Humanitarian intervention in conflict management in Africa: selected case study analysis of Sudan and Libya
- Authors: Muruviwa, Tapiwa Gladmore
- Date: 2015-04
- Subjects: Humanitarian intervention , Conflict management -- Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24772 , vital:63550
- Description: The study investigates the effectiveness of humanitarian intervention as a strategy in conflict management in Africa drawing from case studies in Sudan and Libya. The research utilized an interaction of both primary and secondary data sources. Primary sources used are African Union (AU) official reports, United Nations Security Council (UNSC) official reports as well as official International Commission on Intervention and State Sovereignty (ICISS) reports. Secondary sources used include journal articles, newspapers, books and other online publications. Among others, the study found out that humanitarian intervention in Sudan by the AU from 2004 until 2006 lacked the capacity and political will to effectively manage the conflict. At the same time, an analysis of the North Atlantic Treaty Organization‟s (NATO) military intervention in Libya in 2011 reveals that western-led interventions in Africa are often driven by geostrategic interests rather than the need to save people in danger. Against this backdrop, the study recommends amongst others that the AU should have a capacitated standby-force that will rapidly respond to manage conflicts in Africa. Also, UN peacekeeping operations in Africa should be coordinated by the African Union. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2015
- Full Text:
- Date Issued: 2015-04
- Authors: Muruviwa, Tapiwa Gladmore
- Date: 2015-04
- Subjects: Humanitarian intervention , Conflict management -- Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24772 , vital:63550
- Description: The study investigates the effectiveness of humanitarian intervention as a strategy in conflict management in Africa drawing from case studies in Sudan and Libya. The research utilized an interaction of both primary and secondary data sources. Primary sources used are African Union (AU) official reports, United Nations Security Council (UNSC) official reports as well as official International Commission on Intervention and State Sovereignty (ICISS) reports. Secondary sources used include journal articles, newspapers, books and other online publications. Among others, the study found out that humanitarian intervention in Sudan by the AU from 2004 until 2006 lacked the capacity and political will to effectively manage the conflict. At the same time, an analysis of the North Atlantic Treaty Organization‟s (NATO) military intervention in Libya in 2011 reveals that western-led interventions in Africa are often driven by geostrategic interests rather than the need to save people in danger. Against this backdrop, the study recommends amongst others that the AU should have a capacitated standby-force that will rapidly respond to manage conflicts in Africa. Also, UN peacekeeping operations in Africa should be coordinated by the African Union. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2015
- Full Text:
- Date Issued: 2015-04
Examining the nature of entrepreneurship within the towns and rural areas of Sakhisizwe Local Municipality, Eastern Cape
- Authors: Maliwa, Noluvuyo
- Date: 2022-11
- Subjects: Entrepreneurship , Developing countries--Economic conditions , Small business
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27555 , vital:69315
- Description: Entrepreneurship plays an important role in societies around the world because it supports economic growth and creates job opportunities. This study investigated the nature of entrepreneurship in three distinct parts of Sakhisizwe Local Municipality, including a town within Sakhisizwe’s former homeland area, rural communities within its former homeland area, and a town within an area characterised by large-scale commercial farms. The study sought to establish the share of adults in the different parts of the municipality involved in entrepreneurship, to identify factors that contribute to the decision to become an entrepreneur, and to examine strategies pursued by, and challenges experienced, different types of entrepreneurs. The study involved a random sample of 362 respondents and both quantitative and qualitative data analysis. Among the main findings is that the proportion of adults involved in enterprise in Sakhisizwe is higher than found by other studies for South Africa as a whole, but is especially high for those living in the town in the former homeland area. While those residing in rural communities also engage in enterprise, they are generally compelled to practice their enterprises in town, thus have the disadvantage of needing frequent transport. While residing in the town in the commercial farming area is not disadvantageous in the same way, the challenge is that the town itself is able to support relatively few entrepreneurs due to fewer people coming to town for their shopping. , Thesis (MSci) -- Faculty of Science and Agricultures, 2022
- Full Text:
- Date Issued: 2022-11
- Authors: Maliwa, Noluvuyo
- Date: 2022-11
- Subjects: Entrepreneurship , Developing countries--Economic conditions , Small business
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/27555 , vital:69315
- Description: Entrepreneurship plays an important role in societies around the world because it supports economic growth and creates job opportunities. This study investigated the nature of entrepreneurship in three distinct parts of Sakhisizwe Local Municipality, including a town within Sakhisizwe’s former homeland area, rural communities within its former homeland area, and a town within an area characterised by large-scale commercial farms. The study sought to establish the share of adults in the different parts of the municipality involved in entrepreneurship, to identify factors that contribute to the decision to become an entrepreneur, and to examine strategies pursued by, and challenges experienced, different types of entrepreneurs. The study involved a random sample of 362 respondents and both quantitative and qualitative data analysis. Among the main findings is that the proportion of adults involved in enterprise in Sakhisizwe is higher than found by other studies for South Africa as a whole, but is especially high for those living in the town in the former homeland area. While those residing in rural communities also engage in enterprise, they are generally compelled to practice their enterprises in town, thus have the disadvantage of needing frequent transport. While residing in the town in the commercial farming area is not disadvantageous in the same way, the challenge is that the town itself is able to support relatively few entrepreneurs due to fewer people coming to town for their shopping. , Thesis (MSci) -- Faculty of Science and Agricultures, 2022
- Full Text:
- Date Issued: 2022-11
Negotiating identity in an online virtual environment
- Authors: Dube, Nompumelelo
- Date: 2011-11
- Subjects: Online Identities , Internet , Personal Information Managenment
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23883 , vital:61284
- Description: This study investigates ways in which people in an online anonymous virtual environment use language to negotiate and manage their identities. The study is informed by the tenets of social constructionism, a theory that explores the problematic manner in which the self is taken for granted as unchanging (Burr, 1998). One point made by alternative theorists other than social constructionist theorists is the notion of the “essential self”; one tenet of social constructionist theory suggests that the “essential self” of a person remains fluid. The implication is that one ultimately changes as each day passes, for example at the core of one’s personality is an “essential self” that changes with experiences, conflicts and/or age (Tuffin, 2005). From a social constructionist perspective, the self is more fractured and contingent on life’s circumstances. This theory was found to be an appropriate paradigm from which to study anonymous online identities, where individuals were found to create and negotiate certain identities outside of those identities that people often find important to portray to outsiders in the general public. Sixty-seven (67) students from different races participated in this study and online discussions from a course discussion forum, “blackboard”, were monitored. This study found that one’s identity is negotiated in an anonymous virtual environment. Data was collected from these discussions and was analysed using Potter and Wetherell’s (1987) method of discourse analysis. Research findings ultimately found that people use discursive strategies in negotiating and maintaining their identity online, but that distinct racial characteristics were noticeable despite some attempts to mask one’s background. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-11
- Authors: Dube, Nompumelelo
- Date: 2011-11
- Subjects: Online Identities , Internet , Personal Information Managenment
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23883 , vital:61284
- Description: This study investigates ways in which people in an online anonymous virtual environment use language to negotiate and manage their identities. The study is informed by the tenets of social constructionism, a theory that explores the problematic manner in which the self is taken for granted as unchanging (Burr, 1998). One point made by alternative theorists other than social constructionist theorists is the notion of the “essential self”; one tenet of social constructionist theory suggests that the “essential self” of a person remains fluid. The implication is that one ultimately changes as each day passes, for example at the core of one’s personality is an “essential self” that changes with experiences, conflicts and/or age (Tuffin, 2005). From a social constructionist perspective, the self is more fractured and contingent on life’s circumstances. This theory was found to be an appropriate paradigm from which to study anonymous online identities, where individuals were found to create and negotiate certain identities outside of those identities that people often find important to portray to outsiders in the general public. Sixty-seven (67) students from different races participated in this study and online discussions from a course discussion forum, “blackboard”, were monitored. This study found that one’s identity is negotiated in an anonymous virtual environment. Data was collected from these discussions and was analysed using Potter and Wetherell’s (1987) method of discourse analysis. Research findings ultimately found that people use discursive strategies in negotiating and maintaining their identity online, but that distinct racial characteristics were noticeable despite some attempts to mask one’s background. , Thesis (MA) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-11
Parenting and moral behaviour: an exploration of young mothers raising children in golf course, Alice, Eastern Cape
- Authors: Nyatanga, Georgina
- Date: 2021-01
- Subjects: Parenting , Child rearing
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22339 , vital:52027
- Description: Regardless of the efforts that have been put forward to reduce adolescent pregnancies on a global scale, the prevalence of adolescent pregnancy is still on the rise, and this has ultimately led to young motherhood to be a common feature in many societies, South Africa inclusive. A number of factors have contributed towards the parenting capacity of young mothers to nurture their children towards developing warranted behavior to be questioned. Owing to this, this study embarked on a journey to explore how young motherhood influences the development of immoral or unwarranted behavior in children in Golf Course, Alice, Eastern Cape, South Africa. Informed by the theoretical lenses of the Moral Development Theory, Social Learning Theory, and the Systems Theory; the study aimed to answer the following questions: (i) How does young motherhood influence the development of immoral behavior in children? (ii) What are the types of immoral behaviors that children raised by young mothers are involved in? (iii) What are the possible strategies that can be implemented to curb the prevalence of immoral behavior in children raised by young mothers? The study adopted a qualitative research approach with a case study research design. Data was collected through in depths interviews from the young mothers and key informants. A semi structured interview schedule was used as a data collection instrument. Non-probability sampling technique was used, and the sample of the study was obtained through purposive sampling. Twenty-five participants (twenty young mothers and five key informants) were recruited to participate in the study using the fore mentioned technique. Thematic analysis was used to analyze the collected data. The study revealed the following aspects: young mothers are confronted with a number of challenges which affect their parenting capacity and nurturing of their children; a majority of children raised by young mothers in Golf Course exhibit a number of unwarranted behavior which is influenced by their family situation and the nature of parenting they receive; lastly training in parenting, availability of child protection services and development of support group services for young mothers were identified as the strategies that can be employed to reduce the development of unwarranted behavior in children raised by young mothers. Based on the findings, the study recommends that government entities together with non-governmental social service providers provide the financial, social support and mental support to young mothers to empower and capacitate them so that they can be able to adopt positive parenting skills which are necessary towards nurturing warranted behavior in children. The study also recommends that young mothers must be conscious of their lifestyle and life choices as these have a direct impact on the behavior of their children. The study concludes that if the conditions of children raised by young mothers are to be enhanced, the prevalence of immoral or unwarranted behavior amongst children raised by young mothers will drop drastically. , Thesis (MSW) -- Faculty of Social Sciences and Humanities, 2021
- Full Text:
- Date Issued: 2021-01
- Authors: Nyatanga, Georgina
- Date: 2021-01
- Subjects: Parenting , Child rearing
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22339 , vital:52027
- Description: Regardless of the efforts that have been put forward to reduce adolescent pregnancies on a global scale, the prevalence of adolescent pregnancy is still on the rise, and this has ultimately led to young motherhood to be a common feature in many societies, South Africa inclusive. A number of factors have contributed towards the parenting capacity of young mothers to nurture their children towards developing warranted behavior to be questioned. Owing to this, this study embarked on a journey to explore how young motherhood influences the development of immoral or unwarranted behavior in children in Golf Course, Alice, Eastern Cape, South Africa. Informed by the theoretical lenses of the Moral Development Theory, Social Learning Theory, and the Systems Theory; the study aimed to answer the following questions: (i) How does young motherhood influence the development of immoral behavior in children? (ii) What are the types of immoral behaviors that children raised by young mothers are involved in? (iii) What are the possible strategies that can be implemented to curb the prevalence of immoral behavior in children raised by young mothers? The study adopted a qualitative research approach with a case study research design. Data was collected through in depths interviews from the young mothers and key informants. A semi structured interview schedule was used as a data collection instrument. Non-probability sampling technique was used, and the sample of the study was obtained through purposive sampling. Twenty-five participants (twenty young mothers and five key informants) were recruited to participate in the study using the fore mentioned technique. Thematic analysis was used to analyze the collected data. The study revealed the following aspects: young mothers are confronted with a number of challenges which affect their parenting capacity and nurturing of their children; a majority of children raised by young mothers in Golf Course exhibit a number of unwarranted behavior which is influenced by their family situation and the nature of parenting they receive; lastly training in parenting, availability of child protection services and development of support group services for young mothers were identified as the strategies that can be employed to reduce the development of unwarranted behavior in children raised by young mothers. Based on the findings, the study recommends that government entities together with non-governmental social service providers provide the financial, social support and mental support to young mothers to empower and capacitate them so that they can be able to adopt positive parenting skills which are necessary towards nurturing warranted behavior in children. The study also recommends that young mothers must be conscious of their lifestyle and life choices as these have a direct impact on the behavior of their children. The study concludes that if the conditions of children raised by young mothers are to be enhanced, the prevalence of immoral or unwarranted behavior amongst children raised by young mothers will drop drastically. , Thesis (MSW) -- Faculty of Social Sciences and Humanities, 2021
- Full Text:
- Date Issued: 2021-01
Potential effects of different salinities on the survival of the mangrove crab, Uca urvillei and its associated chemoautotrophic bacterial symbionts
- Mbobo, Tumeka https://orcid.org/0000-0002-0159-6569
- Authors: Mbobo, Tumeka https://orcid.org/0000-0002-0159-6569
- Date: 2015-06
- Subjects: Mangrove ecology http://id.loc.gov/authorities/subjects/sh85080528 , Crabs--South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19225 , vital:43033
- Description: The ability of natural populations to maintain fitness is important to their long-term persistence and has further relevance in the light of climate change scenarios. Fitness is however also influenced strongly by interactions with other species of the community. It is, therefore, important to focus on how environmental change can alter key biological interactions. The present study aimed to investigate the effects of different salinity levels on one species of mangrove crab, Uca urvillei and the associated chemoautotrophic bacterial symbionts, from the Mngazana estuary, South Africa. To examine the influence of different salinities over time on the symbiotic bacterial community, salinity experiments were set up, choosing three salinity exposures (5, 20 and 35percent) and four time exposures (3, 7, 14 and 21 days). The results showed that microbial community associated with U. urvillei was generally stable throughout the three salinity treatments, while the survival of the host (crab), was influenced by high salinities, particularly after day 14. Overall, the results of this study suggest that over time, environmental salinity (35percent) has the potential to affect significantly the physiology of U. urvillei, but this might not necessarily be the case for the associated microbial communities. The modes at which the significant symbionts are transferred from mother to offspring were also investigated by analysing the bacterial profiles from eggs, ovigerous and non-ovigerous females, along with mud. The results were fairly complex, but with significant differences in the bacterial communities of eggs from mud and females. These differences were driven mostly by two dominant phyla: Actinobacteria and Proteobacteria. The presence of both these phyla throughout the categories (even though in different percentages) suggest that U. urvillei might employ a mixed mode strategy of acquiring and maintaining the bacterial symbionts. Overall, this study contributes to further understand the dynamic and complex effects of environmental Abstract ii change on symbiotic communities, with overall potential cascading repercussions to the persistence of mangrove systems. , Thesis (MSc) (Zoology) -- Faculty of Science and Agriculture, 2015
- Full Text:
- Date Issued: 2015-06
- Authors: Mbobo, Tumeka https://orcid.org/0000-0002-0159-6569
- Date: 2015-06
- Subjects: Mangrove ecology http://id.loc.gov/authorities/subjects/sh85080528 , Crabs--South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19225 , vital:43033
- Description: The ability of natural populations to maintain fitness is important to their long-term persistence and has further relevance in the light of climate change scenarios. Fitness is however also influenced strongly by interactions with other species of the community. It is, therefore, important to focus on how environmental change can alter key biological interactions. The present study aimed to investigate the effects of different salinity levels on one species of mangrove crab, Uca urvillei and the associated chemoautotrophic bacterial symbionts, from the Mngazana estuary, South Africa. To examine the influence of different salinities over time on the symbiotic bacterial community, salinity experiments were set up, choosing three salinity exposures (5, 20 and 35percent) and four time exposures (3, 7, 14 and 21 days). The results showed that microbial community associated with U. urvillei was generally stable throughout the three salinity treatments, while the survival of the host (crab), was influenced by high salinities, particularly after day 14. Overall, the results of this study suggest that over time, environmental salinity (35percent) has the potential to affect significantly the physiology of U. urvillei, but this might not necessarily be the case for the associated microbial communities. The modes at which the significant symbionts are transferred from mother to offspring were also investigated by analysing the bacterial profiles from eggs, ovigerous and non-ovigerous females, along with mud. The results were fairly complex, but with significant differences in the bacterial communities of eggs from mud and females. These differences were driven mostly by two dominant phyla: Actinobacteria and Proteobacteria. The presence of both these phyla throughout the categories (even though in different percentages) suggest that U. urvillei might employ a mixed mode strategy of acquiring and maintaining the bacterial symbionts. Overall, this study contributes to further understand the dynamic and complex effects of environmental Abstract ii change on symbiotic communities, with overall potential cascading repercussions to the persistence of mangrove systems. , Thesis (MSc) (Zoology) -- Faculty of Science and Agriculture, 2015
- Full Text:
- Date Issued: 2015-06
ZIMBABWE’S LIBERATION STRUGGLE: A CRITICAL DECADE OF THE ZIMBABWE AFRICAN NATIONAL UNION (ZANU)’S GUERRILLA WAR, 1970-1980
- Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Authors: Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Date: 2011-01
- Subjects: National Liberation Movements -- Zimbabwe , Guerillas , Zimbabwe -- History -- Chimurenga
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23315 , vital:57048
- Description: This study offers a comprehensive examination of the Zimbabwean war of independence depicting the mobilisation of forces of liberation against an intransigent colonial Rhodesian settler state during a critical decade of the 1970s. Its introductory outline presents a broad historical context to the decolonisation processes in Africa. It also introduces the two liberation movements that drove the war of independence, and these revolved around the Zimbabwe African People’s Union (ZAPU) and the Zimbabwe African National Union (ZANU). The empirical chapters of the thesis narrow the focus to the main research subject, that explain the ZANU’s guerrilla warfare and how that was launched under the military wing of the Zimbabwe African National Liberation Army (ZANLA). The study looks, particularly on how and why that formation assembled groundswell support and generated pervasive intelligence to operate relentlessly against the Rhodesian colonial government resulting in a compromised independence in 1980. In addition to a wide-ranging survey of literature that deals with the Zimbabwean war of independence, the production of this thesis is thoroughly grounded on empirical methods that hinge on archival research and oral testimonies. The study breaks new ground in outlining the various facets and different phases of the Zimbabwean liberation war. It reveals that the liberation fighters were not merely provided with arms and deployed to fight the Rhodesian army. Rather they underwent a methodical process, which comprised recruitment, extensive training and fundamental political education. This re-represents an alternative narrative or even eccentric paradigm to that persistently presented within the conventional Zimbabwean liberation war historiography. The thesis breaks further new ground in discussing the complex nature of how intelligence gathering and propaganda uses were also centrally linked to the cooperation of or assistance from the various segments of the colonial African society. Its empirical chapters outline the various actions undertaken by the various groups and individuals, the language they adopted in expressing themselves and the convivial connections between them and the guerrilla fighters in the countryside as the war front expanded within the home boundaries. Chapters also explore in greater detail how the liberation movement bred the complex relation and contestation between the political formation of ZANU and its military wing, ZANLA. The uneven power relations between these two formations somehow dictated the course and the outcome of the liberation war. As a result a constitutional settlement or military victory became the two options by which the Rhodesian question could be resolved in the later 1970s. As it turned out, attempts to seek a constitutional solution became a feature of diplomatic dimensions of the postcolonial Rhodesian political landscape. The study concludes with the latter point. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
- Authors: Dzimbanhete, Jephias Andrew (https://orcid.org/0000-0002-7648-8722)
- Date: 2011-01
- Subjects: National Liberation Movements -- Zimbabwe , Guerillas , Zimbabwe -- History -- Chimurenga
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/23315 , vital:57048
- Description: This study offers a comprehensive examination of the Zimbabwean war of independence depicting the mobilisation of forces of liberation against an intransigent colonial Rhodesian settler state during a critical decade of the 1970s. Its introductory outline presents a broad historical context to the decolonisation processes in Africa. It also introduces the two liberation movements that drove the war of independence, and these revolved around the Zimbabwe African People’s Union (ZAPU) and the Zimbabwe African National Union (ZANU). The empirical chapters of the thesis narrow the focus to the main research subject, that explain the ZANU’s guerrilla warfare and how that was launched under the military wing of the Zimbabwe African National Liberation Army (ZANLA). The study looks, particularly on how and why that formation assembled groundswell support and generated pervasive intelligence to operate relentlessly against the Rhodesian colonial government resulting in a compromised independence in 1980. In addition to a wide-ranging survey of literature that deals with the Zimbabwean war of independence, the production of this thesis is thoroughly grounded on empirical methods that hinge on archival research and oral testimonies. The study breaks new ground in outlining the various facets and different phases of the Zimbabwean liberation war. It reveals that the liberation fighters were not merely provided with arms and deployed to fight the Rhodesian army. Rather they underwent a methodical process, which comprised recruitment, extensive training and fundamental political education. This re-represents an alternative narrative or even eccentric paradigm to that persistently presented within the conventional Zimbabwean liberation war historiography. The thesis breaks further new ground in discussing the complex nature of how intelligence gathering and propaganda uses were also centrally linked to the cooperation of or assistance from the various segments of the colonial African society. Its empirical chapters outline the various actions undertaken by the various groups and individuals, the language they adopted in expressing themselves and the convivial connections between them and the guerrilla fighters in the countryside as the war front expanded within the home boundaries. Chapters also explore in greater detail how the liberation movement bred the complex relation and contestation between the political formation of ZANU and its military wing, ZANLA. The uneven power relations between these two formations somehow dictated the course and the outcome of the liberation war. As a result a constitutional settlement or military victory became the two options by which the Rhodesian question could be resolved in the later 1970s. As it turned out, attempts to seek a constitutional solution became a feature of diplomatic dimensions of the postcolonial Rhodesian political landscape. The study concludes with the latter point. , Thesis (PHD) -- Faculty of Social Sciences and Humanities, 2011
- Full Text:
- Date Issued: 2011-01
Experiences of children who have transitioned into foster care in Breidbach community in King Williams, Buffalo City, Eastern Cape
- Authors: Nkumbi, Sinazo
- Date: 2022-06
- Subjects: Foster children--Care , Children's rights , Participation
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23776 , vital:60520
- Description: The study explored the experiences of children who have transitioned into foster care, looking in depth at their level of participation in matters concerning their lives. The researcher was predominantly inspired to conduct this research by children in communities who found themselves falling unintentionally into a system of foster care. There are overt hardships in communities that result in children needing care and protection. Children find themselves faced with abusive circumstances, experiencing loss and being abandoned. There is little research on experiences of children who have transitioned into foster care, on child participation in matters that involve their lives, and research that documents the perspectives of children. Children’s ability to exercise their constitutional right to participate, and making their voices heard regarding their life experiences through their own milieu, have also not received attention. There are several intervention systems put in place by the South African government to aid children in need of care and protection, and systems to place children in conducive environments. These systems are largely focused on placement of the child in need, application for foster care grants, foster parents, and the extension of the foster placement. However, there is very little information regarding the child’s right to participate in matters that involve their lives. The goal of the study was to investigate children’s participation in matters that affect their lives. It was interested in children’s perspectives. The aim was to explore the experiences of children who had transitioned into the foster care system in Breidbach Community in King Williams Town it Buffalo City Municipality. The purpose was to identify gaps, as there is minimal information concerning experiences of children who have transitioned into foster care and on children’s participation as stipulated within section 10 of the Children’s Act 38 of 2005. To be able to achieve the objectives of the study, interviews were conducted with purposefully sampled participants. Data obtained was analysed according to qualitative data analysis procedures. The researcher utilised exploratory, descriptive and contextual research designs. The domain where participants were interviewed was Breidbach, King Williams Town, and Buffalo City under the jurisdiction of the Department of Social Development (DSD) and Child Protection Organisations (CPO). Findings indicate the children lacked education on their right to participate in matters that affect their lives. Furthermore, some professionals did not involve the children in matters that affected them, leading to interventions on matters concerning the children that did not benefit from input by the children. Taking into cognisance of all the relevant information stated above, children’s right to participate in matters involving their lives is as paramount as the involvement of the social workers and the foster parents when determining their placement. A holistic approach has to be used, hence it is primary and recommended that, the investigation, intervention strategies and framework used by social workers in making sure that children in need of care and protection include the perspectives of children who are to be placed into foster care. This will be possible through the participation of a child. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2022
- Full Text:
- Date Issued: 2022-06
- Authors: Nkumbi, Sinazo
- Date: 2022-06
- Subjects: Foster children--Care , Children's rights , Participation
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23776 , vital:60520
- Description: The study explored the experiences of children who have transitioned into foster care, looking in depth at their level of participation in matters concerning their lives. The researcher was predominantly inspired to conduct this research by children in communities who found themselves falling unintentionally into a system of foster care. There are overt hardships in communities that result in children needing care and protection. Children find themselves faced with abusive circumstances, experiencing loss and being abandoned. There is little research on experiences of children who have transitioned into foster care, on child participation in matters that involve their lives, and research that documents the perspectives of children. Children’s ability to exercise their constitutional right to participate, and making their voices heard regarding their life experiences through their own milieu, have also not received attention. There are several intervention systems put in place by the South African government to aid children in need of care and protection, and systems to place children in conducive environments. These systems are largely focused on placement of the child in need, application for foster care grants, foster parents, and the extension of the foster placement. However, there is very little information regarding the child’s right to participate in matters that involve their lives. The goal of the study was to investigate children’s participation in matters that affect their lives. It was interested in children’s perspectives. The aim was to explore the experiences of children who had transitioned into the foster care system in Breidbach Community in King Williams Town it Buffalo City Municipality. The purpose was to identify gaps, as there is minimal information concerning experiences of children who have transitioned into foster care and on children’s participation as stipulated within section 10 of the Children’s Act 38 of 2005. To be able to achieve the objectives of the study, interviews were conducted with purposefully sampled participants. Data obtained was analysed according to qualitative data analysis procedures. The researcher utilised exploratory, descriptive and contextual research designs. The domain where participants were interviewed was Breidbach, King Williams Town, and Buffalo City under the jurisdiction of the Department of Social Development (DSD) and Child Protection Organisations (CPO). Findings indicate the children lacked education on their right to participate in matters that affect their lives. Furthermore, some professionals did not involve the children in matters that affected them, leading to interventions on matters concerning the children that did not benefit from input by the children. Taking into cognisance of all the relevant information stated above, children’s right to participate in matters involving their lives is as paramount as the involvement of the social workers and the foster parents when determining their placement. A holistic approach has to be used, hence it is primary and recommended that, the investigation, intervention strategies and framework used by social workers in making sure that children in need of care and protection include the perspectives of children who are to be placed into foster care. This will be possible through the participation of a child. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2022
- Full Text:
- Date Issued: 2022-06
Investigating the role of the South African Schools Choral Eisteddfod in introducing learners to music career
- Authors: Sibene, Vuyelwa
- Date: 2016
- Subjects: Choral music -- South Africa , Choral singing -- Instruction and study -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26382 , vital:65298
- Description: This research investigates the role of South African Schools Choral Eisteddfod (SASCE) in introducing learners in high schools to music career. It attempts to identify learners in grade 12 who want to study music at university and students who were involved in SASCE and are now in university. These learners and students have limited music background and are/were involved in the South African Schools Choral Eisteddfod (SASCE) program. Within the study, I felt to also include a graduated music student to validate the study. The study proceeds with the investigation by exploring numerous areas such as SASCE as a music program, music education, music careers, national curriculum, music literacy etc. Also, I write about the background to the study in which I share my motivation and experiences about the SASCE programme and how it influenced me and other former SASCE participants’ decisions about musical careers. Data collection is executed through the involvement of the sampled learner and students through participating in semi-structured interview, document analysis and personal observations. Four interviews which were in qualitative method were conducted with 4 participants, one interview each participant was in a semi-structure form. Interviews were aimed in recognizing the current status of the learner/students in music literacy and are they coping in their respected places of study. The data is analyzed using a qualitative analyses technique. Further, the study outlines problems and one research question of the investigation, 'To which extent do University music students with limited music background succeed or fail to obtain their music degrees?’. , Thesis (BMUS) -- Faculty of Humanities, 2016
- Full Text:
- Date Issued: 2016
- Authors: Sibene, Vuyelwa
- Date: 2016
- Subjects: Choral music -- South Africa , Choral singing -- Instruction and study -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26382 , vital:65298
- Description: This research investigates the role of South African Schools Choral Eisteddfod (SASCE) in introducing learners in high schools to music career. It attempts to identify learners in grade 12 who want to study music at university and students who were involved in SASCE and are now in university. These learners and students have limited music background and are/were involved in the South African Schools Choral Eisteddfod (SASCE) program. Within the study, I felt to also include a graduated music student to validate the study. The study proceeds with the investigation by exploring numerous areas such as SASCE as a music program, music education, music careers, national curriculum, music literacy etc. Also, I write about the background to the study in which I share my motivation and experiences about the SASCE programme and how it influenced me and other former SASCE participants’ decisions about musical careers. Data collection is executed through the involvement of the sampled learner and students through participating in semi-structured interview, document analysis and personal observations. Four interviews which were in qualitative method were conducted with 4 participants, one interview each participant was in a semi-structure form. Interviews were aimed in recognizing the current status of the learner/students in music literacy and are they coping in their respected places of study. The data is analyzed using a qualitative analyses technique. Further, the study outlines problems and one research question of the investigation, 'To which extent do University music students with limited music background succeed or fail to obtain their music degrees?’. , Thesis (BMUS) -- Faculty of Humanities, 2016
- Full Text:
- Date Issued: 2016
The Influence of stakeholder orientation and entrepreneurial orientation on the performance of small tourism businesses in the Eastern Cape Province
- Maseko, Ian https://orcid.org/0000-0003-1374-1660
- Authors: Maseko, Ian https://orcid.org/0000-0003-1374-1660
- Date: 2010-12
- Subjects: Small business -- South Africa , Tourism -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25937 , vital:64635
- Description: Small businesses have been identified as a catalyst for the growth and expansion of both developed and developing economies. In South Africa, tourism is an important element of the economy and small tourism businesses play an integral role in this sector. However, the success of these firms is influenced by the business orientation adopted. In this regard, entrepreneurial orientation and stakeholder orientation are considered key factors in ensuring enterprise performance and longevity. The main objective of this research is to establish the relationship between stakeholder orientation, entrepreneurial orientation and the performance of small tourism businesses. In order to accomplish this purpose, the reliability and validity of the instrument was assessed, followed by a multiple regression analysis and a Pearson correlation analysis to test the proposed hypotheses. Overall findings from this study suggest that one dimension of stakeholder orientation and entrepreneurial orientation has a positive significant relationship with small firm performance. The results also confirm that stakeholder orientation dimensions and entrepreneurial orientation are positively correlated. , Thesis (MCom) -- Faculty of Management and Commerce, 2010
- Full Text:
- Date Issued: 2010-12
- Authors: Maseko, Ian https://orcid.org/0000-0003-1374-1660
- Date: 2010-12
- Subjects: Small business -- South Africa , Tourism -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25937 , vital:64635
- Description: Small businesses have been identified as a catalyst for the growth and expansion of both developed and developing economies. In South Africa, tourism is an important element of the economy and small tourism businesses play an integral role in this sector. However, the success of these firms is influenced by the business orientation adopted. In this regard, entrepreneurial orientation and stakeholder orientation are considered key factors in ensuring enterprise performance and longevity. The main objective of this research is to establish the relationship between stakeholder orientation, entrepreneurial orientation and the performance of small tourism businesses. In order to accomplish this purpose, the reliability and validity of the instrument was assessed, followed by a multiple regression analysis and a Pearson correlation analysis to test the proposed hypotheses. Overall findings from this study suggest that one dimension of stakeholder orientation and entrepreneurial orientation has a positive significant relationship with small firm performance. The results also confirm that stakeholder orientation dimensions and entrepreneurial orientation are positively correlated. , Thesis (MCom) -- Faculty of Management and Commerce, 2010
- Full Text:
- Date Issued: 2010-12
Integration of nanostructured metal sulfides into titanium (iv) oxide for high performance dye sensitized solar cell
- Adedoyin Mojeed Agoro https://orcid.org/0000-0002-0434-9635
- Authors: Adedoyin Mojeed Agoro https://orcid.org/0000-0002-0434-9635
- Date: 2020-01
- Subjects: Nanostructured materials , Sulfur compounds
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/21523 , vital:48857
- Description: The work in this thesis describes synthesis, characterization and integration of nanostructured metal sulfides into titanium (IV) oxide for high performance dye sensitized solar cell. The synthesised single source precursors were evaluated using TGA, FTIR, , UV-Vis, PL,1H and 13CNMR, SEM, EDS, HRTEM, XRD, AFM, Raman, I-V, CV, Bode plot and EIS. TGA revealed the thermal degradation and quantified the mass percentage of metal sulphides as 33percent, 45percent and 27percent for CuS, PbS and SnS nanoparticles, respectively. FTIR analysis showed bands at 1580-1450 cm-1, and 1060-940 cm-1 tentatively assigned to C-N and C-S stretching frequencies correspondingly. The (M-S) stretching was observed at 577-406 cm-1 for the complexes using bis(N-di-isopropyl-N-octyldithiocarbamato) as primary ligands. IR spectra of bis(N-1,4-phenyl-N-(4-morpholinedithiocarbamato) as secondary ligands suggested the presence of (C-N) vibrations at 1508-1513 cm-1 for the complexes and 1507-1584 cm-1 for the ligands. The bands in the region of 973-1030 cm-1 were assigned to the complexes and 974- 983 cm-1 were attributed to the ligands, whereas vibration frequencies at 416-625 cm-1 were Nelson's Choice were included in these preliminary variety trials (PVTs) as checks. Twenty-five hybrids expressing high values for the Smith – Hazel selection index were identified across sites over years. Among those hybrids were two checks, namely Q16 (PAN5Q649R) and Q33 (Phb31MO7BR). The top five high – yielding hybrids selected based on the selection index were considered to be the most productive, stable and adaptable based on the GGE biplot and AMMI stability values. None of these single cross hybrids over yielded the best hybrid check (Q16) in the current study. A high potential environment, Centane, was the ideal environments for evaluating genotypes in the present study. The studies showed inbred lines L22, L23, L26, L28, L25, L29 and L31 to be low N stress tolerant at 0 kg N ha-1 based on the low N stress tolerance indices under glasshouse and the field conditions; they were also among the top ten grain-yielders under field conditions at 0 kg N ha-1. Also, in the NUE study, they were found to be among the top ten most N-efficient inbred lines under low N soils, under 30 kg N ha-1, and were among the top twenty-four inbred lines with high NUE values across the N levels in the study. Inbred lines L29 and L22 also produced testcross hybrids that were among the top twenty based on GY under 0 kg N ha-1. The testcross hybrids produced from these inbred lines were also among the top twenty-five with outstanding SCA effects for GY. These inbred lines were also parental lines of some of the top twenty- five best hybrids selected based on the Smith – Hazel selection index in the PVT study. Inbred lines L22, L23, L26, L28, L25, L29 and L31 can therefore further be evaluated and used as sources of N-tolerance genes in QPM breeding programs. tentatively assigned to M-S bond in the complexes. UV-Vis spectroscopy analysis for the complexes and from primary and secondary ligands are between within the range of 338 – 340 nm. PL studies of the primary ligands with metal complexes indicated emissions at 464 nm, 462 nm, 462 nm for Pb(II) and Sn(II), and Cu(II). The presence of secondary ligands was revealed by the absorption peaks at 455, 456 and 457 nm, exhibiting both the signals and chemical constituents of the respective ligands and their corresponding complexes. The electrochemistry in chapters 3 and 4 reveals that phase angle in the Bode plots changes with frequencies for Sn(II) complexes at 58, 57 and 8 respectively. Bode plots showed remarkable electronics of Cu(II) and Pb(II) complex interfaces. The CV curves exhibit two kinds of redox peaks indicating reduction at the negative potentials and oxidation at the positive potentials. The EIS, electrodes produced Rct for Pb(II), Cu(II) and Sn(II) electrodes in chapter 3. Moreover The EIS revealed that Sn(II) sensitizer displaced a stronger chemical capacitance and improved efficiency which could lead to better electron lifetime yield. The obtained CV exhibited anodic and cathodic peaks for Pb(II), connoting a reduction in Pb2+ and oxidation in Pb2-. Bode plot phase angle displayed Sn(II) and Pb(II) with maxima phase, indicating the presence of time constants of the electrode processes in Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes. From the results in chapter 4, the XRD patterns exhibited good crystalline nature of CuS as a result of sharp and strong diffraction peaks obtained. There are eight peaks of 2θ angle between 26° and 79° relating to orthorhombic structure of SnS. While PbS has a cubic structure with polycrystalline nature, PbS/HDA and PbS both correspond to their crystalline planes of (200), (111), (220), (311), (222), (400), (331), (420) and (422) affirming to PbS QDs structure. SnS/HDA and SnS photosensitizers displayed eleven peaks between the values of 27.02° to 66.05° for SnS/HDA and 26.03° to 66.04° for SnS, in confirming the orthorhombic structure. SEM analysis revealed hexagonal structure for CuS, while PbS and SnS exhibited mesoporous nanostructures with spherical nanoparticles. HRTEM images indicated spherical nano-particles with particle sizes in the range of 3.14 - 44.39 nm. The outcome of HRTEM analysis revealed crystallite sizes varying as 10.90 – 11.57 nm, 3.14 – 5.95 nm and 14.96 – 44.39 nm for the CuS, PbS and SnS, originated from the primary ligands. HRTEM images originating from the Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes indicated spherical nano-particles with particle sizes of 3.14 - 44.39 nm. Raman images in chapter 5 revealed the presence of Raman active modes of E2g 66 cm-1 and 304, cm-1 and E1g 627 cm-1 and 706 cm-1 for CuS, the active modes of TO 65 cm-1 and 2LO 626 cm-1 for PbS, active modes of B1g 69 cm-1 for SnS and 266 cm-1 for Ag. From the AFM results in chapter 5, CuS photosensitizer displayed a smooth surface and particle estimated to be 0.50 μm and height profile of 12percent. The PbS photosensitizer exhibited particle size of 1.82 μm and 0.654 μm for PbS/HDA, depicting a regular crystal growth rate. The size distribution of SnS nanoparticle at 357 nm connotes smooth surface and good compactness on the substrate. However, SnS/HDA at 122 nm displayed shape and size of non-symmetrical particles. AFM analysis in chapter 8 revealed good size roughness for CuS film. PbS exhibited particle size of 365 nm and size height of 18percent as the smoothest film, while PbS/HDA revealed 1.22 um size with 9percent size height. The evaluated particle sizes varied as 0.11- 1.18 um for SnS/HDA and 0.054 – 0.54 um for SnS films grown at 360 ℃ with size height of 16.8 and 8.4percent. The I-V efficiency obtained indicated that the CuS exhibited a much better efficiency in the QDSCs with higher Voc and the highest η being 2.85percent compared to CuS/HDA and Cu(II). High JSC of 11 mA/cm has been observed in the PbS/HDA QDSSCs, compared to the PbS and Pb(II) cells. The SnS/HDA exhibited a better performance compared to SnS and Sn(II) sensitizers due to the presence of HDA capping agent. , Thesis (MSc -- Faculty of Science and Agriculture, 2020
- Full Text:
- Date Issued: 2020-01
- Authors: Adedoyin Mojeed Agoro https://orcid.org/0000-0002-0434-9635
- Date: 2020-01
- Subjects: Nanostructured materials , Sulfur compounds
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/21523 , vital:48857
- Description: The work in this thesis describes synthesis, characterization and integration of nanostructured metal sulfides into titanium (IV) oxide for high performance dye sensitized solar cell. The synthesised single source precursors were evaluated using TGA, FTIR, , UV-Vis, PL,1H and 13CNMR, SEM, EDS, HRTEM, XRD, AFM, Raman, I-V, CV, Bode plot and EIS. TGA revealed the thermal degradation and quantified the mass percentage of metal sulphides as 33percent, 45percent and 27percent for CuS, PbS and SnS nanoparticles, respectively. FTIR analysis showed bands at 1580-1450 cm-1, and 1060-940 cm-1 tentatively assigned to C-N and C-S stretching frequencies correspondingly. The (M-S) stretching was observed at 577-406 cm-1 for the complexes using bis(N-di-isopropyl-N-octyldithiocarbamato) as primary ligands. IR spectra of bis(N-1,4-phenyl-N-(4-morpholinedithiocarbamato) as secondary ligands suggested the presence of (C-N) vibrations at 1508-1513 cm-1 for the complexes and 1507-1584 cm-1 for the ligands. The bands in the region of 973-1030 cm-1 were assigned to the complexes and 974- 983 cm-1 were attributed to the ligands, whereas vibration frequencies at 416-625 cm-1 were Nelson's Choice were included in these preliminary variety trials (PVTs) as checks. Twenty-five hybrids expressing high values for the Smith – Hazel selection index were identified across sites over years. Among those hybrids were two checks, namely Q16 (PAN5Q649R) and Q33 (Phb31MO7BR). The top five high – yielding hybrids selected based on the selection index were considered to be the most productive, stable and adaptable based on the GGE biplot and AMMI stability values. None of these single cross hybrids over yielded the best hybrid check (Q16) in the current study. A high potential environment, Centane, was the ideal environments for evaluating genotypes in the present study. The studies showed inbred lines L22, L23, L26, L28, L25, L29 and L31 to be low N stress tolerant at 0 kg N ha-1 based on the low N stress tolerance indices under glasshouse and the field conditions; they were also among the top ten grain-yielders under field conditions at 0 kg N ha-1. Also, in the NUE study, they were found to be among the top ten most N-efficient inbred lines under low N soils, under 30 kg N ha-1, and were among the top twenty-four inbred lines with high NUE values across the N levels in the study. Inbred lines L29 and L22 also produced testcross hybrids that were among the top twenty based on GY under 0 kg N ha-1. The testcross hybrids produced from these inbred lines were also among the top twenty-five with outstanding SCA effects for GY. These inbred lines were also parental lines of some of the top twenty- five best hybrids selected based on the Smith – Hazel selection index in the PVT study. Inbred lines L22, L23, L26, L28, L25, L29 and L31 can therefore further be evaluated and used as sources of N-tolerance genes in QPM breeding programs. tentatively assigned to M-S bond in the complexes. UV-Vis spectroscopy analysis for the complexes and from primary and secondary ligands are between within the range of 338 – 340 nm. PL studies of the primary ligands with metal complexes indicated emissions at 464 nm, 462 nm, 462 nm for Pb(II) and Sn(II), and Cu(II). The presence of secondary ligands was revealed by the absorption peaks at 455, 456 and 457 nm, exhibiting both the signals and chemical constituents of the respective ligands and their corresponding complexes. The electrochemistry in chapters 3 and 4 reveals that phase angle in the Bode plots changes with frequencies for Sn(II) complexes at 58, 57 and 8 respectively. Bode plots showed remarkable electronics of Cu(II) and Pb(II) complex interfaces. The CV curves exhibit two kinds of redox peaks indicating reduction at the negative potentials and oxidation at the positive potentials. The EIS, electrodes produced Rct for Pb(II), Cu(II) and Sn(II) electrodes in chapter 3. Moreover The EIS revealed that Sn(II) sensitizer displaced a stronger chemical capacitance and improved efficiency which could lead to better electron lifetime yield. The obtained CV exhibited anodic and cathodic peaks for Pb(II), connoting a reduction in Pb2+ and oxidation in Pb2-. Bode plot phase angle displayed Sn(II) and Pb(II) with maxima phase, indicating the presence of time constants of the electrode processes in Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes. From the results in chapter 4, the XRD patterns exhibited good crystalline nature of CuS as a result of sharp and strong diffraction peaks obtained. There are eight peaks of 2θ angle between 26° and 79° relating to orthorhombic structure of SnS. While PbS has a cubic structure with polycrystalline nature, PbS/HDA and PbS both correspond to their crystalline planes of (200), (111), (220), (311), (222), (400), (331), (420) and (422) affirming to PbS QDs structure. SnS/HDA and SnS photosensitizers displayed eleven peaks between the values of 27.02° to 66.05° for SnS/HDA and 26.03° to 66.04° for SnS, in confirming the orthorhombic structure. SEM analysis revealed hexagonal structure for CuS, while PbS and SnS exhibited mesoporous nanostructures with spherical nanoparticles. HRTEM images indicated spherical nano-particles with particle sizes in the range of 3.14 - 44.39 nm. The outcome of HRTEM analysis revealed crystallite sizes varying as 10.90 – 11.57 nm, 3.14 – 5.95 nm and 14.96 – 44.39 nm for the CuS, PbS and SnS, originated from the primary ligands. HRTEM images originating from the Bis(N-1,4-Phenyl-N-Morhpo-dithiocarbamato bis(Mo/1,4-PHDTC) complexes indicated spherical nano-particles with particle sizes of 3.14 - 44.39 nm. Raman images in chapter 5 revealed the presence of Raman active modes of E2g 66 cm-1 and 304, cm-1 and E1g 627 cm-1 and 706 cm-1 for CuS, the active modes of TO 65 cm-1 and 2LO 626 cm-1 for PbS, active modes of B1g 69 cm-1 for SnS and 266 cm-1 for Ag. From the AFM results in chapter 5, CuS photosensitizer displayed a smooth surface and particle estimated to be 0.50 μm and height profile of 12percent. The PbS photosensitizer exhibited particle size of 1.82 μm and 0.654 μm for PbS/HDA, depicting a regular crystal growth rate. The size distribution of SnS nanoparticle at 357 nm connotes smooth surface and good compactness on the substrate. However, SnS/HDA at 122 nm displayed shape and size of non-symmetrical particles. AFM analysis in chapter 8 revealed good size roughness for CuS film. PbS exhibited particle size of 365 nm and size height of 18percent as the smoothest film, while PbS/HDA revealed 1.22 um size with 9percent size height. The evaluated particle sizes varied as 0.11- 1.18 um for SnS/HDA and 0.054 – 0.54 um for SnS films grown at 360 ℃ with size height of 16.8 and 8.4percent. The I-V efficiency obtained indicated that the CuS exhibited a much better efficiency in the QDSCs with higher Voc and the highest η being 2.85percent compared to CuS/HDA and Cu(II). High JSC of 11 mA/cm has been observed in the PbS/HDA QDSSCs, compared to the PbS and Pb(II) cells. The SnS/HDA exhibited a better performance compared to SnS and Sn(II) sensitizers due to the presence of HDA capping agent. , Thesis (MSc -- Faculty of Science and Agriculture, 2020
- Full Text:
- Date Issued: 2020-01
Synthesis of bioethanol from lignocellulosic materials: A focus on grass and waste paper as raw materials
- Authors: Vala, Mavula Kikwe
- Date: 2009-12
- Subjects: Ethanol as fuel , Biomass energy , Lignocellulose -- Biotechnology
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24499 , vital:63049
- Description: Biofuels are currently recognized as not only a necessity, but an inevitable pathway to secure the planet future energy needs. Food crops have been used (so far) as the biomass for bioethanol and biodiesel production. This has increased concerns over food security and led to the search for diversification and alternative feedstocks for biofuel production. The use of lignocellulosic materials, the most abundant, low cost and easy feedstock to harvest for bioethanol purpose, involves challenging production processes. Several approaches have been used to facilitate the breakdown of the biopolymer structure to produce fermentable sugars that can be converted to ethanol. Most of the approaches have used high temperatures and pressures and have often led to the production of inhibitors of fermentation. In this study, lignocellulosic materials from grass and newsprint were investigated as sources of biomass for bioethanol production using a chemical route (sulfuric acid hydrolysis) which made use of temperatures below 100°C at normal atmospheric pressure. Fermentation of toxic lignocellulosic hydrolyzates was possible after the development of a method for inhibitors removal. The method used treated wood chips as a stationary phase in a chromatographic column to remove inhibitors. This method is expected to be extended to applications such as in municipal wastewater treatment. Sugar yields of 22.26 and 8.9 g/L of hydrolyzate; and an ethanol yield of 184.5 and 130.4 mg/mL of must were achieved for 5g grass and newsprint respectively using optimum conditions of 2percent H2SO4 at 97.5°C for grass and 0.5percent H2SO4 at 97.5°C for newsprint during the hydrolysis process. Pure cellulose was used as a control for the biomass where 254.1 g/L of fermentable sugars were recovered from soluble cellulose and the yield of ethanol was 201.8 mg/mL. , Thesis (MSc) -- Faculty of Science and Agriculture, 2009
- Full Text:
- Date Issued: 2009-12
- Authors: Vala, Mavula Kikwe
- Date: 2009-12
- Subjects: Ethanol as fuel , Biomass energy , Lignocellulose -- Biotechnology
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24499 , vital:63049
- Description: Biofuels are currently recognized as not only a necessity, but an inevitable pathway to secure the planet future energy needs. Food crops have been used (so far) as the biomass for bioethanol and biodiesel production. This has increased concerns over food security and led to the search for diversification and alternative feedstocks for biofuel production. The use of lignocellulosic materials, the most abundant, low cost and easy feedstock to harvest for bioethanol purpose, involves challenging production processes. Several approaches have been used to facilitate the breakdown of the biopolymer structure to produce fermentable sugars that can be converted to ethanol. Most of the approaches have used high temperatures and pressures and have often led to the production of inhibitors of fermentation. In this study, lignocellulosic materials from grass and newsprint were investigated as sources of biomass for bioethanol production using a chemical route (sulfuric acid hydrolysis) which made use of temperatures below 100°C at normal atmospheric pressure. Fermentation of toxic lignocellulosic hydrolyzates was possible after the development of a method for inhibitors removal. The method used treated wood chips as a stationary phase in a chromatographic column to remove inhibitors. This method is expected to be extended to applications such as in municipal wastewater treatment. Sugar yields of 22.26 and 8.9 g/L of hydrolyzate; and an ethanol yield of 184.5 and 130.4 mg/mL of must were achieved for 5g grass and newsprint respectively using optimum conditions of 2percent H2SO4 at 97.5°C for grass and 0.5percent H2SO4 at 97.5°C for newsprint during the hydrolysis process. Pure cellulose was used as a control for the biomass where 254.1 g/L of fermentable sugars were recovered from soluble cellulose and the yield of ethanol was 201.8 mg/mL. , Thesis (MSc) -- Faculty of Science and Agriculture, 2009
- Full Text:
- Date Issued: 2009-12
Xenophobia in South Africa: a socio-legal analysis
- Authors: Sibanda, Samukeliso
- Date: 2011-04
- Subjects: Xenophobia -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25548 , vital:64334
- Description: The ways in which xenophobia continues to express itself in South Africa deserve to be noted at an advanced study. Over the past 15 years the expressions of xenophobia have been accompanied by increased deaths, more discrimination, increase of stereotyping of people of African descent and increased violence towards non-nationals, especially in the poorer parts of South Africa. Many of such xenophobic expressions have gone unnoticed and where they have been noticed, they have received little attention, leading to the exacerbation of the problem. The researcher of this study dwelt on a socio-legal analysis of xenophobia in South Africa. Appreciating the legal connotations and the expressions of xenophobia in South African society is a major concern of this study. To fulfill the objectives of this study, the researcher explores the extent and expression of xenophobia, in addition to analyzing and assessing the efficacy of legislative and other measures aimed to protect non-nationals in South Africa. The study investigates the role of state organizations, government and civil society and evaluates the impact of xenophobia on the enjoyment of human rights by non-nationals. A central objective of this study was to suggest alternative ways of explaining and understanding xenophobia and the responses to it. Empirical research was conducted to explore the extent of xenophobia in South Africa and how and why it is manifested in the way it is. Through in-depth face-to-face interviews it was revealed that the extent and manifestation of xenophobia differs in relation to particular communities, economic set ups and social settings; with poor communities being the most vulnerable to violent xenophobic attacks. Further, it was interesting to note that people have no firm understanding of what xenophobia entails as a social, legal, political and economical phenomenon. Again, it became evident that xenophobia still manifests in a country founded on values of equality, dignity and justice. Moreover, it was established that there is a weak link between law, human action and human behavior. It also became evident that education and sensitization need to be employed if xenophobic perceptions and behaviors are to be sufficiently dealt with. Recommendations were provided upon completion of the study. These included developing the law consciously, thus ensuring that the law has public legitimacy; effective law enforcement and prosecution; human rights education and training (especially in government departments, civil society organizations and institutions of learning); use of media and other communication channels to advocate for non discrimination, equality and respect for human rights, values and integration. Finally, the fight against xenophobia, racial discrimination and other related forms of intolerance needs to be taken up by all members of South African society and Africa at large. , Thesis (LLM) -- Faculty of Law, 2011
- Full Text:
- Date Issued: 2011-04
- Authors: Sibanda, Samukeliso
- Date: 2011-04
- Subjects: Xenophobia -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25548 , vital:64334
- Description: The ways in which xenophobia continues to express itself in South Africa deserve to be noted at an advanced study. Over the past 15 years the expressions of xenophobia have been accompanied by increased deaths, more discrimination, increase of stereotyping of people of African descent and increased violence towards non-nationals, especially in the poorer parts of South Africa. Many of such xenophobic expressions have gone unnoticed and where they have been noticed, they have received little attention, leading to the exacerbation of the problem. The researcher of this study dwelt on a socio-legal analysis of xenophobia in South Africa. Appreciating the legal connotations and the expressions of xenophobia in South African society is a major concern of this study. To fulfill the objectives of this study, the researcher explores the extent and expression of xenophobia, in addition to analyzing and assessing the efficacy of legislative and other measures aimed to protect non-nationals in South Africa. The study investigates the role of state organizations, government and civil society and evaluates the impact of xenophobia on the enjoyment of human rights by non-nationals. A central objective of this study was to suggest alternative ways of explaining and understanding xenophobia and the responses to it. Empirical research was conducted to explore the extent of xenophobia in South Africa and how and why it is manifested in the way it is. Through in-depth face-to-face interviews it was revealed that the extent and manifestation of xenophobia differs in relation to particular communities, economic set ups and social settings; with poor communities being the most vulnerable to violent xenophobic attacks. Further, it was interesting to note that people have no firm understanding of what xenophobia entails as a social, legal, political and economical phenomenon. Again, it became evident that xenophobia still manifests in a country founded on values of equality, dignity and justice. Moreover, it was established that there is a weak link between law, human action and human behavior. It also became evident that education and sensitization need to be employed if xenophobic perceptions and behaviors are to be sufficiently dealt with. Recommendations were provided upon completion of the study. These included developing the law consciously, thus ensuring that the law has public legitimacy; effective law enforcement and prosecution; human rights education and training (especially in government departments, civil society organizations and institutions of learning); use of media and other communication channels to advocate for non discrimination, equality and respect for human rights, values and integration. Finally, the fight against xenophobia, racial discrimination and other related forms of intolerance needs to be taken up by all members of South African society and Africa at large. , Thesis (LLM) -- Faculty of Law, 2011
- Full Text:
- Date Issued: 2011-04
Barriers to participation in sports among urban adolescents at an International School in Cape Town, South Africa
- Authors: Klaasen, Robyn Jade
- Date: 2021-10
- Subjects: Urban teenagers -- Sports , Sports administration
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22155 , vital:51991
- Description: The benefits of participating in sport have been well documented and great emphasis has been placed on the role that it plays in the development of character and social skills, apart from physical and psychological benefits. Sport represents an optimal means of enabling children and adolescents to meet their daily requirements for physical activity to maintain health. Conversely, despite all of the widely acknowledged benefits, participation in sport among children and adolescents continues to decline throughout the world. Although a great deal of research has been conducted to identify barriers to participation in sport, most of it has concerned poor, rural, disadvantaged, or other marginalised groups. As a consequence, a large proportion of the research has attributed low rates of participation in sport to practical barriers, which usually take the forms of either logistical problems or a lack of resources. The aim of this study was to identify the barriers to participation in sport among adolescents in an affluent, urban setting, at an international school in Cape Town, South Africa. The Barriers to Sport Participation Questionnaire was used to identify the social, personal, and practical barriers that affected 107 adolescents who were enrolled in the school. The data was analysed by means of the SPSS (IBM, Version 27) software package and seven significant barriers were identified. Fear of academic failure, environmental constraints, and lack of interest were identified as the primary barriers, thereby emphasising the significant influence of personal barriers, rather than practical ones. It was also found that the influence of particular barriers was greater on females than their male counterparts and that the respondents who either did not participate in sport themselves or were from households in which other members did not do so were more adversely affected by some barriers than the others. Significant correlations were found between some grades and certain barriers, the most notable being those between respondents in Grades 7, 9, and 10 and the fear of academic failure barrier. In light of these findings, it could be concluded that the global decline in participation in sport among the youth is a complex problem and that particular barriers, which might not have been identified in previous research, could be particularly influential in affluent environments. As it is evident that as barriers can be specific to particular groups and settings, the optimal means of overcoming them is unlikely to be found through the adoption of a one-size-fitsall approach. Instead, further research and customised interventions are required. , Thesis (HMS) -- Faculty of Health Sciences, 2021
- Full Text:
- Date Issued: 2021-10
- Authors: Klaasen, Robyn Jade
- Date: 2021-10
- Subjects: Urban teenagers -- Sports , Sports administration
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22155 , vital:51991
- Description: The benefits of participating in sport have been well documented and great emphasis has been placed on the role that it plays in the development of character and social skills, apart from physical and psychological benefits. Sport represents an optimal means of enabling children and adolescents to meet their daily requirements for physical activity to maintain health. Conversely, despite all of the widely acknowledged benefits, participation in sport among children and adolescents continues to decline throughout the world. Although a great deal of research has been conducted to identify barriers to participation in sport, most of it has concerned poor, rural, disadvantaged, or other marginalised groups. As a consequence, a large proportion of the research has attributed low rates of participation in sport to practical barriers, which usually take the forms of either logistical problems or a lack of resources. The aim of this study was to identify the barriers to participation in sport among adolescents in an affluent, urban setting, at an international school in Cape Town, South Africa. The Barriers to Sport Participation Questionnaire was used to identify the social, personal, and practical barriers that affected 107 adolescents who were enrolled in the school. The data was analysed by means of the SPSS (IBM, Version 27) software package and seven significant barriers were identified. Fear of academic failure, environmental constraints, and lack of interest were identified as the primary barriers, thereby emphasising the significant influence of personal barriers, rather than practical ones. It was also found that the influence of particular barriers was greater on females than their male counterparts and that the respondents who either did not participate in sport themselves or were from households in which other members did not do so were more adversely affected by some barriers than the others. Significant correlations were found between some grades and certain barriers, the most notable being those between respondents in Grades 7, 9, and 10 and the fear of academic failure barrier. In light of these findings, it could be concluded that the global decline in participation in sport among the youth is a complex problem and that particular barriers, which might not have been identified in previous research, could be particularly influential in affluent environments. As it is evident that as barriers can be specific to particular groups and settings, the optimal means of overcoming them is unlikely to be found through the adoption of a one-size-fitsall approach. Instead, further research and customised interventions are required. , Thesis (HMS) -- Faculty of Health Sciences, 2021
- Full Text:
- Date Issued: 2021-10
Investigating grade 6 teachers’ views and practices regarding creating an intellectually safe classroom environment
- Authors: Damana, Yanga
- Date: 2019-05
- Subjects: Classroom environment , Classroom management
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19947 , vital:44808
- Description: An intellectually safe classroom (ISC) is essential for teaching and learning to occur. The aim of this study was to investigate Grade 6 teachers’ views and practices regarding the creation of intellectually safe classroom environments. The paradigm that was used in the study was the interpretive paradigm and the research approach was qualitative. A case study design was used. Three Mdantsane primary schools was purposively selected and two Grade 6 teachers from each school were the participants. Semi structured interviews and observations were used to collect data. The research found that participants are cognizant of the need to develop ISC. They define ISC as a classroom that is both emotionally and physically safe for learning to occur. The participants are very conversant with the benefits of ISC. Most of the teachers purposefully tried to implement ISC. This included the establishment of classroom rules, and they acknowledged the role that the teacher plays in setting up an ISC and the manner in which they establish trust and co-operation within their classrooms. However, they are often constrained in their implementation of ISC by their own teaching styles and by factors outside of their control. This emphasised the pivotal role that teachers have in the establishment of an ISC. It is recommended that ISC be implemented in all classrooms with the entire school community working together to do so. , Thesis (MEd) -- Faculty of Education, 2019
- Full Text:
- Date Issued: 2019-05
- Authors: Damana, Yanga
- Date: 2019-05
- Subjects: Classroom environment , Classroom management
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/19947 , vital:44808
- Description: An intellectually safe classroom (ISC) is essential for teaching and learning to occur. The aim of this study was to investigate Grade 6 teachers’ views and practices regarding the creation of intellectually safe classroom environments. The paradigm that was used in the study was the interpretive paradigm and the research approach was qualitative. A case study design was used. Three Mdantsane primary schools was purposively selected and two Grade 6 teachers from each school were the participants. Semi structured interviews and observations were used to collect data. The research found that participants are cognizant of the need to develop ISC. They define ISC as a classroom that is both emotionally and physically safe for learning to occur. The participants are very conversant with the benefits of ISC. Most of the teachers purposefully tried to implement ISC. This included the establishment of classroom rules, and they acknowledged the role that the teacher plays in setting up an ISC and the manner in which they establish trust and co-operation within their classrooms. However, they are often constrained in their implementation of ISC by their own teaching styles and by factors outside of their control. This emphasised the pivotal role that teachers have in the establishment of an ISC. It is recommended that ISC be implemented in all classrooms with the entire school community working together to do so. , Thesis (MEd) -- Faculty of Education, 2019
- Full Text:
- Date Issued: 2019-05
The obligation of unmarried biological parents to provide financial support for their children: a contemporary assessment from a children’s rights perspective
- Authors: Obi, Lauretta
- Date: 2021-07
- Subjects: Children's rights , Support (Domestic relations)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22445 , vital:52322
- Description: In South Africa, the compelling task of unmarried biological parents to provide financial support (in the form of paying monthly maintenance) to their children, as a matter of children’s rights, is intended to ensure the children’s economic and psychological well-being both in the present and future. This study seeks, within the private judicial system and socio-economic context, to explore the nature of children’s rights as they pertain to parental financial support and, the responsibilities of unmarried parents to provide financial support for their biological children until they become self-supporting. This is significant as many unmarried parents usually downplay their responsibilities towards ensuring the well-being of their minor children. Section 28 of the South African Constitution of 1996 enshrines it as a duty of parents to fulfil this aspect of their children’s fundamental rights and our courts apply these rules to the letter. The task of providing support to children basically rests with their birth parents as the primary care givers, and in the absence of these parents or, due to their inability, this legal obligation falls on the state. , Thesis (LLM) -- Faculty of Law, 2021
- Full Text:
- Date Issued: 2021-07
- Authors: Obi, Lauretta
- Date: 2021-07
- Subjects: Children's rights , Support (Domestic relations)
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/22445 , vital:52322
- Description: In South Africa, the compelling task of unmarried biological parents to provide financial support (in the form of paying monthly maintenance) to their children, as a matter of children’s rights, is intended to ensure the children’s economic and psychological well-being both in the present and future. This study seeks, within the private judicial system and socio-economic context, to explore the nature of children’s rights as they pertain to parental financial support and, the responsibilities of unmarried parents to provide financial support for their biological children until they become self-supporting. This is significant as many unmarried parents usually downplay their responsibilities towards ensuring the well-being of their minor children. Section 28 of the South African Constitution of 1996 enshrines it as a duty of parents to fulfil this aspect of their children’s fundamental rights and our courts apply these rules to the letter. The task of providing support to children basically rests with their birth parents as the primary care givers, and in the absence of these parents or, due to their inability, this legal obligation falls on the state. , Thesis (LLM) -- Faculty of Law, 2021
- Full Text:
- Date Issued: 2021-07
Sustainability challenges of community newspapers: The case study of iDike-Lethu Community Newspaper
- Authors: Ndarane, Luvuyo Gladstone
- Date: 2022-09
- Subjects: Community newspapers , Journalism, Regional
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23754 , vital:60485
- Description: Community newspapers are an important source of information and play a vital role in the development of communities. They are, therefore, an important stakeholder in community development. IDike-Lethu community newspaper`s presence in the community of Alice and in the areas where it is distributed is facilitating communication and development in these areas. Raymond Mhlaba Local Municipality is benefiting in the presence of iDike-Lethu because this newspaper is the conduit through which communication to its citizens is submitted. This study assessed the challenges iDike- Lethu is having that impact on its maximum contribution in this society. Participants in this study are residents of Alice and are readers of iDike-Lethu Community Newspaper. This study adopted a mixed method design in which questionnaires and interviews were used to collect primary data. Data collected was analyzed using both qualitative and quantitative methods. Major findings that impede smooth operations in this newspaper were discovered. These include inadequate funding, lack of technical backing and lack of community support. The study findings show that with all the challenges iDike-Lethu is having it continues to play a meaningful role by disseminating information, promoting local culture, equipping communities with skills and providing a platform on which these communities including local businesses send information across. Recommendations include the need for this newspaper to find a commercial, profitable and sustainable financial model which will support and reinforce its operations. This study will contribute in further research of methods to link communities and community newspapers to work harmoniously. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2022
- Full Text:
- Date Issued: 2022-09
Sustainability challenges of community newspapers: The case study of iDike-Lethu Community Newspaper
- Authors: Ndarane, Luvuyo Gladstone
- Date: 2022-09
- Subjects: Community newspapers , Journalism, Regional
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23754 , vital:60485
- Description: Community newspapers are an important source of information and play a vital role in the development of communities. They are, therefore, an important stakeholder in community development. IDike-Lethu community newspaper`s presence in the community of Alice and in the areas where it is distributed is facilitating communication and development in these areas. Raymond Mhlaba Local Municipality is benefiting in the presence of iDike-Lethu because this newspaper is the conduit through which communication to its citizens is submitted. This study assessed the challenges iDike- Lethu is having that impact on its maximum contribution in this society. Participants in this study are residents of Alice and are readers of iDike-Lethu Community Newspaper. This study adopted a mixed method design in which questionnaires and interviews were used to collect primary data. Data collected was analyzed using both qualitative and quantitative methods. Major findings that impede smooth operations in this newspaper were discovered. These include inadequate funding, lack of technical backing and lack of community support. The study findings show that with all the challenges iDike-Lethu is having it continues to play a meaningful role by disseminating information, promoting local culture, equipping communities with skills and providing a platform on which these communities including local businesses send information across. Recommendations include the need for this newspaper to find a commercial, profitable and sustainable financial model which will support and reinforce its operations. This study will contribute in further research of methods to link communities and community newspapers to work harmoniously. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2022
- Full Text:
- Date Issued: 2022-09
Water governance and social equity in South Africa: a case study of Amathole District Municipality.
- Authors: Hutete, Clarity
- Date: 2022-03
- Subjects: Municipal water supply
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21931 , vital:51844
- Description: South Africa has reformed its water governance to remedy the prominent disparities in water service provision that resulted from the legacy of apartheid. However, despite the new policy reforms and strategies adopted, inequities in water governance remain prevalent. Those residing in marginalised and poor rural areas are the most vulnerable and highly affected by this phenomenon. While this has been attributed to several factors, such as fragmentation of the water sector and lack of capacity, among other reasons, an analysis of the literature revealed that the absence of a water governance framework for social equity is highly prevalent in the context of Amathole District Municipality (ADM) where the research was conducted. Hence, the study's main objective was to develop a water governance framework for social equity that can be utilised to advise councils and policymakers on the attainment of social equity by water service providers at the local level. The study utilised the constructivist research philosophy by adopting a qualitative case study research design and an inductive research approach to address the research questions. Focus group discussions, semi-structured interviews, participant observations and document analysis were used to collect data. A total sample of thirty-four (n=34) participants was purposefully selected; twenty participants (n=20) participated in semi-structured interviews, while fourteen (n=14) participants were engaged through focus group discussions. Findings obtained from the thematic data analysis utilised revealed that while human rights principles and social equity values underpin South Africa’s water reforms, Amathole District Municipality is yet to fully absorb these foundational concepts into its water governance. The study revealed that this is largely attributed to a lack of meaningful participation, limited transparency and accountability in the processes and procedures of the municipality. Results also revealed that persistent inequities still exist in Amathole District Municipality as reflected by the unequal distribution of water services, inconsistency in services provision, lack of transparency and established procedures to guarantee procedural fairness and limited impact on interventions specifically in rural areas. Furthermore, the study revealed that the municipality’s efforts to address water inequities are highly undermined by various economic, environmental, socio- economic, and institutional governance factors. Therefore, the study recommended a Water Governance Framework for Social Equity (WGFSE) and proffered recommendations to enhance social equity for Amathole District Municipality and other municipalities with similar contexts. , Thesis (MPA) -- University of Fort Hare, 2021
- Full Text:
- Date Issued: 2022-03
- Authors: Hutete, Clarity
- Date: 2022-03
- Subjects: Municipal water supply
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21931 , vital:51844
- Description: South Africa has reformed its water governance to remedy the prominent disparities in water service provision that resulted from the legacy of apartheid. However, despite the new policy reforms and strategies adopted, inequities in water governance remain prevalent. Those residing in marginalised and poor rural areas are the most vulnerable and highly affected by this phenomenon. While this has been attributed to several factors, such as fragmentation of the water sector and lack of capacity, among other reasons, an analysis of the literature revealed that the absence of a water governance framework for social equity is highly prevalent in the context of Amathole District Municipality (ADM) where the research was conducted. Hence, the study's main objective was to develop a water governance framework for social equity that can be utilised to advise councils and policymakers on the attainment of social equity by water service providers at the local level. The study utilised the constructivist research philosophy by adopting a qualitative case study research design and an inductive research approach to address the research questions. Focus group discussions, semi-structured interviews, participant observations and document analysis were used to collect data. A total sample of thirty-four (n=34) participants was purposefully selected; twenty participants (n=20) participated in semi-structured interviews, while fourteen (n=14) participants were engaged through focus group discussions. Findings obtained from the thematic data analysis utilised revealed that while human rights principles and social equity values underpin South Africa’s water reforms, Amathole District Municipality is yet to fully absorb these foundational concepts into its water governance. The study revealed that this is largely attributed to a lack of meaningful participation, limited transparency and accountability in the processes and procedures of the municipality. Results also revealed that persistent inequities still exist in Amathole District Municipality as reflected by the unequal distribution of water services, inconsistency in services provision, lack of transparency and established procedures to guarantee procedural fairness and limited impact on interventions specifically in rural areas. Furthermore, the study revealed that the municipality’s efforts to address water inequities are highly undermined by various economic, environmental, socio- economic, and institutional governance factors. Therefore, the study recommended a Water Governance Framework for Social Equity (WGFSE) and proffered recommendations to enhance social equity for Amathole District Municipality and other municipalities with similar contexts. , Thesis (MPA) -- University of Fort Hare, 2021
- Full Text:
- Date Issued: 2022-03
Indigenous knowledge systems and gender relations interface and its implications for food security: the case of Khambashe rural households in the Amathole District, South Africa
- Garutsa, T C https://orcid.org/0000-0003-1904-2764
- Authors: Garutsa, T C https://orcid.org/0000-0003-1904-2764
- Date: 2015-01
- Subjects: Food security -- South Africa -- Eastern Cape , Indigenous peoples -- South Africa -- Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/26581 , vital:65660
- Description: The aim of this study was to find out about how the intersection of indigenous knowledge systems and gender relations affects food security in the rural households of the Khambashe village in the Eastern Cape. The focus is on food security-related indigenous knowledge utilized by women rather than the general indigenous knowledge of the people in the Eastern Cape. Ample literature exists on food security and gender, food security and indigenous knowledge systems and the role of gender dynamics in the application of indigenous knowledge systems. However, there is dearth of literature on studies on the role of the indigenous knowledge systems-gender relations interface in food security. Hence this study was directed at investigating the indigenous knowledge systems-gender dynamics interplay and its implications for food security and sustainable development with specific reference to the rural households of Khambashe village of the Eastern Cape Province. Furthermore, the study seeks to determine factors accounting for the attrition of women’s indigenous knowledge in food production systems of the Khambashe rural households. The main position advanced in this thesis is that domination coupled with marginalisation of women and indigenous knowledge systems by hegemonic Western power/knowledge and traditional African practices account for challenges faced by rural households with regard to food security and sustainable livelihoods. Put differently, the core argument of this study is that the intersection between gender and indigenous knowledge systems has two opposing possibilities for food security. On the one hand, through the various roles of women in the application of indigenous knowledge systems in rural areas, the indigenous knowledge and gender relations interplay can operate to enhance the likelihood of achieving sustainable rural livelihoods and hence food security. On the other hand, gender oppression, subjugation, exclusion and marginalization through various practices such as the utilization of discriminatory patriarchal cultural values and norms can inhibit the application of the rich folk knowledge reservoir of ideas held by women in food production processes. Key illustrative examples of the constraints imposed by cultural traditions that pose problems for the realization of sustainable rural livelihoods are cultural practices which prohibit women to inter alia own and inherit land. These cultural practices also deprive women the liberty to make their own decisions without the consultation of men despite being sole providers of their own households. In other words, lack of access to assets and other resources owing to the marginalization of local knowledge by the dominant Western-based scientific knowledge systems and culturally-derived gender discriminatory practices make the role of women in the process of utilizing indigenous knowledge systems for the purposes of food security difficult. The theoretical framework of this study is drawn from the post-development discourse derived from Foucault’s archaeology of power and knowledge, ecofeminism and African feminism. Such a framework has a utility to reinvigorate marginalised indigenous knowledge and thereby help women reclaim their leadership in processes of ensuring food security. In a situation where indigenous knowledge systems have been excluded and subjugated by the dominant Western knowledge systems, an extended post-development discourse of this nature is transformative. While Foucault’s theory will provide key insights around power/knowledge dynamics and issues, ecofeminism and African feminism will extend these insights in the exploration of the patterns of power in both the knowledge and gender relations domains. In fact interactions in food production processes are embedded in systematized knowledge and traditional gender relations. Hence, in order to ensure a deep-going analysis of these phenomena, Foucault’s framework on power/knowledge is augmented by the ideas of ecofeminism and African feminism owing to the fact that systems of domination whether in the knowledge arena or gender relations domain are responsible for the challenges relating to food secure households and sustainable rural livelihoods. The rationale for this approach is that subjugation and marginalization of indigenous knowledge systems by Western hegemonic power/knowledge coupled with exclusionary and discriminatory practices of patriarchal cultural values is seen as inhibiting the proper application of indigenous knowledge in food production processes. The extended post-development discourse adopted for this study takes into consideration the fact that oppression and discrimination the world over has taken the Foucauldian power/knowledge dimension in the sense that women in rural African settings are not only prevented by Western science from the application of indigenous knowledge for the development of sustainable livelihoods but that their own cultural traditions are also a hindrance towards them owning land and property, making their own decisions without recourse to men and exercising their own authority. A mixed method approach combining qualitative and quantitative research design was utilized in order to gain a full grasp of nuances of the interface between indigenous knowledge and gender dynamics in food production processes in Khambashe. This methodological triangulation was used for purposes of enhancing the capturing of comprehensive data and a holistic understanding of food security issues in the area. Further, owing to the fact that survey questionnaires as research instruments would have not given a voice to women as key research participants and that the deployment of in-depth interviews alone as research tools would have compromised the generalizability of the findings of the study, each of the two research methods were to confirm, clarify, complement, enhance and elaborate the research results of the other. In other words, in order to counterbalance the limitation of questionnaires with regard to artificiality and not affording a voice to research participants in-depth interviews were conducted. The lack of generalizability of the latter was compensated by the high degree of representativity afforded by the use of the former (that is, questionnaires). As already indicated above, the study setting for the empirical data was the Khambashe village in the Eastern Cape. Information gathered included the more positive effects of the IK-gender relations interplay on food security covered in Chapter 7. This chapter described and analysed the various roles women play inter alia animal husbandry, crop production, creation and utilization of indigenous technology in food production processes and in post-harvesting practices. In contrast, chapter 8 investigated and discusses the various constrains which account for the hindrance in the operationalization of IK in food production processes by women. Chief among the identified constrains in Khambashe are the marginalization of local knowledge by hegemonic Western science and the discriminatory traditional practices. The research results of this study show that despite the key role of women in the application of local knowledge, practices and technologies in food production processes, the penetration, colonization and domination of the African socio-economic and cultural sphere by the West has resulted in the deterioration in the use of indigenous knowledge. Imperialistic Western knowledge masquerading as modern science and technology manifested in inter alia chemical fertilizers and modified food is a constraint to the utility of women’s indigenous knowledge and practices that ensures both food security and sustainable development. In view of the fact that failure to utilize readily available indigenous knowledge, practices and technologies owing to the marginalisation of local epistemes by Western science and the discriminatory African traditional practices and gender relations has led to further impoverishment of rural communities, there is a need to both empower women and to revitalize their indigenous knowledge for purposes of food security and sustainable development in rural areas such as Khambashe. , Thesis (PhD) -- Faculty of Social Sciences & Humanities, 2015
- Full Text:
- Date Issued: 2015-01
- Authors: Garutsa, T C https://orcid.org/0000-0003-1904-2764
- Date: 2015-01
- Subjects: Food security -- South Africa -- Eastern Cape , Indigenous peoples -- South Africa -- Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/26581 , vital:65660
- Description: The aim of this study was to find out about how the intersection of indigenous knowledge systems and gender relations affects food security in the rural households of the Khambashe village in the Eastern Cape. The focus is on food security-related indigenous knowledge utilized by women rather than the general indigenous knowledge of the people in the Eastern Cape. Ample literature exists on food security and gender, food security and indigenous knowledge systems and the role of gender dynamics in the application of indigenous knowledge systems. However, there is dearth of literature on studies on the role of the indigenous knowledge systems-gender relations interface in food security. Hence this study was directed at investigating the indigenous knowledge systems-gender dynamics interplay and its implications for food security and sustainable development with specific reference to the rural households of Khambashe village of the Eastern Cape Province. Furthermore, the study seeks to determine factors accounting for the attrition of women’s indigenous knowledge in food production systems of the Khambashe rural households. The main position advanced in this thesis is that domination coupled with marginalisation of women and indigenous knowledge systems by hegemonic Western power/knowledge and traditional African practices account for challenges faced by rural households with regard to food security and sustainable livelihoods. Put differently, the core argument of this study is that the intersection between gender and indigenous knowledge systems has two opposing possibilities for food security. On the one hand, through the various roles of women in the application of indigenous knowledge systems in rural areas, the indigenous knowledge and gender relations interplay can operate to enhance the likelihood of achieving sustainable rural livelihoods and hence food security. On the other hand, gender oppression, subjugation, exclusion and marginalization through various practices such as the utilization of discriminatory patriarchal cultural values and norms can inhibit the application of the rich folk knowledge reservoir of ideas held by women in food production processes. Key illustrative examples of the constraints imposed by cultural traditions that pose problems for the realization of sustainable rural livelihoods are cultural practices which prohibit women to inter alia own and inherit land. These cultural practices also deprive women the liberty to make their own decisions without the consultation of men despite being sole providers of their own households. In other words, lack of access to assets and other resources owing to the marginalization of local knowledge by the dominant Western-based scientific knowledge systems and culturally-derived gender discriminatory practices make the role of women in the process of utilizing indigenous knowledge systems for the purposes of food security difficult. The theoretical framework of this study is drawn from the post-development discourse derived from Foucault’s archaeology of power and knowledge, ecofeminism and African feminism. Such a framework has a utility to reinvigorate marginalised indigenous knowledge and thereby help women reclaim their leadership in processes of ensuring food security. In a situation where indigenous knowledge systems have been excluded and subjugated by the dominant Western knowledge systems, an extended post-development discourse of this nature is transformative. While Foucault’s theory will provide key insights around power/knowledge dynamics and issues, ecofeminism and African feminism will extend these insights in the exploration of the patterns of power in both the knowledge and gender relations domains. In fact interactions in food production processes are embedded in systematized knowledge and traditional gender relations. Hence, in order to ensure a deep-going analysis of these phenomena, Foucault’s framework on power/knowledge is augmented by the ideas of ecofeminism and African feminism owing to the fact that systems of domination whether in the knowledge arena or gender relations domain are responsible for the challenges relating to food secure households and sustainable rural livelihoods. The rationale for this approach is that subjugation and marginalization of indigenous knowledge systems by Western hegemonic power/knowledge coupled with exclusionary and discriminatory practices of patriarchal cultural values is seen as inhibiting the proper application of indigenous knowledge in food production processes. The extended post-development discourse adopted for this study takes into consideration the fact that oppression and discrimination the world over has taken the Foucauldian power/knowledge dimension in the sense that women in rural African settings are not only prevented by Western science from the application of indigenous knowledge for the development of sustainable livelihoods but that their own cultural traditions are also a hindrance towards them owning land and property, making their own decisions without recourse to men and exercising their own authority. A mixed method approach combining qualitative and quantitative research design was utilized in order to gain a full grasp of nuances of the interface between indigenous knowledge and gender dynamics in food production processes in Khambashe. This methodological triangulation was used for purposes of enhancing the capturing of comprehensive data and a holistic understanding of food security issues in the area. Further, owing to the fact that survey questionnaires as research instruments would have not given a voice to women as key research participants and that the deployment of in-depth interviews alone as research tools would have compromised the generalizability of the findings of the study, each of the two research methods were to confirm, clarify, complement, enhance and elaborate the research results of the other. In other words, in order to counterbalance the limitation of questionnaires with regard to artificiality and not affording a voice to research participants in-depth interviews were conducted. The lack of generalizability of the latter was compensated by the high degree of representativity afforded by the use of the former (that is, questionnaires). As already indicated above, the study setting for the empirical data was the Khambashe village in the Eastern Cape. Information gathered included the more positive effects of the IK-gender relations interplay on food security covered in Chapter 7. This chapter described and analysed the various roles women play inter alia animal husbandry, crop production, creation and utilization of indigenous technology in food production processes and in post-harvesting practices. In contrast, chapter 8 investigated and discusses the various constrains which account for the hindrance in the operationalization of IK in food production processes by women. Chief among the identified constrains in Khambashe are the marginalization of local knowledge by hegemonic Western science and the discriminatory traditional practices. The research results of this study show that despite the key role of women in the application of local knowledge, practices and technologies in food production processes, the penetration, colonization and domination of the African socio-economic and cultural sphere by the West has resulted in the deterioration in the use of indigenous knowledge. Imperialistic Western knowledge masquerading as modern science and technology manifested in inter alia chemical fertilizers and modified food is a constraint to the utility of women’s indigenous knowledge and practices that ensures both food security and sustainable development. In view of the fact that failure to utilize readily available indigenous knowledge, practices and technologies owing to the marginalisation of local epistemes by Western science and the discriminatory African traditional practices and gender relations has led to further impoverishment of rural communities, there is a need to both empower women and to revitalize their indigenous knowledge for purposes of food security and sustainable development in rural areas such as Khambashe. , Thesis (PhD) -- Faculty of Social Sciences & Humanities, 2015
- Full Text:
- Date Issued: 2015-01
The relationship between green behaviours and their effect on the performance of small businesses in South Africa
- Authors: Banana, Zingisa
- Date: 2021-01
- Subjects: Small business--Management , Environmental economics
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21377 , vital:48514
- Description: Purpose: Academics and the government are placing more emphasis and importance on the role that enterprises can play in response to challenges of the environment. This study aimed to establish the relationship between green behaviours and the performance of small businesses in South Africa. Green behaviours are measured as consisting of green entrepreneurial orientation, green technology dynamism and green innovation behaviour. Conversely, performance is defined as consisting of environmental performance, objective performance and subjective performance. Design/methodology/approach: To achieve the purpose of this study, the study adopted a positivist paradigm which is motivated by the quantitative approach using a descriptive research design. Self-administered questionnaires were employed with a sample of 180 participants that were randomly selected across small businesses in the Buffalo City Metropolitan Municipality in the Eastern Cape province of South Africa. Findings/results: The major findings of the study, using simple linear regression analysis, revealed that a significant positive relationship between green entrepreneurial orientation and environmental, objective and subjective performance does exist. However, the hierarchical regression analysis results revealed that green technology dynamism and green innovation behaviour do not moderate the relationship between green entrepreneurial orientation and performance as measured by environmental, objective and subjective performance dimensions. Practical implications: Based on the findings of the study, small businesses need to develop policy related to promoting green behaviours, given that green entrepreneurial orientation has been found to be related to performance. Originality/value: The results of this study could guide small business owners and managers in the implementation of environmentally-friendly practices in an effort to reduce green economy issues and environmental problems facing the present generation. , Thesis (MCom) (Business Management) -- University of Fort Hare, 2021
- Full Text:
- Date Issued: 2021-01
- Authors: Banana, Zingisa
- Date: 2021-01
- Subjects: Small business--Management , Environmental economics
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/21377 , vital:48514
- Description: Purpose: Academics and the government are placing more emphasis and importance on the role that enterprises can play in response to challenges of the environment. This study aimed to establish the relationship between green behaviours and the performance of small businesses in South Africa. Green behaviours are measured as consisting of green entrepreneurial orientation, green technology dynamism and green innovation behaviour. Conversely, performance is defined as consisting of environmental performance, objective performance and subjective performance. Design/methodology/approach: To achieve the purpose of this study, the study adopted a positivist paradigm which is motivated by the quantitative approach using a descriptive research design. Self-administered questionnaires were employed with a sample of 180 participants that were randomly selected across small businesses in the Buffalo City Metropolitan Municipality in the Eastern Cape province of South Africa. Findings/results: The major findings of the study, using simple linear regression analysis, revealed that a significant positive relationship between green entrepreneurial orientation and environmental, objective and subjective performance does exist. However, the hierarchical regression analysis results revealed that green technology dynamism and green innovation behaviour do not moderate the relationship between green entrepreneurial orientation and performance as measured by environmental, objective and subjective performance dimensions. Practical implications: Based on the findings of the study, small businesses need to develop policy related to promoting green behaviours, given that green entrepreneurial orientation has been found to be related to performance. Originality/value: The results of this study could guide small business owners and managers in the implementation of environmentally-friendly practices in an effort to reduce green economy issues and environmental problems facing the present generation. , Thesis (MCom) (Business Management) -- University of Fort Hare, 2021
- Full Text:
- Date Issued: 2021-01
Characterization of bioflocculants produced by consortia of three marine bacteria belonging to the genera bacillus and cobetia previously isolated from the bottom sediment of Algoa Bay in the Eastern Cape Province of South Africa
- Ugbenyen, Anthony Moses https://orcid.org/0000-0002-1381-3428
- Authors: Ugbenyen, Anthony Moses https://orcid.org/0000-0002-1381-3428
- Date: 2013
- Subjects: Water -- Purification -- Flocculation , Water quality management , Flocculation
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24454 , vital:62804
- Description: The bioflocculant-producing potentials of three marine bacteria isolated from the sediment samples of Algoa Bay in the Eastern Cape Province of South Africa were assessed. Analysis of the partial nucleotide sequence of the 16S rDNA of the bacteria revealed 99 percent, 99 percent, and 98 percent similarity to Cobetia sp. L222, Bacillus sp. A-5A, and Bacillus sp. HXG-C1 respectively and the sequence was deposited in GenBank as Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert (accession number JF799092, JF799093, and HQ537128 respectively). Cultivation condition studies for Cobetia sp. OAUIFE revealed that bioflocculant production was optimal with an inoculum size of 2 percent (v/v), initial pH of 6.0, Mn2+ as the metal ion, and glucose as the carbon source. Metal ions, including Na+, K+, Li+, Ca2+and Mg2+ stimulated bioflocculant production resulting in flocculating activity of above 90 percent. This crude bioflocculant is thermally stable, with about 78 percent of its flocculating activity remaining after heating at 100 oC for 25 min. Analysis of the purified bioflocculant revealed it to be an acidic extracellular polysaccharide. FTIR analysis revealed the presence of methoxyl, hydroxyl, and carboxyl - groups in the compound bioflocculant and SEM micrograph of the bioflocculant revealed a crystal-linear structure. On the other hand, bioflocculant production by Bacillus sp. MAYA was optimal when glucose (95.6 percent flocculating activity) and ammonium nitrate (83.3 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 2 percent (v/v); initial pH 6; and Ca2+ as coagulant aid. Chemical analysis of the purified bioflocculant shows that it is composed of uronic acid, neutral sugar and protein. FTIR analysis also revealed the presence of methoxyl, hydroxyl, carboxyl and amino- groups in this bioflocculant. The bioflocculant is thermostable with about 65.6 percent residual flocculating activity retained after heating the bioflocculant at 100 oC for 25 min. However bioflocculant production by Bacillus sp. Gilbert was optimal when sodium carbonate (95.2 percent flocculating activity) and potassium nitrate (76.6 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 3 percent (v/v); initial pH 9; and Al3+ as cation. The crude bioflocculant retained 44.2 percent residual flocculating activity after heating at 100 oC for 15 min. FTIR analysis reveals the presence of hydroxyl, carboxyl and methylene - groups in the compound bioflocculant. SEM micrograph of the bioflocculant revealed an amorphous compound. The consortia of these bacteria strains also produced bioflocculants with high flocculating activities which were highly efficient in removing turbidity and chemical oxygen demand (COD) from brewery wastewater, diary wastewater and river water. The bioflocculants from the consortia seemed better than traditional flocculants such as alum . The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE and Bacillus sp. MAYA showed that this extracellular bioflocculant, composed of 66percent uronic acid and 31percent protein and an optimum flocculation (90 percent) of kaolin suspension, when the dosage concentration was 0.8 mg/ml, under weak alkaline pH of 8, and Ca2+ as a coagulant aid. The bioflocculant is thermally stable, with a high residual flocculating activity of 86.7 percent, 89.3 percent and 87.0 percent after heating at 50 oC, 80 oC and 100 oC for 25 min respectively. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl functional groups. Scanning electron microscopy (SEM) image revealed a crystal-linear spongy-like bioflocculant structure and EDX analysis of the purified bioflocculant showed that the elemental composition in mass proportion of C,N,O,S and P was 6.67:6.23:37.55:0.38:4.42 (percent w/w). However, the characteristics of the bioflocculant produced by the consortium of Cobetia sp OAUIFE and Bacillus sp. Gilbert showed an optimum flocculation (90 percent) of kaolin suspension when the dosage concentration was 0.2 mg/ml, under neutral pH of 7, and Ca2+ as a coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl and carbonyl functional groups. Scanning electron microscopy (SEM) image revealed an amorphous morphology. On the other hand the bioflocculant produced by the consortium of Bacillus sp. MAYA and Bacillus sp. Gilbert showed similar characteristic with the bioflocculant from the consortium of Cobetia sp. OAUIFE and Bacillus sp. Gilbert except for Al3+ being the preferred coagulant aid. The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert showed an optimum flocculation (87 percent) of kaolin suspension when the dosage concentration was 1.0 mg/ml. Under strong alkaline pH of 12, flocculating activity reached (95 percent) when Al3+ was the coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl and phosphoryl functional groups. Scanning electron microscopy (SEM) image revealed a flaky amorphous morphological structure. Due to the excellent COD and turbidity removal efficiencies of the bioflocculants produced by the consortia, these make those attractive candidates for use in water and wastewater treatment. , Thesis (PhD) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013
- Authors: Ugbenyen, Anthony Moses https://orcid.org/0000-0002-1381-3428
- Date: 2013
- Subjects: Water -- Purification -- Flocculation , Water quality management , Flocculation
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/24454 , vital:62804
- Description: The bioflocculant-producing potentials of three marine bacteria isolated from the sediment samples of Algoa Bay in the Eastern Cape Province of South Africa were assessed. Analysis of the partial nucleotide sequence of the 16S rDNA of the bacteria revealed 99 percent, 99 percent, and 98 percent similarity to Cobetia sp. L222, Bacillus sp. A-5A, and Bacillus sp. HXG-C1 respectively and the sequence was deposited in GenBank as Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert (accession number JF799092, JF799093, and HQ537128 respectively). Cultivation condition studies for Cobetia sp. OAUIFE revealed that bioflocculant production was optimal with an inoculum size of 2 percent (v/v), initial pH of 6.0, Mn2+ as the metal ion, and glucose as the carbon source. Metal ions, including Na+, K+, Li+, Ca2+and Mg2+ stimulated bioflocculant production resulting in flocculating activity of above 90 percent. This crude bioflocculant is thermally stable, with about 78 percent of its flocculating activity remaining after heating at 100 oC for 25 min. Analysis of the purified bioflocculant revealed it to be an acidic extracellular polysaccharide. FTIR analysis revealed the presence of methoxyl, hydroxyl, and carboxyl - groups in the compound bioflocculant and SEM micrograph of the bioflocculant revealed a crystal-linear structure. On the other hand, bioflocculant production by Bacillus sp. MAYA was optimal when glucose (95.6 percent flocculating activity) and ammonium nitrate (83.3 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 2 percent (v/v); initial pH 6; and Ca2+ as coagulant aid. Chemical analysis of the purified bioflocculant shows that it is composed of uronic acid, neutral sugar and protein. FTIR analysis also revealed the presence of methoxyl, hydroxyl, carboxyl and amino- groups in this bioflocculant. The bioflocculant is thermostable with about 65.6 percent residual flocculating activity retained after heating the bioflocculant at 100 oC for 25 min. However bioflocculant production by Bacillus sp. Gilbert was optimal when sodium carbonate (95.2 percent flocculating activity) and potassium nitrate (76.6 percent flocculating activity) were used as carbon and nitrogen sources respectively; inoculum size was 3 percent (v/v); initial pH 9; and Al3+ as cation. The crude bioflocculant retained 44.2 percent residual flocculating activity after heating at 100 oC for 15 min. FTIR analysis reveals the presence of hydroxyl, carboxyl and methylene - groups in the compound bioflocculant. SEM micrograph of the bioflocculant revealed an amorphous compound. The consortia of these bacteria strains also produced bioflocculants with high flocculating activities which were highly efficient in removing turbidity and chemical oxygen demand (COD) from brewery wastewater, diary wastewater and river water. The bioflocculants from the consortia seemed better than traditional flocculants such as alum . The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE and Bacillus sp. MAYA showed that this extracellular bioflocculant, composed of 66percent uronic acid and 31percent protein and an optimum flocculation (90 percent) of kaolin suspension, when the dosage concentration was 0.8 mg/ml, under weak alkaline pH of 8, and Ca2+ as a coagulant aid. The bioflocculant is thermally stable, with a high residual flocculating activity of 86.7 percent, 89.3 percent and 87.0 percent after heating at 50 oC, 80 oC and 100 oC for 25 min respectively. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl functional groups. Scanning electron microscopy (SEM) image revealed a crystal-linear spongy-like bioflocculant structure and EDX analysis of the purified bioflocculant showed that the elemental composition in mass proportion of C,N,O,S and P was 6.67:6.23:37.55:0.38:4.42 (percent w/w). However, the characteristics of the bioflocculant produced by the consortium of Cobetia sp OAUIFE and Bacillus sp. Gilbert showed an optimum flocculation (90 percent) of kaolin suspension when the dosage concentration was 0.2 mg/ml, under neutral pH of 7, and Ca2+ as a coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl and carbonyl functional groups. Scanning electron microscopy (SEM) image revealed an amorphous morphology. On the other hand the bioflocculant produced by the consortium of Bacillus sp. MAYA and Bacillus sp. Gilbert showed similar characteristic with the bioflocculant from the consortium of Cobetia sp. OAUIFE and Bacillus sp. Gilbert except for Al3+ being the preferred coagulant aid. The characteristics of the bioflocculant produced by the consortium of Cobetia sp. OAUIFE, Bacillus sp. MAYA and Bacillus sp. Gilbert showed an optimum flocculation (87 percent) of kaolin suspension when the dosage concentration was 1.0 mg/ml. Under strong alkaline pH of 12, flocculating activity reached (95 percent) when Al3+ was the coagulant aid. The FTIR analysis of the bioflocculant indicated the presence of hydroxyl, amino, carbonyl and carboxyl and phosphoryl functional groups. Scanning electron microscopy (SEM) image revealed a flaky amorphous morphological structure. Due to the excellent COD and turbidity removal efficiencies of the bioflocculants produced by the consortia, these make those attractive candidates for use in water and wastewater treatment. , Thesis (PhD) -- Faculty of Science and Agriculture, 2013
- Full Text:
- Date Issued: 2013