Risk management : a prerequisite for the implementation of government projects by the Eastern Cape Department of Local Government
- Authors: Sojini, Sandile
- Date: 2015
- Subjects: Risk management -- South Africa -- Eastern Cape Project management -- South Africa -- Eastern Cape Local government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/2755 , vital:28073
- Description: This Research Report that this research was motivated by the fact that despite thetremendous achievements have been realized from the successful implementation ofgovernment programmes and projects related the construction and refurbishment of medical facilities, educational, bridges and road infrastructure facilities. Trends indicate that only iota of evidence implies that the concept of risk management is fully integrated and embraced as part of a culture for ensuring the successful project implementation by the Modern South African public sector organizations. Empirical research revealed that the common types of risks that have been affecting the successful implementation of government projects and programmes include: riots, fraud, corruption, changes in demographic figures, outsourcing risks, and floods and changes in weather. Most of the participants stated that risks associated with riots do not only arise from the riots within the government departments, but also in the external environment. In terms of the internal riots, they revealed that when the employees go on strike or riots on their own or in solidarity with the other trade unions, leading to the process for the implementation of government projects and programmes being affected. Yet, in certain cases, they noted that internal riots or strikes most occur as preceded by rumours that the riots by a particular union will take place and may significantly affect the ongoing process of implementation of government programmes. Besides risks associated with the internal riots by the employees and the communities, the interview findings also indicated that the other forms of risks arise from the strikes and riots by the private enterprises.
- Full Text:
- Date Issued: 2015
- Authors: Sojini, Sandile
- Date: 2015
- Subjects: Risk management -- South Africa -- Eastern Cape Project management -- South Africa -- Eastern Cape Local government -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/2755 , vital:28073
- Description: This Research Report that this research was motivated by the fact that despite thetremendous achievements have been realized from the successful implementation ofgovernment programmes and projects related the construction and refurbishment of medical facilities, educational, bridges and road infrastructure facilities. Trends indicate that only iota of evidence implies that the concept of risk management is fully integrated and embraced as part of a culture for ensuring the successful project implementation by the Modern South African public sector organizations. Empirical research revealed that the common types of risks that have been affecting the successful implementation of government projects and programmes include: riots, fraud, corruption, changes in demographic figures, outsourcing risks, and floods and changes in weather. Most of the participants stated that risks associated with riots do not only arise from the riots within the government departments, but also in the external environment. In terms of the internal riots, they revealed that when the employees go on strike or riots on their own or in solidarity with the other trade unions, leading to the process for the implementation of government projects and programmes being affected. Yet, in certain cases, they noted that internal riots or strikes most occur as preceded by rumours that the riots by a particular union will take place and may significantly affect the ongoing process of implementation of government programmes. Besides risks associated with the internal riots by the employees and the communities, the interview findings also indicated that the other forms of risks arise from the strikes and riots by the private enterprises.
- Full Text:
- Date Issued: 2015
Educators'perceptions on the contribution of South African Democratic Teachers' Union to teacher professional development
- Authors: Kwayiba, Xolile Lawrence
- Date: 2015
- Subjects: Teachers' unions Teachers -- In-service training -- South Africa -- Eastern Cape Teachers -- Training of -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/6081 , vital:29489
- Description: The purpose of the study was to investigate the educators’ perceptions on the role of the South African Democratic Teachers’ Union (SADTU) in teacher professional development. The study also investigated the Union’s perceived challenges in contributing to teacher professionalism in South Africa, their perceived professional priorities and perceived expectations of teachers. The research genre used for this study was the interpretivism or constructivism paradigm. The qualitative methodology was used and case study employed as the research design of the study. The findings of this study were that SADTU were perceived as militant activists. Their activities were perceived as often very disruptive to education and their role appeared to be more politically focused than educational. They promoted and protected teacher labour rights and interests. However, they had no programme, nor the expertise nor the resources to respond to teachers’ professional development needs. The perceptions about them were that they had minimal or negligible contribution to teacher professional development. SADTU conducted training, but with nothing of value to teacher professional development. The unethical, unconstitutional and professionally non-developmental cadre deployment of SADTU leadership compromised the Union. Another finding was the important role of appropriate continuous professional development programmes in the improvement of the teachers’ own professional development, in the improvement of classroom practices and eventual enhanced learner performance. Inclusive to professional development are educationally good skills and values to colleagues, learners and parents both at school and out of school. Recommendations for SADTU were the: development of a clear programme on Teacher Professional Development; mobilisation of SADTU members towards restoring and enhancing the dignity of the teaching profession; engaging politically in curriculum policymaking to form inclusive professional associations; ending cadre deployment for senior management posts by SADTU leadership; establish development centres for critical maths and science, computers skills and other subjects and resuscitation of teacher colleges.
- Full Text:
- Date Issued: 2015
- Authors: Kwayiba, Xolile Lawrence
- Date: 2015
- Subjects: Teachers' unions Teachers -- In-service training -- South Africa -- Eastern Cape Teachers -- Training of -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10353/6081 , vital:29489
- Description: The purpose of the study was to investigate the educators’ perceptions on the role of the South African Democratic Teachers’ Union (SADTU) in teacher professional development. The study also investigated the Union’s perceived challenges in contributing to teacher professionalism in South Africa, their perceived professional priorities and perceived expectations of teachers. The research genre used for this study was the interpretivism or constructivism paradigm. The qualitative methodology was used and case study employed as the research design of the study. The findings of this study were that SADTU were perceived as militant activists. Their activities were perceived as often very disruptive to education and their role appeared to be more politically focused than educational. They promoted and protected teacher labour rights and interests. However, they had no programme, nor the expertise nor the resources to respond to teachers’ professional development needs. The perceptions about them were that they had minimal or negligible contribution to teacher professional development. SADTU conducted training, but with nothing of value to teacher professional development. The unethical, unconstitutional and professionally non-developmental cadre deployment of SADTU leadership compromised the Union. Another finding was the important role of appropriate continuous professional development programmes in the improvement of the teachers’ own professional development, in the improvement of classroom practices and eventual enhanced learner performance. Inclusive to professional development are educationally good skills and values to colleagues, learners and parents both at school and out of school. Recommendations for SADTU were the: development of a clear programme on Teacher Professional Development; mobilisation of SADTU members towards restoring and enhancing the dignity of the teaching profession; engaging politically in curriculum policymaking to form inclusive professional associations; ending cadre deployment for senior management posts by SADTU leadership; establish development centres for critical maths and science, computers skills and other subjects and resuscitation of teacher colleges.
- Full Text:
- Date Issued: 2015
An examination of the challenges in intergrated development planning and budget alignment at Amathole District Municipality, (Eastern Cape)
- Authors: Links, Ralph Ronald
- Date: 2015
- Subjects: Municipal services -- South Africa -- Eastern Cape Local budgets -- Political aspects -- South Africa -- Eastern Cape Political participation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/3176 , vital:28329
- Description: The traditional mandate of local government is to deliver sustainable services to communities. The evolution of local government has since put more emphasis on evidence based planning in the form of IDP and sound financial management. The relationship between the IDP and Budget is that, a) the IDP contains community needs, objectives and strategies on how these will be responded or dealt with by the municipality, and b) the budget is the financial plan to execute strategies that need to be employed. The purpose of the study was to examine challenges in integrated development plan and the budget alignment of Amathole District Municipality. The study moved from the premise that municipalities are different and ADM has been in the fore front in terms of producing IDP and Budget. The study therefore is based on the assumption that the Amathole District Municipality has challenges in the IDP and Budget alignment. The study proposed to give a background of the scholarly literature of the IDP and Budget of local government. The empirical survey and research methodology used in the study is described and explained in-depths and followed by data collection in the form of the questionnaire. The research findings of the empirical survey are then analysed and reported in statistical form.
- Full Text:
- Date Issued: 2015
- Authors: Links, Ralph Ronald
- Date: 2015
- Subjects: Municipal services -- South Africa -- Eastern Cape Local budgets -- Political aspects -- South Africa -- Eastern Cape Political participation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/3176 , vital:28329
- Description: The traditional mandate of local government is to deliver sustainable services to communities. The evolution of local government has since put more emphasis on evidence based planning in the form of IDP and sound financial management. The relationship between the IDP and Budget is that, a) the IDP contains community needs, objectives and strategies on how these will be responded or dealt with by the municipality, and b) the budget is the financial plan to execute strategies that need to be employed. The purpose of the study was to examine challenges in integrated development plan and the budget alignment of Amathole District Municipality. The study moved from the premise that municipalities are different and ADM has been in the fore front in terms of producing IDP and Budget. The study therefore is based on the assumption that the Amathole District Municipality has challenges in the IDP and Budget alignment. The study proposed to give a background of the scholarly literature of the IDP and Budget of local government. The empirical survey and research methodology used in the study is described and explained in-depths and followed by data collection in the form of the questionnaire. The research findings of the empirical survey are then analysed and reported in statistical form.
- Full Text:
- Date Issued: 2015
Information communication technology (ICT) community centres and agricultural development in the Eastern Cape province of South Africa: a case of Dwesa community
- Authors: Mukasi, Tafadzwa Jaquline
- Date: 2015
- Subjects: Information technology -- South Africa -- Eastern Cape Telecommunication -- South Africa -- Eastern Cape Agricultural innovations -- South Africa -- Eastern Cape Poverty -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sci
- Identifier: http://hdl.handle.net/10353/1686 , vital:27545
- Description: The development of Information Communication Technology (ICT) in rural areas has
- Full Text:
- Date Issued: 2015
- Authors: Mukasi, Tafadzwa Jaquline
- Date: 2015
- Subjects: Information technology -- South Africa -- Eastern Cape Telecommunication -- South Africa -- Eastern Cape Agricultural innovations -- South Africa -- Eastern Cape Poverty -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Soc Sci
- Identifier: http://hdl.handle.net/10353/1686 , vital:27545
- Description: The development of Information Communication Technology (ICT) in rural areas has
- Full Text:
- Date Issued: 2015
Investigating the factors affecting citizen's ability to access e-government services in Nkonkobe municipality in the Easterrn Cape province
- Authors: Ntobongwana,Nolitha
- Date: 2015
- Subjects: Internet in public administration -- South Africa -- Eastern Cape Electronic government information -- South Africa -- Eastern Cape Municipal services -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Admin
- Identifier: http://hdl.handle.net/10353/1708 , vital:27551
- Description: E-government which refers to electronic Government is the process of transformation of relationships of government with its constituents ie the citizens, the businesses and between its own organs, through the use of the tools of Information and Communications Technology (ICT). E-government services are the outcome of e-governance that come as automated services delivered through ICTs particularly Internet based applications that provide access to and delivery of information or services to the public, businesses, other agencies and governmental departments. This study seeks to examine the factors affecting citizens ability to access e-government services in Nkonkobe Municipality in the province of Eastern Cape and come with recommendations of how to address the issue. E-government services should be developed on platforms with the consideration of devices that people can have access to. The study showed that in as much as one can have cell phone that has access to internet , some website services such as home affairs enquiry applications are not accessible on a phone with a general web browser that has no Java Script capacity but has acces to internet. Therefore developing Short Message Service (SMS) based services or Unstructured Supplementary Serviuce Data (USSD) code that is available on all Globile System for Mobile (GSM) cell phones can increase accessibility of most services at a cheaper cost. The study concludes that although e-government is the future for our country and in this era of technology, much still has to be done in areas like Nkonkobe Municipality in Eastern Cape, as the citizens have no or lack appropriate tools to access the internet, and sometimes citizens are not aware of e-government services available. The research indicates that most citizens have cell phones despite the differences in handset capabilities, which therefore means that applications developed for e-government services can be ported foe accessibility to ordinary GSM cell phone including those without internet access.
- Full Text:
- Date Issued: 2015
- Authors: Ntobongwana,Nolitha
- Date: 2015
- Subjects: Internet in public administration -- South Africa -- Eastern Cape Electronic government information -- South Africa -- Eastern Cape Municipal services -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Admin
- Identifier: http://hdl.handle.net/10353/1708 , vital:27551
- Description: E-government which refers to electronic Government is the process of transformation of relationships of government with its constituents ie the citizens, the businesses and between its own organs, through the use of the tools of Information and Communications Technology (ICT). E-government services are the outcome of e-governance that come as automated services delivered through ICTs particularly Internet based applications that provide access to and delivery of information or services to the public, businesses, other agencies and governmental departments. This study seeks to examine the factors affecting citizens ability to access e-government services in Nkonkobe Municipality in the province of Eastern Cape and come with recommendations of how to address the issue. E-government services should be developed on platforms with the consideration of devices that people can have access to. The study showed that in as much as one can have cell phone that has access to internet , some website services such as home affairs enquiry applications are not accessible on a phone with a general web browser that has no Java Script capacity but has acces to internet. Therefore developing Short Message Service (SMS) based services or Unstructured Supplementary Serviuce Data (USSD) code that is available on all Globile System for Mobile (GSM) cell phones can increase accessibility of most services at a cheaper cost. The study concludes that although e-government is the future for our country and in this era of technology, much still has to be done in areas like Nkonkobe Municipality in Eastern Cape, as the citizens have no or lack appropriate tools to access the internet, and sometimes citizens are not aware of e-government services available. The research indicates that most citizens have cell phones despite the differences in handset capabilities, which therefore means that applications developed for e-government services can be ported foe accessibility to ordinary GSM cell phone including those without internet access.
- Full Text:
- Date Issued: 2015
Synthesis, characterization & application of visible light responsive nitrogen doped Tio2 and copolymer-grafted asymmetric membranes with ozonolysis for water treatment
- Authors: Mungondori, Henry H
- Date: 2015
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11350 , http://hdl.handle.net/10353/d1020257
- Description: The use of titanium dioxide for the photo-catalytic removal of organic, inorganic, and microbial pollutants from natural water and wastewater has been considered a very promising technique. The aim of this study was to prepare nitrogen doped titanium dioxide, immobilize it on asymmetric polymeric membranes of poly (methacrylic acid) grafted onto poly (vinylidene difluoride) (PVDF) blended with poly (acrylonitrile) (PAN), and evaluate the photo-catalytic, antimicrobial, and antifouling properties of the membranes. Nitrogen doped titanium dioxide (N-TiO2) nano-particles were prepared by a low temperature sol gel synthesis technique. The modification of TiO2 with nitrogen allows photo-sensitization of the photo-catalyst towards visible light utilization. The N-TiO2 nano-particles were characterized by fourier transform infrared spectroscopy (FT-IR), scanning x-ray photoelectron spectroscopy (SXPS), X-ray diffraction analysis (XRD), diffuse reflectance spectroscopy (DRS), Brunauer Emmett Teller (BET) surface area analysis, and transmission electron microscopy (TEM). The characterizations revealed the presence of the expected functional groups and confirmed successful doping and that the product was visible light responsive. Novel poly (methacrylic acid) grafted onto poly (vinylidene difluoride)/ poly (acrylonitrile) (PMAA-g-PVDF/ PAN) asymmetric membranes were prepared by the dry-wet phase inversion technique. The poly (methacrylic acid) (PMAA) side chains where grafted onto an activated PVDF backbone by reversible addition fragmentation chain transfer (RAFT) polymerization. The photo-catalytic membranes were generated by blending N-TiO2 with the polymer solution before casting the membranes. The membranes were characterized by FT-IR, nuclear magnetic resonance spectroscopy (NMR), scanning electron microscopy (SEM), and thermo-gravimetric analysis (TGA). FT-IR and NMR analyses confirmed successful grafting of MAA chains onto PVDF while SEM confirmed the successful preparation of membranes with asymmetric structure. The efficacy of the photo-catalytic asymmetric membranes was evaluated on the removal of herbicides from synthetic water. Bentazon was easily degraded while atrazine and paraquat were recalcitrant and proved difficult to degrade. The best results were observed with 3 % N-TiO2-PMAA-g-PVDF/ PAN asymmetric membranes on the photo-degradation of bentazon, atrazine and paraquat in water. Significant enhancement in the photo-degradation of the three herbicides was observed when photo-catalytic degradation was coupled with ozonation. Liquid chromatography-mass spectrometry (LC-MS) analysis confirmed the presence of a degradation by-product during the photo-catalytic degradation of bentazon. The photo-catalytic membranes were also evaluated on the photo-catalytic reduction of heavy metals Pb2+ and Fe3+ in water, and the best results were obtained using 1 % N-TiO2-PMAA-g-PVDF/ PAN and 1 % N-TiO2-PAN asymmetric membranes. All prepared photo-catalytic membranes where capable of completely inactivating E. coli ATCC 8739 within 120 minutes of exposure and inactivation rate increased with increasing N-TiO2 photo-catalyst loading. However, there was an indication from the results obtained that N-TiO2 supported on PMAA-g-PVDF/ PAN showed a higher inactivation rate of E. coli ATCC 8739 compared to N-TiO2-PAN and N-TiO2-PVDF membranes. The 1 % N-TiO2-PMAA-g-PVDF/ PAN membranes gave the highest pure water flux (421.83 L/m2h). This increase (PVDF = 30.50 L/m2h, PAN = 73.85 L/m2h) in pure water flux is owedb to PMAA grafting as well as addition of N-TiO2. These modifications resulted in an increased membrane surface hydrophilicity, which promoted permeation of pure water through the membrane structure. A high bovine serum albumin (BSA) rejection (76.5 %) was noted and can be attributed to steric hindrance brought about by PMAA side chains which prevented the bulky BSA molecules from attaching to the membrane surface for PMAA-g-PVDF/ PAN membranes. However, the supporting porous sub-layer of an asymmetric membrane seemed to play a very important role in the overall permeability of a membrane. PVDF membranes are highly hydrophobic hence they gave a very low pure water flux.
- Full Text:
- Date Issued: 2015
- Authors: Mungondori, Henry H
- Date: 2015
- Language: English
- Type: Thesis , Doctoral , PhD (Chemistry)
- Identifier: vital:11350 , http://hdl.handle.net/10353/d1020257
- Description: The use of titanium dioxide for the photo-catalytic removal of organic, inorganic, and microbial pollutants from natural water and wastewater has been considered a very promising technique. The aim of this study was to prepare nitrogen doped titanium dioxide, immobilize it on asymmetric polymeric membranes of poly (methacrylic acid) grafted onto poly (vinylidene difluoride) (PVDF) blended with poly (acrylonitrile) (PAN), and evaluate the photo-catalytic, antimicrobial, and antifouling properties of the membranes. Nitrogen doped titanium dioxide (N-TiO2) nano-particles were prepared by a low temperature sol gel synthesis technique. The modification of TiO2 with nitrogen allows photo-sensitization of the photo-catalyst towards visible light utilization. The N-TiO2 nano-particles were characterized by fourier transform infrared spectroscopy (FT-IR), scanning x-ray photoelectron spectroscopy (SXPS), X-ray diffraction analysis (XRD), diffuse reflectance spectroscopy (DRS), Brunauer Emmett Teller (BET) surface area analysis, and transmission electron microscopy (TEM). The characterizations revealed the presence of the expected functional groups and confirmed successful doping and that the product was visible light responsive. Novel poly (methacrylic acid) grafted onto poly (vinylidene difluoride)/ poly (acrylonitrile) (PMAA-g-PVDF/ PAN) asymmetric membranes were prepared by the dry-wet phase inversion technique. The poly (methacrylic acid) (PMAA) side chains where grafted onto an activated PVDF backbone by reversible addition fragmentation chain transfer (RAFT) polymerization. The photo-catalytic membranes were generated by blending N-TiO2 with the polymer solution before casting the membranes. The membranes were characterized by FT-IR, nuclear magnetic resonance spectroscopy (NMR), scanning electron microscopy (SEM), and thermo-gravimetric analysis (TGA). FT-IR and NMR analyses confirmed successful grafting of MAA chains onto PVDF while SEM confirmed the successful preparation of membranes with asymmetric structure. The efficacy of the photo-catalytic asymmetric membranes was evaluated on the removal of herbicides from synthetic water. Bentazon was easily degraded while atrazine and paraquat were recalcitrant and proved difficult to degrade. The best results were observed with 3 % N-TiO2-PMAA-g-PVDF/ PAN asymmetric membranes on the photo-degradation of bentazon, atrazine and paraquat in water. Significant enhancement in the photo-degradation of the three herbicides was observed when photo-catalytic degradation was coupled with ozonation. Liquid chromatography-mass spectrometry (LC-MS) analysis confirmed the presence of a degradation by-product during the photo-catalytic degradation of bentazon. The photo-catalytic membranes were also evaluated on the photo-catalytic reduction of heavy metals Pb2+ and Fe3+ in water, and the best results were obtained using 1 % N-TiO2-PMAA-g-PVDF/ PAN and 1 % N-TiO2-PAN asymmetric membranes. All prepared photo-catalytic membranes where capable of completely inactivating E. coli ATCC 8739 within 120 minutes of exposure and inactivation rate increased with increasing N-TiO2 photo-catalyst loading. However, there was an indication from the results obtained that N-TiO2 supported on PMAA-g-PVDF/ PAN showed a higher inactivation rate of E. coli ATCC 8739 compared to N-TiO2-PAN and N-TiO2-PVDF membranes. The 1 % N-TiO2-PMAA-g-PVDF/ PAN membranes gave the highest pure water flux (421.83 L/m2h). This increase (PVDF = 30.50 L/m2h, PAN = 73.85 L/m2h) in pure water flux is owedb to PMAA grafting as well as addition of N-TiO2. These modifications resulted in an increased membrane surface hydrophilicity, which promoted permeation of pure water through the membrane structure. A high bovine serum albumin (BSA) rejection (76.5 %) was noted and can be attributed to steric hindrance brought about by PMAA side chains which prevented the bulky BSA molecules from attaching to the membrane surface for PMAA-g-PVDF/ PAN membranes. However, the supporting porous sub-layer of an asymmetric membrane seemed to play a very important role in the overall permeability of a membrane. PVDF membranes are highly hydrophobic hence they gave a very low pure water flux.
- Full Text:
- Date Issued: 2015
Unravelling the myths about unplanned pregnancy among female students at University of Fort Hare East London Campus, South Africa
- Authors: Chukwunyere , Amadi P
- Date: 2015
- Subjects: Unwanted pregnancy , Women college students , College students
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10353/25415 , vital:64237
- Description: This research study examined: 1. the attitudes and perceptions of female university students towards unplanned pregnancies, their (pregnancies’) associated influences and their social economic consequences on the participants and their family. 2. The level of knowledge, the sources thereof, and the girls’ attitudes and perceptions toward contraception, abortion and their actual use as possible barriers in the prevention of unplanned pregnancies. 3. The possible interventions in curbing the phenomenon of unplanned pregnancies. Data for the study was gathered through in-depth-interviews with ten female undergraduate students at the University of Fort Hare in East London campus, who had the experience of unplanned pregnancy while studying. Selection of participants was done through snowball sampling. A number of factors responsible for the unplanned pregnancy are revealed, including: Inadequate and inconsistent use of contraceptives, ignorance about contraception or rejection of contraceptive use due to religious beliefs. Influential factors regarding unplanned child bearing include: The role of the mother and the boyfriend, traditional and religious beliefs, and the desire for child bearing and motherhood. Although the majority of the girls are knowledgeable about contraception, and their right to abortion, a number of barriers hinder them from putting this knowledge into practical use. Some of the most highlighted consequences of unplanned/unwanted pregnancy are the financial burden on the family and loss of study time. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2015
- Full Text:
- Date Issued: 2015
- Authors: Chukwunyere , Amadi P
- Date: 2015
- Subjects: Unwanted pregnancy , Women college students , College students
- Language: English
- Type: text
- Identifier: http://hdl.handle.net/10353/25415 , vital:64237
- Description: This research study examined: 1. the attitudes and perceptions of female university students towards unplanned pregnancies, their (pregnancies’) associated influences and their social economic consequences on the participants and their family. 2. The level of knowledge, the sources thereof, and the girls’ attitudes and perceptions toward contraception, abortion and their actual use as possible barriers in the prevention of unplanned pregnancies. 3. The possible interventions in curbing the phenomenon of unplanned pregnancies. Data for the study was gathered through in-depth-interviews with ten female undergraduate students at the University of Fort Hare in East London campus, who had the experience of unplanned pregnancy while studying. Selection of participants was done through snowball sampling. A number of factors responsible for the unplanned pregnancy are revealed, including: Inadequate and inconsistent use of contraceptives, ignorance about contraception or rejection of contraceptive use due to religious beliefs. Influential factors regarding unplanned child bearing include: The role of the mother and the boyfriend, traditional and religious beliefs, and the desire for child bearing and motherhood. Although the majority of the girls are knowledgeable about contraception, and their right to abortion, a number of barriers hinder them from putting this knowledge into practical use. Some of the most highlighted consequences of unplanned/unwanted pregnancy are the financial burden on the family and loss of study time. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2015
- Full Text:
- Date Issued: 2015
Socio-economic factors influencing the adoption of in-field rainwater harvesting technololgy for enhancing household food security by small holder farmers in the Nkonkobe Municipality, Eastern Cape Province
- Shange, Nomfundo Sinethemba Queen
- Authors: Shange, Nomfundo Sinethemba Queen
- Date: 2015
- Subjects: Farms, Small -- South Africa -- Eastern Cape , Water harvesting -- South Africa -- Eastern Cape , Sustainable agriculture -- South Africa -- Eastern Cape , Water resources development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: http://hdl.handle.net/10353/734 , vital:26492 , Farms, Small -- South Africa -- Eastern Cape , Water harvesting -- South Africa -- Eastern Cape , Sustainable agriculture -- South Africa -- Eastern Cape , Water resources development -- South Africa -- Eastern Cape
- Description: Infield rainwater harvesting (IRWH) technology has been used in arid and semi-arid parts of the world and promising results have been achieved in terms of increasing yield. The main aim of this study was to identify socio-economic factors determining the adoption of IRWH technology for enhancing household food security by smallholder farmers. The specific objectives were to assess the level of adoption of IRWH technology using descriptive statistics (mean, frequency and percentages). To determine socio-economic factors influencing adoption of IRWH technology, the binary logistic regression mode l was used. To determine whether adopters of IRWH technology are more food secure than non-adopters, the Household Dietary Diversity Score (HDDS) was used as a measure for household food security. For the same objective, to determine socio-economic factors that influence household food security, the binary logistic regression model was also used and adoption of IRWH technology became an independent variable. The study was conducted in Khayalethu, Guquka and Krwakrwa villages in Nkonkobe Municipality in the Eastern Cape Province (EC). The unit of analysis was the individual smallholder farmers practicing agriculture. The availability (accidental) and snowball sampling techniques were used to select 34, 23, 63 respondents from Khayalethu, Guquka and Krwakrwa villages respectively. Since they are non-random, these sampling methods are problematic because of sampling errors. Overall, a sample size of 120 smallholder farmers was targeted for the interviews. Primary and secondary data collected was coded and analysed using statistical package for social sciences (SPSS) version 21. Results were presented using graphs, pie charts and tables (including cross-tables). The descriptive results showed that adoption status of IRWH technology was low in these areas, with 79% not adopting the technology. Food insecurity was high amongst the non-adopters with 86%. On the basis of descriptive analysis it can be concluded that any change in each one of the significant variables can significantly influence the probability of adopting IRWH technology and household food security. The results from the logistic regression model for the incidence of adoption revealed that 6 out of 16 variables were significant, three at 1% (access to extension services, access to information and farmers’ perception towards the IRWH technology); one at 5% (access to market) and two at 10% (access to hired labour and farm income). For the incidence of household food security, out of 17 variables, 6 were significant, three at 1% (adoption of the IRWH technology, access to extension services and farmers’ perception towards the IRWH technology); two at 5% (access to hired labour and household income) and one at 10% (household size). The empirical findings of this study indicate that there are socio-economic factors influencing adoption of IRWH technology and household food security amongst smallholder farmers. This study recommends that the government should provide extension officers and research stations with the capacity, support and physical means to expose smallholder farmers to the IRWH technology through demonstrations and trainings. The government can also introduce agricultural finance institutions in rural areas to assist the rural smallholder farmers to increase their access to credit. Further, it is recommended that smallholder farmers can expand to the communal croplands in order to gain more land size and work as a co-operative or as an association to ease labour constraints.
- Full Text:
- Date Issued: 2015
- Authors: Shange, Nomfundo Sinethemba Queen
- Date: 2015
- Subjects: Farms, Small -- South Africa -- Eastern Cape , Water harvesting -- South Africa -- Eastern Cape , Sustainable agriculture -- South Africa -- Eastern Cape , Water resources development -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: http://hdl.handle.net/10353/734 , vital:26492 , Farms, Small -- South Africa -- Eastern Cape , Water harvesting -- South Africa -- Eastern Cape , Sustainable agriculture -- South Africa -- Eastern Cape , Water resources development -- South Africa -- Eastern Cape
- Description: Infield rainwater harvesting (IRWH) technology has been used in arid and semi-arid parts of the world and promising results have been achieved in terms of increasing yield. The main aim of this study was to identify socio-economic factors determining the adoption of IRWH technology for enhancing household food security by smallholder farmers. The specific objectives were to assess the level of adoption of IRWH technology using descriptive statistics (mean, frequency and percentages). To determine socio-economic factors influencing adoption of IRWH technology, the binary logistic regression mode l was used. To determine whether adopters of IRWH technology are more food secure than non-adopters, the Household Dietary Diversity Score (HDDS) was used as a measure for household food security. For the same objective, to determine socio-economic factors that influence household food security, the binary logistic regression model was also used and adoption of IRWH technology became an independent variable. The study was conducted in Khayalethu, Guquka and Krwakrwa villages in Nkonkobe Municipality in the Eastern Cape Province (EC). The unit of analysis was the individual smallholder farmers practicing agriculture. The availability (accidental) and snowball sampling techniques were used to select 34, 23, 63 respondents from Khayalethu, Guquka and Krwakrwa villages respectively. Since they are non-random, these sampling methods are problematic because of sampling errors. Overall, a sample size of 120 smallholder farmers was targeted for the interviews. Primary and secondary data collected was coded and analysed using statistical package for social sciences (SPSS) version 21. Results were presented using graphs, pie charts and tables (including cross-tables). The descriptive results showed that adoption status of IRWH technology was low in these areas, with 79% not adopting the technology. Food insecurity was high amongst the non-adopters with 86%. On the basis of descriptive analysis it can be concluded that any change in each one of the significant variables can significantly influence the probability of adopting IRWH technology and household food security. The results from the logistic regression model for the incidence of adoption revealed that 6 out of 16 variables were significant, three at 1% (access to extension services, access to information and farmers’ perception towards the IRWH technology); one at 5% (access to market) and two at 10% (access to hired labour and farm income). For the incidence of household food security, out of 17 variables, 6 were significant, three at 1% (adoption of the IRWH technology, access to extension services and farmers’ perception towards the IRWH technology); two at 5% (access to hired labour and household income) and one at 10% (household size). The empirical findings of this study indicate that there are socio-economic factors influencing adoption of IRWH technology and household food security amongst smallholder farmers. This study recommends that the government should provide extension officers and research stations with the capacity, support and physical means to expose smallholder farmers to the IRWH technology through demonstrations and trainings. The government can also introduce agricultural finance institutions in rural areas to assist the rural smallholder farmers to increase their access to credit. Further, it is recommended that smallholder farmers can expand to the communal croplands in order to gain more land size and work as a co-operative or as an association to ease labour constraints.
- Full Text:
- Date Issued: 2015
A comparative economic analysis of small scale tobacco production under contract and non-contract farming : the case of Marondera rural district, Mashonaland East province, Zimbabwe
- Authors: Ruzhani, Freddy
- Date: 2015
- Subjects: Farms, Small -- Zimbabwe Tobacco industry -- Zimbabwe Farmers -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12653 , vital:39296
- Description: Constitutionalism and separation of powers is the most dynamic topic worldwide. Montesquieu, the French philosopher is credited with the doctrine of separation of powers. Various countries adopted the doctrine and modified it, in order to fit their systems of governments. The reason behind is that there is no universally recognized model of separation of powers or one size fit all. Countries apply this doctrine differently in a fashion that fits their domestic laws and constitutional requirements. Montesquieu gave a classic exposition and the rationale for separation of powers in one of his well-celebrated work “The Spirit of Laws”. The concept of separation of powers emerged premised on the theory that the arms of state namely, the judiciary, the legislature and the executive, should operate within their providence without one interfering with the other. From the South African perspective, the Constitution of South Africa of 1996 requires separation of powers even though it is not explicitly so stated in the text. This research examines the unique South African model of separation of powers and how the courts have navigated through it from the time the Constitution was promulgated. It seeks to establish whether or not a South African model of separation of powers has come to the fore. The research further examines the problem of interference amongst the arms of state and mechanism of checks and balances which can be applied to prevent or minimise such interference. In doing so, the study pursued a desktop survey of primary and secondary materials, including scientific literature, legislation, courts’ jurisprudence, and official documents. A comparative perspective was also made in order to learn from the experiences of other jurisdictions where the doctrine is applied. The findings reveal that South Africa has a unique model of separation of powers. The model was learned and enriched from various foreign jurisdictions. The courts have contributed enormously to this model, which contrive to be fluid and living.
- Full Text:
- Date Issued: 2015
- Authors: Ruzhani, Freddy
- Date: 2015
- Subjects: Farms, Small -- Zimbabwe Tobacco industry -- Zimbabwe Farmers -- Zimbabwe
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/12653 , vital:39296
- Description: Constitutionalism and separation of powers is the most dynamic topic worldwide. Montesquieu, the French philosopher is credited with the doctrine of separation of powers. Various countries adopted the doctrine and modified it, in order to fit their systems of governments. The reason behind is that there is no universally recognized model of separation of powers or one size fit all. Countries apply this doctrine differently in a fashion that fits their domestic laws and constitutional requirements. Montesquieu gave a classic exposition and the rationale for separation of powers in one of his well-celebrated work “The Spirit of Laws”. The concept of separation of powers emerged premised on the theory that the arms of state namely, the judiciary, the legislature and the executive, should operate within their providence without one interfering with the other. From the South African perspective, the Constitution of South Africa of 1996 requires separation of powers even though it is not explicitly so stated in the text. This research examines the unique South African model of separation of powers and how the courts have navigated through it from the time the Constitution was promulgated. It seeks to establish whether or not a South African model of separation of powers has come to the fore. The research further examines the problem of interference amongst the arms of state and mechanism of checks and balances which can be applied to prevent or minimise such interference. In doing so, the study pursued a desktop survey of primary and secondary materials, including scientific literature, legislation, courts’ jurisprudence, and official documents. A comparative perspective was also made in order to learn from the experiences of other jurisdictions where the doctrine is applied. The findings reveal that South Africa has a unique model of separation of powers. The model was learned and enriched from various foreign jurisdictions. The courts have contributed enormously to this model, which contrive to be fluid and living.
- Full Text:
- Date Issued: 2015
An assessment of the Auditor General's contribution to good governance in the public service: a case of the Eastern Cape provincial administration
- Authors: Khashe, Sivuyile Churchill
- Date: 2015
- Subjects: Auditing -- South Africa -- Eastern Cape , Civil service -- South Africa -- Eastern Cape Finance, Public -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/1654 , vital:27500
- Description: The Office of the Auditor -General’s role is by no means minor, for it plays a major role in curbing corruption and acts as a ‘’watchdog’’ of the nation over public funds. Amidst high mismanagement and misuse of public resources, as well as corruption, especially in developing countries, the major question one asks is how effective the Auditor -General can be in ensuring good governance within state departments so as to improve service delivery. The gaps between approved budgets and the realisation of policy and development goals stand among key governance challenges in many developing countries. Supreme Audit Institutions (SAIs) play an important role in holding governments to account. However, many SAIs including AGSA face serious challenges when trying to evaluate the expenditures and performance of government agencies. Therefore this study suggests that more resources should be invested in the office of the AG so as to allow it to carry out its duties without impediments. Good governance and public finance accountability is becoming increasingly important in the public sector. One means of effecting good governance and accountability is through auditing. For this reason the Office of the Auditor-General through the Constitution of the Republic of South Africa 1996 (Act 108 of 1996 section 216 (1)) was established to facilitate and encourage good governance and effective accountability through auditing.
- Full Text:
- Date Issued: 2015
- Authors: Khashe, Sivuyile Churchill
- Date: 2015
- Subjects: Auditing -- South Africa -- Eastern Cape , Civil service -- South Africa -- Eastern Cape Finance, Public -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MPA
- Identifier: http://hdl.handle.net/10353/1654 , vital:27500
- Description: The Office of the Auditor -General’s role is by no means minor, for it plays a major role in curbing corruption and acts as a ‘’watchdog’’ of the nation over public funds. Amidst high mismanagement and misuse of public resources, as well as corruption, especially in developing countries, the major question one asks is how effective the Auditor -General can be in ensuring good governance within state departments so as to improve service delivery. The gaps between approved budgets and the realisation of policy and development goals stand among key governance challenges in many developing countries. Supreme Audit Institutions (SAIs) play an important role in holding governments to account. However, many SAIs including AGSA face serious challenges when trying to evaluate the expenditures and performance of government agencies. Therefore this study suggests that more resources should be invested in the office of the AG so as to allow it to carry out its duties without impediments. Good governance and public finance accountability is becoming increasingly important in the public sector. One means of effecting good governance and accountability is through auditing. For this reason the Office of the Auditor-General through the Constitution of the Republic of South Africa 1996 (Act 108 of 1996 section 216 (1)) was established to facilitate and encourage good governance and effective accountability through auditing.
- Full Text:
- Date Issued: 2015
Factors affecting participation rates in farming in the rural areas of South Africa: case of Amathole District Municipality
- Authors: Zamxaka, Xolisa
- Date: 2015
- Subjects: Agricultural systems -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Farms, Small -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11233 , http://hdl.handle.net/10353/d1021291 , Agricultural systems -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Farms, Small -- South Africa -- Eastern Cape
- Description: South Africa and the rest of developing countries are faced with poverty and poor rural development. Rural participation in agricultural activities is one of the components that can be used to address the poverty challenge facing the people residing in rural areas. The broad objective of this research is to determine factors affecting participation rate in farming in the rural areas of Amathole District Municipality of Eastern Cape. In this study stratified random sampling method was applied in order to choose a sample out of 30 households that were interviewed 13 people belonged to Participants and 17 people belonged to non-Participants. The results from this study show that women participate a lot in farming activities. The multiple regression model was used to test the participation rates of the people in Amathole region specifically Phumlani area. A number of variables were considered in this study to assess the impact of different variables on participation in farming activities. The results showed that about 57% of the respondents are not participating in farming while 43% of the respondents participate. The farming participants that were interviewed all claim that there is a lack in farming support in the area. When there is no support of any kind, rural people would not be motivated to start development projects on their own. Consequently, this lack of farming support in the Phumlani area may have an influence on the number of farming participants. Therefore, the lack of support in the area may serve as a motivation for non-participants not to be influenced to farm. Rural farming needs to be promoted amongst the youth so as to protect and sustain agricultural growth in rural areas. The study has discovered that the youth of Phumlani is not actively involved in farming activities. Government can provide community members with farming resources so as to promote farming in the area. It would be wiser for the government to provide physical farming resources and implements rather than cash grants.
- Full Text:
- Date Issued: 2015
- Authors: Zamxaka, Xolisa
- Date: 2015
- Subjects: Agricultural systems -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Farms, Small -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc Agric (Agricultural Economics)
- Identifier: vital:11233 , http://hdl.handle.net/10353/d1021291 , Agricultural systems -- South Africa -- Eastern Cape , Rural development -- South Africa -- Eastern Cape , Sustainable development -- South Africa -- Eastern Cape , Farms, Small -- South Africa -- Eastern Cape
- Description: South Africa and the rest of developing countries are faced with poverty and poor rural development. Rural participation in agricultural activities is one of the components that can be used to address the poverty challenge facing the people residing in rural areas. The broad objective of this research is to determine factors affecting participation rate in farming in the rural areas of Amathole District Municipality of Eastern Cape. In this study stratified random sampling method was applied in order to choose a sample out of 30 households that were interviewed 13 people belonged to Participants and 17 people belonged to non-Participants. The results from this study show that women participate a lot in farming activities. The multiple regression model was used to test the participation rates of the people in Amathole region specifically Phumlani area. A number of variables were considered in this study to assess the impact of different variables on participation in farming activities. The results showed that about 57% of the respondents are not participating in farming while 43% of the respondents participate. The farming participants that were interviewed all claim that there is a lack in farming support in the area. When there is no support of any kind, rural people would not be motivated to start development projects on their own. Consequently, this lack of farming support in the Phumlani area may have an influence on the number of farming participants. Therefore, the lack of support in the area may serve as a motivation for non-participants not to be influenced to farm. Rural farming needs to be promoted amongst the youth so as to protect and sustain agricultural growth in rural areas. The study has discovered that the youth of Phumlani is not actively involved in farming activities. Government can provide community members with farming resources so as to promote farming in the area. It would be wiser for the government to provide physical farming resources and implements rather than cash grants.
- Full Text:
- Date Issued: 2015
Educators and learners perceptions on english first additional language speakers use of english as medium of instruction
- Authors: Nqoma, Lungiswa
- Date: 2015
- Subjects: English language -- Study and teaching , English language
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24934 , vital:63678
- Description: This study investigates Educators‟ and learners‟ perceptions on English first additional language speakers‟ use of English as medium of instruction in two primary schools in the East London District. The study made use of a qualitative research method which includes interviews, observation and document analysis (learners‟ books). The uncovered data is analyzed against the background of the socio-economic and historical factors that led to this medium of instruction using content analysis (CA). After the apartheid regime in 1994 and the formation of a new government in 1996, the South African Constitution declared 11 languages in an attempt to encourage multilingualism in the country with each province having its provincial language policy. In the Eastern Cape where the study is conducted the language policy recognizes Xhosa, English, and Afrikaans as the official languages with English as the medium of instruction especially at the intermediate phase. The theoretical and conceptual framework for the study is provided by studies on language policy and planning, English as an international language, and Language as a mediating tool. The findings of the study indicate the crucial role that language of instruction plays in teaching and learning. However, challenges arise when the language of instruction is not the mother tongue. The study indicates dissatisfaction in the use of EMOI as a result of inadequate proficiency in the language of instruction, school environment, lack of resources; and lack of parental support. As a result of the above, some educators resorted to code switching when teaching. Hence, the study sheds light on EFAL learner‟s perspective on both comprehension and the level of educator‟s English skills and whether there is a connection between these two aspects. This resulted to conceivable methods that could be used to improve learner performance, teaching and learning methods and the efficiency of East London District support system. , Thesis (MEd) -- Faculty of Education, 2015
- Full Text:
- Date Issued: 2015
- Authors: Nqoma, Lungiswa
- Date: 2015
- Subjects: English language -- Study and teaching , English language
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24934 , vital:63678
- Description: This study investigates Educators‟ and learners‟ perceptions on English first additional language speakers‟ use of English as medium of instruction in two primary schools in the East London District. The study made use of a qualitative research method which includes interviews, observation and document analysis (learners‟ books). The uncovered data is analyzed against the background of the socio-economic and historical factors that led to this medium of instruction using content analysis (CA). After the apartheid regime in 1994 and the formation of a new government in 1996, the South African Constitution declared 11 languages in an attempt to encourage multilingualism in the country with each province having its provincial language policy. In the Eastern Cape where the study is conducted the language policy recognizes Xhosa, English, and Afrikaans as the official languages with English as the medium of instruction especially at the intermediate phase. The theoretical and conceptual framework for the study is provided by studies on language policy and planning, English as an international language, and Language as a mediating tool. The findings of the study indicate the crucial role that language of instruction plays in teaching and learning. However, challenges arise when the language of instruction is not the mother tongue. The study indicates dissatisfaction in the use of EMOI as a result of inadequate proficiency in the language of instruction, school environment, lack of resources; and lack of parental support. As a result of the above, some educators resorted to code switching when teaching. Hence, the study sheds light on EFAL learner‟s perspective on both comprehension and the level of educator‟s English skills and whether there is a connection between these two aspects. This resulted to conceivable methods that could be used to improve learner performance, teaching and learning methods and the efficiency of East London District support system. , Thesis (MEd) -- Faculty of Education, 2015
- Full Text:
- Date Issued: 2015
Evaluation of knowledge and practices of nurses with regard to prevention of nosocomial infection in the intensive care units of Eastern Cape Province
- Mlenzana, Nosiphiwo Priscilla
- Authors: Mlenzana, Nosiphiwo Priscilla
- Date: 2015
- Subjects: Nosocomial infections http://id.loc.gov/authorities/subjects/sh85092770 , Cross infection--Prevention http://id.loc.gov/authorities/subjects/sh2009122612 , Infection http://id.loc.gov/authorities/subjects/sh85066076
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19639 , vital:43154
- Description: Aim: To determine the level of knowledge and practice of the nurses in the prevention and control of nosocomial infection in the intensive care units and make recommendations aiming at bridging the gap identified. In this study, the level of knowledge and practice of nurses in the intensive care units was described and its relationship with the demographic characteristics was examined utilising a quantitative approach. A quantitative descriptive design was used to examine and describe knowledge and practices of intensive care nurses with regards to prevention and control of nosocomial infection. One hundred and thirty (130) nurses participated in the study taken from the intensive care units of the five (5) state hospitals of the Eastern Cape Province. A self-designed questionnaire with close-ended questions was utilised comprising of dichotomous questions, with ‘yes’ or ‘no’ measuring knowledge nurses have and a Likert scale that measured knowledge with regards to clinical practice utilised in the prevention and control of nosocomial infections. The following ethical considerations were addressed by the study: ethical clearance, permission to conduct the study, informed consent from participants, anonymity and confidentiality and respect of individual autonomy. Findings: The respondents showed encouraging agreement with the different practices that should be followed in order to prevent spreading of nosocomial infections in their units. This knowledge suggests that the problem of infection control in ICUs may be related to the individual characteristics of the profession as opposed to being institutional. Limitations: Not all the intensive care units of the Eastern Cape hospitals were included due to challenges of time, finance and geographic factors. Recommendations: The following recommendations were made: Orientation programme to all new staff coming into the ICUs including infection control policies and guidelines; Involvement of the ICU staff in the development of infection control policies so as to ensure ownership and ultimate compliance; The employer must ensure that all resources for infection control and prevention are available and accessible to the health care workers at all times to ensure compliance. , Thesis (MCur) -- University of Fort Hare, 2015
- Full Text:
- Date Issued: 2015
- Authors: Mlenzana, Nosiphiwo Priscilla
- Date: 2015
- Subjects: Nosocomial infections http://id.loc.gov/authorities/subjects/sh85092770 , Cross infection--Prevention http://id.loc.gov/authorities/subjects/sh2009122612 , Infection http://id.loc.gov/authorities/subjects/sh85066076
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19639 , vital:43154
- Description: Aim: To determine the level of knowledge and practice of the nurses in the prevention and control of nosocomial infection in the intensive care units and make recommendations aiming at bridging the gap identified. In this study, the level of knowledge and practice of nurses in the intensive care units was described and its relationship with the demographic characteristics was examined utilising a quantitative approach. A quantitative descriptive design was used to examine and describe knowledge and practices of intensive care nurses with regards to prevention and control of nosocomial infection. One hundred and thirty (130) nurses participated in the study taken from the intensive care units of the five (5) state hospitals of the Eastern Cape Province. A self-designed questionnaire with close-ended questions was utilised comprising of dichotomous questions, with ‘yes’ or ‘no’ measuring knowledge nurses have and a Likert scale that measured knowledge with regards to clinical practice utilised in the prevention and control of nosocomial infections. The following ethical considerations were addressed by the study: ethical clearance, permission to conduct the study, informed consent from participants, anonymity and confidentiality and respect of individual autonomy. Findings: The respondents showed encouraging agreement with the different practices that should be followed in order to prevent spreading of nosocomial infections in their units. This knowledge suggests that the problem of infection control in ICUs may be related to the individual characteristics of the profession as opposed to being institutional. Limitations: Not all the intensive care units of the Eastern Cape hospitals were included due to challenges of time, finance and geographic factors. Recommendations: The following recommendations were made: Orientation programme to all new staff coming into the ICUs including infection control policies and guidelines; Involvement of the ICU staff in the development of infection control policies so as to ensure ownership and ultimate compliance; The employer must ensure that all resources for infection control and prevention are available and accessible to the health care workers at all times to ensure compliance. , Thesis (MCur) -- University of Fort Hare, 2015
- Full Text:
- Date Issued: 2015
Phytochemical, antibacterial and pharmacological investigations of Clausena Anisata (Wild). Hook : bone of the medicinal plants used for traditional treatment of "tuberculosis" in Eastern Cape, South Africa
- Authors: Lawal, Ibraheem O
- Date: 2015
- Subjects: Traditional medicine--South Africa--Eastern Cape Tuberculosis--Treatment--South Africa--Eastern Cape Mycobacterial diseases--South Africa--Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Ethnobotany
- Identifier: http://hdl.handle.net/10353/11828 , vital:39110
- Description: Clausena anisata (Willd) Hook, is the only species out of the 15 species of the genus found in the African continent and is regarded as a threatened species in this area of Southern region of Africa. Its distribution spread across Africa to south-east Asia. C. anisata has a wide range of ethno-pharmacological importance. Despite the numerous studies on the pharmacological profile of the plant, there is still dearth of scientific literature on the foliar micro-morphology of this valuable medicinal plant. The morphorlogical structure of the leaves of C. anisata was examined under Light Microscopy (LM), Scanning Electron Microscopy (SEM) and Energy Dispersive x-ray Spectroscopy (EDS) following standard procedures. LM indicates the types of stomata of the leaves (amphistomatic). SEM revealed the presence of the whip like trichomes with its uniqueness to the plants. EDS showed the chemical composition of the foliar appendages which indicated the presence Ca, Mg, S, and Fe. The indication of the elements could probably be helpful in the herbal drug regulation based on the mineral composition and in return reduced herbal drug toxicity.
- Full Text:
- Date Issued: 2015
- Authors: Lawal, Ibraheem O
- Date: 2015
- Subjects: Traditional medicine--South Africa--Eastern Cape Tuberculosis--Treatment--South Africa--Eastern Cape Mycobacterial diseases--South Africa--Eastern Cape
- Language: English
- Type: Thesis , Doctoral , Ethnobotany
- Identifier: http://hdl.handle.net/10353/11828 , vital:39110
- Description: Clausena anisata (Willd) Hook, is the only species out of the 15 species of the genus found in the African continent and is regarded as a threatened species in this area of Southern region of Africa. Its distribution spread across Africa to south-east Asia. C. anisata has a wide range of ethno-pharmacological importance. Despite the numerous studies on the pharmacological profile of the plant, there is still dearth of scientific literature on the foliar micro-morphology of this valuable medicinal plant. The morphorlogical structure of the leaves of C. anisata was examined under Light Microscopy (LM), Scanning Electron Microscopy (SEM) and Energy Dispersive x-ray Spectroscopy (EDS) following standard procedures. LM indicates the types of stomata of the leaves (amphistomatic). SEM revealed the presence of the whip like trichomes with its uniqueness to the plants. EDS showed the chemical composition of the foliar appendages which indicated the presence Ca, Mg, S, and Fe. The indication of the elements could probably be helpful in the herbal drug regulation based on the mineral composition and in return reduced herbal drug toxicity.
- Full Text:
- Date Issued: 2015
Through the Burtonesque looking-glass : interrogating the psychoanalytic in Tim Burton's adaptation of selected children's texts
- Authors: Van Zyl, Simone
- Date: 2015
- Subjects: Burton, Tim, -- 1958 Children's literature Psychoanalysis and literature
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10353/12304 , vital:39251
- Description: The primary aim of this thesis is to interrogate existing psychoanalytical theory, as well as to conduct research on ‘the Burtonesque’ in order to examine two of Tim Burton's filmic adaptations of classic literary works for children, namely: Alice in Wonderland (2010), an adaptation inspired by Lewis Carroll's Alice books, and Charlie and the Chocolate Factory (2005), based on Roald Dahl's novel of the same title. Firstly, the chapters will explore the psychological elements found in the original texts, which Burton amplifies in his onscreen adaptations by means of various stylistic and thematic techniques that have become known as ‘the Burtonesque’. Secondly, the ‘Burtonesque’ itself will be explored, and thirdly, by means of comparative analysis, the investigation will focus on the manner in which such aesthetics aid Burton in highlighting psychological concerns in his films, as well as interrogate his cinematic alterations to existing texts in order to further his purpose. As a keen enthusiast of psychology and having won awards within the field, Tim Burton, a foremost contemporary Hollywood filmmaker, in his adaptations of children’s classics, deliberately magnifies the psychoanalytic components that are often found in the tales. Through his unique interpretation, Burton brings the psychoanalytic approach to children’s stories to a new level. He explores certain themes such as death, childhood fantasies, psychological development and parental relationships, and makes use of specific artistic techniques that create a sense of the uncanny and defamiliarisation in the viewer. Due to his gothic cinematic approach, Burton is one of the most recognisable artists in his field, with a consistent vision that is concerned with cinematic and thematic aspects of his work, branding his films with a unique ‘Burtonesque’ quality that has become instantly identifiable. As a result of Burton’s psychological interest in children’s stories, Tim Burton’s film adaptations of the Dahl and Carroll classic children’s stories can be interrogated under a psychoanalytic lens. Psychoanalytic literary criticism is a method of literary analysis that is informed by the tradition of psychoanalysis established by Freud. In Burton scholarship, critical exploration should take the form of not only a close reading of the original text and analysis of the film version in order to come to a psychoanalytic interpretation, but by means of comparison of film and text, highlight the methods applied by psychoanalytic theory. A close comparative analysis of original literary works by Roald Dahl and Lewis Carroll, and Tim Burton’s filmic adaptations will be conducted in this study. Thereby, the manner in which Tim Burton employs specific techniques in order to emphasise the stories’ psychological components will be explored. Biographical information of Dahl and Lewis, as well as a short synopsis of their stories will be included in order to provide the context for psychoanalytical criticism. A discussion of ‘the Burtonesque’ will be provided, as well as a brief exploration of his adaptation history and Burton’s specific interest in psychology. Research methods to be applied in the analysis of the original texts and their film versions are psychoanalytic literary theory, drawing predominantly on the work of theorists: Sigmund Freud, Jacques Lacan and Carl Jung. A close examination of auteur theory, the unique voice Burton has established through his iconic cinematic techniques, now coined ‘the Burtonesque’, will also be applied to provide a fuller and rounder interrogation. The focus of this project is to investigate thempsychoanalytical elements found in the texts and films, in order to clearly illustrate how Tim Burton’s cinematic approach serves to highlight a psychoanalytic interpretation.
- Full Text:
- Date Issued: 2015
- Authors: Van Zyl, Simone
- Date: 2015
- Subjects: Burton, Tim, -- 1958 Children's literature Psychoanalysis and literature
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10353/12304 , vital:39251
- Description: The primary aim of this thesis is to interrogate existing psychoanalytical theory, as well as to conduct research on ‘the Burtonesque’ in order to examine two of Tim Burton's filmic adaptations of classic literary works for children, namely: Alice in Wonderland (2010), an adaptation inspired by Lewis Carroll's Alice books, and Charlie and the Chocolate Factory (2005), based on Roald Dahl's novel of the same title. Firstly, the chapters will explore the psychological elements found in the original texts, which Burton amplifies in his onscreen adaptations by means of various stylistic and thematic techniques that have become known as ‘the Burtonesque’. Secondly, the ‘Burtonesque’ itself will be explored, and thirdly, by means of comparative analysis, the investigation will focus on the manner in which such aesthetics aid Burton in highlighting psychological concerns in his films, as well as interrogate his cinematic alterations to existing texts in order to further his purpose. As a keen enthusiast of psychology and having won awards within the field, Tim Burton, a foremost contemporary Hollywood filmmaker, in his adaptations of children’s classics, deliberately magnifies the psychoanalytic components that are often found in the tales. Through his unique interpretation, Burton brings the psychoanalytic approach to children’s stories to a new level. He explores certain themes such as death, childhood fantasies, psychological development and parental relationships, and makes use of specific artistic techniques that create a sense of the uncanny and defamiliarisation in the viewer. Due to his gothic cinematic approach, Burton is one of the most recognisable artists in his field, with a consistent vision that is concerned with cinematic and thematic aspects of his work, branding his films with a unique ‘Burtonesque’ quality that has become instantly identifiable. As a result of Burton’s psychological interest in children’s stories, Tim Burton’s film adaptations of the Dahl and Carroll classic children’s stories can be interrogated under a psychoanalytic lens. Psychoanalytic literary criticism is a method of literary analysis that is informed by the tradition of psychoanalysis established by Freud. In Burton scholarship, critical exploration should take the form of not only a close reading of the original text and analysis of the film version in order to come to a psychoanalytic interpretation, but by means of comparison of film and text, highlight the methods applied by psychoanalytic theory. A close comparative analysis of original literary works by Roald Dahl and Lewis Carroll, and Tim Burton’s filmic adaptations will be conducted in this study. Thereby, the manner in which Tim Burton employs specific techniques in order to emphasise the stories’ psychological components will be explored. Biographical information of Dahl and Lewis, as well as a short synopsis of their stories will be included in order to provide the context for psychoanalytical criticism. A discussion of ‘the Burtonesque’ will be provided, as well as a brief exploration of his adaptation history and Burton’s specific interest in psychology. Research methods to be applied in the analysis of the original texts and their film versions are psychoanalytic literary theory, drawing predominantly on the work of theorists: Sigmund Freud, Jacques Lacan and Carl Jung. A close examination of auteur theory, the unique voice Burton has established through his iconic cinematic techniques, now coined ‘the Burtonesque’, will also be applied to provide a fuller and rounder interrogation. The focus of this project is to investigate thempsychoanalytical elements found in the texts and films, in order to clearly illustrate how Tim Burton’s cinematic approach serves to highlight a psychoanalytic interpretation.
- Full Text:
- Date Issued: 2015
An assessment of the effectiveness of school governing bodies in implementing school policy: a case study of Xengxe Junior Secondary School in King William's Town district
- Authors: Ngcuka, Zimkhita Zenith
- Date: 2015
- Subjects: School management and organization -- South Africa -- Eastern Cape School administrators -- South Africa -- Eastern Cape School boards -- South Africa -- Eastern Cape Education -- Parent participation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Admin
- Identifier: http://hdl.handle.net/10353/1719 , vital:27552
- Description: This study looks at School Governing Bodies and its role and their effectiveness in school management. In terms of the South African Schools Act, all schools are now required to have School Government Bodies to compliment the formal school administrative structures. The research looks at how these bodies have functioned in a rural context. The empirical evidence, supported by other research evidence show that even though these bodies are sometimes dutifully constituted in schools, their functionality and effectiveness remains limited due to a number of reasons. This research study has shown that the ineffectiveness of SGBs in a rural context is attributed to that following key issues- firstly, there is limited knowledge of the functions of SGB, which can be traced to the lack of training on the body member; secondly, there is a inadequate framework in many public schools to engage with the SGBs; and finally there is a lack of school resources to make effective use of these bodies.
- Full Text:
- Date Issued: 2015
- Authors: Ngcuka, Zimkhita Zenith
- Date: 2015
- Subjects: School management and organization -- South Africa -- Eastern Cape School administrators -- South Africa -- Eastern Cape School boards -- South Africa -- Eastern Cape Education -- Parent participation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Admin
- Identifier: http://hdl.handle.net/10353/1719 , vital:27552
- Description: This study looks at School Governing Bodies and its role and their effectiveness in school management. In terms of the South African Schools Act, all schools are now required to have School Government Bodies to compliment the formal school administrative structures. The research looks at how these bodies have functioned in a rural context. The empirical evidence, supported by other research evidence show that even though these bodies are sometimes dutifully constituted in schools, their functionality and effectiveness remains limited due to a number of reasons. This research study has shown that the ineffectiveness of SGBs in a rural context is attributed to that following key issues- firstly, there is limited knowledge of the functions of SGB, which can be traced to the lack of training on the body member; secondly, there is a inadequate framework in many public schools to engage with the SGBs; and finally there is a lack of school resources to make effective use of these bodies.
- Full Text:
- Date Issued: 2015
An assessment of the Auditor General's contribution to good governance in the public service: a case of the Eastern Cape provincial administration
- Authors: Khashe, Sivuyile Churchill
- Date: 2015
- Subjects: Auditing -- South Africa -- Eastern Cape Civil service -- South Africa -- Eastern Cape Public administration -- South Africa -- Eastern Cape Political corruption -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Admin
- Identifier: http://hdl.handle.net/10353/1675 , vital:27544
- Description: The Office of the Auditor -General’s role is by no means minor, for it plays a major role in curbing corruption and acts as a ‘’watchdog’’ of the nation over public funds. Amidst high mismanagement and misuse of public resources, as well as corruption, especially in developing countries, the major question one asks is how effective the Auditor -General can be in ensuring good governance within state departments so as to improve service delivery. The gaps between approved budgets and the realisation of policy and development goals stand among key governance challenges in many developing countries. Supreme Audit Institutions (SAIs) play an important role in holding governments to account. However, many SAIs including AGSA face serious challenges when trying to evaluate the expenditures and performance of government agencies. Therefore this study suggests that more resources should be invested in the office of the AG so as to allow it to carry out its duties without impediments. Good governance and public finance accountability is becoming increasingly important in the public sector. One means of effecting good governance and accountability is through auditing. For this reason the Office of the Auditor-General through the Constitution of the Republic of South Africa 1996 (Act 108 of 1996 section 216 (1)) was established to facilitate and encourage good governance and effective accountability through auditing. To this end the study assesses the contribution made by the AGSA in encouraging good governance practices in government departments in the Eastern Cape Province.
- Full Text:
- Date Issued: 2015
- Authors: Khashe, Sivuyile Churchill
- Date: 2015
- Subjects: Auditing -- South Africa -- Eastern Cape Civil service -- South Africa -- Eastern Cape Public administration -- South Africa -- Eastern Cape Political corruption -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , M Admin
- Identifier: http://hdl.handle.net/10353/1675 , vital:27544
- Description: The Office of the Auditor -General’s role is by no means minor, for it plays a major role in curbing corruption and acts as a ‘’watchdog’’ of the nation over public funds. Amidst high mismanagement and misuse of public resources, as well as corruption, especially in developing countries, the major question one asks is how effective the Auditor -General can be in ensuring good governance within state departments so as to improve service delivery. The gaps between approved budgets and the realisation of policy and development goals stand among key governance challenges in many developing countries. Supreme Audit Institutions (SAIs) play an important role in holding governments to account. However, many SAIs including AGSA face serious challenges when trying to evaluate the expenditures and performance of government agencies. Therefore this study suggests that more resources should be invested in the office of the AG so as to allow it to carry out its duties without impediments. Good governance and public finance accountability is becoming increasingly important in the public sector. One means of effecting good governance and accountability is through auditing. For this reason the Office of the Auditor-General through the Constitution of the Republic of South Africa 1996 (Act 108 of 1996 section 216 (1)) was established to facilitate and encourage good governance and effective accountability through auditing. To this end the study assesses the contribution made by the AGSA in encouraging good governance practices in government departments in the Eastern Cape Province.
- Full Text:
- Date Issued: 2015
An exploration of perceptions, adaptive capacity and food security in the Ngqushwa local municipality, Eastern Cape, South Africa
- Authors: Mazinyo, Sonwabo Perez
- Date: 2015
- Subjects: Food security -- South Africa -- Eastern Cape Climatic changes -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/19043 , vital:40107
- Description: Approximately sixty percent of Africans depend on rainfed agriculture for their livelihoods. South Africa is evidenced to be susceptible to inclement climate which impacts on rural livelihoods as well as on farming systems. While South Africa is considered to be food sufficient, it is estimated that approximately 35percent of the population is vulnerable to food insecurity. Therefore with the application of surveys and interviews this study investigates the factors influencing household, subsistence and small-scale farmer perceptions of vulnerability to climate variability as well as the determinants of adaptive capacity. A sample of 308 households is surveyed and four focus group discussions are administered in Ngqushwa Local Municipality as a case study. Furthermore, the study also focuses on the biophysical changes or factors (scientific analysis of the prevailing climatic regimes–rainfall trends); the interrogation of the impact of food systems on both food prices as well as its implications on food sovereignty. The study also interrogates the relationship between crop yield and rainfall data over a 30-year period. Therefore the study adopts a mixed method approach to ensure triangulation. The study finds that rural communities are able to perceive climate variability and its related changes as well as its negative impact on crop production, food access and availability. The perceived rainfall trends also corroborate this Pearson product-moment correlation coefficient reveals that there is a strong correlation between crop yields and rainfall (r = 0.69). Meteorological analyses also show that the rainfall trend has been significantly variable over 112 years (1900 - 2011) with several dry spells threatening the subsistence and small-scale farmers’ sustainable livelihoods. The food systems pose threats to food safety, food security and historical food sovereignty for the rural community of Ngqushwa Local Municipality. Adaptive capacity is greatly impaired by the lack of co-ordination of adaptation strategies, which communally benefit the majority of the farming respondents in the study area. Therefore vulnerability to climate variability impacts on the ability of the respondents to achieve food security. The study also finds that there is perceived competition between the farmers and wild life for the natural resources. The respondents’ perception is that climate variability and change is responsible for such competition. The study recommends that the national, provincial and local governments must foster a new food production model that is not based on the agro-business model and its attendant technologies but on one that is based on robust agro-ecological farming techniques which enhance adaptive capacity; which foster food safety; which promote food sovereignty; and which reduce vulnerability in a sustainable manner. Given the extent of climate variability in the study area the restoration of the NLM weather station infrastructure can also aid the farmers in taking advantage of a robust early warning system for better estimation of climate trends which enhance crop production.
- Full Text:
- Date Issued: 2015
- Authors: Mazinyo, Sonwabo Perez
- Date: 2015
- Subjects: Food security -- South Africa -- Eastern Cape Climatic changes -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , DPhil
- Identifier: http://hdl.handle.net/10353/19043 , vital:40107
- Description: Approximately sixty percent of Africans depend on rainfed agriculture for their livelihoods. South Africa is evidenced to be susceptible to inclement climate which impacts on rural livelihoods as well as on farming systems. While South Africa is considered to be food sufficient, it is estimated that approximately 35percent of the population is vulnerable to food insecurity. Therefore with the application of surveys and interviews this study investigates the factors influencing household, subsistence and small-scale farmer perceptions of vulnerability to climate variability as well as the determinants of adaptive capacity. A sample of 308 households is surveyed and four focus group discussions are administered in Ngqushwa Local Municipality as a case study. Furthermore, the study also focuses on the biophysical changes or factors (scientific analysis of the prevailing climatic regimes–rainfall trends); the interrogation of the impact of food systems on both food prices as well as its implications on food sovereignty. The study also interrogates the relationship between crop yield and rainfall data over a 30-year period. Therefore the study adopts a mixed method approach to ensure triangulation. The study finds that rural communities are able to perceive climate variability and its related changes as well as its negative impact on crop production, food access and availability. The perceived rainfall trends also corroborate this Pearson product-moment correlation coefficient reveals that there is a strong correlation between crop yields and rainfall (r = 0.69). Meteorological analyses also show that the rainfall trend has been significantly variable over 112 years (1900 - 2011) with several dry spells threatening the subsistence and small-scale farmers’ sustainable livelihoods. The food systems pose threats to food safety, food security and historical food sovereignty for the rural community of Ngqushwa Local Municipality. Adaptive capacity is greatly impaired by the lack of co-ordination of adaptation strategies, which communally benefit the majority of the farming respondents in the study area. Therefore vulnerability to climate variability impacts on the ability of the respondents to achieve food security. The study also finds that there is perceived competition between the farmers and wild life for the natural resources. The respondents’ perception is that climate variability and change is responsible for such competition. The study recommends that the national, provincial and local governments must foster a new food production model that is not based on the agro-business model and its attendant technologies but on one that is based on robust agro-ecological farming techniques which enhance adaptive capacity; which foster food safety; which promote food sovereignty; and which reduce vulnerability in a sustainable manner. Given the extent of climate variability in the study area the restoration of the NLM weather station infrastructure can also aid the farmers in taking advantage of a robust early warning system for better estimation of climate trends which enhance crop production.
- Full Text:
- Date Issued: 2015
Investigation into the characteristics and possible applications of biomass gasification by-products from a downdraft gasifier system
- Authors: Melapi, Aviwe
- Date: 2015
- Subjects: Biomass gasification -- South Africa -- Eastern Cape , Renewable energy sources -- South Africa -- Eastern Cape , Biomass energy -- South Africa -- Eastern Cape , Crop residue management -- South Africa -- Eastern Cape , Coal gasification -- South Africa -- Eastern Cape , Lignocellulose -- Biodegradation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11348 , http://hdl.handle.net/10353/d1020174 , Biomass gasification -- South Africa -- Eastern Cape , Renewable energy sources -- South Africa -- Eastern Cape , Biomass energy -- South Africa -- Eastern Cape , Crop residue management -- South Africa -- Eastern Cape , Coal gasification -- South Africa -- Eastern Cape , Lignocellulose -- Biodegradation -- South Africa -- Eastern Cape
- Description: Biomass gasification has attracted the interest of researchers because it produces zero carbon to the atmosphere. This technology does not only produce syngas but also the byproducts which can be used for various application depending on quality.The study conducted at Melani village in Alice in the Eastern Cape of South Africa was aimed at investigating the possible applications of the gasification byproducts instead of being thrown away. Pine wood was employed as the parent feedstock material for the gasifier. Biomass gasification by-products were then collected for further analysis. The studied by-products included tar(condensate), char, soot and resin. These materials were also blended to produce strong materials.The essence of the blending was to generate ideal material that is strong but light at the same time.The elemental analysis of the samples performed by CHNS analyser revealed that carbon element is in large quantities in all samples. The FTIR spectra showed almost similar results for all the studied samples, since the samples are end products of lignocellulosegasification. SEM gave the sticky images of resin as well as porous char structures. Char showed a higher heating value of 35.37MJ/Kg when compared to other by-products samples.
- Full Text:
- Date Issued: 2015
- Authors: Melapi, Aviwe
- Date: 2015
- Subjects: Biomass gasification -- South Africa -- Eastern Cape , Renewable energy sources -- South Africa -- Eastern Cape , Biomass energy -- South Africa -- Eastern Cape , Crop residue management -- South Africa -- Eastern Cape , Coal gasification -- South Africa -- Eastern Cape , Lignocellulose -- Biodegradation -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11348 , http://hdl.handle.net/10353/d1020174 , Biomass gasification -- South Africa -- Eastern Cape , Renewable energy sources -- South Africa -- Eastern Cape , Biomass energy -- South Africa -- Eastern Cape , Crop residue management -- South Africa -- Eastern Cape , Coal gasification -- South Africa -- Eastern Cape , Lignocellulose -- Biodegradation -- South Africa -- Eastern Cape
- Description: Biomass gasification has attracted the interest of researchers because it produces zero carbon to the atmosphere. This technology does not only produce syngas but also the byproducts which can be used for various application depending on quality.The study conducted at Melani village in Alice in the Eastern Cape of South Africa was aimed at investigating the possible applications of the gasification byproducts instead of being thrown away. Pine wood was employed as the parent feedstock material for the gasifier. Biomass gasification by-products were then collected for further analysis. The studied by-products included tar(condensate), char, soot and resin. These materials were also blended to produce strong materials.The essence of the blending was to generate ideal material that is strong but light at the same time.The elemental analysis of the samples performed by CHNS analyser revealed that carbon element is in large quantities in all samples. The FTIR spectra showed almost similar results for all the studied samples, since the samples are end products of lignocellulosegasification. SEM gave the sticky images of resin as well as porous char structures. Char showed a higher heating value of 35.37MJ/Kg when compared to other by-products samples.
- Full Text:
- Date Issued: 2015
Ni(II) and Pb(II) dithiocarbamate complexes as precursors for the synthesis of HDA-capped NiS and PbS nanoparticles
- Authors: Chintso, Thobani
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11349 , http://hdl.handle.net/10353/d1020201
- Description: Ni(II) and Pb(II) dithiocarbamate complexes were synthesized and characterized by elemental analysis, UV-Vis, FTIR and TGA and some of the Ni(II) complexes and one Pb(II) were further analyzed by 1H-NMR and 13C-NMR spectroscopy. Generally all the dithiocarbamate ligands are soluble in water while the complexes were soluble mostly in solvents such as chloroform, toluene, DMSO and DCM. Based on the elemental analysis, the dithiocarbamate complexes are formulated as four coordinate (tetrahedral or square planar) compounds. However, the FTIR showed that each of the dithiocarbamate ligands acted as bidentate ligand through two sulfur atoms. The TGA of the most complexes showed one major decomposition step to give respective metal sulfide above 200 oC. In this research project, dithiocarbamate complexes were used as single source precursor for the synthesis of metal sulfide nanoparticles. We studied the optical and structural properties of metal sulfide nanoparticles using UV-Vis, photoluminescence (PL), powder X-ray diffraction (XRD), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The absorption spectra of the metal sulfide nanoparticles are blue shifted in respect to bulk material and they also showed broad emission. The XRD of the NiS nanoparticles were indexed to the cubic and rhombohedral phase, with crystallite sizes of 15 - 18 nm. The XRD of PbS nanoparticles were indexed to the face centered cubic and cubic rock salts, with the crystallite sizes 12 - 18 nm. The TEM images of the metal sulfide nanoparticles showed particles with spherical and rectangular shapes with crystallite sizes 4 - 35 nm.
- Full Text:
- Date Issued: 2015
- Authors: Chintso, Thobani
- Date: 2015
- Language: English
- Type: Thesis , Masters , MSc (Chemistry)
- Identifier: vital:11349 , http://hdl.handle.net/10353/d1020201
- Description: Ni(II) and Pb(II) dithiocarbamate complexes were synthesized and characterized by elemental analysis, UV-Vis, FTIR and TGA and some of the Ni(II) complexes and one Pb(II) were further analyzed by 1H-NMR and 13C-NMR spectroscopy. Generally all the dithiocarbamate ligands are soluble in water while the complexes were soluble mostly in solvents such as chloroform, toluene, DMSO and DCM. Based on the elemental analysis, the dithiocarbamate complexes are formulated as four coordinate (tetrahedral or square planar) compounds. However, the FTIR showed that each of the dithiocarbamate ligands acted as bidentate ligand through two sulfur atoms. The TGA of the most complexes showed one major decomposition step to give respective metal sulfide above 200 oC. In this research project, dithiocarbamate complexes were used as single source precursor for the synthesis of metal sulfide nanoparticles. We studied the optical and structural properties of metal sulfide nanoparticles using UV-Vis, photoluminescence (PL), powder X-ray diffraction (XRD), energy dispersive X-ray (EDX), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The absorption spectra of the metal sulfide nanoparticles are blue shifted in respect to bulk material and they also showed broad emission. The XRD of the NiS nanoparticles were indexed to the cubic and rhombohedral phase, with crystallite sizes of 15 - 18 nm. The XRD of PbS nanoparticles were indexed to the face centered cubic and cubic rock salts, with the crystallite sizes 12 - 18 nm. The TEM images of the metal sulfide nanoparticles showed particles with spherical and rectangular shapes with crystallite sizes 4 - 35 nm.
- Full Text:
- Date Issued: 2015