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"Burnout" in children's home houseparents
- Authors: Bath, Peter John
- Date: 1983
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/193118 , vital:45300
- Description: Aimed at replicating the results of an American study into "Burnout" in Group Home houseparents, this research had the following aims: 1) To ascertain the validity and reliability of the instrument used in the original study and presented as a "useful measure of burnout”. 2) To establish whether this line of research, within a highly problematic research field, can at present offer any guidelines in the resolution of the current staffing crisis faced by South African children's homes. 3} To describe more closely the burnout syndrome. 4) To study possible etiological factors within a local context. Sixty three houseparents completed questionaires and three independent measures of burnout were obtained. The results were regarded as having failed to replicate those of the original study. The reason for this was found to be the low validity of the original instrument. The main conclusion drawn was that the line of research adopted in the original study can offer only very tentative guidelines towards the resolution of the staffing crisis faced until such time as valid and reliable instruments to measure burnout have been developed. Many of the suggested relationships between situational variables and ones of personal characteristics were confirmed for the local population of houseparents. , Thesis (MSocSci) -- Faculty of Humanities, Psychology, 1983
- Full Text:
- Date Issued: 1983
- Authors: Bath, Peter John
- Date: 1983
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/193118 , vital:45300
- Description: Aimed at replicating the results of an American study into "Burnout" in Group Home houseparents, this research had the following aims: 1) To ascertain the validity and reliability of the instrument used in the original study and presented as a "useful measure of burnout”. 2) To establish whether this line of research, within a highly problematic research field, can at present offer any guidelines in the resolution of the current staffing crisis faced by South African children's homes. 3} To describe more closely the burnout syndrome. 4) To study possible etiological factors within a local context. Sixty three houseparents completed questionaires and three independent measures of burnout were obtained. The results were regarded as having failed to replicate those of the original study. The reason for this was found to be the low validity of the original instrument. The main conclusion drawn was that the line of research adopted in the original study can offer only very tentative guidelines towards the resolution of the staffing crisis faced until such time as valid and reliable instruments to measure burnout have been developed. Many of the suggested relationships between situational variables and ones of personal characteristics were confirmed for the local population of houseparents. , Thesis (MSocSci) -- Faculty of Humanities, Psychology, 1983
- Full Text:
- Date Issued: 1983
"The word as image": survey with special reference to the twentieth century
- Authors: Edworthy, S
- Date: 1991-03
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191247 , vital:45075
- Description: This essay is intended, firstly for those who at some time have had the urge to include words into their otherwise conventional representational images, but are deterred by the suspicion that such elements have no place in the picture plane. Secondly, it is hoped, that this dissertation will provide some understanding concerning the motivations and aims of artists, using "verbal symbols" in their visual images. At this point, I offer some explanation of the term "verbal symbols". The alphabet that we are accustomed to today differs vastly from the first writing that was invented. The naming of items nowadays is arbitrarily established and all we are left with is a name that bears no visual resemblance to the object it represents in real life. The word "house", for example, tells us nothing of the physical nature of a house. However, owing to our conditioning, the word evokes in us a mental picture of a house, even if the details of this picture will vary amongst individuals. Words then are symbols which denote, broadly speaking, objects that exist in our daily lives, without being in any way visual representations of these objects. Of course there are also words which are dependent on other words for their meaning, such as prepositions, conjunctions or suffices, but this is irrelevant to this essay. , Thesis (MFA) -- Faculty of Humanities, Fine Art, 1991
- Full Text:
- Date Issued: 1991-03
- Authors: Edworthy, S
- Date: 1991-03
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191247 , vital:45075
- Description: This essay is intended, firstly for those who at some time have had the urge to include words into their otherwise conventional representational images, but are deterred by the suspicion that such elements have no place in the picture plane. Secondly, it is hoped, that this dissertation will provide some understanding concerning the motivations and aims of artists, using "verbal symbols" in their visual images. At this point, I offer some explanation of the term "verbal symbols". The alphabet that we are accustomed to today differs vastly from the first writing that was invented. The naming of items nowadays is arbitrarily established and all we are left with is a name that bears no visual resemblance to the object it represents in real life. The word "house", for example, tells us nothing of the physical nature of a house. However, owing to our conditioning, the word evokes in us a mental picture of a house, even if the details of this picture will vary amongst individuals. Words then are symbols which denote, broadly speaking, objects that exist in our daily lives, without being in any way visual representations of these objects. Of course there are also words which are dependent on other words for their meaning, such as prepositions, conjunctions or suffices, but this is irrelevant to this essay. , Thesis (MFA) -- Faculty of Humanities, Fine Art, 1991
- Full Text:
- Date Issued: 1991-03
& salt the earth behind you
- Authors: Naidoo, Prenesa
- Date: 2021-04
- Subjects: Creative writing (Higher education) -- South Africa , South African fiction (English) -- 21st century , South African poetry (English) -- 21st century , Short stories, South African (English) -- 21st century , Diaries -- Authorship , Korean fiction -- 21st century -- History and criticism , Short stories, Argentine -- 21st century -- History and criticism , Arabic fiction -- Palestine 21st century -- History and criticism , Argentine fiction -- 21st century -- History and criticism
- Language: English
- Type: thesis , text , Masters , MA
- Identifier: http://hdl.handle.net/10962/178212 , vital:42921
- Description: My thesis is a collection of prose pieces in the form of short stories, flash fiction and prose poetry drawing on memory and lived experiences to explore the trauma of death, grief and displacement, solace and the paroxysms of home. As a young woman from an Indian South Africa community, Hindu superstitions and folktales are my second skin, and shape both my worldview and my writing. I am inspired by Lidia Yuknavitch’s observation that, “all artists see things that are not there”, and by Dambudzo Marechera’s belief that, “Beneath reality, there is always fantasy: the writer’s task is to reveal it, to open it out, to feel it, to experience it.” In my stories about trauma and grief, I often distort the line between seen and unseen worlds, where, for example, hauntings are taken seriously as lived experiences. I have also been influenced by Han Kang’s The White Book, Kali Fajardo-Anstine’s Sabrina & Corina, and Sandra Cisneros’ The House on Mango Street. Read together, Kang’s stand-alone short stories form part of a greater collective ‘memory’ or ‘life’; Fajardo-Anstine’s collection illustrates how to write about a specific female Latina community while still telling individual stories; and Cisneros’ fragments of memories tell the story of a person’s life in narratives which are as long or short as they need to be. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Naidoo, Prenesa
- Date: 2021-04
- Subjects: Creative writing (Higher education) -- South Africa , South African fiction (English) -- 21st century , South African poetry (English) -- 21st century , Short stories, South African (English) -- 21st century , Diaries -- Authorship , Korean fiction -- 21st century -- History and criticism , Short stories, Argentine -- 21st century -- History and criticism , Arabic fiction -- Palestine 21st century -- History and criticism , Argentine fiction -- 21st century -- History and criticism
- Language: English
- Type: thesis , text , Masters , MA
- Identifier: http://hdl.handle.net/10962/178212 , vital:42921
- Description: My thesis is a collection of prose pieces in the form of short stories, flash fiction and prose poetry drawing on memory and lived experiences to explore the trauma of death, grief and displacement, solace and the paroxysms of home. As a young woman from an Indian South Africa community, Hindu superstitions and folktales are my second skin, and shape both my worldview and my writing. I am inspired by Lidia Yuknavitch’s observation that, “all artists see things that are not there”, and by Dambudzo Marechera’s belief that, “Beneath reality, there is always fantasy: the writer’s task is to reveal it, to open it out, to feel it, to experience it.” In my stories about trauma and grief, I often distort the line between seen and unseen worlds, where, for example, hauntings are taken seriously as lived experiences. I have also been influenced by Han Kang’s The White Book, Kali Fajardo-Anstine’s Sabrina & Corina, and Sandra Cisneros’ The House on Mango Street. Read together, Kang’s stand-alone short stories form part of a greater collective ‘memory’ or ‘life’; Fajardo-Anstine’s collection illustrates how to write about a specific female Latina community while still telling individual stories; and Cisneros’ fragments of memories tell the story of a person’s life in narratives which are as long or short as they need to be. , Thesis (MA) -- Faculty of Humanities, School of Languages and Literatures, 2021
- Full Text:
- Date Issued: 2021-04
'I won't be squeezed into someone else's frame': Stories of supervisor selection
- Harrison, Liz, McKenna, Sioux, Searle, Ruth
- Authors: Harrison, Liz , McKenna, Sioux , Searle, Ruth
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187395 , vital:44629 , xlink:href="https://hdl.handle.net/10520/EJC15100"
- Description: Using a collection of stories from a group of women who belong to a PhD support group, this article tracks the issue of choosing a supervisor. These women are all academics and therefore had some claim to an "insider" status but as novice researchers they were also "outsiders". Their discussions around how and why they chose their supervisors highlight issues often underplayed or ignored in textbooks on postgraduate supervision. In particular, this article examines issues of knowledge, embodied subjectivity and power by following three questions that arise from the data : whose knowing is important; who should I be, and whose PhD is it?
- Full Text:
- Date Issued: 2010
- Authors: Harrison, Liz , McKenna, Sioux , Searle, Ruth
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187395 , vital:44629 , xlink:href="https://hdl.handle.net/10520/EJC15100"
- Description: Using a collection of stories from a group of women who belong to a PhD support group, this article tracks the issue of choosing a supervisor. These women are all academics and therefore had some claim to an "insider" status but as novice researchers they were also "outsiders". Their discussions around how and why they chose their supervisors highlight issues often underplayed or ignored in textbooks on postgraduate supervision. In particular, this article examines issues of knowledge, embodied subjectivity and power by following three questions that arise from the data : whose knowing is important; who should I be, and whose PhD is it?
- Full Text:
- Date Issued: 2010
'We throw away our books': Students’ reading practices and identities
- O'Shea, Cathy, McKenna, Sioux, Thomson, Carol
- Authors: O'Shea, Cathy , McKenna, Sioux , Thomson, Carol
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187128 , vital:44570 , xlink:href="https://doi.org/10.1016/j.linged.2018.11.001"
- Description: The aim of this research was to understand university students’ self-reported reading practices. The students attended the University of Fort Hare in South Africa, a historically black institution in a rural and under-resourced setting. A framework of New Literacy Studies (NLS) was used to understand students’ self-reported reading practices and the links between these and their identities. Tools provided by Gee, 2005, Gee, 2011 were applied to conduct a CDA of focus group discussions. In the ‘We Blacks’ Discourse, interviewees ‘othered’ the idea of reading as not being culturally valued. It was closely allied to the ‘Resistance to Reading’ Discourse, as participants explained that they tended to disregard books and did not enjoy leisure reading. The ‘Better Than Us’ discourse was drawn upon to suggest that reading was associated with attitudes of superiority. These discourses tended to homogenise class and other differences between black students and indicated the ways in which their experiences made adopting academic identities difficult. The analysis suggests that the racism of the past continues to impact students’ reading identities. The article concludes that the effects of these and related discourses require a response across the education sector, and transformative pedagogies might be needed in higher education.
- Full Text:
- Date Issued: 2019
- Authors: O'Shea, Cathy , McKenna, Sioux , Thomson, Carol
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187128 , vital:44570 , xlink:href="https://doi.org/10.1016/j.linged.2018.11.001"
- Description: The aim of this research was to understand university students’ self-reported reading practices. The students attended the University of Fort Hare in South Africa, a historically black institution in a rural and under-resourced setting. A framework of New Literacy Studies (NLS) was used to understand students’ self-reported reading practices and the links between these and their identities. Tools provided by Gee, 2005, Gee, 2011 were applied to conduct a CDA of focus group discussions. In the ‘We Blacks’ Discourse, interviewees ‘othered’ the idea of reading as not being culturally valued. It was closely allied to the ‘Resistance to Reading’ Discourse, as participants explained that they tended to disregard books and did not enjoy leisure reading. The ‘Better Than Us’ discourse was drawn upon to suggest that reading was associated with attitudes of superiority. These discourses tended to homogenise class and other differences between black students and indicated the ways in which their experiences made adopting academic identities difficult. The analysis suggests that the racism of the past continues to impact students’ reading identities. The article concludes that the effects of these and related discourses require a response across the education sector, and transformative pedagogies might be needed in higher education.
- Full Text:
- Date Issued: 2019
(Ferrocenylpyrazolyl) zinc (II) benzoates as catalysts for the ring opening polymerization of ε-caprolactone
- Obuah, Collins, Lochee, Yemanlall, Jordaan, Johan H L, Otto, Daniel P, Nyokong, Tebello, Darkwa, James
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H L , Otto, Daniel P , Nyokong, Tebello , Darkwa, James
- Date: 2015
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/189515 , vital:44853 , xlink:href="https://doi.org/10.1016/j.poly.2015.02.007"
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3 COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of e-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1 H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 107 h1 mol1 at 110 C.
- Full Text:
- Date Issued: 2015
10 Years of IEASA history
- International Education Association of South Africa (IEASA), Jooste, Nico
- Authors: International Education Association of South Africa (IEASA) , Jooste, Nico
- Date: 2007
- Subjects: International Education Association of South Africa -- History , Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65356 , vital:28752 , ISBN 1920176004
- Description: [Preface - Nico Jooste]: For more than ten years, we have been involved in implementing internationalisation of South African Higher Education. The we I am referring too, are those who are both visionaries and passionately dedicated to the process of internationalisation. A small group of South African Higher Education administrators, academics and senior managers involved themselves in the process of internationalisation of their institutions, and collectively the South African system. This process of internationalisation started as an uncoordinated response to the demands of a South African higher education system that was determined to break with the past, and re-connect with global higher education, it was left to a few dedicated visionaries to create the support structure that would not only assist the higher education institutions, but also the system. The other bodies that were supposed to pay attention to this very important aspect of Higher Education in the 21st century were too busy with other, equally important, matters. It became clear that the priorities of organisations like SAUVCA were not internationalisation, and IEASA was established as the vehicle to promote it. This story of IEASA needed to be told. This book is not aimed at IEASA members only, but also at the broader higher education public. This is the story of an organisation that touched all parts of South African Higher Education society as well as the broader society. It is partly the ‘corporate memory’ of Internationalisation, as well as a reflection on achievements. Ten years looked like a short period to reflect on an organisations history, I am however of the opinion that in a society that is changing so rapidly, we need to reflect more frequently on the past so that we can plan a better future. For any historian operating in the modem era of electronic communication, access to sources of information has become a major challenge. IEASA, Thilor Manikam in particular, needs to be commended for the accurate record keeping of events over the past ten years. Kirstin Nussgruber very diligently captured the efforts of the forces driving the establishment of IEASA for the first two years. This book was mainly based on evidence gathered from minutes, reports and letters that are in the possession of the IEASA Office. I also had the privilege, and advantage, to be a member of the Executive Committee for the past five years. This book cannot be the last word on IEASA, as it is only the view of a member. The bias is thus toward IEASA and focusses mainly on its achievements. Chapter 3 focusses mainly on the achievements of a voluntary organisation. The efforts over the ten years of three persons namely. Roshen Kishun as President, Derek Swemmer as Treasurer, and Thilor Manikam as the Administrator stood out, and was the stabilising factor during the foundation years. The role of Roshen Kishun in the publication of Study South African cannot be underestimated. Without his vision, drive and effort, this publication would not be preparing for the launch of the seventh edition. It is a unique source of information about South African Higher Education. Very few other systems, if any. produce such a publication. Although the author was requested by the IEASA Executive Committee to write this book, the views expressed in this publication is not the views of the Executive Committee, but that of the author.
- Full Text:
- Date Issued: 2007
- Authors: International Education Association of South Africa (IEASA) , Jooste, Nico
- Date: 2007
- Subjects: International Education Association of South Africa -- History , Education, Higher -- South Africa , Education and globalization -- South Africa Student mobility -- Africa International education -- South Africa Education, Higher -- International cooperation , Universities and colleges -- South Africa , Technical Institutes -- South Africa , Vocational guidance -- South Africa
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/65356 , vital:28752 , ISBN 1920176004
- Description: [Preface - Nico Jooste]: For more than ten years, we have been involved in implementing internationalisation of South African Higher Education. The we I am referring too, are those who are both visionaries and passionately dedicated to the process of internationalisation. A small group of South African Higher Education administrators, academics and senior managers involved themselves in the process of internationalisation of their institutions, and collectively the South African system. This process of internationalisation started as an uncoordinated response to the demands of a South African higher education system that was determined to break with the past, and re-connect with global higher education, it was left to a few dedicated visionaries to create the support structure that would not only assist the higher education institutions, but also the system. The other bodies that were supposed to pay attention to this very important aspect of Higher Education in the 21st century were too busy with other, equally important, matters. It became clear that the priorities of organisations like SAUVCA were not internationalisation, and IEASA was established as the vehicle to promote it. This story of IEASA needed to be told. This book is not aimed at IEASA members only, but also at the broader higher education public. This is the story of an organisation that touched all parts of South African Higher Education society as well as the broader society. It is partly the ‘corporate memory’ of Internationalisation, as well as a reflection on achievements. Ten years looked like a short period to reflect on an organisations history, I am however of the opinion that in a society that is changing so rapidly, we need to reflect more frequently on the past so that we can plan a better future. For any historian operating in the modem era of electronic communication, access to sources of information has become a major challenge. IEASA, Thilor Manikam in particular, needs to be commended for the accurate record keeping of events over the past ten years. Kirstin Nussgruber very diligently captured the efforts of the forces driving the establishment of IEASA for the first two years. This book was mainly based on evidence gathered from minutes, reports and letters that are in the possession of the IEASA Office. I also had the privilege, and advantage, to be a member of the Executive Committee for the past five years. This book cannot be the last word on IEASA, as it is only the view of a member. The bias is thus toward IEASA and focusses mainly on its achievements. Chapter 3 focusses mainly on the achievements of a voluntary organisation. The efforts over the ten years of three persons namely. Roshen Kishun as President, Derek Swemmer as Treasurer, and Thilor Manikam as the Administrator stood out, and was the stabilising factor during the foundation years. The role of Roshen Kishun in the publication of Study South African cannot be underestimated. Without his vision, drive and effort, this publication would not be preparing for the launch of the seventh edition. It is a unique source of information about South African Higher Education. Very few other systems, if any. produce such a publication. Although the author was requested by the IEASA Executive Committee to write this book, the views expressed in this publication is not the views of the Executive Committee, but that of the author.
- Full Text:
- Date Issued: 2007
4-Azidoaniline-based electropolymer as a building block for functionalisation of conductive surfaces
- Coates, Megan, Elamari, Hichem, Girard, Christian, Griveau, Sophie, Nyokong, Tebello, Bedioui, Fethi
- Authors: Coates, Megan , Elamari, Hichem , Girard, Christian , Griveau, Sophie , Nyokong, Tebello , Bedioui, Fethi
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/244404 , vital:51254 , xlink:href="https://doi.org/10.1016/j.jelechem.2012.01.001"
- Description: We propose in this work to compare three approaches using 4-azidoaniline combined with “click” chemistry and electrochemistry to anchor ferrocene moieties at glassy carbon surfaces. The immobilisation of a newly synthesised molecule, 4-(4-ferrocenyl-1H-1,2,3-triazol-1-yl)aniline, through direct electropolymerisation or via in situ diazotization followed by electrografting is studied by analysing the samples by XPS and electrochemistry.
- Full Text:
- Date Issued: 2012
4-Azidoaniline-based electropolymer as a building block for functionalisation of conductive surfaces
- Authors: Coates, Megan , Elamari, Hichem , Girard, Christian , Griveau, Sophie , Nyokong, Tebello , Bedioui, Fethi
- Date: 2012
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/244404 , vital:51254 , xlink:href="https://doi.org/10.1016/j.jelechem.2012.01.001"
- Description: We propose in this work to compare three approaches using 4-azidoaniline combined with “click” chemistry and electrochemistry to anchor ferrocene moieties at glassy carbon surfaces. The immobilisation of a newly synthesised molecule, 4-(4-ferrocenyl-1H-1,2,3-triazol-1-yl)aniline, through direct electropolymerisation or via in situ diazotization followed by electrografting is studied by analysing the samples by XPS and electrochemistry.
- Full Text:
- Date Issued: 2012
4-Bis (4-aminophenoxy) phenoxy derivitized phthalocyanine conjugated to metallic nanoparticles
- Nwaji, Njemuwa, Mack, John, Nyokong, Tebello
- Authors: Nwaji, Njemuwa , Mack, John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188965 , vital:44802 , xlink:href="https://doi.org/10.1039/C7NJ02718D"
- Description: In this study, the photophysical, nonlinear absorption and nonlinear optical limiting properties of 4-(2,4-bis(4-aminophenoxy)phenoxy) phthalocyinato zinc(II) phthalocyanine (6) conjugated to metallic nanoparticles have been investigated using open aperture Z-scan techniques using 532 nm nanosecond pulses. The nonlinear optical response demonstrated that the studied complex and the nanoconjugates exhibit higher excited state absorption cross-section compared to ground state absorption. Enhanced optical limiting performance was observed when complex 6 was conjugated to nanoparticles with 6CB-AuNPs (CB = covalent bond) showing the highest optical limiting threshold of 0.36 J cm−2.
- Full Text:
- Date Issued: 2017
- Authors: Nwaji, Njemuwa , Mack, John , Nyokong, Tebello
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/188965 , vital:44802 , xlink:href="https://doi.org/10.1039/C7NJ02718D"
- Description: In this study, the photophysical, nonlinear absorption and nonlinear optical limiting properties of 4-(2,4-bis(4-aminophenoxy)phenoxy) phthalocyinato zinc(II) phthalocyanine (6) conjugated to metallic nanoparticles have been investigated using open aperture Z-scan techniques using 532 nm nanosecond pulses. The nonlinear optical response demonstrated that the studied complex and the nanoconjugates exhibit higher excited state absorption cross-section compared to ground state absorption. Enhanced optical limiting performance was observed when complex 6 was conjugated to nanoparticles with 6CB-AuNPs (CB = covalent bond) showing the highest optical limiting threshold of 0.36 J cm−2.
- Full Text:
- Date Issued: 2017
5-Fu inclusion complex capped gold nanoparticles for breast cancer therapy
- Lakkakula, Jaya R, Krause, Rui W M, Divakaran, Deepika, Barage, Sagar, Srivastava, Rohit
- Authors: Lakkakula, Jaya R , Krause, Rui W M , Divakaran, Deepika , Barage, Sagar , Srivastava, Rohit
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/191713 , vital:45150 , xlink:href="https://doi.org/10.1016/j.molliq.2021.117262"
- Description: We have attempted to prolong the circulation time and increase the solubility of 5-Fluorouracil by complexing it with cyclodextrin and then further conjugating onto the gold nanoparticle to form 5Fu ICAu. The 1H NMR and molecular docking studies suggested that 5-Fu was included within the 2HP-β-CD cavity and H-5 proton probably serves as the binding site for stabilization of the inclusion complex. The 5Fu-ICAu showed higher cell inhibition rate when studied on MDA-MB-231 and MCF-7 breast cancer cell lines due to the enhanced permeability and retention (EPR) effect by allowing the selective accumulation of nanoparticles at tumor site. This unique system can serve as a novel nanocarrier for delivery of hydrophobic drugs.
- Full Text:
- Date Issued: 2021
- Authors: Lakkakula, Jaya R , Krause, Rui W M , Divakaran, Deepika , Barage, Sagar , Srivastava, Rohit
- Date: 2021
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/191713 , vital:45150 , xlink:href="https://doi.org/10.1016/j.molliq.2021.117262"
- Description: We have attempted to prolong the circulation time and increase the solubility of 5-Fluorouracil by complexing it with cyclodextrin and then further conjugating onto the gold nanoparticle to form 5Fu ICAu. The 1H NMR and molecular docking studies suggested that 5-Fu was included within the 2HP-β-CD cavity and H-5 proton probably serves as the binding site for stabilization of the inclusion complex. The 5Fu-ICAu showed higher cell inhibition rate when studied on MDA-MB-231 and MCF-7 breast cancer cell lines due to the enhanced permeability and retention (EPR) effect by allowing the selective accumulation of nanoparticles at tumor site. This unique system can serve as a novel nanocarrier for delivery of hydrophobic drugs.
- Full Text:
- Date Issued: 2021
: the representation of rape in Lewis Nkosi’s Mating Birds and Arthur Maimane’s Hate No More
- Authors: Yawa, Sibulele Yola
- Date: 2021-02
- Subjects: South Africa--Politics and government--1994 , Post-apartheid era--South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21134 , vital:47131
- Description: The main aim of this thesis is to provide a literary study through a comparative analysis of how sexual politics are played out in the texts Mating Birds by Lewis Nkosi and Hate No More by Arthur Maimane. It seeks to determine the modalities of representation of rape in each text and also to investigate the extent to which the novels are similar or different in the way in which they represent sexual politics or the politics of rape during the apartheid era. This investigation was done using Frantz Fanon‟s postcolonial theory and, particularly, his seminal work, Black Skin, White Masks. Most importantly, for the purpose of this study, is Fanon‟s chapter on the love/sexual relationships between the man of colour and the white woman. This is helpful as Fanon touches on what he believes the attraction of the man of colour to the white woman stems from. Using Fanon‟s theory, one discovers that the motivation for Ndi Sibiya to allegedly rape Veronica stems from his anger at the system of apartheid and its oppression of black people. This is similar to Philip Mokone‟s case; the novel explicitly states that he was motivated by anger and his rape of Jean Ryan was a form of communication to the white people and the apartheid system. , Thesis (MA) (English) -- University of Fort Hare, 2021
- Full Text:
- Date Issued: 2021-02
- Authors: Yawa, Sibulele Yola
- Date: 2021-02
- Subjects: South Africa--Politics and government--1994 , Post-apartheid era--South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21134 , vital:47131
- Description: The main aim of this thesis is to provide a literary study through a comparative analysis of how sexual politics are played out in the texts Mating Birds by Lewis Nkosi and Hate No More by Arthur Maimane. It seeks to determine the modalities of representation of rape in each text and also to investigate the extent to which the novels are similar or different in the way in which they represent sexual politics or the politics of rape during the apartheid era. This investigation was done using Frantz Fanon‟s postcolonial theory and, particularly, his seminal work, Black Skin, White Masks. Most importantly, for the purpose of this study, is Fanon‟s chapter on the love/sexual relationships between the man of colour and the white woman. This is helpful as Fanon touches on what he believes the attraction of the man of colour to the white woman stems from. Using Fanon‟s theory, one discovers that the motivation for Ndi Sibiya to allegedly rape Veronica stems from his anger at the system of apartheid and its oppression of black people. This is similar to Philip Mokone‟s case; the novel explicitly states that he was motivated by anger and his rape of Jean Ryan was a form of communication to the white people and the apartheid system. , Thesis (MA) (English) -- University of Fort Hare, 2021
- Full Text:
- Date Issued: 2021-02
[iLahleko - Loss]
- Authors: Qhali, Itumeleng
- Date: 2021-10-29
- Subjects: Creative writing (Higher education) South Africa , Xhosa poetry 21st century , South African poetry (English) 21st century , Short stories, South African (English) 21st century , Loss (Psychology) in literature , Poetry History and criticism , Bilingual authors , Bilingualism and literature , Bilingualism in literature
- Language: English , Xhosa
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191825 , vital:45169
- Description: My thesis is a collection of poems and prose that explores the disjunction of losses for women and children across the two languages I inhabit, isiXhosa and English. Ukulahlekelwa lithemba, ukudukelwa yingqondo, ukholo, ubuwena, umzimba nothando. For me, isiXhosa captures the innate musicality and deep emotions within a word or a sound that are not available in English. On the other hand, English readily produces visceral images that are more difficult for me to access in isiXhosa. Kolu phononongo ndikwasebenzisa namagama emboleko ukuze ndikhulise isigama. Ndisebenzisa amagama azibeka zinjalo iimvakalelo, angqalileyo kuncwadi lwesiXhosa. Ndisebenzisa zombini ilyric form kunye neprozi ngenxa yesingqi esiphuhliswa yilyric, nangenxa yenkululeko umbali ayifumanayo kwiprozi. As a bilingual writer ndifuthelwe sisingqi nobunzulu bentlungu obufumaneka in the translated and bilingual works of Isabella Motadinyane, noMarina Ivanovna Tsvetaeva, imibongo yeDaikwan eguqulwe nguStephen Watson ethi Song of the Broken String; iimbongi zespanish ezinjengo Antonia Machado; ngendlela abasebenzisa ngayo ulwimi lwabo ukunabisa nokugqithisa umyalezo ngeentlungu abadibana nazo, bakwanaso nesingqi somculo othuthuzelayo kwimibongo yabo. The structure of my thesis is inspired by the innovative mixed genre layout of Sindiswa Busuku-Mathese’s Loud and Yellow Laughter, and the new formats of isiXhosa writing presented in Mthunzikazi Mbugwana’s poetry. My work has also been shaped by the visceral imagery and briefly captured moments of loss in imisebenzi ka S.S Mema, Nontsizi Mgqwetho, noPascale Petit, novangile gantsho. Imisebenzi yabo ikuzobela umfanekiso ngqondweni ophilayo. Bonke abababhali bahambe indlela endinika umdla nendifuna ukuyihamba nam njengombhali omtsha obhala ngeelwimi ezimbini. , My thesis is a collection of poems and prose that explores the disjunction of losses for women and children across the two languages I inhabit, isiXhosa and English. For me, isiXhosa captures the innate musicality and deep emotions within a word or a sound that are not available to me in English. On the other hand, English readily produces visceral images that are more difficult for me to find in isiXhosa. My poems use the music and introspection of the lyric form, as well as the emotional outpouring that prose poetry allows. As a bilingual writer, I am influenced by the transference of musicality and gravity of loss conveyed in the translated and bilingual work of Isabella Motadinyane, the Russian Marina Tsvetaeva, Stephen Watson’s Song of the Broken String, as well as the Spanish poets Antonio Machado. The structure of my thesis is inspired by the innovative mixed genre layout of Sindiswa Busuku-Mathese’s Loud and Yellow Laughter, and the new formats of isiXhosa writing presented in Mthunzikazi Mbugwana’s poetry. My work has also been shaped by the visceral imagery and briefly captured moments of loss in the work of South African poets vangile gantsho, S.S. Mema, and Nontsizi Mgqwetho, as well as the English poet, Pascale Petit. , Thesis (MA) -- Faculty of Humanitites, School of Languages and Literatures, 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Qhali, Itumeleng
- Date: 2021-10-29
- Subjects: Creative writing (Higher education) South Africa , Xhosa poetry 21st century , South African poetry (English) 21st century , Short stories, South African (English) 21st century , Loss (Psychology) in literature , Poetry History and criticism , Bilingual authors , Bilingualism and literature , Bilingualism in literature
- Language: English , Xhosa
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191825 , vital:45169
- Description: My thesis is a collection of poems and prose that explores the disjunction of losses for women and children across the two languages I inhabit, isiXhosa and English. Ukulahlekelwa lithemba, ukudukelwa yingqondo, ukholo, ubuwena, umzimba nothando. For me, isiXhosa captures the innate musicality and deep emotions within a word or a sound that are not available in English. On the other hand, English readily produces visceral images that are more difficult for me to access in isiXhosa. Kolu phononongo ndikwasebenzisa namagama emboleko ukuze ndikhulise isigama. Ndisebenzisa amagama azibeka zinjalo iimvakalelo, angqalileyo kuncwadi lwesiXhosa. Ndisebenzisa zombini ilyric form kunye neprozi ngenxa yesingqi esiphuhliswa yilyric, nangenxa yenkululeko umbali ayifumanayo kwiprozi. As a bilingual writer ndifuthelwe sisingqi nobunzulu bentlungu obufumaneka in the translated and bilingual works of Isabella Motadinyane, noMarina Ivanovna Tsvetaeva, imibongo yeDaikwan eguqulwe nguStephen Watson ethi Song of the Broken String; iimbongi zespanish ezinjengo Antonia Machado; ngendlela abasebenzisa ngayo ulwimi lwabo ukunabisa nokugqithisa umyalezo ngeentlungu abadibana nazo, bakwanaso nesingqi somculo othuthuzelayo kwimibongo yabo. The structure of my thesis is inspired by the innovative mixed genre layout of Sindiswa Busuku-Mathese’s Loud and Yellow Laughter, and the new formats of isiXhosa writing presented in Mthunzikazi Mbugwana’s poetry. My work has also been shaped by the visceral imagery and briefly captured moments of loss in imisebenzi ka S.S Mema, Nontsizi Mgqwetho, noPascale Petit, novangile gantsho. Imisebenzi yabo ikuzobela umfanekiso ngqondweni ophilayo. Bonke abababhali bahambe indlela endinika umdla nendifuna ukuyihamba nam njengombhali omtsha obhala ngeelwimi ezimbini. , My thesis is a collection of poems and prose that explores the disjunction of losses for women and children across the two languages I inhabit, isiXhosa and English. For me, isiXhosa captures the innate musicality and deep emotions within a word or a sound that are not available to me in English. On the other hand, English readily produces visceral images that are more difficult for me to find in isiXhosa. My poems use the music and introspection of the lyric form, as well as the emotional outpouring that prose poetry allows. As a bilingual writer, I am influenced by the transference of musicality and gravity of loss conveyed in the translated and bilingual work of Isabella Motadinyane, the Russian Marina Tsvetaeva, Stephen Watson’s Song of the Broken String, as well as the Spanish poets Antonio Machado. The structure of my thesis is inspired by the innovative mixed genre layout of Sindiswa Busuku-Mathese’s Loud and Yellow Laughter, and the new formats of isiXhosa writing presented in Mthunzikazi Mbugwana’s poetry. My work has also been shaped by the visceral imagery and briefly captured moments of loss in the work of South African poets vangile gantsho, S.S. Mema, and Nontsizi Mgqwetho, as well as the English poet, Pascale Petit. , Thesis (MA) -- Faculty of Humanitites, School of Languages and Literatures, 2021
- Full Text:
- Date Issued: 2021-10-29
A 3, 5-DistyrylBODIPY Dye Functionalized with Boronic Acid Groups for Direct Electrochemical Glucose Sensing
- Ndebele, Nobuhle, Mack, John, Nyokong, Tebello
- Authors: Ndebele, Nobuhle , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187556 , vital:44671 , xlink:href="https://doi.org/10.1002/elan.201800651"
- Description: The synthesis and characterization of a novel BODIPY dye functionalized with bis-boronic acid groups to enable direct glucose sensing through selective recognition of carbohydrates is reported. Styrylation with boronic acid groups at the 3,5-positions of the BODIPY core results in an extension of the π-conjugation system of the dye and in a red-shift of the main absorption band from 500 to 637 nm. The functionalized BODIPY dye was adsorbed on a glassy carbon electrode using the drop and dry method. Modified and bare electrodes were characterized using cyclic voltammetry and scanning electrochemical microscopy, while glucose detection was carried out by using differential pulse voltammetry and chronoamperometry. The detection limit was determined to be 1.42 μM. The dye was found to be selective and sensitive towards glucose, since likely interferences have only minor effects on the glucose detection.
- Full Text:
- Date Issued: 2019
- Authors: Ndebele, Nobuhle , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187556 , vital:44671 , xlink:href="https://doi.org/10.1002/elan.201800651"
- Description: The synthesis and characterization of a novel BODIPY dye functionalized with bis-boronic acid groups to enable direct glucose sensing through selective recognition of carbohydrates is reported. Styrylation with boronic acid groups at the 3,5-positions of the BODIPY core results in an extension of the π-conjugation system of the dye and in a red-shift of the main absorption band from 500 to 637 nm. The functionalized BODIPY dye was adsorbed on a glassy carbon electrode using the drop and dry method. Modified and bare electrodes were characterized using cyclic voltammetry and scanning electrochemical microscopy, while glucose detection was carried out by using differential pulse voltammetry and chronoamperometry. The detection limit was determined to be 1.42 μM. The dye was found to be selective and sensitive towards glucose, since likely interferences have only minor effects on the glucose detection.
- Full Text:
- Date Issued: 2019
A baseline study of land tenure rights and livelihoods in the Amatole District in the context of proposed shale gas development
- Authors: Mmtsila, Mkhuseli
- Date: 2021-04
- Subjects: Gqeberha (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52969 , vital:44869
- Description: Shale Gas Exploration (SGE) is one among various means that are seen as a solution to the energy crisis of the 21st century. In many first world countries, especially in America, Shale Gas Exploration (SGE) has been one of the energy sources that has been utilised along with other energy sources like coal as a means of moving towards a cleaner and more sustainable renewable energy source to reduce carbon emissions as it burns cleaner than coal. Shale Gas Development (SGD) is now gaining momentum around the world, including in the African continent and in particular, South Africa, which has shown potential for exploration. The recently discovered shale gas deposits in the Karoo region have drawn significant attention across the entire central region of the interior, including the Amathole District of the Eastern Cape Province of South Africa, a region often neglected in the discussion surrounding SGD as it falls within the far eastern corner of the existing areas under application for exploration. In the District, as in the Province as a whole, this has brought discussions around potential for development for the area and the country at large. Since the discovery of shale gas extracts in the Karoo, there has also been a heated debate in looking at Shale Gas Development (SGD) as one of the alternatives to coal within the Integrated Resource Plan (IRP) to be a part of a mixed resource plan for the country. The heated debate is based on anticipated environmental short run effects together with long-run impacts in comparison with the economic benefits that could bring about economic growth and development in the Eastern Cape and South Africa at large. The concerns around Shale Gas Development (SGD) make it difficult to exploit the resource due to scepticism of residents of the Amathole District Municipality, environmental organisations, NGOs and civil society, including land tenure rights as there is an unresolved land question in South Africa. The debate around the land question in South Africa is based on redressing the socio-economic imbalances that were caused by the historical land dispossessions and the apartheid system that disallowed the indigenous black majority land rights. , Thesis (MA) -- Faculty of Business and Economic Sciences, Department of Development Studies, 2021
- Full Text: false
- Date Issued: 2021-04
- Authors: Mmtsila, Mkhuseli
- Date: 2021-04
- Subjects: Gqeberha (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52969 , vital:44869
- Description: Shale Gas Exploration (SGE) is one among various means that are seen as a solution to the energy crisis of the 21st century. In many first world countries, especially in America, Shale Gas Exploration (SGE) has been one of the energy sources that has been utilised along with other energy sources like coal as a means of moving towards a cleaner and more sustainable renewable energy source to reduce carbon emissions as it burns cleaner than coal. Shale Gas Development (SGD) is now gaining momentum around the world, including in the African continent and in particular, South Africa, which has shown potential for exploration. The recently discovered shale gas deposits in the Karoo region have drawn significant attention across the entire central region of the interior, including the Amathole District of the Eastern Cape Province of South Africa, a region often neglected in the discussion surrounding SGD as it falls within the far eastern corner of the existing areas under application for exploration. In the District, as in the Province as a whole, this has brought discussions around potential for development for the area and the country at large. Since the discovery of shale gas extracts in the Karoo, there has also been a heated debate in looking at Shale Gas Development (SGD) as one of the alternatives to coal within the Integrated Resource Plan (IRP) to be a part of a mixed resource plan for the country. The heated debate is based on anticipated environmental short run effects together with long-run impacts in comparison with the economic benefits that could bring about economic growth and development in the Eastern Cape and South Africa at large. The concerns around Shale Gas Development (SGD) make it difficult to exploit the resource due to scepticism of residents of the Amathole District Municipality, environmental organisations, NGOs and civil society, including land tenure rights as there is an unresolved land question in South Africa. The debate around the land question in South Africa is based on redressing the socio-economic imbalances that were caused by the historical land dispossessions and the apartheid system that disallowed the indigenous black majority land rights. , Thesis (MA) -- Faculty of Business and Economic Sciences, Department of Development Studies, 2021
- Full Text: false
- Date Issued: 2021-04
A biological assessment of the Cape knifejaw (Oplegnathus conwayi) an endemic South African teleost
- Authors: Foster, Ryan Matthew
- Date: 2021-10-29
- Subjects: Perciformes South Africa , Osteichthyes South Africa , Fisheries South Africa , Perciformes Growth , Perciformes Age , Perciformes Reproduction , Sampling Citizen participation , Cape knifejaw (Oplegnathus conwayi)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191057 , vital:45054
- Description: The South African spearfishery forms a small component of South Africa’s complex coastal fishery. Although the smallest, this fishery sector has the largest proportion of data deficient species, and as a consequence is poorly managed. Oplegnathus conwayi (Cape knifejaw) is an example of one of these species for which there is very little and outdated biological and ecological data. This species is among the top target species by recreational spearfishers in South Africa. This thesis aimed to improve our socio-ecological knowledge of the South African spearfishery through the collection of biological and Fishers’ Ecological Knowledge (FEK) information on Oplegnathus conwayi, and human dimension information on the South African spearfishery. Monthly biological samples were collected through routine sampling (spearfishing) and augmented by recreational spearfishers. A total of 254 fish were collected from the warm-temperate coastal zone (East London – Cape Agulhas), 28 from the sub-tropical zone (Durban – East London) and 23 from the cool-temperate zone (Cape Agulhas – Cape Point). The results indicated that Oplegnathus conwayi is a slow-growing species, with a maximum recorded age of 27 years. The population sex ratio was skewed, with males dominant in the population (1M:0.6F). The length- and age-frequency distributions were, however, similar for both sexes. No significant differences were observed between male and female growth (LRT, p > 0.05), with the overall population growth curve being best described as L(t) = 697.15(1-e-0.06(t-6.30)). Males matured at a slightly larger size than females, however, no significant differences were observed (LRT, p > 0.05). The length- and age- at-50% maturity was 330 mm (FL) and 5.73 years for the full population, respectively. Histological analyses showed that Oplegnathus conwayi are asynchronous spawners with a gonochoristic reproductive style. Macroscopic staging and gonadosomatic index results indicated a protracted spawning season for Oplegnathus conwayi, with a peak in spring. A survey was designed and disseminated to collect FEK on the biology and population status of Oplegnathus conwayi and human dimension information on South Africa’s spearfishery. A total of 103 survey responses were received, of which 94 were regarded as specialised (spearfishers who had greater experience, skill and avidity, and maintained spearfishing as an important component of their lifestyle) spearfishers. Based on the responses of the specialist spearfishers, the top four main species caught by spearfishers from this survey were Seriola lalandi (13.9%), Pachymetopon grande (11.7%), Oplegnathus conwayi (11.4%) and Sparodon durbanensis (11%), and the majority of respondents indicated that there had been no changes in abundance, size and catches of these species in the years that they had been spearfishing. Respondents indicated that Oplegnathus conwayi are most commonly targeted in the Eastern Cape and are found at depths of up to 40 m. Respondents also indicated that there may be a seasonal onshore (Summer/Winter) and offshore (Summer/Winter) migration with year-round spawning and a peak in November, December and January. The incorporation of spearfishers into the data collection, both through the collection of specimens and their FEK, was beneficial to this study. Besides providing samples from a broader geographical range than the primary collection area, the collaboration with spearfishers has promoted the inclusion of this group into the management system. The findings of this study also suggest that FEK data can be more reliable if the concept of recreational specialisation is incorporated into data collection. While the FEK suggested that the population was stable, a stock assessment is necessary to fully understand the population status and implement management strategies. Nevertheless, the key life history characteristics (slow growth and late maturation) observed in this study are characteristic of species that is vulnerable to overexploitation, and thus the precautionary approach should be applied. The reproductive information collected in this study has provided information for the implementation of an appropriate size limit regulation for Oplegnathus conwayi. Here, a minimum size limit of 400 mm TL, which corresponds approximately with the length-at-50% maturity of 330 mm FL, would be appropriate to allow fish to mature and spawn, and reduce the likelihood of recruitment overfishing. Reduction in the bag limit from five to two fish per person per day may also be appropriate as a precautionary measure until a stock assessment has been completed. Finally, the incorporation of stakeholder into biological collection and the use of FEK may be a useful approach for other data deficient species and in countries with limited resources for ecological research. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Foster, Ryan Matthew
- Date: 2021-10-29
- Subjects: Perciformes South Africa , Osteichthyes South Africa , Fisheries South Africa , Perciformes Growth , Perciformes Age , Perciformes Reproduction , Sampling Citizen participation , Cape knifejaw (Oplegnathus conwayi)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191057 , vital:45054
- Description: The South African spearfishery forms a small component of South Africa’s complex coastal fishery. Although the smallest, this fishery sector has the largest proportion of data deficient species, and as a consequence is poorly managed. Oplegnathus conwayi (Cape knifejaw) is an example of one of these species for which there is very little and outdated biological and ecological data. This species is among the top target species by recreational spearfishers in South Africa. This thesis aimed to improve our socio-ecological knowledge of the South African spearfishery through the collection of biological and Fishers’ Ecological Knowledge (FEK) information on Oplegnathus conwayi, and human dimension information on the South African spearfishery. Monthly biological samples were collected through routine sampling (spearfishing) and augmented by recreational spearfishers. A total of 254 fish were collected from the warm-temperate coastal zone (East London – Cape Agulhas), 28 from the sub-tropical zone (Durban – East London) and 23 from the cool-temperate zone (Cape Agulhas – Cape Point). The results indicated that Oplegnathus conwayi is a slow-growing species, with a maximum recorded age of 27 years. The population sex ratio was skewed, with males dominant in the population (1M:0.6F). The length- and age-frequency distributions were, however, similar for both sexes. No significant differences were observed between male and female growth (LRT, p > 0.05), with the overall population growth curve being best described as L(t) = 697.15(1-e-0.06(t-6.30)). Males matured at a slightly larger size than females, however, no significant differences were observed (LRT, p > 0.05). The length- and age- at-50% maturity was 330 mm (FL) and 5.73 years for the full population, respectively. Histological analyses showed that Oplegnathus conwayi are asynchronous spawners with a gonochoristic reproductive style. Macroscopic staging and gonadosomatic index results indicated a protracted spawning season for Oplegnathus conwayi, with a peak in spring. A survey was designed and disseminated to collect FEK on the biology and population status of Oplegnathus conwayi and human dimension information on South Africa’s spearfishery. A total of 103 survey responses were received, of which 94 were regarded as specialised (spearfishers who had greater experience, skill and avidity, and maintained spearfishing as an important component of their lifestyle) spearfishers. Based on the responses of the specialist spearfishers, the top four main species caught by spearfishers from this survey were Seriola lalandi (13.9%), Pachymetopon grande (11.7%), Oplegnathus conwayi (11.4%) and Sparodon durbanensis (11%), and the majority of respondents indicated that there had been no changes in abundance, size and catches of these species in the years that they had been spearfishing. Respondents indicated that Oplegnathus conwayi are most commonly targeted in the Eastern Cape and are found at depths of up to 40 m. Respondents also indicated that there may be a seasonal onshore (Summer/Winter) and offshore (Summer/Winter) migration with year-round spawning and a peak in November, December and January. The incorporation of spearfishers into the data collection, both through the collection of specimens and their FEK, was beneficial to this study. Besides providing samples from a broader geographical range than the primary collection area, the collaboration with spearfishers has promoted the inclusion of this group into the management system. The findings of this study also suggest that FEK data can be more reliable if the concept of recreational specialisation is incorporated into data collection. While the FEK suggested that the population was stable, a stock assessment is necessary to fully understand the population status and implement management strategies. Nevertheless, the key life history characteristics (slow growth and late maturation) observed in this study are characteristic of species that is vulnerable to overexploitation, and thus the precautionary approach should be applied. The reproductive information collected in this study has provided information for the implementation of an appropriate size limit regulation for Oplegnathus conwayi. Here, a minimum size limit of 400 mm TL, which corresponds approximately with the length-at-50% maturity of 330 mm FL, would be appropriate to allow fish to mature and spawn, and reduce the likelihood of recruitment overfishing. Reduction in the bag limit from five to two fish per person per day may also be appropriate as a precautionary measure until a stock assessment has been completed. Finally, the incorporation of stakeholder into biological collection and the use of FEK may be a useful approach for other data deficient species and in countries with limited resources for ecological research. , Thesis (MSc) -- Faculty of Science, Ichthyology and Fisheries Science, 2021
- Full Text:
- Date Issued: 2021-10-29
A career in photophysicochemical and electrochemical properties of phthalocyanine: A Linstead Career Award paper
- Authors: Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186045 , vital:44458 , xlink:href="https://doi.org/10.1142/S1088424620300037"
- Description: This manuscript highlights the author’s contributions to phthalocyanine chemistry, especially the applications based on their electrochemistry and photophysicochemistry. In particular, the use of phthalocyanines as electrocatalysts and photocatalysts is presented. For photocatalysis, photodynamic antimicrobial chemotherapy and pollution control using green technologies are highlighted. For electrocatalysis the phthalocyanines are employed for the detection of pollutants and environmentally important molecules. Phthalocyanines are combined with nanomaterials for improved photocatalysis and electrocatalysis.
- Full Text:
- Date Issued: 2020
- Authors: Nyokong, Tebello
- Date: 2020
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186045 , vital:44458 , xlink:href="https://doi.org/10.1142/S1088424620300037"
- Description: This manuscript highlights the author’s contributions to phthalocyanine chemistry, especially the applications based on their electrochemistry and photophysicochemistry. In particular, the use of phthalocyanines as electrocatalysts and photocatalysts is presented. For photocatalysis, photodynamic antimicrobial chemotherapy and pollution control using green technologies are highlighted. For electrocatalysis the phthalocyanines are employed for the detection of pollutants and environmentally important molecules. Phthalocyanines are combined with nanomaterials for improved photocatalysis and electrocatalysis.
- Full Text:
- Date Issued: 2020
A case study of lessons learned through empowering and mobilizing unemployed youth into sustainable green jobs within the SANBI – Groen Sebenza partnership programme by a Host Institution in South Africa
- Authors: Fullard, Donovan
- Date: 2021-10-29
- Subjects: South African National Biodiversity Institute , Green movement South Africa , Environmental education South Africa , Communities of practice South Africa , Social learning South Africa , Biodiversity conservation Employees , Job creation South Africa , Mentoring South Africa , Groen Sebenza
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191964 , vital:45183
- Description: This research project constituted as a thesis of limited scope for a Masters in Education Degree (i.e. as 50% of the degree) focusses on a job creation programme named ‘Groen Sebenza’ [Green Work]. Groen Sebenza is an environmental education ‘incubator’ programme driven and implemented by the South African National Biodiversity Institute (SANBI) to unlock green jobs and bridge the gap between education and job opportunities in the biodiversity sector in South Africa. The programme is a key intervention to strengthen biodiversity human capacity development in the biodiversity sector in South Africa, seeking to contribute to transformation of the biodiversity sector, and also address issues of youth unemployment in the country. The young ‘interns’ in the programme were called ‘pioneers’ at the start of the project. This research project explores how a host institution operating as a community of practice within a landscape of practice managed to implement the Groen Sebenza programme by absorbing and appointing all their pioneers into sustainable jobs beyond the pilot project. I sought to better understand the process of supporting and empowering unemployed youth into sustainable green jobs within the Groen Sebenza partnership programme. I drew on Community of Practice (CoP) theory, and its value creation framework to develop this understanding, and I under-laboured the analysis with a social realist analysis of enabling and constraining factors. The unit of analysis of a Community of Practice was a useful focus for the study, as these mentors, managers, and administrators were all involved in supporting the empowerment and retention of the young pioneers in the host institution. To develop deeper insight into the learning and knowing, and value created in and by the Groen Sebenza CoP in the Host Institution, I also sought insight into enabling and constraining factors and how these shaped and contributed to empowerment and retention of the pioneers in sustainable green jobs. The research addressed the main question of ‘How do processes of learning, knowing and value creation contribute to empowerment and retention of unemployed youth in a successful Host Institution in the Groen Sebenza programme, and what enabled or constrained the empowerment and retention processes and outcomes?’. Three sub-questions were used in the study, which focussed on the mentoring, training and workplace experiences and how they contribute to the process of learning and knowing within the Groen Sebenza Community of Practice in the Host Institution? [Addressed in Chapter 4], the value creation elements that emerged in the implementation of the programme in support and empowerment of the pioneers in the Host institution’s Groen Sebenza CoP? [Addressed in Chapter 5], and the enabling and constraining factors that shaped and contributed to the uptake of the Pioneers into sustainable green jobs at the Host Institution within the Groen Sebenza Programme? [Addressed in Chapter 6]. The research was conducted as a qualitative case study, in which I used semi-structured interviews as a key data source, as well as document analysis, and a questionnaire. The study drew on inductive, abductive and retroductive modes of inference since I sought to explore an understanding of the practices and learning that occurred that contributed and led to the successful uptake of Pioneers into jobs, as well as the enabling and constraining factors. The study was interpretive at the epistemic level, and had a social realist under-labouring at the ontological level. Key findings of the study point to the development of enabling cultures of mentoring in workplaces, and the provision of a diversity of workplace learning experiences including formal training. It also points to the importance of personal emergent properties amongst mentors and pioneers that embrace a willingness to work together and build strong relationships, and to learn together. Learning in the community of practice was shown to develop identity and a sense of belonging as pioneers were given meaningful tasks to do and their training and interactions with mentors was experienced as meaningful and relevant. The contributions of the pioneers to the institutional mandate was appreciated by the mentors and therefore also well supported within an empowerment orientation. Various structural factors contributed to this enabling situation, most notably strong support from management as well as good co-operation across divisions. Constraining factors included the physical distances in the province, as well as financial and technical issues such as poor ICT communication systems. Overall, though the study showed that a strong approach to learning in communities of practice supported by empowering mentoring can lead to the integration of young pioneers into sustainable green jobs in the environmental sector. A whole institution approach to this process is, however, needed, and the organisation needs to develop a culture of social learning. As recently as September 2020 as this study was being finalised, the Presidential Employment Stimulus Plan (Office of the President, 2020) following the initial economic shocks emanating from the COVID-19 pandemic, made yet another commitment to using the Groen Sebenza model to create and support sustainable job creation for young people in South Africa today in the environmental sector. This study has been developed and designed to understand those processes and enabling conditions that can support retention and empowerment of young people to take up jobs in the environmental sector today. Its recommendations may therefore be of value to those involved in seeking to support sustainable impacts in terms of retention and employment in programmes such as the Groen Sebenza, and in the Groen Sebenza programme itself as it continues to unfold as a key job creation tool for unemployed youth. , Thesis (MEd) -- Faculty of Education, Education, 2021
- Full Text:
- Date Issued: 2021-10-29
- Authors: Fullard, Donovan
- Date: 2021-10-29
- Subjects: South African National Biodiversity Institute , Green movement South Africa , Environmental education South Africa , Communities of practice South Africa , Social learning South Africa , Biodiversity conservation Employees , Job creation South Africa , Mentoring South Africa , Groen Sebenza
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/191964 , vital:45183
- Description: This research project constituted as a thesis of limited scope for a Masters in Education Degree (i.e. as 50% of the degree) focusses on a job creation programme named ‘Groen Sebenza’ [Green Work]. Groen Sebenza is an environmental education ‘incubator’ programme driven and implemented by the South African National Biodiversity Institute (SANBI) to unlock green jobs and bridge the gap between education and job opportunities in the biodiversity sector in South Africa. The programme is a key intervention to strengthen biodiversity human capacity development in the biodiversity sector in South Africa, seeking to contribute to transformation of the biodiversity sector, and also address issues of youth unemployment in the country. The young ‘interns’ in the programme were called ‘pioneers’ at the start of the project. This research project explores how a host institution operating as a community of practice within a landscape of practice managed to implement the Groen Sebenza programme by absorbing and appointing all their pioneers into sustainable jobs beyond the pilot project. I sought to better understand the process of supporting and empowering unemployed youth into sustainable green jobs within the Groen Sebenza partnership programme. I drew on Community of Practice (CoP) theory, and its value creation framework to develop this understanding, and I under-laboured the analysis with a social realist analysis of enabling and constraining factors. The unit of analysis of a Community of Practice was a useful focus for the study, as these mentors, managers, and administrators were all involved in supporting the empowerment and retention of the young pioneers in the host institution. To develop deeper insight into the learning and knowing, and value created in and by the Groen Sebenza CoP in the Host Institution, I also sought insight into enabling and constraining factors and how these shaped and contributed to empowerment and retention of the pioneers in sustainable green jobs. The research addressed the main question of ‘How do processes of learning, knowing and value creation contribute to empowerment and retention of unemployed youth in a successful Host Institution in the Groen Sebenza programme, and what enabled or constrained the empowerment and retention processes and outcomes?’. Three sub-questions were used in the study, which focussed on the mentoring, training and workplace experiences and how they contribute to the process of learning and knowing within the Groen Sebenza Community of Practice in the Host Institution? [Addressed in Chapter 4], the value creation elements that emerged in the implementation of the programme in support and empowerment of the pioneers in the Host institution’s Groen Sebenza CoP? [Addressed in Chapter 5], and the enabling and constraining factors that shaped and contributed to the uptake of the Pioneers into sustainable green jobs at the Host Institution within the Groen Sebenza Programme? [Addressed in Chapter 6]. The research was conducted as a qualitative case study, in which I used semi-structured interviews as a key data source, as well as document analysis, and a questionnaire. The study drew on inductive, abductive and retroductive modes of inference since I sought to explore an understanding of the practices and learning that occurred that contributed and led to the successful uptake of Pioneers into jobs, as well as the enabling and constraining factors. The study was interpretive at the epistemic level, and had a social realist under-labouring at the ontological level. Key findings of the study point to the development of enabling cultures of mentoring in workplaces, and the provision of a diversity of workplace learning experiences including formal training. It also points to the importance of personal emergent properties amongst mentors and pioneers that embrace a willingness to work together and build strong relationships, and to learn together. Learning in the community of practice was shown to develop identity and a sense of belonging as pioneers were given meaningful tasks to do and their training and interactions with mentors was experienced as meaningful and relevant. The contributions of the pioneers to the institutional mandate was appreciated by the mentors and therefore also well supported within an empowerment orientation. Various structural factors contributed to this enabling situation, most notably strong support from management as well as good co-operation across divisions. Constraining factors included the physical distances in the province, as well as financial and technical issues such as poor ICT communication systems. Overall, though the study showed that a strong approach to learning in communities of practice supported by empowering mentoring can lead to the integration of young pioneers into sustainable green jobs in the environmental sector. A whole institution approach to this process is, however, needed, and the organisation needs to develop a culture of social learning. As recently as September 2020 as this study was being finalised, the Presidential Employment Stimulus Plan (Office of the President, 2020) following the initial economic shocks emanating from the COVID-19 pandemic, made yet another commitment to using the Groen Sebenza model to create and support sustainable job creation for young people in South Africa today in the environmental sector. This study has been developed and designed to understand those processes and enabling conditions that can support retention and empowerment of young people to take up jobs in the environmental sector today. Its recommendations may therefore be of value to those involved in seeking to support sustainable impacts in terms of retention and employment in programmes such as the Groen Sebenza, and in the Groen Sebenza programme itself as it continues to unfold as a key job creation tool for unemployed youth. , Thesis (MEd) -- Faculty of Education, Education, 2021
- Full Text:
- Date Issued: 2021-10-29
A case study on the incidence and extent of medullated and coloured fibres in the commercially produced South African wool clip 2010 – 2017
- Authors: Zietsman, Jolandrie
- Date: 2022-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55445 , vital:52002
- Description: No formal study on the incidence and extent of medullated and coloured fibres has been performed in South Africa. The purpose of this research project was to investigate the validity of the claims that there has been an increase in the production of wool contaminated with medullated and coloured fibres. Therefore, the main aim of this study was to determine whether the incidence and extent of medullated and coloured fibres in the South African wool clip have changed over time. Secondly, the study aimed to determine whether the incidence and extent of medullated and coloured fibres have a distinct geographic distribution. This study explored eight years of wool production records (2010 to 2017) obtained from BKB, the largest wool broker in South Africa. For the purpose of this research, the wool-producing areas of South Africa were divided into 6 regions, according to average annual rainfall, vegetation type and major farming practices applied in the area. Statistical analysis of the data included descriptive statistics, analysis of variance and post-hoc tests, as well as regression analyses. This study succeeded in quantifying the extent and prevalence of contamination with medullated and coloured fibres in the South African wool clip. The overarching conclusions were: • Floating kemp is the most important contaminant of wool in South Africa, with the incidence of harsh kemp and coloured fibres being very low. • Generally, the most important areas that need attention in combatting contamination in the South African wool clip, are the Mixed Farming Summer Rainfall Region, the Semi-Arid Grassveld and the High Rainfall Grassland. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-04
- Authors: Zietsman, Jolandrie
- Date: 2022-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55445 , vital:52002
- Description: No formal study on the incidence and extent of medullated and coloured fibres has been performed in South Africa. The purpose of this research project was to investigate the validity of the claims that there has been an increase in the production of wool contaminated with medullated and coloured fibres. Therefore, the main aim of this study was to determine whether the incidence and extent of medullated and coloured fibres in the South African wool clip have changed over time. Secondly, the study aimed to determine whether the incidence and extent of medullated and coloured fibres have a distinct geographic distribution. This study explored eight years of wool production records (2010 to 2017) obtained from BKB, the largest wool broker in South Africa. For the purpose of this research, the wool-producing areas of South Africa were divided into 6 regions, according to average annual rainfall, vegetation type and major farming practices applied in the area. Statistical analysis of the data included descriptive statistics, analysis of variance and post-hoc tests, as well as regression analyses. This study succeeded in quantifying the extent and prevalence of contamination with medullated and coloured fibres in the South African wool clip. The overarching conclusions were: • Floating kemp is the most important contaminant of wool in South Africa, with the incidence of harsh kemp and coloured fibres being very low. • Generally, the most important areas that need attention in combatting contamination in the South African wool clip, are the Mixed Farming Summer Rainfall Region, the Semi-Arid Grassveld and the High Rainfall Grassland. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-04
A Century of South African Theatre
- Authors: Krueger, Anton
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229623 , vital:49694 , xlink:href="https://doi.org/10.1080/10137548.2020.1716515"
- Description: In many ways, this is an updated repackaging of Loren Kruger's seminal work of 20 years ago, Plays, Pageants and the Drama of South Africa (1999). The material has been extensively revised and reworked using similar categories as the first book, including: pageantry and representations of nationhood, neo-colonial theatre, urbanization and its consequences; the rise of Afrikaans theatre; theatres of resistance; black consciousness; and contemporary theatre. Some of these sections have been extended (such as a longer discussion of HIE Dhlomo) and there is also a completely new section which has not been published elsewhere on current theatre trends (cleverly titled “The Constitution of South African Theatre at the Present Time”).
- Full Text:
- Date Issued: 2019
- Authors: Krueger, Anton
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229623 , vital:49694 , xlink:href="https://doi.org/10.1080/10137548.2020.1716515"
- Description: In many ways, this is an updated repackaging of Loren Kruger's seminal work of 20 years ago, Plays, Pageants and the Drama of South Africa (1999). The material has been extensively revised and reworked using similar categories as the first book, including: pageantry and representations of nationhood, neo-colonial theatre, urbanization and its consequences; the rise of Afrikaans theatre; theatres of resistance; black consciousness; and contemporary theatre. Some of these sections have been extended (such as a longer discussion of HIE Dhlomo) and there is also a completely new section which has not been published elsewhere on current theatre trends (cleverly titled “The Constitution of South African Theatre at the Present Time”).
- Full Text:
- Date Issued: 2019
A chiral hemiporphyrazine derivative
- Wu, Yanping, Gai, Lizhi, Xiao, Xuqiong, Lu, Hua, Li, Zhifang, Mack, John, Harris, Jessica, Nyokong, Tebello, Shen, Zhen
- Authors: Wu, Yanping , Gai, Lizhi , Xiao, Xuqiong , Lu, Hua , Li, Zhifang , Mack, John , Harris, Jessica , Nyokong, Tebello , Shen, Zhen
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240404 , vital:50831 , xlink:href="https://doi.org/10.1002/asia.201600754"
- Description: The synthesis of an optically active hemiporphyrazine with chiral binaphthyl substituents (1) is reported, providing the first example of the incorporation of an intrinsically chiral moiety into the macrocyclic core of a hemiporphyrazine analogue. A negative circular dichroism (CD) signal is observed in the 325–450 nm region of the CD spectrum of (S,S)-1, while mainly positive bands are observed in the 220–325 nm region. Mirror symmetry is observed across the entire wavelength range of the CD spectra of (R,R)-1 and (S,S)-1. An irreversible one-electron oxidation wave with an onset potential at 1.07 V is observed by cyclic voltammetry, along with a reversible one-electron reduction wave at −0.85 V. Density functional calculations reproduce the experimentally observed data and trends, and provide further insight into the nature of the electronic transitions.
- Full Text:
- Date Issued: 2016
- Authors: Wu, Yanping , Gai, Lizhi , Xiao, Xuqiong , Lu, Hua , Li, Zhifang , Mack, John , Harris, Jessica , Nyokong, Tebello , Shen, Zhen
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240404 , vital:50831 , xlink:href="https://doi.org/10.1002/asia.201600754"
- Description: The synthesis of an optically active hemiporphyrazine with chiral binaphthyl substituents (1) is reported, providing the first example of the incorporation of an intrinsically chiral moiety into the macrocyclic core of a hemiporphyrazine analogue. A negative circular dichroism (CD) signal is observed in the 325–450 nm region of the CD spectrum of (S,S)-1, while mainly positive bands are observed in the 220–325 nm region. Mirror symmetry is observed across the entire wavelength range of the CD spectra of (R,R)-1 and (S,S)-1. An irreversible one-electron oxidation wave with an onset potential at 1.07 V is observed by cyclic voltammetry, along with a reversible one-electron reduction wave at −0.85 V. Density functional calculations reproduce the experimentally observed data and trends, and provide further insight into the nature of the electronic transitions.
- Full Text:
- Date Issued: 2016