Development of manganese phthalocyanine decorated with silver nanoparticles nanocomposite for improved electrocatalytic oxidation of hydrazine:
- Mpeta, Lekhetho S, Sen, Pinar, Nyokong, Tebello
- Authors: Mpeta, Lekhetho S , Sen, Pinar , Nyokong, Tebello
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148472 , vital:38742 , https://doi.org/10.1016/j.jelechem.2020.114173
- Description: In this study we report on the synthesis of tetrakis [4-(4-(5-chloro-1H-benzo [d]imidazol-2-yl) phenoxy phthalocyaninato] manganese (III) chloride (MnPc). The MnPc was first used to modify a glassy carbon electrode, followed by the growth of silver nanoparticles (AgNPs) onto the MnPc modified electrode to form MnPc-AgNPs modified electrode. The modified electrode was characterized using cydic voltammetry, chronoamperometry, scanning electrochemical microscopy and electrochemical impedance spectroscopy. The modified MnPc-AgNPs electrode was employed for the detection of hydrazine. The MnPc-AgNPs gave better current responses for electrooxidation of hydrazine relative to MnPc and AgNPs, individually. The catalytic rate constant was 1.90 x 10(5 )M(-1) S-1, with the detection limit (LoD) of 2.42 pM (using 3 sigma notation), and sensitivity of 61.56 mu A mM(-1), for MnPc-AgNPs. (C) 2020 Elsevier B.V. All rights reserved.
- Full Text:
- Date Issued: 2020
- Authors: Mpeta, Lekhetho S , Sen, Pinar , Nyokong, Tebello
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148472 , vital:38742 , https://doi.org/10.1016/j.jelechem.2020.114173
- Description: In this study we report on the synthesis of tetrakis [4-(4-(5-chloro-1H-benzo [d]imidazol-2-yl) phenoxy phthalocyaninato] manganese (III) chloride (MnPc). The MnPc was first used to modify a glassy carbon electrode, followed by the growth of silver nanoparticles (AgNPs) onto the MnPc modified electrode to form MnPc-AgNPs modified electrode. The modified electrode was characterized using cydic voltammetry, chronoamperometry, scanning electrochemical microscopy and electrochemical impedance spectroscopy. The modified MnPc-AgNPs electrode was employed for the detection of hydrazine. The MnPc-AgNPs gave better current responses for electrooxidation of hydrazine relative to MnPc and AgNPs, individually. The catalytic rate constant was 1.90 x 10(5 )M(-1) S-1, with the detection limit (LoD) of 2.42 pM (using 3 sigma notation), and sensitivity of 61.56 mu A mM(-1), for MnPc-AgNPs. (C) 2020 Elsevier B.V. All rights reserved.
- Full Text:
- Date Issued: 2020
Examining intraspecific multiple predator effects across shifting predator sex ratios:
- Cuthbert, Ross N, Dalu, Tatenda, Wasserman, Ryan J, Weyl, Olaf L F, Froneman, P William, Callaghan, Amanda, Dick, Jaimie T A
- Authors: Cuthbert, Ross N , Dalu, Tatenda , Wasserman, Ryan J , Weyl, Olaf L F , Froneman, P William , Callaghan, Amanda , Dick, Jaimie T A
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150119 , vital:38941 , https://doi.org/10.1016/j.baae.2020.03.002
- Description: Predator-predator interactions, or “multiple predator effects” (MPEs), are pervasive in the structuring of communities and complicate predictive quantifications of ecosystem dynamics. The nature of MPEs is also context-dependent, manifesting differently among species, prey densities and habitat structures. However, there has hitherto been a lack of consideration for the implications of intraspecific demographic variation within populations for the strength of MPEs. The present study extends MPE concepts to examine intraspecific interactions among male and female predators across differences in prey densities using a functional response approach. Focusing on a copepod-mosquito model predator-prey system, interaction strengths of different sex ratio pairs of Lovenula raynerae were quantified towards larval Culex pipiens complex prey, with observations compared to both additive and substitutive model predictions.
- Full Text:
- Date Issued: 2020
- Authors: Cuthbert, Ross N , Dalu, Tatenda , Wasserman, Ryan J , Weyl, Olaf L F , Froneman, P William , Callaghan, Amanda , Dick, Jaimie T A
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150119 , vital:38941 , https://doi.org/10.1016/j.baae.2020.03.002
- Description: Predator-predator interactions, or “multiple predator effects” (MPEs), are pervasive in the structuring of communities and complicate predictive quantifications of ecosystem dynamics. The nature of MPEs is also context-dependent, manifesting differently among species, prey densities and habitat structures. However, there has hitherto been a lack of consideration for the implications of intraspecific demographic variation within populations for the strength of MPEs. The present study extends MPE concepts to examine intraspecific interactions among male and female predators across differences in prey densities using a functional response approach. Focusing on a copepod-mosquito model predator-prey system, interaction strengths of different sex ratio pairs of Lovenula raynerae were quantified towards larval Culex pipiens complex prey, with observations compared to both additive and substitutive model predictions.
- Full Text:
- Date Issued: 2020
Non-material costs of wildlife conservation to local people and their implications for conservation interventions:
- Thondhlana, Gladman, Redpath, Stephen Mark, Vedeld, Pål Olav, van Eden, Lily, Pascual, Unai, Sherren, Kate, Murata, Chenai
- Authors: Thondhlana, Gladman , Redpath, Stephen Mark , Vedeld, Pål Olav , van Eden, Lily , Pascual, Unai , Sherren, Kate , Murata, Chenai
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150174 , vital:38946 , https://doi.org/10.1016/j.biocon.2020.108578
- Description: In assessment of costs (and benefits) of wildlife conservation, conventional economic valuation frameworks may inadequately address various non-tangible values and neglect social, cultural and political contexts of resources and their use. Correspondingly, there seems to be much more focus on quantifying the economic, material benefits and costs of wildlife conservation than the non-material aspects that also affect human well-being. In addition, current research on the costs of wildlife conservation tends to be discipline-focused which constrains comparability, often causing conceptual ambiguity. This paper is an attempt to address this ambiguity. While there is growing acknowledgement of the material costs of wildlife conservation, we contend that employing a broader, composite social well-being approach may provide better conceptual insights on—and practical options for—managing various non-material impacts of wildlife conservation for local people.
- Full Text:
- Date Issued: 2020
- Authors: Thondhlana, Gladman , Redpath, Stephen Mark , Vedeld, Pål Olav , van Eden, Lily , Pascual, Unai , Sherren, Kate , Murata, Chenai
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150174 , vital:38946 , https://doi.org/10.1016/j.biocon.2020.108578
- Description: In assessment of costs (and benefits) of wildlife conservation, conventional economic valuation frameworks may inadequately address various non-tangible values and neglect social, cultural and political contexts of resources and their use. Correspondingly, there seems to be much more focus on quantifying the economic, material benefits and costs of wildlife conservation than the non-material aspects that also affect human well-being. In addition, current research on the costs of wildlife conservation tends to be discipline-focused which constrains comparability, often causing conceptual ambiguity. This paper is an attempt to address this ambiguity. While there is growing acknowledgement of the material costs of wildlife conservation, we contend that employing a broader, composite social well-being approach may provide better conceptual insights on—and practical options for—managing various non-material impacts of wildlife conservation for local people.
- Full Text:
- Date Issued: 2020
Social capital reduces vulnerability in rural coastal communities of Solomon Islands:
- Malherbe, Willem, Sauer, Warwick H H, Aswani, Shankar
- Authors: Malherbe, Willem , Sauer, Warwick H H , Aswani, Shankar
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150230 , vital:38951 , https://doi.org/10.1016/j.ocecoaman.2020.105186
- Description: Rural island communities are generally regarded as the most vulnerable groups affected by climate change. This perception arises due to them often being in less developed areas with high levels of exposure to stressors, while reportedly lacking the means to cope with these stressors. Studies which use developed-country yardsticks, such as those used in past IPCC-based assessments, when measuring vulnerability in less developed states will however inevitably over-pronounce its effects in such areas. The sustainable livelihoods approach provides an alternate means of determining vulnerability using capital assets such as social capital. The presence of these assets enables communities to pursue diverse livelihood strategies which ultimately serve to reduce their vulnerability. This study seeks to measure attributes of social capital in five marine dependent communities of Solomon Islands.
- Full Text:
- Date Issued: 2020
- Authors: Malherbe, Willem , Sauer, Warwick H H , Aswani, Shankar
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150230 , vital:38951 , https://doi.org/10.1016/j.ocecoaman.2020.105186
- Description: Rural island communities are generally regarded as the most vulnerable groups affected by climate change. This perception arises due to them often being in less developed areas with high levels of exposure to stressors, while reportedly lacking the means to cope with these stressors. Studies which use developed-country yardsticks, such as those used in past IPCC-based assessments, when measuring vulnerability in less developed states will however inevitably over-pronounce its effects in such areas. The sustainable livelihoods approach provides an alternate means of determining vulnerability using capital assets such as social capital. The presence of these assets enables communities to pursue diverse livelihood strategies which ultimately serve to reduce their vulnerability. This study seeks to measure attributes of social capital in five marine dependent communities of Solomon Islands.
- Full Text:
- Date Issued: 2020
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