A Digital Forensic investigative model for business organisations
- Forrester, Jock, Irwin, Barry V W
- Authors: Forrester, Jock , Irwin, Barry V W
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430078 , vital:72664 , https://www.researchgate.net/profile/Barry-Ir-win/publication/228783555_A_Digital_Forensic_investigative_model_for_business_organisations/links/53e9c5e80cf28f342f414987/A-Digital-Forensic-investigative-model-for-business-organisations.pdf
- Description: When a digital incident occurs there are generally three courses of ac-tions that are taken, generally dependant on the type of organisation within which the incident occurs, or which is responding the event. In the case of law enforcement the priority is to secure the crime scene, followed by the identification of evidentiary sources which should be dispatched to a specialist laboratory for analysis. In the case of an inci-dent military (or similar critical infrastructures) infrastructure the primary goal becomes one of risk identification and elimination, followed by re-covery and possible offensive measures. Where financial impact is caused by an incident, and revenue earning potential is adversely af-fected, as in the case of most commercial organisations), root cause analysis, and system remediation is of primary concern, with in-depth analysis of the how and why left until systems have been restored.
- Full Text:
- Date Issued: 2007
- Authors: Forrester, Jock , Irwin, Barry V W
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/430078 , vital:72664 , https://www.researchgate.net/profile/Barry-Ir-win/publication/228783555_A_Digital_Forensic_investigative_model_for_business_organisations/links/53e9c5e80cf28f342f414987/A-Digital-Forensic-investigative-model-for-business-organisations.pdf
- Description: When a digital incident occurs there are generally three courses of ac-tions that are taken, generally dependant on the type of organisation within which the incident occurs, or which is responding the event. In the case of law enforcement the priority is to secure the crime scene, followed by the identification of evidentiary sources which should be dispatched to a specialist laboratory for analysis. In the case of an inci-dent military (or similar critical infrastructures) infrastructure the primary goal becomes one of risk identification and elimination, followed by re-covery and possible offensive measures. Where financial impact is caused by an incident, and revenue earning potential is adversely af-fected, as in the case of most commercial organisations), root cause analysis, and system remediation is of primary concern, with in-depth analysis of the how and why left until systems have been restored.
- Full Text:
- Date Issued: 2007
A naive salience-based method for speaker identification in fiction books
- Glass, Kevin R, Bangay, Shaun D
- Authors: Glass, Kevin R , Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432627 , vital:72888 , https://pubmed.ncbi.nlm.nih.gov/10350927/
- Description: This paper presents a salience-based technique for the annotation of directly quoted speech from fiction text. In particular, this paper determines to what extent a naïve (without the use of complex machine learning or knowledge-based techniques) scoring technique can be used for the identification of the speaker of speech quotes. The presented technique makes use of a scoring technique, similar to that commonly found in knowledge-poor anaphora resolution research, as well as a set of hand-coded rules for the final identification of the speaker of each quote in the text. Speaker identification is shown to be achieved using three tasks: the identification of a speech-verb associated with a quote with a recall of 94.41%; the identification of the actor associated with a quote with a recall of 88.22%; and the selection of a speaker with an accuracy of 79.40%.
- Full Text:
- Date Issued: 2007
- Authors: Glass, Kevin R , Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/432627 , vital:72888 , https://pubmed.ncbi.nlm.nih.gov/10350927/
- Description: This paper presents a salience-based technique for the annotation of directly quoted speech from fiction text. In particular, this paper determines to what extent a naïve (without the use of complex machine learning or knowledge-based techniques) scoring technique can be used for the identification of the speaker of speech quotes. The presented technique makes use of a scoring technique, similar to that commonly found in knowledge-poor anaphora resolution research, as well as a set of hand-coded rules for the final identification of the speaker of each quote in the text. Speaker identification is shown to be achieved using three tasks: the identification of a speech-verb associated with a quote with a recall of 94.41%; the identification of the actor associated with a quote with a recall of 88.22%; and the selection of a speaker with an accuracy of 79.40%.
- Full Text:
- Date Issued: 2007
A probabilistic movement model for shortest path formation in virtual ant-like agents
- Chibaya, Colin, Bangay, Shaun D
- Authors: Chibaya, Colin , Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433125 , vital:72945 , https://doi.org/10.1145/1292491.1292493
- Description: We propose a probabilistic movement model for controlling ant-like agents foraging between two points. Such agents are all identical, simple, autonomous and can only communicate indirectly through the environment. These agents secrete two types of pheromone, one to mark trails towards the goal and another to mark trails back to the starting point. Three pheromone perception strategies are proposed (Strategy A, B and C). Agents that use strategy A perceive the desirability of a neighbouring location as the difference between levels of attractive and repulsive pheromone in that location. With strategy B, agents perceive the desirability of a location as the quotient of levels of attractive and repulsive pheromone. Agents using strategy C determine the product of the levels of attractive pheromone with the complement of levels of repulsive pheromone. We conduct experiments to confirm directionality as emergent property of trails formed by agents that use each strategy. In addition, we compare path formation speed and the quality of the formed path under changes in the environment. We also investigate each strategy's robustness in environments that contain obstacles. Finally, we investigate how adaptive each strategy is when obstacles are eventually removed from the scene and find that the best strategy of these three is strategy A. Such a strategy provides useful guidelines to researchers in further applications of swarm intelligence metaphors for complex problem solving.
- Full Text:
- Date Issued: 2007
- Authors: Chibaya, Colin , Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433125 , vital:72945 , https://doi.org/10.1145/1292491.1292493
- Description: We propose a probabilistic movement model for controlling ant-like agents foraging between two points. Such agents are all identical, simple, autonomous and can only communicate indirectly through the environment. These agents secrete two types of pheromone, one to mark trails towards the goal and another to mark trails back to the starting point. Three pheromone perception strategies are proposed (Strategy A, B and C). Agents that use strategy A perceive the desirability of a neighbouring location as the difference between levels of attractive and repulsive pheromone in that location. With strategy B, agents perceive the desirability of a location as the quotient of levels of attractive and repulsive pheromone. Agents using strategy C determine the product of the levels of attractive pheromone with the complement of levels of repulsive pheromone. We conduct experiments to confirm directionality as emergent property of trails formed by agents that use each strategy. In addition, we compare path formation speed and the quality of the formed path under changes in the environment. We also investigate each strategy's robustness in environments that contain obstacles. Finally, we investigate how adaptive each strategy is when obstacles are eventually removed from the scene and find that the best strategy of these three is strategy A. Such a strategy provides useful guidelines to researchers in further applications of swarm intelligence metaphors for complex problem solving.
- Full Text:
- Date Issued: 2007
Adjustment of commercial bank's interest rates and the effectiveness of monetary policy in South Africa
- Aziakpono, Meshach J, Wilson, Magdalene K, Manuel, Jason
- Authors: Aziakpono, Meshach J , Wilson, Magdalene K , Manuel, Jason
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/469676 , vital:77277 , https://hdl.handle.net/10520/EJC33833
- Description: The study uses the asymmetric error correction model as in Scholnick (1996) and two wholesale bank interest rates (prime interbank lending and the negotiable certificate of deposit rates), to examine how market interest rates adjust to changes in the SARB official rate under different policy regimes in South Africa. The study covered the period between 1973 and 2004, which was divided into six sub-periods to reflect the different monetary policy regimes in South Africa. The results indicate a varying degree of adjustment under the different regimes, but clearly show that there was greater speed of adjustment under regimes that stress more market-oriented policies as opposed to control measures. The response of market Interest rates to monetary policy was quick and with high magnitude which suggest a fairly efficient money market. The evidence on the asymmetric adjustment was weak. On the whole, the results of this study suggest that a market-oriented policy would be more effective in transmitting the effects of the Bank's monetary policy stance to the rest of the economy.
- Full Text:
- Date Issued: 2007
- Authors: Aziakpono, Meshach J , Wilson, Magdalene K , Manuel, Jason
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/469676 , vital:77277 , https://hdl.handle.net/10520/EJC33833
- Description: The study uses the asymmetric error correction model as in Scholnick (1996) and two wholesale bank interest rates (prime interbank lending and the negotiable certificate of deposit rates), to examine how market interest rates adjust to changes in the SARB official rate under different policy regimes in South Africa. The study covered the period between 1973 and 2004, which was divided into six sub-periods to reflect the different monetary policy regimes in South Africa. The results indicate a varying degree of adjustment under the different regimes, but clearly show that there was greater speed of adjustment under regimes that stress more market-oriented policies as opposed to control measures. The response of market Interest rates to monetary policy was quick and with high magnitude which suggest a fairly efficient money market. The evidence on the asymmetric adjustment was weak. On the whole, the results of this study suggest that a market-oriented policy would be more effective in transmitting the effects of the Bank's monetary policy stance to the rest of the economy.
- Full Text:
- Date Issued: 2007
An acoustic analysis of White South African English (WSAfE) monophthongs
- Authors: Bekker, Ian , Eley, Georgina
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/469179 , vital:77217 , https://doi.org/10.2989/16073610709486449
- Description: This article has two main aims: (1) to introduce instrumental acoustic techniques to the analysis of the WSAfE accent, and (2), to provide tentative evidence for a new prestige value in the Johannesburg (Northern Suburbs) variety of this accent. As such, focus falls on an acoustic analysis of the monophthongs of WSAfE, as produced by ten young South African women in citation-form. Half of the subjects are from the Northern Suburbs of Johannesburg, the other half from East London. The results of the analysis provide some evidence for a new prestige value in the Johannesburg (Northern Suburbs) variety of WSAfE i.e. the lowering and retraction of the so-called TRAP vowel.
- Full Text:
- Date Issued: 2007
- Authors: Bekker, Ian , Eley, Georgina
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/469179 , vital:77217 , https://doi.org/10.2989/16073610709486449
- Description: This article has two main aims: (1) to introduce instrumental acoustic techniques to the analysis of the WSAfE accent, and (2), to provide tentative evidence for a new prestige value in the Johannesburg (Northern Suburbs) variety of this accent. As such, focus falls on an acoustic analysis of the monophthongs of WSAfE, as produced by ten young South African women in citation-form. Half of the subjects are from the Northern Suburbs of Johannesburg, the other half from East London. The results of the analysis provide some evidence for a new prestige value in the Johannesburg (Northern Suburbs) variety of WSAfE i.e. the lowering and retraction of the so-called TRAP vowel.
- Full Text:
- Date Issued: 2007
An inexpensive geometrical micrometer for measuring small, live insects quickly without harming them
- Authors: Villet, Martin H
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/441860 , vital:73928 , https://doi.org/10.1111/j.1570-7458.2006.00520.x
- Description: The article discusses the technical note for the journal" Entomologia Experimentalis et Applicata," in the first quarter of 2007 issue. The author provides information about an inexpensive geometrical micrometer for measuring small, live insects rapidly and accurately without causing harm to the organism. The method he applied for making the measurements is related to the wedge micrometer as described by the scientist SD Porter in 1983.
- Full Text:
- Date Issued: 2007
An inexpensive geometrical micrometer for measuring small, live insects quickly without harming them
- Authors: Villet, Martin H
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/441860 , vital:73928 , https://doi.org/10.1111/j.1570-7458.2006.00520.x
- Description: The article discusses the technical note for the journal" Entomologia Experimentalis et Applicata," in the first quarter of 2007 issue. The author provides information about an inexpensive geometrical micrometer for measuring small, live insects rapidly and accurately without causing harm to the organism. The method he applied for making the measurements is related to the wedge micrometer as described by the scientist SD Porter in 1983.
- Full Text:
- Date Issued: 2007
An ontology-based, multi-modal platform for the inclusion of marginalized rural communities into the knowledge society
- Thinyane, Mamello, Dalvit, Lorenzo, Slay, Hannah, Mapi, Thandeka, Terzoli, Alfredo
- Authors: Thinyane, Mamello , Dalvit, Lorenzo , Slay, Hannah , Mapi, Thandeka , Terzoli, Alfredo
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431218 , vital:72755 , https://doi.org/10.1145/1292491.1292508
- Description: With the information revolution that promises to shape the 21st century, knowledge has become the prime commodity, very much like land, means of production and capital have been at different times in the past. Access to information, made instantly available by the growth of the Internet, determines access to economic resources, social participa-tion and better quality of life. For this reason, the knowledge stored on the Web and the advantages offered by the spread of Information and Communication Technology (ICT) are equally important for rich socie-ties to prosper and for poor ones to develop. The only difference is that marginalised communities do not have access to the tools and have little control over the content found in the domain of ICTs. In this paper we describe an intervention to develop the potential of a typical rural community in South Africa through ICTs. This involves providing Inter-net connectivity and deploying a platform to support e-commerce, e-learning, e-government and e-health. The core of the platform is an on-tology-based model designed to integrate and respond to Indigenous Knowledge Systems. This has been achieved by combining a deep understanding of local knowledge and social networks with the use of authoring, communication and ontology-management tools. The prima-ry goal of this new approach is to find a way to make ICT solutions more sensitive to the local context, and therefore more effective. Sec-ondly, we hope to foster a sense of ownership of the project among the community, by capitalising on local knowledge and resources.
- Full Text:
- Date Issued: 2007
- Authors: Thinyane, Mamello , Dalvit, Lorenzo , Slay, Hannah , Mapi, Thandeka , Terzoli, Alfredo
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/431218 , vital:72755 , https://doi.org/10.1145/1292491.1292508
- Description: With the information revolution that promises to shape the 21st century, knowledge has become the prime commodity, very much like land, means of production and capital have been at different times in the past. Access to information, made instantly available by the growth of the Internet, determines access to economic resources, social participa-tion and better quality of life. For this reason, the knowledge stored on the Web and the advantages offered by the spread of Information and Communication Technology (ICT) are equally important for rich socie-ties to prosper and for poor ones to develop. The only difference is that marginalised communities do not have access to the tools and have little control over the content found in the domain of ICTs. In this paper we describe an intervention to develop the potential of a typical rural community in South Africa through ICTs. This involves providing Inter-net connectivity and deploying a platform to support e-commerce, e-learning, e-government and e-health. The core of the platform is an on-tology-based model designed to integrate and respond to Indigenous Knowledge Systems. This has been achieved by combining a deep understanding of local knowledge and social networks with the use of authoring, communication and ontology-management tools. The prima-ry goal of this new approach is to find a way to make ICT solutions more sensitive to the local context, and therefore more effective. Sec-ondly, we hope to foster a sense of ownership of the project among the community, by capitalising on local knowledge and resources.
- Full Text:
- Date Issued: 2007
Animated feather coats using field lines
- Authors: Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433338 , vital:72963 , https://doi.org/10.1145/1294685.1294713
- Description: The tedious task of manually placing feathers on computer animated ob-jects involves aligning feathers, ensuring that they do not insect each other or penetrate the surface, deforming every feather to match the local surface features, and ensuring that the feather coat is consistent when the underly-ing object is animated. We present a technique for generating a feather coat over an object. Feather orientation is specified quickly and easily, feathers are deformed while ensuring collision prevention, and the coat can be ani-mated. We create a vector field in the space surrounding the body object and deform feathers to align with the field lines. The non-intersection proper-ty of the field lines ensures that feather intersections are avoided. We pro-vide a formulation of a suitable vector field and demonstrate that it is capa-ble of producing realistic feather coats. The process can easily be integrated into the work-flow of standard modelling and animation processes. We show examples of feather coat creation on a range of objects, proving that field line based placement of feather coats provides the desired functionality for feather modelling and animation.
- Full Text:
- Date Issued: 2007
- Authors: Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433338 , vital:72963 , https://doi.org/10.1145/1294685.1294713
- Description: The tedious task of manually placing feathers on computer animated ob-jects involves aligning feathers, ensuring that they do not insect each other or penetrate the surface, deforming every feather to match the local surface features, and ensuring that the feather coat is consistent when the underly-ing object is animated. We present a technique for generating a feather coat over an object. Feather orientation is specified quickly and easily, feathers are deformed while ensuring collision prevention, and the coat can be ani-mated. We create a vector field in the space surrounding the body object and deform feathers to align with the field lines. The non-intersection proper-ty of the field lines ensures that feather intersections are avoided. We pro-vide a formulation of a suitable vector field and demonstrate that it is capa-ble of producing realistic feather coats. The process can easily be integrated into the work-flow of standard modelling and animation processes. We show examples of feather coat creation on a range of objects, proving that field line based placement of feather coats provides the desired functionality for feather modelling and animation.
- Full Text:
- Date Issued: 2007
Assessing the effects of invasive alien species on rural livelihoods: Case examples and a framework from South Africa
- Shackleton, Charlie M, McGarry, Dylan K, Fourie, Saskia, Gambiza, James, Shackleton, Sheona E, Fabricius, Christo
- Authors: Shackleton, Charlie M , McGarry, Dylan K , Fourie, Saskia , Gambiza, James , Shackleton, Sheona E , Fabricius, Christo
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181279 , vital:43715 , xlink:href="https://doi.org/10.1007/s10745-006-9095-0"
- Description: The detrimental impacts of invasive alien species (IAS) on ecosystem goods and services and local and regional economies are well documented. However, the use of IAS by rural communities is little understood, and rarely factored into IAS control programmes. Understanding the use of IAS by rural communities and factoring these into cost-benefit models is complex, depending upon a range of local-level attributes such as the time since invasion, abundance, and local-level costs and benefits. This paper reports on two case studies examining the role of IAS in rural livelihoods in the Eastern Cape, South Africa. In both cases, rural communities made widespread consumptive use of the IAS and generally would prefer higher densities, except in certain key localities. Several households traded in IAS products to generate supplementary income. We present a conceptual framework to guide interpretation of these and future case studies, considering attributes such as time since invasion, the competitiveness of the species, and the relative costs and benefits.
- Full Text:
- Date Issued: 2007
- Authors: Shackleton, Charlie M , McGarry, Dylan K , Fourie, Saskia , Gambiza, James , Shackleton, Sheona E , Fabricius, Christo
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181279 , vital:43715 , xlink:href="https://doi.org/10.1007/s10745-006-9095-0"
- Description: The detrimental impacts of invasive alien species (IAS) on ecosystem goods and services and local and regional economies are well documented. However, the use of IAS by rural communities is little understood, and rarely factored into IAS control programmes. Understanding the use of IAS by rural communities and factoring these into cost-benefit models is complex, depending upon a range of local-level attributes such as the time since invasion, abundance, and local-level costs and benefits. This paper reports on two case studies examining the role of IAS in rural livelihoods in the Eastern Cape, South Africa. In both cases, rural communities made widespread consumptive use of the IAS and generally would prefer higher densities, except in certain key localities. Several households traded in IAS products to generate supplementary income. We present a conceptual framework to guide interpretation of these and future case studies, considering attributes such as time since invasion, the competitiveness of the species, and the relative costs and benefits.
- Full Text:
- Date Issued: 2007
Assessment of spatial variation in carbon utilization by benthic and pelagic invertebrates in a temperate South African estuary using stable isotope signatures
- Richoux, Nicole B, Froneman, P William
- Authors: Richoux, Nicole B , Froneman, P William
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/457923 , vital:75695 , xlink:href="https://doi.org/10.1016/j.ecss.2006.09.007 "
- Description: Stable isotope analyses (δ13C and δ15N) were used to evaluate the spatial variations in carbon flow from primary producers to consumers at two sites in the temperate and permanently open Kariega Estuary on the southeastern coast of South Africa during October 2005 and February 2006. One site was located opposite a salt marsh while the second was upstream of the marsh. Except for significantly enriched δ13C values of Zostera capensis and surface sediments near the salt marsh, the δ13C and δ15N signatures of the producers were similar between sites. The invertebrates were clustered into groups roughly corresponding to the predominant feeding modes. The suspension feeders showed δ13C values closest to the seston, whereas the deposit feeders, detritivores and scavengers/predators had more enriched δ13C values reflecting primary carbon sources that were likely a combination of seston, Spartina maritima and Z. capensis at the upstream site, with an increased influence of benthic algae and Z. capensis at the salt marsh site. The δ15N signatures of the consumers showed a stepwise continuum rather than distinct levels of fractionation, indicating highly complex trophic linkages and significant dietary overlap among the species. Consumers exhibited significantly enriched δ13C values at the salt marsh site, an effect that was attributed to enriched Z. capensis detritus in this region in addition to increased phytoplankton biomass in their diets compared with invertebrates living upstream. The data reinforce the concept that between-site variations in the stable isotope ratios of consumers can result not only from dietary shifts, but also from alterations in the isotope ratios of primary producers.
- Full Text:
- Date Issued: 2007
- Authors: Richoux, Nicole B , Froneman, P William
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/457923 , vital:75695 , xlink:href="https://doi.org/10.1016/j.ecss.2006.09.007 "
- Description: Stable isotope analyses (δ13C and δ15N) were used to evaluate the spatial variations in carbon flow from primary producers to consumers at two sites in the temperate and permanently open Kariega Estuary on the southeastern coast of South Africa during October 2005 and February 2006. One site was located opposite a salt marsh while the second was upstream of the marsh. Except for significantly enriched δ13C values of Zostera capensis and surface sediments near the salt marsh, the δ13C and δ15N signatures of the producers were similar between sites. The invertebrates were clustered into groups roughly corresponding to the predominant feeding modes. The suspension feeders showed δ13C values closest to the seston, whereas the deposit feeders, detritivores and scavengers/predators had more enriched δ13C values reflecting primary carbon sources that were likely a combination of seston, Spartina maritima and Z. capensis at the upstream site, with an increased influence of benthic algae and Z. capensis at the salt marsh site. The δ15N signatures of the consumers showed a stepwise continuum rather than distinct levels of fractionation, indicating highly complex trophic linkages and significant dietary overlap among the species. Consumers exhibited significantly enriched δ13C values at the salt marsh site, an effect that was attributed to enriched Z. capensis detritus in this region in addition to increased phytoplankton biomass in their diets compared with invertebrates living upstream. The data reinforce the concept that between-site variations in the stable isotope ratios of consumers can result not only from dietary shifts, but also from alterations in the isotope ratios of primary producers.
- Full Text:
- Date Issued: 2007
Asymmetric tariff reduction within the SADC protocol on trade and its implications for industrial development within member states
- Authors: Mutambara, Tsitsi E
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/477798 , vital:78125 , https://hdl.handle.net/10520/AJA20062184_29
- Description: The Southern African Development Community (SADC) aims to facilitate and attain deeper economic integration and industrial development among its members. To achieve these objectives, the grouping developed the SADC Protocol on Trade whose implementation began in 2000. While this Protocol is mainly a trade instrument, this article seeks to explore how it could be used to facilitate industrial development instead of using it solely for trade integration. In analysing this Protocol it has been observed that it has specific provisions that address issues on industrial development within the grouping. These provisions are Part Two Article 3 and Part Four Article 21. As the region progresses in implementing the Protocol, the aforementioned Articles could be utilised to facilitate industrial development. Theoretical debates upon which these Articles could be used to facilitate industrial development rest on the infant industry argument, the static and dynamic effects of economic integration. Limitations of the theoretical frameworks will be explored and how this could impact on industrial development initiatives by the grouping.
- Full Text:
- Date Issued: 2007
- Authors: Mutambara, Tsitsi E
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/477798 , vital:78125 , https://hdl.handle.net/10520/AJA20062184_29
- Description: The Southern African Development Community (SADC) aims to facilitate and attain deeper economic integration and industrial development among its members. To achieve these objectives, the grouping developed the SADC Protocol on Trade whose implementation began in 2000. While this Protocol is mainly a trade instrument, this article seeks to explore how it could be used to facilitate industrial development instead of using it solely for trade integration. In analysing this Protocol it has been observed that it has specific provisions that address issues on industrial development within the grouping. These provisions are Part Two Article 3 and Part Four Article 21. As the region progresses in implementing the Protocol, the aforementioned Articles could be utilised to facilitate industrial development. Theoretical debates upon which these Articles could be used to facilitate industrial development rest on the infant industry argument, the static and dynamic effects of economic integration. Limitations of the theoretical frameworks will be explored and how this could impact on industrial development initiatives by the grouping.
- Full Text:
- Date Issued: 2007
cargo
- Authors: Berold, Robert
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , poem
- Identifier: http://hdl.handle.net/10962/461984 , vital:76257 , ISBN 0028-4459 , https://journals.co.za/doi/epdf/10.10520/EJC47794
- Description: New Coin is one of South Africa's most established and influential poetry journals. It publishes poetry, and poetry-related reviews, commentary and interviews. New Coin places a particular emphasis on evolving forms and experimental use of the English language in poetry in the South African context. In this sense it has traced the most exciting trends and currents in contemporary poetry in South Africa for a decade of more. The journal is published twice a year in June and December by the Institute for the Study of English in Africa (ISEA), Rhodes University.
- Full Text:
- Date Issued: 2007
- Authors: Berold, Robert
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , poem
- Identifier: http://hdl.handle.net/10962/461984 , vital:76257 , ISBN 0028-4459 , https://journals.co.za/doi/epdf/10.10520/EJC47794
- Description: New Coin is one of South Africa's most established and influential poetry journals. It publishes poetry, and poetry-related reviews, commentary and interviews. New Coin places a particular emphasis on evolving forms and experimental use of the English language in poetry in the South African context. In this sense it has traced the most exciting trends and currents in contemporary poetry in South Africa for a decade of more. The journal is published twice a year in June and December by the Institute for the Study of English in Africa (ISEA), Rhodes University.
- Full Text:
- Date Issued: 2007
Characterization of self-assembled monolayers of iron and cobalt octaalkylthiosubstituted phthalocyanines and their use in nitrite electrocatalytic oxidation
- Matemadombo, Fungisai, Nyokong, Tebello
- Authors: Matemadombo, Fungisai , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271182 , vital:54519 , xlink:href="https://doi.org/10.1016/j.electacta.2007.05.002"
- Description: Cobalt and iron phenylthiosubstituted phthalocyanines have been deposited on Au electrode surfaces through the self-assembled monolayer (SAM) technique. The so formed layers were studied using voltammetric and impedance techniques. These SAMs blocked a number of Faradic processes and electrocatalyzed the oxidation of nitrite. The electrocatalytic parameters of the cobalt and iron phenylthiosubstituted phthalocyanines deposited on Au electrodes in nitrite solution were studied. Nitrite overpotentials which are lower than ever reported were obtained in this work for the iron phenylthiosubstituted phthalocyanines with very high stability.
- Full Text:
- Date Issued: 2007
- Authors: Matemadombo, Fungisai , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271182 , vital:54519 , xlink:href="https://doi.org/10.1016/j.electacta.2007.05.002"
- Description: Cobalt and iron phenylthiosubstituted phthalocyanines have been deposited on Au electrode surfaces through the self-assembled monolayer (SAM) technique. The so formed layers were studied using voltammetric and impedance techniques. These SAMs blocked a number of Faradic processes and electrocatalyzed the oxidation of nitrite. The electrocatalytic parameters of the cobalt and iron phenylthiosubstituted phthalocyanines deposited on Au electrodes in nitrite solution were studied. Nitrite overpotentials which are lower than ever reported were obtained in this work for the iron phenylthiosubstituted phthalocyanines with very high stability.
- Full Text:
- Date Issued: 2007
Cobalt Phthalocyanine Molecular Electrode for the Electrochemical Investigation of the Release of Glutathione upon Copper-Catalyzed Decomposition of S-Nitrosoglutathione
- Sehlotho, Nthapo, Griveau, Sophie, Nyokong, Tebello, Bedioui, Fethi
- Authors: Sehlotho, Nthapo , Griveau, Sophie , Nyokong, Tebello , Bedioui, Fethi
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281201 , vital:55701 , xlink:href="https://doi.org/10.1002/elan.200603656"
- Description: Decomposition of S-nitrosoglutathione (GSNO) in phosphate buffer solution at physiological pH 7.4 in the presence of cuprous ion as a catalyst and sodium borohydride as a reducing agent is analyzed by observing the transient apparition of reduced glutathione GSH through its electrooxidation. Transient formation of GSH, upon decomposition of 1 mM GSNO in presence of 0.025 mM Cu(NO3)2 and 1 mM NaBH4 was detected by using an ordinary pyrolytic graphite electrode modified with an adsorbed monolayer of cobalt phthalocyanine at 0 V vs. SCE.
- Full Text:
- Date Issued: 2007
- Authors: Sehlotho, Nthapo , Griveau, Sophie , Nyokong, Tebello , Bedioui, Fethi
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281201 , vital:55701 , xlink:href="https://doi.org/10.1002/elan.200603656"
- Description: Decomposition of S-nitrosoglutathione (GSNO) in phosphate buffer solution at physiological pH 7.4 in the presence of cuprous ion as a catalyst and sodium borohydride as a reducing agent is analyzed by observing the transient apparition of reduced glutathione GSH through its electrooxidation. Transient formation of GSH, upon decomposition of 1 mM GSNO in presence of 0.025 mM Cu(NO3)2 and 1 mM NaBH4 was detected by using an ordinary pyrolytic graphite electrode modified with an adsorbed monolayer of cobalt phthalocyanine at 0 V vs. SCE.
- Full Text:
- Date Issued: 2007
Comparative electrooxidation of nitrite by electrodeposited Co (II), Fe (II) and Mn (III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines on gold electrodes
- Agboola, Bolade, Nyokong, Tebello
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281212 , vital:55702 , xlink:href="https://doi.org/10.1016/j.aca.2007.01.031"
- Description: This work reports on the electrooxidation of nitrite using Co(II), Fe(II) and Mn(III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines electrodeposited onto a gold electrode. Good catalytic activity (in terms of lowering overpotential) was obtained for these molecules when compared to previously reported MPc catalysts. The catalytic current was found to vary linearly with nitrite concentration in the range employed in this work (0.1–1 mM) and high sensitivities ranging from 6.9 to 9.9 μA mM−1 were observed for all the modified electrodes.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281212 , vital:55702 , xlink:href="https://doi.org/10.1016/j.aca.2007.01.031"
- Description: This work reports on the electrooxidation of nitrite using Co(II), Fe(II) and Mn(III) tetrakis (benzylmercapto) and tetrakis (dodecylmercapto) phthalocyanines electrodeposited onto a gold electrode. Good catalytic activity (in terms of lowering overpotential) was obtained for these molecules when compared to previously reported MPc catalysts. The catalytic current was found to vary linearly with nitrite concentration in the range employed in this work (0.1–1 mM) and high sensitivities ranging from 6.9 to 9.9 μA mM−1 were observed for all the modified electrodes.
- Full Text:
- Date Issued: 2007
Comparative electrooxidation of sulphite by self-assembled monolayers (SAMs) of Co (II), Fe (II), Ni (II) and Mn (III) tetrakis benzylmercapto and dodecylmercapto metallophthalocyanines complexes on gold electrodes
- Agboola, Bolade, Nyokong, Tebello
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281223 , vital:55703 , xlink:href="https://doi.org/10.1016/j.talanta.2006.11.042"
- Description: This work reports on the use of Co(II), Fe(II), Mn(III) and Ni(II) tetrakis benzylmercapto and dodecylmercapto phthalocyanine complexes for gold electrode modification for electrooxidation of sulphite ions. The complexes were successfully used to modify gold electrodes by self-assembled monolayer (SAM) technique. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, underpotential deposition (UPD) of copper and solution redox chemistry of [Fe(H2O)63+]/[Fe(H2O)62+]. All the modified electrodes showed improved catalytic activities than the unmodified gold electrode towards sulphite ion electrooxidation with all the modified electrodes exhibiting high resistance to electrode surface passivation. Better catalytic performance were obtained for the CoPcs, FePcs and MnPcs which have metal based redox processes within the range of the sulphite electrooxidation peak, while the NiPcs which did not show metal based redox reaction performed less. The catalytic current was found to be linear with sulphite ion concentration in the concentration range employed in this work (0.1–1 mM) and sensitivities ranging from 1.68 to 2.96 μA/mM were observed for all the modified electrodes. Mechanisms of the catalytic oxidation of sulphite ions are proposed.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281223 , vital:55703 , xlink:href="https://doi.org/10.1016/j.talanta.2006.11.042"
- Description: This work reports on the use of Co(II), Fe(II), Mn(III) and Ni(II) tetrakis benzylmercapto and dodecylmercapto phthalocyanine complexes for gold electrode modification for electrooxidation of sulphite ions. The complexes were successfully used to modify gold electrodes by self-assembled monolayer (SAM) technique. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, underpotential deposition (UPD) of copper and solution redox chemistry of [Fe(H2O)63+]/[Fe(H2O)62+]. All the modified electrodes showed improved catalytic activities than the unmodified gold electrode towards sulphite ion electrooxidation with all the modified electrodes exhibiting high resistance to electrode surface passivation. Better catalytic performance were obtained for the CoPcs, FePcs and MnPcs which have metal based redox processes within the range of the sulphite electrooxidation peak, while the NiPcs which did not show metal based redox reaction performed less. The catalytic current was found to be linear with sulphite ion concentration in the concentration range employed in this work (0.1–1 mM) and sensitivities ranging from 1.68 to 2.96 μA/mM were observed for all the modified electrodes. Mechanisms of the catalytic oxidation of sulphite ions are proposed.
- Full Text:
- Date Issued: 2007
Comparative photocatalytic efficiency of oxotitanium (IV) phthalocyanines for the oxidation of 1-hexene
- Tau, Prudence, Nyokong, Tebello
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271193 , vital:54520 , xlink:href="https://doi.org/10.1016/j.molcata.2007.04.005"
- Description: The comparative photocatalytic activities of aryloxy and arylthio tetrasubstituted oxotitanium(IV) phthalocyanine complexes for the oxidation of 1-hexene in DCM are reported for the first time. The singlet oxygen quantum yield, photostability and photocatalytic properties are investigated. The catalysts effectively catalyse 1-hexene to 1,2-epoxyhexane and 1-hexen-3-ol as major and minor products respectively. The photooxidation products are formed via two reaction mechanisms, namely via singlet oxygen (Type II) and radical (Type I) reaction pathways. These are also dependent on the singlet oxygen quantum yields and photostabilities of the phthalocyanines. Complex 1a that is peripherally substituted with phenoxy groups exhibited the best activity in terms of overall performance.
- Full Text:
- Date Issued: 2007
- Authors: Tau, Prudence , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271193 , vital:54520 , xlink:href="https://doi.org/10.1016/j.molcata.2007.04.005"
- Description: The comparative photocatalytic activities of aryloxy and arylthio tetrasubstituted oxotitanium(IV) phthalocyanine complexes for the oxidation of 1-hexene in DCM are reported for the first time. The singlet oxygen quantum yield, photostability and photocatalytic properties are investigated. The catalysts effectively catalyse 1-hexene to 1,2-epoxyhexane and 1-hexen-3-ol as major and minor products respectively. The photooxidation products are formed via two reaction mechanisms, namely via singlet oxygen (Type II) and radical (Type I) reaction pathways. These are also dependent on the singlet oxygen quantum yields and photostabilities of the phthalocyanines. Complex 1a that is peripherally substituted with phenoxy groups exhibited the best activity in terms of overall performance.
- Full Text:
- Date Issued: 2007
Constraint-based conversion of fiction text to a time-based graphical representation
- Glass, Kevin R, Bangay, Shaun D
- Authors: Glass, Kevin R , Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433141 , vital:72946 , https://doi.org/10.1145/1292491.1292494
- Description: This paper presents a method for converting unrestricted fiction text into a time-based graphical form. Key concepts extracted from the text are used to formulate constraints describing the interaction of entities in a scene. The solution of these constraints over their respective time intervals provides the trajectories for these entities in a graphical representation.
- Full Text:
- Date Issued: 2007
- Authors: Glass, Kevin R , Bangay, Shaun D
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/433141 , vital:72946 , https://doi.org/10.1145/1292491.1292494
- Description: This paper presents a method for converting unrestricted fiction text into a time-based graphical form. Key concepts extracted from the text are used to formulate constraints describing the interaction of entities in a scene. The solution of these constraints over their respective time intervals provides the trajectories for these entities in a graphical representation.
- Full Text:
- Date Issued: 2007
Corporeal knowledge and pleasure in theatre research: The case of looking at theatre photographs
- Authors: Tang, Cheong W A
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/468606 , vital:77096 , https://doi.org/10.1080/10137548.2007.9687865
- Description: In the context of current efforts at establishing a national framework for recognizing practice as research, a window of opportunity seems to be open for discussions on the nature of research, and indeed the nature of knowledge, in theatre studies. This paper is a contribution toward articulating at once a methodological and an epistemological concern: it provides an overview of the methods in which photographs have been used as sources of data in research; it also attempts to articulate and argue for a particular understanding of the nature of theatre knowledge as corporeal, and how this may impact on research methodology, specifically in terms of using photographs. By intervening in theoretical assumptions of what is legitimate theatre knowledge, the paper ultimately attempts to contribute to laying the theoretical groundwork for the acceptance of practice as research. As Ball and Smith argue, ‘the theoretical framework sets an agenda for the types of researchable questions that can be addressed’ (1992: 3); conversely, to expand the types of researchable questions that are possible in the field of theatre, theoretical frameworks that legitimise practice as knowledge should be articulated (or re-articulated), and this is one such attempt.
- Full Text:
- Date Issued: 2007
- Authors: Tang, Cheong W A
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/468606 , vital:77096 , https://doi.org/10.1080/10137548.2007.9687865
- Description: In the context of current efforts at establishing a national framework for recognizing practice as research, a window of opportunity seems to be open for discussions on the nature of research, and indeed the nature of knowledge, in theatre studies. This paper is a contribution toward articulating at once a methodological and an epistemological concern: it provides an overview of the methods in which photographs have been used as sources of data in research; it also attempts to articulate and argue for a particular understanding of the nature of theatre knowledge as corporeal, and how this may impact on research methodology, specifically in terms of using photographs. By intervening in theoretical assumptions of what is legitimate theatre knowledge, the paper ultimately attempts to contribute to laying the theoretical groundwork for the acceptance of practice as research. As Ball and Smith argue, ‘the theoretical framework sets an agenda for the types of researchable questions that can be addressed’ (1992: 3); conversely, to expand the types of researchable questions that are possible in the field of theatre, theoretical frameworks that legitimise practice as knowledge should be articulated (or re-articulated), and this is one such attempt.
- Full Text:
- Date Issued: 2007
Critical assessment of the quartz crystal microbalance with dissipation as an analytical tool for biosensor development and fundamental studies
- Fogel, Ronen, Mashazi, Philani N, Nyokong, Tebello, Limson, Janice L
- Authors: Fogel, Ronen , Mashazi, Philani N , Nyokong, Tebello , Limson, Janice L
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271204 , vital:54521 , xlink:href="https://doi.org/10.1016/j.bios.2007.03.012"
- Description: One of the challenges in electrochemical biosensor design is gaining a fundamental knowledge of the processes underlying immobilisation of the molecules onto the electrode surface. This is of particular importance in biocomposite sensors where concerns have arisen as to the nature of the interaction between the biological and synthetic molecules immobilised. We examined the use of the Quartz Crystal Microbalance with Dissipation (QCM-D) as a tool for fundamental analyses of a model sensor constructed by the immobilisation of cobalt(II) phthalocyanine (TCACoPc) and glucose oxidase (GOx) onto a gold-quartz electrode (electrode surface) for the enhanced detection of glucose. The model sensor was constructed in aqueous phase and covalently linked the gold surface to the TCACoPc, and the TCACoPc to the GOx, using the QCM-D. The aqueous metallophthalocyanine (MPc) formed a multi-layer over the surface of the electrode, which could be removed to leave a monolayer with a mass loading that compared favourably to the theoretical value expected. Analysis of frequency and dissipation plots indicated covalent attachment of glucose oxidase onto the metallophthalocyanine layer. The amount of GOx bound using the model system compared favourably to calculations derived from the maximal amperometric functioning of the electrochemical sensor (examined in previously-published literature, Mashazi, P.N., Ozoemena, K.I., Nyokong, T., 2006. Electrochim. Acta 52, 177–186), but not to theoretical values derived from dimensions of GOx as established by crystallography. The strength of the binding of the GOx film with the TCACoPc layer was tested by using 2% SDS as a denaturant/surfactant, and the GOx film was not found to be significantly affected by exposure to this. This paper thus showed that QCM-D can be used in order to model essential processes and interactions that dictate the functional parameters of a biosensor.
- Full Text:
- Date Issued: 2007
- Authors: Fogel, Ronen , Mashazi, Philani N , Nyokong, Tebello , Limson, Janice L
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271204 , vital:54521 , xlink:href="https://doi.org/10.1016/j.bios.2007.03.012"
- Description: One of the challenges in electrochemical biosensor design is gaining a fundamental knowledge of the processes underlying immobilisation of the molecules onto the electrode surface. This is of particular importance in biocomposite sensors where concerns have arisen as to the nature of the interaction between the biological and synthetic molecules immobilised. We examined the use of the Quartz Crystal Microbalance with Dissipation (QCM-D) as a tool for fundamental analyses of a model sensor constructed by the immobilisation of cobalt(II) phthalocyanine (TCACoPc) and glucose oxidase (GOx) onto a gold-quartz electrode (electrode surface) for the enhanced detection of glucose. The model sensor was constructed in aqueous phase and covalently linked the gold surface to the TCACoPc, and the TCACoPc to the GOx, using the QCM-D. The aqueous metallophthalocyanine (MPc) formed a multi-layer over the surface of the electrode, which could be removed to leave a monolayer with a mass loading that compared favourably to the theoretical value expected. Analysis of frequency and dissipation plots indicated covalent attachment of glucose oxidase onto the metallophthalocyanine layer. The amount of GOx bound using the model system compared favourably to calculations derived from the maximal amperometric functioning of the electrochemical sensor (examined in previously-published literature, Mashazi, P.N., Ozoemena, K.I., Nyokong, T., 2006. Electrochim. Acta 52, 177–186), but not to theoretical values derived from dimensions of GOx as established by crystallography. The strength of the binding of the GOx film with the TCACoPc layer was tested by using 2% SDS as a denaturant/surfactant, and the GOx film was not found to be significantly affected by exposure to this. This paper thus showed that QCM-D can be used in order to model essential processes and interactions that dictate the functional parameters of a biosensor.
- Full Text:
- Date Issued: 2007