A Hall-effect study of as-grown and hydrogenerated n-type ZnO layers grown by MOCVD
- Somhlahlo, Nomabali Nelisiwe
- Authors: Somhlahlo, Nomabali Nelisiwe
- Date: 2006
- Subjects: Hall effect , Electric currents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10535 , http://hdl.handle.net/10948/444 , http://hdl.handle.net/10948/d1012014 , Hall effect , Electric currents
- Description: A series of as-grown ZnO layers have been electrically characterised by the temperature dependent (20 – 300 K) Hall-effect technique. The ZnO layers were grown by metal organic chemical vapour deposition (MOCVD) on glass substrates under various growth conditions. The temperature dependent Hall-effect technique produced mobility and carrier concentration measurements. These measurements were found to be reproducible and reliable. The carrier concentration data for the layers was fitted by the charge balance equation to accurately determine the donor level and corresponding donor concentration as well as the acceptor concentration for each sample. The measured donor levels were found to vary from sample to sample and there is evidence from the results that the variations are related to the differing growth conditions of the layers. The mobility data was also fitted to establish the dominant electron scattering mechanisms in the layers. The dominant scattering mechanisms were found to vary from sample to sample. For most of the layers studied, the dominant scattering mechanism was found to be both the ionised impurity scattering at low temperatures (20 – 100 K) and grain boundary scattering at higher temperatures (100 – 300 K). The effects of exposing the ZnO layers to hydrogen plasma were also investigated by the temperature dependent Hall-effect technique. Findings indicate that hydrogen is readily incorporated in ZnO, leading always to an increased carrier concentration. It was further noted that incorporating hydrogen into ZnO in some layers increased the mobility while in other layers it caused a decrease in the mobility. The hydrogenated samples were subsequently annealed at 600 °C for 1 hour in argon ambient resulting in the carrier concentration reducing to its original value. This effect is attributed to hydrogen diffusing out of ZnO.
- Full Text:
- Date Issued: 2006
- Authors: Somhlahlo, Nomabali Nelisiwe
- Date: 2006
- Subjects: Hall effect , Electric currents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10535 , http://hdl.handle.net/10948/444 , http://hdl.handle.net/10948/d1012014 , Hall effect , Electric currents
- Description: A series of as-grown ZnO layers have been electrically characterised by the temperature dependent (20 – 300 K) Hall-effect technique. The ZnO layers were grown by metal organic chemical vapour deposition (MOCVD) on glass substrates under various growth conditions. The temperature dependent Hall-effect technique produced mobility and carrier concentration measurements. These measurements were found to be reproducible and reliable. The carrier concentration data for the layers was fitted by the charge balance equation to accurately determine the donor level and corresponding donor concentration as well as the acceptor concentration for each sample. The measured donor levels were found to vary from sample to sample and there is evidence from the results that the variations are related to the differing growth conditions of the layers. The mobility data was also fitted to establish the dominant electron scattering mechanisms in the layers. The dominant scattering mechanisms were found to vary from sample to sample. For most of the layers studied, the dominant scattering mechanism was found to be both the ionised impurity scattering at low temperatures (20 – 100 K) and grain boundary scattering at higher temperatures (100 – 300 K). The effects of exposing the ZnO layers to hydrogen plasma were also investigated by the temperature dependent Hall-effect technique. Findings indicate that hydrogen is readily incorporated in ZnO, leading always to an increased carrier concentration. It was further noted that incorporating hydrogen into ZnO in some layers increased the mobility while in other layers it caused a decrease in the mobility. The hydrogenated samples were subsequently annealed at 600 °C for 1 hour in argon ambient resulting in the carrier concentration reducing to its original value. This effect is attributed to hydrogen diffusing out of ZnO.
- Full Text:
- Date Issued: 2006
Our society, our university, our challenges and responsibilities
- Authors: Badat, Saleem
- Date: 2006
- Language: English
- Type: Text
- Identifier: vital:574 , http://hdl.handle.net/10962/d1006567
- Description: Inaugural address of the Vice-Chancellor of Rhodes University, Dr. Saleem Badat
- Full Text:
- Date Issued: 2006
- Authors: Badat, Saleem
- Date: 2006
- Language: English
- Type: Text
- Identifier: vital:574 , http://hdl.handle.net/10962/d1006567
- Description: Inaugural address of the Vice-Chancellor of Rhodes University, Dr. Saleem Badat
- Full Text:
- Date Issued: 2006
Maximum likelihood and Bayesian approaches to stock assessment when data are questionable
- Booth, Anthony J, Quinn II, T J
- Authors: Booth, Anthony J , Quinn II, T J
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6764 , http://hdl.handle.net/10962/d1007962
- Description: This study examines the use of age-structured maximum likelihood and Bayesian approaches for stock assessment of the Namibian monkfish, Lophius vomerinus, resource with questionable data, in which time series are short, abundance indices are variable, and research data conflict with commercial data. Bayesian approaches with both noninformative and informative priors are investigated to determine if they enhance estimation stability. Three data scenarios are assessed: commercial and research survey data, research survey data only, and commercial data only. Both statistical approaches show that resource abundance has decreased with exploitable biomass estimated at approximately 44% of pristine levels. The maximum likelihood and the Bayesian approach with noninformative priors result in similar estimates. As the abundance data contained little information pertaining to possible density dependence within the stock–recruit relationship, only a Bayesian approach with informative priors reduces uncertainty in the steepness parameter h. Estimated management quantities are sensitive both to the set of data sources and whether prior information was informative or not. The strengths of the Bayesian approach include the integration of prior information with uncertain data, the exploration of data conflicts, and the ability to show the uncertainty in estimates of management parameters. Its weakness is that estimation stability is dependent on the choice of priors, which alters some posterior distributions of management quantities.
- Full Text:
- Date Issued: 2006
- Authors: Booth, Anthony J , Quinn II, T J
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6764 , http://hdl.handle.net/10962/d1007962
- Description: This study examines the use of age-structured maximum likelihood and Bayesian approaches for stock assessment of the Namibian monkfish, Lophius vomerinus, resource with questionable data, in which time series are short, abundance indices are variable, and research data conflict with commercial data. Bayesian approaches with both noninformative and informative priors are investigated to determine if they enhance estimation stability. Three data scenarios are assessed: commercial and research survey data, research survey data only, and commercial data only. Both statistical approaches show that resource abundance has decreased with exploitable biomass estimated at approximately 44% of pristine levels. The maximum likelihood and the Bayesian approach with noninformative priors result in similar estimates. As the abundance data contained little information pertaining to possible density dependence within the stock–recruit relationship, only a Bayesian approach with informative priors reduces uncertainty in the steepness parameter h. Estimated management quantities are sensitive both to the set of data sources and whether prior information was informative or not. The strengths of the Bayesian approach include the integration of prior information with uncertain data, the exploration of data conflicts, and the ability to show the uncertainty in estimates of management parameters. Its weakness is that estimation stability is dependent on the choice of priors, which alters some posterior distributions of management quantities.
- Full Text:
- Date Issued: 2006
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