The analysis of trace gas emissions from landfills
- Authors: Rubidge, Gletwyn Robert
- Date: 2000
- Subjects: Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10983 , http://hdl.handle.net/10948/d1006341 , Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Description: Numerous informal houses have been built on and adjacent to a landfill in iBayi, Port Elizabeth, South Africa, which accepted domestic and industrial waste. Formal housing surrounds most of the site at a greater distance - some 60 m, or further, from the landfill. Both formal and informally housed residents complain of odours, burning eyes, sore throats and headaches - symptoms which they believed were caused by the landfill. The landfill gas and ambient air were analyzed to classify and quantify the VOCs (volatile organic compounds) emitted and then to compare the quantitative data with recognised standards to establish if the residents are at risk. Eighteen target (potentially hazardous) VOCs were quantified. A wide variety of compounds were detected in both the ambient air and landfill gas. The results of the VOC analyses were similar to those of other workers in both the qualitative and quantitative studies. The concentrations of the VOCs were mostly lower than the TLV (threshold limit values) values, but exceeded the MRLs (minimum recommended levels). The combined concentrations of the VOC’s in the ambient air either approached or exceeded the limit values for combined exposure thus indicating that a potential health hazard exists. One third of the VOCs were detected in both the ambient air and the subsurface gas, however, external pollution sources also appear to contribute to the VOC concentrations ambient air. Dangerously high methane concentrations were repeatedly detected in the landfill gas amongst the informal houses. There was a vast improvement in the aesthetic qualities of the landfill since the disposal restriction to accept only domestic refuse and building rubble in July 1997. The ambient air was less odorous and landfill site littered. Fewer informal recyclers were present and their concomitant squabbling over valuables had almost vanished. The management of the iBayi landfill holds much room for improvement. There is potential for serious injury or even death if no action is taken to remedy the problems at the iBayi landfill. A holistic solution will have to be found to make the landfill a safe neighbour. Some complementary analyses (such as pH, heavy metal concentrations in the water and sediments etc.) were performed on the leachate and water surrounding the landfill.
- Full Text:
- Date Issued: 2000
- Authors: Rubidge, Gletwyn Robert
- Date: 2000
- Subjects: Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10983 , http://hdl.handle.net/10948/d1006341 , Gases, Asphyxiating and poisonnous , Gases -- Analysis , Sanitation -- Environmental engineering
- Description: Numerous informal houses have been built on and adjacent to a landfill in iBayi, Port Elizabeth, South Africa, which accepted domestic and industrial waste. Formal housing surrounds most of the site at a greater distance - some 60 m, or further, from the landfill. Both formal and informally housed residents complain of odours, burning eyes, sore throats and headaches - symptoms which they believed were caused by the landfill. The landfill gas and ambient air were analyzed to classify and quantify the VOCs (volatile organic compounds) emitted and then to compare the quantitative data with recognised standards to establish if the residents are at risk. Eighteen target (potentially hazardous) VOCs were quantified. A wide variety of compounds were detected in both the ambient air and landfill gas. The results of the VOC analyses were similar to those of other workers in both the qualitative and quantitative studies. The concentrations of the VOCs were mostly lower than the TLV (threshold limit values) values, but exceeded the MRLs (minimum recommended levels). The combined concentrations of the VOC’s in the ambient air either approached or exceeded the limit values for combined exposure thus indicating that a potential health hazard exists. One third of the VOCs were detected in both the ambient air and the subsurface gas, however, external pollution sources also appear to contribute to the VOC concentrations ambient air. Dangerously high methane concentrations were repeatedly detected in the landfill gas amongst the informal houses. There was a vast improvement in the aesthetic qualities of the landfill since the disposal restriction to accept only domestic refuse and building rubble in July 1997. The ambient air was less odorous and landfill site littered. Fewer informal recyclers were present and their concomitant squabbling over valuables had almost vanished. The management of the iBayi landfill holds much room for improvement. There is potential for serious injury or even death if no action is taken to remedy the problems at the iBayi landfill. A holistic solution will have to be found to make the landfill a safe neighbour. Some complementary analyses (such as pH, heavy metal concentrations in the water and sediments etc.) were performed on the leachate and water surrounding the landfill.
- Full Text:
- Date Issued: 2000
An investigation of the effect of time of pruning on the growth and fruiting of lemons [Citrus limon(L.) Burmann f.] cv. Eureka
- Authors: Pittaway, Timothy Michael
- Date: 2002
- Subjects: Lemon , Pruning , Fruit-culture
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10974 , http://hdl.handle.net/10948/106 , Lemon , Pruning , Fruit-culture
- Description: Pruning has been used to reduce tree size, allow light penetration into trees, improve yield, improve fruit size and fruit quality, overcome alternate bearing, assist fruit harvest, and assist pest and disease control. The use of pruning has increased due to improving agricultural management techniques such as high planting densities, use of mechanical machinery in orchards and the need for effective pesticide and pathological chemical spray applications. The main objective of this study was to obtain a practical means of manipulating lemon trees at the right time. Pruning at the correct time to cultivate productive trees that produce quality fruit would have financial benefits. Lemon fruit quality is dependent on market demand and involves a number of features such as fruit shelf life, rind thickness, fruit size, rind colour, and juice content. The study was conducted on ’Eureka’ lemon trees budded on C. volkameriana rootstock, bearing the fifth and sixth commercial crops in 1999 and 2000 respectively. Twelve monthly pruning treatments per year were conducted on one row of trees starting in December 1997 (site 1) and repeated in the second year on the adjacent row of the same orchard starting in December 1998 (site 2). Selective pruning heading cuts were applied below the intercalation on the intercalary units. Potential branch bearing units were tagged and assessed during the harvest and flowering periods. Summer pruning between 16 to 19 months before the subsequent April/May harvest, resulted in the longest and most complex (intercalation sprouted per axil) vegetative response. The estimated crop value indicated that summer pruning treatments produced the highest income. This was ascribed not to differences in fruit size or quality, but to an increase in yield. The industry’s trend is to prune citrus from post-harvest to the pre-bloom stage. Results from this study have provided a beneficial cultural practice to prune during the summer months and provides a practice to optimise farm production and profit margins.
- Full Text:
- Date Issued: 2002
- Authors: Pittaway, Timothy Michael
- Date: 2002
- Subjects: Lemon , Pruning , Fruit-culture
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10974 , http://hdl.handle.net/10948/106 , Lemon , Pruning , Fruit-culture
- Description: Pruning has been used to reduce tree size, allow light penetration into trees, improve yield, improve fruit size and fruit quality, overcome alternate bearing, assist fruit harvest, and assist pest and disease control. The use of pruning has increased due to improving agricultural management techniques such as high planting densities, use of mechanical machinery in orchards and the need for effective pesticide and pathological chemical spray applications. The main objective of this study was to obtain a practical means of manipulating lemon trees at the right time. Pruning at the correct time to cultivate productive trees that produce quality fruit would have financial benefits. Lemon fruit quality is dependent on market demand and involves a number of features such as fruit shelf life, rind thickness, fruit size, rind colour, and juice content. The study was conducted on ’Eureka’ lemon trees budded on C. volkameriana rootstock, bearing the fifth and sixth commercial crops in 1999 and 2000 respectively. Twelve monthly pruning treatments per year were conducted on one row of trees starting in December 1997 (site 1) and repeated in the second year on the adjacent row of the same orchard starting in December 1998 (site 2). Selective pruning heading cuts were applied below the intercalation on the intercalary units. Potential branch bearing units were tagged and assessed during the harvest and flowering periods. Summer pruning between 16 to 19 months before the subsequent April/May harvest, resulted in the longest and most complex (intercalation sprouted per axil) vegetative response. The estimated crop value indicated that summer pruning treatments produced the highest income. This was ascribed not to differences in fruit size or quality, but to an increase in yield. The industry’s trend is to prune citrus from post-harvest to the pre-bloom stage. Results from this study have provided a beneficial cultural practice to prune during the summer months and provides a practice to optimise farm production and profit margins.
- Full Text:
- Date Issued: 2002
The evaluation of potential improvements of barton pot oxides for lead acid batteries
- Authors: Geyer, Laurence Thomas
- Date: 2003
- Subjects: Lead oxides -- South Africa , Lead acid batteries -- South Africa
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10982 , http://hdl.handle.net/10948/233 , Lead oxides -- South Africa , Lead acid batteries -- South Africa
- Description: Lead Oxide (PbO) is the main material used for the preparation of the active material for the positive and negative electrodes in the lead acid battery where the electrochemical reaction that provides the electrical energy of the battery takes place. The particle size distribution and surface area characteristics of the lead oxide play a major role in the electrical performance of the completed battery. The two most commonly used processes to manufacture PbO in the lead acid battery industry are the Barton pot and the Ball mill processes. These two processes produce oxides that differ in particle size distribution, particle shape and surface area. It is generally accepted that the Ball mill process produces an oxide with a smaller mean particle size with a higher surface area and better initial electrical performance than the Barton pot process to the detriment of an initial higher capital and running cost. The study showed that it is possible to improve the surface area and particle size distribution characteristics of Barton pot oxide, by subsequently hammer milling the oxide particles before the paste manufacturing process. The results showed that there was an initial reduction in the particle size with an increase in the surface area. This increased the electrochemical performance in terms of the high rate discharge. However, further hammering of the oxide reduced the average particle size only slightly with little change in the surface area and a reduction in the electrochemical performance. The study showed that an improvement in Barton pot oxide can be achieved with a hammering of the oxide in order to obtain a uniform particle size with improved surface area and an improved high rate performance of the electrochemical cells made with such an oxide. As a comparison, the particle size and surface area characteristics of Ball mill lead oxide subjected to the hammer milling process was also studied. The results showed a similar effect to the Barton pot oxide on the particle size distribution. However, there was no appreciable change in the surface area due to the hammer milling process.
- Full Text:
- Date Issued: 2003
- Authors: Geyer, Laurence Thomas
- Date: 2003
- Subjects: Lead oxides -- South Africa , Lead acid batteries -- South Africa
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10982 , http://hdl.handle.net/10948/233 , Lead oxides -- South Africa , Lead acid batteries -- South Africa
- Description: Lead Oxide (PbO) is the main material used for the preparation of the active material for the positive and negative electrodes in the lead acid battery where the electrochemical reaction that provides the electrical energy of the battery takes place. The particle size distribution and surface area characteristics of the lead oxide play a major role in the electrical performance of the completed battery. The two most commonly used processes to manufacture PbO in the lead acid battery industry are the Barton pot and the Ball mill processes. These two processes produce oxides that differ in particle size distribution, particle shape and surface area. It is generally accepted that the Ball mill process produces an oxide with a smaller mean particle size with a higher surface area and better initial electrical performance than the Barton pot process to the detriment of an initial higher capital and running cost. The study showed that it is possible to improve the surface area and particle size distribution characteristics of Barton pot oxide, by subsequently hammer milling the oxide particles before the paste manufacturing process. The results showed that there was an initial reduction in the particle size with an increase in the surface area. This increased the electrochemical performance in terms of the high rate discharge. However, further hammering of the oxide reduced the average particle size only slightly with little change in the surface area and a reduction in the electrochemical performance. The study showed that an improvement in Barton pot oxide can be achieved with a hammering of the oxide in order to obtain a uniform particle size with improved surface area and an improved high rate performance of the electrochemical cells made with such an oxide. As a comparison, the particle size and surface area characteristics of Ball mill lead oxide subjected to the hammer milling process was also studied. The results showed a similar effect to the Barton pot oxide on the particle size distribution. However, there was no appreciable change in the surface area due to the hammer milling process.
- Full Text:
- Date Issued: 2003
The long term effects of fire frequency and season on the colophospermum mopane shrubveld of the Kruger National Park
- Lombard, Pieter Jacobus Lategan
- Authors: Lombard, Pieter Jacobus Lategan
- Date: 2003
- Subjects: Mopane tree -- Effect of fires on -- South Africa -- Kruger National Park
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10970 , http://hdl.handle.net/10948/257 , Mopane tree -- Effect of fires on -- South Africa -- Kruger National Park
- Description: Background : The recorded history of veld burning in the Kruger National Park (KNP) started with the appointment of Colonel James Stevenson-Hamilton as warden of the Park (then the Sabie Game Reserve) in July 1912 and can be divided into five periods: From 1912 to 1926, a haphazard, and indecisive burning policy was practiced, mainly due to the perception that fire was unfavourable for the environment and because the means to combat veld fires were very meagre. From 1926 to 1948, in which period it was realized that fire was not only unavoidable over a large area such as the KNP, but also actually desirable, necessary and beneficial when applied with circumspection. During this period the capability to successfully introduce and apply a definite fire policy did not exist. From 1948 to 1956, prescribed burning was not practiced, but a network of graded firebreaks was being established (to create burning blocks), and wild fires were actively combated. From 1957 to 1993, during which period a definite prescribed burning policy was practiced, amended several times, but basically consisting of a triennial rotational system where blocks were burned by management. All fires of non-management ignition sources were combated. From 1993 to the present, when a policy of allowing lightning-ignited fires to burn freely was introduced, and fires of human origin were suppressed. The shift away from a rigid prescribed burning programme was because of the concern that the dominance of grass species characteristic of over utilised veld was a result of too frequent burning (Potgieter, 2001). Lightning fires probably played just as an important role in shaping African savanna in pre-industrial times as anthropogenic fires caused by preindustrial man. The role of post-industrial man as far as its influence on the creation of savanna is concerned is probably negligible, but significantly important in the role of maintaining savanna, although probably not more so than that of lighting fires. Fires caused by postindustrial man becomes suspect as far as the creation of savanna is concerned, because instead of the mere burning of the veld for the pure reasons of survival as practiced by pre-industrial man, a measure of commercialism crept in (Potgieter, 2001). Fire management of the KNP in pre-industrial times can be regarded in the same light as that of post-industrial times. Although the motive for burning the veld in the KNP was beyond reproach, the underlying reasoning was not. Managers’ thinking was geared towards preventing so called “devastating fires”, laying to waste large areas of the Park, not realising that this was in actual fact nature going about its business in this ecosystem. They therefore devised a system of firebreak roads, which was gradually extended to the extent that we now have more than 4000 km roads that must be maintained. This was all in the cause of preventing or managing lightning and arson fires. Given the above, a revision of the veld fire policy was extremely necessary. The mission statement hammered out during the revising process in 1993 underscored and supported the proposal put forward in 1992, that lightning fires should be recognised as a legitimate and completely natural phenomenon in the Lowveld ecosystem. This had to be weighed against the prevailing practice of combating all fires caused by lightning and non-management anthropogenic sources of fire. The essence of this policy would therefore be to allow lightning-fires to burn to their full extent i.e. if vegetation conditions (available biomass) are such that large areas will burn, then such burns will be permitted to proceed to their full extent with the provision that no more than 50% of the management unit will be allowed to burn out (no matter what the ignition source) in a specific fire season (Potgieter, 2001).
- Full Text:
- Date Issued: 2003
- Authors: Lombard, Pieter Jacobus Lategan
- Date: 2003
- Subjects: Mopane tree -- Effect of fires on -- South Africa -- Kruger National Park
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10970 , http://hdl.handle.net/10948/257 , Mopane tree -- Effect of fires on -- South Africa -- Kruger National Park
- Description: Background : The recorded history of veld burning in the Kruger National Park (KNP) started with the appointment of Colonel James Stevenson-Hamilton as warden of the Park (then the Sabie Game Reserve) in July 1912 and can be divided into five periods: From 1912 to 1926, a haphazard, and indecisive burning policy was practiced, mainly due to the perception that fire was unfavourable for the environment and because the means to combat veld fires were very meagre. From 1926 to 1948, in which period it was realized that fire was not only unavoidable over a large area such as the KNP, but also actually desirable, necessary and beneficial when applied with circumspection. During this period the capability to successfully introduce and apply a definite fire policy did not exist. From 1948 to 1956, prescribed burning was not practiced, but a network of graded firebreaks was being established (to create burning blocks), and wild fires were actively combated. From 1957 to 1993, during which period a definite prescribed burning policy was practiced, amended several times, but basically consisting of a triennial rotational system where blocks were burned by management. All fires of non-management ignition sources were combated. From 1993 to the present, when a policy of allowing lightning-ignited fires to burn freely was introduced, and fires of human origin were suppressed. The shift away from a rigid prescribed burning programme was because of the concern that the dominance of grass species characteristic of over utilised veld was a result of too frequent burning (Potgieter, 2001). Lightning fires probably played just as an important role in shaping African savanna in pre-industrial times as anthropogenic fires caused by preindustrial man. The role of post-industrial man as far as its influence on the creation of savanna is concerned is probably negligible, but significantly important in the role of maintaining savanna, although probably not more so than that of lighting fires. Fires caused by postindustrial man becomes suspect as far as the creation of savanna is concerned, because instead of the mere burning of the veld for the pure reasons of survival as practiced by pre-industrial man, a measure of commercialism crept in (Potgieter, 2001). Fire management of the KNP in pre-industrial times can be regarded in the same light as that of post-industrial times. Although the motive for burning the veld in the KNP was beyond reproach, the underlying reasoning was not. Managers’ thinking was geared towards preventing so called “devastating fires”, laying to waste large areas of the Park, not realising that this was in actual fact nature going about its business in this ecosystem. They therefore devised a system of firebreak roads, which was gradually extended to the extent that we now have more than 4000 km roads that must be maintained. This was all in the cause of preventing or managing lightning and arson fires. Given the above, a revision of the veld fire policy was extremely necessary. The mission statement hammered out during the revising process in 1993 underscored and supported the proposal put forward in 1992, that lightning fires should be recognised as a legitimate and completely natural phenomenon in the Lowveld ecosystem. This had to be weighed against the prevailing practice of combating all fires caused by lightning and non-management anthropogenic sources of fire. The essence of this policy would therefore be to allow lightning-fires to burn to their full extent i.e. if vegetation conditions (available biomass) are such that large areas will burn, then such burns will be permitted to proceed to their full extent with the provision that no more than 50% of the management unit will be allowed to burn out (no matter what the ignition source) in a specific fire season (Potgieter, 2001).
- Full Text:
- Date Issued: 2003
Optimization of a manufacturing process for atrazine with a focus on waste minimization
- Authors: Mtyopo, Mteteleli Bethwell
- Date: 2004
- Subjects: Waste minimization , Atrazine -- Environmental aspects
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10976 , http://hdl.handle.net/10948/259 , Waste minimization , Atrazine -- Environmental aspects
- Description: Chemical synthesis is not complete without waste treatment. There is no chemical process that does not produce waste. The untreated effluent discharged by chemical industries poses a major environmental concern. This dissertation describes the results of an investigation carried out on the formation of by-products (impurities) during the synthesis of atrazine by neutralization of the reaction mixture during the actual synthesis procedure, and prior to disposal using carbon dioxide or hydrochloric acid. The main objectives for the said investigation were: {u100083} To optimise the reaction parameters to obtain a higher yield and purity of atrazine. {u100083} To evaluate the use of carbon dioxide and hydrochloric acid to neutralise the reaction mixture. {u100083} To study the solids present in the effluent. Synthetic reactions were carried out in the presence of an organic solvent, methyl isobutyl ketone (MIBK). The synthesis of atrazine was optimised in terms of addition sequence and rates of amine reagents and base (proton acceptor) additions by means of bench scale reactions. It was found that addition of a neutralising step (hydrochloric acid or carbon dioxide) to neutralise the basic reaction mixture prior to and after addition of the secondary amine and the base minimizes the formation of by-products. Of particular importance in ensuring high yields and selectivity to the atrazine product was temperature control, pH control, reagent ratios, addition rates and mixing. The latter was important in view of the rapid reaction of amine/NaOH with cyanuric chloride, as well as the possible reaction of mono-i, the reaction intermediate, with IPA in cases of excesses of reagent. Under optimum conditions, an atrazine composition of >97% was achieved where the resultant product was well within stipulated product specifications.
- Full Text:
- Date Issued: 2004
- Authors: Mtyopo, Mteteleli Bethwell
- Date: 2004
- Subjects: Waste minimization , Atrazine -- Environmental aspects
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10976 , http://hdl.handle.net/10948/259 , Waste minimization , Atrazine -- Environmental aspects
- Description: Chemical synthesis is not complete without waste treatment. There is no chemical process that does not produce waste. The untreated effluent discharged by chemical industries poses a major environmental concern. This dissertation describes the results of an investigation carried out on the formation of by-products (impurities) during the synthesis of atrazine by neutralization of the reaction mixture during the actual synthesis procedure, and prior to disposal using carbon dioxide or hydrochloric acid. The main objectives for the said investigation were: {u100083} To optimise the reaction parameters to obtain a higher yield and purity of atrazine. {u100083} To evaluate the use of carbon dioxide and hydrochloric acid to neutralise the reaction mixture. {u100083} To study the solids present in the effluent. Synthetic reactions were carried out in the presence of an organic solvent, methyl isobutyl ketone (MIBK). The synthesis of atrazine was optimised in terms of addition sequence and rates of amine reagents and base (proton acceptor) additions by means of bench scale reactions. It was found that addition of a neutralising step (hydrochloric acid or carbon dioxide) to neutralise the basic reaction mixture prior to and after addition of the secondary amine and the base minimizes the formation of by-products. Of particular importance in ensuring high yields and selectivity to the atrazine product was temperature control, pH control, reagent ratios, addition rates and mixing. The latter was important in view of the rapid reaction of amine/NaOH with cyanuric chloride, as well as the possible reaction of mono-i, the reaction intermediate, with IPA in cases of excesses of reagent. Under optimum conditions, an atrazine composition of >97% was achieved where the resultant product was well within stipulated product specifications.
- Full Text:
- Date Issued: 2004
Replacing maize with barley in concetrates fed to jersey cows grazing on kikuyu/ryegrass pasture
- Authors: Lehmann, Maryna
- Date: 2004
- Subjects: Jersey cattle -- Feeding and feeds , Dairy cattle -- Feeding and feeds
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10732 , http://hdl.handle.net/10948/181 , Jersey cattle -- Feeding and feeds , Dairy cattle -- Feeding and feeds
- Description: The aim of the first study was to determine if barley could replace maize as an energy source in concentrates fed to dairy cows grazing on kikuyu/ryegrass pasture without affecting the milk production, milk composition, or cause metabolic disorders. Sixty Jersey cows, in early to mid lactation were randomly allocated to one of five treatments (n = 12) based on feeding concentrates with different ratios of maize to barley, ranging from 100:0, 75:25, 50:50, 25:75 and 0:100, respectively. Concentrates contained 12 MJ ME kg -1 and 130g CP kg-1 DM and cows were fed 3 kg (as-is) concentrate after each milking for a period of 42 days (14-day adaptation and 28-day measurement). Cows strip-grazed the irrigated kikuyu/ryegrass pastures (15.7 ± 1.8 percent DM; 20.2 ± 4.3 percent CP; 44.7 ± 3.5 percent NDF). Milk weights were recorded daily and milk samples collected weekly and analyzed for milk fat and protein content. Body condition score and live weight were recorded at the start and end of the experimental period. Data of all the studies were subjected to a one-way ANOVA. Daily milk yield, FCM, MUN, milk fat yield, milk fat percent, protein yield, protein percent, live weight change, or body condition score change were not affected by treatment and values were 15.8 kg, 17.2 kg, 14.9 mg dl-1, 0.72 kg, 4.56 percent, 0.59 kg, 3.77 percent, 6.67 kg, and 0.15 BCS; 15.6 kg, 17.4 kg, 15.2 mg dl-1, 0.73 kg, 4.3 percent, 0.57 kg, 3.71 percent, 1.33 kg and 0.04 BCS; 17.2 kg, 17.9 kg, 15.2 mg dl-1, 0.74 kg, 4.36 percent, 0.63 kg, 3.71 percent, 0.33 kg and 0.08 BCS; 15.6 kg, 16.4 kg, 15.5 mg dl-1, 0.67 kg, 4.33 percent, 0.60 kg, 3.83 percent, -1.46 kg and 0.11 BCS; and 15.0 kg, 16.0 kg, 15.5 mg dl-1, 0.67 kg, 4.57 percent, 0.57 kg, 3.85 percent, 8.86 kg, and 0.05 BCS, respectively for the cows fed 100:0, 75:25, 50:50, 25:75 and 0:100 maize to barley ratio concentrate. According to these results, barley can replace maize without significantly affecting the milk production or milk composition. None of the cows presented any visible symptoms of acidosis. As it was clear from the results in the first study that maize could replace barley the aim of study 2A was therefore focused on determining the effect of feeding different levels of such a barley-based (2.4, 4.8 or 7.2 kg cow-1day-1) concentrate, on milk production, milk composition and live weight change of Jersey cows on kikuyu/ryegrass pasture (23.1 ± 2.95 percent DM, 11.1 ± 0.11 percent CP, 60.8 ± 0.58 percent NDF). Forty-five Jersey cows (early- to mid lactation), were randomly allocated to one of three treatments (n = 15) involving different levels of concentrate (12 MJ ME and 130g CP kg-1 DM) feeding for a period of 42 days (14-day adaptation and 28-day measurement). Milk weights were also recorded daily, and milk samples collected weekly, and analyzed for milk fat and protein. Body condition score and live weight were recorded at the start and end of the experimental period. The results of this study indicated that increasing the concentrate level from 2.4 to 4.8 and 7.2kg cow-1day-1 did not increase the milk yield (14.0 kg, 15.2 kg, 14.4 kg; P = 0.19). The FCM production increased from 15.8 to 17.5kg (P = 0.04) as the concentrate level increased from 2.4 to 4.8kg cow-1day-1. Increasing the concentrate from 4.8 to 7.2kg cow-1day-1 did not result in a significant increase in FCM. The milk protein percent increased significantly from 3.4 - 3.6 percent when the concentrate feeding level was increased from 2.4 to 7.2kg cow-1day-1. The MUN levels were 17.09 mg dl-1, 16.03 5 mg dl-1, and 16.36 mg dl-1 for the 2.4, 4.8 and 7.2kg cow-1day-1 concentrate levels, respectively. This is well within the recommended MUN levels (12 – 18 mg dl-1) indicating that sufficient protein was fed to cows. Increasing the concentrate level from 4.8 to 7.2 kg cow-1day-1 did not increase production, probably due to a higher pasture substitution rate. Supplementing large quantities of rapidly fermentable grains, such as barley, can suppress rumen pH and may have a negative effect on the rate and extent of fibre digestion in the rumen. Therefore the aim of study 2B was not only to determine the effect of feeding different levels of a barley-based concentrate, on milk production, milk composition and live weight change, but was also to determine the effect of a low (4.8 kg cow-1day-1) versus a high (7.2 kg cow-1day-1) level of barley-based concentrate supplementation on ruminal DM and NDF degradability of Westerworld ryegrass sampled from the pastures that these cows were grazing on. Sixty Jersey cows (early- to mid lactation), were randomly allocated to one of three treatments (n = 20) involving different levels of concentrate feeding. Concentrate (12 MJ ME, 130g CP kg-1 DM) was fed at 2.4, 4.8 or 7.2 kg cow-1day-1 for a period of 74 days (14-day adaptation and 60-day measurement). These cows stripgrazed irrigated kikuyu/ryegrass pastures (14.7 ± 4.37 percent DM, 25.1 ± 1.53 percent CP, and 44.4 ± 2.58 percent NDF) at a daily pasture allocation of 10 kg DM cow-1. Milk weights were recorded daily and milk samples collected weekly and analyzed for milk fat and protein. Body condition score and live weight were recorded at the start and end of the experimental period. Twelve Jersey cows, fitted with ruminal cannulae, were randomly allocated to two of the three treatments in the production study and received either 2.4 or 7.2 kg cow-1 day-1, of the same barley-based concentrate, in a two-period crossover design. These cows strip-grazed the same irrigated kikuyu/ryegrass pastures as the sixty cows in the production study. Each period consisted of 21 days for adaptation and seven days for data collection. Rumen liquor samples were collected every 4 hours within a 24-hour cycle and repeated once. Rumen pH was measured immediately, recorded, and the supernatant fluid preserved and frozen, pending VFA analysis. The in situ nylon bag technique was used to determine DM and NDF degradation and dried samples of Westerworld ryegrass pasture were incubated for 0, 4, 8, 12, 20, 30, 48, 72 and 96 hours. The data were fitted in the non-linear model p = a + b (1-exp-ct) (Ørskov & McDonald, 1979). Daily milk production, fat corrected milk, milk fat yield and milk fat percent were not affected by treatment and values were 17.3 kg, 18.4 kg, 0.76 kg and 4.42 percent; 19.0 kg, 20.0 kg, 0.82 kg and 4.35 percent; and 18.1 kg, 19.1 kg, 0.79 kg and 4.37 percent for the 2.4, 4.8 and 7.2 kg cow-1 day-1 concentrate treatments, respectively. Milk protein percentage of cows on the 7.2 kg concentrate cow-1 day-1 was significantly higher than that of cows on 4.2 kg concentrate cow-1 day-1 feeding level. Live weight increased significantly as the level of concentrate feeding increased and values were 17.9 kg; and 28.9 kg on the 2.4 and 7.2kg concentrate treatment, respectively. There was a significant increase in the live weight of cows that were fed 7.2 kg cow-1 day-1 (as-is) in comparison to those cows that were fed 2.4 kg concentrate cow-1 day-1 (as-is). This may have resulted from more nutrients being partitioned to live weight gain rather than milk production. No further response in milk production was observed when concentrate daily feeding was increased from 4.8 to 7.2 kg cow-1 day-1. It is postulated that the higher concentrate allowance resulted in a higher substitution rate and lower DMI intake from pasture. 6 There was no significant decline in the rumen pH (6.2 ± 0.4 and 6.2 ± 0.5) when the concentrate level was increased from 2.4 to 7.2 kg cow-1 day-1 (as-is). The total VFA (118.1 ± 45.9 and 139.4 ± 45.6 mmol L-1) and isovalerate (0.009 ± 0.07 and 0.248 ± 0.52 mmol L-1) increased significantly when the concentrate was increased from 2.4 to 7.2 kg cow-1day-1. No other rumen parameters were affected by treatment. Ruminal DM and NDF degradability of the Kikuyu/ryegrass pature were not affected by the level of concentrate supplementation. An increase in the concentrate level from 2.4 to 7.2 kg cow-1day-1 did not reduce degradability of either DM (94.67 ± 5.97, 94.49 ± 5.09; P = 0.919) or NDF (92.15 ± 8.69, 94.4 ± 11.73; P = 0.451), respectively. Results of rumen parameters and PD values were within the range reported by Bargo et al., (2003), viz. pH 5.76 – 6.29, NH3-N concentration 8.7 – 32.2 mg dl-1, total VFA concentration 90.3 - 151.4 mmol L-1 and PD values 89.5 – 93.5 % reported by Bargo et al. (2003). According to these authors, there is no simple relationship between any amount of the concentrate supplemented, and the ruminal pH and concentrate feeding only affects the in situ ruminal digestion of pasture when it is fed, at quantities higher than 8 kg DM cow-1day-1 (Bargo et al., 2003).
- Full Text:
- Date Issued: 2004
- Authors: Lehmann, Maryna
- Date: 2004
- Subjects: Jersey cattle -- Feeding and feeds , Dairy cattle -- Feeding and feeds
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10732 , http://hdl.handle.net/10948/181 , Jersey cattle -- Feeding and feeds , Dairy cattle -- Feeding and feeds
- Description: The aim of the first study was to determine if barley could replace maize as an energy source in concentrates fed to dairy cows grazing on kikuyu/ryegrass pasture without affecting the milk production, milk composition, or cause metabolic disorders. Sixty Jersey cows, in early to mid lactation were randomly allocated to one of five treatments (n = 12) based on feeding concentrates with different ratios of maize to barley, ranging from 100:0, 75:25, 50:50, 25:75 and 0:100, respectively. Concentrates contained 12 MJ ME kg -1 and 130g CP kg-1 DM and cows were fed 3 kg (as-is) concentrate after each milking for a period of 42 days (14-day adaptation and 28-day measurement). Cows strip-grazed the irrigated kikuyu/ryegrass pastures (15.7 ± 1.8 percent DM; 20.2 ± 4.3 percent CP; 44.7 ± 3.5 percent NDF). Milk weights were recorded daily and milk samples collected weekly and analyzed for milk fat and protein content. Body condition score and live weight were recorded at the start and end of the experimental period. Data of all the studies were subjected to a one-way ANOVA. Daily milk yield, FCM, MUN, milk fat yield, milk fat percent, protein yield, protein percent, live weight change, or body condition score change were not affected by treatment and values were 15.8 kg, 17.2 kg, 14.9 mg dl-1, 0.72 kg, 4.56 percent, 0.59 kg, 3.77 percent, 6.67 kg, and 0.15 BCS; 15.6 kg, 17.4 kg, 15.2 mg dl-1, 0.73 kg, 4.3 percent, 0.57 kg, 3.71 percent, 1.33 kg and 0.04 BCS; 17.2 kg, 17.9 kg, 15.2 mg dl-1, 0.74 kg, 4.36 percent, 0.63 kg, 3.71 percent, 0.33 kg and 0.08 BCS; 15.6 kg, 16.4 kg, 15.5 mg dl-1, 0.67 kg, 4.33 percent, 0.60 kg, 3.83 percent, -1.46 kg and 0.11 BCS; and 15.0 kg, 16.0 kg, 15.5 mg dl-1, 0.67 kg, 4.57 percent, 0.57 kg, 3.85 percent, 8.86 kg, and 0.05 BCS, respectively for the cows fed 100:0, 75:25, 50:50, 25:75 and 0:100 maize to barley ratio concentrate. According to these results, barley can replace maize without significantly affecting the milk production or milk composition. None of the cows presented any visible symptoms of acidosis. As it was clear from the results in the first study that maize could replace barley the aim of study 2A was therefore focused on determining the effect of feeding different levels of such a barley-based (2.4, 4.8 or 7.2 kg cow-1day-1) concentrate, on milk production, milk composition and live weight change of Jersey cows on kikuyu/ryegrass pasture (23.1 ± 2.95 percent DM, 11.1 ± 0.11 percent CP, 60.8 ± 0.58 percent NDF). Forty-five Jersey cows (early- to mid lactation), were randomly allocated to one of three treatments (n = 15) involving different levels of concentrate (12 MJ ME and 130g CP kg-1 DM) feeding for a period of 42 days (14-day adaptation and 28-day measurement). Milk weights were also recorded daily, and milk samples collected weekly, and analyzed for milk fat and protein. Body condition score and live weight were recorded at the start and end of the experimental period. The results of this study indicated that increasing the concentrate level from 2.4 to 4.8 and 7.2kg cow-1day-1 did not increase the milk yield (14.0 kg, 15.2 kg, 14.4 kg; P = 0.19). The FCM production increased from 15.8 to 17.5kg (P = 0.04) as the concentrate level increased from 2.4 to 4.8kg cow-1day-1. Increasing the concentrate from 4.8 to 7.2kg cow-1day-1 did not result in a significant increase in FCM. The milk protein percent increased significantly from 3.4 - 3.6 percent when the concentrate feeding level was increased from 2.4 to 7.2kg cow-1day-1. The MUN levels were 17.09 mg dl-1, 16.03 5 mg dl-1, and 16.36 mg dl-1 for the 2.4, 4.8 and 7.2kg cow-1day-1 concentrate levels, respectively. This is well within the recommended MUN levels (12 – 18 mg dl-1) indicating that sufficient protein was fed to cows. Increasing the concentrate level from 4.8 to 7.2 kg cow-1day-1 did not increase production, probably due to a higher pasture substitution rate. Supplementing large quantities of rapidly fermentable grains, such as barley, can suppress rumen pH and may have a negative effect on the rate and extent of fibre digestion in the rumen. Therefore the aim of study 2B was not only to determine the effect of feeding different levels of a barley-based concentrate, on milk production, milk composition and live weight change, but was also to determine the effect of a low (4.8 kg cow-1day-1) versus a high (7.2 kg cow-1day-1) level of barley-based concentrate supplementation on ruminal DM and NDF degradability of Westerworld ryegrass sampled from the pastures that these cows were grazing on. Sixty Jersey cows (early- to mid lactation), were randomly allocated to one of three treatments (n = 20) involving different levels of concentrate feeding. Concentrate (12 MJ ME, 130g CP kg-1 DM) was fed at 2.4, 4.8 or 7.2 kg cow-1day-1 for a period of 74 days (14-day adaptation and 60-day measurement). These cows stripgrazed irrigated kikuyu/ryegrass pastures (14.7 ± 4.37 percent DM, 25.1 ± 1.53 percent CP, and 44.4 ± 2.58 percent NDF) at a daily pasture allocation of 10 kg DM cow-1. Milk weights were recorded daily and milk samples collected weekly and analyzed for milk fat and protein. Body condition score and live weight were recorded at the start and end of the experimental period. Twelve Jersey cows, fitted with ruminal cannulae, were randomly allocated to two of the three treatments in the production study and received either 2.4 or 7.2 kg cow-1 day-1, of the same barley-based concentrate, in a two-period crossover design. These cows strip-grazed the same irrigated kikuyu/ryegrass pastures as the sixty cows in the production study. Each period consisted of 21 days for adaptation and seven days for data collection. Rumen liquor samples were collected every 4 hours within a 24-hour cycle and repeated once. Rumen pH was measured immediately, recorded, and the supernatant fluid preserved and frozen, pending VFA analysis. The in situ nylon bag technique was used to determine DM and NDF degradation and dried samples of Westerworld ryegrass pasture were incubated for 0, 4, 8, 12, 20, 30, 48, 72 and 96 hours. The data were fitted in the non-linear model p = a + b (1-exp-ct) (Ørskov & McDonald, 1979). Daily milk production, fat corrected milk, milk fat yield and milk fat percent were not affected by treatment and values were 17.3 kg, 18.4 kg, 0.76 kg and 4.42 percent; 19.0 kg, 20.0 kg, 0.82 kg and 4.35 percent; and 18.1 kg, 19.1 kg, 0.79 kg and 4.37 percent for the 2.4, 4.8 and 7.2 kg cow-1 day-1 concentrate treatments, respectively. Milk protein percentage of cows on the 7.2 kg concentrate cow-1 day-1 was significantly higher than that of cows on 4.2 kg concentrate cow-1 day-1 feeding level. Live weight increased significantly as the level of concentrate feeding increased and values were 17.9 kg; and 28.9 kg on the 2.4 and 7.2kg concentrate treatment, respectively. There was a significant increase in the live weight of cows that were fed 7.2 kg cow-1 day-1 (as-is) in comparison to those cows that were fed 2.4 kg concentrate cow-1 day-1 (as-is). This may have resulted from more nutrients being partitioned to live weight gain rather than milk production. No further response in milk production was observed when concentrate daily feeding was increased from 4.8 to 7.2 kg cow-1 day-1. It is postulated that the higher concentrate allowance resulted in a higher substitution rate and lower DMI intake from pasture. 6 There was no significant decline in the rumen pH (6.2 ± 0.4 and 6.2 ± 0.5) when the concentrate level was increased from 2.4 to 7.2 kg cow-1 day-1 (as-is). The total VFA (118.1 ± 45.9 and 139.4 ± 45.6 mmol L-1) and isovalerate (0.009 ± 0.07 and 0.248 ± 0.52 mmol L-1) increased significantly when the concentrate was increased from 2.4 to 7.2 kg cow-1day-1. No other rumen parameters were affected by treatment. Ruminal DM and NDF degradability of the Kikuyu/ryegrass pature were not affected by the level of concentrate supplementation. An increase in the concentrate level from 2.4 to 7.2 kg cow-1day-1 did not reduce degradability of either DM (94.67 ± 5.97, 94.49 ± 5.09; P = 0.919) or NDF (92.15 ± 8.69, 94.4 ± 11.73; P = 0.451), respectively. Results of rumen parameters and PD values were within the range reported by Bargo et al., (2003), viz. pH 5.76 – 6.29, NH3-N concentration 8.7 – 32.2 mg dl-1, total VFA concentration 90.3 - 151.4 mmol L-1 and PD values 89.5 – 93.5 % reported by Bargo et al. (2003). According to these authors, there is no simple relationship between any amount of the concentrate supplemented, and the ruminal pH and concentrate feeding only affects the in situ ruminal digestion of pasture when it is fed, at quantities higher than 8 kg DM cow-1day-1 (Bargo et al., 2003).
- Full Text:
- Date Issued: 2004
The effect of ozone on the production of broiler
- Authors: Amwele, Hilma Rantilla
- Date: 2004
- Subjects: Broilers (Chickens) , Ozone
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10585 , http://hdl.handle.net/10948/226 , Broilers (Chickens) , Ozone
- Description: The aim of the study was to evaluate the effect of ozone (O3) on mature body weight (MBW), feed conversion rate (FCR), mortality rate (MR) and ammonia (NH3) production of broiler chickens (referred to as “broilers” in this thesis) under controlled conditions. Ozone was used for the purifying of air and water in order to eliminate harmful microorganisms. Two trials were conducted over a twelve week production period. In experiment 1, day old broiler chicks were randomly allocated to a control (n=130) and treatment (n=130) group. The treatment groups were exposed to ozone continuously for the entire period of the trial. Both air and water were ozonated on a 24 hours daily basis, while the control group was reared under normal commercial conditions. In experiment 2: day old broiler chicks were randomly allocated to a control (n=123) and a treatment (n=123) group. The treatment group was exposed to ozone for 3 hours per day for the entire period of the trial. Both air and water were ozonated, where the air was treated for 3 hours/day and the water for 1 hour/day during the entire production period. The control group was reared under normal commercial conditions. The results indicate that broilers exposed to continuous O3 (0.1 ppm) conditions had significantly higher (P< 0.001) mortality rates than the control group. The treatment group had a mortality rate of 55.38% compared to the 5.38% for the control group. No significant difference (P= 0. 2468) for MBW was found between the broilers that were reared in the O3 environment compared to the control iii group. Although the control group were on average 200g heavier at the end of the trial. No significant difference (p = 0. 6143) was recorded in FCR between the O3 and control groups. However the FCR of the broilers treated with O3 was lower by 100g than that of the control group. The O3 significantly (P< 0. 0001) reduced the NH3 in the treatment group. When the trial was repeated with limited exposure to an O3 environment there was no significant difference in MBW (P = 0. 0979), FCR (P = 0. 8913) and MR (P = 0. 1108) between the treatment and control groups. However, ammonia levels were lower in the treatment group compared to the control group. When the data was further analyzed comparing the two trials, the results indicated that there was no significant difference (P = 0. 4112) in the MBW for the broilers reared under normal conditions (control group) from experiment 1 and experiment 2, while a significant difference (P = 0. 0002) was recorded between the broilers reared under continuous O3 and regulated O3 conditions from experiment 1 and experiment 2 respectively. When the FCR data was analyzed using the Gompertz equation a significant difference (P = 0.0403) in the FCR of broilers reared in the control group between experiment 1 and experiment 2 was recorded (Table 8). No significant difference (P = 0.3226) in the FCR of broilers raised under O3 conditions of continuous and regulated O3 production were reported between experiment 1 and experiment 2. A highly significant difference (P = 0. 0001) in the MR of broilers reared under ozone conditions was recorded between experiment 1 and experiment 2. In experiment 1, the MR was 55.38% while in experiment 2 the MR was only 8.78%. A significant difference (P = 0.0355) was also recorded in the MR of broilers that iv were raised in the control groups between experiment 1 and experiment 2. The MR for broilers in the control group was 5.38% in experiment 1 and for experiment 2 it was 9.74%. The mortality rate of broilers raised in the control groups conditions increased by approximately 4% points or 81% between experiment 1 and experiment 2. The level (0.1 ppm) of ozone production had a limited effect on the MBW and FCR of broilers, however it is evident that ozone is toxic to broilers when they are exposed to a continuous ozonated environment. Ozone was however effective in controlling ammonia levels.
- Full Text:
- Date Issued: 2004
- Authors: Amwele, Hilma Rantilla
- Date: 2004
- Subjects: Broilers (Chickens) , Ozone
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10585 , http://hdl.handle.net/10948/226 , Broilers (Chickens) , Ozone
- Description: The aim of the study was to evaluate the effect of ozone (O3) on mature body weight (MBW), feed conversion rate (FCR), mortality rate (MR) and ammonia (NH3) production of broiler chickens (referred to as “broilers” in this thesis) under controlled conditions. Ozone was used for the purifying of air and water in order to eliminate harmful microorganisms. Two trials were conducted over a twelve week production period. In experiment 1, day old broiler chicks were randomly allocated to a control (n=130) and treatment (n=130) group. The treatment groups were exposed to ozone continuously for the entire period of the trial. Both air and water were ozonated on a 24 hours daily basis, while the control group was reared under normal commercial conditions. In experiment 2: day old broiler chicks were randomly allocated to a control (n=123) and a treatment (n=123) group. The treatment group was exposed to ozone for 3 hours per day for the entire period of the trial. Both air and water were ozonated, where the air was treated for 3 hours/day and the water for 1 hour/day during the entire production period. The control group was reared under normal commercial conditions. The results indicate that broilers exposed to continuous O3 (0.1 ppm) conditions had significantly higher (P< 0.001) mortality rates than the control group. The treatment group had a mortality rate of 55.38% compared to the 5.38% for the control group. No significant difference (P= 0. 2468) for MBW was found between the broilers that were reared in the O3 environment compared to the control iii group. Although the control group were on average 200g heavier at the end of the trial. No significant difference (p = 0. 6143) was recorded in FCR between the O3 and control groups. However the FCR of the broilers treated with O3 was lower by 100g than that of the control group. The O3 significantly (P< 0. 0001) reduced the NH3 in the treatment group. When the trial was repeated with limited exposure to an O3 environment there was no significant difference in MBW (P = 0. 0979), FCR (P = 0. 8913) and MR (P = 0. 1108) between the treatment and control groups. However, ammonia levels were lower in the treatment group compared to the control group. When the data was further analyzed comparing the two trials, the results indicated that there was no significant difference (P = 0. 4112) in the MBW for the broilers reared under normal conditions (control group) from experiment 1 and experiment 2, while a significant difference (P = 0. 0002) was recorded between the broilers reared under continuous O3 and regulated O3 conditions from experiment 1 and experiment 2 respectively. When the FCR data was analyzed using the Gompertz equation a significant difference (P = 0.0403) in the FCR of broilers reared in the control group between experiment 1 and experiment 2 was recorded (Table 8). No significant difference (P = 0.3226) in the FCR of broilers raised under O3 conditions of continuous and regulated O3 production were reported between experiment 1 and experiment 2. A highly significant difference (P = 0. 0001) in the MR of broilers reared under ozone conditions was recorded between experiment 1 and experiment 2. In experiment 1, the MR was 55.38% while in experiment 2 the MR was only 8.78%. A significant difference (P = 0.0355) was also recorded in the MR of broilers that iv were raised in the control groups between experiment 1 and experiment 2. The MR for broilers in the control group was 5.38% in experiment 1 and for experiment 2 it was 9.74%. The mortality rate of broilers raised in the control groups conditions increased by approximately 4% points or 81% between experiment 1 and experiment 2. The level (0.1 ppm) of ozone production had a limited effect on the MBW and FCR of broilers, however it is evident that ozone is toxic to broilers when they are exposed to a continuous ozonated environment. Ozone was however effective in controlling ammonia levels.
- Full Text:
- Date Issued: 2004
Socio-economic, cultural and policy issues impacting on community forestry development : a case study of Hlabisa district in Kwazulu-Natal
- Authors: Masuku, Sipho Sikhumbuzo
- Date: 2005
- Subjects: Forests and forestry -- South Africa -- KwaZulu-Natal , Forests and forestry -- Economic aspects -- South Africa -- KwaZulu-Natal , Forests and forestry -- Social aspect -- South Africa -- KwaZulu-Natal , Forests and forestry -- Cultural aspect -- South Africa -- KwaZulu-Natal
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10743 , http://hdl.handle.net/10948/818 , Forests and forestry -- South Africa -- KwaZulu-Natal , Forests and forestry -- Economic aspects -- South Africa -- KwaZulu-Natal , Forests and forestry -- Social aspect -- South Africa -- KwaZulu-Natal , Forests and forestry -- Cultural aspect -- South Africa -- KwaZulu-Natal
- Description: South Africa is not well-endowed with indigenous forests and those that remain are known to be degraded and declining at an alarming rate. This constitutes a direct threat to the quality of life of the resource-poor rural households which are directly dependent on the resources indigenous forests offer, as well as to ecological integrity. It is also recognised that the declining tree resources, particularly the indigenous tree species of high value, are increasingly threatened by a number of growing subsistence demands. This emphasises the need to establish, cultivate and conserve high-value tree species. Community forestry is recognised as a viable option for optimising land productivity; reducing pressure on indigenous forests and woodlands; ensuring a sustainable supply of desired tree products and services; and improving the quality of life of the resource-poor rural households. The primary purpose of Community Forestry Development (CFD) in the Hlabisa District is the provision of an information service and of technical support to enhance the livelihoods of rural communities by means of tree-related resources. Community forestry mainly focuses on tree resources that form an integral part of or contribute to rural people’s livelihoods. This includes small-scale growers (woodlots), woodlands and indigenous forests. Community forestry can be defined as tree growing and managed by the people for the people. Community forestry encompasses a wide range of activities which include farm forestry, agroforestry, village planting, woodlots, woodland management and indigenous-forest management by rural people, as well as tree planting in urban and peri-urban areas. Natural forests in South Africa account for less than 1 percent of the total land area. It has been suggested that these natural forests will no longer be able to meet the demand for forest products by 2020. The KwaZulu Department of Agriculture and Forestry embarked on community forestry in 1976 (but only on an ad hoc basis) as a possible solution to this dilemma. Later, the two South African pulp and paper giants, SAPPI and Mondi, started the Project Grow and Khulanathi Schemes respectively. One of the objectives of out-grower schemes was to encourage rural communities to plant trees on their own lands for the economic, social and environmental benefits trees offer. For example, timber could be sold to forestry companies. Financial assistance was offered to these communities to encourage implementation of such schemes. This exercise was aimed at bringing economic activity, capacity- building and community empowerment to the rural areas. The growers would benefit from the financial assistance and the readily available market provided by the company, while the company would be able to satisfy its demand for timber.
- Full Text:
- Date Issued: 2005
- Authors: Masuku, Sipho Sikhumbuzo
- Date: 2005
- Subjects: Forests and forestry -- South Africa -- KwaZulu-Natal , Forests and forestry -- Economic aspects -- South Africa -- KwaZulu-Natal , Forests and forestry -- Social aspect -- South Africa -- KwaZulu-Natal , Forests and forestry -- Cultural aspect -- South Africa -- KwaZulu-Natal
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10743 , http://hdl.handle.net/10948/818 , Forests and forestry -- South Africa -- KwaZulu-Natal , Forests and forestry -- Economic aspects -- South Africa -- KwaZulu-Natal , Forests and forestry -- Social aspect -- South Africa -- KwaZulu-Natal , Forests and forestry -- Cultural aspect -- South Africa -- KwaZulu-Natal
- Description: South Africa is not well-endowed with indigenous forests and those that remain are known to be degraded and declining at an alarming rate. This constitutes a direct threat to the quality of life of the resource-poor rural households which are directly dependent on the resources indigenous forests offer, as well as to ecological integrity. It is also recognised that the declining tree resources, particularly the indigenous tree species of high value, are increasingly threatened by a number of growing subsistence demands. This emphasises the need to establish, cultivate and conserve high-value tree species. Community forestry is recognised as a viable option for optimising land productivity; reducing pressure on indigenous forests and woodlands; ensuring a sustainable supply of desired tree products and services; and improving the quality of life of the resource-poor rural households. The primary purpose of Community Forestry Development (CFD) in the Hlabisa District is the provision of an information service and of technical support to enhance the livelihoods of rural communities by means of tree-related resources. Community forestry mainly focuses on tree resources that form an integral part of or contribute to rural people’s livelihoods. This includes small-scale growers (woodlots), woodlands and indigenous forests. Community forestry can be defined as tree growing and managed by the people for the people. Community forestry encompasses a wide range of activities which include farm forestry, agroforestry, village planting, woodlots, woodland management and indigenous-forest management by rural people, as well as tree planting in urban and peri-urban areas. Natural forests in South Africa account for less than 1 percent of the total land area. It has been suggested that these natural forests will no longer be able to meet the demand for forest products by 2020. The KwaZulu Department of Agriculture and Forestry embarked on community forestry in 1976 (but only on an ad hoc basis) as a possible solution to this dilemma. Later, the two South African pulp and paper giants, SAPPI and Mondi, started the Project Grow and Khulanathi Schemes respectively. One of the objectives of out-grower schemes was to encourage rural communities to plant trees on their own lands for the economic, social and environmental benefits trees offer. For example, timber could be sold to forestry companies. Financial assistance was offered to these communities to encourage implementation of such schemes. This exercise was aimed at bringing economic activity, capacity- building and community empowerment to the rural areas. The growers would benefit from the financial assistance and the readily available market provided by the company, while the company would be able to satisfy its demand for timber.
- Full Text:
- Date Issued: 2005
Study of the skincalm filling process at Aspen Pharmacare applying some six sigma principles
- Authors: Marx, Johannes
- Date: 2005
- Subjects: Ointments -- Packaging , Six sigma (Quality control standard)
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10369 , http://hdl.handle.net/10948/184 , Ointments -- Packaging , Six sigma (Quality control standard)
- Description: Aspen Pharmacare is listed on the Johannesburg Securities Exchange South Africa (JSE) and is Africa’s largest pharmaceutical manufacturer. The company is a major supplier of branded pharmaceutical and healthcare products to the local and selected international markets. For decades, Aspen has manufactured a basket of affordable, quality, and effective products for the ethical, generic over-the-counter (OTC) and personal care markets. Aspen is also the leading supplier of generic medicines to the public sector, providing comprehensive coverage of the products on the Essential Drug List. Aspen continues to deliver on its commitment toward playing a role in social responsibility diseases such as HIV/AIDS, tuberculosis and malaria. In August 2003 Aspen developed Africa’s first generic anti-retroviral drug, namely Aspen-Stavudine. Aspen’s manufacturing facilities are based in Port Elizabeth (PE) and East London. Aspen has recently completed an Oral Solid Dosage (OSD) manufacturing facility worth approximately R150 million in PE. The Group manufactures approximately 20 tons of product daily and in excess of 400 tons of solid dosage pharmaceuticals, which equates to more than 2 billion tablets. In addition, more than 3 million litres of liquid pharmaceuticals and over 200 tons of pharmaceutical creams and ointments are produced per year [1]. Aspen excels at delivering quality products and services, exceeding customer expectations, complying with international standards in an environment that cultivates technical expertise and innovation. Following this philosophy through to the shop floor areas mean that there are always initiatives in continuous production improvement. One of these improvement projects introduced is called Six Sigma. 8 Ten members of the staff, selected from different expertise fields in the company were trained in Six Sigma. Knowledge gained from the two week training course were applied to different areas in the factory using Six Sigma principles. This dissertation focuses on the study undertaken in one of production areas, namely the filling process of the ointments and creams at the Aspen Port Elizabeth facility.
- Full Text:
- Date Issued: 2005
- Authors: Marx, Johannes
- Date: 2005
- Subjects: Ointments -- Packaging , Six sigma (Quality control standard)
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10369 , http://hdl.handle.net/10948/184 , Ointments -- Packaging , Six sigma (Quality control standard)
- Description: Aspen Pharmacare is listed on the Johannesburg Securities Exchange South Africa (JSE) and is Africa’s largest pharmaceutical manufacturer. The company is a major supplier of branded pharmaceutical and healthcare products to the local and selected international markets. For decades, Aspen has manufactured a basket of affordable, quality, and effective products for the ethical, generic over-the-counter (OTC) and personal care markets. Aspen is also the leading supplier of generic medicines to the public sector, providing comprehensive coverage of the products on the Essential Drug List. Aspen continues to deliver on its commitment toward playing a role in social responsibility diseases such as HIV/AIDS, tuberculosis and malaria. In August 2003 Aspen developed Africa’s first generic anti-retroviral drug, namely Aspen-Stavudine. Aspen’s manufacturing facilities are based in Port Elizabeth (PE) and East London. Aspen has recently completed an Oral Solid Dosage (OSD) manufacturing facility worth approximately R150 million in PE. The Group manufactures approximately 20 tons of product daily and in excess of 400 tons of solid dosage pharmaceuticals, which equates to more than 2 billion tablets. In addition, more than 3 million litres of liquid pharmaceuticals and over 200 tons of pharmaceutical creams and ointments are produced per year [1]. Aspen excels at delivering quality products and services, exceeding customer expectations, complying with international standards in an environment that cultivates technical expertise and innovation. Following this philosophy through to the shop floor areas mean that there are always initiatives in continuous production improvement. One of these improvement projects introduced is called Six Sigma. 8 Ten members of the staff, selected from different expertise fields in the company were trained in Six Sigma. Knowledge gained from the two week training course were applied to different areas in the factory using Six Sigma principles. This dissertation focuses on the study undertaken in one of production areas, namely the filling process of the ointments and creams at the Aspen Port Elizabeth facility.
- Full Text:
- Date Issued: 2005
Factors influencing species richness, cover and composition of vegetation on Namaqualand quartz fields
- Authors: Van Tonder, Carlo
- Date: 2006
- Subjects: Plant diversity -- South Africa -- Namaqualand , Soil biology -- South Africa -- Namaqualand
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10752 , http://hdl.handle.net/10948/630 , Plant diversity -- South Africa -- Namaqualand , Soil biology -- South Africa -- Namaqualand
- Description: Quartz fields contribute significantly to plant diversity in the Succulent Karoo biome. They are distinctly different from surrounding habitats and have high levels of plant endemism. Biological soil crusts are features of quartz field soils and fulfill a vital function in that they stabilize soils. It is important for managers of nature reserves and agricultural rangelands to know what factors influence quartz field soils and vegetation. Both stakeholders could benefit from new information that would allow for informed decision-making regarding land-use on quartz fields. The present study took place in the Namaqua National Park that contains a significant proportion of the Riethuis-Wallekraal quartz fields phytochorion. The first part of the study aimed to understand whether certain land-use activities potentially destabilize quartz field soils, which might have possible ramifications for associated biological soil crusts and vegetation. It was followed by relating variation in soil stability with species richness, cover and species composition of quartz field vegetation. Overall, positions assumed to be impacted by land-use activities had less stable soils compared to positions assumed not be impacted. Soil stability had a significant influence on species richness and cover but to a lesser degree on species composition. Quartz field vegetation was significantly influenced by soil physical and chemical properties as well as location in the quartz fields landscape. The second part of the study aimed at understanding how species richness of isolated quartz outcrops is related to their size compared to that of a mainland body of quartz outcrops. No clear species-area relationships emerged from the study. There were significant differences between isolated outcrops and mainland outcrops in substrate and vegetation composition. Findings are discussed in relation to Island Biogeography Theory.
- Full Text:
- Date Issued: 2006
- Authors: Van Tonder, Carlo
- Date: 2006
- Subjects: Plant diversity -- South Africa -- Namaqualand , Soil biology -- South Africa -- Namaqualand
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10752 , http://hdl.handle.net/10948/630 , Plant diversity -- South Africa -- Namaqualand , Soil biology -- South Africa -- Namaqualand
- Description: Quartz fields contribute significantly to plant diversity in the Succulent Karoo biome. They are distinctly different from surrounding habitats and have high levels of plant endemism. Biological soil crusts are features of quartz field soils and fulfill a vital function in that they stabilize soils. It is important for managers of nature reserves and agricultural rangelands to know what factors influence quartz field soils and vegetation. Both stakeholders could benefit from new information that would allow for informed decision-making regarding land-use on quartz fields. The present study took place in the Namaqua National Park that contains a significant proportion of the Riethuis-Wallekraal quartz fields phytochorion. The first part of the study aimed to understand whether certain land-use activities potentially destabilize quartz field soils, which might have possible ramifications for associated biological soil crusts and vegetation. It was followed by relating variation in soil stability with species richness, cover and species composition of quartz field vegetation. Overall, positions assumed to be impacted by land-use activities had less stable soils compared to positions assumed not be impacted. Soil stability had a significant influence on species richness and cover but to a lesser degree on species composition. Quartz field vegetation was significantly influenced by soil physical and chemical properties as well as location in the quartz fields landscape. The second part of the study aimed at understanding how species richness of isolated quartz outcrops is related to their size compared to that of a mainland body of quartz outcrops. No clear species-area relationships emerged from the study. There were significant differences between isolated outcrops and mainland outcrops in substrate and vegetation composition. Findings are discussed in relation to Island Biogeography Theory.
- Full Text:
- Date Issued: 2006
The effect of different slaughter age regimes on the primary and secondary production parameters of Ostriches (Struthio Camelus Domesticus) and the economic consequences of different slaughter ages
- Authors: Bhiya, Clovis Solomon
- Date: 2006
- Subjects: Slaughtering and slaughter-houses -- South Africa , Ostrich farming -- South Africa , Ostriches -- Breeding -- South Africa
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10735 , http://hdl.handle.net/10948/837 , Slaughtering and slaughter-houses -- South Africa , Ostrich farming -- South Africa , Ostriches -- Breeding -- South Africa
- Description: The South African ostrich industry is presently characterised by a drastic decline in the slaughter price of slaughter birds, due to the drop in the price of meat as well as leather. As a result, the economic viability of ostrich farming is severely hampered by these developments, and many generally accepted industry practices have to be reviewed. Among the practices under review is the possibility of slaughtering ostriches at an earlier age than the traditional slaughter age of 12 - 14 months, in order to minimise feed costs and the incidence of damage to the skin. However, little information is available on the effect of the slaughter age on the yield and quality of the economically important end-products. The effect of slaughter age on production and the economic viability of a commercially intensive ostrich production system was consequently evaluated in a completely randomised experimental design involving two batches (n= 81 and n= 94) of ostriches. The experiments took place at Kromme Rhee experimental farm of the Elsenburg Research Centre near Stellenbosch. The birds were subject to experimental treatment at the age of 4 months (n= 81, from May 2004 to March 2005) and 6 months (n= 94, from August 2004 to August 2005) respectively. The ostriches were randomly divided into 10 groups of between 16 and 20 birds per group. Standard production practices, as applied in an intensive ostrich production unit, were implemented. Clean drinking water and self-mixed grower diet (min 15 percent crude protein, 0.68 percent lysine and 11.4 MJ ME per kg feed) and finisher diet (min 14 percent crude protein, 0.55 percent lysine and 9.8 MJ ME per kg feed) were provided ad libitum to the birds. Birds were slaughtered at the ages of 8.5, 10.5, 12.5, 14.5, and 16.5 months respectively. Data on feed intake and yields of cold carcass, crust skin size, skin grade and total feathers was recorded for birds slaughtered at the respective ages. Data was analysed according to the analysis of variances. Values for meat yield, skin size yield and feed intake were predicted by regression analysis based on experimental values. Industry figures and norms were used as proxy for other production inputs and costs. A gross margin type analysis was performed to evaluate the effect of different slaughter ages on the profitability of each production system. There was a positive correlation between age and feed intake (r2= 0.40), slaughter weight (r2= 0.97), cold carcass yield (r2= 0.48), skin surface area (r2= 0.39), skin grade (r2= 0.19) and total yield of feathers (r2= 0.29). The dry skin grade showed deterioration as slaughter age was prolonged. Highly significant differences (P< 0.01) in slaughter weight, cold carcass yield, skin surface area, dry skin grade and total feathers were detected at the different slaughter ages. There were no significant differences (P> 0.05) with respect to gender for slaughter weight, skin surface area and dry skin grade within the different age groups. Males had significantly higher (P< 0.05) cold carcass yield and total feather yield than their female counterparts. From this study it can be concluded that an increase in slaughter age significantly increases feed intake, slaughter weight, cold carcass yield, and skin surface area. It is also clear that an increase in slaughter age can be detrimental to dry skin grade. The relative income contribution of the three main products (skin: meat: feathers) occurred in a ratio of 47:53:0, 52:47:1, 47:50:3, 44:51:5, 39:56:5 at the respective slaughter ages. Total income revealed an increase of 26 percent from 8.5 to 10.5 months slaughtering, an increase of 4 percent between 10.5 and 12.5 months, and an increase of 11 percent between 12.5 and 14.5 months. The income dropped by 0.3 percent between 14.5 and 16.5 months slaughtering. Total costs increased with slaughter age, particularly feed costs which showed an increase (at a decreasing rate) between the different slaughter ages. The margin above specified cost per bird was the highest for birds slaughtered at the age of 10.5 months. The margin above cost showed a steady decline as birds were slaughtered at higher ages. Slaughtering at 16.5 months revealed a negative margin. To compare the effect of differences in time span on different slaughter age regimes, margin above costs for each system over 5 years were discounted to a present value. In this study, with current feed costs and income from end products, slaughtering at 10.5 months revealed the highest present value for the margin above cost. Furthermore, slaughtering at 16.5 months revealed a negative present value on the margin above cost after 5 years. Financial viability calculations are relevant and valid for data obtained in this case study. Financial viability is however case-specific and may vary between producers, depending on their individual management practices, production systems and cost structures. Results from this study may be of significant value to managerial decision-making in the ostrich industry.
- Full Text:
- Date Issued: 2006
- Authors: Bhiya, Clovis Solomon
- Date: 2006
- Subjects: Slaughtering and slaughter-houses -- South Africa , Ostrich farming -- South Africa , Ostriches -- Breeding -- South Africa
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10735 , http://hdl.handle.net/10948/837 , Slaughtering and slaughter-houses -- South Africa , Ostrich farming -- South Africa , Ostriches -- Breeding -- South Africa
- Description: The South African ostrich industry is presently characterised by a drastic decline in the slaughter price of slaughter birds, due to the drop in the price of meat as well as leather. As a result, the economic viability of ostrich farming is severely hampered by these developments, and many generally accepted industry practices have to be reviewed. Among the practices under review is the possibility of slaughtering ostriches at an earlier age than the traditional slaughter age of 12 - 14 months, in order to minimise feed costs and the incidence of damage to the skin. However, little information is available on the effect of the slaughter age on the yield and quality of the economically important end-products. The effect of slaughter age on production and the economic viability of a commercially intensive ostrich production system was consequently evaluated in a completely randomised experimental design involving two batches (n= 81 and n= 94) of ostriches. The experiments took place at Kromme Rhee experimental farm of the Elsenburg Research Centre near Stellenbosch. The birds were subject to experimental treatment at the age of 4 months (n= 81, from May 2004 to March 2005) and 6 months (n= 94, from August 2004 to August 2005) respectively. The ostriches were randomly divided into 10 groups of between 16 and 20 birds per group. Standard production practices, as applied in an intensive ostrich production unit, were implemented. Clean drinking water and self-mixed grower diet (min 15 percent crude protein, 0.68 percent lysine and 11.4 MJ ME per kg feed) and finisher diet (min 14 percent crude protein, 0.55 percent lysine and 9.8 MJ ME per kg feed) were provided ad libitum to the birds. Birds were slaughtered at the ages of 8.5, 10.5, 12.5, 14.5, and 16.5 months respectively. Data on feed intake and yields of cold carcass, crust skin size, skin grade and total feathers was recorded for birds slaughtered at the respective ages. Data was analysed according to the analysis of variances. Values for meat yield, skin size yield and feed intake were predicted by regression analysis based on experimental values. Industry figures and norms were used as proxy for other production inputs and costs. A gross margin type analysis was performed to evaluate the effect of different slaughter ages on the profitability of each production system. There was a positive correlation between age and feed intake (r2= 0.40), slaughter weight (r2= 0.97), cold carcass yield (r2= 0.48), skin surface area (r2= 0.39), skin grade (r2= 0.19) and total yield of feathers (r2= 0.29). The dry skin grade showed deterioration as slaughter age was prolonged. Highly significant differences (P< 0.01) in slaughter weight, cold carcass yield, skin surface area, dry skin grade and total feathers were detected at the different slaughter ages. There were no significant differences (P> 0.05) with respect to gender for slaughter weight, skin surface area and dry skin grade within the different age groups. Males had significantly higher (P< 0.05) cold carcass yield and total feather yield than their female counterparts. From this study it can be concluded that an increase in slaughter age significantly increases feed intake, slaughter weight, cold carcass yield, and skin surface area. It is also clear that an increase in slaughter age can be detrimental to dry skin grade. The relative income contribution of the three main products (skin: meat: feathers) occurred in a ratio of 47:53:0, 52:47:1, 47:50:3, 44:51:5, 39:56:5 at the respective slaughter ages. Total income revealed an increase of 26 percent from 8.5 to 10.5 months slaughtering, an increase of 4 percent between 10.5 and 12.5 months, and an increase of 11 percent between 12.5 and 14.5 months. The income dropped by 0.3 percent between 14.5 and 16.5 months slaughtering. Total costs increased with slaughter age, particularly feed costs which showed an increase (at a decreasing rate) between the different slaughter ages. The margin above specified cost per bird was the highest for birds slaughtered at the age of 10.5 months. The margin above cost showed a steady decline as birds were slaughtered at higher ages. Slaughtering at 16.5 months revealed a negative margin. To compare the effect of differences in time span on different slaughter age regimes, margin above costs for each system over 5 years were discounted to a present value. In this study, with current feed costs and income from end products, slaughtering at 10.5 months revealed the highest present value for the margin above cost. Furthermore, slaughtering at 16.5 months revealed a negative present value on the margin above cost after 5 years. Financial viability calculations are relevant and valid for data obtained in this case study. Financial viability is however case-specific and may vary between producers, depending on their individual management practices, production systems and cost structures. Results from this study may be of significant value to managerial decision-making in the ostrich industry.
- Full Text:
- Date Issued: 2006
Volhoubaarheid van die kommersiële benutting van inheemse dekriet (Thamnochortus insignis) in die Suid-Kaap
- Authors: Horn, Johan Andries Muller
- Date: 2006
- Subjects: Fynbos -- Harvesting -- South Africa , Thatched roofs -- South Africa
- Language: Afrikaans
- Type: Thesis , Masters , MTech
- Identifier: vital:10591 , http://hdl.handle.net/10948/836 , http://hdl.handle.net/10948/d1012882 , Fynbos -- Harvesting -- South Africa , Thatched roofs -- South Africa
- Description: Thamnochortus insignis (Albertinia thatching reed) is a restio specie which is endemic in the narrow (20 km wide) coastal dune veld, from the Gouritz River in the east to the Breede River in the west (120 km). The area within this belt, where this reed is the dominant restio, covers 65 500 hectares. The culms of the reed is harvested as a natural product from the veld and used as thatch on roofs of houses. The traditional use has been as roofing material in Cape Dutch architecture. At this time, thatch roofs are regarded as a luxury commodity and are used in prestigious residential areas and also eco-friendly housing developments. The first section of the research project was based on a Delphi technique questionnaire completed first by 37 and secondly by 10 stakeholders in the industry. This group of growers, contract harvesters, crop agents and thatchers represented 80 percent percent of the estimated 2005 harvest and 87 percent of the estimated farm gate crop value. The thatching reed industry is the main agricultural enterprise situated in the coastal dune veld of the Southern Cape, i.e. 55 percent of total Gross Product Value generated by the survey respondents. The second section is based on an analysis of experimental harvest plots (50 m2), selected at random (4 replications per site) in the 2 x 3 different production systems, i.e. traditional harvest from natural veld, harvest from veld which had been subjected to mechanical injury ("sleep") and harvest from established orchard-type lands. Harvest data was collected at each site in terms of the following components, i.e. number of harvestable tussocks, circumference of tussocks and number of reed bundles (minimum circumference 210 mm, minimum length 1,2 m). The gross income per site was calculated on the basis of R1,80 per bundle (2006-price level). Economic analysis (Gross Margin above selected costs) indicates that plant density (reed tussocks/ha) is a critical factor, in order to offset the establishment cost of R2 100/ha in established lands, which is not incurred in the other two production systems. Economic returns from the first planted lands (2 100 and 2 900 plants/ha) averaged R7 666/ha against R8 781/ha for the mechanical-injury plants. However, at a density of 5 000 plants/ha, the projected Gross Margin increases to R15 765/ha. The use of mechanicalinjury and natural vegetation production systems both interfere with biodiversity and raise major concerns with regard to sustainability of the sensitive coastal dune fynbos. ANOVA-analysis of the data indicates a highly significant difference (p = 0,01) for all sites and production systems. Statistical analysis of averages indicates that mechanical injury treatment results in a significant increase in the number of tussocks, when compared to established and natural veld, respectively. The variance in the circumference of tussocks was greatest in natural veld (55 to 71 percent) and mechanical injury (54 to 61 percent). Tussocks harvested from established plantings reflected the least level of variance (28 to 38 percent). The larger reed tussocks in the established lands produced more bundles of marketable reed (8 200/ha) than the mechanical-injury (7 625/ha) and natural veld (3 450/ha) respectively. Establishment of T. insignis plantlets in an "orchard" system at spacings of 2 m x 1 m on previous winter cereal lands or old pastures, is shown to meet all the requirements within a sustainable production system, i.e. viability, productivity, environmental-friendly, risk management and social acceptance. Furthermore, the quality of the yield was in line with the proposed grading standard for thatching reed, i.e. minimum circumference 210 mm, minimum length 1,2 m and less than 6,5 percent grey culm content.
- Full Text:
- Date Issued: 2006
- Authors: Horn, Johan Andries Muller
- Date: 2006
- Subjects: Fynbos -- Harvesting -- South Africa , Thatched roofs -- South Africa
- Language: Afrikaans
- Type: Thesis , Masters , MTech
- Identifier: vital:10591 , http://hdl.handle.net/10948/836 , http://hdl.handle.net/10948/d1012882 , Fynbos -- Harvesting -- South Africa , Thatched roofs -- South Africa
- Description: Thamnochortus insignis (Albertinia thatching reed) is a restio specie which is endemic in the narrow (20 km wide) coastal dune veld, from the Gouritz River in the east to the Breede River in the west (120 km). The area within this belt, where this reed is the dominant restio, covers 65 500 hectares. The culms of the reed is harvested as a natural product from the veld and used as thatch on roofs of houses. The traditional use has been as roofing material in Cape Dutch architecture. At this time, thatch roofs are regarded as a luxury commodity and are used in prestigious residential areas and also eco-friendly housing developments. The first section of the research project was based on a Delphi technique questionnaire completed first by 37 and secondly by 10 stakeholders in the industry. This group of growers, contract harvesters, crop agents and thatchers represented 80 percent percent of the estimated 2005 harvest and 87 percent of the estimated farm gate crop value. The thatching reed industry is the main agricultural enterprise situated in the coastal dune veld of the Southern Cape, i.e. 55 percent of total Gross Product Value generated by the survey respondents. The second section is based on an analysis of experimental harvest plots (50 m2), selected at random (4 replications per site) in the 2 x 3 different production systems, i.e. traditional harvest from natural veld, harvest from veld which had been subjected to mechanical injury ("sleep") and harvest from established orchard-type lands. Harvest data was collected at each site in terms of the following components, i.e. number of harvestable tussocks, circumference of tussocks and number of reed bundles (minimum circumference 210 mm, minimum length 1,2 m). The gross income per site was calculated on the basis of R1,80 per bundle (2006-price level). Economic analysis (Gross Margin above selected costs) indicates that plant density (reed tussocks/ha) is a critical factor, in order to offset the establishment cost of R2 100/ha in established lands, which is not incurred in the other two production systems. Economic returns from the first planted lands (2 100 and 2 900 plants/ha) averaged R7 666/ha against R8 781/ha for the mechanical-injury plants. However, at a density of 5 000 plants/ha, the projected Gross Margin increases to R15 765/ha. The use of mechanicalinjury and natural vegetation production systems both interfere with biodiversity and raise major concerns with regard to sustainability of the sensitive coastal dune fynbos. ANOVA-analysis of the data indicates a highly significant difference (p = 0,01) for all sites and production systems. Statistical analysis of averages indicates that mechanical injury treatment results in a significant increase in the number of tussocks, when compared to established and natural veld, respectively. The variance in the circumference of tussocks was greatest in natural veld (55 to 71 percent) and mechanical injury (54 to 61 percent). Tussocks harvested from established plantings reflected the least level of variance (28 to 38 percent). The larger reed tussocks in the established lands produced more bundles of marketable reed (8 200/ha) than the mechanical-injury (7 625/ha) and natural veld (3 450/ha) respectively. Establishment of T. insignis plantlets in an "orchard" system at spacings of 2 m x 1 m on previous winter cereal lands or old pastures, is shown to meet all the requirements within a sustainable production system, i.e. viability, productivity, environmental-friendly, risk management and social acceptance. Furthermore, the quality of the yield was in line with the proposed grading standard for thatching reed, i.e. minimum circumference 210 mm, minimum length 1,2 m and less than 6,5 percent grey culm content.
- Full Text:
- Date Issued: 2006
A comparison between the game and hunting industries in KwaZulu-Natal and the Eastern Cape
- Authors: Kobus, Louann
- Date: 2007
- Subjects: Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10590 , http://hdl.handle.net/10948/534 , http://hdl.handle.net/10948/d1011724 , Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Description: The objectives of this research, were to investigate the characteristics and develop a profile of the game and hunting industries of KwaZulu-Natal, and to undertake a comparison between the game and hunting industries in KwaZulu-Natal and the Eastern Cape. The comparative part of this study was completed using results obtained from a study done in 2002 in the Eastern Cape (van Niekerk, 2002). The main farming activities in KwaZulu-Natal are large livestock production and sugar cane production. In recent years, private landowners in KwaZulu-Natal have undergone a transition from livestock production to game ranching due to the problems faced and the cost implications of the HIV epidemic, stock theft, difficulties faced with changes in the labour laws and the increasing number of land claims against farmers. Although the game and hunting industries are relatively young industries in KwaZulu-Natal they contribute significantly to the economy of the province. Not only is greater conservation of the biodiversity more effective in game ranching but it is also proving to yield great economic returns. The increase in game ranching in recent years is namely due to the monetary value placed on wildlife, the increased value in ecotourism and its value as an earner of foreign exchange, less dependency on unskilled labour than that of livestock farming and lower rates of animal loss through theft compared to that of livestock farming. In KwaZulu-Natal game numbers indicate that impala have the greatest population amongst the respondents, followed by nyala, blesbok, common reedbuck, kudu and blue wildebeest, whilst other game species occur in smaller numbers. Respondents in KwaZulu-Natal indicate that nyala is the largest economic earner for them followed by buffalo, whereas in the Eastern Cape (2002), kudu and springbok provide the greatest income for the province. In KwaZulu-Natal income generated from hunting is second to that of live game sales compared to the Eastern Cape (2002) where hunting is the most important form of game utilisation in terms of income generated. At the time of this study, respondents in KwaZulu-Natal reported an income of R 15 382 397 generated from live sales and R 13 561 459 from hunting. These respondents also indicated that the total value of game utilised annually was in excess of R 30 million. Although game utilisation is occurring on a sustainable basis, there is room for greater utilisation of some game species which, if undertaken correctly, can increase the revenue for the province significantly and also contribute positively to further sustainability of the game populations. KwaZulu-Natal’s competitive advantage is derived from the fact that there is an abundance of game on the ranches, quality trophy animals are available, the number of game species available for hunting and quality of service rendered to hunters by the professional hunters and ranch owners. This study has clearly shown that there is a need for further investigation into the game and hunting industries in KwaZulu-Natal.
- Full Text:
- Date Issued: 2007
- Authors: Kobus, Louann
- Date: 2007
- Subjects: Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10590 , http://hdl.handle.net/10948/534 , http://hdl.handle.net/10948/d1011724 , Big game hunting -- South Africa -- KwaZulu-Natal , Big game hunting -- South Africa -- Eastern Cape , Hunting -- South Africa -- KwaZulu-Natal , Hunting -- South Africa -- Eastern Cape , Game farms -- South Africa -- KwaZulu-Natal , Game farms -- South Africa -- Eastern Cape
- Description: The objectives of this research, were to investigate the characteristics and develop a profile of the game and hunting industries of KwaZulu-Natal, and to undertake a comparison between the game and hunting industries in KwaZulu-Natal and the Eastern Cape. The comparative part of this study was completed using results obtained from a study done in 2002 in the Eastern Cape (van Niekerk, 2002). The main farming activities in KwaZulu-Natal are large livestock production and sugar cane production. In recent years, private landowners in KwaZulu-Natal have undergone a transition from livestock production to game ranching due to the problems faced and the cost implications of the HIV epidemic, stock theft, difficulties faced with changes in the labour laws and the increasing number of land claims against farmers. Although the game and hunting industries are relatively young industries in KwaZulu-Natal they contribute significantly to the economy of the province. Not only is greater conservation of the biodiversity more effective in game ranching but it is also proving to yield great economic returns. The increase in game ranching in recent years is namely due to the monetary value placed on wildlife, the increased value in ecotourism and its value as an earner of foreign exchange, less dependency on unskilled labour than that of livestock farming and lower rates of animal loss through theft compared to that of livestock farming. In KwaZulu-Natal game numbers indicate that impala have the greatest population amongst the respondents, followed by nyala, blesbok, common reedbuck, kudu and blue wildebeest, whilst other game species occur in smaller numbers. Respondents in KwaZulu-Natal indicate that nyala is the largest economic earner for them followed by buffalo, whereas in the Eastern Cape (2002), kudu and springbok provide the greatest income for the province. In KwaZulu-Natal income generated from hunting is second to that of live game sales compared to the Eastern Cape (2002) where hunting is the most important form of game utilisation in terms of income generated. At the time of this study, respondents in KwaZulu-Natal reported an income of R 15 382 397 generated from live sales and R 13 561 459 from hunting. These respondents also indicated that the total value of game utilised annually was in excess of R 30 million. Although game utilisation is occurring on a sustainable basis, there is room for greater utilisation of some game species which, if undertaken correctly, can increase the revenue for the province significantly and also contribute positively to further sustainability of the game populations. KwaZulu-Natal’s competitive advantage is derived from the fact that there is an abundance of game on the ranches, quality trophy animals are available, the number of game species available for hunting and quality of service rendered to hunters by the professional hunters and ranch owners. This study has clearly shown that there is a need for further investigation into the game and hunting industries in KwaZulu-Natal.
- Full Text:
- Date Issued: 2007
An analysis of the influence of phosphorus poisoning on the exhaust emission after treatement systems of light-duty diesel vehicles
- Authors: Toral del Rio, Maria Isabel
- Date: 2007
- Subjects: Diesel motor -- Alternative fuels , Automobiles -- Pollution control devices , Automobiles -- Motors -- Exhaust gas , Motor fuels
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10405 , http://hdl.handle.net/10948/697 , Diesel motor -- Alternative fuels , Automobiles -- Pollution control devices , Automobiles -- Motors -- Exhaust gas , Motor fuels
- Description: Climate change has become a discussion topic of exponentially increasing urgency and importance amoung world leaders of all disciplines. These changes are brought about by the emission of so-called Greenhouse gases from various human activities. The primary cause of CO2 emissions is the burning of the Earth’s supply of nonrenewable natural fossil fuels like coal, oil and natural gas. The world first agreed on the prevention of “dangerous” climatic changes at the Earth Summit in 1992. The Kyoto Protocol of 1997 was the first step toward protection of the atmosphere and prescribes restrictions on emission pollutants. Since then the vehicle gas emissions are being controlled by means of different gas emissions norms, like the European Union Norm in Europe. The automotive manufacturers and suppliers are collectively working on reducing overall vehicle emissions. They are focusing on several different emission limiting possibilities, for example improved engine design, special fuel development and exhaust gas treatment systems. The exhaust gas treatment process requires continuous controlling and management of the exhaust gas emissions while driving a vehicle. Certain factors such as high emission temperatures have a negative influence on the life span of these systems. Their functionality and durability is also known to be reduced by the presence of chemical poisoning species like sulphur, phosphorus, zinc and calcium. The chemical poisoning species are produced during combustion of fuel and engine oil. They are therefore contained in the exhaust emissions and can poison the catalyst when passing over it. Phosphorous poisoning is particularly problematic and should be reduced considerably. This study involves the investigation of the phosphorous poisoning process and aims to provide clarity regarding the influences of different fuel and oil compositions on the severity of the process. Engine oil and biodiesel are two major sources of phosphorous poisoning. The phosphorus contained in biodiesel fuel is a natural component and can be minimized during the refining procedure. In contrast to others studies, the biodiesel fuel used during this project was SME (Soya Methyl Ester) with a 20% biodiesel content. This choice of fuel was made because of the increasingly important role that this type of biodiesel is playing in the European market and the future tendency to increase the percentage of biodiesel in the mixture with standard diesel fuel. The phosphorus contained in engine oil is a necessary additive to retain the antioxidant and anti-wear properties of the oil. This study examined the poisoning influences from the most commonly used phosphorus containing oil additive, Zinc Dithiophosphates (ZDDP), as well as a Zn-free, phosphorus containing anti-wear oil additive. This formulation provides information about the phosphorus poisoning process as caused by the engine oil in the absence of Zn in the oil additives. The results show how the phosphorus content in biodiesel fuel affects the functionality of the exhaust gas treatment systems and the importance of reducing the permitted content of phosphorus contained in the fuel. Reducing the phosphorus content in the fuel will conserve the functionality of the exhaust gas treatment systems during their operational life and thereby protect the environmental from emission pollutants. It also provides insight into the differences in the poisoning processes when the phosphorus deposited on the catalyst comes from biodiesel fuel and when it comes from the engine oil. Finally the results also illustrate the influence of different phosphorous forms contained in engine oil additives on the catalyst poisoning process. This information could be used for the development of new oil additive formulations.
- Full Text:
- Date Issued: 2007
- Authors: Toral del Rio, Maria Isabel
- Date: 2007
- Subjects: Diesel motor -- Alternative fuels , Automobiles -- Pollution control devices , Automobiles -- Motors -- Exhaust gas , Motor fuels
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10405 , http://hdl.handle.net/10948/697 , Diesel motor -- Alternative fuels , Automobiles -- Pollution control devices , Automobiles -- Motors -- Exhaust gas , Motor fuels
- Description: Climate change has become a discussion topic of exponentially increasing urgency and importance amoung world leaders of all disciplines. These changes are brought about by the emission of so-called Greenhouse gases from various human activities. The primary cause of CO2 emissions is the burning of the Earth’s supply of nonrenewable natural fossil fuels like coal, oil and natural gas. The world first agreed on the prevention of “dangerous” climatic changes at the Earth Summit in 1992. The Kyoto Protocol of 1997 was the first step toward protection of the atmosphere and prescribes restrictions on emission pollutants. Since then the vehicle gas emissions are being controlled by means of different gas emissions norms, like the European Union Norm in Europe. The automotive manufacturers and suppliers are collectively working on reducing overall vehicle emissions. They are focusing on several different emission limiting possibilities, for example improved engine design, special fuel development and exhaust gas treatment systems. The exhaust gas treatment process requires continuous controlling and management of the exhaust gas emissions while driving a vehicle. Certain factors such as high emission temperatures have a negative influence on the life span of these systems. Their functionality and durability is also known to be reduced by the presence of chemical poisoning species like sulphur, phosphorus, zinc and calcium. The chemical poisoning species are produced during combustion of fuel and engine oil. They are therefore contained in the exhaust emissions and can poison the catalyst when passing over it. Phosphorous poisoning is particularly problematic and should be reduced considerably. This study involves the investigation of the phosphorous poisoning process and aims to provide clarity regarding the influences of different fuel and oil compositions on the severity of the process. Engine oil and biodiesel are two major sources of phosphorous poisoning. The phosphorus contained in biodiesel fuel is a natural component and can be minimized during the refining procedure. In contrast to others studies, the biodiesel fuel used during this project was SME (Soya Methyl Ester) with a 20% biodiesel content. This choice of fuel was made because of the increasingly important role that this type of biodiesel is playing in the European market and the future tendency to increase the percentage of biodiesel in the mixture with standard diesel fuel. The phosphorus contained in engine oil is a necessary additive to retain the antioxidant and anti-wear properties of the oil. This study examined the poisoning influences from the most commonly used phosphorus containing oil additive, Zinc Dithiophosphates (ZDDP), as well as a Zn-free, phosphorus containing anti-wear oil additive. This formulation provides information about the phosphorus poisoning process as caused by the engine oil in the absence of Zn in the oil additives. The results show how the phosphorus content in biodiesel fuel affects the functionality of the exhaust gas treatment systems and the importance of reducing the permitted content of phosphorus contained in the fuel. Reducing the phosphorus content in the fuel will conserve the functionality of the exhaust gas treatment systems during their operational life and thereby protect the environmental from emission pollutants. It also provides insight into the differences in the poisoning processes when the phosphorus deposited on the catalyst comes from biodiesel fuel and when it comes from the engine oil. Finally the results also illustrate the influence of different phosphorous forms contained in engine oil additives on the catalyst poisoning process. This information could be used for the development of new oil additive formulations.
- Full Text:
- Date Issued: 2007
An investigation into the parameters affecting the stability of Dithane
- Authors: Williams, Nadia
- Date: 2007
- Subjects: Fungicides , Dithane
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10407 , http://hdl.handle.net/10948/645 , Fungicides , Dithane
- Description: Plant diseases caused by fungi are the number one cause of crop loss worldwide. The application of a fungicide which is a toxic substance applied either to prevent the growth of, or to kill fungi is one of the methods by which plant diseases are controlled. Ethylenebisdithiocarbamate fungicides are a group of surface acting fungicides which control a broad spectrum of fungi and their associated plant diseases. Mancozeb, also commonly known as Dithane, falls under the polymeric Dithiocarbamate fungicides which have several sites of toxicity to the fungal cell. The use of Mancozeb as a fungicide is increasing worldwide due to the advantages of low acute toxicity, low production and short environmental persistence. However, it has one major disadvantage, namely its lack of oxidative stability under ambient conditions. One of the objectives of this study was to characterize the Dithane samples supplied by Dow AgroSciences in terms of their active ingredient, metal and stabilizer content, and to study the thermal decomposition behaviour of Dithane. An attempt was made to correlate the active ingredient analyses with the TGA and DSC results to establish whether the thermal stability and active ingredient content of Dithane could be simultaneously determined by thermal analysis. This approach offered the attractive advantage of shorter analysis times thus allowing the elimination of the more tedious analytical methods employed by Dow AgroSciences. Furthermore, Fourier Transform infra-red characterization of Dithane samples and metal complexes containing HMT, Mn and/or Zn was carried out in order to identify the presence of functional groups and to gain some insight into the nature of the bonding of HMT, sulfate and water. A study of the nature of the bands in the FTIR spectra of these complexes was able to highlight the nature of the bonding but could not give confirmation of the structures of these complexes. In addition to this, the amount of HMT present in the said complexes was determined by the FTIR using the standard addition method. A final objective of the study was to investigate the reconstitution of Dithane by investigating the influence of the addition order of the various constituents on the stability of the final product. The addition order was found to have a definite influence on the thermal stability of the final product as well as on the percentage of fixed HMT in the product, and the kinetics of the Mn/Zn exchange.
- Full Text:
- Date Issued: 2007
- Authors: Williams, Nadia
- Date: 2007
- Subjects: Fungicides , Dithane
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10407 , http://hdl.handle.net/10948/645 , Fungicides , Dithane
- Description: Plant diseases caused by fungi are the number one cause of crop loss worldwide. The application of a fungicide which is a toxic substance applied either to prevent the growth of, or to kill fungi is one of the methods by which plant diseases are controlled. Ethylenebisdithiocarbamate fungicides are a group of surface acting fungicides which control a broad spectrum of fungi and their associated plant diseases. Mancozeb, also commonly known as Dithane, falls under the polymeric Dithiocarbamate fungicides which have several sites of toxicity to the fungal cell. The use of Mancozeb as a fungicide is increasing worldwide due to the advantages of low acute toxicity, low production and short environmental persistence. However, it has one major disadvantage, namely its lack of oxidative stability under ambient conditions. One of the objectives of this study was to characterize the Dithane samples supplied by Dow AgroSciences in terms of their active ingredient, metal and stabilizer content, and to study the thermal decomposition behaviour of Dithane. An attempt was made to correlate the active ingredient analyses with the TGA and DSC results to establish whether the thermal stability and active ingredient content of Dithane could be simultaneously determined by thermal analysis. This approach offered the attractive advantage of shorter analysis times thus allowing the elimination of the more tedious analytical methods employed by Dow AgroSciences. Furthermore, Fourier Transform infra-red characterization of Dithane samples and metal complexes containing HMT, Mn and/or Zn was carried out in order to identify the presence of functional groups and to gain some insight into the nature of the bonding of HMT, sulfate and water. A study of the nature of the bands in the FTIR spectra of these complexes was able to highlight the nature of the bonding but could not give confirmation of the structures of these complexes. In addition to this, the amount of HMT present in the said complexes was determined by the FTIR using the standard addition method. A final objective of the study was to investigate the reconstitution of Dithane by investigating the influence of the addition order of the various constituents on the stability of the final product. The addition order was found to have a definite influence on the thermal stability of the final product as well as on the percentage of fixed HMT in the product, and the kinetics of the Mn/Zn exchange.
- Full Text:
- Date Issued: 2007
Cost-benefit analysis of land restoration in the Assegaaibos Catchment Area with regard to water yield and tourism benefit
- Authors: Currie, Bianca
- Date: 2007
- Subjects: Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10751 , http://hdl.handle.net/10948/726 , Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Description: With the emergence of the new field of resource economics, one now has the ability to value and to include natural resources in decision making. This thesis aims to explore the valuation of natural resources by reviewing the economic values, techniques, methods and ecological aspects of restoration. Assegaaibos mountain catchment in the Western Cape Province has been used as a case-study example. A cost-benefit analysis of the restoration of the mountain catchment, in terms of the direct benefits of water and tourism, has been performed. The costs of restoration were observed to see whether they outweighed the benefits (income) derived (water and tourism). The results show that the water and tourism benefits did outweigh the costs of a basic restoration scenario. However, the basic restoration scenario did not fulfil the ecological requirements of the project. The results also illustrated that in the moderate restoration scenario, costs only outweighed the benefits when a three percent discount rate was applied. With the optimistic restoration scenario, costs outweighed benefits only when an eight percent discount rate was used. In the comprehensive restoration scenario, costs were shown to outweigh by far the water and tourism benefits over a thirty-year time frame. However, it should be noted that the deterioration of the environment (accelerated erosion, reinvasion, reduced water quality) was not factored into the costs of failure to rehabilitate.
- Full Text:
- Date Issued: 2007
- Authors: Currie, Bianca
- Date: 2007
- Subjects: Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10751 , http://hdl.handle.net/10948/726 , Reclamation of land -- Economic aspects -- South Africa -- Assegaaibos Catchment Area , Land use -- Environmental aspects -- South Africa -- Assegaaibos Catchment Area
- Description: With the emergence of the new field of resource economics, one now has the ability to value and to include natural resources in decision making. This thesis aims to explore the valuation of natural resources by reviewing the economic values, techniques, methods and ecological aspects of restoration. Assegaaibos mountain catchment in the Western Cape Province has been used as a case-study example. A cost-benefit analysis of the restoration of the mountain catchment, in terms of the direct benefits of water and tourism, has been performed. The costs of restoration were observed to see whether they outweighed the benefits (income) derived (water and tourism). The results show that the water and tourism benefits did outweigh the costs of a basic restoration scenario. However, the basic restoration scenario did not fulfil the ecological requirements of the project. The results also illustrated that in the moderate restoration scenario, costs only outweighed the benefits when a three percent discount rate was applied. With the optimistic restoration scenario, costs outweighed benefits only when an eight percent discount rate was used. In the comprehensive restoration scenario, costs were shown to outweigh by far the water and tourism benefits over a thirty-year time frame. However, it should be noted that the deterioration of the environment (accelerated erosion, reinvasion, reduced water quality) was not factored into the costs of failure to rehabilitate.
- Full Text:
- Date Issued: 2007
Improving certain high performance properties of natural fibres
- Authors: Chapple, Stephen Anthony
- Date: 2007
- Subjects: Textile chemistry , Fireproofing of fabrics
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10451 , http://hdl.handle.net/10948/815 , Textile chemistry , Fireproofing of fabrics
- Description: Cotton possesses many characteristics that make it desirable to the consumer, and this has resulted in its usage in a broad range of products. Cotton, however, is a flammable material that is easily ignited and rapidly consumed. The flame retardant treatment of cotton is, therefore, an important textile process that has received wide attention over many years. There are a number of commercial flame retardant treatments available for cotton, the most common being phosphate-based. These treatments, however, often have drawbacks or have a negative impact on the desirable properties of the fibre and the challenge still exists for designing better flame retardant products and systems that are durable and have limited impact on fibre properties. The study considers the application of the sol-gel as a coating on fabric that was pre-treated with a phosphate-based flame retardant or as a means for applying a phosphate-based flame retardant. Both treatment methods were found to be suitable for imparting flame resistance to the fabric. The effect of various phosphate-based flame retardants on flammability and fabric properties such as colour, handle and strength was investigated and it was shown that a diammonium phosphate and urea combination gave the best flame resistance. In this regard, a flame resistance was achieved with a lower amount of phosphorous than was used in similar conventional treatments. The durability of the coating to rinsing with water and soaping with a detergent was also investigated. It was found that the flame resistance was lost after rinsing or soaping but the prevention of afterglow combustion was retained. It was shown that the preparatory treatment of the fabric influenced the sol-gel coating process and the flammability of the fabric. Mercerisation and bleaching of the fabric increased the “wet pick-up” during the coating process and improved the flame resistance. The influence of various factors was also investigated in further detail. The ratio of the sol-gel components, the delay after coating prior to drying (hang time) and the curing time were investigated using an experimental design. The curing time and the ratio of components in the sol-gel were shown to have the greatest influence on fabric properties and fabric flammability. It was shown that there is a trade-off between the desired high level of fabric flame resistance and preserving the inherent properties of the fabric such as colour, handle and strength.
- Full Text:
- Date Issued: 2007
- Authors: Chapple, Stephen Anthony
- Date: 2007
- Subjects: Textile chemistry , Fireproofing of fabrics
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10451 , http://hdl.handle.net/10948/815 , Textile chemistry , Fireproofing of fabrics
- Description: Cotton possesses many characteristics that make it desirable to the consumer, and this has resulted in its usage in a broad range of products. Cotton, however, is a flammable material that is easily ignited and rapidly consumed. The flame retardant treatment of cotton is, therefore, an important textile process that has received wide attention over many years. There are a number of commercial flame retardant treatments available for cotton, the most common being phosphate-based. These treatments, however, often have drawbacks or have a negative impact on the desirable properties of the fibre and the challenge still exists for designing better flame retardant products and systems that are durable and have limited impact on fibre properties. The study considers the application of the sol-gel as a coating on fabric that was pre-treated with a phosphate-based flame retardant or as a means for applying a phosphate-based flame retardant. Both treatment methods were found to be suitable for imparting flame resistance to the fabric. The effect of various phosphate-based flame retardants on flammability and fabric properties such as colour, handle and strength was investigated and it was shown that a diammonium phosphate and urea combination gave the best flame resistance. In this regard, a flame resistance was achieved with a lower amount of phosphorous than was used in similar conventional treatments. The durability of the coating to rinsing with water and soaping with a detergent was also investigated. It was found that the flame resistance was lost after rinsing or soaping but the prevention of afterglow combustion was retained. It was shown that the preparatory treatment of the fabric influenced the sol-gel coating process and the flammability of the fabric. Mercerisation and bleaching of the fabric increased the “wet pick-up” during the coating process and improved the flame resistance. The influence of various factors was also investigated in further detail. The ratio of the sol-gel components, the delay after coating prior to drying (hang time) and the curing time were investigated using an experimental design. The curing time and the ratio of components in the sol-gel were shown to have the greatest influence on fabric properties and fabric flammability. It was shown that there is a trade-off between the desired high level of fabric flame resistance and preserving the inherent properties of the fabric such as colour, handle and strength.
- Full Text:
- Date Issued: 2007
Investigating the influences of validation on pharmaceutical manufacturing processes
- Authors: Muller, Damian Christian
- Date: 2007
- Subjects: Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10412 , http://hdl.handle.net/10948/566 , Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Description: This investigation attempts to examine the influences of validation on pharmaceutical processes especially at a new manufacturing facility that has to meet international requirements, and fulfil a cost effective business strategy. At Aspen Pharmacare, a pharmaceutical organisation, there are two manufacturing facilities situated adjacent to each other, one new and one old. The new facility creates ideal opportunities to supply products to local and international markets. The investigation compares legal requirements from local and international regulatory authorities. Validation and qualification practices as well as the problems encountered during the different phases are discussed. Particular attention is given to the validation approach at the new Aspen facility. Problems and proposed solutions relating to the design review, installation, operational, and performance qualification are discussed. Validation of analytical methods for cleaning analysis, cleaning validation of equipment, and optimisation of some tablet manufacturing processes are described. Statistical evaluations of analytical results are included to find the optimum conditions for integrating new personnel with new processes and equipment. A business model reviews the cost of non-conformances of the enalapril maleate 10 mg tablets manufactured at the two manufacturing facilities. Finally the dissertation proves that validation is not only a regulatory requirement but that it also provides benefits such as adding value to the business, and ultimately reducing the cost of medicines.
- Full Text:
- Date Issued: 2007
- Authors: Muller, Damian Christian
- Date: 2007
- Subjects: Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10412 , http://hdl.handle.net/10948/566 , Pharmaceutical industry -- Quality control , Pharmaceutical technology , Drugs -- Standards
- Description: This investigation attempts to examine the influences of validation on pharmaceutical processes especially at a new manufacturing facility that has to meet international requirements, and fulfil a cost effective business strategy. At Aspen Pharmacare, a pharmaceutical organisation, there are two manufacturing facilities situated adjacent to each other, one new and one old. The new facility creates ideal opportunities to supply products to local and international markets. The investigation compares legal requirements from local and international regulatory authorities. Validation and qualification practices as well as the problems encountered during the different phases are discussed. Particular attention is given to the validation approach at the new Aspen facility. Problems and proposed solutions relating to the design review, installation, operational, and performance qualification are discussed. Validation of analytical methods for cleaning analysis, cleaning validation of equipment, and optimisation of some tablet manufacturing processes are described. Statistical evaluations of analytical results are included to find the optimum conditions for integrating new personnel with new processes and equipment. A business model reviews the cost of non-conformances of the enalapril maleate 10 mg tablets manufactured at the two manufacturing facilities. Finally the dissertation proves that validation is not only a regulatory requirement but that it also provides benefits such as adding value to the business, and ultimately reducing the cost of medicines.
- Full Text:
- Date Issued: 2007
Ionic liquids as media for electro-organic synthesis
- Authors: Kruger, Elna
- Date: 2007
- Subjects: Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10413 , http://hdl.handle.net/10948/538 , Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Description: The IL’s used in this study were either synthesized or commercially available. Preparation of the IL’s involved 2 step processes: firstly the heating of distilled 1-methylimidazole with distilled 1-chlorobutane under reflux to obtain 1-butyl-3- methylimidazolium chloride; secondly, the metathesis reaction of sodium tetrafluoroborate with 1-butyl-3-methylimidazolium chloride to obtain 1-butyl-3- methylimidazolium tetrafluoroborate. The addition of sodium tetrafluoroborate, sodium hexafluorophosphate and lithium trifluoromethane sulfonamide with 1-butyl-3-methylimidazolium chloride produced good yields of 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium hexafluorophosphate and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide respectively. The IL’s are hygroscopic and must be stored under a nitrogen atmosphere. The IL’s were analyzed using 1H and 13C NMR analysis with CDCl3 as solvent. The physical and chemical properties of these IL’s were compared to commercial products. The physical and chemical properties compared well to reference values from the literature. The physical properties measured include the density, conductivity and electrochemical window. The electrochemical window is dependant primarily on the resistance of the cation to reduction and the resistance of the anion to oxidation. The electrochemical windows of the IL’s were very similar to the reference windows obtained from literature and it can be seen that some IL’s have a slightly lower window which can be due to water present. Water content in the IL’s was determined with the use of a Karl Fischer titrator, with Hydranal 5 Composite as titrant and HPLC grade methanol as the base. The concentration of halide in the IL’s was determined with a Perkin-Elmer ICP-MS.
- Full Text:
- Date Issued: 2007
- Authors: Kruger, Elna
- Date: 2007
- Subjects: Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10413 , http://hdl.handle.net/10948/538 , Ionic solutions , Inorganic compounds -- Synthesis , Electrochemistry
- Description: The IL’s used in this study were either synthesized or commercially available. Preparation of the IL’s involved 2 step processes: firstly the heating of distilled 1-methylimidazole with distilled 1-chlorobutane under reflux to obtain 1-butyl-3- methylimidazolium chloride; secondly, the metathesis reaction of sodium tetrafluoroborate with 1-butyl-3-methylimidazolium chloride to obtain 1-butyl-3- methylimidazolium tetrafluoroborate. The addition of sodium tetrafluoroborate, sodium hexafluorophosphate and lithium trifluoromethane sulfonamide with 1-butyl-3-methylimidazolium chloride produced good yields of 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium hexafluorophosphate and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide respectively. The IL’s are hygroscopic and must be stored under a nitrogen atmosphere. The IL’s were analyzed using 1H and 13C NMR analysis with CDCl3 as solvent. The physical and chemical properties of these IL’s were compared to commercial products. The physical and chemical properties compared well to reference values from the literature. The physical properties measured include the density, conductivity and electrochemical window. The electrochemical window is dependant primarily on the resistance of the cation to reduction and the resistance of the anion to oxidation. The electrochemical windows of the IL’s were very similar to the reference windows obtained from literature and it can be seen that some IL’s have a slightly lower window which can be due to water present. Water content in the IL’s was determined with the use of a Karl Fischer titrator, with Hydranal 5 Composite as titrant and HPLC grade methanol as the base. The concentration of halide in the IL’s was determined with a Perkin-Elmer ICP-MS.
- Full Text:
- Date Issued: 2007
Micellar-enhanced ultrafiltration of palladium and platinum anions
- Authors: Gwicana, Sakumzi
- Date: 2007
- Subjects: Micelles , Ultrafiltration , Palladium catalysts
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10414 , http://hdl.handle.net/10948/518 , Micelles , Ultrafiltration , Palladium catalysts
- Description: The project was concerned with studying the capability of a micellar-enhanced ultrafiltration system (MEUF) to remove platinum group metal ions namely Pt (lV) and Pd (ll) chloro anions from aqueous industrial waste effluents. South Africa has the world’s largest reserves of platinum group metals (PGMs) and other valuable metals such as manganese, chrome ores, titanium minerals etc. which are required for new automotive and other technologies, including fuel cells, catalytic converters and lighter components. The consistent loss with the industrial waste stream and the toxicological effects of these precious metals led to the need to develop new and effective methods to recover them from industrial waste effluents. With such a wide variety of fields where these PGMs are used and the failure of the traditional techniques namely sedimentation, fermentation etc. to effectively reduce or recover these highly toxic and precious metal ions prior to discharging industrial waste effluents, it is necessary to explore other techniques such as membrane technology that can be used to recover these valuable species from industrial waste streams. The present study involved the use of a cationic surfactant, viz cetylpyridinium chloride, which was introduced into an aqueous solution containing palladium and platinum metal anions. The surfactant forms charged micelles above a certain critical concentration value. The metal anions adsorb onto the available oppositely charged sites on the micelle surfaces and are then able to be retained by a suitable membrane. Hollow fibre ultrafiltration membranes with the MWCO of +/- 10 kD and +/-30nm pore size were used as a filter component in this study. For this MEUF system to be effective, it was vital that the anionic metal ion species adsorbed sufficiently onto the available oppositely charged sites of the micelles and that the micelles were retained efficiently by the membrane. Results obtained during the investigation made it possible to make certain predictions about the micellisation process. It was also found that, it was not only the metal ion: surfactant (M:S) ratio that was critical, but the presence of other electrolytes in the aqueous stream proved to have a huge impact on the capability of the MEUF system. Findings of this research study showed that the MEUF system using cetylpyridinium chloride (CPC) can be used to recover or retain Pt (lV) and Pd (ll) anions from industrial waste effluents. It was also found that PtCl6 2-, due to its greater adsorption capabilities onto the micelle surface than PdCl4 2- or PdCl3(H2O)-, was preferentially retained in neutral medium. This may be exploited as a possible means of separating the two metal ions. The developed system offers the following advantages over some traditional and current methods: simplified unit operation line flow process, smaller amounts of chemical usage and no solid toxic sludge to be disposed of. Applications of this work could be of vital importance in catalytic converter recycling, especially in Port Elizabeth where extensive automobile parts manufacturing occurs.
- Full Text:
- Date Issued: 2007
- Authors: Gwicana, Sakumzi
- Date: 2007
- Subjects: Micelles , Ultrafiltration , Palladium catalysts
- Language: English
- Type: Thesis , Masters , MTech
- Identifier: vital:10414 , http://hdl.handle.net/10948/518 , Micelles , Ultrafiltration , Palladium catalysts
- Description: The project was concerned with studying the capability of a micellar-enhanced ultrafiltration system (MEUF) to remove platinum group metal ions namely Pt (lV) and Pd (ll) chloro anions from aqueous industrial waste effluents. South Africa has the world’s largest reserves of platinum group metals (PGMs) and other valuable metals such as manganese, chrome ores, titanium minerals etc. which are required for new automotive and other technologies, including fuel cells, catalytic converters and lighter components. The consistent loss with the industrial waste stream and the toxicological effects of these precious metals led to the need to develop new and effective methods to recover them from industrial waste effluents. With such a wide variety of fields where these PGMs are used and the failure of the traditional techniques namely sedimentation, fermentation etc. to effectively reduce or recover these highly toxic and precious metal ions prior to discharging industrial waste effluents, it is necessary to explore other techniques such as membrane technology that can be used to recover these valuable species from industrial waste streams. The present study involved the use of a cationic surfactant, viz cetylpyridinium chloride, which was introduced into an aqueous solution containing palladium and platinum metal anions. The surfactant forms charged micelles above a certain critical concentration value. The metal anions adsorb onto the available oppositely charged sites on the micelle surfaces and are then able to be retained by a suitable membrane. Hollow fibre ultrafiltration membranes with the MWCO of +/- 10 kD and +/-30nm pore size were used as a filter component in this study. For this MEUF system to be effective, it was vital that the anionic metal ion species adsorbed sufficiently onto the available oppositely charged sites of the micelles and that the micelles were retained efficiently by the membrane. Results obtained during the investigation made it possible to make certain predictions about the micellisation process. It was also found that, it was not only the metal ion: surfactant (M:S) ratio that was critical, but the presence of other electrolytes in the aqueous stream proved to have a huge impact on the capability of the MEUF system. Findings of this research study showed that the MEUF system using cetylpyridinium chloride (CPC) can be used to recover or retain Pt (lV) and Pd (ll) anions from industrial waste effluents. It was also found that PtCl6 2-, due to its greater adsorption capabilities onto the micelle surface than PdCl4 2- or PdCl3(H2O)-, was preferentially retained in neutral medium. This may be exploited as a possible means of separating the two metal ions. The developed system offers the following advantages over some traditional and current methods: simplified unit operation line flow process, smaller amounts of chemical usage and no solid toxic sludge to be disposed of. Applications of this work could be of vital importance in catalytic converter recycling, especially in Port Elizabeth where extensive automobile parts manufacturing occurs.
- Full Text:
- Date Issued: 2007