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Hydrothermal co-liquefaction of microalgae biomass and coal

  • Authors: Charlie, David
  • Date: 2015
  • Subjects: Microalgae -- Biotechnology Biomass chemicals , Biomass energy
  • Language: English
  • Type: Thesis , Masters , MTech
  • Identifier: http://hdl.handle.net/10948/50087 , vital:42035
  • Description: In this research, the objective was to investigate under the chosen liquefaction conditions whether co-liquefaction of coal and microalgae biomass as agglomerates does possess a distinct advantage over the individual liquefaction of microalgae and coal. This was initially done by preparing dry micro algal biomass, followed by the preparation of coal fines and finally coal-algae as agglomerates. The agglomerates were prepared by continuously adsorbing wet concentrated microalgae slurry/solution onto the dry coal fines in order to prepare different ratios of coal-algae agglomerate(s). Ultimate analysis of the starting material (coal fines and the microalgae) as well the agglomerates then followed. According to research, wet microalgae biomass has the potential of acting as a hydrogen donor. By preparing the agglomerates, the rationale was to promote hydrogen supply from the micro algal biomass that has high hydrogen content to the coal with lower hydrogen content. The resulting product was then expected to have fairly higher hydrogen content. However, this was not observed or evident from the elemental analysis results. The results (elemental composition) showed no difference between the agglomerates and the coal. Based on the observed ultimate analysis results, liquefaction experiments were conducted to determine whether hydrogen transfer and the expected synergistic effect between micro algal biomass and coal would occur. The crude oil product was recovered and simulated distillation technique was used for the characterization of the crude oil product. The results we in agreement that higher yields can be achieved during co-liquefaction as compared to the individual liquefaction. A possible synergistic effect that was investigated in this research existed. Liquefaction results provided evidence of higher yields recovery from the agglomerates compared to those of coal fines and microalgae biomass. Although there was higher recovery on the agglomerates, there appears to be a downward trend (decrease) in product recovery with higher loadings of micro algal biomass on to the coal. This means that higher loading of micro algal biomass tend to suppress liquefaction of coal, thus resulting in lower product recovery. While lower loadings tend to effectively facilitate the liquefaction of coal, thus proving that the proposed synergistic effect between the two does exist. Overall product recovery (yields) of the agglomerates is higher compared to the individual recovery of coal fines and microalgae biomass. This was followed by mass balancing to determine the overall conversion. Higher conversions were achieved on the agglomerates compared to coal. This could mean that microalgae have the potential to facilitate the liquefaction of coal and improve its conversion. The observed trend results in improved conversion as well as higher oil yields (simulated distillation results). Overall, the mass balancing provided insightful information regarding the coal-microalgae interaction based on the conversion, and this further corresponds or supports the simulated distillation results. This research paper provides evidence of the synergistic effect that exists between micro algal biomass and coal.
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  • Date Issued: 2015

Sedimentological and geochemical investigations on borehole cores of the Lower Ecca Group black shales, for their gas potential : Karoo basin, South Africa

  • Authors: Chere, Naledi
  • Date: 2015
  • Subjects: Sediments (Geology) -- South Africa , Gas reservoirs -- South Africa , Natural gas reserves -- South Africa
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10679 , http://hdl.handle.net/10948/d1021201
  • Description: In the recent years, the shale gas discourse has become central to discussions about future energy supply in South Africa. In particular, the Permian black shales of the Lower Ecca Group formations in the Karoo Basin are considered potential source rocks for shale gas. The research presented in this thesis advances the understanding of the shale gas potential of mainly the Prince Albert, Whitehill and Tierberg/Collingham Formations. These shale sequences were sampled from eight deep boreholes spread across the main Karoo Basin and geochemically analysed at the GFZ - Helmholtz Centre Potsdam, Germany. Three key questions guided the study, these are: (i) what is the lithology of the sequence; (ii) where in the basin do the shale sequences attain maximum thickness at optimum depth i.e. beneath 1000-1500m; and (iii) and their shale characteristics. To evaluate these, borehole core logging, petrology and organic geochemistry were used extensively. Petrology involved the use of thin section, scanned electron and transmission electron microscopy for mineralogy as well as the identification of sedimentary features, organic matter and nano-scale porosity. These were coupled with standard organic geochemistry techniques such as Rock Eval. analysis, open pyrolysis gas chromatography and thermovaporisation to quantify the free gas, total organic carbon (TOC), present-day gas generative potential and kerogen type. The results show that the Whitehill Formation, away from the CFB and not intruded by dolerite, has the most potential for shale gas. Microscopic studies of this pyritic black shale reveal the occurrence of porous amorphous matter, indicating thermal maturity within the gas generation zone (i.e. > 1.1 percent Ro, 120ºC). The TOC content is consistently high within the Whitehill (exceeding industry requirement of 2 percent), attaining maximum of 7.3 percent. The highest yields of free and desorbed gas, especially methane, were emitted within this formation (S1 and nC1 peaks); mostly within its dolomitic units. In addition, dissolution porosity within dolomite units of the Whitehill Formation was identified as the predominant type of porosity. Thus, it is deduced that the dolomitic units of Whitehill Formation potentially contain the greatest volumes of free gas. HI values attain maximum of 25 mg HC/g TOC, whereas the OI values 26 mg CO2/g TOC. Such low HI and OI values are typically attributed to the dominance of Type IV kerogen, and consistent with overmaturity. Open pyrolysis (GC) show the main the chemical compound of the organic matter to be m-p-xylene, consistent with a mix of Type III, Type I/II and Type IV kerogen. Lithologically, the Whitehill Formation is composed of ~ 35 quartz, 13 percent feldspar, 26 percent illite and ~ 23 percent dolomite with variable amounts of pyrite. The dominance of quartz is directly proportional to the brittleness of the rock. Thus it can be deduced that the Whitehill Formation is relatively brittle and therefore fraccable. Burial trends indicate increasing depth (from ground level) to the top of the Whitehill Formation towards the south and south-eastern portion of the basin. It is in the southern region where thicknesses of this black shale exceeding 50m occur at depths more than 1500m; 1000m beneath fresh water aquifers. It therefore concluded that Whitehill Formation in the southern portion of Karoo Basin, but away from the thermo-tectonic overprint of the Cape Orogeny, is the most probable shale gas reservoir in South Africa.
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  • Date Issued: 2015

Engaging within zones of proximal development on Facebook : the case of using Facebook to support learning and mentoring on a NQF Level 5 environmental education, training and development practices learnership

  • Authors: Chetty, Preven
  • Date: 2015
  • Subjects: Social media -- Study and teaching (Higher) -- South Africa , Internet in education , Online social networks , Organizational learning , Employees -- Training of , Group work in education
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: vital:2024 , http://hdl.handle.net/10962/d1017335
  • Description: This study focuses on two roll-outs of a, year-long National Qualification Framework (NQF) level 5, environmental education learnership in South Africa and attempts at enhancing collaborative learning at workplaces using a familiar social networking site called Facebook. This study uses the Facebook group sites created for the workplace course component of the course as one of the means of data collection. Additional interviews and focus groups with learners and administrators on both Environmental Education Training and Development Practices (EETDP) courses also informed the study. The study is located within the context of the rise of the information age, its effects on socio-ecological landscape at large and ways of using social networking sites in order to facilitate scaffolding and meaning making within zones of proximal development for environmental education learnerships. It also looks at the model of apprenticeship and workplace based learning as it is broadly located at the nexus of the SAQA-led academic inquiry into workplace based learning and professional development. It was found that the use of Facebook on the EETDP learnership allowed for collaborative learning to take place between peer to peer interactions as well as between tutors and learners. It was also noted that scaffolding processes requires both technical assistance and strong instructional input from course tutors. One of the most important findings in terms of collaborative learning and engaging within the Zone of Proximal Development (ZPD) was that learners were able to communicate more effectively and freely with both fellow learners and tutors on course after participating on the Facebook group sites. The study offers recommendations on how a social networking platform like Facebook can be utilised effectively for environmental education. The study recommends that scaffolding of workplace based tasks and concepts needs to be better integrated with the course and in both online and offline interactions between learners. It also illustrates how social networking sites can become powerful tools for creating meaning making when combined with course work.
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  • Date Issued: 2015

An empirical study on staff turnover and retention within Eskom : Eastern Cape Operating Unit

  • Authors: Chibba, Rajesh Chagan
  • Date: 2015
  • Subjects: Eskom (Firm) , Labor turnover -- South Africa -- Eastern Cape , Employee retention -- South Africa -- Eastern Cape , Job satisfaction -- South Africa -- Eastern Cape , Career development -- South Africa -- Eastern Cape
  • Language: English
  • Type: Thesis , Masters , MBA
  • Identifier: vital:847 , http://hdl.handle.net/10962/d1017514
  • Description: This research paper is broken up into three sections, namely an evaluation report, a literature review and a description of the research methodology. The evaluation report section is an assessment of the factors that could contribute to staff leaving the organisation and why staff would choose to remain with the organisation. The Distribution Division of Eskom is divided into nine separate Operating Units (OU's), in line with the nine Provinces. According to an Eskom Human Resource Manager (Mjali, 2013), as at March 2012 there were 2231 employees in the Easter Cape Operating Unit, while the staff turnover for the same period was 4.53%. Of the 101 staff that had resigned for the period 01 April 2011 to 31 March 2012, there were 27 transfers, 26 resignations and 30 retirements. The balance of 18 staff that left was due to dismissals and deaths. While the statistics suggest a healthy level of staff turnover at present, given the current pressures that Eskom employees are under, it is important to investigate their future intentions and to see what Eskom can do to continue to retain their services. The literature relating to staff turnover and retention was examined to determine the meaning of the terms retention and turnover and to review the relevant turnover topics that were emerging from the exit interview data. The research conducted was quantitative in nature, and a questionnaire was distributed to all managerial staff within the Eastern Cape Operating Unit of Eskom. The questionnaire was sent electronically to the participants via email with the link to the questionnaire. Participants were requested to respond on questions relating to factors on turnover and retention, and the responses were used to assess employee's intention to either remain with the organisation or to leave. The feedback received was analysed with the use of data analysis in Microsoft Excel (2010). The results of the research showed that there were two distinct themes related to employees' intention to remain with the organisation, namely job satisfaction and career development. On the other end of the scale, themes which would cause staff to want to leave the organisation were the performance management system of the organisation, not being listened to (i.e. to the ideas and views of staff) and leadership (i.e. the way the organisation was being led). Recommendations are made to management. The study also recommends future research that can be done to get greater insight into factors relating to staff turnover and retention. A detailed review of the literature is included in Section two of the report. Only essential components of the literature are included in Section one of report. Section three of the report provided a detailed description of the research design and the research procedure that was followed.
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  • Date Issued: 2015

The regulation of agricultural subsidies in the World Trade Organization framework : a developing country perspective

  • Authors: Chigavazira, Farai
  • Date: 2015
  • Subjects: Foreign trade regulation -- Developing countries Agricultural laws and legislation -- Developing countries Tariff on farm produce -- Developing countries
  • Language: English
  • Type: Thesis , Masters , LLM
  • Identifier: http://hdl.handle.net/10353/1874 , vital:27569
  • Description: The Agreement on Agriculture (AoA) was adopted to eliminate the illegitimate use of tradedistorting agricultural subsidies and thereby reduce and avoid the negative effects subsidies have on global agricultural trade. However, the AoA has been fashioned in a way that is enabling developed countries to continue high levels of protectionism through subsidization, whilst many developing countries are facing severe and often damaging competition from imports artificially cheapened through subsidies. The regulation of subsidies in the World Trade Organisation (WTO) has been a highly sensitive issue. This is mainly due to the fear of compromising food security especially by developed countries. Developing countries have suffered negatively from the subsidy programmes of developed countries who continue to subsidize their agricultural sector. This position of the developing countries in the global trade system which has been described as weak, has drawn criticism that the WTO as it currently operates does not protect the interests of the weak developing nations, but rather strengthens the interests of the strong developed nations. The green box provisions which are specifically designed to regulate payments that are considered trade neutral or minimally trade distorting has grossly been manipulated by developed countries at the mercy of the AoA. Developed countries continue to provide trade distorting subsidies under the guise of green box support. This is defeating the aims and objectives of the AoA. The study examines the regulation of WTO agricultural subsidies from the developing countries’ belvedere. It looks at the problems WTO member states face with trade distorting subsidies, but focuses more on the impact these have on developing states. It scrutinizes the AoA’s provisions regulating subsidies with a view to identify any loopholes or shortcomings which undermine the interests and aspirations of developing countries. This is behind the background that some of the provisions of the AoA are lenient towards the needs of developed countries at the expense of developing countries.
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  • Date Issued: 2015

Understanding the poverty-reducing livelihoods of child support grant caregivers in Riebeeck East, South Africa

  • Authors: Chikukwa, Vimbainashe
  • Date: 2015
  • Subjects: Archer, Margaret Scotford -- Political and social views , Child caregivers -- South Africa -- Riebeek-Oos , Public welfare -- South Africa -- Riebeek-Oos , Grants-in-aid -- South Africa -- Riebeek-Oos , Poverty -- South Africa -- Riebeek-Oos , Critical realism , South Africa -- Social conditions -- 1994- , South Africa -- Economic conditions -- 1991-
  • Language: English
  • Type: Thesis , Masters , MSocSc
  • Identifier: vital:3393 , http://hdl.handle.net/10962/d1018196
  • Description: In 1994, racial domination in the form of apartheid ended in South Africa and the first postapartheid government was elected through a non-racial and democratic franchise. The new government inherited an entrenched system of racial inequality as well as widespread poverty amongst the formerly oppressed population, and it sought to address these challenges through policies of redistribution based on a new progressive constitution which emphasised the realisation of socio-economic rights. At the same time, and despite its redistributive measures, the post-apartheid government has pursued a macro-economic strategy with pronounced neoliberal dimensions. One of its critical redistributive measures focuses on social assistance to poor blacks, and this has entailed the construction and expansion of a massive social grant system including the child support grant which is received by millions of black South Africans on a monthly basis. The objective of this thesis is to examine and understand the livelihoods of child support grant recipients (or caregivers) in the context of conditions of extreme vulnerability marked by poverty. It does so by focusing on the small town of Riebeek East located in the Eastern Cape Province of South Africa. Though undoubtedly child support grant caregivers are victims of poverty, the thesis demonstrates that they are not without agency. They exist in structural conditions of vulnerability and poverty, but they nevertheless seek to manoeuvre and negotiate their way in and through their conditions of existence. This does not necessarily alleviate their poverty in any significant manner but it does show evidence of reflexivity, decision-making and responsibility in the pursuit of livelihood practices and outcomes. In making this argument, I draw upon the mega-theory of Margaret Archer (specifically, her morphogenetic approach) and the more middle-level perspective of the Sustainable Livelihoods Framework. Beyond contributing to the prevailing academic literature on the child support grant in South Africa, this thesis also hopefully makes a small contribution to controversies about structure and agency within sociology.
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  • Date Issued: 2015

The design of a new opera house for central, Port Elizabeth

  • Authors: Chilton, Marc John
  • Date: 2015
  • Subjects: Theaters -- South Africa -- Port Elizabeth -- Designs and plans Centers for the performing arts -- South Africa -- Port Elizabeth , Theater architecture -- South Africa -- Port Elizabeth
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: http://hdl.handle.net/10948/15356 , vital:28224
  • Description: Urban decentralization and inner city decay is a ubiquitous phenomenon of social and economic circumstance. The rise of sub-urban sprawl around new centres has encouraged urban degeneration and produced unsustainable cities, particularly in South Africa. Consequently, the loss of cultural assets in decaying historic centres, specifi cally in Port Elizabeth, reveals issues pertinent to loss of place and heritage. In combatting urban degeneration, the utilization of culture and the arts has proven to be a powerful rejuvenation strategy. The vision of the Mandela Bay Development Agency, and similar successful global precedents, suggest that a cultural precinct could effectively tackle urban decay in the historic core. This premise guides the proposal.The principal aim of this treatise is the design of a new Opera House acting as a catalyst for the proposed cultural district, based on the inner-city rejuvenation of Central. This aim is achieved by several objectives, which are explored in an effort to unveil potential and appropriate design responses: An investigation of the Opera House typology, which uncovers its dignity, vitality and signifi cance within past and present cities; An exploration of context, which reveals the opportunities to transform identity and urban cultural practise; Research into technical, spatial and physical demands of the program provide depth and root the design responses in reality. As a result, the Opera House sits as a gateway building into the precinct, as well as a cultural and physical landmark within the city. A duality of expression presents both a contrast and self-similarity in the historic context, simultaneously rooting the building in place while conveying a unique character.
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  • Date Issued: 2015

Ni(II) and Pb(II) dithiocarbamate complexes as precursors for the synthesis of HDA-capped NiS and PbS nanoparticles

  • Authors: Chintso, Thobani
  • Date: 2015
  • Language: English
  • Type: Thesis , Masters , MSc (Chemistry)
  • Identifier: vital:11349 , http://hdl.handle.net/10353/d1020201
  • Description: Ni(II) and Pb(II) dithiocarbamate complexes were synthesized and characterized by elemental analysis, UV-Vis, FTIR and TGA and some of the Ni(II) complexes and one Pb(II) were further analyzed by 1H-NMR and 13C-NMR spectroscopy. Generally all the dithiocarbamate ligands are soluble in water while the complexes were soluble mostly in solvents such as chloroform, toluene, DMSO and DCM. Based on the elemental analysis, the dithiocarbamate complexes are formulated as four coordinate (tetrahedral or square planar) compounds. However, the FTIR showed that each of the dithiocarbamate ligands acted as bidentate ligand through two sulfur atoms. The TGA of the most complexes showed one major decomposition step to give respective metal sulfide above 200 oC. In this research project, dithiocarbamate complexes were used as single source precursor for the synthesis of metal sulfide nanoparticles. We studied the optical and structural properties of metal sulfide nanoparticles using UV-Vis, photoluminescence (PL), powder X-ray diffraction (XRD), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The absorption spectra of the metal sulfide nanoparticles are blue shifted in respect to bulk material and they also showed broad emission. The XRD of the NiS nanoparticles were indexed to the cubic and rhombohedral phase, with crystallite sizes of 15 - 18 nm. The XRD of PbS nanoparticles were indexed to the face centered cubic and cubic rock salts, with the crystallite sizes 12 - 18 nm. The TEM images of the metal sulfide nanoparticles showed particles with spherical and rectangular shapes with crystallite sizes 4 - 35 nm.
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  • Date Issued: 2015

Eliciting and combining expert opinion : an overview and comparison of methods

  • Authors: Chinyamakobvu, Mutsa Carole
  • Date: 2015
  • Subjects: Decision making -- Statistical methods , Expertise , Bayesian statistical decision theory , Statistical decision , Delphi method , Paired comparisons (Statistics)
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5579 , http://hdl.handle.net/10962/d1017827
  • Description: Decision makers have long relied on experts to inform their decision making. Expert judgment analysis is a way to elicit and combine the opinions of a group of experts to facilitate decision making. The use of expert judgment is most appropriate when there is a lack of data for obtaining reasonable statistical results. The experts are asked for advice by one or more decision makers who face a specific real decision problem. The decision makers are outside the group of experts and are jointly responsible and accountable for the decision and committed to finding solutions that everyone can live with. The emphasis is on the decision makers learning from the experts. The focus of this thesis is an overview and comparison of the various elicitation and combination methods available. These include the traditional committee method, the Delphi method, the paired comparisons method, the negative exponential model, Cooke’s classical model, the histogram technique, using the Dirichlet distribution in the case of a set of uncertain proportions which must sum to one, and the employment of overfitting. The supra Bayes approach, the determination of weights for the experts, and combining the opinions of experts where each opinion is associated with a confidence level that represents the expert’s conviction of his own judgment are also considered.
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  • Date Issued: 2015

Perceived undersupply of local labour in the presence of unemployment: a case of selected Sundays River Valley citrus farms, 2013

  • Authors: Chirara, Malon Tinotenda
  • Date: 2015
  • Subjects: Unemployment -- South Africa -- Sundays River (Eastern Cape) , Citrus fruit industry -- South Africa -- Sundays River (Eastern Cape) , Labor market -- South Africa -- Sundays River (Eastern Cape) , Work environment -- South Africa -- Sundays River (Eastern Cape) , Agricultural wages -- South Africa -- Sundays River (Eastern Cape) , Agricultural laborers -- South Africa -- Sundays River (Eastern Cape) , Seasonal labor -- South Africa -- Sundays River (Eastern Cape) , Migrant agricultural laborers -- South Africa -- Sundays River (Eastern Cape) , Personnel management -- South Africa -- Sundays River (Eastern Cape)
  • Language: English
  • Type: Thesis , Masters , MCom
  • Identifier: vital:1125 , http://hdl.handle.net/10962/d1020367
  • Description: While skilled labour shortages are common in many countries, including South Africa, mainly due to a skills mismatch, the undersupply of unskilled labour was less expected, especially in developing countries with high unemployment. The thesis utilises data on perceived worker undersupply on selected citrus farms in the Sundays River Valley (SRV), located in the Eastern Cape Province of South Africa, collected in 2013, to analyse why unemployed residents, surprisingly, do not fill up vacancies on farms. In contrast to other labour markets, farm employment is not restricted by educational levels and as workers reported, with little training the various job tasks and skills required are easy and quick to grasp. At a time the government is trying to find ways of reducing unemployment, and the SRV Municipality (2012:29) reported approximately 42% unemployment, the question arises as to why the relatively low educated residents do not take advantage of the employment opportunities on farms. According to local workers and unemployed residents, the farm job was unattractive largely because of a combination of two factors: perceived relatively low salaries partly caused by the availability of migrant seasonal workers accepting lower remuneration and poor non-wage working conditions. The survey also found that farmers preferred migrant workers because they were more productive compared to their local counterparts who were, reportedly, characterised by high absenteeism and laziness, caused mainly by a reliance on social grants and alcohol abuse. Other reasons given for the unattractiveness of the farm job included the seasonal nature of farm employment, which left workers with no source of income in the offseason, the redundancy associated with farm tasks, perceived poor treatment of workers and lack of information on UIF and Provident funds to farm workers. To address problems associated with the dislike of farm work, seasonality of on-farm employment and the reportedly relatively low income, farm managers, the local municipality and the Labour Department could possibly be involved in creating more communal agricultural projects and help provide local community members to venture into supporting alternative careers within the Hospitality, Ecotourism and Conservation Industries through training programmes. Farm managers may need to consider improving their working relationship with workers in communication and when assigning tasks. Farmers and the local municipality could also consider investing in training programmes for the unemployed residents to equip them with technical skills that can improve their chances of finding jobs.
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  • Date Issued: 2015

Efficiency evaluation of South Africa tertiary education institutions using data envelopment analysis

  • Authors: Chitekedza, Ignatious
  • Date: 2015
  • Subjects: Data envelopment analysis -- South Africa , Principal components analysis
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: http://hdl.handle.net/10948/4764 , vital:20674
  • Description: With an increasing number of students enrolling at higher education institutions in South Africa, it has become important to investigate whether these institutions are using their resources adequately. This study uses data envelopment analysis (DEA) to estimate the efficiency of 23 South African tertiary education institutions based on both teaching and research outputs. Using DEA we are able to rank South African universities according to their use of resources in these two areas. These rankings can identify institutions which are performing well and also those which require improvement. The effect that merging institutions has on this efficiency is also determined. Owing to the limited sample size, variable reduction techniques, including the efficiency contribution measure (ECM) and principal components analysis (PCA-DEA), were used to improve the discrimination of the analysis.
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  • Date Issued: 2015

An investigation into the perceptions of female academics on their career development: a comparative study of South African and Zimbabwean universities

  • Authors: Chitsamatanga, Bellita Banda
  • Date: 2015
  • Subjects: Career development -- Education (Higher) -- Africa , College teachers -- Africa , Universities and colleges -- Africa
  • Language: English
  • Type: Thesis , Masters , M Ed
  • Identifier: vital:16223 , http://hdl.handle.net/10353/d1019735 , Career development -- Education (Higher) -- Africa , College teachers -- Africa , Universities and colleges -- Africa
  • Description: This study investigated the perceptions of female academics on their career development in South African and Zimbabwean universities. The study attempted to unravel the story of the female academics which must be heard but is seldom accorded the space within the academia. The interpretive paradigm was utilised in this study because it focuses on individual perceptions and experiences. In addition a qualititative approach was employed for the collection of data since it allowed for triangulation of data collection techniques so as to gain in-depth and rich information on the career trajectory of female academics in South African and Zimbabwean universities. Therefore, semi-structured interviews, focus group interviews and document analysis were employed. The participants were purposively selected for the sample of this study and comprised of 5 senior female academics from each university and 5 junior female academics also representing each university respectively. Thematic content analysis was used to analyse data and this was carried out in line with the research questions, aims and objectives of the study. Through the participants' answers from both universities under study, a transcript was formulated, coded and categorised in view of the career development of female academics in South African and Zimbabwean universities. It was discovered from the data that the female academics still encounter a number of challenges with regard to their career mobility both in and out of academia inter alia, (1) gender stereotyping and male domination (2) knowledge retention (3) lack of mentorship and organisational support especially through funding and professional staff development programmes (4) lack of female solidarity (5) under-representation of female academics (6) teaching workloads and research publications and (7) lack of family support, were illuminated by the participants as common fixtures that hinder their career development in academia. Moreover, there were variances in both universities under study especially with relations to funding, gender policies in place and male domination. Consequently, the above mentioned factors were more pronounced in Zimbabwean universities than in South African universities. As a result, emphasis was that both South African and Zimbabwean universities have to draw a line between theory and practice especially on the professional staff development programmes that are offered to the academics. A crucial observation was made by the researcher on how most of the participants from both universities under study had negotiated their roles as mothers, wifes, academic and sisters in a bid to realise career growth, such that striking a balance between work and family posed a continuous hindrance their career development. As a result, hard work, commitment, confidence, self-assertiveness and sacrifice cut across both universities as strategies used if the battle of career development of female academics had to be won. In sum, this study attempted to illuminate the perceptions and experiences of female academics and what it means to be a female academicin the 21st century universityn and why there is a need to create, cultivate and have a conducive and supportive working environment. Moreover, promotion of knowledge expansion and sharing, gender equity and equality needs to be employed by both universities under research. Additionally, the professtional staff development programmes offered need to be conducted by qualified and experienced personnel in a bid to avoid repetition of workshops and training programs. Furthermore, formalisation of mentoring and role modelling should also be employed by South African and Zimbabwean universities. Lastly, the study recommended that there is a need for universities source out resources for its academics if there are to produce well rounded scholars who will be able to experience career development.
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  • Date Issued: 2015

Conscientious objection and South African medical practitioners' constructions of termination of pregnancy and emergency contraception

  • Authors: Chiwandire, Desire
  • Date: 2015
  • Subjects: Abortion -- South Africa , Abortion -- Moral and ethical aspects -- South Africa , Emergency contraceptives -- South Africa , Contraception -- Moral and ethical aspects -- South Africa , Medical personnel -- Attitudes -- South Africa , Patients -- Legal status, laws, etc. -- South Africa , Reproductive rights -- South Africa , Women's rights -- South Africa , Liberty of conscience
  • Language: English
  • Type: Thesis , Masters , MSocSc
  • Identifier: vital:2888 , http://hdl.handle.net/10962/d1017863
  • Description: Aim: The 1996 Choice on Termination of Pregnancy Act decriminalized abortion in South Africa and the South African Medicines Control Council in 2000 approved the dispensing of emergency contraceptive methods by pharmacists to women without a doctor's prescription. This legislation has been hailed as among the most progressive in the world with respect to women's reproductive justice. However the realisation of these rights in practice has not always met expectations in part due to medical practitioners' ethical objections to termination of pregnancy and the provision of related services. The aim of this study was to interpret the varying ways in which medical practitioners frame termination of pregnancy and emergency contraceptive services, their own professional identities and that of their patients/clients. Methods: Sample of 58 doctors and 59 pharmacists drawn from all nine provinces of South Africa. Data collected using an anonymous confidential internet-based self-administered questionnaire. Participants were randomly recruited from online listings of South African doctors and pharmacists practicing in both private and public sectors. Data were analysed using theoretically derived qualitative content analysis. Results: Participants drew on eight frames to justify their willingness or unwillingness to provide termination-of-pregnancy related services: the foetal life frame, the women's rights frame, the balancing frame, the social justice frame, the do no harm frame, the legal and professional obligation frame, the consequences frame and the moral absolutist frame. Conclusion: Health professionals' willingness or unwillingness to provide termination of pregnancy related services is highly dependent on how they frame or understand termination of pregnancy, and how they understand their own professional identities and those of their patients/clients.
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  • Date Issued: 2015

Political communication: a case study of the Democratic Alliance and its use of digital media in the 2014 South African General Elections

  • Authors: Chong, Sandra Pow
  • Date: 2015
  • Subjects: Communication -- Political aspects -- South Africa Mass media -- Political aspects -- South Africa Political campaigns -- South Africa
  • Language: English
  • Type: Thesis , Masters , MA
  • Identifier: http://hdl.handle.net/10948/11416 , vital:26923
  • Description: Political organisations are now using a two-way path of communication thanks to the development of technological platforms that work in-sync with the internet to allow this to happen. Information can now flow across new networks to allow exchanges from the many to the many. This study sets out to explore the use of social media by political organisations as a means of political communication. A case study was conducted which focussed on online communication used by the Democratic Alliance in the 2014 General Elections in South Africa. The social media strategies adopted by the Democratic Alliance was examined. Reference is made to the 2008 Obama Campaign. The study revealed that the DA primarily made use of two-way asymmetrical communication despite the party posting a lot of consistent information and content; however in response to many questions and comments posted on the social media fora by online users, the DA only selectively responded to a handful of these.
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  • Date Issued: 2015

Love in a cold war

  • Authors: Christenson, Anna
  • Date: 2015
  • Subjects: South African fiction (English) -- 21st century
  • Language: English
  • Type: text , Thesis , Masters , MA
  • Identifier: vital:5988
  • Description: A collection of short stories in two parts written in realist and fabulist styles. The first part looks at the post-war generation of baby boomers growing up in the American Midwest. The second half follows an American abroad and explores themes of disintegration, the shifting power balance in relationships and the terrible hole at the core of expatriate identity.
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  • Date Issued: 2015

A geoscientific framework for the proposed site of South Africa's second nuclear power plant: Thyspunt, Eastern Cape

  • Authors: Claassen, Debbie
  • Date: 2015
  • Subjects: Geology, Structural -- South Africa -- Eastern Cape , Geology, Stratigraphic , Geochemistry , Rock mechanics
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:10678 , http://hdl.handle.net/10948/d1021182
  • Description: This study describes the bedrock lithologies and structure of the Ordovician to early Devonian (485-419 Ma) Table Mountain Group (TMG), the Devonian (419-358 Ma) lower Bokkeveld Group, and the Miocene to Holocene (<23 Ma) overburden sediments of the Algoa Group within an area identified by Eskom for the potential construction of South Africa’s second proposed nuclear power plant (NPP), ‘Nuclear-1’. The study area is located along the southern coastal margin of the Eastern Cape Province, South Africa, between Oyster Bay and St. Francis (approximately 88 km west of Port Elizabeth), and encompasses the Thyspunt site where the proposed NPP will be built. The study aims to supplement existing information about the Thyspunt area, related to the geoscientific topic ‘Geological Setting’, as outlined in section 2.5.1.1 of the US Nuclear Regulatory Commission (USNRC) Standard Review Plan NUREG-800, which details the geological information required for review of a proposed NPP. The results obtained from geoscientific studies are used to determine geological factors that may potentially affect site specific design. Factors considered include: bedrock lithology, stratigraphic bedrock contacts, bedrock palaeotopography, thickness of overburden sediments and structural geology. Work by previous authors is combined with new data to create a GIS based 2½D model of the study area’s geology (geomodel) and on which future research or interpretations can be based. Field mapping and petrographic analyses of the TMG, comprising the Peninsula, Cedarberg, Goudini, Skurweberg and Baviaanskloof Formations as well as the lower undifferentiated Bokkeveld Group were undertaken to define the study area’s lithologies and structure. Interpretation of geophysical results and the integration of existing borehole data aided in defining the variability in overburden sediments, the identification of contacts between TMG formations beneath overburden, and the palaeotopography of bedrock. Borehole data indicates a clear N-S trend in the thickness distribution of Algoa Group aeolian and marine related sediments. Four coast-parallel trending thickness zones (zones A – D) are recognized within the study area. At Thyspunt overburden thickness reaches a maximum of 61 m, approximately 1200 m from the coastline, in areas underlain by the argillaceous Goudini and Cedarberg Formations. Overburden thickness is influenced by a combination of dune relief, bedrock lithology, palaeotopography and the area’s sediment supply. Interpolation of bedrock elevation points and detailed cross sections across bedrock reveals four NW-SE trending palaeovalleys at Thyspunt, Tony’s Bay, Cape St. Francis and St. Francis, where bedrock relief (beneath overburden) is formed to be below present day sea-level. Approximately 450 m NW of Thys Bay, a 1050 m2 (area below sea-level) palaeovalley, gently sloping SE to a depth of -15.5 m asl, is cut into strata of the Goudini Formation resulting in thicker overburden fill in that area. Structural analysis of the TMG confirms that NE-SW striking strata form part of the regional SE plunging, north verging Cape St. Francis anticline. Bedding inclination is controlled by the distance away from the fold axis, varying from a 5° SE dip along the broad fold hinge to 65° along its moderately steeper SE limb. Folds within the study area plunge gently southeastward at shallow angles, with axial planes dipping steeply SW or NE. Fold axes orientated perpendicular to the fold axis of the Cape St. Francis anticline indicate a secondary stress orientation oblique to the main palaeostress direction. The previously identified 40 km long, NW-SE trending Cape St. Francis fault occurring offshore within 17.5 km of Thyspunt show no onshore continuation within the bounds of the study area. Late jointing is pervasive within the study area and four joint systems are identified. The dominant joint set J1, trends N-S to NNE - SSW; perpendicular to bedding and has a subvertical dip. Normal right-lateral and left-lateral micro-faults dip subvertically, with a displacement that ranges from a few centimetres to <3 m. Micro-faults trend parallel to joints sets J1 and J4 (ESE-WSW). Inferred faults, identified by the Atomic Energy Co-operation (AEC), are interpreted as zones of closely spaced jointing (shatter zones), and show little to no recognizable displacement. Faults and joints do not extend into the younger cover deposits of the Algoa Group and are therefore older than 23 Ma years.
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  • Date Issued: 2015

A case study: the role of a positive school climate in the enhancement of parental and community involvement at a primary school in Port Elizabeth

  • Authors: Cloete, Jacqueline
  • Date: 2015
  • Subjects: Education -- Parent participation , Community and school , Home and school
  • Language: English
  • Type: Thesis , Masters , MEd
  • Identifier: http://hdl.handle.net/10948/8735 , vital:26425
  • Description: This study examines the phenomenon of parental and community involvement in a primary school and the benefits thereof to the learners, teachers and community members. The aim of this study is to investigate how a positive school climate can improve the involvement of parents and community members in a school’s activities. The research attempted to determine what the role of a positive school climate is; the strategies schools could apply to enhance parental and community involvement, the possible benefits of involvement and reasons for non-involvement of parents and community members in school activities. The theoretical frameworks of Urie Bronfenbrenner’s ecological model and Joyce Epstein’s overlapping spheres of influence were used in the study. A case study was used as the qualitative research methodology. The data for the research was gathered from a purposive sample of teachers, community volunteer workers, parents and the principal. Semi-structured interview schedules and pre-designed questionnaires including open and closed questions, were used to collect data. The data was analysed inductively by using a descriptive open coding method to identify emerging themes. The findings of the research suggest that a positive school climate to improve parent and community involvement can be created by applying the strategies of effective communication, good working relationships, creating opportunities for involvement, ensuring a healthy and safe environment, formulating a school policy for parent and community involvement, creating a friendly and welcoming atmosphere as well as upholding an ethos of good moral values. The study found that parent and community involvement in a school’s activities offers various benefits to all stakeholders.
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  • Date Issued: 2015

Visualisation of PF firewall logs using open source

  • Authors: Coetzee, Dirk
  • Date: 2015
  • Subjects: Open source software -- South Africa , Firewalls (Computer security) -- South Africa , Data logging -- South Africa , Data integrity -- South Africa , Data protection -- South Africa , Computer crimes -- South Africa , Hacktivism
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4719 , http://hdl.handle.net/10962/d1018552
  • Description: If you cannot measure, you cannot manage. This is an age old saying, but still very true, especially within the current South African cybercrime scene and the ever-growing Internet footprint. Due to the significant increase in cybercrime across the globe, information security specialists are starting to see the intrinsic value of logs that can ‘tell a story’. Logs do not only tell a story, but also provide a tool to measure a normally dark force within an organisation. The collection of current logs from installed systems, operating systems and devices is imperative in the event of a hacking attempt, data leak or even data theft, whether the attempt is successful or unsuccessful. No logs mean no evidence, and in many cases not even the opportunity to find the mistake or fault in the organisation’s defence systems. Historically, it remains difficult to choose what logs are required by your organization. A number of questions should be considered: should a centralised or decentralised approach for collecting these logs be followed or a combination of both? How many events will be collected, how much additional bandwidth will be required and will the log collection be near real time? How long must the logs be saved and what if any hashing and encryption (integrity of data) should be used? Lastly, what system must be used to correlate, analyse, and make alerts and reports available? This thesis will address these myriad questions, examining the current lack of log analysis, practical implementations in modern organisation, and also how a need for the latter can be fulfilled by means of a basic approach. South African organizations must use technology that is at hand in order to know what electronic data are sent in and out of their organizations network. Concentrating only on FreeBSD PF firewall logs, it is demonstrated within this thesis the excellent results are possible when logs are collected to obtain a visual display of what data is traversing the corporate network and which parts of this data are posing a threat to the corporate network. This threat is easily determined via a visual interpretation of statistical outliers. This thesis aims to show that in the field of corporate data protection, if you can measure, you can manage.
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  • Date Issued: 2015

An investigation of ISO/IEC 27001 adoption in South Africa

  • Authors: Coetzer, Christo
  • Date: 2015
  • Subjects: ISO 27001 Standard , Information technology -- Security measures , Computer security , Data protection
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:4720 , http://hdl.handle.net/10962/d1018669
  • Description: The research objective of this study is to investigate the low adoption of the ISO/IEC 27001 standard in South African organisations. This study does not differentiate between the ISO/IEC 27001:2005 and ISO/IEC 27001:2013 versions, as the focus is on adoption of the ISO/IEC 27001 standard. A survey-based research design was selected as the data collection method. The research instruments used in this study include a web-based questionnaire and in-person interviews with the participants. Based on the findings of this research, the organisations that participated in this study have an understanding of the ISO/IEC 27001 standard; however, fewer than a quarter of these have fully adopted the ISO/IEC 27001 standard. Furthermore, the main business objectives for organisations that have adopted the ISO/IEC 27001 standard were to ensure legal and regulatory compliance, and to fulfil client requirements. An Information Security Management System management guide based on the ISO/IEC 27001 Plan-Do-Check-Act model is developed to help organisations interested in the standard move towards ISO/IEC 27001 compliance.
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  • Date Issued: 2015

DNA-based identification of forensically significant beetles from Southern Africa

  • Authors: Collett, Isabel Judith
  • Date: 2015
  • Subjects: Carrion insects , Forensic entomology , Cleridae , Dermestidae , Silphidae , Staphylinidae , Scarabaeidae , Histeridae
  • Language: English
  • Type: Thesis , Masters , MSc
  • Identifier: vital:5923 , http://hdl.handle.net/10962/d1017801
  • Description: Necrophilous insects, if correctly identified, can provide useful forensic information. Research in this area has focussed on flies and beetles remain comparatively under-studied, partly because some adult carrion beetles are difficult to identify morphologically, as are their juvenile stages, often requiring specialist expertise in both cases. Molecular taxonomy has been proposed as a solution to these problems. DNA “barcodes" are short fragments of mitochondrial cytochrome oxidase I (COI) DNA that are anticipated to delineate species. This approach is becoming increasingly popular, but has been met with varying enthusiasm from taxonomists. This thesis examines their use in identifying forensically significant beetles.The DNA barcodes of 234 specimens of 25 forensically significant southern African beetle species from seven families (Cleridae, Dermestidae, Silphidae, Staphylinidae, Scarabaeidae, Trogidae and Histeridae) were obtained. Thirty-three initial barcode amplification failures were overcome by using primers other than the standard Folmer pair, undermining the barcode concept’s hope of universal primers that would allow even non-specialists to produce barcodes. Another 150 specimens (64%) entirely failed to yield barcodes, including 18 fresh specimens of three species of Trogidae, implying another lack of universality of the barcoding protocol. The majority of the beetles clustered with confamilials on neighbour-joining and maximum likelihood trees, but 1.3% of the barcodes failed to cluster with their respective families, raising questions concerning the associating power of barcodes. The identification tools of the GenBank and BOLD on-line DNA sequence databases identified 21% of the specimens to the species level, 6% of them correctly. There was evidence of a paralogous sequence in the Cleridae that, while supporting identification now that it has been associated with a morphological identification, would hamper attempts at identification by clustering or phylogenetic analysis.Distance and haplotype network analyses of the barcodes of six widespread species showed that they are not geographically structured. Barcodes are thus unlikely to be indicators of the region of origin of a species and will not determine whether a corpse has been relocated after death. To assess whether a different mitochondrial DNA fragment might address (some of) these problems, a 2.2 kb fragment extending from the 5’ end of the COI gene to the 3’ end of the Cytochrome Oxidase II (COII) gene was analysed for nine species. It was found that, for Dermestidae, Scarabaeidae and Histeridae, higher degrees of diversity occurred downstreamof the barcode region, but the region of highest diversity in the Cleridae was in the barcode region. Thus, finding a more reliable fragment along the COI-COII region for each family may make robust and guaranteed DNA-based identification of these beetles more likely. The possibility of a forensic specimen being incorrectly or not identified based on its barcode alone exists in about 40% of cases, even with the new barcodes reported here. Forensic science sets a very high bar in assessing the performance of its techniques, and it is concluded that barcodes currently have unsettling failure rates as court-worthy evidence.
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  • Date Issued: 2015
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