- Title
- Formation, surface characterization, and electrocatalytic application of self-assembled monolayer films of tetra-substituted manganese, iron, and cobalt benzylthio phthalocyanine complexes
- Creator
- Akinbulu, Isaac Adebayo
- Creator
- Ozoemena, Kenneth Iyke
- Creator
- Nyokong, Tebello
- Subject
- To be catalogued
- Date Issued
- 2011
- Date
- 2011
- Type
- text
- Type
- article
- Identifier
- http://hdl.handle.net/10962/247163
- Identifier
- vital:51552
- Identifier
- xlink:href="https://doi.org/10.1007/s10008-010-1243-1"
- Description
- Molecular thin films of manganese (SAM-2), iron (SAM-3), and cobalt (SAM-4) phthalocyanine complexes, non-peripherally tetra-substituted with benzylmercapto, were formed on polycrystalline gold disc electrode by self-assembly technique. Surface characteristics of the films were interrogated by cyclic voltammetry. Significant passivation of voltammetry processes associated with bare gold surface (gold oxidation and underpotential deposition of copper) confirmed formation of the films. Electrocatalytic property of the films was evidenced from better voltammetry responses (less positive oxidation potential and better current signal) of the insecticide, carbofuran, on these films, relative to that on bare gold electrode. In terms of less positive oxidation potential, the FePc derivative (3) gave the best response, while the best current signal was observed on SAM-2-modified gold electrode. The average heterogeneous rate constant, k, for the oxidation of carbofuran was 3.6 × 10−2 cm s−1 on the SAM film with the best current signal (SAM-2).
- Format
- computer
- Format
- online resource
- Format
- application/pdf
- Format
- 1 online resource (13 pages)
- Format
- Publisher
- Elsevier
- Language
- English
- Relation
- Journal of Solid State Electrochemistry
- Relation
- Akinbulu, I.A., Ozoemena, K.I. and Nyokong, T., 2011. Formation, surface characterization, and electrocatalytic application of self-assembled monolayer films of tetra-substituted manganese, iron, and cobalt benzylthio phthalocyanine complexes. Journal of Solid State Electrochemistry, 15(10), pp.2239-2251
- Relation
- Journal of Solid State Electrochemistry volume 15 number 10 p. 2239 2011 1433-0768
- Rights
- Publisher
- Rights
- Use of this resource is governed by the terms and conditions of the Elsevier Terms and Conditions Statement (https://www.elsevier.com/legal/elsevier-website-terms-and-conditions)
- Rights
- Closed Access
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Collections
Nyokong, Tebello (Distinguished Professor)
RU DST/NRF SARChI for Medicinal Chemistry and Nanotechnology
RU Department of Chemistry
| Thumbnail | File | Description | Size | Format | |||
|---|---|---|---|---|---|---|---|
| View Details Download | SOURCE1 | Formation, surface characterization, and electrocatalytic application of self-assembled monolayer films.pdf | 1 MB | Adobe Acrobat PDF | View Details Download |