in the wind speed profile, shear velocity decreases to 0.1 m/sec. It is not known at what height the wind speed profile recovers from the intrusion of the dune into the boundary layer. High values of shear velocity (1.6 m/sec) above the rounded crestal area of the dune record the recovery of the wind speed profile from flow divergence, which is a response to the rapid reduction of dune gradient and is accompanied by deposition of sand in this region. 2 The erosion pin data act as a simple and sensitive test for changes in gradient, reflecting the dune's response to changes in the airflow regime. The shape of the dune plays a major role in determining the extent of the compression and the distribution of shear velocity up the slope. Increased shear velocity is experienced on that part of the slope which is nonaerodynamic with respect to the prevailing wind. Under unidirectional conditions, feedback between flow and form results ultimately in a slope with a curvature such that shear velocity increases systematically upslope. The survey data and erosion pin data record the reversal process as the dune achieves a new steady state during each wind season. The existence of a non-logarithmic wind speed profile makes it difficult to know what relevant measure of shear velocity is to be used in sand transport equations. Future work should include wind speed measurements within 10 cm of the surface. An ideal study modelling aeolian bedform development would utilise wind tunnel measurements, combined with field measurements such as obtained in this study, for comparison with numerical modelling. The study needs to be extended to 3-dimensional airflow measurements. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2021
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- Date Issued: 2021-04
A study of the catalysis of the Diels-Alder and Aldol Condensation Reactions
- Authors: Ndagano, Urbain Nshokano
- Date: 2021-04
- Subjects: To be added
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/178525 , vital:42947
- Description: Access restricted until April 2022. , Thesis (MSc) -- Faculty of Science, Chemistry, 2021
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- Date Issued: 2021-04
A systematic review of research into working capital management in South Africa
- Authors: Watson, Storm Brandon
- Date: 2021-04
- Subjects: Gqeberha (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52995 , vital:44906
- Description: This study is set out to apply mixed methods approach to a systematic review of research into working capital management in South Africa. Research into working capital management has primarily focused on the effect it has on a business’s profitability, liquidity and performance. There is, however, limited research on the topic working capital management in South Africa and, as such, the primary objective of this study is to review research outputs on working capital management in South Africa. The purpose is to identify research gaps in the current body of knowledge by means of the development of a recommendation’s framework. , Thesis (MA) -- Faculty of Business and Economic Sciences, School of Management Sciences, 2021
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- Date Issued: 2021-04
A Systematic Visualisation Framework for Radio-Imaging Pipelines
- Authors: Andati, Lexy Acherwa Livoyi
- Date: 2021-04
- Subjects: Radio interferometers , Radio astronomy -- Data processing , Radio astronomy -- Data processing -- Software , Jupyter
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/177338 , vital:42812
- Description: Pipelines for calibration and imaging of radio interferometric data produce many intermediate images and other data products (gain tables, etc.) These often contain valuable information about the quality of the data and the calibration, and can provide the user with valuable insights, if only visualised in the right way. However, the deluge of data that we’re experiencing with modern instruments means that most of these products are never looked at, and only the final images and data products are examined. Furthermore, the variety of imaging algorithms currently available, and the range of their options, means that very different results can be produced from the same set of original data. Proper understanding of this requires a systematic comparison that can be carried out both by individual users locally, and by the community globally. We address both problems by developing a systematic visualisation framework based around Jupyter notebooks, enriched with interactive plots based on the Bokeh and Datashader visualisation libraries. , Thesis (MSc) -- Faculty of Science, Department of Physics and Electronics, 2021
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- Date Issued: 2021-04
A theoretical study of alkoxyl radical and radical cation mediated cyclisation reactions in unsaturated alkanols
- Authors: Lee, Peter Mattison Clarke
- Date: 2021-04
- Subjects: Gqeberha (South Africa) , Eastern Cape (South Africa) , Density functionals
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/52130 , vital:43430
- Description: A large part of this computational study focussed on selectivity patterns for 4-penten- 1-oxyl radical 1,5- and 1,6-cyclisations and for those of analogous 5-hexenyl, 4- penten-1-aminyl, 4-penten-1-iminyl and 3-phenylpropan-1-oxyl radicals. The study furthermore included cyclisation reactions of the radical cations of 4-penten-1-ol and 3-phenylpropan-1-ol. Calculations were performed for all applicable species involved in the two cyclisation modes studied, i.e. 1,5- and 1,6-cyclisation. These species included radical and radical cation precursors, as well as relevant radical transition state structures and radical adducts. All cyclisation systems investigated used the Density Functional Theory (DFT) functional B3LYP with a combination of eight basis sets. Each basis set used was a progressively higher level of theory than B3LYP/6-31G* which was used as a starting point. Cyclisations for unsubstituted species, e.g. the 4-penten-1-oxyl radical 1,5- and 1,6-cyclisations, were also simulated using the ωB97X-D and ωB97X-V functionals which account for dispersive effects. The same set of eight basis sets were used with these two functionals. , Thesis (PhD) -- Faculty of Science, School of Computer Science, Mathematics, Physics and Statistics, 2021
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- Date Issued: 2021-04
Abortion and the role of self-forgiveness
- Authors: Van der Berg, Hailey
- Date: 2021-04
- Subjects: Grahamstown (South Africa) , Forgiveness -- Psychological aspects , Abortion -- South Africa -- Eastern Cape -- Psychological aspects
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/51917 , vital:43384
- Description: Women who have terminated a pregnancy may identify shame, guilt, grief, and/or regret after the procedure. This study aimed to explore and describe the self-forgiveness process of women in the Nelson Mandela Metropole area who identified negative emotions such as guilt and/or regret after an abortion. The methodology followed an exploratory-descriptive, qualitative design, adopting Lincoln and Guba's (1985) model of trustworthiness. Participants were obtained through non-probability purposive sampling and data was gathered via semi-structured, online individual interviews on a face-to-face basis. Data gathered was analysed using Braun and Clarke’s (2006) thematic analysis. The findings reflected the participants’ perceptions of forgiveness and self-forgiveness, as well as the psychological experiences of women post-abortion. A self-forgiveness model developed by Enright and the Human Development Study Group (1996), as well as the stages of grief developed by Kübler-Ross and Kessler (2005), was utilised to conceptualise the psychological experiences and psychological healing of post-abortion women. , Thesis (MA) -- Faculty of Health Sciences, 2021
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- Date Issued: 2021-04
Access to digitised archival collections in National Heritage and Cultural study Centre and International Library of African Music
- Authors: Barbra, Kakumba
- Date: 2021-04
- Subjects: Archives--Access control , Archival materials -- Access control
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22356 , vital:52030
- Description: The study investigated access to digitised archival collections in two selected institutions in the Eastern Cape Province, South Africa. This study is significant because it sought to generate insights on adaptability of technology in archives and library operations, and accessibility thereof. This is important for monitoring the accessibility of digitised archival collections at institutions to improve their operations and maximize the global visibility. This study adopted qualitative research methodology. The researcher followed a rigorous methodological path that began with a thorough literature review and the careful and thoughtful posing of research questions and objectives. A purposive sample was chosen from National Heritage and Cultural Studies Centre (NAHECS) and International library of African Music (ILAM) (staff members) and interviewed through face-to-face interviews. The collected data was analysed thematically. The study established that, the type of materials digitised at NAHECS and ILAM are bound books, fragile papers, photographic prints, slides, audio-visual materials,artefacts and documents such as personal letters of early travellers,missionary’s records,traders writing personal file and political parties documents. Secondly, the study established that end users of digitised materials are researchers, students, archivist, librarians, international and local community, composers, musicians, and historians. It also emerged that awareness programmes used to increase public knowledge about access to digitised content in the two study sites include conferences, social media, and television advertisements. However, there are challenges faced in providing access to digitised materials at NAHECS and ILAM. Some of these challenges include lack of funding, unavailability of resources, lack of awareness, and information insecurity. These challenges have made access to digitised archival materials difficult. Based on these findings, it is recommended that archives facilities should be well resourced and archivists be continually trained on access to digitised archival materials. , Thesis (M Bibl) -- Faculty of Social Sciences and Humanities, 2021
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- Date Issued: 2021-04
Accountability in the global health regime : a critical examination of the institutional policy and practice of the global fund to fight HIV/AIDS, tuberculosis and malaria partnership programme in Ghana
- Authors: Onokwai, John Chukwuemeka
- Date: 2021-04
- Subjects: World health , Global Fund to Fight AIDS, Tuberculosis, and Malaria -- Administration , Public-private sector cooperation -- Political aspects , Public-private sector cooperation -- Social aspects , Public-private sector cooperation -- Administration , Medical policy -- Ghana , Public health laws, International , Ghana -- Social conditions
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/177099 , vital:42790 , 10.21504/10962/177099
- Description: The overarching objective of this thesis is to undertake a critical examination of the institutional accountability policy and practice of the Global Fund to Fight AIDS, Tuberculosis and Malaria (Global Fund) in the context of its partnership programme in Ghana. The Global Fund is a global public-private partnership (GPPP) in health engaged in public health policy processes worldwide. As a GPPP, the policy mandate that underpins its global response to fight the aforementioned diseases requires it to enter into partnerships with recipient countries to finance their national health policy responses and strategies to tackle these diseases. Situating accountability within the context of the shift from an international health to a global health regime, the study argues that the emergence of GPPPs in health and the formal policy mandate and decision-making powers they exercise have had knock-on consequences for understanding accountability in the global health regime. This is because while the understanding of accountability for public health policy processes in the international health regime revolved solely around state-based and state-led accountability processes, it is no longer so in current global health regime. Since these GPPPs are not states, they derive their understanding of accountability from the nature and character of their individual policy and practice arrangements. However, despite contestation around the Global Fund’s accountability in global health literature, this literature has little to say on the question of how the Global Fund itself (as a partnership organisation) understands accountability in policy and how this understanding informs its practice in specific settings of global health. Thus, this study contributes to literature on GPPPs’ accountability in global health by specifically exploring how the Global Fund understands accountability in policy and how this understanding informs its accountability in practice, in particular in relationship to its implications for country ownership of health policy in Ghana. Drawing on fieldwork undertaken in Ghana, and guided by a critical political economy approach, this study will demonstrate how: 1) the Global Fund’s institutional policy and practice arrangements undermine accountability to the government and to those affected by their activities; 2) the Global Fund’s practice of country ownership is reflective of conditional ownership despite the fact that the Global Fund claims to promote country ownership as a core principle of its accountability practice in aid recipient countries; and 3) the accountability policy and practice instruments of the Global Fund are not politically neutral, but are rather a function of relations of power. To improve the ability of Ghana (and other recipient countries) to own their developmental policies, a reordering of global economic relations is needed, with a renewed emphasis and focus on economic justice and human rights. Such a reordering will improve the material capabilities (control of and access to global centres of production, finance and technology) of aid recipient countries. This will empower Ghana (and other recipient countries) to play a more dominant, rather than a subsidiary role in how the global health landscape is organised and financed and in policy processes undertaken by global health policy institutions like the Global Fund. In this way, Ghana (and other developing countries) will be able to limit and mitigate the dominance and influence of powerful donors who shape the institutional policy and practice arrangements of global health policy institutions like the Global Fund. , Thesis (PhD) -- Faculty of Humanities, Department of Political and International Studies, 2021
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- Date Issued: 2021-04
Agro-morphological characterization and investigations into the response of yellow Quality Protein Maize (QPM) genotypes to low soil pH
- Authors: Bobotyana, Simthandile
- Date: 2021-04
- Subjects: Corn as food , Plants--Drought tolerance
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/20528 , vital:46087
- Description: Maize (Zea mays L) is an essential food grain crop in South Africa and is mainly grown under rainfed conditions by small-scale farmers. Quality Protein Maize (QPM) contains a higher level of two essential amino acids, tryptophan, and lysine when equated to normal maize. Therefore, the QPM in communities is a vital cereal where maize is a staple crop. Among the significant abiotic stresses that adversely affect maize productivity, such as soil fertility. Low soil pH or soil acidity results in nutrient deficiencies, as well as the toxicity of minerals such as manganese (Mn), aluminium (Al), and iron (Fe). The objectives of the study were to: (1) Characterize yellow QPM inbred lines and testcross hybrids for agro-morphological variability under optimum conditions, (2) Determine the response of QPM inbred lines and testcross hybrids to Al toxicity, and (3) Estimate the combining ability of QPM genotypes for the tolerance to Al toxicity. The laboratory assessment for tolerance to Al toxicity revealed a negative relationship between relative root growth RRG and hematoxylin staining; among the inbred lines, the genotype 8Y, 17Y, and 7Y had the highest RRG and net root growth (NRG) values and exhibited the highest tolerance to Al tolerance with the least hematoxylin staining. Inbred lines 12Y, 16Y, 19Y, 2Y, 20Y, 24Y, 30Y, 27Y, 34Y, 4Y, and 11Y were moderately tolerant. On the other hand, inbred lines 13Y, 18Y, and QSY5 had the least RRG were susceptible. Forty-four testcross hybrids were generated by crossing 22 QPM inbred lines with two open-pollinated variety (OPV) testers. These hybrids were evaluated together with five checks for different agronomic traits. The hybrids were planted in the summer season of 2017/18 and 2018/19 under rain-fed conditions 7 x 7 alpha lattice design was used. The significant variations among the genotypes for grain yield and most other agronomic traits under optimum, acidic conditions and across environments on combined analysis of variance. The hybrid was 14Y x NC (3.22 t/ha), followed by QSY5 x NC (3.02 t/ha) showed the highest yielding. The mean plant height was 226.23 cm, with ranges 197.60 to 254.85cm. The number of kernels per ear was 35, with a range from 29.45 to 40.25. Conversely, the mean ear length was 19.30 cm with a range of 17.65 to 20.95 cm, and the mean ear diameter ranged from 13,50 to 16,05 cm. The highest yielding hybrid, according to ranking, was 14Y x NC (2,93t/ha), which was ranked number 3, followed by 3Y x NC (2,83 t/ha), which was ranked number 4. Twenty-two yellow QPM inbred lines were evaluated for agro-morphological characteristics. A randomized complete block design with three replicates was used under acidic and normal soil conditions at two locations. The mean performance of inbred lines for grain yield ranged from 1.6 t/ha to 3.1 t/ha under optimum conditions, whereas it ranged from 1.1.t/ha to 1.7 t/ha under an acidic environment. The highest grain yielding genotypes under the optimum environment were 14Y, 7Y, and QSY5, while, in the acidic environment, the highest yielders were 3Y, QSY5, and 17Y. The lowest grain yielder under the optimum environment was 16Y at 1.5 t/ha, whereas 6Y, 7Y, 8Y, and 29Y were the most moderate yielders under the acidic environment. Grain yield displayed positive and significant (p<0,05) correlation with ear height (0.59), plant height (0.55), leaf length (0.18), number of leaves (0.37), number of ears per plot (0,54), number of kernels per row, number of rows per ear and thousand kernel weight. Combined ANOVA revealed that the environment effect was significant for all traits except the number of rows per ear and the number of ears in both environments. A total of 71 genotypes (22 inbred lines, forty-four single crosses, and five checks) were evaluated using a 7 x 7 alpha lattice design with two replications in combining ability. Across environments, the analysis showed a mean grain yield record of hybrids that ranged from 1.78 t/ha to 3.42 t/ha. Combined analysis showed only about 4 percent of the 44 hybrids had better grain yield than hybrid checks, whereas about 11 percent of the 44 hybrids had higher grain yield than two of the five hybrid checks. The highest yielding hybrid was 14Y x NC followed by QSY5 x NC. The Mid-parent heterosis (MPH) for grain yield ranged from -32.70 for 11YxObat to 16.50 percent for 14YxNC among the top-yielding genotypes. The highest positive mid-parent heterosis (MPH) for grain yield was observed in hybrid 14YxNC followed by QSY9xNC, QSY5xOBAT, 3YxNC, 13YxNC and 4YxOBAT, while the remaining hybrids exhibited negative estimates. Inbred lines' proportional contributions to the total variances were much higher than the testers for all traits. Whereas the inbred lines' proportional contribution was lower than the interaction of line x tester except on the number of ears which displayed the highest estimates of variances due to SCA effects, significant variation was observed. The GCA effects on grain yield in both environments generally showed no significant difference among inbred lines except for inbred lines such as QSY5 and 34Y but were positive. The selected crosses showed significant SCA effects in a few agronomic yield-related traits in the combined analysis. Among the hybrids, the only crosses that showed significant and positive SCA effects for grain yield were 25YxNC under optimum and 34YxObat under acidic environment. The inbred lines were assessed for tolerance to Al toxicity under laboratory conditions. Overall, the study identified soil acidity tolerant QPM inbred lines with an excellent combining ability for high-yielding QPM test hybrids, grain yield, and related traits. , Thesis (MSc) (Agriculture, Crop Science) -- University of Fort Hare, 2021
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- Date Issued: 2021-04
Alternative approach to controlling citrus black spot disease
- Authors: Thabede, Jahman Thabo
- Date: 2021-04
- Subjects: To be added
- Language: English
- Type: thesis , text , Masters , MSc
- Identifier: http://hdl.handle.net/10962/178569 , vital:42951
- Description: Access restricted until April 2022. , Thesis (MSc) -- Faculty of Science, Biochemistry and Microbiology, 2021
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- Date Issued: 2021-04