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Wage settlement agreement entered into between Bronkhorstspruit Golf Club and Food and Allied Workers Union (FAWU)

Perceptions of a multi-disciplinary team on the effectiveness of their treatment approach at an in-patient adolescent drug treatment facility

  • Authors: Bronkhorst, Willem Lukas Rudolf , Goliath, Veonna
  • Date: 2019
  • Subjects: Drug abuse -- Treatment -- South Africa , Substance abuse -- Treatment -- South Africa Teenagers -- Substance use -- South Africa Substance abuse -- Prevention -- South Africa
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: http://hdl.handle.net/10948/37720 , vital:34231
  • Description: The problem of adolescent substance use disorder as well as the high relapse rates associated with addiction treatment has been recognised both locally and internationally. The ability to effectively implement and monitor existing treatment programs therefore becomes critical to improving treatment outcomes at addiction treatment facilities that serve adolescent clients. The Multi-disciplinary team (MDT) have a key role to play with regard to the delivery and implementation of effective adolescent addiction treatment. The main aim of this qualitative research study was to explore the functioning of the MDT at an in-patient adolescent drug treatment facility and their perceptions regarding the extent to which the nine essential key elements of effective adolescent addiction treatment aligns with their approach to program implementation. This qualitative exploratory-descriptive study employed a non-probability purposive sampling technique to recruit research participants from an adolescent drug treatment centre in Nelson Mandela Bay. Two separate focus group interviews were conducted with participants who met the study’s inclusion criteria. The first group included eight participants, with the second consisting of ten participants. Tesch’s framework for qualitative data analysis was used to analyse raw interview data; validated by an analysis conducted by an independent coder. Guba’s model was used to ensure trustworthiness throughout the research process and of the findings. Emphasis was therefore placed on the concepts of truth value, applicability, consistency, and neutrality. The findings of the study were presented in ten main themes and associated sub-themes. Ethical conduct was ensured by meeting the requirements for 1) ethical review, 2) informed consent, 3) confidentiality and anonymity, 4) the right to confidentiality and privacy of data, 5) beneficence and non-maleficence, and finally 6) exiting ethics.
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  • Date Issued: 2019

Studies in South African marine molluscan chemistry

  • Authors: Bromley, Candice Leigh
  • Date: 2011
  • Subjects: Mollusks -- South Africa , Marine invertebrates -- South Africa , Marine metabolites -- South Africa , Chemical oceanography -- South Africa
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4356 , http://hdl.handle.net/10962/d1005021
  • Description: This thesis investigates the variability occurring in the secondary metabolites produced by three South African marine molluscs. Chapter Two discusses the isolation and spectroscopic structure elucidation of the metabolites isolated from two Siphonaria species. The re-investigation of Siphonaria capensis yielded siphonarienfuranone (2.2) as the only common polypropionate isolated from both the 1998 and 2009 collections of S. capensis from the same areas suggesting possible seasonal or genetic variation in polypropionate production. The sterol cholest-7-en-3,5,7- triol (2.33) was also isolated form the 2009 collection of S. capensis and this is the first time this compound has been isolated from a Siphonaria species. The second species, Siphonaria oculus is closely related to S. capensis and the investigation into the former’s secondary metaboliteproduction revealed 2.2 as a major metabolite suggesting an inter-species overlap in polypropionate production. Three new polypropionate metabolites, 2.35, 2.36 and 2.37 were also isolated from S. oculus. An unsuccessful attempt was made to establish the absolute configuration of 2.37 using the modified Mosher’s method and the limited amount of 2.37 available prevented any further attempts at resolving the absolute configuration of this compound. The 1H NMR analysis of the defensive mucus collected directly from S. oculus revealed the presence of the acyclic polypropionate 2.37 as a minor metabolite. The absence of characteristic signals for the furanone containing compounds 2.2, 2.35 and 2.36, might suggest that these compounds cyclise from a hypothetical acyclic precursor (2.38) during standard work up of bulk acetone extracts of Siphonaria species. Chapter Three discusses the re-isolation and spectroscopic structure elucidation of the metabolites isolated from the nudibranch, Leminda millecra. Three known natural products, millecrone A (3.1), 8-hydroxycalamenene (3.6) and cubebenone (3.8) were re-isolated from our 2010 collection of L. millecra, as well as the new minor metabolite 8-acetoxycalamenene (3.16). The cytotoxic prenylated toluquinones and toluhydroquinones (3.9-3.15) initially isolated from the 1998 collection of L. millecra were not found in the 2010 collection supporting the hypothesis that these compounds may be of fungal origin. L. millecra clearly shows variability in the compounds sequestered by this species with millecrone A (3.1) being the only common metabolite in the three investigations of L. millecra to date. An unsuccessful attempt was made to establish the absolute configuration of 3.1, 3.6 and 3.8 through initial LAH reduction of the ketone moiety contained in 3.1 and 3.8 and esterification of the resultant diastereomeric alcohol mixtures and the phenol functionality in 3.6 with (1S)-camphanic chloride. Crystallisation of the (S)- camphanate esters of 3.6 and 3.8 for X-ray analysis were unsuccessful, while the unexpected conjugate addition of a hydride in 3.1 resulted in complex diastereomeric mixtures which could not be separated by HPLC.
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  • Date Issued: 2011

The chemistry of Algoa Bay ascidians

  • Authors: Bromley, Candice Leigh
  • Date: 2016
  • Subjects: Sea squirts -- South Africa -- Algoa Bay , Marine metabolites , Chemistry, Analytic , Liquid chromatography , Inductively coupled plasma mass spectrometry , Metal ions , Nucleosides , Vanadium
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:4560 , http://hdl.handle.net/10962/d1020606
  • Description: This thesis investigates the chemistry of 25 ascidian species collected from Algoa Bay, South Africa with a concerted focus on metal accumulation by these ascidians and the possible interaction of these metals with ascidian metabolites. Chapter 2 details the screening techniques employed to establish the presence of nitrogenous metabolites (1H- 15N HMBC), hyper-accumulated metal ions (ICP-MS) and potential metal ion/ ascidian metabolite complexes (LC-ICP-MS/ESI-MS). Unfortunately, exhaustive attempts to detect intact metal ion/ascidian metabolite complexes through the use of liquid chromatography with parallel inductively coupled plasma mass spectrometry/electrospray mass spectrometry (LC-ICPMS/ ESI-MS) were unsuccessful. However, the LC-ICP-MS/ESI-MS data obtained for the crude organic extracts of six of the Algoa Bay ascidian species, Distaplia skoogi, Aplidium monile, Aplidium sp., Didemnum sp., Leptoclindines sp. and Polycitor sp. enabled identification of a number of ten halogenated metabolites, namely the indoles 2.28-2.30, and the tyramine and tyrosine derivatives (2.31-2.33, 2.41, 2.43, 2.44 and 2.46), within the ascidian extracts. This study confirmed that LC-ICP-MS/ESI-MS is a powerful tool for the dereplication of halogenated metabolites in complex mixtures especially where these compounds are present in very small amounts. This study is also the first report of these compounds (eight of which are known) in African ascidians. Compounds 2.32 and 2.46 have not been reported before from a marine source. Compounds 2.28-2.30 and 2.33 were present in sufficient amounts in the respective ascidian extracts to allow their isolation and structure elucidation using standard spectroscopic techniques Chapter 3 explores the ability of ascidians to accumulate a wide range of metal ions at concentrations which are often orders of magnitude higher than those of the surrounding sea water. Inductively coupled plasma mass spectrometry (ICP-MS) was used to determine the total ion concentrations of 24 metals in 25 Algoa Bay ascidian species. To the best of our knowledge this is the largest and most extensive investigation of metal concentrations in a group of different ascidians occurring in the same area. Hypotheisizing that the metal ion concentrations for each ascidian specimen screened may represent a unique fingerprint for each specimen principal component analysis (PCA) was used in an attempt to establish whether there were spatial, temporal or phylogenetic relationships associated with the metal concentration fingerprints of the ascidians that formed part of this study. The PCA results showed that there were no statistically significant relationships between ascidian metal ion concentrations and either the collection year or the collection site of the ascidians. However, species from the family Didemnidae provided the clearest statistical evidence supporting a phylogenetic relationship between these ascidians and their hyperaccumulated metal ion profiles. Furthermore, these results suggested that ascidian species are indeed actively concentrating metal ions from the surrounding sea water and are not simply sinks for passively accumulated metal ions. Interestingly, the concentration of vanadium in the set of ascidians studied did not appear to correlate with any of the other metals accumulated by these ascidians suggesting that there is possibly a unique method employed for the accumulation of vanadium by ascidians. Chapter 4 investigated this possibility further after the nucleosides 4.10, 4.11, 4.13, 4.15, 4.17 and 4.40 were isolated from the vanadium accumulating ascidian Aplidium monile. Studies into the interactions between nucleosides and vanadyl are unfortunately rare and usually qualitative in nature with limited information provided about the stability or structures of the complexes formed. The vanadyl accumulating aplousobranch ascidians e.g. Aplidium monile dominated our study of Algoa Bay ascidians therefore providing us with the rationale to investigate the relatively little studied binding ability and stability of vandyl-nucleoside complexes. Potentiometric studies were conducted to determine the stability constants of complexes formed between the oxovanadium ion vanadyl (VO2+) and the commercially available nucleosides 4.10-4.14. The data afforded by this analysis clearly confirmed the complexity of the vanadyl/nucleoside complexation and suggested that guanosine (4.12) formed the most stable complex with oxovanadium ions. We were also able to establish a third protonation constant for the hydroxyl moiety in 4.12 with a logK 8.87 which has not been previously reported. Finally, Chapter 5 revisited the cytoxicity two Algoa Bay ascidians, Clavelina sp. and Atriolum marinense the extracts from which produced promising bioactivity results in previous studies against oesophageal cancer cells. The HP-20 fractionated extracts of Clavelina sp. and Atriolum marinense proved to be similalrly cytotoxic to breast cancer cells. With the exception for the 100% acetone(aq)fractions the NMR data for both species suggested that most active non polar fractions were dominated by what appeared to be structurally unremarkable fatty acid glycerides and as such were not pursued further. Purification of the 100% acetone(aq)fraction of A. marinense resulted in the isolation of a styrene trimer, 5.1, common to both ascidian extracts. The NMR simulation software WIN-DAISY was employed to confirm the structure of 5.1. Attempts to establish if 5.1 was an isolation artefact or a product of marine pollution were inconclusive
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  • Date Issued: 2016

Halogenated oxindole and indoles from the South African marine ascidian Distaplia skoogi:

  • Authors: Bromley, Candice L , Parker-Nance, Shirley , de la Mare, Jo-Anne , Edkins, Adrienne L , Beukes, Denzil R , Davies-Coleman, Michael T
  • Date: 2013
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/164918 , vital:41184
  • Description: The known 3,6-dibromoindole (1), 6-bromo-3-chloroindole (2) and 6-bromo-2-oxindole (3) were isolated from the marine ascidian (sea squirt) Distapia skoogi collected from Algoa Bay, South Africa. Standard spectroscopic techniques were used to elucidate the structures of 1-3. All three compounds were found to be moderately cytotoxic to metastatic MDA-MB-231 breast cancer cells.
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  • Date Issued: 2013

Measuring discrimination experienced by people with a mental illness

  • Authors: Brohan, Elaine , Thornicroft, Graham , Rüsch, Nicolas , Lasalvia, Antonio , Campbell, Megan , Yalçınkaya-Alkar, Özden , Lanfredi, Mariangela , Ochoa, Susana , Üçok, Alp , Tomás, Catarina , Fadipe, Babatunde , Sebes, Julia , Fiorillo, Andrea , Sampogna, Gaia , Paula, Cristiane Silvestre , Valverde, Leonadis , Schomerus, Georg , Klemm, Pia , Ouali, Uta , Castelein, Stynke , Alexová, Aneta , Oexle, Nathalie , Guimarães, Patrícia Neves , Sportel, Bouwina Esther , Chang, Chih-Cheng , Li, Jie , Shanthi, Chilasagaram , Reneses, Blanca , Bakolis, Ioannis , Evans-Lacko, Sarah
  • Date: 2022
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/302498 , vital:58202 , xlink:href="https://doi.org/10.1017/S0033291722000630"
  • Description: Background: The Discrimination and Stigma Scale (DISC) is a patient-reported outcome measure which assesses experiences of discrimination among persons with a mental illness globally. Methods: This study evaluated whether the psychometric properties of a short-form version, DISC-Ultra Short (DISCUS) (11-item), could be replicated in a sample of people with a wide range of mental disorders from 21 sites in 15 countries/territories, across six global regions. The frequency of experienced discrimination was reported. Scaling assumptions (confirmatory factor analysis, inter-item and item-total correlations), reliability (internal consistency) and validity (convergent validity, known groups method) were investigated in each region, and by diagnosis group. Results: 1195 people participated. The most frequently reported experiences of discrimination were being shunned or avoided at work (48.7%) and discrimination in making or keeping friends (47.2%). Confirmatory factor analysis supported a unidimensional model across all six regions and five diagnosis groups. Convergent validity was confirmed in the total sample and within all regions [ Internalised Stigma of Mental Illness (ISMI-10): 0.28–0.67, stopping self: 0.54–0.72, stigma consciousness: −0.32–0.57], as was internal consistency reliability (α = 0.74–0.84). Known groups validity was established in the global sample with levels of experienced discrimination significantly higher for those experiencing higher depression [Patient Health Questionnaire (PHQ)-2: p more than 0.001], lower mental wellbeing [Warwick-Edinburgh Well-being Scale (WEMWBS): p is less than 0.001], higher suicidal ideation [Beck Hopelessness Scale (BHS)-4: p is less than 0.001] and higher risk of suicidal behaviour [Suicidal Ideation Attributes Scale (SIDAS): p is less than 0.001]. Conclusions: The DISCUS is a reliable and valid unidimensional measure of experienced discrimination for use in global settings with similar properties to the longer DISC. It offers a brief assessment of experienced discrimination for use in clinical and research settings.
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  • Date Issued: 2022

Explanation of the geological map of the country east of Kariba

  • Authors: Broderick, T J
  • Date: 1977
  • Subjects: Geology -- Kariba, Lake (Zambia and Zimbabwe) -- Maps , Geology -- Kariba, Lake (Zambia and Zimbabwe)
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5075 , http://hdl.handle.net/10962/d1014650
  • Description: The area covers part of the western end of the Zambezi Metamorphic Belt as it is known in Rhodesia. Most of the rocks are paragneisses of various ages that have suffered a long and complex history which has taken them into the highest facies of metamorphism and into the realm of granitization. Only the Karoo sediments of the Zambezi Valley are unaffected by these metamorphic events. From the scanty geochronological results obtainable from the north of Rhodesia, the history of this area started more than 2 500 million years ago. In the east and south-east of the mapped area are a group of highly migmatized granitic gneisses which represent a continuation westwards of similar rocks found in the area described in Bulletin 51 by Wiles (1961}. These Urungwe Paragneisses are regarded as forrning the basement on which all other rocks in the area lie, although their relationship with the Basement Complex is unknown. Climatically Kariba is hot and humid. Mean summer temperatures average 30°C (86°F), with temperatures in October that often exceed 40°C (100°F). Away from the Lake the humidity decreases and the increased altitudes above the Escarpment have a cooling effect. The township's mean annual rainfall is 665 millimetres (26,2 inches), most of which falls in the months between November and February. Basically. the area is well timbered but population pressures in the tribal areas, and depredation by elephants elsewhere, have made serious inroads upon the natural vegetation. The gneissic terrain above the Escarpment is characterized by mufuti trees (Brachystegia boehmiz). The baobab (Adansonia digitata) is common in the larger river valleys and in the low-lying area surrounding the lake shore where it occurs together with mopane (Colophospermum mopane) and thick jessie bush. In the river valleys, trees typical of the Zambezi Valley are common and include the tamarind (Tamarindus indica), mumvey (Kigelia africana) and Steculia species. Buffalo beans (Mucuma coriacea) are not uncommon in grassy river-beds. Physiographically, the area can be subdivided into three distinct regions, all of which have a marked geological control. They are- (1) The fault-lined Gwembe trough which has subsequently been inundated by the waters of Lake Kariba to an average altitude of 487 metres (1 600 feet) above sea level since the completion of the dam across the upstream entrance to the Kariba Gorge in 1960. The fiat land that now forms part of the lake shore is underlain by sediments of Karoo age and these, in the mapped area, occupy the Charara and Gachegache Basins, that lie to the north and south respectively of the Msango Range. These fiat-lying areas give way sharply to the gneissic terrain of the Zambezi Metamorphic Belt along the fault-lined Zambezi Escarpment. (2) The northern boundary of the area and the Msango Range are underlain by metasediments of the Makuti Group. The relief is strongly influenced by the regional geological structure of these complexly folded rocks with resistant meta-arkose and quartzite forming the sharp ridges and metapelites occupying the valleys. The ridges and valleys trend eastwards in the Msango Range, but along the northern boundary they trend north-westwards. (3) The linear topographic features of the Makuti Group terrain give way southwards to the older gneisses along an abrupt scarp edge, the base of which is marked by the Tsororo River. This terrain of gneisses is very rugged and highly dissected above the Zambezi Escarpment until it flattens out, at about 900 metres (2 950 feet) above sea level, into the Urungwe Tribal Trust Lands. In the rugged country above the Escarpment, granulites of the Piriwiri Group stand out above the gneisses as steep-sided conical bills. The country rises in a series of fault-lined steps to its highest point, at Nyamangwe trigonometrical beacon, which stands at 1 336 metres (4 382 feet) above sea level.
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  • Date Issued: 1977

A production function for cricket: the South African perspective

  • Authors: Brock, Kelsey , Fraser, Gavin , Botha, Ferdi
  • Date: 2012
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/396007 , vital:69143 , xlink:href="https://hdl.handle.net/10520/EJC124240"
  • Description: Production functions are common to any productive activity. Although it may not appear obvious, cricket is no different. Production functions in cricket provide a wide range of information, utilised to enhance efficiency and maximize match success. Given these benefits, this study involved the derivation of a production function for the South African SuperSport Series and an analysis of technical efficiency. An econometric analysis was conducted on data from the 2004-2011 cricket seasons and it was concluded that the most optimal strategy for South African teams involved a combination of attacking batting and defensive bowling. Furthermore, South African teams had a relatively low variable substitutability and a high degree of technical efficiency.
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  • Date Issued: 2012

Sport consumption patterns in the Eastern Cape: cricket spectators as sporting univores or omnivores

  • Authors: Brock, Kelcey
  • Date: 2015
  • Subjects: Cricket -- South Africa -- Eastern Cape , Cricket -- Social aspects , Consumption (Economics) , Consumer behavior
  • Language: English
  • Type: Thesis , Masters , MCom
  • Identifier: vital:1115 , http://hdl.handle.net/10962/d1017534
  • Description: Since its inception, consumption behaviour theory has developed to account for the important social aspect that underpins or at least to some extent can be used to explain consumption behaviour. Modern consumption behaviour theory is anthropocentric in nature, with people and societal influence at the forefront of the theory. To date, empirical studies on consumption behaviour of cultural activities (for example, music and arts), entertainment and sport have used Bourdieu’s (1984) omnivore/univore theory to suggest that consumption of leisure activities is bound up in social ties. To date, no such investigation has been conducted in the context of sport in South Africa. The aim of the study therefore is to investigate whether South African cricket spectators are sporting omnivores or univores, thus, essentially investigating whether sports consumption behaviour in South Africa is bound up in social ties. A number of positive economic and social ramifications could result from gaining a holistic understanding of sports consumption behaviour in South Africa. Given these ramifications, the secondary goal of the research is to identify motives for consumers making specific sport consumption decisions, and determining whether certain characteristics can be attributed to these consumption decisions. Recommendations based on the findings of the research could help various stakeholders understand sports consumption patterns in South Africa, which could in turn lead to the realization of positive economic and social benefits. The study made use of a questionnaire, administered at four different limited overs cricket matches in the 2012/13 cricket season, to obtain a range of responses reflecting specific types of consumption behaviour as well as motives for consumption decisions of cricket spectators in the Eastern Cape. Using individual binary probit models and post estimation F-tests, the results indicate that consumption behaviour of sport within South Africa predominantly differs on the grounds of education and race. This suggests that there are aspects of social connotations underpinning sports consumption behaviour within South Africa
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  • Date Issued: 2015

Sport consumption patterns in the Eastern Cape: cricket spectators as sporting univores or omnivores

  • Authors: Brock, Kelcey , Fraser, Gavin C G , Botha, Ferdi
  • Date: 2016
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/69362 , vital:29508 , https://doi.org/10.4102/jef.v9i3.64
  • Description: Since its inception, consumption behaviour theory has developed to account for the important social aspects that underpin or at least to some extent explain consumer behaviour. Empirical studies on consumption behaviour of cultural activities, entertainment and sport have used Bourdieu’s (1984) omnivore/univore theory to investigate consumption of leisure activities. The aim of this study is to investigate whether South African cricket spectators are sporting omnivores or univores. The study was conducted among cricket spectators in the Eastern Cape at four limited overs cricket matches in the 2012/2013 cricket season. The results indicate that consumption behaviour of sport predominantly differs on the grounds of education and race. This suggests that there are aspects of social connotations underpinning sports consumption behaviour within South Africa.
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  • Date Issued: 2016

Adventures with abalone : aquaculture, poaching, and fishery restoration

  • Authors: Britz, Peter Jacobus, 1959-
  • Date: 2011
  • Language: English
  • Type: Text
  • Identifier: vital:583 , http://hdl.handle.net/10962/d1018943
  • Description: [From the text] Tonight I am going to tell you about my research on a another mollusc, the humble abalone. - In contrast with the highly evolved squid, this marine snail belonging to the ancient archeogastrod lineage which has a much simpler anatomy and lifestyle. It doesn’t posses a proper brain mass, only having 4 ganglia or nerves knots at the front end. Its two simple eye spots which detect light and dark, a tough shell and a large and extremely powerful foot muscle to adhere to rocks. This simple configuration has served well for over 100 million years.
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  • Date Issued: 2011

The nutritional requirements of Haliotis midae and development of a practical diet for abalone aquaculture

  • Authors: Britz, Peter Jacobus
  • Date: 1996
  • Subjects: Abalones -- Nutrition Abalone culture
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:5307 , http://hdl.handle.net/10962/d1005152
  • Description: The available literature on abalone nutrition was synthesised and the prospects for developing a complete pelleted dry feed for Haliotis midae evaluated. The similar body compositions, digestive structures, enzyme activity, acceptance of a wide variety of feed ingredients and comparable growth performance on formulated diets of various abalone species suggests that they have similar nutritional requirements. Abalone also appear to be similar to other farmed monogastric animals in that digestion is primarily extracelluar and they possess a large, muscular crop and stomach. Abalone energy metabolism is carbohydrate based. They are capable of digesting high levels of dietary protein but their ability to utilise fat is limited. Abalone have been shown to consume predictable amounts of dry feed which is efficiently converted into body weight. Efficiency indices of utilisation of formulated feeds, such as feed conversion ratio, protein efficiency ratio, net protein utilisation and apparent digestibility have been successfully applied to abalone. It was concluded that the prospects for developing complete diets for H. midae using a conventional animal feed science model were good. The ability of H. midae to utilise a range of proteins which had potential for inclusion in practical diets was investigated. Five protein rich ingredients, namely, casein, fishmeal, soya oil cake, Spirulina, and torula yeast, were fed to H. midae in semi-purified diets. Two algal diets, fresh Plocamium corallorhiza and dried Ecklonia maxima were fed as controls. Abalone fed on fishmeal and Spirulina based diets displayed significantly higher growth rates than diets containing soya oil cake, torula yeast, casein and E. maxima. Growth rates of abalone fed with P. corallorhiza were significantly lower than all other diets. All artificial diets yield lower feed conversion ratios (0.7-1.8) and higher protein efficiency ratios (3.3-6.5) ratios than the seaweed control diets (FCR = 2.8-3.4; PER = 2.2-3.0). The results indicated that fishmeal and Spirulina were the most suitable proteins for inclusion in practical diets for H. midae. The effect of protein level on growth rate and nutritional indices was evaluated by feeding starch bound, fishmeal based diets containing 27, 32, 37, 42 and 47% protein to juvenile H. midae. Weight gain was positively related to the level of dietary protein, increasing by 18% between 27% and 47% protein. Protein efficiency ratio declining from 3.2 to 2.3 with an increasing dietary protein content. Feed consumption rate was approximately 1% of body weight per day for all diets. Post-weaning abalone (ca. lOmm shell length, 0.2g) differed from larger juveniles (ca. 35mm, 8g) in their response to varying proportions of dietary protein and energy. The smaller animals appeared to have a lower protein requirement and poorer ability to utilise lipid than the larger juveniles. Proximate analyses revealed that the levels of protein, lipid and carbohydrate in abalone soft tissue increased with increasing dietary levels of these nutrients. Larger juveniles contained significantly higher levels of protein and carbohydrate, but lower levels of lipid, ash and moisture, than the smaller post-weaning abalone. The assimilation efficiency of [U-¹⁴C]-arginine by H. midae fed diets enriched with [U-¹⁴C]-arginine was only 0.45%. Furthennore, supplementation of diets with graded levels of crystalline arginine did not have any effect on growth rates. It was concluded that the prospects for defining the quantitative amino acid requirements of H. midae using crystalline amino acids are not promising. Rates of gastric evacuation and enzyme secretion were monitored in juvenile H. midae fed an extruded, fishmeal based dry feed. Gut fullness peaked 6h after feed was offered and the bulk of feed consumed was digested within 24 h. Enzyme secretion appeared to begin with the onset of feeding and continued for at least 6h after peak gut fullness was attained. Protease activity increased significantly following ingestion but amylase activity was maintained at a more or less constant level. A low level of lipase activity was observed suggesting that the ability of H. midae to digest fat is limited. The growth rate of H. midae fed an extruded, fishmeal based feed increased with increasing temperature between 12°C and 20°C. Between 20°C and 24°C a marked decline in growth rate accompanied by a deterioration in feed conversion and increased mortality was observed. Consumption of a dry pelleted feed was shown to be a function of body size and temperature. Based on these data a model which predicts a daily ration for H. midae was developed. The present study showed that H. midae efficiently utilises extruded dry feeds containing conventional feed ingredients. Although technical difficulties were encountered in measuring apparent digestibility, it was concluded that the prospects for developing practical diets according to established nutritional principles are promising.
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  • Date Issued: 1996

Environmental requirements for the hatchery rearing of African catfish Clarias Gariepinus (Pisces: Clariidae) larvae and juveniles

  • Authors: Britz, P J (Peter Jacobus), 1959-
  • Date: 1988
  • Subjects: Catfishes -- Africa , Fish culture , Clariidae , Clarias
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5188 , http://hdl.handle.net/10962/d1001964 , Catfishes -- Africa , Fish culture , Clariidae , Clarias
  • Description: Inadequate seed production has historically been a factor limiting the commercial culture of Clarias gariepinus. The need to determine the environmental requirements of larvae was identified, in order to facilitate their successful mass rearing in hatcheries. The effects of key environmental factors on the growth, survival and aspects of the behaviour of C. gariepinus larvae and juveniles were investigated under controlled conditions. A strong emphasis was placed on the interpretation of the observed responses in terms of the natural history of the animal. Larvae were obtained by artificially inducing and spawning feral adult broodfish. Larval growth rates were highest in the temperature range 26-33ºC, with a peak at 30ºC. Survival of larvae was high between 22 and 33ºC. The final temperature preferendum of juveniles, determined in a thermal gradient was 30ºC, and it was concluded that this temperature is probably optimal for most of the physiological processes of the animal. Larvae and juveniles displayed strong negative phototaxis. When reared under different photoperiod regimes, larval growth increased with longer dark periods, however a similar rate of mortality was recorded in all photoperiod treatments. The provision of cover was found to enhance larval growth under conditions of continual light (24L/OD), however under conditions of continual darkness (OL/24D) similar growth rates were recorded regardless of the presence or absence of cover. All growth rates in continual darkness (OL/24D) were higher than those in continual light (24L/OD), regardless of whether cover was provided or not. It was concluded that a OL/24D photoperiod is optimal for larval rearing. At salinities between 0 and 5% similar growth and mortality rates of larvae were recorded. At 7.5 % larval growth and survival rates were lower, and at 10 % all larvae died within 48 hours. The 96h-LCSO for unionised ammonia was found to be 2.3 mg/l. The cytological effects of unionised ammonia were evident as degenerative changes in the gill and liver tissues. In an investigation of tank hygiene, it was found that larval growth and survival rates were highest in tanks not cleaned at all. As the frequency of tank cleaning increased, the growth and survival rates of larvae decreased. When reared at densities ranging from 45-450/1, larval growth was found to be density dependent. A model of hatchery productivity (number larvae of standard size produced/time/vol.) was developed based on the density dependent nature of larval growth. The model predicts that maximum productivity, will be achieved at a rearing density of 1400/1. The high growth and survival rates obtained over a broad range of each environmental parameter investigated serve to explain how larvae survive and grow in their unstable floodplain habitat in nature. The broad environmental tolerances of C. gariepinus are of benefit with respect to the culture of larvae, as successful larval rearing is possible over a fairly wide range of environmental conditions.
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  • Date Issued: 1988

A comparison of the comfort properties, measured with a sweating manikin (WalterTM), of clothing containing different fibres

  • Authors: Britz, Lizaan
  • Date: 2017
  • Subjects: Textile chemistry Cotton fabrics , Cotton textiles
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: http://hdl.handle.net/10948/14752 , vital:27842
  • Description: The main objective of the present study was to determine the relative role and importance of worsted suiting fabric fibre blend vis-à-vis fabric structural parameters, on the comfort related properties of 12 clothing ensembles, each comprising a different man’s suit, but the same wool/nylon underwear and cotton shirt. To achieve the objective, the comfort related properties, namely thermal resistance (Rt) and water vapour resistance (Ret) and water vapour permeability index (Im), of the clothing ensembles, as determined by means of WalterTM, a thermal sweating fabric manikin, were subjected to multi-linear and multi-quadratic analysis, as dependent variables, with the various suiting fabric parameters, namely weight, thickness, density, porosity, air permeability and wool content, as independent variables. It was found that the multi-quadratic regression analysis was able to best explain the observed differences in the clothing ensemble comfort related properties, in terms of the differences in suiting fabric properties. The regression analyses were used to isolate and quantify the effects of the various fabric and fibre content variables on the above mentioned comfort related properties of the various clothing ensembles. This study indicated that the suiting fabric structural properties (notably air permeability), had a more significant influence than either fibre blend or suiting fabric, as measured on WalterTM, a thermal sweating fabric manikin.
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  • Date Issued: 2017

The use of Geographical Information Systems for the promotion of spatial cognition, spatial perspective taking and problem solving in school level geography

  • Authors: Britz, Hendrina Wilhemina
  • Date: 2013
  • Subjects: Geography -- Study and teaching -- South Africa -- Port Elizabeth , Geographic information systems -- South Africa -- Port Elizabeth
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:9579 , http://hdl.handle.net/10948/d1020298
  • Description: A question asked at the United States of America (USA) National Council for Geographic Education (NCGE) conference in 1967, namely, what learning does GIS allow that other ways do not and whether teaching GIS at school level is worth the time and effort required to implement it, remains largely unanswered. Literature searches suggest that little more has been done since 1967 to investigate the effectiveness of GIS in education, or that there are any findings to suggest that GIS is worth the time and effort to implement in schools. Internationally the implementation of GIS software and geo-spatial data in schools has been slow, and South Africa is no exception. The main reasons given for slow implementation internationally have included lack of resources, lack of training and lack of time. The majority of secondary schools that offer Geography in the Port Elizabeth Education District, South Africa, teach GIS theory without the use of GIS software and geo-spatial data. The purpose of this research was to elicit the perceptions of secondary school level Geography teachers and learners of the benefits, barriers and obstacles to implementing GIS software and geo-spatial data as a teaching strategy. As a focused exercise to investigate what learning using GIS allows that other ways do not, this study also investigated whether using GIS as a teaching and learning strategy enables the promotion of learners spatial cognition, spatial perspective taking and problem solving abilities better than traditional methods do. The findings are viewed through the lens of developing Crystallized Intelligence (Gc), Spatial Intelligence (Gv) and Fluid Intelligence (Gf), respectively. The study followed a concurrent transformative mixed methods design with pre-post testing and the use of crossover experimental and control groups to generate both qualitative and quantitative data. Questionnaires aimed at all secondary Geography teachers in the Port Elizabeth Education District were used to assess how GIS is taught in their schools and to evaluate their perceptions of the benefits and barriers of implementing GIS software and geo-spatial data in the classroom. Four secondary school Geography teachers in four schools volunteered to take part in the experimental aspects of the study. Empirical data on the development of spatial cognition, spatial perspective taking, and problem solving were generated via pre- and post-tests in which the grade 11 Geography learners participated. Experimental and comparison groups of learners wrote four different types of pre- and post-tests where the experimental groups worked on GIS software with geo-spatial data while the comparison groups used traditional methods. Teacher interviews and learner interviews were also conducted to assess attitudes towards GIS software and geo-spatial data as a teaching strategy. The results from this aspect of the study mirrored the benefits and barriers to implementing GIS in schools recorded in international literature. However, and possibly more importantly, the empirical data generated by the learners revealed that GIS software and geo-spatial data do statistically significantly promote better spatial cognition (Crystallized Intelligence) and spatial perspective taking (Spatial Intelligence) than traditional methods do (i.e. using atlases, rulers and calculators). No improvement was found in the experimental groups‟ problem solving abilities. This report offers possible explanations and recommendations in terms of socio-cultural findings from other educational studies on the effects of exploratory talk on the development of Fluid Intelligence. Recommendations are made for the attention of curriculum developers, teachers, school principals, departmental officials and other educational stakeholders in terms of what is required for the successful implementation of GIS software and the use of geo-spatial data in secondary school Geography classes.
  • Full Text:
  • Date Issued: 2013

Knowledge levels of school learners before and after a life skills program on rape and child abuse

  • Authors: Britz, Cecelia Adonia
  • Date: 2005
  • Subjects: Rape -- Prevention , Child abuse -- Prevention , School children -- Life skills assessment -- South Africa -- Port Elizabeth
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: vital:11017 , http://hdl.handle.net/10948/360 , Rape -- Prevention , Child abuse -- Prevention , School children -- Life skills assessment -- South Africa -- Port Elizabeth
  • Description: Due to the early age at which children are exposed to rape and child abuse, preventative programs should be implemented as early as possible. Schools provide ample opportunity to reach learners of all ages. Educators have regular contact with learners and have a key role to play in the implementation of comprehensive health and education life skills programs. Non-Governmental Organisations (NGO) can link up with schools to combat abuse that affects children in South African communities. The Ubuntu Education Fund requested the Health and Development Research Institute (HDRI) of the University of Port Elizabeth to assist with the evaluation of the Mpilo-Lwazi life skills program for grade 6 to 9 learners at 5 primary and 5 secondary schools in the Nelson Mandela Metropole. The schools were selected by non-probability convenience sampling and the learners via simple random sampling. The life skills program addressed issues of HIV/AIDS, STI and rape and child abuse and the requested evaluation encompassed both the quantitative pretest-posttest assessment of knowledge plus a qualitative focus group assessment of perception of the content and presentation of the life skills program. A multiple pretest-post-test quasi-experimental research design was used. This study focused on the quantitative aspect of rape and child abuse and aimed to describe learners’ base line knowledge before receiving education in rape and child abuse life skills programs and acquired knowledge after the program had been implemented. Descriptive statistics were employed to describe the pre and post test information and the Hotelling’s T2 was used to identify variation in profiles. Posthoc t-tests established significant differences between grades. Structured questionnaires were used to achieve the aims of the research. Results of both the quantitative and qualitative findings were collated to be presented to the Ubuntu Education Fund. The results of the study were as follows: ix The results indicated that the overall level of knowledge regarding Rape and Child Abuse among the sample of grade six to nine learners was average. A small increase in knowledge was identified in the post-test. The area most successful for knowledge increase was the section relating to general information on the victims of Rape and Child Abuse. An area where knowledge actually decreased was that on reporting the rape or abuse. Knowledge of rape and child abuse alone is not sufficient to bring about change in behaviour. Changes in beliefs, such as increased awareness that rape and child abuse are prevalent in families and communities, and attitude change are necessary to facilitate the adoption of health-promoting behaviour. Future education efforts need to introduce health educators into the Rape and Child Abuse life skills program at schools in educating the learners. The format of teaching should also take into account the preferred method of presentation indicated by the learners as this would facilitate optimal intake of information.
  • Full Text:
  • Date Issued: 2005

An investigation into the competencies associated with change leadership : a case study analysis of an information technology organisation

  • Authors: Britton, Leola
  • Date: 2010
  • Subjects: Organizational change -- Management
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: vital:16138 , http://hdl.handle.net/10948/1227 , Organizational change -- Management
  • Description: In this research, the researcher-consultant together with the management corps of a merged IT organisation, embarked on a process of participative research with the aim to identify the competencies and skills that are required of the management-leadership corps to drive a process of change management and to ensure the organisation will be characterised by sustained growth and development. In using participative research methodology, qualitative data was mainly gathered through informal interviews and focus group sessions to identify the competencies and skills that are defined as important for the change manager-cum-leader role within the merged IT organisation. In addition, a matrix was compiled to enable each manager/leader to undertake a self-assessment of how capable they are in using the identified competencies and skills. The outcome of the assessment provided an indication of the areas of competencies and skills that through various interventions would enable the management-leadership corps to deal with the challenges of change, as well as to guide those that report to them through a process of change. While the management-leadership corps – referred to as the Executive, Senior, and Middle Management cohorts – all require enhancing their change management / leadership competencies and skills capability, it is the Middle Management cohort that is better equipped to perform their change management and leadership role. During the research, focus group sessions enhanced a participative methodology to enable identification of competencies important to the IT Company’s vision, mission and core values, as well as opportunity to identify interventions that will encourage an on-going process of change, growth and development. However, there is indication that the members of the Executive and Senior Management cohorts assessed themselves higher on those competencies that relate directly to their functionary roles, rather than the change management-leadership role. The scope of a treatise limits an in-depth and expanded research endeavour; however, the methodology used provided information on how a platform for participation in a change management process can be enabled. Furthermore, this research gives indication of how a management-leadership strata can ‘buy-in’ to the process of change, growth and development, commencing with the self and, which is aimed to encourage the same in those that share responsibility for sustained growth and development of the IT company. The research is also example of how an applied sociology endeavour can be undertaken.
  • Full Text:
  • Date Issued: 2010

Nonlinear optical studies of metallophtalocyanines and hemiporphyrazines in solution

  • Authors: Britton, Jonathan
  • Date: 2014
  • Subjects: Phthalocyanines Photochemistry Nanoparticles Nanostructured materials Polymers Quantum dots
  • Language: English
  • Type: Thesis , Doctoral , PhD
  • Identifier: vital:4464 , http://hdl.handle.net/10962/d1011608
  • Description: This thesis presents the study of the effects of CdTe-TGA quantum dots (QDs) on optical limiting ability of different phthalocyanine (Pc) complexes (5-12) containing Zn, Ga, In central metals and substituted with benzyloxyphenoxy, phenoxy, tertbutylphenoxy and amino groups in solution and in poly (methyl methacrylate) (PMMA) films. The optical limiting parameters of Pcs were higher for tertbutylphenoxy when compared to benzyloxyphenoxy and phenoxy substituents, in DMSO. Non-peripheral substitution decreased the optical limiting parameters. Third-order susceptibility (Im[χ⁽³⁾]/α) values of Pcs in the absence and presence of CdTe QDs were in the 10⁻¹² to 10⁻¹° esu cm range. Hyperpolarizabilities (γ) ranged from 10⁻³¹ to 10⁻²⁹ esu L for Pc alone or in mixture with QDs. The effect on the optical limiting abilities of twelve embedded phthalocyanines containing In, Ga, Zn and Al as central metals in polymer thin films was also examined. The effect of forming a covalent link zinc tetraamino phthalocyanine (12) with poly (methyl acrylic acid) (PMAA) and Zn (13) and OHAl (14) octacarboxy phthalocyanines to polyethylenimine (PEI) was also studied. The hyperpolarizability of the twelve phthalocyanines in polymer was found to be in the range of 10⁻²⁶ to 10⁻²⁴ esu.L. This is significantly higher than the hyperpolarizabilities of these phthalocyanines in solution. Non-linear optical (NLO) parameters were determined for phthalocyanine complexes containing In, Ga and Zn as central metals when embedded in PMMA polymer in the presence of quantum dots (QDs). The QDs mainly employed were CdTe-TGA (TGA = thioglylcolic acid). Triplet lifetimes increased as k (excited state (σex) to ground state (σg) absorption cross section ratio) values decreased with the addition of the CdTe-TGA to the phthalocyanines. The saturation energy density (Fsat) values were smaller in the films when compared to the solutions. Complex 7 tetrasubstituted with tert-butylphenoxy groups at non-peripheral positions was also studied in the presence of CdS-TGA, CdSe-TGA, fullerenes and single walled carbon nanotubes. There is a general improvement in optical limiting ability of Pc complexes in the presence of nanomaterials (NMs). Degradation studies seem to indicate that placing a phthalocyanine within a polymer thin film may protect it slightly from photo- and thermal degradation. 3(4), 15(16)-Bis-(4 -tert-butyl-phenoxy)-10, 22-diaminohemiporphyrazinato chloroindium hemiporphyrazine was synthesized from 1, 3, 5-triaminobenzene and 4-tert-butyl-phenoxyisoindoline. The structure of the complex was confirmed using mass, nuclear magnetic resonance and infrared spectroscopies. The nonlinear parameters of the compound was also analyzed in dimethylformamide and found to be significantly greater than previously analyzed phthalocyanines.
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  • Date Issued: 2014

Improvement of nonlinear optical properties of phthalocyanine bearing diethyleneglycole chains

  • Authors: Britton, Jonathan , Martynov, Alexander G , Oluwole, David O , Gorbunova, Yulia G , Tsivadze, Yulia G , Nyokong, Tebello
  • Date: 2016
  • Subjects: To be catalogued
  • Language: English
  • Type: text , article
  • Identifier: http://hdl.handle.net/10962/239812 , vital:50769 , xlink:href="https://doi.org/10.1142/S1088424616501042"
  • Description: This paper reports the successful synthesis of the low symmetry phthalocyanines: metal-free 2,3-bis[2′-(2′′-hydroxyethoxy)ethoxy]-9,10,16,17,23,24-hexa-nn-butoxyphthalocyanine 1H22 and its zinc complex 1Zn along with their nonlinear optical (NLO) behavior in solution and in thin films. 1H NMR investigations evidenced of higher dissymmetry of electronic density in 1H22 in comparison with 1Zn. This dissymmetry is responsible for unusually higher values of Im[χ(3)χ(3)]/αα, βeffβeff, and γγ for 1H22in contrast to 1Zn, where the notable effect of heavy-metal enhancement of ISC was expected. Both compounds showed Im[χ(3)χ(3)]/αα values of the order of 10−11−11 in chloroform which are higher in comparison to the symmetrical octabutoxyphthalocyanine H2[(BuO)8Pc]. NLO properties of 1H22 were improved via its incorporation into polycarbonate polymeric matrix together with CdSe@CdS-TOPO quantum dots. In such composite the value of Im[χ(3)χ(3)]/αα was almost three times higher in comparison with 1H22 solution in chloroform. The obtained composites are expected to be perspective components of optical materials, capable of protection against strong light irradiation
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  • Date Issued: 2016

Photophysical studies of zinc and indium tetraaminophthalocyanines in the presence of CdTe quantum dots

  • Authors: Britton, Jonathan
  • Date: 2010
  • Subjects: Indium , Zinc , Quantum dots , Phthalocyanines , Photochemotherapy , Nonlinear optics , Nanocrystals
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4332 , http://hdl.handle.net/10962/d1004993 , Indium , Zinc , Quantum dots , Phthalocyanines , Photochemotherapy , Nonlinear optics , Nanocrystals
  • Description: CdTe QDs capped with mercaptopropionic acid (MPA) and thioglycolic acid (TGA) were covalently linked to zinc and indium tetraaminophthalocyanines (TAPcs) using N-ethyl-N(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxy succinimide (NHS) as the coupling agents. The results presented give evidence in favour of formation of an amide bond between the MTAPc and CdTe QDs. Both the linked ZnTAPc–QD complexes and the mixture of QDs and ZnTAPc (without chemical linking) showed Förster resonance energy transfer (FRET), though the linked showed less FRET, whereas the QD interactions with InTAPc yielded no evidence of FRET. Both MTAPcs quenched the QDs emission, with quenching constants of the order of 103–104M−1, binding constants of the order of 108-1010M-1 and the number of binding sites for the MTAPc upon the QD being 2. High energy transfer efficiencies were obtained (in some cases as high as 93%), due to the low donor to acceptor distances. Lastly, both MTAPc were shown to be poor optical limiters because their imaginary third-order susceptibility (Im[χ(3)]) was of the order of 10-17-10-16 (optimal range is 10-9-10-11), the hyperpolarizability (γ) of the order of 10-37-10-36 (optimal range is 10-29-10-34) and the k values were above one but below ten.
  • Full Text:
  • Date Issued: 2010
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