An entrepreneurial framework for new venture property development projects
- Authors: Abrey, Mark Henry Shaw
- Date: 2015
- Subjects: Real estate development -- South Africa , Entrepreneurship -- South Africa , Land subdivision -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:9709 , http://hdl.handle.net/10948/d1020162
- Description: The business of real estate is one of the largest suppliers of employment, and contributes significantly to the gross domestic product of numerous countries worldwide. It is, therefore, imperative that new real estate development entrepreneurs entering the market identify key competitiveness indicators in order to survive and ensure their success within an ever-changing market. However, property development is a complex process and considered to be 'too risky' Consequently, property development entrepreneurs lack the skills and expertise to effectively manage their business enterprises and the associated risks from project inception to completion, and commissioning. The study was conducted by means of a review of the related literature and by conducting an empirical study. The empirical study was conducted using a quantitative statistical approach by distributing research questionnaires to members falling within the sample population. The primary objective of the study was to develop an entrepreneurial framework for perceived success of new venture property development projects. A descriptive survey was conducted among professionals registered with the South African Property Owners Association (SAPOA) and property development practitioners within South Africa. The salient findings suggest that the following variables positively influence the perceived success of new venture property development projects: Entrepreneurial vision; Strategic management; Stakeholders‘ interests; Professional feasibility and viability reporting; Procurement; Communication; Consumer confidence; Risk management; Governance structures; Specialist advice; The entrepreneurial framework, and The project management body of knowledge (PMBOK). Furthermore, the following variables were identified in the empirical framework affecting the perceived success of new venture property development projects: Entrepreneurial Vision; Strategic Management; Stakeholders‘ Interest; Professional Feasibility and Viability Reporting; Procurement; Communication; Consumer Confidence; Risk Management; Governance Structures; Specialist Advice, and The Project Management Body of Knowledge (PMBOK). This study contributed to the South African property development body of knowledge by addressing the challenges faced by inexperienced entrepreneurs entering the property development market. Furthermore, this study aimed to improve the framework utilised by emerging property developers.
- Full Text:
- Date Issued: 2015
- Authors: Abrey, Mark Henry Shaw
- Date: 2015
- Subjects: Real estate development -- South Africa , Entrepreneurship -- South Africa , Land subdivision -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:9709 , http://hdl.handle.net/10948/d1020162
- Description: The business of real estate is one of the largest suppliers of employment, and contributes significantly to the gross domestic product of numerous countries worldwide. It is, therefore, imperative that new real estate development entrepreneurs entering the market identify key competitiveness indicators in order to survive and ensure their success within an ever-changing market. However, property development is a complex process and considered to be 'too risky' Consequently, property development entrepreneurs lack the skills and expertise to effectively manage their business enterprises and the associated risks from project inception to completion, and commissioning. The study was conducted by means of a review of the related literature and by conducting an empirical study. The empirical study was conducted using a quantitative statistical approach by distributing research questionnaires to members falling within the sample population. The primary objective of the study was to develop an entrepreneurial framework for perceived success of new venture property development projects. A descriptive survey was conducted among professionals registered with the South African Property Owners Association (SAPOA) and property development practitioners within South Africa. The salient findings suggest that the following variables positively influence the perceived success of new venture property development projects: Entrepreneurial vision; Strategic management; Stakeholders‘ interests; Professional feasibility and viability reporting; Procurement; Communication; Consumer confidence; Risk management; Governance structures; Specialist advice; The entrepreneurial framework, and The project management body of knowledge (PMBOK). Furthermore, the following variables were identified in the empirical framework affecting the perceived success of new venture property development projects: Entrepreneurial Vision; Strategic Management; Stakeholders‘ Interest; Professional Feasibility and Viability Reporting; Procurement; Communication; Consumer Confidence; Risk Management; Governance Structures; Specialist Advice, and The Project Management Body of Knowledge (PMBOK). This study contributed to the South African property development body of knowledge by addressing the challenges faced by inexperienced entrepreneurs entering the property development market. Furthermore, this study aimed to improve the framework utilised by emerging property developers.
- Full Text:
- Date Issued: 2015
Isolation and structure elucidation of halogenated metabolites from Portieria hornemannii and Portieria tripinnata
- Authors: Adam, Mohammed
- Date: 2015
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/64674 , vital:28591
- Description: The red marine algal genus, Portieria, is known to produce a number of potent cytotoxic compounds with anticancer potential. The most important anticancer lead produced by this genus is the compound halomon. Unfortunately, the lack of sufficient quantities of this compound hampered its further development. Two Portieria species, Portieria hornemannii and Portieria tripinnata, are found along the South African coastline. Recent studies, based on DNA analysis, suggest that Portieria hornemannii may in fact be divided into several cryptic species. The current project is part of a larger study designed to investigate the use of secondary metabolites to identify new marine algal species. In this study 1H NMR profiles of the organic extracts of selected Portieria spp were compared in order to identify new species. Selected compounds were then isolated and characterised as potential chemotaxonomic markers. Four halogenated monoterpenes were isolated from Portieria hornemannii. Two of these were new compounds 4-(3-bromo-4-chloro-4-methylpentyl)-3-chlorofuran-2(5H)-one, which were isomers of each other. The two known compounds had been previously isolated from Portieria hornemannii samples off the Madagascar coast. These compounds could prove to be useful as chemotaxonomic marker compounds, as they have never been isolated from any other species of marine algae. Three known halogenated monoterpenes were isolated from Portieria tripinnata. These compounds had been previously isolated from different species of marine algae and therefore, could not serve as chemotaxonomic marker compounds for this species of marine alga. Further work needs to be done on Portieria tripinnata, with regards to its chemistry, as it is a species of marine algae that has not been previously researched.
- Full Text:
- Date Issued: 2015
- Authors: Adam, Mohammed
- Date: 2015
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/64674 , vital:28591
- Description: The red marine algal genus, Portieria, is known to produce a number of potent cytotoxic compounds with anticancer potential. The most important anticancer lead produced by this genus is the compound halomon. Unfortunately, the lack of sufficient quantities of this compound hampered its further development. Two Portieria species, Portieria hornemannii and Portieria tripinnata, are found along the South African coastline. Recent studies, based on DNA analysis, suggest that Portieria hornemannii may in fact be divided into several cryptic species. The current project is part of a larger study designed to investigate the use of secondary metabolites to identify new marine algal species. In this study 1H NMR profiles of the organic extracts of selected Portieria spp were compared in order to identify new species. Selected compounds were then isolated and characterised as potential chemotaxonomic markers. Four halogenated monoterpenes were isolated from Portieria hornemannii. Two of these were new compounds 4-(3-bromo-4-chloro-4-methylpentyl)-3-chlorofuran-2(5H)-one, which were isomers of each other. The two known compounds had been previously isolated from Portieria hornemannii samples off the Madagascar coast. These compounds could prove to be useful as chemotaxonomic marker compounds, as they have never been isolated from any other species of marine algae. Three known halogenated monoterpenes were isolated from Portieria tripinnata. These compounds had been previously isolated from different species of marine algae and therefore, could not serve as chemotaxonomic marker compounds for this species of marine alga. Further work needs to be done on Portieria tripinnata, with regards to its chemistry, as it is a species of marine algae that has not been previously researched.
- Full Text:
- Date Issued: 2015
Towards measuring corporate sustainability in the Nelson Mandela Bay automotive manufacturing sector
- Authors: Adams, Abulele
- Date: 2015
- Subjects: Sustainability -- South Africa -- Port Elizabeth Sustainable development -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/18465 , vital:28648
- Description: This study explored the methods available for measuring corporate sustainability and created an instrument to measure corporate sustainability in the Nelson Mandela Bay (NMB) automotive manufacturing sector. The instrument was created based on three components of sustainability which are environment, society and economy. The study went a step further and added a fourth dimension, current trends to design a measuring instrument. The instrument was then applied on participating companies and further refined to improve it. A total of 16 multi-dimensional indicators to measure corporate sustainability were created and applied to 12 companies in the automotive manufacturing sector. The indicators were used to create a composite corporate sustainability index which can be used to compare the corporate sustainability performance of companies. These indicators were created based on theoretical research and fist hand experience observing the automotive manufacturing sector in the NMB. The indicators were applied to companies as a pilot to test whether they are feasible. Following this, the indicators were refined, improved and applied to more companies to measure corporate sustainability performance. The results of the study were the measuring instrument created, the creation of a composite index as well as the application of the instrument on 12 companies to determine whether the instrument was refined enough to detect differences in the corporate sustainability performance of companies. The results are discussed and further recommendations are made for improvements in the creation and application of the instrument to measure corporate sustainability in the NMB automotive manufacturing sector.
- Full Text:
- Date Issued: 2015
Towards measuring corporate sustainability in the Nelson Mandela Bay automotive manufacturing sector
- Authors: Adams, Abulele
- Date: 2015
- Subjects: Sustainability -- South Africa -- Port Elizabeth Sustainable development -- South Africa -- Port Elizabeth
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/18465 , vital:28648
- Description: This study explored the methods available for measuring corporate sustainability and created an instrument to measure corporate sustainability in the Nelson Mandela Bay (NMB) automotive manufacturing sector. The instrument was created based on three components of sustainability which are environment, society and economy. The study went a step further and added a fourth dimension, current trends to design a measuring instrument. The instrument was then applied on participating companies and further refined to improve it. A total of 16 multi-dimensional indicators to measure corporate sustainability were created and applied to 12 companies in the automotive manufacturing sector. The indicators were used to create a composite corporate sustainability index which can be used to compare the corporate sustainability performance of companies. These indicators were created based on theoretical research and fist hand experience observing the automotive manufacturing sector in the NMB. The indicators were applied to companies as a pilot to test whether they are feasible. Following this, the indicators were refined, improved and applied to more companies to measure corporate sustainability performance. The results of the study were the measuring instrument created, the creation of a composite index as well as the application of the instrument on 12 companies to determine whether the instrument was refined enough to detect differences in the corporate sustainability performance of companies. The results are discussed and further recommendations are made for improvements in the creation and application of the instrument to measure corporate sustainability in the NMB automotive manufacturing sector.
- Full Text:
- Date Issued: 2015
Risk factors associated with developing asthma and tuberculosis: a case study of a hospital, Lagos Nigeria
- Authors: Adeniji, Tolulope Olubunmi
- Date: 2015
- Subjects: Asthma -- Nigeria -- Epidemiology , Diseases -- Risk factors -- Nigeria
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/13216 , vital:39616
- Description: The purpose of the study is to assess risk factors associated with developing asthma and tuberculosis. Methodology: A quantitative study was conducted on 133 randomly selected tuberculosis respondents, 91 of whom were suffering from TB at the time of the study. 120 respondents were also selected randomly for asthma of which 82 were asthmatic. Data were collected by using a self-structured questionnaire. The statistical analysis was done with the statistical package for social sciences (SPSS, version 18) using the descriptive statistics and logistic regression model. Results: Findings from the study show that a large percentage of the participants for both diseases were male, and the carriers of the diseases were also mostly male. Amongst the factors assessed, smoking, a weak immune system and a history of contact with tuberculosis infected persons were factors independently associated with developing tuberculosis. In the case of asthma, family history, smoking and exposure to allergen irritants were the factors independently associated with developing the disease. Conclusion: The findings highlight the need for increasing awareness through information, education and communication to address the risk factors of tuberculosis and asthma in order to decrease the rate of outspread. Recommendations: Factors triggering asthma among humans should be avoided. Since tuberculosis can be contracted through person to person contact, proper sanitation and regular medical attention are advocated for safeguarding personal and public health.
- Full Text:
- Date Issued: 2015
- Authors: Adeniji, Tolulope Olubunmi
- Date: 2015
- Subjects: Asthma -- Nigeria -- Epidemiology , Diseases -- Risk factors -- Nigeria
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/13216 , vital:39616
- Description: The purpose of the study is to assess risk factors associated with developing asthma and tuberculosis. Methodology: A quantitative study was conducted on 133 randomly selected tuberculosis respondents, 91 of whom were suffering from TB at the time of the study. 120 respondents were also selected randomly for asthma of which 82 were asthmatic. Data were collected by using a self-structured questionnaire. The statistical analysis was done with the statistical package for social sciences (SPSS, version 18) using the descriptive statistics and logistic regression model. Results: Findings from the study show that a large percentage of the participants for both diseases were male, and the carriers of the diseases were also mostly male. Amongst the factors assessed, smoking, a weak immune system and a history of contact with tuberculosis infected persons were factors independently associated with developing tuberculosis. In the case of asthma, family history, smoking and exposure to allergen irritants were the factors independently associated with developing the disease. Conclusion: The findings highlight the need for increasing awareness through information, education and communication to address the risk factors of tuberculosis and asthma in order to decrease the rate of outspread. Recommendations: Factors triggering asthma among humans should be avoided. Since tuberculosis can be contracted through person to person contact, proper sanitation and regular medical attention are advocated for safeguarding personal and public health.
- Full Text:
- Date Issued: 2015
Studies towards the development of novel antimalarial agents
- Authors: Adeyemi, Christiana Modupe
- Date: 2015
- Subjects: Antimalarials , Malaria , Drug resistance , Drug development , Enzyme inhibitors , Plasmodium
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54645 , vital:26596
- Description: Considerable efforts have been made in the modification of existing antimalarial drugs, and the support of incentive programmes have led to a drastic decrease in malaria cases reported by WHO during the past 6 years. However, the development of drug resistance threatens the eradication of this deadly disease and has prompted research on the synthesis of novel antimalarial drugs. Our research has involved the design and synthesis of novel benzylated phosphonate esters as potential 1-deoxy-D-xylose-5-phosphate reductoisomerase (DXR) inhibitors. A series of amidoalkylphosphonate esters were obtained by reacting various 3-subsituted anilines and heterocyclic amines with chloroalkanoyl chlorides and reacting the resulting chloroalkanamides with triethyl phosphite using Michaelis-Arbuzov methodology. Benzylation of the phosphonate esters afforded a series of novel N-benzylated derivatives in good yields and these compounds were fully characterised by NMR and HRMS methods. Several approaches to the introduction of a benzyl group at the C-2 position of the phosphonate ester derivatives have been explored, leading unexpectedly to the isolation of unprecedented tetrahydrofuranyl derivatives. Studies towards the preparation of potential bi-functional PfDXR / HIV-1 RT inhibitors have also been initiated. Preliminary in silico docking studies of selected non-benzylated and benzylated phosphonated derivatives into the Pf-DXR active-site has provided useful insight into the binding potential of these ligands. Bioassays have revealed a very low toxicity for all the synthesised phosphonated compounds and a number of these ligands also exhibit a promising inhibitory activity against the Plasmodium parasite.
- Full Text:
- Date Issued: 2015
- Authors: Adeyemi, Christiana Modupe
- Date: 2015
- Subjects: Antimalarials , Malaria , Drug resistance , Drug development , Enzyme inhibitors , Plasmodium
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/54645 , vital:26596
- Description: Considerable efforts have been made in the modification of existing antimalarial drugs, and the support of incentive programmes have led to a drastic decrease in malaria cases reported by WHO during the past 6 years. However, the development of drug resistance threatens the eradication of this deadly disease and has prompted research on the synthesis of novel antimalarial drugs. Our research has involved the design and synthesis of novel benzylated phosphonate esters as potential 1-deoxy-D-xylose-5-phosphate reductoisomerase (DXR) inhibitors. A series of amidoalkylphosphonate esters were obtained by reacting various 3-subsituted anilines and heterocyclic amines with chloroalkanoyl chlorides and reacting the resulting chloroalkanamides with triethyl phosphite using Michaelis-Arbuzov methodology. Benzylation of the phosphonate esters afforded a series of novel N-benzylated derivatives in good yields and these compounds were fully characterised by NMR and HRMS methods. Several approaches to the introduction of a benzyl group at the C-2 position of the phosphonate ester derivatives have been explored, leading unexpectedly to the isolation of unprecedented tetrahydrofuranyl derivatives. Studies towards the preparation of potential bi-functional PfDXR / HIV-1 RT inhibitors have also been initiated. Preliminary in silico docking studies of selected non-benzylated and benzylated phosphonated derivatives into the Pf-DXR active-site has provided useful insight into the binding potential of these ligands. Bioassays have revealed a very low toxicity for all the synthesised phosphonated compounds and a number of these ligands also exhibit a promising inhibitory activity against the Plasmodium parasite.
- Full Text:
- Date Issued: 2015
A natural user interface architecture using gestures to facilitate the detection of fundamental movement skills
- Authors: Amanzi, Richard
- Date: 2015
- Subjects: Human activity recognition , Human-computer interaction
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/6204 , vital:21055
- Description: Fundamental movement skills (FMSs) are considered to be one of the essential phases of motor skill development. The proper development of FMSs allows children to participate in more advanced forms of movements and sports. To be able to perform an FMS correctly, children need to learn the right way of performing it. By making use of technology, a system can be developed that can help facilitate the learning of FMSs. The objective of the research was to propose an effective natural user interface (NUI) architecture for detecting FMSs using the Kinect. In order to achieve the stated objective, an investigation into FMSs and the challenges faced when teaching them was presented. An investigation into NUIs was also presented including the merits of the Kinect as the most appropriate device to be used to facilitate the detection of an FMS. An NUI architecture was proposed that uses the Kinect to facilitate the detection of an FMS. A framework was implemented from the design of the architecture. The successful implementation of the framework provides evidence that the design of the proposed architecture is feasible. An instance of the framework incorporating the jump FMS was used as a case study in the development of a prototype that detects the correct and incorrect performance of a jump. The evaluation of the prototype proved the following: - The developed prototype was effective in detecting the correct and incorrect performance of the jump FMS; and - The implemented framework was robust for the incorporation of an FMS. The successful implementation of the prototype shows that an effective NUI architecture using the Kinect can be used to facilitate the detection of FMSs. The proposed architecture provides a structured way of developing a system using the Kinect to facilitate the detection of FMSs. This allows developers to add future FMSs to the system. This dissertation therefore makes the following contributions: - An experimental design to evaluate the effectiveness of a prototype that detects FMSs - A robust framework that incorporates FMSs; and - An effective NUI architecture to facilitate the detection of fundamental movement skills using the Kinect.
- Full Text:
- Date Issued: 2015
- Authors: Amanzi, Richard
- Date: 2015
- Subjects: Human activity recognition , Human-computer interaction
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/6204 , vital:21055
- Description: Fundamental movement skills (FMSs) are considered to be one of the essential phases of motor skill development. The proper development of FMSs allows children to participate in more advanced forms of movements and sports. To be able to perform an FMS correctly, children need to learn the right way of performing it. By making use of technology, a system can be developed that can help facilitate the learning of FMSs. The objective of the research was to propose an effective natural user interface (NUI) architecture for detecting FMSs using the Kinect. In order to achieve the stated objective, an investigation into FMSs and the challenges faced when teaching them was presented. An investigation into NUIs was also presented including the merits of the Kinect as the most appropriate device to be used to facilitate the detection of an FMS. An NUI architecture was proposed that uses the Kinect to facilitate the detection of an FMS. A framework was implemented from the design of the architecture. The successful implementation of the framework provides evidence that the design of the proposed architecture is feasible. An instance of the framework incorporating the jump FMS was used as a case study in the development of a prototype that detects the correct and incorrect performance of a jump. The evaluation of the prototype proved the following: - The developed prototype was effective in detecting the correct and incorrect performance of the jump FMS; and - The implemented framework was robust for the incorporation of an FMS. The successful implementation of the prototype shows that an effective NUI architecture using the Kinect can be used to facilitate the detection of FMSs. The proposed architecture provides a structured way of developing a system using the Kinect to facilitate the detection of FMSs. This allows developers to add future FMSs to the system. This dissertation therefore makes the following contributions: - An experimental design to evaluate the effectiveness of a prototype that detects FMSs - A robust framework that incorporates FMSs; and - An effective NUI architecture to facilitate the detection of fundamental movement skills using the Kinect.
- Full Text:
- Date Issued: 2015
Regolith mapping and gold geochemical anomalies in the Siguiri Gold Mine of AngloGold Ashanti, Guinea, West Africa
- Authors: Bah, Boubacar
- Date: 2015
- Subjects: AngloGold Ashanti Ltd. , Regolith -- Guinea -- Siguiri (Region) , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Soil surveys -- Geochemical methods -- Guinea -- Siguiri (Region) , Kriging
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5090 , http://hdl.handle.net/10962/d1019878
- Description: Gold exploration in the laterite terrains of the Siguiri basin (Guinea-West Africa) is discussed in this thesis. It seeks to propose and develop effective and reliable geochemical exploration techniques applied in such laterite terrains. The study is also intended to investigate and provide some geological clues as to why, in some target areas, the reconnaissance test drilling across the geochemical anomalies couldn’t intersect economic gold mineralisation. Targets were generated based on soil geochemical results, some of which were drilled without delivering economic discoveries even on areas with strong and consistent geochemical signatures. To find the failure and define the appropriate methods to be used is the core of the thesis. More importantly, the geological observation is aimed at sourcing and establishing the nature and validity of geochemical anomalies within the license area and their relationship with the underlying lithologies and structural networks. The geological field work conducted during this study is mostly based on regolith and surface geological mapping. The thick laterite cover, deep weathering, bedrock geology, gold geochemistry (the gold geochemical anomalous results are defined according to historical data before 2007), soil formations and variations in climate conditions are emphasized to illustrate the importance of mineral element mobility and dispersion in the weathering profiles. The knowledge and experience in regolith geochemistry and regolith mapping provide the advantage to exploration geologists. The depletion of ore resources and reserves in Siguiri and the continuous decline of the gold price in comparison to the complexity of exploring for gold are demanding more scientific-related thoughts and techniques to be integrated in the available geological, geochemical and geophysical information so as to reduce costs. The integration of good exploration strategy and technique may result in the possibility of making viable discoveries in this highly competitive geological environment where the mineral resources become depleted every day.
- Full Text:
- Date Issued: 2015
- Authors: Bah, Boubacar
- Date: 2015
- Subjects: AngloGold Ashanti Ltd. , Regolith -- Guinea -- Siguiri (Region) , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Soil surveys -- Geochemical methods -- Guinea -- Siguiri (Region) , Kriging
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5090 , http://hdl.handle.net/10962/d1019878
- Description: Gold exploration in the laterite terrains of the Siguiri basin (Guinea-West Africa) is discussed in this thesis. It seeks to propose and develop effective and reliable geochemical exploration techniques applied in such laterite terrains. The study is also intended to investigate and provide some geological clues as to why, in some target areas, the reconnaissance test drilling across the geochemical anomalies couldn’t intersect economic gold mineralisation. Targets were generated based on soil geochemical results, some of which were drilled without delivering economic discoveries even on areas with strong and consistent geochemical signatures. To find the failure and define the appropriate methods to be used is the core of the thesis. More importantly, the geological observation is aimed at sourcing and establishing the nature and validity of geochemical anomalies within the license area and their relationship with the underlying lithologies and structural networks. The geological field work conducted during this study is mostly based on regolith and surface geological mapping. The thick laterite cover, deep weathering, bedrock geology, gold geochemistry (the gold geochemical anomalous results are defined according to historical data before 2007), soil formations and variations in climate conditions are emphasized to illustrate the importance of mineral element mobility and dispersion in the weathering profiles. The knowledge and experience in regolith geochemistry and regolith mapping provide the advantage to exploration geologists. The depletion of ore resources and reserves in Siguiri and the continuous decline of the gold price in comparison to the complexity of exploring for gold are demanding more scientific-related thoughts and techniques to be integrated in the available geological, geochemical and geophysical information so as to reduce costs. The integration of good exploration strategy and technique may result in the possibility of making viable discoveries in this highly competitive geological environment where the mineral resources become depleted every day.
- Full Text:
- Date Issued: 2015
An ergonomics intervention study into the physiological, perceptual and productivity effects of three citrus harvesting bag designs in the Eastern Cape of South Africa : a combined laboratory and field approach
- Bassey-Duke, Elizabeth Misan
- Authors: Bassey-Duke, Elizabeth Misan
- Date: 2015
- Subjects: Citrus -- Harvesting -- South Africa -- Eastern Cape , Lifting and carrying -- South Africa -- Eastern Cape , Manual work -- South Africa -- Eastern Cape , Blue collar workers -- South Africa -- Eastern Cape , Work -- Physiological aspects , Human mechanics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5176 , http://hdl.handle.net/10962/d1018908
- Description: Background: Agriculture plays a vital role in the economy of any industrially developing country, including South Africa. In the Eastern Cape of South Africa citrus farming is a significant contributor to the local economy (Johnson et al., 2005). The harvesting phase of citrus farming is performed manually and exposes workers to physical risks, which can lead to the development of musculoskeletal disorders. In particular, the standard harvesting bag comprises of a single shoulder strap and promotes asymmetrical load carriage which results in shoulder and lower back pain complaints. The current study compared the physiological (EMG), perceptual (RPE), usability (PUEU) and productivity effects of two new harvesting bag designs (a hip belt and a backpack bag design) to the standard harvesting bag design. This was performed in a laboratory as well as a field setting. Methods (Laboratory phase): 36 participants (12 males and 24 females) were assigned to one worker group. The “tall ladder worker” group was comprised of only males and the “step ladder worker” and “ground worker” group of females. Each participant was required to simulate a citrus harvesting task while utilizing each of the bag designs on different days. On each day/test session, participants performed three harvesting cycles. Muscle activity was measured throughout the entire testing session and RPE were recorded at the end of each cycle. Results (Laboratory phase): The EMG and RPE results indicate that the backpack design was the most ideal design to reduce asymmetry, while the standard harvesting bag design was the worst. Although not significant, there was greater muscle asymmetry (p=0.109) and a significantly higher perceived exertion when using the standard bag (p=0.0004), in comparison to using the backpack. Methods (Field phase): 17 Xhosa-speaking citrus harvesters (6 females and 11 males) participated in this study. Each harvester worked with one of the three bag designs on a different day. Productivity of each worker was assessed every hour by recording the number of bags filled with fruit and at the end of the shift. A Perceived Usefulness & Ease of Use questionnaire was presented to each participant to obtain feedback on worker acceptance to the new bag designs. Results (Field phase): A general trend in support of the hip belt bag design over the other two bag designs were found, even within the different worker demographic groups (age, sex and worker experience). The workers perceived less exertion (7.98 ± 1.86) and were more productive (9.90 ± 2.11 bags/hour) when using the hip belt design; they also found this bag the most useful (1.02 ± 0.09) and easy to use (1.07 ± 0.25). In contrast, the backpack bag design had significantly poorer responses when compared to the other two bag designs and this was evident in all the dependent variables assessed (RPE, productivity and PUEU). Conclusion: The results from the laboratory phase supported the expectation that the backpack bag design reduces asymmetry and hence, is more suitable than the standard harvesting bag. However, results from the field show that the hip belt bag design was the most preferred and the backpack was the least preferred. Bao & Shahnavaz (1989) highlight the need for ergonomics researcher to convey laboratory findings into the field context. However, as shown by the current study, there are numerous challenges associated with field work, making it difficult for laboratory findings to be successfully conveyed to the field. Limitations and Recommendations: For the laboratory phase of the project, no biomechanical and cardiovascular responses were assessed. However, for a holistic approach, these variables should be considered in future studies. Due to high variability from one harvesting cycle to another, more than three harvesting cycles should also be performed to accurately replicate the harvesting process as done in the field over extended durations of time. For the field phase, data should be collected from more than one citrus farm and thus a larger sample size could be obtained. This would improve the validity of the study. In addition to this, data should be collected for a full working day, especially if environmental conditions are not a hindrance, as well as for a whole season, since workloads vary, depending on the time of the harvesting season. , Name on Graduation Programme: Bassey-Duke, Elizabeth Missan
- Full Text:
- Date Issued: 2015
- Authors: Bassey-Duke, Elizabeth Misan
- Date: 2015
- Subjects: Citrus -- Harvesting -- South Africa -- Eastern Cape , Lifting and carrying -- South Africa -- Eastern Cape , Manual work -- South Africa -- Eastern Cape , Blue collar workers -- South Africa -- Eastern Cape , Work -- Physiological aspects , Human mechanics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5176 , http://hdl.handle.net/10962/d1018908
- Description: Background: Agriculture plays a vital role in the economy of any industrially developing country, including South Africa. In the Eastern Cape of South Africa citrus farming is a significant contributor to the local economy (Johnson et al., 2005). The harvesting phase of citrus farming is performed manually and exposes workers to physical risks, which can lead to the development of musculoskeletal disorders. In particular, the standard harvesting bag comprises of a single shoulder strap and promotes asymmetrical load carriage which results in shoulder and lower back pain complaints. The current study compared the physiological (EMG), perceptual (RPE), usability (PUEU) and productivity effects of two new harvesting bag designs (a hip belt and a backpack bag design) to the standard harvesting bag design. This was performed in a laboratory as well as a field setting. Methods (Laboratory phase): 36 participants (12 males and 24 females) were assigned to one worker group. The “tall ladder worker” group was comprised of only males and the “step ladder worker” and “ground worker” group of females. Each participant was required to simulate a citrus harvesting task while utilizing each of the bag designs on different days. On each day/test session, participants performed three harvesting cycles. Muscle activity was measured throughout the entire testing session and RPE were recorded at the end of each cycle. Results (Laboratory phase): The EMG and RPE results indicate that the backpack design was the most ideal design to reduce asymmetry, while the standard harvesting bag design was the worst. Although not significant, there was greater muscle asymmetry (p=0.109) and a significantly higher perceived exertion when using the standard bag (p=0.0004), in comparison to using the backpack. Methods (Field phase): 17 Xhosa-speaking citrus harvesters (6 females and 11 males) participated in this study. Each harvester worked with one of the three bag designs on a different day. Productivity of each worker was assessed every hour by recording the number of bags filled with fruit and at the end of the shift. A Perceived Usefulness & Ease of Use questionnaire was presented to each participant to obtain feedback on worker acceptance to the new bag designs. Results (Field phase): A general trend in support of the hip belt bag design over the other two bag designs were found, even within the different worker demographic groups (age, sex and worker experience). The workers perceived less exertion (7.98 ± 1.86) and were more productive (9.90 ± 2.11 bags/hour) when using the hip belt design; they also found this bag the most useful (1.02 ± 0.09) and easy to use (1.07 ± 0.25). In contrast, the backpack bag design had significantly poorer responses when compared to the other two bag designs and this was evident in all the dependent variables assessed (RPE, productivity and PUEU). Conclusion: The results from the laboratory phase supported the expectation that the backpack bag design reduces asymmetry and hence, is more suitable than the standard harvesting bag. However, results from the field show that the hip belt bag design was the most preferred and the backpack was the least preferred. Bao & Shahnavaz (1989) highlight the need for ergonomics researcher to convey laboratory findings into the field context. However, as shown by the current study, there are numerous challenges associated with field work, making it difficult for laboratory findings to be successfully conveyed to the field. Limitations and Recommendations: For the laboratory phase of the project, no biomechanical and cardiovascular responses were assessed. However, for a holistic approach, these variables should be considered in future studies. Due to high variability from one harvesting cycle to another, more than three harvesting cycles should also be performed to accurately replicate the harvesting process as done in the field over extended durations of time. For the field phase, data should be collected from more than one citrus farm and thus a larger sample size could be obtained. This would improve the validity of the study. In addition to this, data should be collected for a full working day, especially if environmental conditions are not a hindrance, as well as for a whole season, since workloads vary, depending on the time of the harvesting season. , Name on Graduation Programme: Bassey-Duke, Elizabeth Missan
- Full Text:
- Date Issued: 2015
Short-term changes to the life history of shad, Pomatomus saltatrix (Perciformes: Pomatomidae), in Southern Angola
- Authors: Bealey, Roy Steven John
- Date: 2015
- Subjects: Shad -- Angola , Bluefish -- Angola , Bluefish -- Climatic factors -- Angola , Bluefish -- Effect of temperature on -- Angola , Bluefish -- Effect of global warming on -- Angola , Bluefish -- Effect of fishing on -- Angola , Bluefish -- Life cycles , Pomatomidae -- Angola , Fishery management -- Angola , Climatic changes -- Angola
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5379 , http://hdl.handle.net/10962/d1017211
- Description: A general lack of biological information is hampering the effective management of Angola’s fisheries. While this lack of information is largely a result of the country’s extended civil war that ended in 2002, the subsequent rapid expansion of fisheries is most likely impacting fish abundance and influencing the biology of this regions fishes. Besides the influence of fisheries, the southern Angolan coastal region is considered to be a climate change “hotspot” due to rapidly (>0.8°C/decade) increasing water temperatures. These changes are thought to drive further changes to the biology of fishes. It is therefore critical to provide baseline biological information and to identify the impacts of exploitation and warming on the biology of southern Angolan fishes. Pomatomus saltatrix is a warm-temperate marine fish species that forms an important component of fisheries throughout its broad distribution. P. saltatrix is a migratory predator that displays variable growth and maturity schedules. Typically it is heavily targeted in a range of coastal fisheries of Angola and is therefore an ideal candidate to study the biological impacts of exploitation and climate change. The aim of this study was to provide the first description of P. saltatrix biology in Angola and examine recent changes of the species biological parameters in an attempt to uncouple fishery driven from climate driven changes. Samples of P. saltatrix were collected monthly using standardised biological methods from June 2005 to December 2006 (period 1) and from June 2012 to February 2013 (period 2). The average (508mm – 1st period, 462mm – 2nd period) and maximum (760mm – 1st period, 746mm – 2nd period) size of P. saltatrix was smaller during the second period to suggest selective overharvesting of large individuals by developing fisheries. Angolan P. saltatrix grew very rapidly in their first year and thereafter, relatively slowly when compared to other populations globally. However, fish grew faster (ω = 103 – 1st period, ω = 124 – 2nd period), matured at a larger size (303mm - 1st period, 336mm - 2nd period) and younger age (0.83 years - 1st period, 0.67 years – 2nd period) during the second period. Peaks in reproductive activity remained similar (November) during both periods but a temperature anomaly appears to have influenced spawning during period 2. Sardinella aurita was the dominant prey during both periods but a greater dependence upon mugilids was observed during the second period. Although the changes in life history were not statistically significant, the faster growth observed during period two could be attributed to both increasing temperature and/or exploitation. Fishes generally grow faster, mature smaller and attain a smaller maximum size in warmer temperatures. Fisheries targeting small and large specimens of a species (as observed in this study) largely have the same impacts as ocean warming. With rapidly increasing water temperatures and exploitation rates, faster growth and earlier maturation of P. saltatrix populations will mitigate the impacts of exploitation in the short-term. However, the sustainability of Angola’s P. saltatrix stock is questionable as phenotypic adaptation will have a limited thermal scope and overexploitation will, like in all fisheries, negatively influence recruitment. Ultimately, strict monitoring, regulation and control will be necessary to ensure the sustainability of the P. saltatrix resource in Angola as it continues to face increasing anthropogenic and environmental pressures. Management guidelines and future research suggestions are therefore outlined with reference to the results of analyses conducted during this study.
- Full Text:
- Date Issued: 2015
- Authors: Bealey, Roy Steven John
- Date: 2015
- Subjects: Shad -- Angola , Bluefish -- Angola , Bluefish -- Climatic factors -- Angola , Bluefish -- Effect of temperature on -- Angola , Bluefish -- Effect of global warming on -- Angola , Bluefish -- Effect of fishing on -- Angola , Bluefish -- Life cycles , Pomatomidae -- Angola , Fishery management -- Angola , Climatic changes -- Angola
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5379 , http://hdl.handle.net/10962/d1017211
- Description: A general lack of biological information is hampering the effective management of Angola’s fisheries. While this lack of information is largely a result of the country’s extended civil war that ended in 2002, the subsequent rapid expansion of fisheries is most likely impacting fish abundance and influencing the biology of this regions fishes. Besides the influence of fisheries, the southern Angolan coastal region is considered to be a climate change “hotspot” due to rapidly (>0.8°C/decade) increasing water temperatures. These changes are thought to drive further changes to the biology of fishes. It is therefore critical to provide baseline biological information and to identify the impacts of exploitation and warming on the biology of southern Angolan fishes. Pomatomus saltatrix is a warm-temperate marine fish species that forms an important component of fisheries throughout its broad distribution. P. saltatrix is a migratory predator that displays variable growth and maturity schedules. Typically it is heavily targeted in a range of coastal fisheries of Angola and is therefore an ideal candidate to study the biological impacts of exploitation and climate change. The aim of this study was to provide the first description of P. saltatrix biology in Angola and examine recent changes of the species biological parameters in an attempt to uncouple fishery driven from climate driven changes. Samples of P. saltatrix were collected monthly using standardised biological methods from June 2005 to December 2006 (period 1) and from June 2012 to February 2013 (period 2). The average (508mm – 1st period, 462mm – 2nd period) and maximum (760mm – 1st period, 746mm – 2nd period) size of P. saltatrix was smaller during the second period to suggest selective overharvesting of large individuals by developing fisheries. Angolan P. saltatrix grew very rapidly in their first year and thereafter, relatively slowly when compared to other populations globally. However, fish grew faster (ω = 103 – 1st period, ω = 124 – 2nd period), matured at a larger size (303mm - 1st period, 336mm - 2nd period) and younger age (0.83 years - 1st period, 0.67 years – 2nd period) during the second period. Peaks in reproductive activity remained similar (November) during both periods but a temperature anomaly appears to have influenced spawning during period 2. Sardinella aurita was the dominant prey during both periods but a greater dependence upon mugilids was observed during the second period. Although the changes in life history were not statistically significant, the faster growth observed during period two could be attributed to both increasing temperature and/or exploitation. Fishes generally grow faster, mature smaller and attain a smaller maximum size in warmer temperatures. Fisheries targeting small and large specimens of a species (as observed in this study) largely have the same impacts as ocean warming. With rapidly increasing water temperatures and exploitation rates, faster growth and earlier maturation of P. saltatrix populations will mitigate the impacts of exploitation in the short-term. However, the sustainability of Angola’s P. saltatrix stock is questionable as phenotypic adaptation will have a limited thermal scope and overexploitation will, like in all fisheries, negatively influence recruitment. Ultimately, strict monitoring, regulation and control will be necessary to ensure the sustainability of the P. saltatrix resource in Angola as it continues to face increasing anthropogenic and environmental pressures. Management guidelines and future research suggestions are therefore outlined with reference to the results of analyses conducted during this study.
- Full Text:
- Date Issued: 2015
Structural controls of gold mineralisation in Seguelen pit of Siguiri gold mine, Guinea
- Authors: Beavogui, Massa
- Date: 2015
- Subjects: AngloGold Ashanti Ltd. , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Geology, Structural -- Guinea -- Siguiri (Region) , Faults (Geology) -- Guinea -- Siguiri (Region) , Folds (Geology) -- Guinea -- Siguiri (Region) , Turbidites -- Guinea -- Siguiri (Region) , Metamorphism (Geology) -- Guinea -- Siguiri (Region) , Hydrothermal alteration -- Guinea -- Siguiri (Region)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5091 , http://hdl.handle.net/10962/d1019879
- Description: The present study provides the results of detailed mapping and analysis of structures encountered in Seguelen pit of Siguiri gold mine, Guinea, where the Siguiri mine is geo-tectonically located in the Baoulé-Mossi domain of Man Shield in West African craton. The gold deposit is hosted in low-grade metamorphic sediments of turbidites sequences which form part of the Lower Proterozoic of Birimian Super group. Three rock formations of Balato, Fatoya and Kintinian underlay the overall pits. The Siguiri gold mine is characterized by the deep weathering profile, developed over the rocks reaching 200 m below the surface in some areas and often capped by the lateritic gravel or duricrust. The rock formations at Seguelen area are characterised by strong bedding monotonously dipping towards SW and trending NW-SE. The lithology of the host rocks has strong control on the disseminated mineralisation throughout the deposit. Two domains of rock formations are clearly distinguished at Seguelen: Fatoya Formation(Ffm) domain ; and Kintinian Formation (Kfm) domain. The two domains are separated by a contact zone of 1.7 m wide parallel to bedding and characterised by the presence of quartz fragments as well as thinly sheeted shale and black shale. This contact zone is identified as disconformity. The major tectonic deformation which has affected the region is known as D2 corresponding to the Eburnean orogeny. The major D2 related structures is the regional thrust striking N-S over an area of 12 km long and 3 km wide and within which corridors all Siguiri gold Mine open pits are located. In the N-S trending structures, there is east-northeast shortening and north-northwest extension. There is pervasive hydrothermal alteration (carbonatization and sideritization) and supergene alteration in the all pits. The hydrothermal alteration attests the intensity of hydrothermal fluid-flow over the host rocks. The hydrothermal fluids flowed along the fractures and within the wall rocks through bedding plans to form numerous auriferous quartz veins bearing disseminated sulphides through chemical reaction between fluids and wall rocks, which are remarkable at Seguelen pit. Three quartz vein sets are distinguished at Seguelen: NNE-SSW quartz vein set NE-SW quartz vein set NW-SE quartz vein set The NE-SW and NNE-SSW quartz veins are often lenticular and associated with the bulk mineralisation.
- Full Text:
- Date Issued: 2015
- Authors: Beavogui, Massa
- Date: 2015
- Subjects: AngloGold Ashanti Ltd. , Gold mines and mining -- Guinea -- Siguiri (Region) , Geochemical surveys -- Guinea -- Siguiri (Region) , Geology, Structural -- Guinea -- Siguiri (Region) , Faults (Geology) -- Guinea -- Siguiri (Region) , Folds (Geology) -- Guinea -- Siguiri (Region) , Turbidites -- Guinea -- Siguiri (Region) , Metamorphism (Geology) -- Guinea -- Siguiri (Region) , Hydrothermal alteration -- Guinea -- Siguiri (Region)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5091 , http://hdl.handle.net/10962/d1019879
- Description: The present study provides the results of detailed mapping and analysis of structures encountered in Seguelen pit of Siguiri gold mine, Guinea, where the Siguiri mine is geo-tectonically located in the Baoulé-Mossi domain of Man Shield in West African craton. The gold deposit is hosted in low-grade metamorphic sediments of turbidites sequences which form part of the Lower Proterozoic of Birimian Super group. Three rock formations of Balato, Fatoya and Kintinian underlay the overall pits. The Siguiri gold mine is characterized by the deep weathering profile, developed over the rocks reaching 200 m below the surface in some areas and often capped by the lateritic gravel or duricrust. The rock formations at Seguelen area are characterised by strong bedding monotonously dipping towards SW and trending NW-SE. The lithology of the host rocks has strong control on the disseminated mineralisation throughout the deposit. Two domains of rock formations are clearly distinguished at Seguelen: Fatoya Formation(Ffm) domain ; and Kintinian Formation (Kfm) domain. The two domains are separated by a contact zone of 1.7 m wide parallel to bedding and characterised by the presence of quartz fragments as well as thinly sheeted shale and black shale. This contact zone is identified as disconformity. The major tectonic deformation which has affected the region is known as D2 corresponding to the Eburnean orogeny. The major D2 related structures is the regional thrust striking N-S over an area of 12 km long and 3 km wide and within which corridors all Siguiri gold Mine open pits are located. In the N-S trending structures, there is east-northeast shortening and north-northwest extension. There is pervasive hydrothermal alteration (carbonatization and sideritization) and supergene alteration in the all pits. The hydrothermal alteration attests the intensity of hydrothermal fluid-flow over the host rocks. The hydrothermal fluids flowed along the fractures and within the wall rocks through bedding plans to form numerous auriferous quartz veins bearing disseminated sulphides through chemical reaction between fluids and wall rocks, which are remarkable at Seguelen pit. Three quartz vein sets are distinguished at Seguelen: NNE-SSW quartz vein set NE-SW quartz vein set NW-SE quartz vein set The NE-SW and NNE-SSW quartz veins are often lenticular and associated with the bulk mineralisation.
- Full Text:
- Date Issued: 2015
An analysis of the risk exposure of adopting IPV6 in enterprise networks
- Authors: Berko, Istvan Sandor
- Date: 2015
- Subjects: International Workshop on Deploying the Future Infrastructure , Computer networks , Computer networks -- Security measures , Computer network protocols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4722 , http://hdl.handle.net/10962/d1018918
- Description: The IPv6 increased address pool presents changes in resource impact to the Enterprise that, if not adequately addressed, can change risks that are locally significant in IPv4 to risks that can impact the Enterprise in its entirety. The expected conclusion is that the IPv6 environment will impose significant changes in the Enterprise environment - which may negatively impact organisational security if the IPv6 nuances are not adequately addressed. This thesis reviews the risks related to the operation of enterprise networks with the introduction of IPv6. The global trends are discussed to provide insight and background to the IPv6 research space. Analysing the current state of readiness in enterprise networks, quantifies the value of developing this thesis. The base controls that should be deployed in enterprise networks to prevent the abuse of IPv6 through tunnelling and the protection of the enterprise access layer are discussed. A series of case studies are presented which identify and analyse the impact of certain changes in the IPv6 protocol on the enterprise networks. The case studies also identify mitigation techniques to reduce risk.
- Full Text:
- Date Issued: 2015
- Authors: Berko, Istvan Sandor
- Date: 2015
- Subjects: International Workshop on Deploying the Future Infrastructure , Computer networks , Computer networks -- Security measures , Computer network protocols
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4722 , http://hdl.handle.net/10962/d1018918
- Description: The IPv6 increased address pool presents changes in resource impact to the Enterprise that, if not adequately addressed, can change risks that are locally significant in IPv4 to risks that can impact the Enterprise in its entirety. The expected conclusion is that the IPv6 environment will impose significant changes in the Enterprise environment - which may negatively impact organisational security if the IPv6 nuances are not adequately addressed. This thesis reviews the risks related to the operation of enterprise networks with the introduction of IPv6. The global trends are discussed to provide insight and background to the IPv6 research space. Analysing the current state of readiness in enterprise networks, quantifies the value of developing this thesis. The base controls that should be deployed in enterprise networks to prevent the abuse of IPv6 through tunnelling and the protection of the enterprise access layer are discussed. A series of case studies are presented which identify and analyse the impact of certain changes in the IPv6 protocol on the enterprise networks. The case studies also identify mitigation techniques to reduce risk.
- Full Text:
- Date Issued: 2015
On the characterisation of photovoltaic device parameters using light beam induced current measurements
- Bezuidenhout, Lucian John-Ross
- Authors: Bezuidenhout, Lucian John-Ross
- Date: 2015
- Subjects: Solar cells--Materials , Semiconductors
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10551 , http://hdl.handle.net/10948/d1020282
- Description: Light Beam Induced Current (LBIC) measurement is a non-destructive technique used to perform localized characterization of solar cells using a light beam as a probe. The technique allows the determination of local photo response of a cell, the electrical parameters and defects that occur in the individual solar cell. The semiconductor materials used to create solar cells are not always defect free and these defects reduce the electrical performance of the device. It is therefore important to use a system that will allow the characterization and extract the solar cell parameters as can be done using the LBIC system. By analysing these parameters and cell defects, further studies can be done to enhance the cell’s lifetime and hence its efficiency. Light beam induced current (LBIC) is a technique that focuses light onto a solar cell device and thus creating a photo-generated current that can be measured in the external circuit for analyses. By scanning this beam probe across a solar cell while measuring the current-voltage characteristics, a map of various parameters can be obtained. This thesis presents the design of the LBIC system, the software interfacing of the data acquisition system and local photo-response within different solar cell technologies. In addition, this thesis represent two curve fitting algorithms namely: the Gradient Descent Optimisation and the Differential Evolution used for the extraction of solar cell device parameters. The algorithms are based on the one-diode solar cell model and make use of the light generated current-voltage (I-V) data obtained from the LBIC system. Different solar cell technologies namely; single crystalline (c-Si) and multicrystalline silicon (mc-Si) was used for analysis. LBIC maps and I-V characteristics of both technologies was obtained. The LBIC maps shows performance degrading defects present in the bulk and the surface of the solar cells as a function of spatial distribution. These localised defects acts as trapping mechanism for the charge carriers and therefore limits recombination within the solar cell and thus decreasing the performance of the solar cell device. The resulting I-V characteristics obtained from the LBIC system were used to determine the performance parameters using the two algorithms. The resultant effect of these parameters on the performance of the solar cells was observed. The overall results showed that LBIC is a useful tool for identifying and characterising defects in solar cells.
- Full Text:
- Date Issued: 2015
- Authors: Bezuidenhout, Lucian John-Ross
- Date: 2015
- Subjects: Solar cells--Materials , Semiconductors
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10551 , http://hdl.handle.net/10948/d1020282
- Description: Light Beam Induced Current (LBIC) measurement is a non-destructive technique used to perform localized characterization of solar cells using a light beam as a probe. The technique allows the determination of local photo response of a cell, the electrical parameters and defects that occur in the individual solar cell. The semiconductor materials used to create solar cells are not always defect free and these defects reduce the electrical performance of the device. It is therefore important to use a system that will allow the characterization and extract the solar cell parameters as can be done using the LBIC system. By analysing these parameters and cell defects, further studies can be done to enhance the cell’s lifetime and hence its efficiency. Light beam induced current (LBIC) is a technique that focuses light onto a solar cell device and thus creating a photo-generated current that can be measured in the external circuit for analyses. By scanning this beam probe across a solar cell while measuring the current-voltage characteristics, a map of various parameters can be obtained. This thesis presents the design of the LBIC system, the software interfacing of the data acquisition system and local photo-response within different solar cell technologies. In addition, this thesis represent two curve fitting algorithms namely: the Gradient Descent Optimisation and the Differential Evolution used for the extraction of solar cell device parameters. The algorithms are based on the one-diode solar cell model and make use of the light generated current-voltage (I-V) data obtained from the LBIC system. Different solar cell technologies namely; single crystalline (c-Si) and multicrystalline silicon (mc-Si) was used for analysis. LBIC maps and I-V characteristics of both technologies was obtained. The LBIC maps shows performance degrading defects present in the bulk and the surface of the solar cells as a function of spatial distribution. These localised defects acts as trapping mechanism for the charge carriers and therefore limits recombination within the solar cell and thus decreasing the performance of the solar cell device. The resulting I-V characteristics obtained from the LBIC system were used to determine the performance parameters using the two algorithms. The resultant effect of these parameters on the performance of the solar cells was observed. The overall results showed that LBIC is a useful tool for identifying and characterising defects in solar cells.
- Full Text:
- Date Issued: 2015
Studies on flax/polypropylene-reinforced composites for automotive applications
- Authors: Biyana, Nobuhle Yvonne
- Date: 2015
- Subjects: Polypropylene fibers , Fibrous composites , Reinforced plastics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10456 , http://hdl.handle.net/10948/d1021150
- Description: The use of natural fibers as reinforcement in thermoplastics presents an interesting alternative for the production of low cost and ecologically friendly composites. One of the advantages of using natural fibres is their low specific weight, resulting in higher specific strength and stiffness when compared to glass reinforced composites. Natural fibres also present safer handling and working conditions. They are non-abrasive to mixing and can contribute to significant cost reduction. This work is divided into two phases: Phase 1 deals with developing nonwoven mats composites from flax/polypropylene (PP) and evaluating their properties. Flax/polypropylene fibres (at different weight ratios) were processed by needle-punching technique in order to form nonwoven mats. The mats were compression-molded at a temperature of 180oC to form composite materials. The mechanical, thermal and viscoelastic properties of the composites were analyzed. Composites (untreated and silane-treated) were also subjected to varying conditions of temperature and humidity and the tensile properties of the conditioned and unconditioned composites were investigated. The mechanical properties (tensile, flexural and impact) of flax/PP composites were found to increase and reach maximum values at 30 per cent fibre loading and then decrease at higher fibre content. Thermal studies revealed that the composites were stable up to 320oC and samples containing 40 per cent flax fibres were found to exhibit greater thermal stability than neat PP. The dynamic mechanical analyses of the composites showed that the incorporation of flax in the composites resulted in an increase of the storage modulus with a maximum value exhibited by composite containing 40 per cent fibre loading. Composites containing chemically modified fibres exhibited low tensile modulus after conditioning. Phase 2 is based on the investigation of the effect of nano-calcium carbonate (CaCO3) on the properties of two types of polymer matrices: recycled PP and virgin PP. In this case, composites were prepared by melt-mixing and injection molding. The mechanical and thermal properties of the composites were characterized. The tensile modulus of the nano-CaCO3 filled PP (virgin and recycled) composites were found to increase and reach maximum at 30 per cent nano-CaCO3 loading, while the tensile strength decreased with increasing filler content. Thermal studies showed that the nano-CaCO3 filled PP samples exhibited a one-step degradation pattern and are thermally stable up to 450oC. The thermal stability of the samples was found to decrease following the addition of nano-CaCO3. SEM micrographs of the tensile fractured surfaces of composites of the nano-CaCO3 filled virgin and recycled PP revealed the presence of nano-CaCO3 agglomeration.
- Full Text:
- Date Issued: 2015
- Authors: Biyana, Nobuhle Yvonne
- Date: 2015
- Subjects: Polypropylene fibers , Fibrous composites , Reinforced plastics
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10456 , http://hdl.handle.net/10948/d1021150
- Description: The use of natural fibers as reinforcement in thermoplastics presents an interesting alternative for the production of low cost and ecologically friendly composites. One of the advantages of using natural fibres is their low specific weight, resulting in higher specific strength and stiffness when compared to glass reinforced composites. Natural fibres also present safer handling and working conditions. They are non-abrasive to mixing and can contribute to significant cost reduction. This work is divided into two phases: Phase 1 deals with developing nonwoven mats composites from flax/polypropylene (PP) and evaluating their properties. Flax/polypropylene fibres (at different weight ratios) were processed by needle-punching technique in order to form nonwoven mats. The mats were compression-molded at a temperature of 180oC to form composite materials. The mechanical, thermal and viscoelastic properties of the composites were analyzed. Composites (untreated and silane-treated) were also subjected to varying conditions of temperature and humidity and the tensile properties of the conditioned and unconditioned composites were investigated. The mechanical properties (tensile, flexural and impact) of flax/PP composites were found to increase and reach maximum values at 30 per cent fibre loading and then decrease at higher fibre content. Thermal studies revealed that the composites were stable up to 320oC and samples containing 40 per cent flax fibres were found to exhibit greater thermal stability than neat PP. The dynamic mechanical analyses of the composites showed that the incorporation of flax in the composites resulted in an increase of the storage modulus with a maximum value exhibited by composite containing 40 per cent fibre loading. Composites containing chemically modified fibres exhibited low tensile modulus after conditioning. Phase 2 is based on the investigation of the effect of nano-calcium carbonate (CaCO3) on the properties of two types of polymer matrices: recycled PP and virgin PP. In this case, composites were prepared by melt-mixing and injection molding. The mechanical and thermal properties of the composites were characterized. The tensile modulus of the nano-CaCO3 filled PP (virgin and recycled) composites were found to increase and reach maximum at 30 per cent nano-CaCO3 loading, while the tensile strength decreased with increasing filler content. Thermal studies showed that the nano-CaCO3 filled PP samples exhibited a one-step degradation pattern and are thermally stable up to 450oC. The thermal stability of the samples was found to decrease following the addition of nano-CaCO3. SEM micrographs of the tensile fractured surfaces of composites of the nano-CaCO3 filled virgin and recycled PP revealed the presence of nano-CaCO3 agglomeration.
- Full Text:
- Date Issued: 2015
Stratigraphic characterisation of the Collingham formation in the context of shale gas from a borehole (SFT 2) near Jansenville, Eastern Cape, South Africa
- Authors: Black, Dawn Ebony
- Date: 2015
- Subjects: Geology, Stratigraphic , Formations (Geology) -- South Africa , Collingham formation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10676 , http://hdl.handle.net/10948/d1021148
- Description: This study is an extensive lithological, petrographical, mineralogical and geochemical description of fresh Collingham Formation core samples collected from borehole SFT 2, located on the farm Slangfontein, south of Jansenville in the Eastern Cape, South Africa. The borehole, drilled to 295 m on the northerly limb of a shallow westerly plunging syncline, intersected the lower Ecca Group rocks of the Ripon, Collingham, Whitehill and Prince Albert Formations and terminated in the upper Dwyka Group. A comprehensive log and stratigraphic column were compiled for the Collingham Formation and fresh core samples were analysed using X-Ray Diffraction (“XRD”), X-Ray Fluorescence (“XRF”), mercury porosimetry, and Total Organic Carbon (“TOC”). Thin section microscopy and Scanning Electron Microscopy (“SEM”) analyses were carried out on selected samples of core from borehole SFT 2. The matrix supported, massive to laminated lithological units of the Collingham Formation are interpreted as detrital, terrigenous sediments. These sediments are composed of intercalated fine-grained, poorly sorted, non-fissile mudstone; fine- to very fine-grained, predominantly pyroclastic airfall tephra; and less common fine-grained sandstones. Sediments of the Collingham Formation are considered to be immature, composed primarily of clay and aluminosilicates. The predominance of a clay fraction and aluminosilicates in mudstone samples is indicated by elevated K2O/Al2O3 ratio values, and the relationship of Zr, Al2O3 and TiO2. The presence of glauconite within the Collingham Formation indicates deposition in a mildly alkaline, slightly reducing marine environment. Rb/K ratio values (1.9 – 2.3 x 10-3) indicate brackish to slightly marine conditions, while low Zr/Rb ratio values indicate a low hydro-energy environment, with stable bottom water conditions. Hf and Nb concentrations indicate that detrital input was greatest during the deposition of tuffaceous units; while stable mineral assemblages and a low Fe2O3/K2O ratio values indicate deposition close to the source. A variation in Si/Ca values indicate times when sediments were affected by turbidity, interspersed with times of relative quiescence. The predominance of K2O over Na2O indicates that the Collingham Formation is alkali-rich, while SiO2/Al2O3 ratio values and the relationship of Zr, Al2O3 and TiO2 indicate that sediments are immature. In the lower portion of the formation, non-sulphidic, anoxic conditions are indicated by Mn/Al, V/(V+Ni), V/Cr ratio values, the Fe-Mn- V content, and the correlation between V and TOC. The upper portion of the formation is considered dysoxic, due to the presence and distribution of pyrite framboids, which indicate a fluctuating O2 level, likely indicating deposition at the interface between anoxic and slightly more oxic conditions. V/Cr ratio values indicate that the O2 regime was lowest during the deposition of the mudstones. The Chemical Index of Alteration (“CIA”) indicates a consistent weathering regime throughout the deposition of the Collingham Formation, associated with a temperate climate on the interface between glacial and tropical conditions. Although an anoxic and low hydro-energy environment is generally favourable for hydrocarbon accumulation, the Collingham Formation contains low levels of Total Organic Carbon (well below 0.9 per cent) and low porosities (ranging from 0.35 per cent to a maximum of 2.22 per cent), both of which are characteristic of a poor source for gas accumulation. Due to the laminate nature, permeability and fracturability of the Collingham Formation, there is the potential that the formation may form a good sealing sequence to the potentially gas-rich Whitehill Formation below. The metamorphic impact related to the Cape Orogeny (± 250 Ma), and reflected in the textures of the minerals making up the sediments of the Collingham Formation, suggests the enhancement in the sealing efficiency of this formation.
- Full Text:
- Date Issued: 2015
- Authors: Black, Dawn Ebony
- Date: 2015
- Subjects: Geology, Stratigraphic , Formations (Geology) -- South Africa , Collingham formation
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10676 , http://hdl.handle.net/10948/d1021148
- Description: This study is an extensive lithological, petrographical, mineralogical and geochemical description of fresh Collingham Formation core samples collected from borehole SFT 2, located on the farm Slangfontein, south of Jansenville in the Eastern Cape, South Africa. The borehole, drilled to 295 m on the northerly limb of a shallow westerly plunging syncline, intersected the lower Ecca Group rocks of the Ripon, Collingham, Whitehill and Prince Albert Formations and terminated in the upper Dwyka Group. A comprehensive log and stratigraphic column were compiled for the Collingham Formation and fresh core samples were analysed using X-Ray Diffraction (“XRD”), X-Ray Fluorescence (“XRF”), mercury porosimetry, and Total Organic Carbon (“TOC”). Thin section microscopy and Scanning Electron Microscopy (“SEM”) analyses were carried out on selected samples of core from borehole SFT 2. The matrix supported, massive to laminated lithological units of the Collingham Formation are interpreted as detrital, terrigenous sediments. These sediments are composed of intercalated fine-grained, poorly sorted, non-fissile mudstone; fine- to very fine-grained, predominantly pyroclastic airfall tephra; and less common fine-grained sandstones. Sediments of the Collingham Formation are considered to be immature, composed primarily of clay and aluminosilicates. The predominance of a clay fraction and aluminosilicates in mudstone samples is indicated by elevated K2O/Al2O3 ratio values, and the relationship of Zr, Al2O3 and TiO2. The presence of glauconite within the Collingham Formation indicates deposition in a mildly alkaline, slightly reducing marine environment. Rb/K ratio values (1.9 – 2.3 x 10-3) indicate brackish to slightly marine conditions, while low Zr/Rb ratio values indicate a low hydro-energy environment, with stable bottom water conditions. Hf and Nb concentrations indicate that detrital input was greatest during the deposition of tuffaceous units; while stable mineral assemblages and a low Fe2O3/K2O ratio values indicate deposition close to the source. A variation in Si/Ca values indicate times when sediments were affected by turbidity, interspersed with times of relative quiescence. The predominance of K2O over Na2O indicates that the Collingham Formation is alkali-rich, while SiO2/Al2O3 ratio values and the relationship of Zr, Al2O3 and TiO2 indicate that sediments are immature. In the lower portion of the formation, non-sulphidic, anoxic conditions are indicated by Mn/Al, V/(V+Ni), V/Cr ratio values, the Fe-Mn- V content, and the correlation between V and TOC. The upper portion of the formation is considered dysoxic, due to the presence and distribution of pyrite framboids, which indicate a fluctuating O2 level, likely indicating deposition at the interface between anoxic and slightly more oxic conditions. V/Cr ratio values indicate that the O2 regime was lowest during the deposition of the mudstones. The Chemical Index of Alteration (“CIA”) indicates a consistent weathering regime throughout the deposition of the Collingham Formation, associated with a temperate climate on the interface between glacial and tropical conditions. Although an anoxic and low hydro-energy environment is generally favourable for hydrocarbon accumulation, the Collingham Formation contains low levels of Total Organic Carbon (well below 0.9 per cent) and low porosities (ranging from 0.35 per cent to a maximum of 2.22 per cent), both of which are characteristic of a poor source for gas accumulation. Due to the laminate nature, permeability and fracturability of the Collingham Formation, there is the potential that the formation may form a good sealing sequence to the potentially gas-rich Whitehill Formation below. The metamorphic impact related to the Cape Orogeny (± 250 Ma), and reflected in the textures of the minerals making up the sediments of the Collingham Formation, suggests the enhancement in the sealing efficiency of this formation.
- Full Text:
- Date Issued: 2015
The cheetahs of the Northern Tuli Game Reserve, Botswana: population estimates, monitoring techniques and human-predator conflict
- Authors: Brassine, Eleanor I
- Date: 2015
- Subjects: Cheetah -- Botswana , Northern Tuli Game Reserve , Animal populations -- Botswana
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5922 , http://hdl.handle.net/10962/d1017800
- Description: Remaining viable cheetah (Acinonyx jubatus) populations in Africa are threatened by direct persecution through conflict with farmers and habitat degradation and fragmentation. Botswana is considered a stronghold for free roaming cheetahs in Africa, yet the country has had relatively limited research on its cheetahs, and information from the east of the country is lacking. Data on the current status of populations is thus required to make informed management decisions. My study provides estimates of population density, abundance, distribution and status for the demographically open cheetah population of the Northern Tuli Game Reserve (NOTUGRE) in Botswana. The effectiveness of two population monitoring methods, namely camera trapping and a photographic survey, were also investigated. Moreover, I report on the level of conflict between livestock farmers and predators on rural communal farmlands within and adjacent to NOTUGRE. Data were collected between May 2012 and November 2013. Results indicate a low population density of 0.61 ± 0.18 adult cheetahs per 100 km² and a minimum population size of 10 individuals (nine adults and one cub). Camera traps placed at cheetah scent-marking posts increased detection rates and provided ideal set up locations. This approach, together with Spatial Explicit Capture- Recapture (SECR) models, is recommended for future studies. The long-term studies that are required to better understand the status of cheetahs in Botswana do not exist. Thus, photographic surveys may provide an alternative method for providing baseline data on population numbers, distribution and demography. The third aspect of my study gathered information on levels of livestock loss and human tolerance of predators through the use of interviews (n = 80). Conflict with subsistence farmers is a concern as livestock depredation is relatively high (9.1% of total livestock owned) and farmers had an overall negative attitude towards conservation of large predators. My results suggest that human-predator conflict in this area is more complex than the direct financial loss from depredation. Hence, reducing depredation rates alone is unlikely to change farmer tolerance of wildlife on farmlands. Improved, responsible farm management, including self-responsibility for livestock rearing, and positive appreciation for wildlife are necessary. The NOTUGRE cheetah population requires further research to understand possible threats to the population. Furthermore, a better understanding of the connectivity between cheetahs of NOTUGRE, South Africa and Zimbabwe is required. The number of cheetahs within NOTUGRE is too small to sustain a viable population, hence conserving cheetahs outside of the protected area should be a priority for the conservation of the population. This can only be achieved through assistance and involvement from national authorities, local people and conservation organisations.
- Full Text:
- Date Issued: 2015
- Authors: Brassine, Eleanor I
- Date: 2015
- Subjects: Cheetah -- Botswana , Northern Tuli Game Reserve , Animal populations -- Botswana
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5922 , http://hdl.handle.net/10962/d1017800
- Description: Remaining viable cheetah (Acinonyx jubatus) populations in Africa are threatened by direct persecution through conflict with farmers and habitat degradation and fragmentation. Botswana is considered a stronghold for free roaming cheetahs in Africa, yet the country has had relatively limited research on its cheetahs, and information from the east of the country is lacking. Data on the current status of populations is thus required to make informed management decisions. My study provides estimates of population density, abundance, distribution and status for the demographically open cheetah population of the Northern Tuli Game Reserve (NOTUGRE) in Botswana. The effectiveness of two population monitoring methods, namely camera trapping and a photographic survey, were also investigated. Moreover, I report on the level of conflict between livestock farmers and predators on rural communal farmlands within and adjacent to NOTUGRE. Data were collected between May 2012 and November 2013. Results indicate a low population density of 0.61 ± 0.18 adult cheetahs per 100 km² and a minimum population size of 10 individuals (nine adults and one cub). Camera traps placed at cheetah scent-marking posts increased detection rates and provided ideal set up locations. This approach, together with Spatial Explicit Capture- Recapture (SECR) models, is recommended for future studies. The long-term studies that are required to better understand the status of cheetahs in Botswana do not exist. Thus, photographic surveys may provide an alternative method for providing baseline data on population numbers, distribution and demography. The third aspect of my study gathered information on levels of livestock loss and human tolerance of predators through the use of interviews (n = 80). Conflict with subsistence farmers is a concern as livestock depredation is relatively high (9.1% of total livestock owned) and farmers had an overall negative attitude towards conservation of large predators. My results suggest that human-predator conflict in this area is more complex than the direct financial loss from depredation. Hence, reducing depredation rates alone is unlikely to change farmer tolerance of wildlife on farmlands. Improved, responsible farm management, including self-responsibility for livestock rearing, and positive appreciation for wildlife are necessary. The NOTUGRE cheetah population requires further research to understand possible threats to the population. Furthermore, a better understanding of the connectivity between cheetahs of NOTUGRE, South Africa and Zimbabwe is required. The number of cheetahs within NOTUGRE is too small to sustain a viable population, hence conserving cheetahs outside of the protected area should be a priority for the conservation of the population. This can only be achieved through assistance and involvement from national authorities, local people and conservation organisations.
- Full Text:
- Date Issued: 2015
Stratigraphy and sedimentology of the Msikaba formation in KwaZulu Natal South Coast, South Africa
- Authors: Busakwe, Nolukholo Sinovuyo
- Date: 2015
- Subjects: Geology, Stratigraphic Sedimentology -- South Africa -- KwaZulu-Natal
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2501 , vital:27877
- Description: The Msikaba Formation is a Late Devonian fluvial and marine succession which outcrops from Hibberdene to Port Edward along the south coast of KwaZulu-Natal Province, South Africa. The Formation is composed of brownish conglomerate at the bottom and white-greyish quartz arenite sequence in the middle and mixed quartz-arenite with feldspathic sandstone in the upper sequence. Previous studies put more emphasis on the correlation of Msikaba Formation with the Natal Group and Cape Supergroup, whereas this study revised the stratigraphy, and also put new insight on the petrography, sedimentary facies, depositional environments and diagenesis of the Formation. The total stratigraphic section attains a thickness of 184 m at Margate area and 186 m at Port Edward area. The stratigraphy of Msikaba Formation is well exposed on the outcrops along the KwaZulu-Natal coastline. The stratigraphy is subdivided into 4 new members along Margate to Shelly beach section; namely Manaba Member, Uvongo Member, Mhlangeni Member and Shelly Beach Member from bottom upward. Twelve sedimentary facies were identified and the sedimentary facies were integrated into 4 facies association: Facies association 1 (Gmm+Sm) represents braided fluvial deposits, Facies association 2 (Gcm+St+Sp+Sl+Shb) represents tidal channel and tidal flat deposit, Facies association 3 (St+Sp+Sr+Sl) is result of shallow marine deposit and Facies association 4 (Sp+Sl+St+Sm) is a mixed marine and fluvial deposit. Each facies association represents a specific stratigraphic unit and were deposited in a specific sedimentary environment. Grain size analysis was conducted on seventeen thin sections and 500 grains were counted from each thin section. The sandstone grain size parameters of mean, sorting, skewness and kurtosis fell under the average of 0.75, 0.78, 0.4 and 1.2φ respectively. The results show that most of the grain size are coarse to medium grained throughout the study areas and sorting of the sandstones are moderate to poorly sorted. The cumulative frequency diagrams and bivariate plots show positive skewness and negative kurtosis, which indicate a high hydrodynamic environment. Modal composition analysis and petrography studies show that detrital components of the Msikaba Formation are dominated by monocrystalline quartz, feldspar (mostly K-feldspar) and lithic fragments of igneous and metamorphic rocks. The sandstones could be classified as quartz arenite, sub-arkosic sandstone and feldspathic litharenite; and the provenance analysis indicates that the sandstones were derived from craton interior, recycled or quartzose recycled sources which may derived from weathering and erosion of igneous and metamorphic rocks. Diagenetic processes of the Msikaba Formation have been passed through early, mid- and late diagenetic stages. Cementation, mineral conversion and compaction affect early diagenetic stage; authigenic minerals, quartz and feldspar overgrowth are presented in mid-diagenetic stage, whereas recrystallization, replacement, deformation and dissolution have been strongly affected late diagenetic stage. Microscopy, XRD and SEM-EDX studies have identified five types of cements including smectite clay, kaolinite, hematite, quartz and feldspar cements. Quartz cement, pore-filling and pore-lining clay are the major type of cements in the Msikaba Formation. Based on the lithology, sedimentary structure and facies variations, the Manaba Member was most probably deposited in a braided fluvial environment, the Uvongo Member was deposited in a tidal channel environment, the Mhlangeni Member was formed in shallow marine storm-influenced environment, whereas the Shelly Beach Member was represented mixed marine and fluvial environment. The sequence stratigraphy of Msikaba Formation constitutes a transgressive sequence from Manaba Member to Uvongo Member, whereas it ended as a regressive sequence from Mhlangeni Member to Shelly beach Member. The Msikaba Formation shows major differences with the Natal Group and Table Mountain Group (Cape Supergroup) in the lithology, stratigraphic sequence, sedimentary structures, facies system, palaeocurrent styles, fossil contents and depositional environments, which demonstrate that they are not the equivalent stratigraphic unit. Therefore, the Msikaba Formation is a separate, younger stratigraphic unit, and cannot correlate with the Natal Group and Table Mountain Group as suggested by previous researchers.
- Full Text:
- Date Issued: 2015
- Authors: Busakwe, Nolukholo Sinovuyo
- Date: 2015
- Subjects: Geology, Stratigraphic Sedimentology -- South Africa -- KwaZulu-Natal
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/2501 , vital:27877
- Description: The Msikaba Formation is a Late Devonian fluvial and marine succession which outcrops from Hibberdene to Port Edward along the south coast of KwaZulu-Natal Province, South Africa. The Formation is composed of brownish conglomerate at the bottom and white-greyish quartz arenite sequence in the middle and mixed quartz-arenite with feldspathic sandstone in the upper sequence. Previous studies put more emphasis on the correlation of Msikaba Formation with the Natal Group and Cape Supergroup, whereas this study revised the stratigraphy, and also put new insight on the petrography, sedimentary facies, depositional environments and diagenesis of the Formation. The total stratigraphic section attains a thickness of 184 m at Margate area and 186 m at Port Edward area. The stratigraphy of Msikaba Formation is well exposed on the outcrops along the KwaZulu-Natal coastline. The stratigraphy is subdivided into 4 new members along Margate to Shelly beach section; namely Manaba Member, Uvongo Member, Mhlangeni Member and Shelly Beach Member from bottom upward. Twelve sedimentary facies were identified and the sedimentary facies were integrated into 4 facies association: Facies association 1 (Gmm+Sm) represents braided fluvial deposits, Facies association 2 (Gcm+St+Sp+Sl+Shb) represents tidal channel and tidal flat deposit, Facies association 3 (St+Sp+Sr+Sl) is result of shallow marine deposit and Facies association 4 (Sp+Sl+St+Sm) is a mixed marine and fluvial deposit. Each facies association represents a specific stratigraphic unit and were deposited in a specific sedimentary environment. Grain size analysis was conducted on seventeen thin sections and 500 grains were counted from each thin section. The sandstone grain size parameters of mean, sorting, skewness and kurtosis fell under the average of 0.75, 0.78, 0.4 and 1.2φ respectively. The results show that most of the grain size are coarse to medium grained throughout the study areas and sorting of the sandstones are moderate to poorly sorted. The cumulative frequency diagrams and bivariate plots show positive skewness and negative kurtosis, which indicate a high hydrodynamic environment. Modal composition analysis and petrography studies show that detrital components of the Msikaba Formation are dominated by monocrystalline quartz, feldspar (mostly K-feldspar) and lithic fragments of igneous and metamorphic rocks. The sandstones could be classified as quartz arenite, sub-arkosic sandstone and feldspathic litharenite; and the provenance analysis indicates that the sandstones were derived from craton interior, recycled or quartzose recycled sources which may derived from weathering and erosion of igneous and metamorphic rocks. Diagenetic processes of the Msikaba Formation have been passed through early, mid- and late diagenetic stages. Cementation, mineral conversion and compaction affect early diagenetic stage; authigenic minerals, quartz and feldspar overgrowth are presented in mid-diagenetic stage, whereas recrystallization, replacement, deformation and dissolution have been strongly affected late diagenetic stage. Microscopy, XRD and SEM-EDX studies have identified five types of cements including smectite clay, kaolinite, hematite, quartz and feldspar cements. Quartz cement, pore-filling and pore-lining clay are the major type of cements in the Msikaba Formation. Based on the lithology, sedimentary structure and facies variations, the Manaba Member was most probably deposited in a braided fluvial environment, the Uvongo Member was deposited in a tidal channel environment, the Mhlangeni Member was formed in shallow marine storm-influenced environment, whereas the Shelly Beach Member was represented mixed marine and fluvial environment. The sequence stratigraphy of Msikaba Formation constitutes a transgressive sequence from Manaba Member to Uvongo Member, whereas it ended as a regressive sequence from Mhlangeni Member to Shelly beach Member. The Msikaba Formation shows major differences with the Natal Group and Table Mountain Group (Cape Supergroup) in the lithology, stratigraphic sequence, sedimentary structures, facies system, palaeocurrent styles, fossil contents and depositional environments, which demonstrate that they are not the equivalent stratigraphic unit. Therefore, the Msikaba Formation is a separate, younger stratigraphic unit, and cannot correlate with the Natal Group and Table Mountain Group as suggested by previous researchers.
- Full Text:
- Date Issued: 2015
The effectiveness of arbitration practice relative to South African construction
- Authors: Bvumbwe, Chikumbutso
- Date: 2015
- Subjects: Arbitration, Industrial -- South Africa Dispute resolution (Law) -- South Africa , Construction industry -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/47981 , vital:40460
- Description: The study investigated the arbitration practice relative to the South African construction industry. Most of the construction contracts include an arbitration clause in the contract document as an instrument to be used for resolving disputes. The aim is to resolve disputes between the parties with minimum costs and within a reasonable period. Some parties opt to involve legal counsel in the process which has a potential of affecting time and cost. The literature review focuses on arbitration, in the construction industry, with a particular focus on how effective the methods are in terms of cost, time and the relationship between the disputing parties, the impact of using legal counsel during the arbitration process versus not involving legal counsel, the arbitration clause not specifying when to declare a dispute, and the perception of construction professionals on arbitration. The study was based on closed-ended questionnaires distributed among senior construction professionals including, architects, quantity surveyors, construction managers, project managers and practising attorneys. 61 respondents completed the questionnaire. The respondents were asked to comment on the effectiveness of alternative dispute resolution, cost, time, causes of disputes, and impacts of disputes. The cost of arbitration seems to escalate as a result of legal counsel being involved during the arbitration procedures. The time factor also seems to be prolonged. A notable finding indicates that the arbitration clause in the contract document should specify when to declare the dispute. The survey was conducted and limited to the Gauteng Province in South Africa. Findings are of value to clients, contractors and consultants and provides a basis for addressing arbitration effectively in the construction industry.
- Full Text:
- Date Issued: 2015
- Authors: Bvumbwe, Chikumbutso
- Date: 2015
- Subjects: Arbitration, Industrial -- South Africa Dispute resolution (Law) -- South Africa , Construction industry -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/47981 , vital:40460
- Description: The study investigated the arbitration practice relative to the South African construction industry. Most of the construction contracts include an arbitration clause in the contract document as an instrument to be used for resolving disputes. The aim is to resolve disputes between the parties with minimum costs and within a reasonable period. Some parties opt to involve legal counsel in the process which has a potential of affecting time and cost. The literature review focuses on arbitration, in the construction industry, with a particular focus on how effective the methods are in terms of cost, time and the relationship between the disputing parties, the impact of using legal counsel during the arbitration process versus not involving legal counsel, the arbitration clause not specifying when to declare a dispute, and the perception of construction professionals on arbitration. The study was based on closed-ended questionnaires distributed among senior construction professionals including, architects, quantity surveyors, construction managers, project managers and practising attorneys. 61 respondents completed the questionnaire. The respondents were asked to comment on the effectiveness of alternative dispute resolution, cost, time, causes of disputes, and impacts of disputes. The cost of arbitration seems to escalate as a result of legal counsel being involved during the arbitration procedures. The time factor also seems to be prolonged. A notable finding indicates that the arbitration clause in the contract document should specify when to declare the dispute. The survey was conducted and limited to the Gauteng Province in South Africa. Findings are of value to clients, contractors and consultants and provides a basis for addressing arbitration effectively in the construction industry.
- Full Text:
- Date Issued: 2015
The Ecca type section (Permian, South Africa) : an outcrop analogue study of conventional and unconventional hydrocarbon reservoirs
- Authors: Campbell, Stuart Alexander
- Date: 2015
- Subjects: Hydrocarbon reservoirs -- Ecca Group , Geology, Stratigraphic -- Permian , Paleogeography -- Ecca Group , Shale gas -- Ecca Group , Shale gas reservoirs -- Ecca Group , Ecca Group , Ripon Formation (South Africa) , Collingham Formation (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5083 , http://hdl.handle.net/10962/d1018199
- Description: The Karoo Basin of South Africa holds an estimated 906 billion to 11 trillion cubic meters of unconventional shale gas within the shales of the Whitehill and Collingham formations of the Ecca Group. Evaluation of this potential resource has been limited due to the lack of exploration and a scarcity of existing drill core data. In order to circumnavigate this problem this study was undertaken to evaluate the potential target horizons exposed in outcrops along the southern portion of the Karoo Basin, north of Grahamstown in the Eastern Cape Province. Detailed field logging was done on the exposed Whitehill and Collingham formations as well as a possible conventional sandstone (turbidite) reservoir, the Ripon Formation, along road cuttings of the Ecca Pass. Palaeocurrent data, jointing directions and fossil material were also documented. Samples were analysed for mineralogy, porosity, permeability, and total organic carbon content (TOC). The extensively weathered black shales of the Whitehill Formation contain a maximum TOC value of 0.9% and the Collingham Formation shales contain a maximum TOC value of 0.6%. The organic lithic arkose sandstones of the Ripon Formation are classified as ‘tight rock’ with an average porosity of 1% and an average permeability of 0.05 mD. The Whitehill Formation in the southern portion of the Karoo Basin has experienced organic matter loss due to low grade metamorphism as well as burial to extreme depths, thus reducing shale gas potential. The Ripon Formation is an unsuitable conventional reservoir along the southern basin boundary due to extensive cementation and filling of pore spaces.
- Full Text:
- Date Issued: 2015
- Authors: Campbell, Stuart Alexander
- Date: 2015
- Subjects: Hydrocarbon reservoirs -- Ecca Group , Geology, Stratigraphic -- Permian , Paleogeography -- Ecca Group , Shale gas -- Ecca Group , Shale gas reservoirs -- Ecca Group , Ecca Group , Ripon Formation (South Africa) , Collingham Formation (South Africa)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5083 , http://hdl.handle.net/10962/d1018199
- Description: The Karoo Basin of South Africa holds an estimated 906 billion to 11 trillion cubic meters of unconventional shale gas within the shales of the Whitehill and Collingham formations of the Ecca Group. Evaluation of this potential resource has been limited due to the lack of exploration and a scarcity of existing drill core data. In order to circumnavigate this problem this study was undertaken to evaluate the potential target horizons exposed in outcrops along the southern portion of the Karoo Basin, north of Grahamstown in the Eastern Cape Province. Detailed field logging was done on the exposed Whitehill and Collingham formations as well as a possible conventional sandstone (turbidite) reservoir, the Ripon Formation, along road cuttings of the Ecca Pass. Palaeocurrent data, jointing directions and fossil material were also documented. Samples were analysed for mineralogy, porosity, permeability, and total organic carbon content (TOC). The extensively weathered black shales of the Whitehill Formation contain a maximum TOC value of 0.9% and the Collingham Formation shales contain a maximum TOC value of 0.6%. The organic lithic arkose sandstones of the Ripon Formation are classified as ‘tight rock’ with an average porosity of 1% and an average permeability of 0.05 mD. The Whitehill Formation in the southern portion of the Karoo Basin has experienced organic matter loss due to low grade metamorphism as well as burial to extreme depths, thus reducing shale gas potential. The Ripon Formation is an unsuitable conventional reservoir along the southern basin boundary due to extensive cementation and filling of pore spaces.
- Full Text:
- Date Issued: 2015
Sedimentological and geochemical investigations on borehole cores of the Lower Ecca Group black shales, for their gas potential : Karoo basin, South Africa
- Authors: Chere, Naledi
- Date: 2015
- Subjects: Sediments (Geology) -- South Africa , Gas reservoirs -- South Africa , Natural gas reserves -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10679 , http://hdl.handle.net/10948/d1021201
- Description: In the recent years, the shale gas discourse has become central to discussions about future energy supply in South Africa. In particular, the Permian black shales of the Lower Ecca Group formations in the Karoo Basin are considered potential source rocks for shale gas. The research presented in this thesis advances the understanding of the shale gas potential of mainly the Prince Albert, Whitehill and Tierberg/Collingham Formations. These shale sequences were sampled from eight deep boreholes spread across the main Karoo Basin and geochemically analysed at the GFZ - Helmholtz Centre Potsdam, Germany. Three key questions guided the study, these are: (i) what is the lithology of the sequence; (ii) where in the basin do the shale sequences attain maximum thickness at optimum depth i.e. beneath 1000-1500m; and (iii) and their shale characteristics. To evaluate these, borehole core logging, petrology and organic geochemistry were used extensively. Petrology involved the use of thin section, scanned electron and transmission electron microscopy for mineralogy as well as the identification of sedimentary features, organic matter and nano-scale porosity. These were coupled with standard organic geochemistry techniques such as Rock Eval. analysis, open pyrolysis gas chromatography and thermovaporisation to quantify the free gas, total organic carbon (TOC), present-day gas generative potential and kerogen type. The results show that the Whitehill Formation, away from the CFB and not intruded by dolerite, has the most potential for shale gas. Microscopic studies of this pyritic black shale reveal the occurrence of porous amorphous matter, indicating thermal maturity within the gas generation zone (i.e. > 1.1 percent Ro, 120ºC). The TOC content is consistently high within the Whitehill (exceeding industry requirement of 2 percent), attaining maximum of 7.3 percent. The highest yields of free and desorbed gas, especially methane, were emitted within this formation (S1 and nC1 peaks); mostly within its dolomitic units. In addition, dissolution porosity within dolomite units of the Whitehill Formation was identified as the predominant type of porosity. Thus, it is deduced that the dolomitic units of Whitehill Formation potentially contain the greatest volumes of free gas. HI values attain maximum of 25 mg HC/g TOC, whereas the OI values 26 mg CO2/g TOC. Such low HI and OI values are typically attributed to the dominance of Type IV kerogen, and consistent with overmaturity. Open pyrolysis (GC) show the main the chemical compound of the organic matter to be m-p-xylene, consistent with a mix of Type III, Type I/II and Type IV kerogen. Lithologically, the Whitehill Formation is composed of ~ 35 quartz, 13 percent feldspar, 26 percent illite and ~ 23 percent dolomite with variable amounts of pyrite. The dominance of quartz is directly proportional to the brittleness of the rock. Thus it can be deduced that the Whitehill Formation is relatively brittle and therefore fraccable. Burial trends indicate increasing depth (from ground level) to the top of the Whitehill Formation towards the south and south-eastern portion of the basin. It is in the southern region where thicknesses of this black shale exceeding 50m occur at depths more than 1500m; 1000m beneath fresh water aquifers. It therefore concluded that Whitehill Formation in the southern portion of Karoo Basin, but away from the thermo-tectonic overprint of the Cape Orogeny, is the most probable shale gas reservoir in South Africa.
- Full Text:
- Date Issued: 2015
- Authors: Chere, Naledi
- Date: 2015
- Subjects: Sediments (Geology) -- South Africa , Gas reservoirs -- South Africa , Natural gas reserves -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10679 , http://hdl.handle.net/10948/d1021201
- Description: In the recent years, the shale gas discourse has become central to discussions about future energy supply in South Africa. In particular, the Permian black shales of the Lower Ecca Group formations in the Karoo Basin are considered potential source rocks for shale gas. The research presented in this thesis advances the understanding of the shale gas potential of mainly the Prince Albert, Whitehill and Tierberg/Collingham Formations. These shale sequences were sampled from eight deep boreholes spread across the main Karoo Basin and geochemically analysed at the GFZ - Helmholtz Centre Potsdam, Germany. Three key questions guided the study, these are: (i) what is the lithology of the sequence; (ii) where in the basin do the shale sequences attain maximum thickness at optimum depth i.e. beneath 1000-1500m; and (iii) and their shale characteristics. To evaluate these, borehole core logging, petrology and organic geochemistry were used extensively. Petrology involved the use of thin section, scanned electron and transmission electron microscopy for mineralogy as well as the identification of sedimentary features, organic matter and nano-scale porosity. These were coupled with standard organic geochemistry techniques such as Rock Eval. analysis, open pyrolysis gas chromatography and thermovaporisation to quantify the free gas, total organic carbon (TOC), present-day gas generative potential and kerogen type. The results show that the Whitehill Formation, away from the CFB and not intruded by dolerite, has the most potential for shale gas. Microscopic studies of this pyritic black shale reveal the occurrence of porous amorphous matter, indicating thermal maturity within the gas generation zone (i.e. > 1.1 percent Ro, 120ºC). The TOC content is consistently high within the Whitehill (exceeding industry requirement of 2 percent), attaining maximum of 7.3 percent. The highest yields of free and desorbed gas, especially methane, were emitted within this formation (S1 and nC1 peaks); mostly within its dolomitic units. In addition, dissolution porosity within dolomite units of the Whitehill Formation was identified as the predominant type of porosity. Thus, it is deduced that the dolomitic units of Whitehill Formation potentially contain the greatest volumes of free gas. HI values attain maximum of 25 mg HC/g TOC, whereas the OI values 26 mg CO2/g TOC. Such low HI and OI values are typically attributed to the dominance of Type IV kerogen, and consistent with overmaturity. Open pyrolysis (GC) show the main the chemical compound of the organic matter to be m-p-xylene, consistent with a mix of Type III, Type I/II and Type IV kerogen. Lithologically, the Whitehill Formation is composed of ~ 35 quartz, 13 percent feldspar, 26 percent illite and ~ 23 percent dolomite with variable amounts of pyrite. The dominance of quartz is directly proportional to the brittleness of the rock. Thus it can be deduced that the Whitehill Formation is relatively brittle and therefore fraccable. Burial trends indicate increasing depth (from ground level) to the top of the Whitehill Formation towards the south and south-eastern portion of the basin. It is in the southern region where thicknesses of this black shale exceeding 50m occur at depths more than 1500m; 1000m beneath fresh water aquifers. It therefore concluded that Whitehill Formation in the southern portion of Karoo Basin, but away from the thermo-tectonic overprint of the Cape Orogeny, is the most probable shale gas reservoir in South Africa.
- Full Text:
- Date Issued: 2015
Eliciting and combining expert opinion : an overview and comparison of methods
- Authors: Chinyamakobvu, Mutsa Carole
- Date: 2015
- Subjects: Decision making -- Statistical methods , Expertise , Bayesian statistical decision theory , Statistical decision , Delphi method , Paired comparisons (Statistics)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5579 , http://hdl.handle.net/10962/d1017827
- Description: Decision makers have long relied on experts to inform their decision making. Expert judgment analysis is a way to elicit and combine the opinions of a group of experts to facilitate decision making. The use of expert judgment is most appropriate when there is a lack of data for obtaining reasonable statistical results. The experts are asked for advice by one or more decision makers who face a specific real decision problem. The decision makers are outside the group of experts and are jointly responsible and accountable for the decision and committed to finding solutions that everyone can live with. The emphasis is on the decision makers learning from the experts. The focus of this thesis is an overview and comparison of the various elicitation and combination methods available. These include the traditional committee method, the Delphi method, the paired comparisons method, the negative exponential model, Cooke’s classical model, the histogram technique, using the Dirichlet distribution in the case of a set of uncertain proportions which must sum to one, and the employment of overfitting. The supra Bayes approach, the determination of weights for the experts, and combining the opinions of experts where each opinion is associated with a confidence level that represents the expert’s conviction of his own judgment are also considered.
- Full Text:
- Date Issued: 2015
- Authors: Chinyamakobvu, Mutsa Carole
- Date: 2015
- Subjects: Decision making -- Statistical methods , Expertise , Bayesian statistical decision theory , Statistical decision , Delphi method , Paired comparisons (Statistics)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5579 , http://hdl.handle.net/10962/d1017827
- Description: Decision makers have long relied on experts to inform their decision making. Expert judgment analysis is a way to elicit and combine the opinions of a group of experts to facilitate decision making. The use of expert judgment is most appropriate when there is a lack of data for obtaining reasonable statistical results. The experts are asked for advice by one or more decision makers who face a specific real decision problem. The decision makers are outside the group of experts and are jointly responsible and accountable for the decision and committed to finding solutions that everyone can live with. The emphasis is on the decision makers learning from the experts. The focus of this thesis is an overview and comparison of the various elicitation and combination methods available. These include the traditional committee method, the Delphi method, the paired comparisons method, the negative exponential model, Cooke’s classical model, the histogram technique, using the Dirichlet distribution in the case of a set of uncertain proportions which must sum to one, and the employment of overfitting. The supra Bayes approach, the determination of weights for the experts, and combining the opinions of experts where each opinion is associated with a confidence level that represents the expert’s conviction of his own judgment are also considered.
- Full Text:
- Date Issued: 2015