Continuous auditing technologies and models
- Authors: Blundell, Adrian Wesley
- Date: 2007
- Subjects: Auditing , Auditing -- Data processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9798 , http://hdl.handle.net/10948/476 , http://hdl.handle.net/10948/d1011922 , Auditing , Auditing -- Data processing
- Description: Continuous auditing is not a totally new concept, but it has not been widely implemented, and has existed mostly as a point of debate amongst the auditing fraternity. This may soon change, as continuous auditing has become a topic of great interest, especially in the last decade. This may be due to a combination of reasons. In the last decade, much of the confidence in auditors’ reports was lost due to corporate governance scandals. This also brought about a greater desire for faster, more reliable reporting on which to base decisions. This desire has been transposed into regulations such as the Sarbanes-Oxley act in the United States, which encourages real-time auditing activities, which would benefit from continuous auditing. A second, possible contributing factor to the heightened interest in continuous auditing is that much of the requisite technology has matured to a point where it can be successfully used to implement continuous auditing. It is the technologies which form the focus of this research. It is therefore, the primary objective of this research to investigate and identify the essential technologies, and identify and define their roles within a continuous auditing solution. To explore this area, three models of continuous auditing are compared according to the roles of the technologies within them. The roots of some auditing technologies which can be adapted to the paradigm of continuous auditing are explored, as well as new technologies, such as XML-based reporting languages. In order to fully explore these technologies, the concepts of data integrity and data quality are first defined and discussed, and some security measures which contribute to integrity are identified. An obstacle to implementing a continuous model is that even with the newly available technologies, the multitudes of systems which are used in organisations, produce data in a plethora of data formats. In performing an audit the continuous auditing system needs to first gather this data and then needs to be able to compare “apples with apples”. Therefore, the technologies which can be used to acquire and standardise the data are identified.
- Full Text:
- Date Issued: 2007
- Authors: Blundell, Adrian Wesley
- Date: 2007
- Subjects: Auditing , Auditing -- Data processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9798 , http://hdl.handle.net/10948/476 , http://hdl.handle.net/10948/d1011922 , Auditing , Auditing -- Data processing
- Description: Continuous auditing is not a totally new concept, but it has not been widely implemented, and has existed mostly as a point of debate amongst the auditing fraternity. This may soon change, as continuous auditing has become a topic of great interest, especially in the last decade. This may be due to a combination of reasons. In the last decade, much of the confidence in auditors’ reports was lost due to corporate governance scandals. This also brought about a greater desire for faster, more reliable reporting on which to base decisions. This desire has been transposed into regulations such as the Sarbanes-Oxley act in the United States, which encourages real-time auditing activities, which would benefit from continuous auditing. A second, possible contributing factor to the heightened interest in continuous auditing is that much of the requisite technology has matured to a point where it can be successfully used to implement continuous auditing. It is the technologies which form the focus of this research. It is therefore, the primary objective of this research to investigate and identify the essential technologies, and identify and define their roles within a continuous auditing solution. To explore this area, three models of continuous auditing are compared according to the roles of the technologies within them. The roots of some auditing technologies which can be adapted to the paradigm of continuous auditing are explored, as well as new technologies, such as XML-based reporting languages. In order to fully explore these technologies, the concepts of data integrity and data quality are first defined and discussed, and some security measures which contribute to integrity are identified. An obstacle to implementing a continuous model is that even with the newly available technologies, the multitudes of systems which are used in organisations, produce data in a plethora of data formats. In performing an audit the continuous auditing system needs to first gather this data and then needs to be able to compare “apples with apples”. Therefore, the technologies which can be used to acquire and standardise the data are identified.
- Full Text:
- Date Issued: 2007
Improving certain high performance properties of natural fibres
- Authors: Chapple, Stephen Anthony
- Date: 2007
- Subjects: Textile chemistry , Fireproofing of fabrics
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10451 , http://hdl.handle.net/10948/815 , Textile chemistry , Fireproofing of fabrics
- Description: Cotton possesses many characteristics that make it desirable to the consumer, and this has resulted in its usage in a broad range of products. Cotton, however, is a flammable material that is easily ignited and rapidly consumed. The flame retardant treatment of cotton is, therefore, an important textile process that has received wide attention over many years. There are a number of commercial flame retardant treatments available for cotton, the most common being phosphate-based. These treatments, however, often have drawbacks or have a negative impact on the desirable properties of the fibre and the challenge still exists for designing better flame retardant products and systems that are durable and have limited impact on fibre properties. The study considers the application of the sol-gel as a coating on fabric that was pre-treated with a phosphate-based flame retardant or as a means for applying a phosphate-based flame retardant. Both treatment methods were found to be suitable for imparting flame resistance to the fabric. The effect of various phosphate-based flame retardants on flammability and fabric properties such as colour, handle and strength was investigated and it was shown that a diammonium phosphate and urea combination gave the best flame resistance. In this regard, a flame resistance was achieved with a lower amount of phosphorous than was used in similar conventional treatments. The durability of the coating to rinsing with water and soaping with a detergent was also investigated. It was found that the flame resistance was lost after rinsing or soaping but the prevention of afterglow combustion was retained. It was shown that the preparatory treatment of the fabric influenced the sol-gel coating process and the flammability of the fabric. Mercerisation and bleaching of the fabric increased the “wet pick-up” during the coating process and improved the flame resistance. The influence of various factors was also investigated in further detail. The ratio of the sol-gel components, the delay after coating prior to drying (hang time) and the curing time were investigated using an experimental design. The curing time and the ratio of components in the sol-gel were shown to have the greatest influence on fabric properties and fabric flammability. It was shown that there is a trade-off between the desired high level of fabric flame resistance and preserving the inherent properties of the fabric such as colour, handle and strength.
- Full Text:
- Date Issued: 2007
- Authors: Chapple, Stephen Anthony
- Date: 2007
- Subjects: Textile chemistry , Fireproofing of fabrics
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10451 , http://hdl.handle.net/10948/815 , Textile chemistry , Fireproofing of fabrics
- Description: Cotton possesses many characteristics that make it desirable to the consumer, and this has resulted in its usage in a broad range of products. Cotton, however, is a flammable material that is easily ignited and rapidly consumed. The flame retardant treatment of cotton is, therefore, an important textile process that has received wide attention over many years. There are a number of commercial flame retardant treatments available for cotton, the most common being phosphate-based. These treatments, however, often have drawbacks or have a negative impact on the desirable properties of the fibre and the challenge still exists for designing better flame retardant products and systems that are durable and have limited impact on fibre properties. The study considers the application of the sol-gel as a coating on fabric that was pre-treated with a phosphate-based flame retardant or as a means for applying a phosphate-based flame retardant. Both treatment methods were found to be suitable for imparting flame resistance to the fabric. The effect of various phosphate-based flame retardants on flammability and fabric properties such as colour, handle and strength was investigated and it was shown that a diammonium phosphate and urea combination gave the best flame resistance. In this regard, a flame resistance was achieved with a lower amount of phosphorous than was used in similar conventional treatments. The durability of the coating to rinsing with water and soaping with a detergent was also investigated. It was found that the flame resistance was lost after rinsing or soaping but the prevention of afterglow combustion was retained. It was shown that the preparatory treatment of the fabric influenced the sol-gel coating process and the flammability of the fabric. Mercerisation and bleaching of the fabric increased the “wet pick-up” during the coating process and improved the flame resistance. The influence of various factors was also investigated in further detail. The ratio of the sol-gel components, the delay after coating prior to drying (hang time) and the curing time were investigated using an experimental design. The curing time and the ratio of components in the sol-gel were shown to have the greatest influence on fabric properties and fabric flammability. It was shown that there is a trade-off between the desired high level of fabric flame resistance and preserving the inherent properties of the fabric such as colour, handle and strength.
- Full Text:
- Date Issued: 2007
Cost-benefit analysis of land restoration in the Assegaaibos Catchment Area with regard to water yield and tourism benefit
- Authors: Currie, Bianca
- Date: 2007
- Subjects: Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10751 , http://hdl.handle.net/10948/726 , Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Description: With the emergence of the new field of resource economics, one now has the ability to value and to include natural resources in decision making. This thesis aims to explore the valuation of natural resources by reviewing the economic values, techniques, methods and ecological aspects of restoration. Assegaaibos mountain catchment in the Western Cape Province has been used as a case-study example. A cost-benefit analysis of the restoration of the mountain catchment, in terms of the direct benefits of water and tourism, has been performed. The costs of restoration were observed to see whether they outweighed the benefits (income) derived (water and tourism). The results show that the water and tourism benefits did outweigh the costs of a basic restoration scenario. However, the basic restoration scenario did not fulfil the ecological requirements of the project. The results also illustrated that in the moderate restoration scenario, costs only outweighed the benefits when a three percent discount rate was applied. With the optimistic restoration scenario, costs outweighed benefits only when an eight percent discount rate was used. In the comprehensive restoration scenario, costs were shown to outweigh by far the water and tourism benefits over a thirty-year time frame. However, it should be noted that the deterioration of the environment (accelerated erosion, reinvasion, reduced water quality) was not factored into the costs of failure to rehabilitate.
- Full Text:
- Date Issued: 2007
- Authors: Currie, Bianca
- Date: 2007
- Subjects: Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10751 , http://hdl.handle.net/10948/726 , Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Description: With the emergence of the new field of resource economics, one now has the ability to value and to include natural resources in decision making. This thesis aims to explore the valuation of natural resources by reviewing the economic values, techniques, methods and ecological aspects of restoration. Assegaaibos mountain catchment in the Western Cape Province has been used as a case-study example. A cost-benefit analysis of the restoration of the mountain catchment, in terms of the direct benefits of water and tourism, has been performed. The costs of restoration were observed to see whether they outweighed the benefits (income) derived (water and tourism). The results show that the water and tourism benefits did outweigh the costs of a basic restoration scenario. However, the basic restoration scenario did not fulfil the ecological requirements of the project. The results also illustrated that in the moderate restoration scenario, costs only outweighed the benefits when a three percent discount rate was applied. With the optimistic restoration scenario, costs outweighed benefits only when an eight percent discount rate was used. In the comprehensive restoration scenario, costs were shown to outweigh by far the water and tourism benefits over a thirty-year time frame. However, it should be noted that the deterioration of the environment (accelerated erosion, reinvasion, reduced water quality) was not factored into the costs of failure to rehabilitate.
- Full Text:
- Date Issued: 2007
A model for integrating information security into the software development life cycle
- Authors: Futcher, Lynn Ann
- Date: 2007
- Subjects: Computer security , Software maintenance
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9737 , http://hdl.handle.net/10948/506 , Computer security , Software maintenance
- Description: It is within highly integrated technology environments that information security is becoming a focal point for designing, developing and deploying software applications. Ensuring a high level of trust in the security and quality of these applications is crucial to their ultimate success. Therefore, information security has become a core requirement for software applications, driven by the need to protect critical assets and the need to build and preserve widespread trust in computing. However, a common weakness that is inherent in the traditional software development methodologies is the lack of attention given to the security aspects of software development. Most of these methodologies do not explicitly include a standardised method for incorporating information security into their life cycles. Meaningful security can be achieved when information security issues are considered as part of a routine development process, and security safeguards are integrated into the software application throughout its life cycle. This, in turn, will lead to users being more confident to use software applications, and to entrust today's computer systems with their personal information. To build better or more secure software, an improved software development process is required. Security of a software application must be based on the risk associated with the application. In order to understand this risk, the relevant information assets need to be identified together with their threats and vulnerabilities. Therefore, security considerations provide input into every phase of the Software Development Life Cycle (SDLC), from requirements gathering to design, implementation, testing and deployment. This research project presents a Secure Software Development Model (SecSDM) for incorporating information security into all phases of the SDLC, from requirements gathering to systems maintenance. The SecSDM is based on many of the recommendations provided by relevant international standards and best practices, for example, the ISO 7498-2 (1989) standard which addresses the underlying security services and mechanisms that form an integral part of the model.
- Full Text:
- Date Issued: 2007
- Authors: Futcher, Lynn Ann
- Date: 2007
- Subjects: Computer security , Software maintenance
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9737 , http://hdl.handle.net/10948/506 , Computer security , Software maintenance
- Description: It is within highly integrated technology environments that information security is becoming a focal point for designing, developing and deploying software applications. Ensuring a high level of trust in the security and quality of these applications is crucial to their ultimate success. Therefore, information security has become a core requirement for software applications, driven by the need to protect critical assets and the need to build and preserve widespread trust in computing. However, a common weakness that is inherent in the traditional software development methodologies is the lack of attention given to the security aspects of software development. Most of these methodologies do not explicitly include a standardised method for incorporating information security into their life cycles. Meaningful security can be achieved when information security issues are considered as part of a routine development process, and security safeguards are integrated into the software application throughout its life cycle. This, in turn, will lead to users being more confident to use software applications, and to entrust today's computer systems with their personal information. To build better or more secure software, an improved software development process is required. Security of a software application must be based on the risk associated with the application. In order to understand this risk, the relevant information assets need to be identified together with their threats and vulnerabilities. Therefore, security considerations provide input into every phase of the Software Development Life Cycle (SDLC), from requirements gathering to design, implementation, testing and deployment. This research project presents a Secure Software Development Model (SecSDM) for incorporating information security into all phases of the SDLC, from requirements gathering to systems maintenance. The SecSDM is based on many of the recommendations provided by relevant international standards and best practices, for example, the ISO 7498-2 (1989) standard which addresses the underlying security services and mechanisms that form an integral part of the model.
- Full Text:
- Date Issued: 2007
A critical review of the IFIP TC11 Security Conference Series
- Authors: Gaadingwe, Tshepo Gaadingwe
- Date: 2007
- Subjects: Database security , Data protection , Computers -- Access control
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9795 , http://hdl.handle.net/10948/507 , Database security , Data protection , Computers -- Access control
- Description: Over the past few decades the field of computing has grown and evolved. In this time, information security research has experienced the same type of growth. The increase in importance and interest in information security research is reflected by the sheer number of research efforts being produced by different type of organizations around the world. One such organization is the International Federation for Information Processing (IFIP), more specifically the IFIP Technical Committee 11 (IFIP TC11). The IFIP TC11 community has had a rich history in producing high quality information security specific articles for over 20 years now. Therefore, IFIP TC11 found it necessary to reflect on this history, mainly to try and discover where it came from and where it may be going. Its 20th anniversary of its main conference presented an opportunity to begin such a study of its history. The core belief driving the study being that the future can only be realized and appreciated if the past is well understood. The main area of interest was to find out topics which may have had prevalence in the past or could be considered as "hot" topics. To achieve this, the author developed a systematic process for the study. The underpinning element being the creation of a classification scheme which was used to aid the analysis of the IFIP TC11 20 year's worth of articles. Major themes were identified and trends in the series highlighted. Further discussion and reflection on these trends were given. It was found that, not surprisingly, the series covered a wide variety of topics in the 20 years. However, it was discovered that there has been a notable move towards technically focused papers. Furthermore, topics such as business continuity had just about disappeared in the series while topics which are related to networking and cryptography continue to gain more prevalence.
- Full Text:
- Date Issued: 2007
- Authors: Gaadingwe, Tshepo Gaadingwe
- Date: 2007
- Subjects: Database security , Data protection , Computers -- Access control
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9795 , http://hdl.handle.net/10948/507 , Database security , Data protection , Computers -- Access control
- Description: Over the past few decades the field of computing has grown and evolved. In this time, information security research has experienced the same type of growth. The increase in importance and interest in information security research is reflected by the sheer number of research efforts being produced by different type of organizations around the world. One such organization is the International Federation for Information Processing (IFIP), more specifically the IFIP Technical Committee 11 (IFIP TC11). The IFIP TC11 community has had a rich history in producing high quality information security specific articles for over 20 years now. Therefore, IFIP TC11 found it necessary to reflect on this history, mainly to try and discover where it came from and where it may be going. Its 20th anniversary of its main conference presented an opportunity to begin such a study of its history. The core belief driving the study being that the future can only be realized and appreciated if the past is well understood. The main area of interest was to find out topics which may have had prevalence in the past or could be considered as "hot" topics. To achieve this, the author developed a systematic process for the study. The underpinning element being the creation of a classification scheme which was used to aid the analysis of the IFIP TC11 20 year's worth of articles. Major themes were identified and trends in the series highlighted. Further discussion and reflection on these trends were given. It was found that, not surprisingly, the series covered a wide variety of topics in the 20 years. However, it was discovered that there has been a notable move towards technically focused papers. Furthermore, topics such as business continuity had just about disappeared in the series while topics which are related to networking and cryptography continue to gain more prevalence.
- Full Text:
- Date Issued: 2007
The effective combating of intrusion attacks through fuzzy logic and neural networks
- Authors: Goss, Robert Melvin
- Date: 2007
- Subjects: Computer security , Fuzzy logic , Neural networks (Computer science)
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9794 , http://hdl.handle.net/10948/512 , http://hdl.handle.net/10948/d1011917 , Computer security , Fuzzy logic , Neural networks (Computer science)
- Description: The importance of properly securing an organization’s information and computing resources has become paramount in modern business. Since the advent of the Internet, securing this organizational information has become increasingly difficult. Organizations deploy many security mechanisms in the protection of their data, intrusion detection systems in particular have an increasingly valuable role to play, and as networks grow, administrators need better ways to monitor their systems. Currently, many intrusion detection systems lack the means to accurately monitor and report on wireless segments within the corporate network. This dissertation proposes an extension to the NeGPAIM model, known as NeGPAIM-W, which allows for the accurate detection of attacks originating on wireless network segments. The NeGPAIM-W model is able to detect both wired and wireless based attacks, and with the extensions to the original model mentioned previously, also provide for correlation of intrusion attacks sourced on both wired and wireless network segments. This provides for a holistic detection strategy for an organization. This has been accomplished with the use of Fuzzy logic and neural networks utilized in the detection of attacks. The model works on the assumption that each user has, and leaves, a unique footprint on a computer system. Thus, all intrusive behaviour on the system and networks which support it, can be traced back to the user account which was used to perform the intrusive behavior.
- Full Text:
- Date Issued: 2007
- Authors: Goss, Robert Melvin
- Date: 2007
- Subjects: Computer security , Fuzzy logic , Neural networks (Computer science)
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9794 , http://hdl.handle.net/10948/512 , http://hdl.handle.net/10948/d1011917 , Computer security , Fuzzy logic , Neural networks (Computer science)
- Description: The importance of properly securing an organization’s information and computing resources has become paramount in modern business. Since the advent of the Internet, securing this organizational information has become increasingly difficult. Organizations deploy many security mechanisms in the protection of their data, intrusion detection systems in particular have an increasingly valuable role to play, and as networks grow, administrators need better ways to monitor their systems. Currently, many intrusion detection systems lack the means to accurately monitor and report on wireless segments within the corporate network. This dissertation proposes an extension to the NeGPAIM model, known as NeGPAIM-W, which allows for the accurate detection of attacks originating on wireless network segments. The NeGPAIM-W model is able to detect both wired and wireless based attacks, and with the extensions to the original model mentioned previously, also provide for correlation of intrusion attacks sourced on both wired and wireless network segments. This provides for a holistic detection strategy for an organization. This has been accomplished with the use of Fuzzy logic and neural networks utilized in the detection of attacks. The model works on the assumption that each user has, and leaves, a unique footprint on a computer system. Thus, all intrusive behaviour on the system and networks which support it, can be traced back to the user account which was used to perform the intrusive behavior.
- Full Text:
- Date Issued: 2007
Micellar-enhanced ultrafiltration of palladium and platinum anions
- Authors: Gwicana, Sakumzi
- Date: 2007
- Subjects: Micelles , Ultrafiltration , Palladium catalysts
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10414 , http://hdl.handle.net/10948/518 , Micelles , Ultrafiltration , Palladium catalysts
- Description: The project was concerned with studying the capability of a micellar-enhanced ultrafiltration system (MEUF) to remove platinum group metal ions namely Pt (lV) and Pd (ll) chloro anions from aqueous industrial waste effluents. South Africa has the world’s largest reserves of platinum group metals (PGMs) and other valuable metals such as manganese, chrome ores, titanium minerals etc. which are required for new automotive and other technologies, including fuel cells, catalytic converters and lighter components. The consistent loss with the industrial waste stream and the toxicological effects of these precious metals led to the need to develop new and effective methods to recover them from industrial waste effluents. With such a wide variety of fields where these PGMs are used and the failure of the traditional techniques namely sedimentation, fermentation etc. to effectively reduce or recover these highly toxic and precious metal ions prior to discharging industrial waste effluents, it is necessary to explore other techniques such as membrane technology that can be used to recover these valuable species from industrial waste streams. The present study involved the use of a cationic surfactant, viz cetylpyridinium chloride, which was introduced into an aqueous solution containing palladium and platinum metal anions. The surfactant forms charged micelles above a certain critical concentration value. The metal anions adsorb onto the available oppositely charged sites on the micelle surfaces and are then able to be retained by a suitable membrane. Hollow fibre ultrafiltration membranes with the MWCO of +/- 10 kD and +/-30nm pore size were used as a filter component in this study. For this MEUF system to be effective, it was vital that the anionic metal ion species adsorbed sufficiently onto the available oppositely charged sites of the micelles and that the micelles were retained efficiently by the membrane. Results obtained during the investigation made it possible to make certain predictions about the micellisation process. It was also found that, it was not only the metal ion: surfactant (M:S) ratio that was critical, but the presence of other electrolytes in the aqueous stream proved to have a huge impact on the capability of the MEUF system. Findings of this research study showed that the MEUF system using cetylpyridinium chloride (CPC) can be used to recover or retain Pt (lV) and Pd (ll) anions from industrial waste effluents. It was also found that PtCl6 2-, due to its greater adsorption capabilities onto the micelle surface than PdCl4 2- or PdCl3(H2O)-, was preferentially retained in neutral medium. This may be exploited as a possible means of separating the two metal ions. The developed system offers the following advantages over some traditional and current methods: simplified unit operation line flow process, smaller amounts of chemical usage and no solid toxic sludge to be disposed of. Applications of this work could be of vital importance in catalytic converter recycling, especially in Port Elizabeth where extensive automobile parts manufacturing occurs.
- Full Text:
- Date Issued: 2007
- Authors: Gwicana, Sakumzi
- Date: 2007
- Subjects: Micelles , Ultrafiltration , Palladium catalysts
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10414 , http://hdl.handle.net/10948/518 , Micelles , Ultrafiltration , Palladium catalysts
- Description: The project was concerned with studying the capability of a micellar-enhanced ultrafiltration system (MEUF) to remove platinum group metal ions namely Pt (lV) and Pd (ll) chloro anions from aqueous industrial waste effluents. South Africa has the world’s largest reserves of platinum group metals (PGMs) and other valuable metals such as manganese, chrome ores, titanium minerals etc. which are required for new automotive and other technologies, including fuel cells, catalytic converters and lighter components. The consistent loss with the industrial waste stream and the toxicological effects of these precious metals led to the need to develop new and effective methods to recover them from industrial waste effluents. With such a wide variety of fields where these PGMs are used and the failure of the traditional techniques namely sedimentation, fermentation etc. to effectively reduce or recover these highly toxic and precious metal ions prior to discharging industrial waste effluents, it is necessary to explore other techniques such as membrane technology that can be used to recover these valuable species from industrial waste streams. The present study involved the use of a cationic surfactant, viz cetylpyridinium chloride, which was introduced into an aqueous solution containing palladium and platinum metal anions. The surfactant forms charged micelles above a certain critical concentration value. The metal anions adsorb onto the available oppositely charged sites on the micelle surfaces and are then able to be retained by a suitable membrane. Hollow fibre ultrafiltration membranes with the MWCO of +/- 10 kD and +/-30nm pore size were used as a filter component in this study. For this MEUF system to be effective, it was vital that the anionic metal ion species adsorbed sufficiently onto the available oppositely charged sites of the micelles and that the micelles were retained efficiently by the membrane. Results obtained during the investigation made it possible to make certain predictions about the micellisation process. It was also found that, it was not only the metal ion: surfactant (M:S) ratio that was critical, but the presence of other electrolytes in the aqueous stream proved to have a huge impact on the capability of the MEUF system. Findings of this research study showed that the MEUF system using cetylpyridinium chloride (CPC) can be used to recover or retain Pt (lV) and Pd (ll) anions from industrial waste effluents. It was also found that PtCl6 2-, due to its greater adsorption capabilities onto the micelle surface than PdCl4 2- or PdCl3(H2O)-, was preferentially retained in neutral medium. This may be exploited as a possible means of separating the two metal ions. The developed system offers the following advantages over some traditional and current methods: simplified unit operation line flow process, smaller amounts of chemical usage and no solid toxic sludge to be disposed of. Applications of this work could be of vital importance in catalytic converter recycling, especially in Port Elizabeth where extensive automobile parts manufacturing occurs.
- Full Text:
- Date Issued: 2007
A code of practice for practitioners in private healthcare: a privacy perspective
- Authors: Harvey, Brett D
- Date: 2007
- Subjects: Information storage and retrieval systems -- Medical care , Medical records -- Data processing , Privacy, Right of Comparative studies
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9735 , http://hdl.handle.net/10948/521 , Information storage and retrieval systems -- Medical care , Medical records -- Data processing , Privacy, Right of Comparative studies
- Description: Whereas there are various initiatives to standardize the storage, processing and use of electronic patient information in the South African health sector, the sector is fragmented through the adoption of various approaches on national, provincial and district levels. Divergent IT systems are used in the public and private health sectors (“Recommendations of the Committee on …” 2003). Furthermore, general practitioners in some parts of the country still use paper as a primary means of documentation and storage. Nonetheless, the use of computerized systems is increasing, even in the most remote rural areas. This leads to the exposure of patient information to various threats that are perpetuated through the use of information technology. Irrespective of the level of technology adoption by practitioners in private healthcare practice, the security and privacy of patient information remains of critical importance. The disclosure of patient information whether intentional or not, can have dire consequences for a patient. In general, the requirements pertaining to the privacy of patient information are controlled and enforced through the adoption of legislation by the governing body of a country. Compared with developed nations, South Africa has limited legislation to help enforce privacy in the health sector. Conversely, Australia, New Zealand and Canada have some of the most advanced legislative frameworks when it comes to the privacy of patient information. In this dissertation, the Australian, New Zealand, Canadian and South African health sectors and the legislation they have in place to ensure the privacy of health information, will be investigated. Additionally, codes of practice and guidelines on privacy of patient information for GPs, in the afore-mentioned countries, will be investigated to form an idea as to what is needed in creating and formulating a new code of practice for the South African GP, as well as a pragmatic tool (checklist) to check adherence to privacy requirements.
- Full Text:
- Date Issued: 2007
- Authors: Harvey, Brett D
- Date: 2007
- Subjects: Information storage and retrieval systems -- Medical care , Medical records -- Data processing , Privacy, Right of Comparative studies
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9735 , http://hdl.handle.net/10948/521 , Information storage and retrieval systems -- Medical care , Medical records -- Data processing , Privacy, Right of Comparative studies
- Description: Whereas there are various initiatives to standardize the storage, processing and use of electronic patient information in the South African health sector, the sector is fragmented through the adoption of various approaches on national, provincial and district levels. Divergent IT systems are used in the public and private health sectors (“Recommendations of the Committee on …” 2003). Furthermore, general practitioners in some parts of the country still use paper as a primary means of documentation and storage. Nonetheless, the use of computerized systems is increasing, even in the most remote rural areas. This leads to the exposure of patient information to various threats that are perpetuated through the use of information technology. Irrespective of the level of technology adoption by practitioners in private healthcare practice, the security and privacy of patient information remains of critical importance. The disclosure of patient information whether intentional or not, can have dire consequences for a patient. In general, the requirements pertaining to the privacy of patient information are controlled and enforced through the adoption of legislation by the governing body of a country. Compared with developed nations, South Africa has limited legislation to help enforce privacy in the health sector. Conversely, Australia, New Zealand and Canada have some of the most advanced legislative frameworks when it comes to the privacy of patient information. In this dissertation, the Australian, New Zealand, Canadian and South African health sectors and the legislation they have in place to ensure the privacy of health information, will be investigated. Additionally, codes of practice and guidelines on privacy of patient information for GPs, in the afore-mentioned countries, will be investigated to form an idea as to what is needed in creating and formulating a new code of practice for the South African GP, as well as a pragmatic tool (checklist) to check adherence to privacy requirements.
- Full Text:
- Date Issued: 2007
An investigation of indoor air quality assessment in office buildings
- Janse van Rensburg, Francois
- Authors: Janse van Rensburg, Francois
- Date: 2007
- Subjects: Indoor air pollution , Air quality management , Air quality -- Measurement
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10824 , http://hdl.handle.net/10948/32 , Indoor air pollution , Air quality management , Air quality -- Measurement
- Description: Over the last several years studies have shown that the quality of indoor air may be worse than outdoor air. People spend as much as 90% of their time indoors, therefor, the associated health risk due to indoor air pollution may be greater than the risk due to outdoor air pollution. Building designs have altered dramatically over the last two decades resulted in "tighter" buildings that rely on sophisticated mechanical systems to provide for the quantity of air required throughout the building. These changes over the years could result in an increased number of complaints received regarding Sick Building Syndrome symptoms. The World Health Organization (WHO) estimates that up to 30% of office buildings world-wide may have significant problems regarding poor indoor air quality (IAQ). This study involves a literature study of the major indoor air pollutants regarding the source of the pollutant, the associated health effects, the measuring techniques available and the results of previous studies conducted on the specific pollutant. Measurements will be taken in two sealed buildings, one an old and the other a new building to identify the major pollutants. A questionnaire was compiled specifically for building occupants and completed by the occupants of both buildings. From the results obtained a step-by-step method for solving indoor air quality (IAQ) problems was proposed. The method was applied and evaluated in a case study of a problem building where indoor air quality related problems were experienced. The results of the study revealed that the major indoor air pollutants are present in old as well as new buildings. The study also revealed that some office workers might be more susceptible than others to the medical reactions cause to human beings by these pollutants. Some concentrations are higher in new buildings than in old buildings. The responses from the questionnaire was evaluated against the results obtained from the measurement study. The step-by-step method in the case study provided a more systematic approach at solving IAQ problems at buildings. Solving indoor air quality problems is a very practical issue and does not necessarily require an investment of expensive high technology equipment, but might merely require a practical approach. Environmental Health Officers can play a major role in providing expert advice when scrutinizing building plans. Environmental Health Officers should empower themselves with the knowledge to do inspections or investigations in office buildings by using the step-by-step method for investigating indoor air quality problems. By addressing indoor air quality problems in buildings, the workers in healthy buildings can increase their productivity with lasting effects on a company’s bottom line.
- Full Text:
- Date Issued: 2007
- Authors: Janse van Rensburg, Francois
- Date: 2007
- Subjects: Indoor air pollution , Air quality management , Air quality -- Measurement
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10824 , http://hdl.handle.net/10948/32 , Indoor air pollution , Air quality management , Air quality -- Measurement
- Description: Over the last several years studies have shown that the quality of indoor air may be worse than outdoor air. People spend as much as 90% of their time indoors, therefor, the associated health risk due to indoor air pollution may be greater than the risk due to outdoor air pollution. Building designs have altered dramatically over the last two decades resulted in "tighter" buildings that rely on sophisticated mechanical systems to provide for the quantity of air required throughout the building. These changes over the years could result in an increased number of complaints received regarding Sick Building Syndrome symptoms. The World Health Organization (WHO) estimates that up to 30% of office buildings world-wide may have significant problems regarding poor indoor air quality (IAQ). This study involves a literature study of the major indoor air pollutants regarding the source of the pollutant, the associated health effects, the measuring techniques available and the results of previous studies conducted on the specific pollutant. Measurements will be taken in two sealed buildings, one an old and the other a new building to identify the major pollutants. A questionnaire was compiled specifically for building occupants and completed by the occupants of both buildings. From the results obtained a step-by-step method for solving indoor air quality (IAQ) problems was proposed. The method was applied and evaluated in a case study of a problem building where indoor air quality related problems were experienced. The results of the study revealed that the major indoor air pollutants are present in old as well as new buildings. The study also revealed that some office workers might be more susceptible than others to the medical reactions cause to human beings by these pollutants. Some concentrations are higher in new buildings than in old buildings. The responses from the questionnaire was evaluated against the results obtained from the measurement study. The step-by-step method in the case study provided a more systematic approach at solving IAQ problems at buildings. Solving indoor air quality problems is a very practical issue and does not necessarily require an investment of expensive high technology equipment, but might merely require a practical approach. Environmental Health Officers can play a major role in providing expert advice when scrutinizing building plans. Environmental Health Officers should empower themselves with the knowledge to do inspections or investigations in office buildings by using the step-by-step method for investigating indoor air quality problems. By addressing indoor air quality problems in buildings, the workers in healthy buildings can increase their productivity with lasting effects on a company’s bottom line.
- Full Text:
- Date Issued: 2007
A comparison between the game and hunting industries in KwaZulu-Natal and the Eastern Cape
- Authors: Kobus, Louann
- Date: 2007
- Subjects: Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10590 , http://hdl.handle.net/10948/534 , http://hdl.handle.net/10948/d1011724 , Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Description: The objectives of this research, were to investigate the characteristics and develop a profile of the game and hunting industries of KwaZulu-Natal, and to undertake a comparison between the game and hunting industries in KwaZulu-Natal and the Eastern Cape. The comparative part of this study was completed using results obtained from a study done in 2002 in the Eastern Cape (van Niekerk, 2002). The main farming activities in KwaZulu-Natal are large livestock production and sugar cane production. In recent years, private landowners in KwaZulu-Natal have undergone a transition from livestock production to game ranching due to the problems faced and the cost implications of the HIV epidemic, stock theft, difficulties faced with changes in the labour laws and the increasing number of land claims against farmers. Although the game and hunting industries are relatively young industries in KwaZulu-Natal they contribute significantly to the economy of the province. Not only is greater conservation of the biodiversity more effective in game ranching but it is also proving to yield great economic returns. The increase in game ranching in recent years is namely due to the monetary value placed on wildlife, the increased value in ecotourism and its value as an earner of foreign exchange, less dependency on unskilled labour than that of livestock farming and lower rates of animal loss through theft compared to that of livestock farming. In KwaZulu-Natal game numbers indicate that impala have the greatest population amongst the respondents, followed by nyala, blesbok, common reedbuck, kudu and blue wildebeest, whilst other game species occur in smaller numbers. Respondents in KwaZulu-Natal indicate that nyala is the largest economic earner for them followed by buffalo, whereas in the Eastern Cape (2002), kudu and springbok provide the greatest income for the province. In KwaZulu-Natal income generated from hunting is second to that of live game sales compared to the Eastern Cape (2002) where hunting is the most important form of game utilisation in terms of income generated. At the time of this study, respondents in KwaZulu-Natal reported an income of R 15 382 397 generated from live sales and R 13 561 459 from hunting. These respondents also indicated that the total value of game utilised annually was in excess of R 30 million. Although game utilisation is occurring on a sustainable basis, there is room for greater utilisation of some game species which, if undertaken correctly, can increase the revenue for the province significantly and also contribute positively to further sustainability of the game populations. KwaZulu-Natal’s competitive advantage is derived from the fact that there is an abundance of game on the ranches, quality trophy animals are available, the number of game species available for hunting and quality of service rendered to hunters by the professional hunters and ranch owners. This study has clearly shown that there is a need for further investigation into the game and hunting industries in KwaZulu-Natal.
- Full Text:
- Date Issued: 2007
- Authors: Kobus, Louann
- Date: 2007
- Subjects: Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10590 , http://hdl.handle.net/10948/534 , http://hdl.handle.net/10948/d1011724 , Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Description: The objectives of this research, were to investigate the characteristics and develop a profile of the game and hunting industries of KwaZulu-Natal, and to undertake a comparison between the game and hunting industries in KwaZulu-Natal and the Eastern Cape. The comparative part of this study was completed using results obtained from a study done in 2002 in the Eastern Cape (van Niekerk, 2002). The main farming activities in KwaZulu-Natal are large livestock production and sugar cane production. In recent years, private landowners in KwaZulu-Natal have undergone a transition from livestock production to game ranching due to the problems faced and the cost implications of the HIV epidemic, stock theft, difficulties faced with changes in the labour laws and the increasing number of land claims against farmers. Although the game and hunting industries are relatively young industries in KwaZulu-Natal they contribute significantly to the economy of the province. Not only is greater conservation of the biodiversity more effective in game ranching but it is also proving to yield great economic returns. The increase in game ranching in recent years is namely due to the monetary value placed on wildlife, the increased value in ecotourism and its value as an earner of foreign exchange, less dependency on unskilled labour than that of livestock farming and lower rates of animal loss through theft compared to that of livestock farming. In KwaZulu-Natal game numbers indicate that impala have the greatest population amongst the respondents, followed by nyala, blesbok, common reedbuck, kudu and blue wildebeest, whilst other game species occur in smaller numbers. Respondents in KwaZulu-Natal indicate that nyala is the largest economic earner for them followed by buffalo, whereas in the Eastern Cape (2002), kudu and springbok provide the greatest income for the province. In KwaZulu-Natal income generated from hunting is second to that of live game sales compared to the Eastern Cape (2002) where hunting is the most important form of game utilisation in terms of income generated. At the time of this study, respondents in KwaZulu-Natal reported an income of R 15 382 397 generated from live sales and R 13 561 459 from hunting. These respondents also indicated that the total value of game utilised annually was in excess of R 30 million. Although game utilisation is occurring on a sustainable basis, there is room for greater utilisation of some game species which, if undertaken correctly, can increase the revenue for the province significantly and also contribute positively to further sustainability of the game populations. KwaZulu-Natal’s competitive advantage is derived from the fact that there is an abundance of game on the ranches, quality trophy animals are available, the number of game species available for hunting and quality of service rendered to hunters by the professional hunters and ranch owners. This study has clearly shown that there is a need for further investigation into the game and hunting industries in KwaZulu-Natal.
- Full Text:
- Date Issued: 2007
Ionic liquids as media for electro-organic synthesis
- Authors: Kruger, Elna
- Date: 2007
- Subjects: Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10413 , http://hdl.handle.net/10948/538 , Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Description: The IL’s used in this study were either synthesized or commercially available. Preparation of the IL’s involved 2 step processes: firstly the heating of distilled 1-methylimidazole with distilled 1-chlorobutane under reflux to obtain 1-butyl-3- methylimidazolium chloride; secondly, the metathesis reaction of sodium tetrafluoroborate with 1-butyl-3-methylimidazolium chloride to obtain 1-butyl-3- methylimidazolium tetrafluoroborate. The addition of sodium tetrafluoroborate, sodium hexafluorophosphate and lithium trifluoromethane sulfonamide with 1-butyl-3-methylimidazolium chloride produced good yields of 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium hexafluorophosphate and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide respectively. The IL’s are hygroscopic and must be stored under a nitrogen atmosphere. The IL’s were analyzed using 1H and 13C NMR analysis with CDCl3 as solvent. The physical and chemical properties of these IL’s were compared to commercial products. The physical and chemical properties compared well to reference values from the literature. The physical properties measured include the density, conductivity and electrochemical window. The electrochemical window is dependant primarily on the resistance of the cation to reduction and the resistance of the anion to oxidation. The electrochemical windows of the IL’s were very similar to the reference windows obtained from literature and it can be seen that some IL’s have a slightly lower window which can be due to water present. Water content in the IL’s was determined with the use of a Karl Fischer titrator, with Hydranal 5 Composite as titrant and HPLC grade methanol as the base. The concentration of halide in the IL’s was determined with a Perkin-Elmer ICP-MS.
- Full Text:
- Date Issued: 2007
- Authors: Kruger, Elna
- Date: 2007
- Subjects: Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10413 , http://hdl.handle.net/10948/538 , Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Description: The IL’s used in this study were either synthesized or commercially available. Preparation of the IL’s involved 2 step processes: firstly the heating of distilled 1-methylimidazole with distilled 1-chlorobutane under reflux to obtain 1-butyl-3- methylimidazolium chloride; secondly, the metathesis reaction of sodium tetrafluoroborate with 1-butyl-3-methylimidazolium chloride to obtain 1-butyl-3- methylimidazolium tetrafluoroborate. The addition of sodium tetrafluoroborate, sodium hexafluorophosphate and lithium trifluoromethane sulfonamide with 1-butyl-3-methylimidazolium chloride produced good yields of 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium hexafluorophosphate and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide respectively. The IL’s are hygroscopic and must be stored under a nitrogen atmosphere. The IL’s were analyzed using 1H and 13C NMR analysis with CDCl3 as solvent. The physical and chemical properties of these IL’s were compared to commercial products. The physical and chemical properties compared well to reference values from the literature. The physical properties measured include the density, conductivity and electrochemical window. The electrochemical window is dependant primarily on the resistance of the cation to reduction and the resistance of the anion to oxidation. The electrochemical windows of the IL’s were very similar to the reference windows obtained from literature and it can be seen that some IL’s have a slightly lower window which can be due to water present. Water content in the IL’s was determined with the use of a Karl Fischer titrator, with Hydranal 5 Composite as titrant and HPLC grade methanol as the base. The concentration of halide in the IL’s was determined with a Perkin-Elmer ICP-MS.
- Full Text:
- Date Issued: 2007
A comparative analysis of the environmental impact of selected low-income housing developments in the Eastern Cape Province
- Authors: Kumm, Simon
- Date: 2007
- Subjects: Low-income housing -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Housing policy -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:8152 , http://hdl.handle.net/10948/539 , Low-income housing -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Housing policy -- South Africa -- Eastern Cape
- Description: South Africa has a shortage of affordable housing for its poor. In order to overcome the shortage, a large number of houses need to be built. The bulk building of these houses has an effect on the environment and it is important to note whether or not this impact will be a lasting positive one or not. Governmental policies have recognised the need to create positive, sustainable settlement environments. The degree to which settlements are sustainable and reflect a positive environment is, however, a point of concern. This dissertation analyses and compares four low-income housing developments in the Eastern Cape in order to make proposals on how future low-income developments can impact more positively on their settlement environments, reduce their impact on non-renewable resources and better implement the ideals of the Development Facilitation Act. This was done in order to meet the expectations put in place by Government policies and to correct the historical shortcomings of South Africa’s low-income settlement provision. The method used was to determine, through literature study, a set of factors that most prominently impacted on low-income settlement environments. These were then compiled into a model, which was then used to analyse and compare existing settlements. This elicited a set of conclusions based on the findings and provided strategies for future settlements to follow to meet the research’s stated ideals. The literature study revealed a myriad of important principles that fell into six main categories that impacted on settlement environments. Furthermore, it was discovered that each of these principles should be assessed in the context of their human and natural environments as well as their effect at the scale of the unit, the settlement and the city. The analysis and comparison of the settlements revealed that all six of the model’s categories performed poorly in at least two of the four settlements analysed, a strong indication that the implementation of the model’s principles was not being successfully achieved in low-income settlements. It further revealed specific areas requiring attention in future developments. The analysis also revealed positive areas of implementation from each settlement that can be used in future settlements to meet the stated ideals of creating a positive impact on their settlement environments, reducing their impact on non-renewable resources and better implementing the ideals of the Development Facilitation Act. The study recommends that future settlements avoid the negative practices identified in these settlements and implement the positive strategies proposed for the benefit of future settlement environments.
- Full Text:
- Date Issued: 2007
- Authors: Kumm, Simon
- Date: 2007
- Subjects: Low-income housing -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Housing policy -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:8152 , http://hdl.handle.net/10948/539 , Low-income housing -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Housing policy -- South Africa -- Eastern Cape
- Description: South Africa has a shortage of affordable housing for its poor. In order to overcome the shortage, a large number of houses need to be built. The bulk building of these houses has an effect on the environment and it is important to note whether or not this impact will be a lasting positive one or not. Governmental policies have recognised the need to create positive, sustainable settlement environments. The degree to which settlements are sustainable and reflect a positive environment is, however, a point of concern. This dissertation analyses and compares four low-income housing developments in the Eastern Cape in order to make proposals on how future low-income developments can impact more positively on their settlement environments, reduce their impact on non-renewable resources and better implement the ideals of the Development Facilitation Act. This was done in order to meet the expectations put in place by Government policies and to correct the historical shortcomings of South Africa’s low-income settlement provision. The method used was to determine, through literature study, a set of factors that most prominently impacted on low-income settlement environments. These were then compiled into a model, which was then used to analyse and compare existing settlements. This elicited a set of conclusions based on the findings and provided strategies for future settlements to follow to meet the research’s stated ideals. The literature study revealed a myriad of important principles that fell into six main categories that impacted on settlement environments. Furthermore, it was discovered that each of these principles should be assessed in the context of their human and natural environments as well as their effect at the scale of the unit, the settlement and the city. The analysis and comparison of the settlements revealed that all six of the model’s categories performed poorly in at least two of the four settlements analysed, a strong indication that the implementation of the model’s principles was not being successfully achieved in low-income settlements. It further revealed specific areas requiring attention in future developments. The analysis also revealed positive areas of implementation from each settlement that can be used in future settlements to meet the stated ideals of creating a positive impact on their settlement environments, reducing their impact on non-renewable resources and better implementing the ideals of the Development Facilitation Act. The study recommends that future settlements avoid the negative practices identified in these settlements and implement the positive strategies proposed for the benefit of future settlement environments.
- Full Text:
- Date Issued: 2007
Evolving a secure grid-enabled, distributed data warehouse : a standards-based perspective
- Authors: Li, Xiao-Yu
- Date: 2007
- Subjects: Computational grids (Computer systems) , Computer networks -- Security measures , Electronic data processing -- Distributed processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9738 , http://hdl.handle.net/10948/544 , Computational grids (Computer systems) , Computer networks -- Security measures , Electronic data processing -- Distributed processing
- Description: As digital data-collection has increased in scale and number, it becomes an important type of resource serving a wide community of researchers. Cross-institutional data-sharing and collaboration introduce a suitable approach to facilitate those research institutions that are suffering the lack of data and related IT infrastructures. Grid computing has become a widely adopted approach to enable cross-institutional resource-sharing and collaboration. It integrates a distributed and heterogeneous collection of locally managed users and resources. This project proposes a distributed data warehouse system, which uses Grid technology to enable data-access and integration, and collaborative operations across multi-distributed institutions in the context of HV/AIDS research. This study is based on wider research into OGSA-based Grid services architecture, comprising a data-analysis system which utilizes a data warehouse, data marts, and near-line operational database that are hosted by distributed institutions. Within this framework, specific patterns for collaboration, interoperability, resource virtualization and security are included. The heterogeneous and dynamic nature of the Grid environment introduces a number of security challenges. This study also concerns a set of particular security aspects, including PKI-based authentication, single sign-on, dynamic delegation, and attribute-based authorization. These mechanisms, as supported by the Globus Toolkit’s Grid Security Infrastructure, are used to enable interoperability and establish trust relationship between various security mechanisms and policies within different institutions; manage credentials; and ensure secure interactions.
- Full Text:
- Date Issued: 2007
- Authors: Li, Xiao-Yu
- Date: 2007
- Subjects: Computational grids (Computer systems) , Computer networks -- Security measures , Electronic data processing -- Distributed processing
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9738 , http://hdl.handle.net/10948/544 , Computational grids (Computer systems) , Computer networks -- Security measures , Electronic data processing -- Distributed processing
- Description: As digital data-collection has increased in scale and number, it becomes an important type of resource serving a wide community of researchers. Cross-institutional data-sharing and collaboration introduce a suitable approach to facilitate those research institutions that are suffering the lack of data and related IT infrastructures. Grid computing has become a widely adopted approach to enable cross-institutional resource-sharing and collaboration. It integrates a distributed and heterogeneous collection of locally managed users and resources. This project proposes a distributed data warehouse system, which uses Grid technology to enable data-access and integration, and collaborative operations across multi-distributed institutions in the context of HV/AIDS research. This study is based on wider research into OGSA-based Grid services architecture, comprising a data-analysis system which utilizes a data warehouse, data marts, and near-line operational database that are hosted by distributed institutions. Within this framework, specific patterns for collaboration, interoperability, resource virtualization and security are included. The heterogeneous and dynamic nature of the Grid environment introduces a number of security challenges. This study also concerns a set of particular security aspects, including PKI-based authentication, single sign-on, dynamic delegation, and attribute-based authorization. These mechanisms, as supported by the Globus Toolkit’s Grid Security Infrastructure, are used to enable interoperability and establish trust relationship between various security mechanisms and policies within different institutions; manage credentials; and ensure secure interactions.
- Full Text:
- Date Issued: 2007
A general genetic algorithm for one and two dimensional cutting and packing problems
- Authors: Mancapa, Vusisizwe
- Date: 2007
- Subjects: Packaging -- Data processing , Genetic algorithms , Cutting stock problem , Packing for shipment , Manufacturing processes -- Planning
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9602 , http://hdl.handle.net/10948/555 , http://hdl.handle.net/10948/d1011727 , Packaging -- Data processing , Genetic algorithms , Cutting stock problem , Packing for shipment , Manufacturing processes -- Planning
- Description: Cutting and packing problems are combinatorial optimisation problems. The major interest in these problems is their practical significance, in manufacturing and other business sectors. In most manufacturing situations a raw material usually in some standard size has to be divided or be cut into smaller items to complete the production of some product. Since the cost of this raw material usually forms a significant portion of the input costs, it is therefore desirable that this resource be used efficiently. A hybrid general genetic algorithm is presented in this work to solve one and two dimensional problems of this nature. The novelties with this algorithm are: A novel placement heuristic hybridised with a Genetic Algorithm is introduced and a general solution encoding scheme which is used to encode one dimensional and two dimensional problems is also introduced.
- Full Text:
- Date Issued: 2007
- Authors: Mancapa, Vusisizwe
- Date: 2007
- Subjects: Packaging -- Data processing , Genetic algorithms , Cutting stock problem , Packing for shipment , Manufacturing processes -- Planning
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9602 , http://hdl.handle.net/10948/555 , http://hdl.handle.net/10948/d1011727 , Packaging -- Data processing , Genetic algorithms , Cutting stock problem , Packing for shipment , Manufacturing processes -- Planning
- Description: Cutting and packing problems are combinatorial optimisation problems. The major interest in these problems is their practical significance, in manufacturing and other business sectors. In most manufacturing situations a raw material usually in some standard size has to be divided or be cut into smaller items to complete the production of some product. Since the cost of this raw material usually forms a significant portion of the input costs, it is therefore desirable that this resource be used efficiently. A hybrid general genetic algorithm is presented in this work to solve one and two dimensional problems of this nature. The novelties with this algorithm are: A novel placement heuristic hybridised with a Genetic Algorithm is introduced and a general solution encoding scheme which is used to encode one dimensional and two dimensional problems is also introduced.
- Full Text:
- Date Issued: 2007
Analysis of fuel consumption reduction potential through the use of an electrically driven air conditioning compressor
- Authors: Marais, Charel
- Date: 2007
- Subjects: Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9623 , http://hdl.handle.net/10948/774 , Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Description: The disturbing current situation regarding the world climate has initiated a major wave of urgent developments towards decreasing the overall impact of human activities on the living environment. A major role player in this development is the automobile industry that is inherently connected to pollution of various types, be it air, water or noise pollution. There have been drastic changes not only in the technologies employed in producing vehicles and components, but also in the construction and technologies built into modern automobiles to lessen the overall environmental impact of the industry. Noxious emissions have been decreased, overall efficiencies increased and vehicles are becoming more economical with each new generation. Stricter laws dictate that the level of acceptable vehicle emissions is to be decreased ever further and all manufacturers are developing various possibilities to achieve this. With the emergence of hybrid vehicle technology, there was also a sudden development of different electrical systems that were made viable by the higher onboard voltage systems employed in hybrid vehicles. One of these developments was the electrical air conditioning compressor for use in automobile applications. Although it is designed to operate with a higher voltage than the traditional 12V onboard vehicle systems, it is theoretically possible to incorporate it into a 12V system by making use of a DC-DC converter to step up the supply voltage of the electrical compressor sufficiently to allow for its successful operation. The question therefore arises whether it would be feasible and sensible to employ an electrical air conditioning system in conventional combustion engine vehicles from an overall fuel consumption and vehicle emissions point of view. A modelling approach was taken where an overall vehicle driving simulation was created to represent an average modern production vehicle. The simulation was then extended to include the options of incorporating models for both mechanically and electrically driven air conditioning systems. This provides insight into the influences of the air conditioning system on the vehicle’s overall fuel consumption and an opportunity to compare the influences from the two different systems. This study attempted to provide answers to some of the viability questions regarding the incorporation of electrically driven air conditioning systems into vehicles that use standard 12V onboard voltage systems. It was found that the electrical system has definite potential as a viable replacement option for the conventional system should it be combined with an appropriate alternator and equipped with an efficient control system.
- Full Text:
- Date Issued: 2007
- Authors: Marais, Charel
- Date: 2007
- Subjects: Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9623 , http://hdl.handle.net/10948/774 , Automobiles -- Air conditioning , Electric vehicles -- Power supply , Automobiles -- Fuel systems , Electric automobiles
- Description: The disturbing current situation regarding the world climate has initiated a major wave of urgent developments towards decreasing the overall impact of human activities on the living environment. A major role player in this development is the automobile industry that is inherently connected to pollution of various types, be it air, water or noise pollution. There have been drastic changes not only in the technologies employed in producing vehicles and components, but also in the construction and technologies built into modern automobiles to lessen the overall environmental impact of the industry. Noxious emissions have been decreased, overall efficiencies increased and vehicles are becoming more economical with each new generation. Stricter laws dictate that the level of acceptable vehicle emissions is to be decreased ever further and all manufacturers are developing various possibilities to achieve this. With the emergence of hybrid vehicle technology, there was also a sudden development of different electrical systems that were made viable by the higher onboard voltage systems employed in hybrid vehicles. One of these developments was the electrical air conditioning compressor for use in automobile applications. Although it is designed to operate with a higher voltage than the traditional 12V onboard vehicle systems, it is theoretically possible to incorporate it into a 12V system by making use of a DC-DC converter to step up the supply voltage of the electrical compressor sufficiently to allow for its successful operation. The question therefore arises whether it would be feasible and sensible to employ an electrical air conditioning system in conventional combustion engine vehicles from an overall fuel consumption and vehicle emissions point of view. A modelling approach was taken where an overall vehicle driving simulation was created to represent an average modern production vehicle. The simulation was then extended to include the options of incorporating models for both mechanically and electrically driven air conditioning systems. This provides insight into the influences of the air conditioning system on the vehicle’s overall fuel consumption and an opportunity to compare the influences from the two different systems. This study attempted to provide answers to some of the viability questions regarding the incorporation of electrically driven air conditioning systems into vehicles that use standard 12V onboard voltage systems. It was found that the electrical system has definite potential as a viable replacement option for the conventional system should it be combined with an appropriate alternator and equipped with an efficient control system.
- Full Text:
- Date Issued: 2007
Establishing the benefits of implementing an I.T. project management office in the Nelson Mandela Metropolitan area
- Martin, Michael Ronald Charles
- Authors: Martin, Michael Ronald Charles
- Date: 2007
- Subjects: Project management -- South Africa -- Port Elizabeth -- Computer network resources , Information technology -- South Africa -- Port Elizabeth -- Management
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9266 , http://hdl.handle.net/10948/558 , Project management -- South Africa -- Port Elizabeth -- Computer network resources , Information technology -- South Africa -- Port Elizabeth -- Management
- Description: The well-known concept of a Project Manager managing an I.T. project in relative isolation is no longer a viable option for organisations that are running numerous projects simultaneously. Due to the enormous costs and risks involved in many of these projects, there needs to be a means to ensure success. This has led to the establishment of the concept of a Project Management Office (PMO). An autonomous business unit that is responsible for managing all projects within an organisation. The need for a Project Management Office (PMO) to effectively manage multiple projects is becoming more and more accepted worldwide. The benefits of a PMO are well documented, but whether these benefits will apply to organisations within the NMM area needed to be investigated. A detailed analysis of the benefits of Project Management and in particular a PMO, have been investigated by means of a literature study. An investigation into the effectiveness of PMO’s in South Africa in general, was conducted by means of a survey targeted at a group of I.T. Project Managers located in all the major centres. A further survey was conducted among local I.T. managers to determine their current level of success and their expectations for the future. When reviewing the expectations of local I.T. management against the performance of Project Managers that are currently operating within PMOs, it is clear that organisations within the NMM area are in need of PMO’s and would certainly benefit from their establishment.
- Full Text:
- Date Issued: 2007
- Authors: Martin, Michael Ronald Charles
- Date: 2007
- Subjects: Project management -- South Africa -- Port Elizabeth -- Computer network resources , Information technology -- South Africa -- Port Elizabeth -- Management
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9266 , http://hdl.handle.net/10948/558 , Project management -- South Africa -- Port Elizabeth -- Computer network resources , Information technology -- South Africa -- Port Elizabeth -- Management
- Description: The well-known concept of a Project Manager managing an I.T. project in relative isolation is no longer a viable option for organisations that are running numerous projects simultaneously. Due to the enormous costs and risks involved in many of these projects, there needs to be a means to ensure success. This has led to the establishment of the concept of a Project Management Office (PMO). An autonomous business unit that is responsible for managing all projects within an organisation. The need for a Project Management Office (PMO) to effectively manage multiple projects is becoming more and more accepted worldwide. The benefits of a PMO are well documented, but whether these benefits will apply to organisations within the NMM area needed to be investigated. A detailed analysis of the benefits of Project Management and in particular a PMO, have been investigated by means of a literature study. An investigation into the effectiveness of PMO’s in South Africa in general, was conducted by means of a survey targeted at a group of I.T. Project Managers located in all the major centres. A further survey was conducted among local I.T. managers to determine their current level of success and their expectations for the future. When reviewing the expectations of local I.T. management against the performance of Project Managers that are currently operating within PMOs, it is clear that organisations within the NMM area are in need of PMO’s and would certainly benefit from their establishment.
- Full Text:
- Date Issued: 2007
Information security awareness: generic content, tools and techniques
- Authors: Mauwa, Hope
- Date: 2007
- Subjects: Computer security , Data protection , Computers -- Safety measures , Information technology -- Security measures
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9733 , http://hdl.handle.net/10948/560 , Computer security , Data protection , Computers -- Safety measures , Information technology -- Security measures
- Description: In today’s computing environment, awareness programmes play a much more important role in organizations’ complete information security programmes. Information security awareness programmes are there to change behaviour or reinforce good security practices, and provide a baseline of security knowledge for all information users. Security awareness is a learning process, which changes individual and organizational attitudes and perceptions so that the importance of security and the adverse consequences of its failure are realized. Therefore, with proper awareness, employees become the most effective layer in an organization’s security defence. With the important role that these awareness programmes play in organizations’ complete information security programmes, it is a must that all organizations that are serious about information security must implement it. But though awareness programmes have become increasing important, the level of awareness in most organizations is still low. It seems that the current approach of developing these programmes does not satisfy the needs of most organizations. Therefore, another approach, which tries to meet the needs of most organizations, is proposed in this project as part of the solution of raising the level of awareness programmes in organizations.
- Full Text:
- Date Issued: 2007
- Authors: Mauwa, Hope
- Date: 2007
- Subjects: Computer security , Data protection , Computers -- Safety measures , Information technology -- Security measures
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9733 , http://hdl.handle.net/10948/560 , Computer security , Data protection , Computers -- Safety measures , Information technology -- Security measures
- Description: In today’s computing environment, awareness programmes play a much more important role in organizations’ complete information security programmes. Information security awareness programmes are there to change behaviour or reinforce good security practices, and provide a baseline of security knowledge for all information users. Security awareness is a learning process, which changes individual and organizational attitudes and perceptions so that the importance of security and the adverse consequences of its failure are realized. Therefore, with proper awareness, employees become the most effective layer in an organization’s security defence. With the important role that these awareness programmes play in organizations’ complete information security programmes, it is a must that all organizations that are serious about information security must implement it. But though awareness programmes have become increasing important, the level of awareness in most organizations is still low. It seems that the current approach of developing these programmes does not satisfy the needs of most organizations. Therefore, another approach, which tries to meet the needs of most organizations, is proposed in this project as part of the solution of raising the level of awareness programmes in organizations.
- Full Text:
- Date Issued: 2007
Analysing the effect of FSP on MIG-laser hybrid welded 6082-T6 AA joints
- Authors: Mjali, Kadephi Vuyolwethu
- Date: 2007
- Subjects: Friction stir welding
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9610 , http://hdl.handle.net/10948/563 , Friction stir welding
- Description: Friction Stir Processing (FSP) of aluminium alloys has been used to modify and improve the microstructure and relevant properties of fusion welded aluminium alloys. The effect of FSP on MIG-Laser Hybrid (MLH) welded aluminium alloy 6082-T6 mechanical and microstructural properties has been studied in this research. The FSP process was used on 6mm thick aluminium alloy plates and a tool was designed specifically for FSP, and the effect of varying speeds was analysed before the final FSP welds were made. The effect of FSP was analysed by optical microscopy, tensile, microhardness and fatigue testing. The aim of the study was to determine whether the FSP process has a beneficial influence on the mechanical properties and metallurgical integrity of MIG-Laser Hybrid welded 6082-T6 aluminium alloy with varying gap tolerances. Three welding processes were compared, namely combined Friction Stir Processing on MIG-Laser hybrid process (FSP-MLH), MLH and Friction Stir Welding (FSW) as part of the analysis. (FSP was carried out on MLH components when it was found that FSP is not an entirely complete welding process but rather a finishing process per se.) The aim of this dissertation is to investigate the effects of the FSP process on the weld quality of MLH welded joints and also to compare this to individual processes like FSW and MLH. This investigation was undertaken in order to gain an understanding of the effect of these processes on fatigue performance and microhardness distribution on aluminium alloy 6082-T6 weld joints.
- Full Text:
- Date Issued: 2007
- Authors: Mjali, Kadephi Vuyolwethu
- Date: 2007
- Subjects: Friction stir welding
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:9610 , http://hdl.handle.net/10948/563 , Friction stir welding
- Description: Friction Stir Processing (FSP) of aluminium alloys has been used to modify and improve the microstructure and relevant properties of fusion welded aluminium alloys. The effect of FSP on MIG-Laser Hybrid (MLH) welded aluminium alloy 6082-T6 mechanical and microstructural properties has been studied in this research. The FSP process was used on 6mm thick aluminium alloy plates and a tool was designed specifically for FSP, and the effect of varying speeds was analysed before the final FSP welds were made. The effect of FSP was analysed by optical microscopy, tensile, microhardness and fatigue testing. The aim of the study was to determine whether the FSP process has a beneficial influence on the mechanical properties and metallurgical integrity of MIG-Laser Hybrid welded 6082-T6 aluminium alloy with varying gap tolerances. Three welding processes were compared, namely combined Friction Stir Processing on MIG-Laser hybrid process (FSP-MLH), MLH and Friction Stir Welding (FSW) as part of the analysis. (FSP was carried out on MLH components when it was found that FSP is not an entirely complete welding process but rather a finishing process per se.) The aim of this dissertation is to investigate the effects of the FSP process on the weld quality of MLH welded joints and also to compare this to individual processes like FSW and MLH. This investigation was undertaken in order to gain an understanding of the effect of these processes on fatigue performance and microhardness distribution on aluminium alloy 6082-T6 weld joints.
- Full Text:
- Date Issued: 2007
Synthesis of P-Methane-3,8-Diol
- Authors: Mpuhlu, Batsho
- Date: 2007
- Subjects: Insect baits and repellents
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10411 , http://hdl.handle.net/10948/570 , http://hdl.handle.net/10948/d1011717 , Insect baits and repellents
- Description: The synthesis of para-menthane-3,8-diol in a batch reactor was investigated in some detail with the view to evaluate the potential of producing said p-menthane- 3,8-diol in a continuous-flow reactor from the results obtained from the batch process. The methodology used as base for this investigation was a published procedure by Takasago of Japan. The Takasago-method produced 92.3 percent Yield for the product para-menthane-3,8-diol, and 2.7 percent Yield of the by-product, acetal. The objective for this investigation was to produce a minimum p-menthane-3,8- diol content of 97.0 percent and a maximum content of 3.0 percent for the by-product acetal. The batch production process was evaluated in detail using statistical experimental design methodologies. Three process variables, namely catalyst loading, organic/aqueous phase ratio and reaction temperature were selected for the study. The experimental method was based on the Takasago procedure, however the substrate was added as a single slug as opposed to gradual addition method and the reaction period was reduced to 30 minutes. Apart from statistical analysis, mechanistic aspects were also used to interpret the following results. Using a central composite design, three response models (one for the conversion of citronellal, p-menthane-3,8-diol and acetal formation) were determined. An analysis of the response surfaces indicated that, to increase the citronellal conversion all three variables should be increased. To increase the amount of pmenthane- 3,8-diol, the reaction temperature and acid concentration should be increased, but the Aq/org ratio should be decreased as the acid catalyst concentration is increased. To minimize the amount of acetals formed during the reaction, the Aq/org ratio should be decreased; temperature and acid concentration can be decreased or increased. The reaction mechanism suggested that p-menthane-3,8-diol may be formed along two pathways: One pathway directly forms p-menthane-3,8-diol, whilst the second pathway forms the isopulegol first, then proceeds to form product by hydrolysis. The acetal is formed as result of the reaction between unreacted citronellal and p-menthane-3,8-diol. From the design experiments it was suggested that reaction time can be reduced to 8 minutes at reaction temperatures between, 80-85 0C The product and acetal were isolated by simple vacuum evaporation of the low boiling citronellal and isopulegol. Results from recycling the catalyst phase were similar to those of the initial process. The results of this investigation has clearly shown that with a proper understanding of the effect of process variables on the performance of the batch synthesis route, the conversion of this traditionally batch (actually semi-batch) process into a continuous process is quite feasible provided that suitable equipment is available. The most important features required for such equipment would be: Intense mixing throughout the reaction zone so as to maximise the surface area between the two immiscible phases, hence the rate of mass transfer between the two phases; and the ability to run reactions above the boiling point of water. Plans for the further study of the process are already well underway and sections of static mixing tubes have been acquired to build a continuous lab scale tubular reactor that would be capable of providing the level of mixing required.
- Full Text:
- Date Issued: 2007
- Authors: Mpuhlu, Batsho
- Date: 2007
- Subjects: Insect baits and repellents
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10411 , http://hdl.handle.net/10948/570 , http://hdl.handle.net/10948/d1011717 , Insect baits and repellents
- Description: The synthesis of para-menthane-3,8-diol in a batch reactor was investigated in some detail with the view to evaluate the potential of producing said p-menthane- 3,8-diol in a continuous-flow reactor from the results obtained from the batch process. The methodology used as base for this investigation was a published procedure by Takasago of Japan. The Takasago-method produced 92.3 percent Yield for the product para-menthane-3,8-diol, and 2.7 percent Yield of the by-product, acetal. The objective for this investigation was to produce a minimum p-menthane-3,8- diol content of 97.0 percent and a maximum content of 3.0 percent for the by-product acetal. The batch production process was evaluated in detail using statistical experimental design methodologies. Three process variables, namely catalyst loading, organic/aqueous phase ratio and reaction temperature were selected for the study. The experimental method was based on the Takasago procedure, however the substrate was added as a single slug as opposed to gradual addition method and the reaction period was reduced to 30 minutes. Apart from statistical analysis, mechanistic aspects were also used to interpret the following results. Using a central composite design, three response models (one for the conversion of citronellal, p-menthane-3,8-diol and acetal formation) were determined. An analysis of the response surfaces indicated that, to increase the citronellal conversion all three variables should be increased. To increase the amount of pmenthane- 3,8-diol, the reaction temperature and acid concentration should be increased, but the Aq/org ratio should be decreased as the acid catalyst concentration is increased. To minimize the amount of acetals formed during the reaction, the Aq/org ratio should be decreased; temperature and acid concentration can be decreased or increased. The reaction mechanism suggested that p-menthane-3,8-diol may be formed along two pathways: One pathway directly forms p-menthane-3,8-diol, whilst the second pathway forms the isopulegol first, then proceeds to form product by hydrolysis. The acetal is formed as result of the reaction between unreacted citronellal and p-menthane-3,8-diol. From the design experiments it was suggested that reaction time can be reduced to 8 minutes at reaction temperatures between, 80-85 0C The product and acetal were isolated by simple vacuum evaporation of the low boiling citronellal and isopulegol. Results from recycling the catalyst phase were similar to those of the initial process. The results of this investigation has clearly shown that with a proper understanding of the effect of process variables on the performance of the batch synthesis route, the conversion of this traditionally batch (actually semi-batch) process into a continuous process is quite feasible provided that suitable equipment is available. The most important features required for such equipment would be: Intense mixing throughout the reaction zone so as to maximise the surface area between the two immiscible phases, hence the rate of mass transfer between the two phases; and the ability to run reactions above the boiling point of water. Plans for the further study of the process are already well underway and sections of static mixing tubes have been acquired to build a continuous lab scale tubular reactor that would be capable of providing the level of mixing required.
- Full Text:
- Date Issued: 2007
Investigating the influences of validation on pharmaceutical manufacturing processes
- Authors: Muller, Damian Christian
- Date: 2007
- Subjects: Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10412 , http://hdl.handle.net/10948/566 , Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Description: This investigation attempts to examine the influences of validation on pharmaceutical processes especially at a new manufacturing facility that has to meet international requirements, and fulfil a cost effective business strategy. At Aspen Pharmacare, a pharmaceutical organisation, there are two manufacturing facilities situated adjacent to each other, one new and one old. The new facility creates ideal opportunities to supply products to local and international markets. The investigation compares legal requirements from local and international regulatory authorities. Validation and qualification practices as well as the problems encountered during the different phases are discussed. Particular attention is given to the validation approach at the new Aspen facility. Problems and proposed solutions relating to the design review, installation, operational, and performance qualification are discussed. Validation of analytical methods for cleaning analysis, cleaning validation of equipment, and optimisation of some tablet manufacturing processes are described. Statistical evaluations of analytical results are included to find the optimum conditions for integrating new personnel with new processes and equipment. A business model reviews the cost of non-conformances of the enalapril maleate 10 mg tablets manufactured at the two manufacturing facilities. Finally the dissertation proves that validation is not only a regulatory requirement but that it also provides benefits such as adding value to the business, and ultimately reducing the cost of medicines.
- Full Text:
- Date Issued: 2007
- Authors: Muller, Damian Christian
- Date: 2007
- Subjects: Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10412 , http://hdl.handle.net/10948/566 , Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Description: This investigation attempts to examine the influences of validation on pharmaceutical processes especially at a new manufacturing facility that has to meet international requirements, and fulfil a cost effective business strategy. At Aspen Pharmacare, a pharmaceutical organisation, there are two manufacturing facilities situated adjacent to each other, one new and one old. The new facility creates ideal opportunities to supply products to local and international markets. The investigation compares legal requirements from local and international regulatory authorities. Validation and qualification practices as well as the problems encountered during the different phases are discussed. Particular attention is given to the validation approach at the new Aspen facility. Problems and proposed solutions relating to the design review, installation, operational, and performance qualification are discussed. Validation of analytical methods for cleaning analysis, cleaning validation of equipment, and optimisation of some tablet manufacturing processes are described. Statistical evaluations of analytical results are included to find the optimum conditions for integrating new personnel with new processes and equipment. A business model reviews the cost of non-conformances of the enalapril maleate 10 mg tablets manufactured at the two manufacturing facilities. Finally the dissertation proves that validation is not only a regulatory requirement but that it also provides benefits such as adding value to the business, and ultimately reducing the cost of medicines.
- Full Text:
- Date Issued: 2007