Overview and comparison of Besshi-type deposits ancient and recent
- Authors: Schoeman, Philo
- Date: 1996
- Subjects: Ore deposits -- Japan , Ore deposits -- Canada , Ore deposits -- Namibia , Ore deposits -- South Africa , Ore deposits
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4983 , http://hdl.handle.net/10962/d1005595 , Ore deposits -- Japan , Ore deposits -- Canada , Ore deposits -- Namibia , Ore deposits -- South Africa , Ore deposits
- Description: Besshi-type deposits range in age from early Proterozoic to early Tertiary, of which the largest number are late Proterozoic, early Palaeozoic or Mesozoic in age. No Archaean examples of Besshi-type deposits are known, probably due to insufficient availability of sialic crust for erosion and clastic marine sedimentation before the start of the Proterozoic. All Besshi-type deposits are contained within sequences of clastic sedimentary rock and intercalated basalts in a marine environment. The basalts and amphibolites are principally tholeiitic in composition. Besshi-type deposits characteristically form stratiform 1enses and sheet-like accumulations of semi-massive to massive sulphide. The main ore assemblage consists dominantly of pyrite and/or pyrrhotite with variable amounts of chalcopyrite, sphalerite and trace galena, arsenopyrite, gold and e1ectrum, barite being absent in general. The median Besshi-type deposit (n=75) contains 1.3 million tonnes (Mt) of massive sulphide with a Cu grade running at 1.43%. It is suggested that Besshi-type deposits form by both exhalative and synsedimentary replacement processes when considering geological features and comparisons with modern analogues in the Guaymas Basin, Middle Valley and Escanaba Trough. The currently forming metalliferous sediments in the Red Sea provide for a brine pool model explaining the lack of footwall feeder zones below sheet-like deposits. Where thick sulphide lenses are contained in some Besshi-type deposits, combinations of exhalative precipitation and sub-sea-floor replacement of permeable sediments and/or volcanic rocks, take place in the upper parts of submarine hydrothermal systems.
- Full Text:
- Date Issued: 1996
- Authors: Schoeman, Philo
- Date: 1996
- Subjects: Ore deposits -- Japan , Ore deposits -- Canada , Ore deposits -- Namibia , Ore deposits -- South Africa , Ore deposits
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4983 , http://hdl.handle.net/10962/d1005595 , Ore deposits -- Japan , Ore deposits -- Canada , Ore deposits -- Namibia , Ore deposits -- South Africa , Ore deposits
- Description: Besshi-type deposits range in age from early Proterozoic to early Tertiary, of which the largest number are late Proterozoic, early Palaeozoic or Mesozoic in age. No Archaean examples of Besshi-type deposits are known, probably due to insufficient availability of sialic crust for erosion and clastic marine sedimentation before the start of the Proterozoic. All Besshi-type deposits are contained within sequences of clastic sedimentary rock and intercalated basalts in a marine environment. The basalts and amphibolites are principally tholeiitic in composition. Besshi-type deposits characteristically form stratiform 1enses and sheet-like accumulations of semi-massive to massive sulphide. The main ore assemblage consists dominantly of pyrite and/or pyrrhotite with variable amounts of chalcopyrite, sphalerite and trace galena, arsenopyrite, gold and e1ectrum, barite being absent in general. The median Besshi-type deposit (n=75) contains 1.3 million tonnes (Mt) of massive sulphide with a Cu grade running at 1.43%. It is suggested that Besshi-type deposits form by both exhalative and synsedimentary replacement processes when considering geological features and comparisons with modern analogues in the Guaymas Basin, Middle Valley and Escanaba Trough. The currently forming metalliferous sediments in the Red Sea provide for a brine pool model explaining the lack of footwall feeder zones below sheet-like deposits. Where thick sulphide lenses are contained in some Besshi-type deposits, combinations of exhalative precipitation and sub-sea-floor replacement of permeable sediments and/or volcanic rocks, take place in the upper parts of submarine hydrothermal systems.
- Full Text:
- Date Issued: 1996
Distribution of iron-titanium oxides in the vanadiferous main magnetite seam of the upper zone : Northern limb, Bushveld complex
- Authors: Gwatinetsa, Demand
- Date: 2014
- Subjects: Igneous rocks -- South Africa -- Bushveld Complex , Sulfide minerals -- South Africa -- Bushveld Complex , Vanadium -- South Africa -- Bushveld Complex , Titanium dioxide -- South Africa -- Bushveld Complex , Ferric oxide -- South Africa -- Bushveld Complex , Geology -- South Africa -- Bushveld Complex , Mineralogy -- South Africa -- Bushveld Complex , Mines and mineral resources -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5063 , http://hdl.handle.net/10962/d1013281
- Description: The main magnetite seam of the Upper Zone of the Rustenburg Layered Suite (SACS, 1980) on the Bushveld Complex is known to host the world‘s largest vanadium bearing titaniferous iron ores. The vanadiferous titanomagnetites, contain vanadium in sufficient concentrations (1.2 - 2.2 per cent V₂O₅) to be considered as resources and vanadium has been mined historically by a number of companies among them Anglo-American, Highveld Steel and Vanadium and VanMag Resources as well as currently by Evraz Highveld Steel and Vanadium Limited of South Africa. The titanomagnetites contain iron ore in the form of magnetite and titanium with concentrations averaging 50-75 per cent FeO and 12-21 per cent TiO₂. The titaniferous iron ores have been historically dismissed as a source of iron and titanium, due to the known difficulties of using iron ore with high titania content in blast furnaces. The economic potential for the extractability of the titaniferous magnetites lies in the capacity of the ores to be separated into iron rich and titanium rich concentrates usually through, crushing, grinding and magnetic separation. The separatability of iron oxides and titanium oxides, is dependent on the nature in which the titanium oxide occurs, with granular ilmenite being the most favourable since it can be separated from magnetite via magnetic separation. Titanium that occurs as finely exsolved lamellae or as iron-titanium oxides with low titania content such as ulvospinel render the potential recoverability of titanium poor. The Upper Zone vanadiferous titanomagnetites contain titanium in various forms varying from discrete granular ilmenite to finely exsolved lamellae as well as occurring as part of the minerals ulvospinel (Fe₂TiO₄) and titanomagnetite (a solid solution series between ulvospinel and magnetite) . Discrete ilmenite constitutes between 3-5 per cent by volume of the massive titanomagnetite ores, and between 5-10 per cent by volume of the magnetite-plagioclase cumulates with more than 50 per cent opaque oxide minerals. The purpose of this research was to investigate the mineralogical setting and distribution of the iron and titanium oxides within the magnetitite layers from top to bottom as well as spatially along a strike length of 2 000m to determine the potential for the titanium to be extracted from the titanomagnetite ores. The titanomagnetites of the Upper Zone of the Bushveld Complex with particular reference to the Northern Limb where this research was conducted contains titanium oxides as discrete ilmenite grains but in low concentrations whose potential for separate economic extraction will be challenging. The highest concentration of titanium in the magnetite ores is not contained in the granular ilmenite, but rather in ulvospinel and titanomagnetite as illustrated by the marked higher concentration of TiO₂ in the massive ores which contain less granular ilmenite in comparison to the disseminated ores which contain 3 to 8 percentage points higher granular ilmenite than the massive ores. On the scale of the main magnetite seam, the TiO₂ content increases with increasing stratigraphic height from being completely absent in the footwall anorthosite. The V₂2O₅ content also increases with stratigraphic height except for in one of the 3 boreholes where it drops with increasing height. The decrease or increase patterns are repeated in every seam. The titanomagnetites of the main magnetite seam display a variety of textures from coarse granular magnetite and ilmenite, to trellis ilmenite lamellae, intergranular ilmenite and magnesian spinels and fine exsolution lamellae of ulvospinel and ferro-magnesian spinels parallel to the magnetite cleavage. The bottom contact of the main magnetite seam is very sharp and there is no titanium or vanadium in the footwall barely 10cm below the contact. Chromium is present in the bottom of the 4 layers that constitute the main magnetite seam and it upwards decreases rapidly. In boreholes P21 and P55, there are slight reversals in the TiO₂ and V₂O₅ content towards the top of the magnetite seams.
- Full Text:
- Date Issued: 2014
- Authors: Gwatinetsa, Demand
- Date: 2014
- Subjects: Igneous rocks -- South Africa -- Bushveld Complex , Sulfide minerals -- South Africa -- Bushveld Complex , Vanadium -- South Africa -- Bushveld Complex , Titanium dioxide -- South Africa -- Bushveld Complex , Ferric oxide -- South Africa -- Bushveld Complex , Geology -- South Africa -- Bushveld Complex , Mineralogy -- South Africa -- Bushveld Complex , Mines and mineral resources -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5063 , http://hdl.handle.net/10962/d1013281
- Description: The main magnetite seam of the Upper Zone of the Rustenburg Layered Suite (SACS, 1980) on the Bushveld Complex is known to host the world‘s largest vanadium bearing titaniferous iron ores. The vanadiferous titanomagnetites, contain vanadium in sufficient concentrations (1.2 - 2.2 per cent V₂O₅) to be considered as resources and vanadium has been mined historically by a number of companies among them Anglo-American, Highveld Steel and Vanadium and VanMag Resources as well as currently by Evraz Highveld Steel and Vanadium Limited of South Africa. The titanomagnetites contain iron ore in the form of magnetite and titanium with concentrations averaging 50-75 per cent FeO and 12-21 per cent TiO₂. The titaniferous iron ores have been historically dismissed as a source of iron and titanium, due to the known difficulties of using iron ore with high titania content in blast furnaces. The economic potential for the extractability of the titaniferous magnetites lies in the capacity of the ores to be separated into iron rich and titanium rich concentrates usually through, crushing, grinding and magnetic separation. The separatability of iron oxides and titanium oxides, is dependent on the nature in which the titanium oxide occurs, with granular ilmenite being the most favourable since it can be separated from magnetite via magnetic separation. Titanium that occurs as finely exsolved lamellae or as iron-titanium oxides with low titania content such as ulvospinel render the potential recoverability of titanium poor. The Upper Zone vanadiferous titanomagnetites contain titanium in various forms varying from discrete granular ilmenite to finely exsolved lamellae as well as occurring as part of the minerals ulvospinel (Fe₂TiO₄) and titanomagnetite (a solid solution series between ulvospinel and magnetite) . Discrete ilmenite constitutes between 3-5 per cent by volume of the massive titanomagnetite ores, and between 5-10 per cent by volume of the magnetite-plagioclase cumulates with more than 50 per cent opaque oxide minerals. The purpose of this research was to investigate the mineralogical setting and distribution of the iron and titanium oxides within the magnetitite layers from top to bottom as well as spatially along a strike length of 2 000m to determine the potential for the titanium to be extracted from the titanomagnetite ores. The titanomagnetites of the Upper Zone of the Bushveld Complex with particular reference to the Northern Limb where this research was conducted contains titanium oxides as discrete ilmenite grains but in low concentrations whose potential for separate economic extraction will be challenging. The highest concentration of titanium in the magnetite ores is not contained in the granular ilmenite, but rather in ulvospinel and titanomagnetite as illustrated by the marked higher concentration of TiO₂ in the massive ores which contain less granular ilmenite in comparison to the disseminated ores which contain 3 to 8 percentage points higher granular ilmenite than the massive ores. On the scale of the main magnetite seam, the TiO₂ content increases with increasing stratigraphic height from being completely absent in the footwall anorthosite. The V₂2O₅ content also increases with stratigraphic height except for in one of the 3 boreholes where it drops with increasing height. The decrease or increase patterns are repeated in every seam. The titanomagnetites of the main magnetite seam display a variety of textures from coarse granular magnetite and ilmenite, to trellis ilmenite lamellae, intergranular ilmenite and magnesian spinels and fine exsolution lamellae of ulvospinel and ferro-magnesian spinels parallel to the magnetite cleavage. The bottom contact of the main magnetite seam is very sharp and there is no titanium or vanadium in the footwall barely 10cm below the contact. Chromium is present in the bottom of the 4 layers that constitute the main magnetite seam and it upwards decreases rapidly. In boreholes P21 and P55, there are slight reversals in the TiO₂ and V₂O₅ content towards the top of the magnetite seams.
- Full Text:
- Date Issued: 2014
The geology, petrology and geochemistry of the mineralization and hydrothermal alteration at Ongeama, Ongombo and Matchless West Extension, Namibia
- Authors: Moroni, Marilena
- Date: 1991
- Subjects: Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5045 , http://hdl.handle.net/10962/d1007693 , Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Description: The Matchless Amphibolite Belt (Damara Orogen, Namibia) hosts several volcanogenic-exhalative, sediment-hosted stratiform cupriferous pyrite deposits. These are thought to be related to submarine volcanism during the early evolutionary stages of a narrow Damaran ocean, the Matchless Trough. The mineralized bodies examined (Ongeama, Ongombo and Matchless West Extension) are deformed and metamorphosed to low-medium grade (greenschist-amphibolite facies). They are associated with metapelite and amphibolite country rocks, and crop out as prominent limonite-rich gossans. The elongated shape of the sulphide bodies suggests a structural control. The mineralization normally consists of a variably developed massive sulphide portion, either quartz-, talc- or amphibole-bearing, and a stratigraphically overlying, extensive horizon of sulphide- and baryte-bearing exhalite (magnetite quartzite and less common talc- and actinolite-bearing schists). Lateral and vertical mineralogical changes within the mineralization match with significant variations in the element distribution. A metamorphosed and deformed alteration pipe, indicating the position of the fluid conduit, can be recognized in association with some ore bodies. The formation of quartz-muscovite and chlorite alteration envelopes (Ongeama, Matchless West Extension) and the presence of subtle mineralogical changes (Ongombo) in the immediate wallrocks, accompanied by extensive redistribution, leaching and introduction of elements from outside, suggest the hydrothermal metasomatic origin of the alteration zones. Element zoning within the mineralized bodies can be related to the original position of the vent, possibly coinciding with the intersection of the axis of the alteration pipe with the sulphide body. Cu, Zn, Au (pro parte) and Mo are enriched proximal to the vent, whereas Pb, Ba, Mn, Ag, Au, Sn, Bi and W enrichment characterizes the distal facies of the mineralization. In spite of the obliterating and disrupting effects of the regional dynamo-metamorphism, the element distribution within the mineralization and alteration zones examined is comparable with the geochemical trends observed in present-day mineralizing systems in early- stage oceanic environments (e.g. Guaymas Basin). During exploration for blind volcanogenic mineralization, the detection of hydrothermally altered rocks is fundamental in indicating the proximity to the mineralization. The localization of the alteration zone is also important in the interpretation of the regional geology of the explored area: in deformed terrains the assessment of the stratigraphic position of the alteration zone, relative to the mineralization, helps in establishing the polarity of the sequence.
- Full Text:
- Date Issued: 1991
- Authors: Moroni, Marilena
- Date: 1991
- Subjects: Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5045 , http://hdl.handle.net/10962/d1007693 , Geology -- Namibia , Petrology -- Namibia , Geochemistry -- Namibia
- Description: The Matchless Amphibolite Belt (Damara Orogen, Namibia) hosts several volcanogenic-exhalative, sediment-hosted stratiform cupriferous pyrite deposits. These are thought to be related to submarine volcanism during the early evolutionary stages of a narrow Damaran ocean, the Matchless Trough. The mineralized bodies examined (Ongeama, Ongombo and Matchless West Extension) are deformed and metamorphosed to low-medium grade (greenschist-amphibolite facies). They are associated with metapelite and amphibolite country rocks, and crop out as prominent limonite-rich gossans. The elongated shape of the sulphide bodies suggests a structural control. The mineralization normally consists of a variably developed massive sulphide portion, either quartz-, talc- or amphibole-bearing, and a stratigraphically overlying, extensive horizon of sulphide- and baryte-bearing exhalite (magnetite quartzite and less common talc- and actinolite-bearing schists). Lateral and vertical mineralogical changes within the mineralization match with significant variations in the element distribution. A metamorphosed and deformed alteration pipe, indicating the position of the fluid conduit, can be recognized in association with some ore bodies. The formation of quartz-muscovite and chlorite alteration envelopes (Ongeama, Matchless West Extension) and the presence of subtle mineralogical changes (Ongombo) in the immediate wallrocks, accompanied by extensive redistribution, leaching and introduction of elements from outside, suggest the hydrothermal metasomatic origin of the alteration zones. Element zoning within the mineralized bodies can be related to the original position of the vent, possibly coinciding with the intersection of the axis of the alteration pipe with the sulphide body. Cu, Zn, Au (pro parte) and Mo are enriched proximal to the vent, whereas Pb, Ba, Mn, Ag, Au, Sn, Bi and W enrichment characterizes the distal facies of the mineralization. In spite of the obliterating and disrupting effects of the regional dynamo-metamorphism, the element distribution within the mineralization and alteration zones examined is comparable with the geochemical trends observed in present-day mineralizing systems in early- stage oceanic environments (e.g. Guaymas Basin). During exploration for blind volcanogenic mineralization, the detection of hydrothermally altered rocks is fundamental in indicating the proximity to the mineralization. The localization of the alteration zone is also important in the interpretation of the regional geology of the explored area: in deformed terrains the assessment of the stratigraphic position of the alteration zone, relative to the mineralization, helps in establishing the polarity of the sequence.
- Full Text:
- Date Issued: 1991
Investigations to determine the long-term sustainable yield of the Karoo aquifer and the sustained availability of groundwater for small-scale irrigation projects, in Dendera area, Kwekwe District - Zimbabwe
- Authors: Njanike, Joseph Tendayi
- Date: 2001
- Subjects: Groundwater , Irrigation -- Equipement and supplies , Irrigation -- Kwekwe (Zimbabwe)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5093 , http://hdl.handle.net/10962/d1020853
- Description: In this thesis the long-term sustainable yield of the Karoo sediment aquifer unit occurring in Dendera area of Kwekwe District is investigated, with the object of providing quantitative data on the sustained availability of groundwater for small-scale irrigation projects. Archaean Basement Schists and Pre-Cambrian gneissic granites, the Basement Complex rocks, underlie the entire study area. Overlying these are Upper Karoo sediments. Aeolian Kalahari sands unconformably mantle higher interfluves, while redistributed sands occur along valleys of major rivers and streams. The Karoo sediments, which predominantly consist of loosely cemented, fine- to medium-grained sandstone alternating with red siltstone and mudstone, constitute the main aquifer. The thickness of the Karoo sediment unit ranges from 30m to 80m. The hydraulic parameters of the Karoo sediment aquifer were characterised in the field by constant discharge pumping tests and slug tests. Pumping tests indicated unconfined conditions and thus the Neuman's method of analysis has been used. Transmissivities from pumping tests are within the range 4.7 m²/d to 13.6 m²/d with an average of 8.9m²/d. The low transmissivities seem to be a major limiting factor in the exploitation of the groundwater resources. Thus the sustainable borehole yields tend to be small, mean values ranging from 33 m²/d to 253 m²/d. Specific yield could not be determined from the pumping tests due to the lack of observation boreholes. Low chemical concentrations render the water suitable for irrigation of all crops, while neither total nor any individual concentrations present health hazards to human or livestock. An average recharge value of 47.7 mm/y was inferred from water table fluctuation method. Chloride mass balance technique in the same area indicates recharge value in the order of 67.4 mm/y. Because the chloride mass balance gives a long-term mean annual recharge, the recharge figure of 67.4 mm/y was adopted for the study area. Based on the abstractable proportion of recharge, the sustainably exploitable volume of groundwater of the order of 2.68 x 10⁷ m³/y was established. This volume is more than 100 times the estimated current demand for groundwater (1.35 x 10⁵ m³/d), implying that there are large volumes of surplus water, which can be utilised for irrigation.
- Full Text:
- Date Issued: 2001
- Authors: Njanike, Joseph Tendayi
- Date: 2001
- Subjects: Groundwater , Irrigation -- Equipement and supplies , Irrigation -- Kwekwe (Zimbabwe)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5093 , http://hdl.handle.net/10962/d1020853
- Description: In this thesis the long-term sustainable yield of the Karoo sediment aquifer unit occurring in Dendera area of Kwekwe District is investigated, with the object of providing quantitative data on the sustained availability of groundwater for small-scale irrigation projects. Archaean Basement Schists and Pre-Cambrian gneissic granites, the Basement Complex rocks, underlie the entire study area. Overlying these are Upper Karoo sediments. Aeolian Kalahari sands unconformably mantle higher interfluves, while redistributed sands occur along valleys of major rivers and streams. The Karoo sediments, which predominantly consist of loosely cemented, fine- to medium-grained sandstone alternating with red siltstone and mudstone, constitute the main aquifer. The thickness of the Karoo sediment unit ranges from 30m to 80m. The hydraulic parameters of the Karoo sediment aquifer were characterised in the field by constant discharge pumping tests and slug tests. Pumping tests indicated unconfined conditions and thus the Neuman's method of analysis has been used. Transmissivities from pumping tests are within the range 4.7 m²/d to 13.6 m²/d with an average of 8.9m²/d. The low transmissivities seem to be a major limiting factor in the exploitation of the groundwater resources. Thus the sustainable borehole yields tend to be small, mean values ranging from 33 m²/d to 253 m²/d. Specific yield could not be determined from the pumping tests due to the lack of observation boreholes. Low chemical concentrations render the water suitable for irrigation of all crops, while neither total nor any individual concentrations present health hazards to human or livestock. An average recharge value of 47.7 mm/y was inferred from water table fluctuation method. Chloride mass balance technique in the same area indicates recharge value in the order of 67.4 mm/y. Because the chloride mass balance gives a long-term mean annual recharge, the recharge figure of 67.4 mm/y was adopted for the study area. Based on the abstractable proportion of recharge, the sustainably exploitable volume of groundwater of the order of 2.68 x 10⁷ m³/y was established. This volume is more than 100 times the estimated current demand for groundwater (1.35 x 10⁵ m³/d), implying that there are large volumes of surplus water, which can be utilised for irrigation.
- Full Text:
- Date Issued: 2001
Epithermal precious metal deposits physicochemical constraints, classification characteristics and exploration guidelines
- Authors: McIver, Donald A
- Date: 1997
- Subjects: Precious metals , Geothermal resources
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4941 , http://hdl.handle.net/10962/d1005553 , Precious metals , Geothermal resources
- Description: Epithermal deposits include a broad range of precious metal, base metal, mercury, and stibnite deposits. These deposits exhibit a low temperature of formation (180-280°C) at pressures of less than a few hundred bars (equivalent to depths of 1.5 - 2.0lkm). Epithermal gold deposits are the product of large-scale hydrothermal systems which mostly occur in convergent plate margin settings. Associated volcanism is largely of andesitic arc (calcalkaline to alkaline), or rhyolitic back-arc type. Porphyry Cu-Mo-Au deposits form deeper in the same systems. Genetic processes within individual deposits take place in an extremely complex manner. The resultant mineral associations, alteration styles and metal deposition patterns are even more complicated. Many attempts have been made to classify epithermal deposits based on mineralogy and alteration, host rocks, deposit form, genetic models, and standard deposits. For the explorationist, the most useful classification schemes should be brief, simple, descriptive, observationally based, and informative. Ultimately, two distinct styles of epithermal gold deposits are readily recognised: high-sulphidation, acid sulphate and low-sulphidation, adularia-sericite types. The terms high-sulphidation (HS) and low-sulphidation (IS) are based on the sulphidation state of associated sulphide minerals, which, along with characteristic hydrothermal alteration, reflect fundamental chemical differences in the epithermal environment. Highsulphidation-type deposits form in the root zones of volcanic domes from acid waters that contain residual magmatic volatiles. The low-sulphidation-type deposits form in geothermal systems where surficial waters mix with deeper, heated saline waters in a lateral flow regime, where neutral to weakly acidic, alkali chloride waters are dominant. The HSILS classification, combined with a simple description of the form of the deposit, conveys a large amount of information on mineralogy, alteration, and spatial characteristics of the mineralisation, and allows inferences to be drawn regarding likely regional controls, and the characteristics of the ore-forming fluids. The modern understanding of these environments allows us to quite effectively identify the most probable foci of mineral deposition in any given district. Current knowledge of these deposits has been derived from studies of active geothermal systems. Through comparison with alteration zones within these systems, the exploration geologist may determine the potential distribution and types of ore in a fossil geothermal system. Alteration zoning specifically can be used as a guide towards the most prospective part of the system. Epithermal gold deposits of both HS- and LS-styles are nevertheless profoundly difficult exploration targets. Successful exploration must rely on the integration of a variety of exploration techniques, guided by an understanding of the characteristics of the deposits and the processes that form them. There are no simple formulae for success in epithermal exploration: what works best must be determined for each terrain and each prospect. On a regional scale tectonic, igneous and structural settings can be used, together with assessment of the depth of erosion, to select areas for project area scale exploration. Integrated geological-geophysical interpretation derived from airborne geophysics providesa basis of targeting potential ore environments for follow-up. Geology, geochemistry and surface geophysics localise mineral concentrations within these target areas
- Full Text:
- Date Issued: 1997
- Authors: McIver, Donald A
- Date: 1997
- Subjects: Precious metals , Geothermal resources
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4941 , http://hdl.handle.net/10962/d1005553 , Precious metals , Geothermal resources
- Description: Epithermal deposits include a broad range of precious metal, base metal, mercury, and stibnite deposits. These deposits exhibit a low temperature of formation (180-280°C) at pressures of less than a few hundred bars (equivalent to depths of 1.5 - 2.0lkm). Epithermal gold deposits are the product of large-scale hydrothermal systems which mostly occur in convergent plate margin settings. Associated volcanism is largely of andesitic arc (calcalkaline to alkaline), or rhyolitic back-arc type. Porphyry Cu-Mo-Au deposits form deeper in the same systems. Genetic processes within individual deposits take place in an extremely complex manner. The resultant mineral associations, alteration styles and metal deposition patterns are even more complicated. Many attempts have been made to classify epithermal deposits based on mineralogy and alteration, host rocks, deposit form, genetic models, and standard deposits. For the explorationist, the most useful classification schemes should be brief, simple, descriptive, observationally based, and informative. Ultimately, two distinct styles of epithermal gold deposits are readily recognised: high-sulphidation, acid sulphate and low-sulphidation, adularia-sericite types. The terms high-sulphidation (HS) and low-sulphidation (IS) are based on the sulphidation state of associated sulphide minerals, which, along with characteristic hydrothermal alteration, reflect fundamental chemical differences in the epithermal environment. Highsulphidation-type deposits form in the root zones of volcanic domes from acid waters that contain residual magmatic volatiles. The low-sulphidation-type deposits form in geothermal systems where surficial waters mix with deeper, heated saline waters in a lateral flow regime, where neutral to weakly acidic, alkali chloride waters are dominant. The HSILS classification, combined with a simple description of the form of the deposit, conveys a large amount of information on mineralogy, alteration, and spatial characteristics of the mineralisation, and allows inferences to be drawn regarding likely regional controls, and the characteristics of the ore-forming fluids. The modern understanding of these environments allows us to quite effectively identify the most probable foci of mineral deposition in any given district. Current knowledge of these deposits has been derived from studies of active geothermal systems. Through comparison with alteration zones within these systems, the exploration geologist may determine the potential distribution and types of ore in a fossil geothermal system. Alteration zoning specifically can be used as a guide towards the most prospective part of the system. Epithermal gold deposits of both HS- and LS-styles are nevertheless profoundly difficult exploration targets. Successful exploration must rely on the integration of a variety of exploration techniques, guided by an understanding of the characteristics of the deposits and the processes that form them. There are no simple formulae for success in epithermal exploration: what works best must be determined for each terrain and each prospect. On a regional scale tectonic, igneous and structural settings can be used, together with assessment of the depth of erosion, to select areas for project area scale exploration. Integrated geological-geophysical interpretation derived from airborne geophysics providesa basis of targeting potential ore environments for follow-up. Geology, geochemistry and surface geophysics localise mineral concentrations within these target areas
- Full Text:
- Date Issued: 1997
Gold metallogeny of Australia
- Authors: Rankine, Graham M
- Date: 1987
- Subjects: Gold ores -- Geology -- Australia , Gold mines and mining -- Australia , Gold -- Metallurgy -- Australia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4928 , http://hdl.handle.net/10962/d1004676
- Description: The gold metallogeny of Australia is predominantly confined to the Archaean and Palaeozoic Provinces. The Archaean gold occurrences are predominantly hosted in ultramafic-mafic dominated greenstone belts, with less associated tofelsic-volcanic and sedimentary sequences. Most gold occurrences are confined to shear zones or faults, and adjacent discoveries of economic laterite-hosted deposits, host rocks. Recent are presently under investigation and will supply a significant proportion of production in the future. The Proterozoic gold deposits of Australia , are confined to geosyncinal sequences, commonly turbidites (eg: Telfer), with other hydrothermal deposits associated directly to granites. An important feature of the North Australian Craton deposits, is the spatial association of most deposits to granite bodies, although a genetic link has not been established conclusively. The Roxby Downs deposit in South Australia is a unique occurrence of gold in association to copper, uranium and R.E.E. This deposit is tentatively related to intraplate alkaline-magmatism, with further work necessary. The most significant recent discovery of gold mineralization in Australia is in the Drummond Basin in Queensland. This epithermal is tentatively related to mineralization within the Georgetown Inlier. The latter mineralization is Permo-Carboniferous, in a Proterozoic (and possibly Archaean) sequence of schists. It is tentatively suggested that all the gold mineralization in northern Queensland may be related to single tectonic event, a feature which requires further study . Other mineralization in the Phanerozoic includes the turbidite-hosted metamorphogenic deposits of Victoria, the rift related deposits in New South Wales and magmatic related deposits in Queensland. The gold deposits in Australia may in the future be classified in a tectonogeological framework, similiar to the layout of this dissertation, particularly once further data becomes available on recent discoveries.
- Full Text:
- Date Issued: 1987
- Authors: Rankine, Graham M
- Date: 1987
- Subjects: Gold ores -- Geology -- Australia , Gold mines and mining -- Australia , Gold -- Metallurgy -- Australia
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4928 , http://hdl.handle.net/10962/d1004676
- Description: The gold metallogeny of Australia is predominantly confined to the Archaean and Palaeozoic Provinces. The Archaean gold occurrences are predominantly hosted in ultramafic-mafic dominated greenstone belts, with less associated tofelsic-volcanic and sedimentary sequences. Most gold occurrences are confined to shear zones or faults, and adjacent discoveries of economic laterite-hosted deposits, host rocks. Recent are presently under investigation and will supply a significant proportion of production in the future. The Proterozoic gold deposits of Australia , are confined to geosyncinal sequences, commonly turbidites (eg: Telfer), with other hydrothermal deposits associated directly to granites. An important feature of the North Australian Craton deposits, is the spatial association of most deposits to granite bodies, although a genetic link has not been established conclusively. The Roxby Downs deposit in South Australia is a unique occurrence of gold in association to copper, uranium and R.E.E. This deposit is tentatively related to intraplate alkaline-magmatism, with further work necessary. The most significant recent discovery of gold mineralization in Australia is in the Drummond Basin in Queensland. This epithermal is tentatively related to mineralization within the Georgetown Inlier. The latter mineralization is Permo-Carboniferous, in a Proterozoic (and possibly Archaean) sequence of schists. It is tentatively suggested that all the gold mineralization in northern Queensland may be related to single tectonic event, a feature which requires further study . Other mineralization in the Phanerozoic includes the turbidite-hosted metamorphogenic deposits of Victoria, the rift related deposits in New South Wales and magmatic related deposits in Queensland. The gold deposits in Australia may in the future be classified in a tectonogeological framework, similiar to the layout of this dissertation, particularly once further data becomes available on recent discoveries.
- Full Text:
- Date Issued: 1987
Aspects of the geochemistry of the Karroo dolerites and basalts of the north-eastern Cape
- Authors: Robey, Julian van Aardt
- Date: 1976
- Subjects: Diabase -- South Africa -- Cape of Good Hope , Basalt -- South Africa -- Cape of Good Hope , Geochemistry -- South Africa -- Cape of Good Hope
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5060 , http://hdl.handle.net/10962/d1013070
- Description: The Birds River Gabbro Complex is intruded into sediments of the Karroo Stormberg Group in the area SW of Dordrecht in the northeastern Cape. A geochemical investigation, restricted to the igneous rock suite, gabbro-ferrogabbro-ferrotholeiite, presents new major-element data as well as data for twelve trace elements - Ba, Sr, Rb, Zr, Y, Nb , Zn, Cu, Ni, Co, V and Cr. The strong degree of differentiation of Kokstad-type tholeiitic magma in the Birds River intrusion, as noted by previous investigators, is revealed in variation diagrams in which data are plotted against a simple index of fractionation. Later differentiates are strongly enriched in Si, Ti, Fe, Na, K, P, Ba, Rb, Zr, Y, Nb, Zn and Cu but depleted in Mg, Ca, AI, Ni, Co and Cr. Extreme differentiation resulted in a strong depletion of Ti, Fe, P, Cu and V in the most highly evolved ferrotholeiites. Field evidence suggests the initial emplacement of strongly fractionated magmatic residua derived from fractional crystallization processes in a magma chamber at depth during cauldron subsidence of a mass of sediments within an annular fracture. These porphyritic, in part glassy, ferrotholeiites are enriched in Si, Na, K, Ba, Zr, Rb, Y, Nb and Zn and were engulfed by a later episode of renewed hypabyssal intrusive activity from the original source area. The younger gabbro was emplaced in a series of closely-spaced heaves or pulses of relatively undifferentiated Kokstad-type magma. The gabbro differentiated in place to form ferrogabbros which chemically closely approximate ferrotholeiite compositions. toidal facies. Residual liquids crystallized as a pegmatoidal facies. A simple fractional crystallization path, modelled on the assumption that the gabbro and ferrotholeiite form a continuous series, indicates that the least evolved ferrotholeiite can be derived from the initial gabbro composition by the fractionation of major amounts of plagioclase and pyroxene but lesser amounts of olivine. Crystallization and removal of magnetite and other Fe-oxides were relatively more important during the later stages of differentiation. The variation of major- and trace-elements in tholeiitic Karroo magma under conditions of strong differentiation at Birds River serves as a framework for the regional study of the geochemistry of other Karroo dolerites and volcanics of the north-eastern Cape. New geochemical data are presented for a sample of thirty chilled and coarse-grained Karroo dolerites collected throughout the north eastern Cape. For the most part, the chilled dolerites are relatively undifferentiated and the average composition differs only slightly from that determined by Walker and Poldervaart (1949). Variation diagrams reveal the steady increase in Si, Al, Ca, Na, K and P and the residual trace elements Ba, Zr, Rb, Y, Nb and Zn with increasing differentiation of the dolerites from more basic types. The concentrations of K, Ba and Rb are highly variable in some Karroo dolerites while new data suggest that Nb levels in the dolerites are low, being generally less than 10 ppm. The strong variation of the K-related elements (K, Ba and Rb) as well as the large ranges determined for certain inter-element ratios, such as K/Rb, Zr/Nb and K/Zr in the chilled Karroo dolerites, suggest that factors other than fractional crystallization processes need to be considered to account for individual variations. Little correlation exists between petrographic type as defined by Walker and Poldervaart (1949) and geochemical character. New geochemical data are also presented for ten Karroo basaltic lavas from the lowermost horizons of the lava sequence exposed in the Barkly East area. Major- and trace-element data indicate that these earliest Karroo extrusives are on average enriched in Si and Rb but depleted in Co and Ni when compared with the averaged chilled Karroo dolerite. Compared with basalts from Lesotho, the Barkly East basalts are enriched in Si but depleted in Ni and possibly Nb, Cu and V. The andesite is markedly enriched in Si, Na, K, Ba, Sr, Rb, Zr and Nb but depleted in Mg, Ca, V, Ni , Cu, Co and Cr. The subdued rate of Ni depletion and the absence of olivine as a major phenocryst phase in the series basalt to andesite, in the Barkly East area, suggests that differentiation trends may be controlled by the fractional crystallization of orthopyroxene and plagioclase, the two common phenocrysts present in these volcanics. The strong depletion of V and Cu in the andesite may indicate some magnetite removal during fractional crystallization.
- Full Text:
- Date Issued: 1976
- Authors: Robey, Julian van Aardt
- Date: 1976
- Subjects: Diabase -- South Africa -- Cape of Good Hope , Basalt -- South Africa -- Cape of Good Hope , Geochemistry -- South Africa -- Cape of Good Hope
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5060 , http://hdl.handle.net/10962/d1013070
- Description: The Birds River Gabbro Complex is intruded into sediments of the Karroo Stormberg Group in the area SW of Dordrecht in the northeastern Cape. A geochemical investigation, restricted to the igneous rock suite, gabbro-ferrogabbro-ferrotholeiite, presents new major-element data as well as data for twelve trace elements - Ba, Sr, Rb, Zr, Y, Nb , Zn, Cu, Ni, Co, V and Cr. The strong degree of differentiation of Kokstad-type tholeiitic magma in the Birds River intrusion, as noted by previous investigators, is revealed in variation diagrams in which data are plotted against a simple index of fractionation. Later differentiates are strongly enriched in Si, Ti, Fe, Na, K, P, Ba, Rb, Zr, Y, Nb, Zn and Cu but depleted in Mg, Ca, AI, Ni, Co and Cr. Extreme differentiation resulted in a strong depletion of Ti, Fe, P, Cu and V in the most highly evolved ferrotholeiites. Field evidence suggests the initial emplacement of strongly fractionated magmatic residua derived from fractional crystallization processes in a magma chamber at depth during cauldron subsidence of a mass of sediments within an annular fracture. These porphyritic, in part glassy, ferrotholeiites are enriched in Si, Na, K, Ba, Zr, Rb, Y, Nb and Zn and were engulfed by a later episode of renewed hypabyssal intrusive activity from the original source area. The younger gabbro was emplaced in a series of closely-spaced heaves or pulses of relatively undifferentiated Kokstad-type magma. The gabbro differentiated in place to form ferrogabbros which chemically closely approximate ferrotholeiite compositions. toidal facies. Residual liquids crystallized as a pegmatoidal facies. A simple fractional crystallization path, modelled on the assumption that the gabbro and ferrotholeiite form a continuous series, indicates that the least evolved ferrotholeiite can be derived from the initial gabbro composition by the fractionation of major amounts of plagioclase and pyroxene but lesser amounts of olivine. Crystallization and removal of magnetite and other Fe-oxides were relatively more important during the later stages of differentiation. The variation of major- and trace-elements in tholeiitic Karroo magma under conditions of strong differentiation at Birds River serves as a framework for the regional study of the geochemistry of other Karroo dolerites and volcanics of the north-eastern Cape. New geochemical data are presented for a sample of thirty chilled and coarse-grained Karroo dolerites collected throughout the north eastern Cape. For the most part, the chilled dolerites are relatively undifferentiated and the average composition differs only slightly from that determined by Walker and Poldervaart (1949). Variation diagrams reveal the steady increase in Si, Al, Ca, Na, K and P and the residual trace elements Ba, Zr, Rb, Y, Nb and Zn with increasing differentiation of the dolerites from more basic types. The concentrations of K, Ba and Rb are highly variable in some Karroo dolerites while new data suggest that Nb levels in the dolerites are low, being generally less than 10 ppm. The strong variation of the K-related elements (K, Ba and Rb) as well as the large ranges determined for certain inter-element ratios, such as K/Rb, Zr/Nb and K/Zr in the chilled Karroo dolerites, suggest that factors other than fractional crystallization processes need to be considered to account for individual variations. Little correlation exists between petrographic type as defined by Walker and Poldervaart (1949) and geochemical character. New geochemical data are also presented for ten Karroo basaltic lavas from the lowermost horizons of the lava sequence exposed in the Barkly East area. Major- and trace-element data indicate that these earliest Karroo extrusives are on average enriched in Si and Rb but depleted in Co and Ni when compared with the averaged chilled Karroo dolerite. Compared with basalts from Lesotho, the Barkly East basalts are enriched in Si but depleted in Ni and possibly Nb, Cu and V. The andesite is markedly enriched in Si, Na, K, Ba, Sr, Rb, Zr and Nb but depleted in Mg, Ca, V, Ni , Cu, Co and Cr. The subdued rate of Ni depletion and the absence of olivine as a major phenocryst phase in the series basalt to andesite, in the Barkly East area, suggests that differentiation trends may be controlled by the fractional crystallization of orthopyroxene and plagioclase, the two common phenocrysts present in these volcanics. The strong depletion of V and Cu in the andesite may indicate some magnetite removal during fractional crystallization.
- Full Text:
- Date Issued: 1976
The geochemistry and petrology of the Karoo andesites and associated basalts of the north-eastern Cape Province
- Authors: Rumble, Keith Christopher
- Date: 1979 , 2013-02-11
- Subjects: Basalt , South Africa , Cape of Good Hope , Geochemistry , Petrology , Andesite
- Language: English
- Type: Thesis , Masters , M.Sc
- Identifier: vital:4902 , http://hdl.handle.net/10962/d1001562
- Description: New geochemical data consisting of major and 15 trace element analyses are presented for 41 rocks from three andesitic and associated basaltic rock occurrences in the North Eastern Cape Province. These include the Pronksberg, Belmore and Roodehoek localities. Field evidence suggests that the three andesites were emplaced during the early stages of Karoo volcanicity. Geochemical variations within the Pronksberg and Roodehoek andesite are small, manifesting the undifferentiated nature of the magmas. Variations within the Belmore andesite are interpreted as representing fractionation of orthopyroxene, accompanied by only minor plagioclase fractionation. Differences in trace element concentrations and inter-element ratios between the andesites and associated basalts of the Pronksberg and Belmore volcanic suites precludes the possibility of the two rock types being genetically related. Geochemical differences constrain the possibility of the three andesites being cogenetic. Magmatic processes resulting in their formation are, however, thought to be similar. The differences in chemistry between the Pronksberg Basalt (High K Type) and Pronksberg Basalt (Drumbo Type) are interpreted as representing the combined influence of weathering, the presence of amygdales and the within-flow variations of alkali elements on the Pronksberg Basalt (High K Type). Similarities in petrography and chemistry justifies a correlation of the Pronksberg Basalt (Drumbo Type) with the Drumbo Basalt Member in the Barkly East area. Data for the Drumbo Basalt (This study) in the Barkly East area confirms and complements previously presented data. Normative chemistry and strontium isotope data indicate a process involving crustal assimilation or melting of crustal rocks as being the most likely explanation for the genesis of the Karoo andesites , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1979
- Authors: Rumble, Keith Christopher
- Date: 1979 , 2013-02-11
- Subjects: Basalt , South Africa , Cape of Good Hope , Geochemistry , Petrology , Andesite
- Language: English
- Type: Thesis , Masters , M.Sc
- Identifier: vital:4902 , http://hdl.handle.net/10962/d1001562
- Description: New geochemical data consisting of major and 15 trace element analyses are presented for 41 rocks from three andesitic and associated basaltic rock occurrences in the North Eastern Cape Province. These include the Pronksberg, Belmore and Roodehoek localities. Field evidence suggests that the three andesites were emplaced during the early stages of Karoo volcanicity. Geochemical variations within the Pronksberg and Roodehoek andesite are small, manifesting the undifferentiated nature of the magmas. Variations within the Belmore andesite are interpreted as representing fractionation of orthopyroxene, accompanied by only minor plagioclase fractionation. Differences in trace element concentrations and inter-element ratios between the andesites and associated basalts of the Pronksberg and Belmore volcanic suites precludes the possibility of the two rock types being genetically related. Geochemical differences constrain the possibility of the three andesites being cogenetic. Magmatic processes resulting in their formation are, however, thought to be similar. The differences in chemistry between the Pronksberg Basalt (High K Type) and Pronksberg Basalt (Drumbo Type) are interpreted as representing the combined influence of weathering, the presence of amygdales and the within-flow variations of alkali elements on the Pronksberg Basalt (High K Type). Similarities in petrography and chemistry justifies a correlation of the Pronksberg Basalt (Drumbo Type) with the Drumbo Basalt Member in the Barkly East area. Data for the Drumbo Basalt (This study) in the Barkly East area confirms and complements previously presented data. Normative chemistry and strontium isotope data indicate a process involving crustal assimilation or melting of crustal rocks as being the most likely explanation for the genesis of the Karoo andesites , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1979
An insight into magma supply to the Karoo Igneous Province a geochemical investigation of Karoo dykes adjacent to the Northwestern sector of the Lesotho volcanic remnant
- Authors: Mitha, Vindina Ramesh
- Date: 2006
- Subjects: Flood basalts -- Lesotho , Volcanism -- Lesotho , Magmatism -- Lesotho , Dikes (Geology) -- Lesotho , Geochemistry -- Lesotho , Lava -- Lesotho
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4973 , http://hdl.handle.net/10962/d1005585 , Flood basalts -- Lesotho , Volcanism -- Lesotho , Magmatism -- Lesotho , Dikes (Geology) -- Lesotho , Geochemistry -- Lesotho , Lava -- Lesotho
- Description: The emplacement of continental flood basalt provinces is often ascribed to fissure eruption. However, in many provinces the locations of actual vent complexes remains illusive. In southern Africa, the Karoo continental flood basalt province was erupted during the Jurassic between 183 and 179 Ma. The southernmost outcrop of the Karoo continental flood basalt lavas is the Lesotho remnant; and is comprised of the Drakensberg Group which forms the uppermost portion of the Karoo Supergroup. The geochemical stratigraphy for the Drakensberg Group is well established. At the base, there are a number of small volume compositionally diverse units, which form the Barkly East Formation, overlying which, there are larger volume, compositionally less variable units of the Lesotho Formation, which form the bulk of the volcanic sequence. The Lesotho remnant is associated with an abundance of dykes in the adjacent vicinity. This suggests that the lavas were fed from local rather than distal eruption sites. This study presents whole rock major and trace element data for 94 dykes and three sills from the northern Lesotho - northeastern Free State region and demonstrates that on the basis of geochemistry, all 97 intrusions can be correlated with various units of the northern Barkly East and Lesotho Formations. In addition, the petrographical; characteristics, orientation and distribution of the dykes do not correlate with geochemistry. Geochemical discrimination diagrams have been used to identify five compositionally diverse dykes, which are similar to the northern Barkly East Formation units. Three dykes are characteristic of the Letele unit and two are compositionally similar to the Wonderkop unit. Although the geochemical characteristics of the Lesotho Formation units are rather well constrained, the composition of these units is typified by considerable overlap in composition. Therefore, since unambiguous classification of dykes with geochemical similarities to the various units of the Lesotho Formation is unachievable using an empirical approach, the multivariate forward-stepwise discriminant function analysis (DFA) technique was used to facilitate the classification of the remaining 89 dykes and three sills. Forward-stepwise DFA classified 23 dykes as having compositional similarities to the Mafika Lisiu unit, 29 as having compositions of the Maloti or Senqu types; and 32 as having the composition of the Mothae type. In addition, eight dykes are compositionally similar to the Oxbow dykes, which intrude the Senqu unit in northern Lesotho. These results suggest that that the Lesotho remnant was fed from local eruption sites and that long distance magma transport for the bulk of the Lesotho remnant basalt lavas is unlikely.
- Full Text:
- Date Issued: 2006
- Authors: Mitha, Vindina Ramesh
- Date: 2006
- Subjects: Flood basalts -- Lesotho , Volcanism -- Lesotho , Magmatism -- Lesotho , Dikes (Geology) -- Lesotho , Geochemistry -- Lesotho , Lava -- Lesotho
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4973 , http://hdl.handle.net/10962/d1005585 , Flood basalts -- Lesotho , Volcanism -- Lesotho , Magmatism -- Lesotho , Dikes (Geology) -- Lesotho , Geochemistry -- Lesotho , Lava -- Lesotho
- Description: The emplacement of continental flood basalt provinces is often ascribed to fissure eruption. However, in many provinces the locations of actual vent complexes remains illusive. In southern Africa, the Karoo continental flood basalt province was erupted during the Jurassic between 183 and 179 Ma. The southernmost outcrop of the Karoo continental flood basalt lavas is the Lesotho remnant; and is comprised of the Drakensberg Group which forms the uppermost portion of the Karoo Supergroup. The geochemical stratigraphy for the Drakensberg Group is well established. At the base, there are a number of small volume compositionally diverse units, which form the Barkly East Formation, overlying which, there are larger volume, compositionally less variable units of the Lesotho Formation, which form the bulk of the volcanic sequence. The Lesotho remnant is associated with an abundance of dykes in the adjacent vicinity. This suggests that the lavas were fed from local rather than distal eruption sites. This study presents whole rock major and trace element data for 94 dykes and three sills from the northern Lesotho - northeastern Free State region and demonstrates that on the basis of geochemistry, all 97 intrusions can be correlated with various units of the northern Barkly East and Lesotho Formations. In addition, the petrographical; characteristics, orientation and distribution of the dykes do not correlate with geochemistry. Geochemical discrimination diagrams have been used to identify five compositionally diverse dykes, which are similar to the northern Barkly East Formation units. Three dykes are characteristic of the Letele unit and two are compositionally similar to the Wonderkop unit. Although the geochemical characteristics of the Lesotho Formation units are rather well constrained, the composition of these units is typified by considerable overlap in composition. Therefore, since unambiguous classification of dykes with geochemical similarities to the various units of the Lesotho Formation is unachievable using an empirical approach, the multivariate forward-stepwise discriminant function analysis (DFA) technique was used to facilitate the classification of the remaining 89 dykes and three sills. Forward-stepwise DFA classified 23 dykes as having compositional similarities to the Mafika Lisiu unit, 29 as having compositions of the Maloti or Senqu types; and 32 as having the composition of the Mothae type. In addition, eight dykes are compositionally similar to the Oxbow dykes, which intrude the Senqu unit in northern Lesotho. These results suggest that that the Lesotho remnant was fed from local eruption sites and that long distance magma transport for the bulk of the Lesotho remnant basalt lavas is unlikely.
- Full Text:
- Date Issued: 2006
Geochemical exploration in arid and semi-arid environments
- Authors: Van Berkel, Ferdinand
- Date: 1983 , 2013-04-02
- Subjects: Geochemical prospecting , Arid regions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4920 , http://hdl.handle.net/10962/d1004389 , Geochemical prospecting , Arid regions
- Description: Anomalous element distributions within the regolith result from chemical adjustments of the earth's surface to prevailing climatic conditions. Because of the lack of moisture in the arid environment, chemical equilibrium related to paleoclimates is largely maintained. Mechanical or clastic dispersion dominates arid weathering and hence the exploration approach is largely dictated by the degree of preservation of the paleoregolith. Arid environment geochemists thus have to contend with surface materials ranging from laterite and calcrete in areas where the imprint of aridity is minimal, to more conventional sample media such as bedrock, stream sediment and lithic soils in actively dissecting areas. Extraction techniques are designed specifically to isolate clastic dispersion trains. Thick mantles of aeolian and water-borne overburden characterise desert lowlands and are a challenge to the exploration geochemist. Techniques showing the most promise in these areas include groundwater geochemistry, vapour geochemistry, surface microlayer geochemistry, geobotany and biogeochemistry which attempt to isolate gaseous and weak hydromorphic, ore-related trace-element dispersions. Termite mound sampling yields convincing results and appears to be an under-utilised geochemical approach. , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1983
- Authors: Van Berkel, Ferdinand
- Date: 1983 , 2013-04-02
- Subjects: Geochemical prospecting , Arid regions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4920 , http://hdl.handle.net/10962/d1004389 , Geochemical prospecting , Arid regions
- Description: Anomalous element distributions within the regolith result from chemical adjustments of the earth's surface to prevailing climatic conditions. Because of the lack of moisture in the arid environment, chemical equilibrium related to paleoclimates is largely maintained. Mechanical or clastic dispersion dominates arid weathering and hence the exploration approach is largely dictated by the degree of preservation of the paleoregolith. Arid environment geochemists thus have to contend with surface materials ranging from laterite and calcrete in areas where the imprint of aridity is minimal, to more conventional sample media such as bedrock, stream sediment and lithic soils in actively dissecting areas. Extraction techniques are designed specifically to isolate clastic dispersion trains. Thick mantles of aeolian and water-borne overburden characterise desert lowlands and are a challenge to the exploration geochemist. Techniques showing the most promise in these areas include groundwater geochemistry, vapour geochemistry, surface microlayer geochemistry, geobotany and biogeochemistry which attempt to isolate gaseous and weak hydromorphic, ore-related trace-element dispersions. Termite mound sampling yields convincing results and appears to be an under-utilised geochemical approach. , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1983
Exploration for stratabound copper, lead and zinc deposits in the Damara-Katanga orogen, central-southern Africa
- Authors: Latorre, J J
- Date: 1992
- Subjects: Mining geology -- Research -- Africa , Copper ores -- Africa , Lead ores -- Africa , Zinc ores -- Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4946 , http://hdl.handle.net/10962/d1005558
- Description: The Damara-Katanga orogen in central-southern Africa represents an area of 1.73xl0⁶ sq. km. The region is considered one of the wealthiest metallogenic provinces in the world. Successful exploration for stratabound base-metal deposits has taken place at this particular area since the introduction of more organised methodology in the early 1920s. The genesis, location and distribution of the ore deposits are related to their tectonic settings. Geodynamic evolution of the orogen, which initially formed part of a complex Pan-African rift system, comprises the following stages rifting; downwarping, including spreading on the western portion; syn-orogeny and late-orogeny. Two major tectonic events in the history of the region have been identified: the Katangan (900-750 Ma) and the Damaran episodes (750-500 Ma). Timing of mineralisation of ore deposits has been related to the evolutionary stages of the orogen. Genetic models of the most productive deposits are briefly discussed in this dissertation. The sedimentological, geochemical, paleogeographic and structural features can be employed as geological guidelines for integrated exploration programmes. Discoveries of major deposits and prospects in the orogen are also summarised, focussing on the exploration methods employed. The cost-effective use of the exploration techniques includes the classical copper-lead-zinc soil sampling for residual soils such as those in the Copperbelt area. Airborne magnetics and electromagnetics and follow-up ground geophysics have proved successful in areas where the cover is transported in the search for shallow ore deposits such as the Matchless massive sulphides. Remote sensing, geochemical and geophysical techniques have been tried in covered areas of western Botswana. The lack of geological control makes this interpretation difficult. A detailed geological mapping and the use of geochemical and geophysical techniques has been used to delineate carbonate-hosted base-metal deposits at the Otavi Land. The more expensive traditional methods necessary for the delineation of orebodies, such as pitting, trenching and drilling, are also discussed. Using a sequential approach, a possible exploration strategy is suggested, outlining the cost-effective use of remote sensing, geochemical and geophysical techniques. Standardisation in basic geological information is required for future successful explorations in the Damara-Katanga orogen, as well as attractive mining policies. In the event of their implementation, exploration perspectives are promising, specifically in terms of ore potential.
- Full Text:
- Date Issued: 1992
- Authors: Latorre, J J
- Date: 1992
- Subjects: Mining geology -- Research -- Africa , Copper ores -- Africa , Lead ores -- Africa , Zinc ores -- Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4946 , http://hdl.handle.net/10962/d1005558
- Description: The Damara-Katanga orogen in central-southern Africa represents an area of 1.73xl0⁶ sq. km. The region is considered one of the wealthiest metallogenic provinces in the world. Successful exploration for stratabound base-metal deposits has taken place at this particular area since the introduction of more organised methodology in the early 1920s. The genesis, location and distribution of the ore deposits are related to their tectonic settings. Geodynamic evolution of the orogen, which initially formed part of a complex Pan-African rift system, comprises the following stages rifting; downwarping, including spreading on the western portion; syn-orogeny and late-orogeny. Two major tectonic events in the history of the region have been identified: the Katangan (900-750 Ma) and the Damaran episodes (750-500 Ma). Timing of mineralisation of ore deposits has been related to the evolutionary stages of the orogen. Genetic models of the most productive deposits are briefly discussed in this dissertation. The sedimentological, geochemical, paleogeographic and structural features can be employed as geological guidelines for integrated exploration programmes. Discoveries of major deposits and prospects in the orogen are also summarised, focussing on the exploration methods employed. The cost-effective use of the exploration techniques includes the classical copper-lead-zinc soil sampling for residual soils such as those in the Copperbelt area. Airborne magnetics and electromagnetics and follow-up ground geophysics have proved successful in areas where the cover is transported in the search for shallow ore deposits such as the Matchless massive sulphides. Remote sensing, geochemical and geophysical techniques have been tried in covered areas of western Botswana. The lack of geological control makes this interpretation difficult. A detailed geological mapping and the use of geochemical and geophysical techniques has been used to delineate carbonate-hosted base-metal deposits at the Otavi Land. The more expensive traditional methods necessary for the delineation of orebodies, such as pitting, trenching and drilling, are also discussed. Using a sequential approach, a possible exploration strategy is suggested, outlining the cost-effective use of remote sensing, geochemical and geophysical techniques. Standardisation in basic geological information is required for future successful explorations in the Damara-Katanga orogen, as well as attractive mining policies. In the event of their implementation, exploration perspectives are promising, specifically in terms of ore potential.
- Full Text:
- Date Issued: 1992
A mineralogical investigation of co-existing iron-titanium oxides from various igneous rocks with special reference to some South African titaniferous iron ores
- Authors: Reynolds, Ivan Melvin
- Date: 1979
- Subjects: Igneous rocks Mineralogy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4926 , http://hdl.handle.net/10962/d1004589
- Description: Part I consists of a detailied review of the available literature on the Fe- Ti oxides and their solid solution relationships. Particular attention is glven to the microstructures exhibited by these oxides and the hypotheses put forward to explain them. These data are synthesised and models are presented in which the microstructural developments in titaniferous magnetites amd ilmenites are explained in terms of current ideas on the influence of oxygen fugacity, exsolution mechanisms and crystal chemistry. These models have direct application to the microintergrowths observed in the naturally occurring Fe-Ti oxides from a wide range of igneous rocks. The available data on the minor and trace element chemistry of the Fe-Ti oxides are reviewed with particular reference to their variation in these minerals from different host rocks. The behaviour of the Fe-Ti oxides during secondary oxidation is discussed with particular reference to the oxidation of titaniferous magnetite and the weathering of ilmenite. The results of a mineralogical investigation into the co-existing Fe-Ti oxides from a range of igneous rocks including kimberlites, gabbros, dolerites, diabases, syenites, granophyres, granites and pegmatites are presented in Part 2 together with data on the ilmenites present in certain Eastern Cape beach sands. The kimberlite ilmenites are chemically distinct and can be readily distinguished on the basis of their relatively high MgO, Fe₂0₃ and Cr₂O₃ contents. They can also be distinguished from ilmenites from other igneous rocks on the basis of unit cell dimensions, d-spacings, reflectivities and micro-indentation hardness. The ilmenites from a wide range of basic to granitic igneous rocks exhibit a limited compositional range in which the MnO content appears to increase with increasing Si0₂ content. Relatively insensitive indirectly determined parameters such as unit cell dimensions, reflectivities and micro-indentation hardnesses cannot be used to distinguish between the ilmenites from the different rock types in these classes. The titaniferous magnetites exhibit progressively decreasing Ti0₂ contents from a maximum in the basic igneous rocks to a minimum in the granitic types. The titaniferous magnetite typically exhibits varying degrees of deuteric alteration, while the microstructures developed can be interpreted 1n terms of the models presented in Part 1. Part 3 represents an extension of Part 2 and deals with a mineralogical investigation of the titaniferous iron ores in five South African basic intrusions. The Bushveld and Kaffirskraal ores consist of multi-phase titaniferous magnetite grains containing crystallographically oriented ilmenite, ulvospinel and pleonaste microintergrowths. Minor coarser-grained ilmenite is also present. The Usushwana ores are texturally similar but contain abundant lamellar ilmenite in place of the ulvospinel. The primary features are well preserved in the unmetamorphosed Bushveld and Kaffirskraal ores. The Usushwana ores have been slightly metamorphosed resulting in the extensive replacement of the titaniferous magnetites by sphene and chlorite aggregates. The ores from these three complexes cannot be beneficiated by conventional ore-dressing techniques and require direct metallurgical treatment for the recovery of Fe, Ti0₂ and V₂O₅. The metamorphosed Mambula and Rooiwater ores have been recrystallised to a varying degrees and consist of multi-phase titaniferous magnetite grains containing modified ilmenite and pleonaste microintergrowths. These modified microstructures differ from those encountered in titaniferous magnetites from unmetnmorphosed basic rocks and their degree of modification can be related to the degree of met amorphism. Variable amounts of coarse granular ilmenite are also present and their development is related to the metamorphic grade and degree of recrystallisation. These ores can be partially beneficiated to yield ilmenite- and lower-Ti0₂ magnetite concentrates in which V₂O₅ contents of the magnetic fractions are higher than those of the original ores. The Trompsburg ores differ from those of the other complexes in that they are Mg-rich and are characterised by the presence of abundant olivine. The titaniferous magnetites typically exhibit well-defined ulvospinel cloth textures and are often surrounded by small amounts of graphite. They show evidence of a variety of extensive late-stage alteration features. The ores from the five investigated complexes are compared with similar ores from the Bushveld Complex. The ores from each complex can be readily distinguished on the basis of their chemical compositions and textural relationships. These features can be related to their crystallisation his tories and, in some cases, to post-crystallisation processes. The microstructural evolution of the ores from each complex is interpreted in terms of the models developed in Part I.
- Full Text:
- Date Issued: 1979
- Authors: Reynolds, Ivan Melvin
- Date: 1979
- Subjects: Igneous rocks Mineralogy
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4926 , http://hdl.handle.net/10962/d1004589
- Description: Part I consists of a detailied review of the available literature on the Fe- Ti oxides and their solid solution relationships. Particular attention is glven to the microstructures exhibited by these oxides and the hypotheses put forward to explain them. These data are synthesised and models are presented in which the microstructural developments in titaniferous magnetites amd ilmenites are explained in terms of current ideas on the influence of oxygen fugacity, exsolution mechanisms and crystal chemistry. These models have direct application to the microintergrowths observed in the naturally occurring Fe-Ti oxides from a wide range of igneous rocks. The available data on the minor and trace element chemistry of the Fe-Ti oxides are reviewed with particular reference to their variation in these minerals from different host rocks. The behaviour of the Fe-Ti oxides during secondary oxidation is discussed with particular reference to the oxidation of titaniferous magnetite and the weathering of ilmenite. The results of a mineralogical investigation into the co-existing Fe-Ti oxides from a range of igneous rocks including kimberlites, gabbros, dolerites, diabases, syenites, granophyres, granites and pegmatites are presented in Part 2 together with data on the ilmenites present in certain Eastern Cape beach sands. The kimberlite ilmenites are chemically distinct and can be readily distinguished on the basis of their relatively high MgO, Fe₂0₃ and Cr₂O₃ contents. They can also be distinguished from ilmenites from other igneous rocks on the basis of unit cell dimensions, d-spacings, reflectivities and micro-indentation hardness. The ilmenites from a wide range of basic to granitic igneous rocks exhibit a limited compositional range in which the MnO content appears to increase with increasing Si0₂ content. Relatively insensitive indirectly determined parameters such as unit cell dimensions, reflectivities and micro-indentation hardnesses cannot be used to distinguish between the ilmenites from the different rock types in these classes. The titaniferous magnetites exhibit progressively decreasing Ti0₂ contents from a maximum in the basic igneous rocks to a minimum in the granitic types. The titaniferous magnetite typically exhibits varying degrees of deuteric alteration, while the microstructures developed can be interpreted 1n terms of the models presented in Part 1. Part 3 represents an extension of Part 2 and deals with a mineralogical investigation of the titaniferous iron ores in five South African basic intrusions. The Bushveld and Kaffirskraal ores consist of multi-phase titaniferous magnetite grains containing crystallographically oriented ilmenite, ulvospinel and pleonaste microintergrowths. Minor coarser-grained ilmenite is also present. The Usushwana ores are texturally similar but contain abundant lamellar ilmenite in place of the ulvospinel. The primary features are well preserved in the unmetamorphosed Bushveld and Kaffirskraal ores. The Usushwana ores have been slightly metamorphosed resulting in the extensive replacement of the titaniferous magnetites by sphene and chlorite aggregates. The ores from these three complexes cannot be beneficiated by conventional ore-dressing techniques and require direct metallurgical treatment for the recovery of Fe, Ti0₂ and V₂O₅. The metamorphosed Mambula and Rooiwater ores have been recrystallised to a varying degrees and consist of multi-phase titaniferous magnetite grains containing modified ilmenite and pleonaste microintergrowths. These modified microstructures differ from those encountered in titaniferous magnetites from unmetnmorphosed basic rocks and their degree of modification can be related to the degree of met amorphism. Variable amounts of coarse granular ilmenite are also present and their development is related to the metamorphic grade and degree of recrystallisation. These ores can be partially beneficiated to yield ilmenite- and lower-Ti0₂ magnetite concentrates in which V₂O₅ contents of the magnetic fractions are higher than those of the original ores. The Trompsburg ores differ from those of the other complexes in that they are Mg-rich and are characterised by the presence of abundant olivine. The titaniferous magnetites typically exhibit well-defined ulvospinel cloth textures and are often surrounded by small amounts of graphite. They show evidence of a variety of extensive late-stage alteration features. The ores from the five investigated complexes are compared with similar ores from the Bushveld Complex. The ores from each complex can be readily distinguished on the basis of their chemical compositions and textural relationships. These features can be related to their crystallisation his tories and, in some cases, to post-crystallisation processes. The microstructural evolution of the ores from each complex is interpreted in terms of the models developed in Part I.
- Full Text:
- Date Issued: 1979
A comparative mineralogical and geochemical study of manganese deposits in the Postmasburg Manganese Field, South Africa
- Authors: Thokoa, Mamello
- Date: 2020
- Subjects: Manganese ores -- South Africa -- Postmasburg , Geology -- South Africa -- Postmasburg
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/167609 , vital:41496
- Description: The Postmasburg Manganese Field (PMF), located in the Northern Cape Province of South Africa, is host to some of the largest deposits of iron and manganese metal in the world. These deposits are restricted to a geographical area known as the Maremane Dome, an anticlinal structure defined by folded dolostones of the Campbellrand Subgroup and overlying ironformations of the Asbestos Hills Subgroup of the Neoarchaean-Palaeproterozoic Transvaal Supergroup. Manganese ores associated with the Maremane Dome have been divided into two major classes in the literature: the Wolhaarkop breccia-hosted massive ores of the Eastern Belt, as well as the shale-associated ores of the Western Belt. The Eastern Belt ores have been classed as siliceous in nature, while the Western Belt deposits are reported to be typically ferruginous. These divisions were made based on their varying bulk chemical and mineralogical compositions in conjunction with their different stratigraphic sub-settings. Presently, both deposit types are explained as variants of supergene mineralisation that would have formed through a combination of intense ancient lateritic weathering in the presence of oxygen, extreme residual enrichments in Mn (and Fe), and accumulations in karstic depressions at the expense of underlying manganiferous dolostones. This study revisits these deposits and their origins by sampling representative end-member examples of both Eastern Belt and Western Belt manganese ores in both drillcore (localities Khumani, McCarthy and Leeuwfontein), and outcrop sections (locality Bishop). In an attempt to provide new insights into the processes responsible for the genesis of these deposits, the possibility of hydrothermal influences and associated metasomatic replacement processes is explored in this thesis. This was achieved using standard petrographic and mineralogical techniques (transmitted and reflected light microscopy, XRD , SEM-EDS and EMPA), coupled with bulk-rock geochemical analysis of the same samples using a combination of XRF and LAICP- MS analyses. Combination of field observations, petrographic and mineralogical results, and geochemical data allowed for the re-assessment of the different ore types encountered in the field. Comparative considerations made between the bulk geochemistry of the different end-member ore types revealed no clear-cut compositional distinctions and therefore do not support existing classifications between siliceous (Eastern Belt) and ferruginous (Western Belt) ores. This is supported by trace and REE element data as well, when normalised against average shale. The geochemistry reflects the bulk mineralogy of the ores which is broadly comparable, whereby braunite and hematite appear to be dominant co-existing minerals in both Eastern Belt (Khumani) and Western Belt (Bishop) ore. In the case of the McCarthy locality, manganese ore is cryptomelane-rich and appears to have involved recent supergene overprint over Eastern Belt type ore, whereas the Leeuwfontein ores are far more ferruginous than at any other locality studied and therefore represent a more complex, hybrid type of oxide-rich Mn mineralisation (mainly bixbyitic) within massive hematite iron ore. In terms of gangue mineralogy, the ores share some close similarities through the omnipresence of barite, and the abundance of alkalirich silicate minerals. Eastern Belt ores contain abundant albite and serandite whereas the main alkali-rich phase in Western Belt ores is the mineral ephesite. In both cases, Na contents are therefore high at several wt% levels registered in selected samples. The afore-mentioned alkali enrichments have been variously reported for both these deposit types. The occurrence of high alkalis cannot be explained through classic residual or aqueous supergene systems of ore formation, as proposed in prevailing genetic models in the literature. Together with the detection of halogens such as F and Br through SEM-EDS analyses of ore from both belts, the alkali enrichments suggest possible hydrothermal processes of ore formation involving circulation of metalliferous sodic brines. Selected textural evidence from samples from both ore belts lends support to fluid-related models and allow the proposal for a common hydrothermal-replacement model to have been responsible for ore formation across the broader Maremane Dome region.
- Full Text:
- Date Issued: 2020
- Authors: Thokoa, Mamello
- Date: 2020
- Subjects: Manganese ores -- South Africa -- Postmasburg , Geology -- South Africa -- Postmasburg
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/167609 , vital:41496
- Description: The Postmasburg Manganese Field (PMF), located in the Northern Cape Province of South Africa, is host to some of the largest deposits of iron and manganese metal in the world. These deposits are restricted to a geographical area known as the Maremane Dome, an anticlinal structure defined by folded dolostones of the Campbellrand Subgroup and overlying ironformations of the Asbestos Hills Subgroup of the Neoarchaean-Palaeproterozoic Transvaal Supergroup. Manganese ores associated with the Maremane Dome have been divided into two major classes in the literature: the Wolhaarkop breccia-hosted massive ores of the Eastern Belt, as well as the shale-associated ores of the Western Belt. The Eastern Belt ores have been classed as siliceous in nature, while the Western Belt deposits are reported to be typically ferruginous. These divisions were made based on their varying bulk chemical and mineralogical compositions in conjunction with their different stratigraphic sub-settings. Presently, both deposit types are explained as variants of supergene mineralisation that would have formed through a combination of intense ancient lateritic weathering in the presence of oxygen, extreme residual enrichments in Mn (and Fe), and accumulations in karstic depressions at the expense of underlying manganiferous dolostones. This study revisits these deposits and their origins by sampling representative end-member examples of both Eastern Belt and Western Belt manganese ores in both drillcore (localities Khumani, McCarthy and Leeuwfontein), and outcrop sections (locality Bishop). In an attempt to provide new insights into the processes responsible for the genesis of these deposits, the possibility of hydrothermal influences and associated metasomatic replacement processes is explored in this thesis. This was achieved using standard petrographic and mineralogical techniques (transmitted and reflected light microscopy, XRD , SEM-EDS and EMPA), coupled with bulk-rock geochemical analysis of the same samples using a combination of XRF and LAICP- MS analyses. Combination of field observations, petrographic and mineralogical results, and geochemical data allowed for the re-assessment of the different ore types encountered in the field. Comparative considerations made between the bulk geochemistry of the different end-member ore types revealed no clear-cut compositional distinctions and therefore do not support existing classifications between siliceous (Eastern Belt) and ferruginous (Western Belt) ores. This is supported by trace and REE element data as well, when normalised against average shale. The geochemistry reflects the bulk mineralogy of the ores which is broadly comparable, whereby braunite and hematite appear to be dominant co-existing minerals in both Eastern Belt (Khumani) and Western Belt (Bishop) ore. In the case of the McCarthy locality, manganese ore is cryptomelane-rich and appears to have involved recent supergene overprint over Eastern Belt type ore, whereas the Leeuwfontein ores are far more ferruginous than at any other locality studied and therefore represent a more complex, hybrid type of oxide-rich Mn mineralisation (mainly bixbyitic) within massive hematite iron ore. In terms of gangue mineralogy, the ores share some close similarities through the omnipresence of barite, and the abundance of alkalirich silicate minerals. Eastern Belt ores contain abundant albite and serandite whereas the main alkali-rich phase in Western Belt ores is the mineral ephesite. In both cases, Na contents are therefore high at several wt% levels registered in selected samples. The afore-mentioned alkali enrichments have been variously reported for both these deposit types. The occurrence of high alkalis cannot be explained through classic residual or aqueous supergene systems of ore formation, as proposed in prevailing genetic models in the literature. Together with the detection of halogens such as F and Br through SEM-EDS analyses of ore from both belts, the alkali enrichments suggest possible hydrothermal processes of ore formation involving circulation of metalliferous sodic brines. Selected textural evidence from samples from both ore belts lends support to fluid-related models and allow the proposal for a common hydrothermal-replacement model to have been responsible for ore formation across the broader Maremane Dome region.
- Full Text:
- Date Issued: 2020
Neogene fluvial deposits along the south-west coast of South Africa understanding the palaeoclimate through proxies
- Authors: Sciscio, Lara
- Date: 2011
- Subjects: Alluvium , Paleoclimatology -- South Africa , Paleoecology -- Miocene -- South Africa , Paleobotany -- Miocene -- South Africa , Paleogeography -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4981 , http://hdl.handle.net/10962/d1005593 , Alluvium , Paleoclimatology -- South Africa , Paleoecology -- Miocene -- South Africa , Paleobotany -- Miocene -- South Africa , Paleogeography -- South Africa
- Description: Branched glycerol dialkyl glycerol tetraether (GDGTs) membrane lipids have been used as a new proxy for the reconstruction of terrestrial palaeoclimates. These biomarkers (or molecular ‗fossils‘) in conjunction with palynology, have been effective in the novel analysis of Miocene organic-rich sediments from three South African west coast sites at Rondeberg, Noordhoek and Langebaanweg. Lastly, a Quaternary south coast site at Rietvlei, South Africa, was also studied to further elucidate the extent of use of this new proxy. The fluvial peat and organic-rich deposits of the Elandsfontyn Formation (Sandveld Group) were investigated at Noordhoek, Langebaanweg and Rondeberg to provide new evidence for the climate and vegetation patterns during Miocene in this region. Drill-core and quarry samples from all four sites were freeze-dried, powered, and prepared for biogeochemical and palynological analyses. The methylation index of branched tetraethers (MBT) and cyclisation ratio of branched tetraethers (CBT) proxies were used to calculate the mean annual air temperature (MAAT) and pH values of the organic-rich horizons at time of deposition. The Branched versus isoprenoid index of tetraethers (BIT) was used to assess the relative contributions of marine archaeal and terrestrial bacterial tetraethers, and thereby assess the validity of the MBT, CBT and calculated palaeoenvironmental factors. The results presented in this thesis suggest that the use of the MBT/CBT proxy has significant potential in southern Africa, and may complement previously attempted palaeoclimatic and palaeoecological studies of Neogene-aged South African sediments. This type of research has the capacity to provide palaeoenvironmental information where other proxies may be absent. Results indicate that all sites yielded branched tetraether membrane lipids with the exception of Rondeberg, where GDGTs were below detection as a result of poor preservation conditions. Palynological investigation confirmed proxy derived temperatures. Furthermore palynomorph analyses supplemented earlier studies of the Noordhoek site and were piloted for the Rondeberg site, reaffirming alternating sequences of tropical and subtropical palynofloras. The MAATs, likewise, show variability and pronounced trends through time at the Langebaanweg and Noordhoek sites, generally corresponding with the variation and diversity of the pollen population. The terrestrial MAAT results appear to compliment Southern Hemisphere sea level changes associated with Antarctic glaciations. Additionally, this data shows a pattern similar to the Southern and Northern Hemisphere marine isotope records of relative fluctuations in the global climate and sea level change from the early to middle Miocene. The application of these past climate change indicators have been proved to be useful in the reconstruction of South Africa Miocene palaeoclimates, and may aid in understanding the consequences of climate change in the Cape region.
- Full Text:
- Date Issued: 2011
- Authors: Sciscio, Lara
- Date: 2011
- Subjects: Alluvium , Paleoclimatology -- South Africa , Paleoecology -- Miocene -- South Africa , Paleobotany -- Miocene -- South Africa , Paleogeography -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4981 , http://hdl.handle.net/10962/d1005593 , Alluvium , Paleoclimatology -- South Africa , Paleoecology -- Miocene -- South Africa , Paleobotany -- Miocene -- South Africa , Paleogeography -- South Africa
- Description: Branched glycerol dialkyl glycerol tetraether (GDGTs) membrane lipids have been used as a new proxy for the reconstruction of terrestrial palaeoclimates. These biomarkers (or molecular ‗fossils‘) in conjunction with palynology, have been effective in the novel analysis of Miocene organic-rich sediments from three South African west coast sites at Rondeberg, Noordhoek and Langebaanweg. Lastly, a Quaternary south coast site at Rietvlei, South Africa, was also studied to further elucidate the extent of use of this new proxy. The fluvial peat and organic-rich deposits of the Elandsfontyn Formation (Sandveld Group) were investigated at Noordhoek, Langebaanweg and Rondeberg to provide new evidence for the climate and vegetation patterns during Miocene in this region. Drill-core and quarry samples from all four sites were freeze-dried, powered, and prepared for biogeochemical and palynological analyses. The methylation index of branched tetraethers (MBT) and cyclisation ratio of branched tetraethers (CBT) proxies were used to calculate the mean annual air temperature (MAAT) and pH values of the organic-rich horizons at time of deposition. The Branched versus isoprenoid index of tetraethers (BIT) was used to assess the relative contributions of marine archaeal and terrestrial bacterial tetraethers, and thereby assess the validity of the MBT, CBT and calculated palaeoenvironmental factors. The results presented in this thesis suggest that the use of the MBT/CBT proxy has significant potential in southern Africa, and may complement previously attempted palaeoclimatic and palaeoecological studies of Neogene-aged South African sediments. This type of research has the capacity to provide palaeoenvironmental information where other proxies may be absent. Results indicate that all sites yielded branched tetraether membrane lipids with the exception of Rondeberg, where GDGTs were below detection as a result of poor preservation conditions. Palynological investigation confirmed proxy derived temperatures. Furthermore palynomorph analyses supplemented earlier studies of the Noordhoek site and were piloted for the Rondeberg site, reaffirming alternating sequences of tropical and subtropical palynofloras. The MAATs, likewise, show variability and pronounced trends through time at the Langebaanweg and Noordhoek sites, generally corresponding with the variation and diversity of the pollen population. The terrestrial MAAT results appear to compliment Southern Hemisphere sea level changes associated with Antarctic glaciations. Additionally, this data shows a pattern similar to the Southern and Northern Hemisphere marine isotope records of relative fluctuations in the global climate and sea level change from the early to middle Miocene. The application of these past climate change indicators have been proved to be useful in the reconstruction of South Africa Miocene palaeoclimates, and may aid in understanding the consequences of climate change in the Cape region.
- Full Text:
- Date Issued: 2011
Geological factors affecting the grade and tonnage of sandstone uranium deposits
- Authors: Holliman, K A
- Date: 1981 , 2013-03-19
- Subjects: Uranium ores , Sandstone , Geology, Economic
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5009 , http://hdl.handle.net/10962/d1005914 , Uranium ores , Sandstone , Geology, Economic
- Description: The largest known reserves of uranium are found in sandstone deposits, in the form of roll-front, peneconcordant and stacked types. Drilling on spacings of between 50 m and 5 m centres is the current method of attempting to delineate such ore bodies but because of the apparent random distribution of the mineralization there is a large degree of uncertainty in these predictions. Even on drilling grids of 3,5 m centres the uncertainty in predicting the distribution of stringer ore in roll front mineralization is still 100 per cent. (Sandefur & Grant 1980). Because of escalating costs it is becoming increasingly less economically feasible to delineate bodies of this nature in this manner and much more reliance will have to be placed on the geologist's interpretation of ore distribution when calculating ore reserves. The grade and tonnage of a sandstone uranium deposit can only be calculated with some degree of confidence if the processes forming the ore body are fully understood. The aim of this review is to examine the factors governing the formation and geometry of a sandstone body, the mobility and fixation of uranium and to establish criteria which will enable a more confident prediction to be made of the distribution of sand bodies and the distribution of the mineralization within them
- Full Text:
- Date Issued: 1981
- Authors: Holliman, K A
- Date: 1981 , 2013-03-19
- Subjects: Uranium ores , Sandstone , Geology, Economic
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5009 , http://hdl.handle.net/10962/d1005914 , Uranium ores , Sandstone , Geology, Economic
- Description: The largest known reserves of uranium are found in sandstone deposits, in the form of roll-front, peneconcordant and stacked types. Drilling on spacings of between 50 m and 5 m centres is the current method of attempting to delineate such ore bodies but because of the apparent random distribution of the mineralization there is a large degree of uncertainty in these predictions. Even on drilling grids of 3,5 m centres the uncertainty in predicting the distribution of stringer ore in roll front mineralization is still 100 per cent. (Sandefur & Grant 1980). Because of escalating costs it is becoming increasingly less economically feasible to delineate bodies of this nature in this manner and much more reliance will have to be placed on the geologist's interpretation of ore distribution when calculating ore reserves. The grade and tonnage of a sandstone uranium deposit can only be calculated with some degree of confidence if the processes forming the ore body are fully understood. The aim of this review is to examine the factors governing the formation and geometry of a sandstone body, the mobility and fixation of uranium and to establish criteria which will enable a more confident prediction to be made of the distribution of sand bodies and the distribution of the mineralization within them
- Full Text:
- Date Issued: 1981
Semi-automated extraction of structural orientation data from aerospace imagery combined with digital elevation models
- Authors: Slabber, Frans Bresler
- Date: 1996
- Subjects: Image processing , Geographic information systems , Information storage and retrieval systems -- Geology , Geology -- Data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5001 , http://hdl.handle.net/10962/d1005614 , Image processing , Geographic information systems , Information storage and retrieval systems -- Geology , Geology -- Data processing
- Description: A computer-based method for determining the orientation of planar geological structures from remotely sensed images, utilizing digital geological images and digital elevation models (DEMs), is developed and assessed. The method relies on operator skill and experience to recognize geological structure traces on images, and then employs software routines (GEOSTRUC©) to calculate the orientation of selected structures. The operator selects three points on the trace of a planar geological feature as seen on a digital geological image that is co registered with a DEM of the same area. The orientation of the plane that contains the three points is determined using vector algebra equations. The program generates an ASCII data file which contains the orientation data as well as the geographical location of the measurements. This ASCII file can then be utilized in further analysis of the orientation data. The software development kit (SDK) for TNTmips v5.00, from MicroImages Inc. and operating in the X Windows environment, was employed to construct the software. The Watcom C\C++ Development Environment was used to generate the executable program, GEOSTRUC© . GEOSTRUC© was tested in two case studies. The case studies utilized digital data derived from the use of different techniques and from different sources which varied in scale and resolution. This was done to illustrate the versatility of the program and its application to a wide range of data types. On the whole, the results obtained using the GEOSTRUC© analyses compare favourably to field data from each test area. Use of the method to determine the orientation of axial planes in the case study revealed the usefulness of the method as a powerful analytic tool for use on a macroscopic scale. The method should not he applied in area with low variation in relief as the method proved to be less accurate in these areas. Advancements in imaging technology will serve to create images with better resolution, which will, in turn, improve the overall accuracy of the method.
- Full Text:
- Date Issued: 1996
- Authors: Slabber, Frans Bresler
- Date: 1996
- Subjects: Image processing , Geographic information systems , Information storage and retrieval systems -- Geology , Geology -- Data processing
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5001 , http://hdl.handle.net/10962/d1005614 , Image processing , Geographic information systems , Information storage and retrieval systems -- Geology , Geology -- Data processing
- Description: A computer-based method for determining the orientation of planar geological structures from remotely sensed images, utilizing digital geological images and digital elevation models (DEMs), is developed and assessed. The method relies on operator skill and experience to recognize geological structure traces on images, and then employs software routines (GEOSTRUC©) to calculate the orientation of selected structures. The operator selects three points on the trace of a planar geological feature as seen on a digital geological image that is co registered with a DEM of the same area. The orientation of the plane that contains the three points is determined using vector algebra equations. The program generates an ASCII data file which contains the orientation data as well as the geographical location of the measurements. This ASCII file can then be utilized in further analysis of the orientation data. The software development kit (SDK) for TNTmips v5.00, from MicroImages Inc. and operating in the X Windows environment, was employed to construct the software. The Watcom C\C++ Development Environment was used to generate the executable program, GEOSTRUC© . GEOSTRUC© was tested in two case studies. The case studies utilized digital data derived from the use of different techniques and from different sources which varied in scale and resolution. This was done to illustrate the versatility of the program and its application to a wide range of data types. On the whole, the results obtained using the GEOSTRUC© analyses compare favourably to field data from each test area. Use of the method to determine the orientation of axial planes in the case study revealed the usefulness of the method as a powerful analytic tool for use on a macroscopic scale. The method should not he applied in area with low variation in relief as the method proved to be less accurate in these areas. Advancements in imaging technology will serve to create images with better resolution, which will, in turn, improve the overall accuracy of the method.
- Full Text:
- Date Issued: 1996
The geology, geochemistry and silicate mineralogy of the upper criticial zone of the north-western Bushveld Complex, at Rustenburg Platinum Mines, Union Section
- Authors: De Klerk, William Johan
- Date: 1982 , 2013-03-20
- Subjects: Mineralogy -- South Africa -- North-Western Transvaal , Geochemistry -- South Africa -- North-Western Transvaal , Geology -- South Africa -- North-Western Transvaal , Platinum mines and mining -- South Africa -- North-Western Transvaal , Rustenburg Platinum Mines
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5013 , http://hdl.handle.net/10962/d1006140 , Mineralogy -- South Africa -- North-Western Transvaal , Geochemistry -- South Africa -- North-Western Transvaal , Geology -- South Africa -- North-Western Transvaal , Platinum mines and mining -- South Africa -- North-Western Transvaal , Rustenburg Platinum Mines
- Description: Rustenburg Platinum Mines, Union Section, is located in the mafic phase of the north-western sector of the Bushveld Complex. This part of the Complex is characterised by transgressions of Upper zone ferrogabbros across the lower sequence of mafic rocks. These transgressions have effectively isolated a roughly triangular segment of Lower, Critical and Main zone rocks. It is in the upper part of the Critical zone that the Merensky Reef, with a strike length of 9,5 km, is found to suboutcrop below a 2-3 m black turf soil cover and it constitutes the orebody being mined at Union Section. Underground mining and development have exposed a stratigraphic succession from the Middle Group chromitites to within the lower part of the Main zone gabbros. A detailed investigation of a 100 m stratigraphic succession was undertaken in the upper part of the Critical zone, which includes the Bastard Reef, Merensky Reef, Pseudo Reef, UG 2 and UG 1 layers. Stratigraphic descriptions are presented for both a normal and potholed succession, as well as a description of pothole characteristics. The variations of Merensky Reef thickness, pothole distribution and structure of the are body are also discussed. Forty seven whole-rock major- and trace-element analyses were carried out on selected samples from both normal and potholed successions, although more emphasis was placed on the former. These samples were taken from just below the UG 1 to above the Bastard Reef. Trace elements determined included Sr, Rb, Y, Nb, Zr, Cr, Co, Ni, Cu and V. The cyclical nature of the layering is clearly defined by breaks in the trends of both the major- and trace element analyses, although some elements are strongly influenced by the modal proportions of the mai n mineral phases. Although major breaks are observed for individual elements , insignificant variation of the Mg/Mg+Fe 2 + ratio is observed throughout. New electron microprobe data are presented for the main silicate phases olivine , orthopyroxene, clinopyroxene and plagioclase , while only a limi ted number of analyses were carried out on the spine l phase. There would appear to be a reversal of the expected fractionation trend from the hanging wal l of the UG 2 to the Pseudo Marker layer. There is an upward increase of the Fo content of the olivine from F0₇₆ , ₇₋₈₁,₆ . A similar trend is observed for the orthopyroxene analyses . The Merensky unit, as a whole, exhibits a gradual decrease in the Mg end member of the Ca-poor pyroxenes from En ₇₈,₅₋₇₄ . was found to be markedly more calcic Cumulus plagioclase (An ₇₂, ₈-₈₁, ₇) than the intercumulus phase (An₅₆,₃₋₇₁, ₉) ' A further feature of the cumulus plagioclase is that strong zonation was observed with the cores of individual crystals being consistently lower in Ca relative to their margins . , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1982
- Authors: De Klerk, William Johan
- Date: 1982 , 2013-03-20
- Subjects: Mineralogy -- South Africa -- North-Western Transvaal , Geochemistry -- South Africa -- North-Western Transvaal , Geology -- South Africa -- North-Western Transvaal , Platinum mines and mining -- South Africa -- North-Western Transvaal , Rustenburg Platinum Mines
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5013 , http://hdl.handle.net/10962/d1006140 , Mineralogy -- South Africa -- North-Western Transvaal , Geochemistry -- South Africa -- North-Western Transvaal , Geology -- South Africa -- North-Western Transvaal , Platinum mines and mining -- South Africa -- North-Western Transvaal , Rustenburg Platinum Mines
- Description: Rustenburg Platinum Mines, Union Section, is located in the mafic phase of the north-western sector of the Bushveld Complex. This part of the Complex is characterised by transgressions of Upper zone ferrogabbros across the lower sequence of mafic rocks. These transgressions have effectively isolated a roughly triangular segment of Lower, Critical and Main zone rocks. It is in the upper part of the Critical zone that the Merensky Reef, with a strike length of 9,5 km, is found to suboutcrop below a 2-3 m black turf soil cover and it constitutes the orebody being mined at Union Section. Underground mining and development have exposed a stratigraphic succession from the Middle Group chromitites to within the lower part of the Main zone gabbros. A detailed investigation of a 100 m stratigraphic succession was undertaken in the upper part of the Critical zone, which includes the Bastard Reef, Merensky Reef, Pseudo Reef, UG 2 and UG 1 layers. Stratigraphic descriptions are presented for both a normal and potholed succession, as well as a description of pothole characteristics. The variations of Merensky Reef thickness, pothole distribution and structure of the are body are also discussed. Forty seven whole-rock major- and trace-element analyses were carried out on selected samples from both normal and potholed successions, although more emphasis was placed on the former. These samples were taken from just below the UG 1 to above the Bastard Reef. Trace elements determined included Sr, Rb, Y, Nb, Zr, Cr, Co, Ni, Cu and V. The cyclical nature of the layering is clearly defined by breaks in the trends of both the major- and trace element analyses, although some elements are strongly influenced by the modal proportions of the mai n mineral phases. Although major breaks are observed for individual elements , insignificant variation of the Mg/Mg+Fe 2 + ratio is observed throughout. New electron microprobe data are presented for the main silicate phases olivine , orthopyroxene, clinopyroxene and plagioclase , while only a limi ted number of analyses were carried out on the spine l phase. There would appear to be a reversal of the expected fractionation trend from the hanging wal l of the UG 2 to the Pseudo Marker layer. There is an upward increase of the Fo content of the olivine from F0₇₆ , ₇₋₈₁,₆ . A similar trend is observed for the orthopyroxene analyses . The Merensky unit, as a whole, exhibits a gradual decrease in the Mg end member of the Ca-poor pyroxenes from En ₇₈,₅₋₇₄ . was found to be markedly more calcic Cumulus plagioclase (An ₇₂, ₈-₈₁, ₇) than the intercumulus phase (An₅₆,₃₋₇₁, ₉) ' A further feature of the cumulus plagioclase is that strong zonation was observed with the cores of individual crystals being consistently lower in Ca relative to their margins . , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1982
Petrography, geochemistry and origin of atypical sedimentary-igneous contact relationships at the base of the Hotazel Formation around Middelplaats, Northern Cape Province, RSA
- Authors: Terracin, Matthew Theodore
- Date: 2014
- Subjects: Petrology -- South Africa , Geochemistry -- South Africa , Igneous rocks -- South Africa , Manganese ores -- South Africa , Manganese ores -- Geology -- South Africa , Metasomatism (Mineralogy) , Potassium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5059 , http://hdl.handle.net/10962/d1012985
- Description: In the Middelplaats mine area of the Kalahari manganese field, two drill holes (MP53 and MP54) intersected anomalously high-grade manganese ore sitting stratigraphically just above an igneous body (likely a dike or sill). Manganese ore located within approximate 5 meters of the contact with the underlying igneous rocks has been substantially metasomatically upgraded from 25 percent manganese, to over 40 percent whilst the dominant manganese species within the ore has been altered to hausmannite. This report demonstrates the metasomatic alteration is related to devolatilization (removal and/or remobilization of H₂O, CO₂ and CaO) due to contact metamorphism caused by the underlying igneous rocks. The Middelplaats mine is situated in the southwest corner of the Kalahari manganese field where the paleo basin shallows out and ends. Within the mine area, several stratigraphic units pinch out or are truncated by the side of the basin. This pinching out of lithological formations has led to the underlying Ongeluk Formation being in contact with the much younger units of the Hotazel Formation. Therefore, geochemical investigation into the nature and source of the igneous rocks was also undertaken to see if the rocks from the two drill holes were related to one another and/or the underlying Ongeluk Formation. Results of these geochemical studies have demonstrated that the Middelplaats igneous rocks (dolerites) from the two drill holes (MP53 and MP54) share a co-genetic source region. There is also reasonable geochemical evidence that the source region of the Middelplaats igneous rocks was substantially similar to the source region of the Ongeluk Formation. This may indicate that the source region of the Ongeluk Formation was reactivated at some later stage resulting in the emplacement of doleritic dikes or sills in the Middelplaats mine area. The Middelplaats igneous rocks were also found to have undergone a slight but pervasive potassic alteration; with most of the original plagioclase feldspar showing some level of replacement by a potassium enriched feldspar. Although no source for this potassic fluid was found, the devolatilization reaction within the manganese ore appears to have released some potassium into the surrounding rocks. This additional potassium may be responsible for some localized potassic alteration.
- Full Text:
- Date Issued: 2014
- Authors: Terracin, Matthew Theodore
- Date: 2014
- Subjects: Petrology -- South Africa , Geochemistry -- South Africa , Igneous rocks -- South Africa , Manganese ores -- South Africa , Manganese ores -- Geology -- South Africa , Metasomatism (Mineralogy) , Potassium
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5059 , http://hdl.handle.net/10962/d1012985
- Description: In the Middelplaats mine area of the Kalahari manganese field, two drill holes (MP53 and MP54) intersected anomalously high-grade manganese ore sitting stratigraphically just above an igneous body (likely a dike or sill). Manganese ore located within approximate 5 meters of the contact with the underlying igneous rocks has been substantially metasomatically upgraded from 25 percent manganese, to over 40 percent whilst the dominant manganese species within the ore has been altered to hausmannite. This report demonstrates the metasomatic alteration is related to devolatilization (removal and/or remobilization of H₂O, CO₂ and CaO) due to contact metamorphism caused by the underlying igneous rocks. The Middelplaats mine is situated in the southwest corner of the Kalahari manganese field where the paleo basin shallows out and ends. Within the mine area, several stratigraphic units pinch out or are truncated by the side of the basin. This pinching out of lithological formations has led to the underlying Ongeluk Formation being in contact with the much younger units of the Hotazel Formation. Therefore, geochemical investigation into the nature and source of the igneous rocks was also undertaken to see if the rocks from the two drill holes were related to one another and/or the underlying Ongeluk Formation. Results of these geochemical studies have demonstrated that the Middelplaats igneous rocks (dolerites) from the two drill holes (MP53 and MP54) share a co-genetic source region. There is also reasonable geochemical evidence that the source region of the Middelplaats igneous rocks was substantially similar to the source region of the Ongeluk Formation. This may indicate that the source region of the Ongeluk Formation was reactivated at some later stage resulting in the emplacement of doleritic dikes or sills in the Middelplaats mine area. The Middelplaats igneous rocks were also found to have undergone a slight but pervasive potassic alteration; with most of the original plagioclase feldspar showing some level of replacement by a potassium enriched feldspar. Although no source for this potassic fluid was found, the devolatilization reaction within the manganese ore appears to have released some potassium into the surrounding rocks. This additional potassium may be responsible for some localized potassic alteration.
- Full Text:
- Date Issued: 2014
Strike comparison of the compositional variations of the lower group and middle group chromitite seams of the critical zone, Western Bushveld complex
- Authors: Doig, Heather Leslie
- Date: 2000
- Subjects: Chromite -- South Africa , Geology -- South Africa , Mineralogy -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5005 , http://hdl.handle.net/10962/d1005618
- Description: The variations in the composition, specifically the Cr20 S content and the Cr:Fe ratio, and the morphology of the Lower Group (LG) and Middle Group (MG) chromitite seams of the Critical Zone (CZ) across the western Bushveld Complex, including the Ruighoek and Brits sections, is investigated by means of whole-rock chemical data, both major and trace elements analysis, XRD and electron microprobe data. As a result ofthe paucity of exposed or developed LG1 - LG5 chromitite seams in the western Bushveld Complex, this study is confined to the investigation of the compositional variations of the LG6 to MG4 chromitite seams. In only one section, the Ruighoek section, was the entire succession of chromitite seams, from the LG1 - MG4, exposed. The silicate host rocks from the LG6 pyroxenite footwall to the collar of the CC2 drillcore (lower uCZ) in the Rustenburg section were sampled. This study reviews the compositional trends of the silicate host rocks, as the compositional variations of the chromitite seams reflect the chemical evolution of the host cumulate environment and, to a lesser degree, the composition onhe interstitial mineral phases in the chromitite seams. The compositional variations of the LG and MG chromitite seams are attributed to the compositional contrast between the replenishing magma and the resident magma. The chemical trends of the LG and MG chromitite layers and the host cumUlate rOCKS do not support the existence of two compositionalfy dissimilar magmas in the CZ, rather the cyclic layering of the CZ and the chemical variations of the chromitite seams are attributed to the mixing of primitive magma with the resident magma, both of which have essentially similar compositions. The compositional variations of the LG and MG chromitite seams along strike away from the supposed feeder site (Union section) to the distal facies (Brits section) are attributed to the advanced compositional contrast between the resident magma and the replenishing primitive magma pulses. The CZ is characterized by reversals in fractionation trends and this is attributed to the compositional evolution of the parental magma and not to the replenishment of the resident magma by influxes of grossly dissimilar magma compositions. The Cr20 S content and the Cr:Fe ratio of the MG chromitite layers increase from the Ruighoek (near proximal) section to the Brits section (distal facies). This is attributed to the advanced compositional contrasts between the resident magma and the replenishing primitive magma. In contrast, the Cr20 3 content and Cr:Fe ratios ofthe LG6 and LG8a chromitite seams decreases eastwards from the Ruighoek section. The average Cr:Fe ratio for the western Bushveld Complex is between 1.5 and\2.0, nonetheless, a progressively lower Cr:Fe ratio is noted from the LG1 chromitite up through to the MG4 chromitite seam in the Ruighoek section. tn the LG2 - LG4 chromitite interval a deviation to higher.lratios is encountered. A progressive substitution of Cr by AT and Fe in the Cr-spinel crystal lattice characterizes the chromitite succession from the LG1 seam up through the chromitite succession to MG4. The petrogeneSiS of the chromitite seams of the CZ is attributed to magma mixing and fractional crystallization of a single magma type.
- Full Text:
- Date Issued: 2000
- Authors: Doig, Heather Leslie
- Date: 2000
- Subjects: Chromite -- South Africa , Geology -- South Africa , Mineralogy -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5005 , http://hdl.handle.net/10962/d1005618
- Description: The variations in the composition, specifically the Cr20 S content and the Cr:Fe ratio, and the morphology of the Lower Group (LG) and Middle Group (MG) chromitite seams of the Critical Zone (CZ) across the western Bushveld Complex, including the Ruighoek and Brits sections, is investigated by means of whole-rock chemical data, both major and trace elements analysis, XRD and electron microprobe data. As a result ofthe paucity of exposed or developed LG1 - LG5 chromitite seams in the western Bushveld Complex, this study is confined to the investigation of the compositional variations of the LG6 to MG4 chromitite seams. In only one section, the Ruighoek section, was the entire succession of chromitite seams, from the LG1 - MG4, exposed. The silicate host rocks from the LG6 pyroxenite footwall to the collar of the CC2 drillcore (lower uCZ) in the Rustenburg section were sampled. This study reviews the compositional trends of the silicate host rocks, as the compositional variations of the chromitite seams reflect the chemical evolution of the host cumulate environment and, to a lesser degree, the composition onhe interstitial mineral phases in the chromitite seams. The compositional variations of the LG and MG chromitite seams are attributed to the compositional contrast between the replenishing magma and the resident magma. The chemical trends of the LG and MG chromitite layers and the host cumUlate rOCKS do not support the existence of two compositionalfy dissimilar magmas in the CZ, rather the cyclic layering of the CZ and the chemical variations of the chromitite seams are attributed to the mixing of primitive magma with the resident magma, both of which have essentially similar compositions. The compositional variations of the LG and MG chromitite seams along strike away from the supposed feeder site (Union section) to the distal facies (Brits section) are attributed to the advanced compositional contrast between the resident magma and the replenishing primitive magma pulses. The CZ is characterized by reversals in fractionation trends and this is attributed to the compositional evolution of the parental magma and not to the replenishment of the resident magma by influxes of grossly dissimilar magma compositions. The Cr20 S content and the Cr:Fe ratio of the MG chromitite layers increase from the Ruighoek (near proximal) section to the Brits section (distal facies). This is attributed to the advanced compositional contrasts between the resident magma and the replenishing primitive magma. In contrast, the Cr20 3 content and Cr:Fe ratios ofthe LG6 and LG8a chromitite seams decreases eastwards from the Ruighoek section. The average Cr:Fe ratio for the western Bushveld Complex is between 1.5 and\2.0, nonetheless, a progressively lower Cr:Fe ratio is noted from the LG1 chromitite up through to the MG4 chromitite seam in the Ruighoek section. tn the LG2 - LG4 chromitite interval a deviation to higher.lratios is encountered. A progressive substitution of Cr by AT and Fe in the Cr-spinel crystal lattice characterizes the chromitite succession from the LG1 seam up through the chromitite succession to MG4. The petrogeneSiS of the chromitite seams of the CZ is attributed to magma mixing and fractional crystallization of a single magma type.
- Full Text:
- Date Issued: 2000
Sedimentology of plio-pleistocene gravel barrier deposits in the palaeo-Orange River mouth, Namibia : depositional history and diamond mineralisation
- Authors: Spaggiari, Renato Igino
- Date: 2011 , 2013-08-19
- Subjects: Diamond mines and mining -- Namibia Sediments (Geology) -- South Africa and Namibia -- Orange River Estuary Diamond deposits -- Namibia Orange River Estuary (Namibia and South Africa)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4927 , http://hdl.handle.net/10962/d1004636
- Description: The largest known marine diamond placer, the Namibian mega-placer, lies along the Atlantic coast of south-western Africa from the Orange River mouth 1,000 km northwards to the Namibian-Angolan border. The most economically viable portion of the Namibian mega-placer (>75 million carats recovered at >95% gem quality) comprises onshore and offshore marine deposits that are developed within ∼100km of the Orange River outfall. For much of the Cainozoic, this long-lived fluvial system has been the main conduit transporting diamonds from kimberlitic and secondary sources in the cratonic hinterland of southern Africa to the Atlantic shelf that has been neutrally buoyant over this period. Highly energetic marine processes, driven in part, by southerly winds with an attendant northward-directed longshore drift, have generated terminal placers that are preserved both onshore and offshore. This study, through detailed field sedimentological and diamond analyses, investigates the development and mineralisation of gravel barrier deposits within the ancestral Orange River mouth area during a major ∼30 m regional transgression ('30 m Package') in the Late Pliocene. At that time, diamond supply from this fluvial conduit was minimal, yet the corresponding onshore marine deposits to the north of the Orange River mouth were significantly diamond enriched, enabling large-scale alluvial diamond mining to take place for over 75 years. Of the entire coastline of south-western Africa, the most complete accumulation of the '30 m Package' is preserved within the palaeo-Orange River mouth as barrier spit and barrier beach deposits. Arranged vertically and laterally in a 16m thick succession, these are deposits of: (1) intertidal beach, (2) lagoon and washover, (3) tidal inlet and spit recurve and (4) storm-dominated subtidal settings. These were parts of larger barrier features, the bulk of which are preserved as highstand deposits that are diamond-bearing with varying, but generally low grades (<13 stones (diamonds) per hundred tons, spht). Intertidal beach and spit recurve deposits have higher economic grades (12-13 spht) due to the energetic sieving and mobile trapping mechanisms associated with their emplacement. In contrast, the less reworked and more sandy subtidal, tidal inlet and washover deposits have un-economic grades (<2 spht). Despite these low grades, the barrier deposits have the largest average stone (diamond) size (1-2 carats/stone, cts/stn) of the entire Namibian mega-placer, given their proximity to the ancestral Orange River outfall. This study demonstrates that barrier shoreline evolution at the fluvial/marine interface was controlled by: (1) a strong and coarse fluvial sediment supply that sustained shoreline growth on a highly energetic coast, (2) accommodation space facilitating sediment preservation and (3) short-duration, high-frequency sea-level cycles superimposed on the∼30 m regional transgression, promoting hierarchal stacking of progradational deposits. During these sea-level fluctuations, diamonds were 'farmed' from older, shelf sequences in the offshore and driven landward to accumulate in '30 m Package' highstand barrier deposits. In spite of the large supply of diamonds, their retention in these deposits was poor due to an incompetent footwall of ancestral Orange River mouth sediment and the inherent cobble-boulder size of the barrier gravels. Thus the principal process controlling diamond entrapment in these barrier deposits was kinetic sieving in a coarse-grained framework. Consequently, at the marine/fluvial interface and down-drift for ∼5 km, larger diamonds (1-2 cts/stn) were retained in low-grade (<2 spht), coarse-gravel barrier shorelines. Smaller diamonds (mostly < I cts/stn) were rejected into the northward-driven littoral sediments and further size-sorted along ∼95 km of Namibian coast to accumulate in finer, high-grade beach placers (> 100 spht) where bedrock footwall promoted such high concentrations. The gravel-dominated palaeo-Orange River mouth is considered to be the ' heart' of the Namibian mega-placer, controlling sediment and diamond supply to the littoral zone further north. Although coarse gravel is retained at the river mouth, the incompetence of this highly energetic setting to trap diamonds renders it sub-economic. This ineffectiveness at the fluvial/marine interface is thus fundamental in enriching the coastal tract farther down-drift and developing highly economic coastal placers along the Atlantic coast of south-western Africa. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2011
- Authors: Spaggiari, Renato Igino
- Date: 2011 , 2013-08-19
- Subjects: Diamond mines and mining -- Namibia Sediments (Geology) -- South Africa and Namibia -- Orange River Estuary Diamond deposits -- Namibia Orange River Estuary (Namibia and South Africa)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4927 , http://hdl.handle.net/10962/d1004636
- Description: The largest known marine diamond placer, the Namibian mega-placer, lies along the Atlantic coast of south-western Africa from the Orange River mouth 1,000 km northwards to the Namibian-Angolan border. The most economically viable portion of the Namibian mega-placer (>75 million carats recovered at >95% gem quality) comprises onshore and offshore marine deposits that are developed within ∼100km of the Orange River outfall. For much of the Cainozoic, this long-lived fluvial system has been the main conduit transporting diamonds from kimberlitic and secondary sources in the cratonic hinterland of southern Africa to the Atlantic shelf that has been neutrally buoyant over this period. Highly energetic marine processes, driven in part, by southerly winds with an attendant northward-directed longshore drift, have generated terminal placers that are preserved both onshore and offshore. This study, through detailed field sedimentological and diamond analyses, investigates the development and mineralisation of gravel barrier deposits within the ancestral Orange River mouth area during a major ∼30 m regional transgression ('30 m Package') in the Late Pliocene. At that time, diamond supply from this fluvial conduit was minimal, yet the corresponding onshore marine deposits to the north of the Orange River mouth were significantly diamond enriched, enabling large-scale alluvial diamond mining to take place for over 75 years. Of the entire coastline of south-western Africa, the most complete accumulation of the '30 m Package' is preserved within the palaeo-Orange River mouth as barrier spit and barrier beach deposits. Arranged vertically and laterally in a 16m thick succession, these are deposits of: (1) intertidal beach, (2) lagoon and washover, (3) tidal inlet and spit recurve and (4) storm-dominated subtidal settings. These were parts of larger barrier features, the bulk of which are preserved as highstand deposits that are diamond-bearing with varying, but generally low grades (<13 stones (diamonds) per hundred tons, spht). Intertidal beach and spit recurve deposits have higher economic grades (12-13 spht) due to the energetic sieving and mobile trapping mechanisms associated with their emplacement. In contrast, the less reworked and more sandy subtidal, tidal inlet and washover deposits have un-economic grades (<2 spht). Despite these low grades, the barrier deposits have the largest average stone (diamond) size (1-2 carats/stone, cts/stn) of the entire Namibian mega-placer, given their proximity to the ancestral Orange River outfall. This study demonstrates that barrier shoreline evolution at the fluvial/marine interface was controlled by: (1) a strong and coarse fluvial sediment supply that sustained shoreline growth on a highly energetic coast, (2) accommodation space facilitating sediment preservation and (3) short-duration, high-frequency sea-level cycles superimposed on the∼30 m regional transgression, promoting hierarchal stacking of progradational deposits. During these sea-level fluctuations, diamonds were 'farmed' from older, shelf sequences in the offshore and driven landward to accumulate in '30 m Package' highstand barrier deposits. In spite of the large supply of diamonds, their retention in these deposits was poor due to an incompetent footwall of ancestral Orange River mouth sediment and the inherent cobble-boulder size of the barrier gravels. Thus the principal process controlling diamond entrapment in these barrier deposits was kinetic sieving in a coarse-grained framework. Consequently, at the marine/fluvial interface and down-drift for ∼5 km, larger diamonds (1-2 cts/stn) were retained in low-grade (<2 spht), coarse-gravel barrier shorelines. Smaller diamonds (mostly < I cts/stn) were rejected into the northward-driven littoral sediments and further size-sorted along ∼95 km of Namibian coast to accumulate in finer, high-grade beach placers (> 100 spht) where bedrock footwall promoted such high concentrations. The gravel-dominated palaeo-Orange River mouth is considered to be the ' heart' of the Namibian mega-placer, controlling sediment and diamond supply to the littoral zone further north. Although coarse gravel is retained at the river mouth, the incompetence of this highly energetic setting to trap diamonds renders it sub-economic. This ineffectiveness at the fluvial/marine interface is thus fundamental in enriching the coastal tract farther down-drift and developing highly economic coastal placers along the Atlantic coast of south-western Africa. , KMBT_363 , Adobe Acrobat 9.54 Paper Capture Plug-in
- Full Text:
- Date Issued: 2011