Thermal degradation of diamond compacts: a TEM investigation
- Authors: Westraadt, Johan Ewald
- Date: 2011
- Subjects: Materials -- Thermal properties Chemical weathering
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/10829 , vital:26827
- Description: Diamond compacts consist of fine diamond grains bonded together by using high pressure and high temperature. In this study transmission electron microscopy (TEM)was used to study thermal degradation of diamond compacts. Three different types of diamond compacts – namely cobalt polycrystalline diamond (PCD), calcium carbonate PCD, and diamond-SiC composites – were investigated with TEM to understand the processes that occur during synthesis. These compacts were then heated in inert atmospheres and the chemical changes studied with TEM. It was found that PCD, using cobalt as a bonding agent, will degrade after exposure to temperatures above 750ºC. The cobalt pools contain tungsten in solid solution. During heat treatment above 700ºC the solid solution tungsten combines with cobalt and dissolved carbon to form η-phase particles at the cobalt/diamond interface. At higher temperatures or insufficient tungsten levels the rate of dissolved carbon, into the cobalt pool, is too high and the excess carbon will form as graphite in the cobalt pool. Increased levels of solid solution tungsten, in the cobalt, is expected to delay the onset of graphitization in the diamond compact, thereby increasing the thermal stability of the diamond compact. Non-metallic PCD using calcium carbonate as a bonding agent was successfully sintered in this study. TEM revealed similar micro-structural features as in cobalt based PCD. No signs of thermal degradation were found after exposure to 1200ºC in vacuum for this PCD. Contaminants introduced during processing prevented a detailed study of the binder in this system. The effect of substitutional metal atoms and plastic deformation of diamond on the thermal stability of diamond-SiC composites were investigated. A piston cylinder press was developed and used to synthesize diamond-SiC composites with different levels of plastically deformed diamond. It was concluded that substitutional metal atoms and plastic deformation of diamond grains play no role in the thermal degradation of diamond compacts at 750ºC. The thermal degradation of cobalt PCD is therefore completely determined by the cobalt/diamond interaction at 750ºC.
- Full Text:
- Date Issued: 2011
- Authors: Westraadt, Johan Ewald
- Date: 2011
- Subjects: Materials -- Thermal properties Chemical weathering
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/10829 , vital:26827
- Description: Diamond compacts consist of fine diamond grains bonded together by using high pressure and high temperature. In this study transmission electron microscopy (TEM)was used to study thermal degradation of diamond compacts. Three different types of diamond compacts – namely cobalt polycrystalline diamond (PCD), calcium carbonate PCD, and diamond-SiC composites – were investigated with TEM to understand the processes that occur during synthesis. These compacts were then heated in inert atmospheres and the chemical changes studied with TEM. It was found that PCD, using cobalt as a bonding agent, will degrade after exposure to temperatures above 750ºC. The cobalt pools contain tungsten in solid solution. During heat treatment above 700ºC the solid solution tungsten combines with cobalt and dissolved carbon to form η-phase particles at the cobalt/diamond interface. At higher temperatures or insufficient tungsten levels the rate of dissolved carbon, into the cobalt pool, is too high and the excess carbon will form as graphite in the cobalt pool. Increased levels of solid solution tungsten, in the cobalt, is expected to delay the onset of graphitization in the diamond compact, thereby increasing the thermal stability of the diamond compact. Non-metallic PCD using calcium carbonate as a bonding agent was successfully sintered in this study. TEM revealed similar micro-structural features as in cobalt based PCD. No signs of thermal degradation were found after exposure to 1200ºC in vacuum for this PCD. Contaminants introduced during processing prevented a detailed study of the binder in this system. The effect of substitutional metal atoms and plastic deformation of diamond on the thermal stability of diamond-SiC composites were investigated. A piston cylinder press was developed and used to synthesize diamond-SiC composites with different levels of plastically deformed diamond. It was concluded that substitutional metal atoms and plastic deformation of diamond grains play no role in the thermal degradation of diamond compacts at 750ºC. The thermal degradation of cobalt PCD is therefore completely determined by the cobalt/diamond interaction at 750ºC.
- Full Text:
- Date Issued: 2011
Land use/cover change modelling and land degradation assessment in the Keiskamma catchment using remote sensing and GIS
- Authors: Mhangara, Paidamwoyo
- Date: 2011
- Subjects: Land use -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape , Keiskamma River (South Africa)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10647 , http://hdl.handle.net/10948/1467 , Land use -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape , Keiskamma River (South Africa)
- Description: Land degradation in most communal parts of the Keiskamma catchment has reached alarming proportions. The Keiskamma catchment is particularly predisposed to severe land degradation associated with soil erosion, thicket degradation and deteriorating riparian vegetation. There is a close coupling between land use/cover dynamics and degradation trends witnessed in the catchment. Soil erosion is prevalent in most of the communal areas in the catchment. The principal aim of this study was to investigate land use/cover trends, model the spatial patterns of soil loss and predict future land use/cover scenarios as a means of assessing land degradation in the Keiskamma catchment. Multi-temporal Landsat satellite imagery from 1972 to 2006 was used for land use/cover change analyses using object-oriented post-classification comparison. Fragmentation analysis was performed by computing and analyzing landscape metrics in the riparian and adjacent hillslope areas to determine the land cover structural changes that have occurred since 1972. The landscape function analysis was used to validate the current rangeland conditions in the communal areas and the former commercial farms. The current condition of the riparian zones and proximal hillslopes was assessed using the Rapid Appraisal of Riparian Condition and future land use/cover scenarios were simulated using the Markovcellular automata model. Spatial patterns of soil loss in the Keiskamma catchment were determined using the Sediment Assessment Tool for Effective Erosion Control (SATEEC), which is a GIS based RUSLE model that integrates sediment delivery ratios. Object oriented classification was used to map soil erosion surfaces and valley infill in ephemeral stream channels as a means of demonstrating the major sediment transfer processes operating in the Keiskamma catchment. The Mahalanobis distance method was used to compute the topographic thresholds for gully erosion. To understand the effect of soil characteristics in severe forms of erosion, laboratory analyses were undertaken to determine the physico-chemical soil properties. iv The temporal land use/cover analysis done using the post-classification change detection indicated that intact vegetation has undergone a significant decline from 1972 to 2006. The temporal changes within the intermediate years are characterized by cyclic transitions of decline and recovery of intact vegetation. An overall decline in intact vegetation cover, an increase in degraded vegetation and bare eroded soil was noted. Fragmentation analyses done in the communal villages of the central Keiskamma catchment indicated increasing vegetation fragmentation manifested by an increase in smaller and less connected vegetation patches, and a subsequent increase of bare and degraded soil patches which are much bigger and more connected. The Landscape Organisation Index revealed very low vegetation connectivity in the communal rangelands that have weak local traditional institutions. Fragmentation analyses in the riparian and proximal hillslopes revealed evidence of increasing vegetation fragmentation from 1972 to 2006. The Markov Cellular Automata simulation predicted a decline in intact vegetation and an increase in bare and degraded soil in 2019. The Keiskamma catchment was noted as experiencing high rates of soil loss that are above provincial and national averages. The classification of erosion features and valley infill showcased the vegetation enrichment in the ephemeral streams which is occurring at the expense of high soil losses from severe gully erosion on the hillslopes. This in turn has led to an inversion of grazing patterns within the catchment, such that grazing is now concentrated within the ephemeral stream channels. Soil chemical analyses revealed a high sodium content and low soluble salt concentration, which promote soil dispersion, piping and gully erosion. The presence of high amounts of illite-smectite in the catchment also accounts for the highly dispersive nature of the soil even at low SAR values. Significant amounts of swelling 2:1 silicate clays such as smectites cause cracking and contribute to the development of piping and gullying in the catchment. Given the worsening degradation trends in the communal areas, a systematic re-allocation of state land in sections of the catchment that belonged to the former commercial farms is recommended to alleviate anthropogenic pressure. Strengthening local institutions that effectively monitor and manage natural resources will be required in order to maintain v optimum flow regimes in rivers and curb thicket degradation. Measures to curb environmental degradation in the Keiskamma catchment should encompass suitable ecological interventions that are sensitive to the socio-economic challenges facing the people in communal areas.
- Full Text:
- Date Issued: 2011
- Authors: Mhangara, Paidamwoyo
- Date: 2011
- Subjects: Land use -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape , Keiskamma River (South Africa)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10647 , http://hdl.handle.net/10948/1467 , Land use -- South Africa -- Eastern Cape , Land degradation -- South Africa -- Eastern Cape , Keiskamma River (South Africa)
- Description: Land degradation in most communal parts of the Keiskamma catchment has reached alarming proportions. The Keiskamma catchment is particularly predisposed to severe land degradation associated with soil erosion, thicket degradation and deteriorating riparian vegetation. There is a close coupling between land use/cover dynamics and degradation trends witnessed in the catchment. Soil erosion is prevalent in most of the communal areas in the catchment. The principal aim of this study was to investigate land use/cover trends, model the spatial patterns of soil loss and predict future land use/cover scenarios as a means of assessing land degradation in the Keiskamma catchment. Multi-temporal Landsat satellite imagery from 1972 to 2006 was used for land use/cover change analyses using object-oriented post-classification comparison. Fragmentation analysis was performed by computing and analyzing landscape metrics in the riparian and adjacent hillslope areas to determine the land cover structural changes that have occurred since 1972. The landscape function analysis was used to validate the current rangeland conditions in the communal areas and the former commercial farms. The current condition of the riparian zones and proximal hillslopes was assessed using the Rapid Appraisal of Riparian Condition and future land use/cover scenarios were simulated using the Markovcellular automata model. Spatial patterns of soil loss in the Keiskamma catchment were determined using the Sediment Assessment Tool for Effective Erosion Control (SATEEC), which is a GIS based RUSLE model that integrates sediment delivery ratios. Object oriented classification was used to map soil erosion surfaces and valley infill in ephemeral stream channels as a means of demonstrating the major sediment transfer processes operating in the Keiskamma catchment. The Mahalanobis distance method was used to compute the topographic thresholds for gully erosion. To understand the effect of soil characteristics in severe forms of erosion, laboratory analyses were undertaken to determine the physico-chemical soil properties. iv The temporal land use/cover analysis done using the post-classification change detection indicated that intact vegetation has undergone a significant decline from 1972 to 2006. The temporal changes within the intermediate years are characterized by cyclic transitions of decline and recovery of intact vegetation. An overall decline in intact vegetation cover, an increase in degraded vegetation and bare eroded soil was noted. Fragmentation analyses done in the communal villages of the central Keiskamma catchment indicated increasing vegetation fragmentation manifested by an increase in smaller and less connected vegetation patches, and a subsequent increase of bare and degraded soil patches which are much bigger and more connected. The Landscape Organisation Index revealed very low vegetation connectivity in the communal rangelands that have weak local traditional institutions. Fragmentation analyses in the riparian and proximal hillslopes revealed evidence of increasing vegetation fragmentation from 1972 to 2006. The Markov Cellular Automata simulation predicted a decline in intact vegetation and an increase in bare and degraded soil in 2019. The Keiskamma catchment was noted as experiencing high rates of soil loss that are above provincial and national averages. The classification of erosion features and valley infill showcased the vegetation enrichment in the ephemeral streams which is occurring at the expense of high soil losses from severe gully erosion on the hillslopes. This in turn has led to an inversion of grazing patterns within the catchment, such that grazing is now concentrated within the ephemeral stream channels. Soil chemical analyses revealed a high sodium content and low soluble salt concentration, which promote soil dispersion, piping and gully erosion. The presence of high amounts of illite-smectite in the catchment also accounts for the highly dispersive nature of the soil even at low SAR values. Significant amounts of swelling 2:1 silicate clays such as smectites cause cracking and contribute to the development of piping and gullying in the catchment. Given the worsening degradation trends in the communal areas, a systematic re-allocation of state land in sections of the catchment that belonged to the former commercial farms is recommended to alleviate anthropogenic pressure. Strengthening local institutions that effectively monitor and manage natural resources will be required in order to maintain v optimum flow regimes in rivers and curb thicket degradation. Measures to curb environmental degradation in the Keiskamma catchment should encompass suitable ecological interventions that are sensitive to the socio-economic challenges facing the people in communal areas.
- Full Text:
- Date Issued: 2011
Land use change, landslide occurrence and livelihood strategies on Mount Elgon Slopes, Eastern Uganda
- Authors: Mugagga, Frank
- Date: 2011
- Subjects: Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10646 , http://hdl.handle.net/10948/1468 , Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Description: An investigation of the relationship between the physical, pedological and anthropogenic influences on landslide occurrence on the midslopes within and outside Mt Elgon National Park was carried out. One of the landslides occurred in a protected pristine forest environment within the Park while the other two were located at sites deforested for cultivation within and outside the National Park. Field based surveys, GIS techniques and laboratory tests were used to collect and analyze the data. A household survey was undertaken to establish the main community livelihood strategies, the drivers of land use change and implications for land degradation on the mid slopes of Mt Elgon. Aerial photographs taken in 1960 and orthophoto maps formed the benchmark for the analysis of the respective land use changes between 1995 and 2006, using 30m Landsat TM and 20m SPOT MS images in IDRISI Andes GIS environment. Landslide sites were mapped using a Magellan Professional MobileMapperTMCX and terrain parameters were derived using a 15M Digital Elevation Model. A hybrid supervised/unsupervised classification approach was employed to generate land cover maps from which the areal extent of three land cover classes (agricultural fields, woodlands and forests) was calculated. Particle size distribution and atterberg limits were used to test the hypothesis that soils at the landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Shear strength parameters (internal of friction and cohesion) were used calculate the slope factor of safety to ascertain slope stability at pristine and disturbed landslide sites. Results from the socio-economic survey revealed that smallholder subsistence agriculture and encroachment on the National Park resources are the main sources of livelihoods for the communities surrounding the Park. The communities also have a strong socio-cultural attachment to the National Park, as it is the source of items used during traditional rituals like circumcision. Encroachment is driven by the high population pressure and the prevalent political climate. Farmers mainly use slash and burn technique to prepare land for cultivation and those close to the National Park are reluctant to adopt appropriate farming and soil conservation practices due to the uncertainties surrounding their future on such plots. Slash and burn iii techniques were observed to accelerate various forms of erosion including rills, gullies and sheet. Soil and water conservation techniques were mainly practiced on privately owned farms. The period 1960 and 1995 was characterized by minimal land use changes and no encroachment into the designated Mount Elgon National Park. Conversely, the period 1995 – 2006 marked a significant loss of woodlands and forest cover particularly on steep concave slopes (36º – 58º) within the National Park. The land use change trends were attributed to the prevalent land politics and exponential population growth in the region. The encroachment onto the critical slopes was noted to have induced a series of shallow and deep landslides in the area. Deforestation on Mt Elgon was reported to have both onsite and offsite climate variability and implications in the form of drought, heat waves, flash floods, economic dislocation, crop failure and associated malnutrition in surrounding low lying areas. The soils on pristine and disturbed slopes contain high amount of clay (>10 percent), are fine textured (>50 percent of the material passing the 0.075mm sieve) and highly plastic. These soil attributes imply low permeability, excessive water retention and high susceptibility to expansion and sliding. The vertic nature of soils at Nametsi was confirmed by the extremely high plasticity indices (averaging 33percent), while, high liquid limits at Buwabwala (53 percent) and Kitati (59 percent) qualified the soils as vertisols which are associated with landslides. The results point to the fact that soils at landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Therefore, the hypothesis that soils at three landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention is accepted. Notwithstanding the fact that the study was focussed on mid-altitude slopes of Mt Elgon, the results are in tandem with investigations carried out earlier on the lower densely populated slopes, thus confirming the widespread nature of problem soils on Mt Elgon. There is an urgent need to control human population growth and restore forest cover on the heavily deforested steep slopes particularly within the National Park, and restrain communities from encroaching on the pristine slopes of Mt Elgon. This will be achieved if the politicians, Park Authorities and local communities jointly participate in the design and implementation of CFMs. Future research could focus on climate change implications of deforestation of Mt Elgon environments and quantification of carbon loss related to deforestation and soil degradation in the mountain environments.
- Full Text:
- Date Issued: 2011
- Authors: Mugagga, Frank
- Date: 2011
- Subjects: Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10646 , http://hdl.handle.net/10948/1468 , Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Description: An investigation of the relationship between the physical, pedological and anthropogenic influences on landslide occurrence on the midslopes within and outside Mt Elgon National Park was carried out. One of the landslides occurred in a protected pristine forest environment within the Park while the other two were located at sites deforested for cultivation within and outside the National Park. Field based surveys, GIS techniques and laboratory tests were used to collect and analyze the data. A household survey was undertaken to establish the main community livelihood strategies, the drivers of land use change and implications for land degradation on the mid slopes of Mt Elgon. Aerial photographs taken in 1960 and orthophoto maps formed the benchmark for the analysis of the respective land use changes between 1995 and 2006, using 30m Landsat TM and 20m SPOT MS images in IDRISI Andes GIS environment. Landslide sites were mapped using a Magellan Professional MobileMapperTMCX and terrain parameters were derived using a 15M Digital Elevation Model. A hybrid supervised/unsupervised classification approach was employed to generate land cover maps from which the areal extent of three land cover classes (agricultural fields, woodlands and forests) was calculated. Particle size distribution and atterberg limits were used to test the hypothesis that soils at the landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Shear strength parameters (internal of friction and cohesion) were used calculate the slope factor of safety to ascertain slope stability at pristine and disturbed landslide sites. Results from the socio-economic survey revealed that smallholder subsistence agriculture and encroachment on the National Park resources are the main sources of livelihoods for the communities surrounding the Park. The communities also have a strong socio-cultural attachment to the National Park, as it is the source of items used during traditional rituals like circumcision. Encroachment is driven by the high population pressure and the prevalent political climate. Farmers mainly use slash and burn technique to prepare land for cultivation and those close to the National Park are reluctant to adopt appropriate farming and soil conservation practices due to the uncertainties surrounding their future on such plots. Slash and burn iii techniques were observed to accelerate various forms of erosion including rills, gullies and sheet. Soil and water conservation techniques were mainly practiced on privately owned farms. The period 1960 and 1995 was characterized by minimal land use changes and no encroachment into the designated Mount Elgon National Park. Conversely, the period 1995 – 2006 marked a significant loss of woodlands and forest cover particularly on steep concave slopes (36º – 58º) within the National Park. The land use change trends were attributed to the prevalent land politics and exponential population growth in the region. The encroachment onto the critical slopes was noted to have induced a series of shallow and deep landslides in the area. Deforestation on Mt Elgon was reported to have both onsite and offsite climate variability and implications in the form of drought, heat waves, flash floods, economic dislocation, crop failure and associated malnutrition in surrounding low lying areas. The soils on pristine and disturbed slopes contain high amount of clay (>10 percent), are fine textured (>50 percent of the material passing the 0.075mm sieve) and highly plastic. These soil attributes imply low permeability, excessive water retention and high susceptibility to expansion and sliding. The vertic nature of soils at Nametsi was confirmed by the extremely high plasticity indices (averaging 33percent), while, high liquid limits at Buwabwala (53 percent) and Kitati (59 percent) qualified the soils as vertisols which are associated with landslides. The results point to the fact that soils at landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Therefore, the hypothesis that soils at three landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention is accepted. Notwithstanding the fact that the study was focussed on mid-altitude slopes of Mt Elgon, the results are in tandem with investigations carried out earlier on the lower densely populated slopes, thus confirming the widespread nature of problem soils on Mt Elgon. There is an urgent need to control human population growth and restore forest cover on the heavily deforested steep slopes particularly within the National Park, and restrain communities from encroaching on the pristine slopes of Mt Elgon. This will be achieved if the politicians, Park Authorities and local communities jointly participate in the design and implementation of CFMs. Future research could focus on climate change implications of deforestation of Mt Elgon environments and quantification of carbon loss related to deforestation and soil degradation in the mountain environments.
- Full Text:
- Date Issued: 2011
Effects of polarization in a distributed raman fibre amplifier
- Authors: Muguro, Kennedy Mwaura
- Date: 2011
- Subjects: Fiber optics , Polarization (Light) , Optical communications , Optical amplifiers , Raman effect
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10544 , http://hdl.handle.net/10948/d1014621
- Description: The need to exploit the large fibre bandwidth and increase the reach has seen the application of the Raman fibre amplifier (RFA) become indispensable in modern light wave systems. The success and resilience of RFAs in optical communication is deeply rooted in their unique optical properties and new technologies which have allowed the amplifier to come of age. However, the full potential of RFAs in optical communication and other applications are yet to be realized. More so are its polarization properties which still remain largely unexploited and have not been fully understood. In this work, fundamental issues regarding distributed RFA have been investigated with the aim of acquiring a better understanding of the amplifier polarization characteristics which have potential applications. In particular the effects of polarization mode dispersion (PMD) and polarization dependent loss (PDL) have been demonstrated both by simulation and experiment. The possibility of Raman polarization pulling in single mode fibres (SMFs) has also been addressed. Polarization sensitivity of RFA has been known for a long time but the clear manifestation of it has become evident in the advent of modern low PMD fibre. Unlike EDFAs which make use of special doped fibre, RFAs require no special fibre for operation. Besides, RFA uses a very long length of fibre and as such the fibre polarization characteristics come into play during amplification. In the demonstrations presented in this thesis a fibre of PMD coefficient < 0.05 pskm-1/2 was regarded as low PMD fibre while one having coefficient ≥ 0.05 pskm-1/2 was categorized to have high PMD unless otherwise stated. Several experiments were performed to evaluate the RFA gain characteristics with respect to fibre PMD and the system performance in the presence of noise emanating from amplified spontaneous emission (ASE). Analysis of Raman gain statistics was done for fibres of low and high PMD coefficients. The statistics of PDG and on-off gain were eventually used to demonstrate the extraction of PMD coefficients of fibres between 0.01- 0.1 pskm-1/2 using a forward pumping configuration. It was found that, at increasing pump power a linear relationship exists between forward and backward signal gain on a dB scale. The interaction of PDL and Raman PDG in the presence of PMD were observed at very fundamental level. It was found the presence of PDL serves to reduce the available on-off gain. It was also established that the presence of PMD mediates the interaction between PDG/PDL. When PMD is high it reduces PDG but the presence of PDL introduces a wavelength dependent gain tilting for WDM channels. Further analysis revealed that signal polarization is influenced by the pump SOP due to the pulling effect which is present even at moderate pump power.
- Full Text:
- Date Issued: 2011
- Authors: Muguro, Kennedy Mwaura
- Date: 2011
- Subjects: Fiber optics , Polarization (Light) , Optical communications , Optical amplifiers , Raman effect
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10544 , http://hdl.handle.net/10948/d1014621
- Description: The need to exploit the large fibre bandwidth and increase the reach has seen the application of the Raman fibre amplifier (RFA) become indispensable in modern light wave systems. The success and resilience of RFAs in optical communication is deeply rooted in their unique optical properties and new technologies which have allowed the amplifier to come of age. However, the full potential of RFAs in optical communication and other applications are yet to be realized. More so are its polarization properties which still remain largely unexploited and have not been fully understood. In this work, fundamental issues regarding distributed RFA have been investigated with the aim of acquiring a better understanding of the amplifier polarization characteristics which have potential applications. In particular the effects of polarization mode dispersion (PMD) and polarization dependent loss (PDL) have been demonstrated both by simulation and experiment. The possibility of Raman polarization pulling in single mode fibres (SMFs) has also been addressed. Polarization sensitivity of RFA has been known for a long time but the clear manifestation of it has become evident in the advent of modern low PMD fibre. Unlike EDFAs which make use of special doped fibre, RFAs require no special fibre for operation. Besides, RFA uses a very long length of fibre and as such the fibre polarization characteristics come into play during amplification. In the demonstrations presented in this thesis a fibre of PMD coefficient < 0.05 pskm-1/2 was regarded as low PMD fibre while one having coefficient ≥ 0.05 pskm-1/2 was categorized to have high PMD unless otherwise stated. Several experiments were performed to evaluate the RFA gain characteristics with respect to fibre PMD and the system performance in the presence of noise emanating from amplified spontaneous emission (ASE). Analysis of Raman gain statistics was done for fibres of low and high PMD coefficients. The statistics of PDG and on-off gain were eventually used to demonstrate the extraction of PMD coefficients of fibres between 0.01- 0.1 pskm-1/2 using a forward pumping configuration. It was found that, at increasing pump power a linear relationship exists between forward and backward signal gain on a dB scale. The interaction of PDL and Raman PDG in the presence of PMD were observed at very fundamental level. It was found the presence of PDL serves to reduce the available on-off gain. It was also established that the presence of PMD mediates the interaction between PDG/PDL. When PMD is high it reduces PDG but the presence of PDL introduces a wavelength dependent gain tilting for WDM channels. Further analysis revealed that signal polarization is influenced by the pump SOP due to the pulling effect which is present even at moderate pump power.
- Full Text:
- Date Issued: 2011
Macrophytes as indicators of physico-chemical factors in South African Estuaries
- Authors: Bezuidenhout, Chantel
- Date: 2011
- Subjects: Estuarine ecology -- South Africa , Aquatic plants -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10597 , http://hdl.handle.net/10948/1387 , Estuarine ecology -- South Africa , Aquatic plants -- South Africa
- Description: This study investigated the response of macrophytes to physico-chemical factors in seven South African estuaries and showed that dominant salt marsh species that occur in different estuaries respond to the same environmental factors. The most important variables influencing distribution were elevation, water level, sediment- and groundwater electrical conductivity and depth to the water table. In permanently open estuaries (Kromme and Olifants) transect surveys identified three distinct vegetation zones i.e. submerged macrophytes, intertidal salt marsh and supratidal salt marsh. In the Kromme Estuary intertidal salt marsh (81.2 ha) covered extensive areas, whereas supratidal (143 ha) and floodplain (797.1 ha) salt marsh were dominant in the Olifants Estuary. Transect surveys identified four distinct vegetation zones (submerged macrophytes, intertidal salt marsh, supratidal salt marsh and reeds and sedges) in the temporarily open/closed estuaries (Mngazi, Great Brak, East Kleinemonde and Seekoei estuaries), although all zones did not occur in all of the estuaries sampled. In the Mngazi Estuary reeds and sedges (1.09 ha) covered extensive areas (no submerged or salt marsh vegetation was present), whereas salt marsh (Great Brak 24.45 ha, East Kleinemonde 17.44 ha and Seekoei 12.9 ha) vegetation was dominant in the other estuaries. Despite the geographic differences, environmental factors influencing macrophyte distribution were similar in all estuaries. Canonical Correspondence Analysis showed that vegetation distribution was significantly affected by elevation, groundwater and sediment electrical conductivity and depth to groundwater. Supratidal species were associated with a greater depth to groundwater (1.2 ± 0.04 m; n = 153) compared to intertidal species (0.5 ± 0.01 m; n = 361). Correlation analysis showed that water level and rainfall were correlated with groundwater electrical conductivity in the lower and upper intertidal zones for all the estuaries sampled. These data indicate the influence of the estuary channel on the physico-chemical conditions of the salt marsh. Low rainfall (16 ± 3.3 mm per annum) in the Olifants Estuary (30-100 mS cm-1) and lack of freshwater flooding in the Kromme Estuary (42-115 mS cm-1) have resulted in high sediment electrical conductivity by comparison with the other estuaries sampled. In the Orange River Estuary approximately 70 ha of salt marsh have been lost through the building of a causeway and flood control levees. Even though salt marsh vegetation can tolerate hypersaline sediments by using the less saline water table, the groundwater at the Orange River Estuary was too saline (avg. of 90.3 ± 6.55 mS cm-1, n = 38) to be of use to the dominant floodplain species, Sarcocornia pillansii. Freshwater inflow to estuaries is important in maintaining longitudinal salinity gradients and reducing hypersaline conditions. In the Olifants Estuary and the Orange River Estuary where supratidal salt marsh is dominant, freshwater inflow is important in raising the water level and maintaining the depth to groundwater and salinity. Lack of freshwater inflow to the Kromme Estuary has highlighted the importance of rainfall in maintaining sediment salinity within acceptable ranges for the salt marsh. Macrophytes are relatively good indicators of physico-chemical factors in estuaries. From an understanding of the response of specific species to environmental variables, ecological water requirements can be set and sensitive areas can be rehabilitated.
- Full Text:
- Date Issued: 2011
- Authors: Bezuidenhout, Chantel
- Date: 2011
- Subjects: Estuarine ecology -- South Africa , Aquatic plants -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10597 , http://hdl.handle.net/10948/1387 , Estuarine ecology -- South Africa , Aquatic plants -- South Africa
- Description: This study investigated the response of macrophytes to physico-chemical factors in seven South African estuaries and showed that dominant salt marsh species that occur in different estuaries respond to the same environmental factors. The most important variables influencing distribution were elevation, water level, sediment- and groundwater electrical conductivity and depth to the water table. In permanently open estuaries (Kromme and Olifants) transect surveys identified three distinct vegetation zones i.e. submerged macrophytes, intertidal salt marsh and supratidal salt marsh. In the Kromme Estuary intertidal salt marsh (81.2 ha) covered extensive areas, whereas supratidal (143 ha) and floodplain (797.1 ha) salt marsh were dominant in the Olifants Estuary. Transect surveys identified four distinct vegetation zones (submerged macrophytes, intertidal salt marsh, supratidal salt marsh and reeds and sedges) in the temporarily open/closed estuaries (Mngazi, Great Brak, East Kleinemonde and Seekoei estuaries), although all zones did not occur in all of the estuaries sampled. In the Mngazi Estuary reeds and sedges (1.09 ha) covered extensive areas (no submerged or salt marsh vegetation was present), whereas salt marsh (Great Brak 24.45 ha, East Kleinemonde 17.44 ha and Seekoei 12.9 ha) vegetation was dominant in the other estuaries. Despite the geographic differences, environmental factors influencing macrophyte distribution were similar in all estuaries. Canonical Correspondence Analysis showed that vegetation distribution was significantly affected by elevation, groundwater and sediment electrical conductivity and depth to groundwater. Supratidal species were associated with a greater depth to groundwater (1.2 ± 0.04 m; n = 153) compared to intertidal species (0.5 ± 0.01 m; n = 361). Correlation analysis showed that water level and rainfall were correlated with groundwater electrical conductivity in the lower and upper intertidal zones for all the estuaries sampled. These data indicate the influence of the estuary channel on the physico-chemical conditions of the salt marsh. Low rainfall (16 ± 3.3 mm per annum) in the Olifants Estuary (30-100 mS cm-1) and lack of freshwater flooding in the Kromme Estuary (42-115 mS cm-1) have resulted in high sediment electrical conductivity by comparison with the other estuaries sampled. In the Orange River Estuary approximately 70 ha of salt marsh have been lost through the building of a causeway and flood control levees. Even though salt marsh vegetation can tolerate hypersaline sediments by using the less saline water table, the groundwater at the Orange River Estuary was too saline (avg. of 90.3 ± 6.55 mS cm-1, n = 38) to be of use to the dominant floodplain species, Sarcocornia pillansii. Freshwater inflow to estuaries is important in maintaining longitudinal salinity gradients and reducing hypersaline conditions. In the Olifants Estuary and the Orange River Estuary where supratidal salt marsh is dominant, freshwater inflow is important in raising the water level and maintaining the depth to groundwater and salinity. Lack of freshwater inflow to the Kromme Estuary has highlighted the importance of rainfall in maintaining sediment salinity within acceptable ranges for the salt marsh. Macrophytes are relatively good indicators of physico-chemical factors in estuaries. From an understanding of the response of specific species to environmental variables, ecological water requirements can be set and sensitive areas can be rehabilitated.
- Full Text:
- Date Issued: 2011
Mutational analysis of the PacC binding sites within the aflR promoter in Aspergillus flavus
- Authors: Suleman, Essa
- Date: 2011
- Subjects: Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10336 , http://hdl.handle.net/10948/d1012683 , Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Description: It is generally known that media containing simple sugars (sucrose, glucose) and organic nitrogen sources (ammonium) when buffered to acidic pH stimulates aflatoxin production in Aspergillus flavus & A. parasiticus while lactose, nitrate and an alkaline pH inhibit aflatoxin biosynthesis. It has been shown that pH of the growth medium is the most important regulatory factor for aflatoxin biosynthesis since media containing stimulatory carbon and/or nitrogen sources (sucrose and ammonia) do not enhance aflatoxin (or sterigmatocystin) production at alkaline pH. RNA interference (in A. flavus) of the pH regulatory transcription factor, PacC, resulted in aflatoxin production under acidic and alkaline pH conditions whilst wildtype Aspergillus flavus produced aflatoxins only under acidic conditions. This conclusively proved that PacC negatively regulates aflatoxin production at alkaline pH in A. flavus. However the exact mechanism involved in PacC repression of aflatoxin biosynthesis at alkaline pH still remains unknown. The AflR protein is essential for expression of several genes in the aflatoxin biosynthetic cluster. In the current study, sequence analysis of the aflR promoter indicated the presence of two putative PacC binding sites within the aflR promoter of A. flavus 3357WT located at positions -162 and -487 bp from the start codon. The presence of the PacC binding sites in the aflR promoter indicated a possible link between aflR expression and PacC regulation under alkaline conditions. Thus, in this study, it was hypothesized that at alkaline pH, PacC inhibits aflR expression by binding to one or both of the PacC binding sites within the aflR promoter. This in turn, would result in inhibition of aflatoxin biosynthesis since expression of several aflatoxin biosynthetic pathway genes is dependent on activation by AflR. The aim and objective of this study was to test the validity of this hypothesis i.e. that at alkaline pH PacC binds to one or both of its recognition sites within the aflR promoter thereby inhibiting aflR expression which subsequently would result in inhibition of aflatoxin biosynthesis. This was done by first mutating each individual and then both PacC binding sites in the A. flavus 3357 aflR promoter via Single-Joint PCR (SJ-PCR) and fusing the wildtype and each mutated aflR promoter to the Green Fluorescent Protein (gfp) gene and the trpC terminator to yield a functional expression vector. These constructs were then transformed into A. flavus 3357.5. Positive transformants were confirmed to express GFP by fluorescence microscopy and spectrofluorometry. Quantification of GFP protein levels of the various transformants in this study indicated that PacC negatively regulated aflR promoter activity at alkaline pH. RT-qPCR was performed on positive transformants after growth on SLS medium at acidic and alkaline pH to determine if PacC negatively regulated aflR promoter activity at alkaline pH and to determine whether PacC binds preferentially to one or both recognition sites within the aflR promoter. RT-qPCR analysis suggest that PacC binds non-preferentially to both recognition sites within the aflR promoter on sucrose and lactose media at alkaline pH, although mutation of PacC binding site 2 results in a slightly higher expression compared to mutation of PacC binding site 1. Increasing the concentration of an aflatoxin conducive nitrogen source stimulated aflR promoter activity but this was not sufficient to overcome negative regulation by PacC. It is generally known that repression of aflR expression results in repression of aflatoxin biosynthesis irrespective of pH. The results of this study strongly suggest that PacC negatively regulates aflR promoter activity at alkaline pH by binding to one or both PacC recognition sites within the aflR promoter. Since aflR promoter activity is repressed by PacC at alkaline pH, this substantiates the hypothesis that PacC represses aflatoxin biosynthesis by inhibiting expression of aflR. Furthermore, the results of this study indicated that there may be some PacC protein present in the active form at acidic pH irrespective of the carbon source and nitrogen source used in the growth medium. RT-qPCR analysis indicated that any active PacC present at acidic pH may cause repression of the aflR promoter based on the position of the PacC binding site relative to the aflR start codon, although it appears that PacC may have a higher affinity for PacC binding site 2 (which is closer to the aflR start codon).
- Full Text:
- Date Issued: 2011
- Authors: Suleman, Essa
- Date: 2011
- Subjects: Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10336 , http://hdl.handle.net/10948/d1012683 , Mutation (Biology) , Genetic regulation , Proteins -- Synthesis , Microbiological synthesis
- Description: It is generally known that media containing simple sugars (sucrose, glucose) and organic nitrogen sources (ammonium) when buffered to acidic pH stimulates aflatoxin production in Aspergillus flavus & A. parasiticus while lactose, nitrate and an alkaline pH inhibit aflatoxin biosynthesis. It has been shown that pH of the growth medium is the most important regulatory factor for aflatoxin biosynthesis since media containing stimulatory carbon and/or nitrogen sources (sucrose and ammonia) do not enhance aflatoxin (or sterigmatocystin) production at alkaline pH. RNA interference (in A. flavus) of the pH regulatory transcription factor, PacC, resulted in aflatoxin production under acidic and alkaline pH conditions whilst wildtype Aspergillus flavus produced aflatoxins only under acidic conditions. This conclusively proved that PacC negatively regulates aflatoxin production at alkaline pH in A. flavus. However the exact mechanism involved in PacC repression of aflatoxin biosynthesis at alkaline pH still remains unknown. The AflR protein is essential for expression of several genes in the aflatoxin biosynthetic cluster. In the current study, sequence analysis of the aflR promoter indicated the presence of two putative PacC binding sites within the aflR promoter of A. flavus 3357WT located at positions -162 and -487 bp from the start codon. The presence of the PacC binding sites in the aflR promoter indicated a possible link between aflR expression and PacC regulation under alkaline conditions. Thus, in this study, it was hypothesized that at alkaline pH, PacC inhibits aflR expression by binding to one or both of the PacC binding sites within the aflR promoter. This in turn, would result in inhibition of aflatoxin biosynthesis since expression of several aflatoxin biosynthetic pathway genes is dependent on activation by AflR. The aim and objective of this study was to test the validity of this hypothesis i.e. that at alkaline pH PacC binds to one or both of its recognition sites within the aflR promoter thereby inhibiting aflR expression which subsequently would result in inhibition of aflatoxin biosynthesis. This was done by first mutating each individual and then both PacC binding sites in the A. flavus 3357 aflR promoter via Single-Joint PCR (SJ-PCR) and fusing the wildtype and each mutated aflR promoter to the Green Fluorescent Protein (gfp) gene and the trpC terminator to yield a functional expression vector. These constructs were then transformed into A. flavus 3357.5. Positive transformants were confirmed to express GFP by fluorescence microscopy and spectrofluorometry. Quantification of GFP protein levels of the various transformants in this study indicated that PacC negatively regulated aflR promoter activity at alkaline pH. RT-qPCR was performed on positive transformants after growth on SLS medium at acidic and alkaline pH to determine if PacC negatively regulated aflR promoter activity at alkaline pH and to determine whether PacC binds preferentially to one or both recognition sites within the aflR promoter. RT-qPCR analysis suggest that PacC binds non-preferentially to both recognition sites within the aflR promoter on sucrose and lactose media at alkaline pH, although mutation of PacC binding site 2 results in a slightly higher expression compared to mutation of PacC binding site 1. Increasing the concentration of an aflatoxin conducive nitrogen source stimulated aflR promoter activity but this was not sufficient to overcome negative regulation by PacC. It is generally known that repression of aflR expression results in repression of aflatoxin biosynthesis irrespective of pH. The results of this study strongly suggest that PacC negatively regulates aflR promoter activity at alkaline pH by binding to one or both PacC recognition sites within the aflR promoter. Since aflR promoter activity is repressed by PacC at alkaline pH, this substantiates the hypothesis that PacC represses aflatoxin biosynthesis by inhibiting expression of aflR. Furthermore, the results of this study indicated that there may be some PacC protein present in the active form at acidic pH irrespective of the carbon source and nitrogen source used in the growth medium. RT-qPCR analysis indicated that any active PacC present at acidic pH may cause repression of the aflR promoter based on the position of the PacC binding site relative to the aflR start codon, although it appears that PacC may have a higher affinity for PacC binding site 2 (which is closer to the aflR start codon).
- Full Text:
- Date Issued: 2011
Using social marketing to bridge the gap between systematic conservation planning and implementation at the local government level
- Authors: Wilhelm-Rechmann, Angelika
- Date: 2011
- Subjects: Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10603 , http://hdl.handle.net/10948/1550 , Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Description: The study presented here describes an attempt to bridge the gap between systematic conservation assessment and decision-making for land-use planning in the Eastern Cape province, South Africa. The aim was to investigate how to effectively convince officials concerned with land use planning processes in the local municipal sphere to include conservation priorities meaningfully in their processes. The approach used to reach this aim was social marketing, the use of marketing technologies and concepts to effect behavior changes to further societal good. So far social marketing is not commonly used in the conservation domain; I therefore aimed also at proving the usefulness of this approach for conservation. Following the introduction which provides background to the project and a more detailed summary, Chapter 2 provides a detailed and comprehensive review of the considerations and concepts regarding the use of social marketing in a context geared at protecting nature. The research on the primary target group for this study, officials concerned with land use planning processes in the local municipal sphere is described in Chapter 3. The main outcomes were that land use planners perceive few needs with regards to implementing the incorporation of biodiversity conservation issues in the land use planning process, and that the deficiencies in the land use planning process per se, as well as the lack of recognition in the political sphere (the domain of elected councilors), represent the core barriers to adopting the conservation priorities. I conclude that to effect behavior change towards adoption of conservation priorities the land use planning processes need to be supported and the political sphere need to be included in the behavior change process. 6 Chapter 4 therefore focuses on the new target group that emerged as essential in the previous chapter, locally elected councilors. I found that councilors do actually consider land use planning procedures as being important, but also as being dysfunctional. Councilors do value their natural environment for themselves as well as for its tourism value, but most councilors had little understanding of what the term “biodiversity” means and did not connect the term “sustainability” with the natural environment. It became also evident, that councilors do not see conservation in a predominantly positive manner. Chapter 5 therefore yields insight on councilor’s perception that environmental protection and development are mutually exclusive, and the negative frames attached to the conservation endeavor as being socially unjust, disrespectful and utopian. In Chapter 6 I investigated the usefulness of a tractable and well established measure of environmental attitudes or beliefs. I assessed my target audience’s responses to the New Ecological Paradigm scale and the Inclusion of Nature in Self scale. I conclude in Chapter 7 with an account of the difficulties I encountered during the project, an assessment of my project from a social marketing perspective, components of my project that did not yield the results expected, and a proposal for future research.
- Full Text:
- Date Issued: 2011
- Authors: Wilhelm-Rechmann, Angelika
- Date: 2011
- Subjects: Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10603 , http://hdl.handle.net/10948/1550 , Nature conservation -- South Africa -- Eastern Cape , Land use -- South Africa -- Eastern Cape
- Description: The study presented here describes an attempt to bridge the gap between systematic conservation assessment and decision-making for land-use planning in the Eastern Cape province, South Africa. The aim was to investigate how to effectively convince officials concerned with land use planning processes in the local municipal sphere to include conservation priorities meaningfully in their processes. The approach used to reach this aim was social marketing, the use of marketing technologies and concepts to effect behavior changes to further societal good. So far social marketing is not commonly used in the conservation domain; I therefore aimed also at proving the usefulness of this approach for conservation. Following the introduction which provides background to the project and a more detailed summary, Chapter 2 provides a detailed and comprehensive review of the considerations and concepts regarding the use of social marketing in a context geared at protecting nature. The research on the primary target group for this study, officials concerned with land use planning processes in the local municipal sphere is described in Chapter 3. The main outcomes were that land use planners perceive few needs with regards to implementing the incorporation of biodiversity conservation issues in the land use planning process, and that the deficiencies in the land use planning process per se, as well as the lack of recognition in the political sphere (the domain of elected councilors), represent the core barriers to adopting the conservation priorities. I conclude that to effect behavior change towards adoption of conservation priorities the land use planning processes need to be supported and the political sphere need to be included in the behavior change process. 6 Chapter 4 therefore focuses on the new target group that emerged as essential in the previous chapter, locally elected councilors. I found that councilors do actually consider land use planning procedures as being important, but also as being dysfunctional. Councilors do value their natural environment for themselves as well as for its tourism value, but most councilors had little understanding of what the term “biodiversity” means and did not connect the term “sustainability” with the natural environment. It became also evident, that councilors do not see conservation in a predominantly positive manner. Chapter 5 therefore yields insight on councilor’s perception that environmental protection and development are mutually exclusive, and the negative frames attached to the conservation endeavor as being socially unjust, disrespectful and utopian. In Chapter 6 I investigated the usefulness of a tractable and well established measure of environmental attitudes or beliefs. I assessed my target audience’s responses to the New Ecological Paradigm scale and the Inclusion of Nature in Self scale. I conclude in Chapter 7 with an account of the difficulties I encountered during the project, an assessment of my project from a social marketing perspective, components of my project that did not yield the results expected, and a proposal for future research.
- Full Text:
- Date Issued: 2011
Time series models for paired comparisons
- Authors: Sjolander, Morne Rowan
- Date: 2011
- Subjects: Paired comparisons (Statistics)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10577 , http://hdl.handle.net/10948/d1012858
- Description: The method of paired comparisons is seen as a technique used to rank a set of objects with respect to an abstract or immeasurable property. To do this, the objects get to be compared two at a time. The results are input into a model, resulting in numbers known as weights being assigned to the objects. The weights are then used to rank the objects. The method of paired comparisons was first used for psychometric investigations. Various other applications of the method are also present, for example economic applications, and applications in sports statistics. This study involves taking paired comparison models and making them time-dependent. Not much research has been done in this area. Three new time series models for paired comparisons are created. Simulations are done to support the evidence obtained, and theoretical as well as practical examples are given to illustrate the results and to verify the efficiency of the new models. A literature study is given on the method of paired comparisons, as well as on the areas in which we apply our models. Our first two time series models for paired comparisons are the Linear-Trend Bradley- Terry Model and the Sinusoidal Bradley-Terry Model. We use the maximum likelihood approach to solve these models. We test our models using exact and randomly simulated data for various time periods and various numbers of objects. We adapt the Linear-Trend Bradley-Terry Model and received our third time series model for paired comparisons, the Log Linear-Trend Bradley-Terry Model. The daily maximum and minimum temperatures were received for Port Elizabeth, Uitenhage and Coega for 2005 until 2009. To evaluate the performance of the Linear-Trend Bradley-Terry Model and the Sinusoidal Bradley-Terry Model on estimating missing temperature data, we artificially remove observations of temperature from Coega’s temperature dataset for 2006 until 2008, and use various forms of these models to estimate the missing data points. The exchange rates for 2005 until 2008 between the following currencies: the Rand, Dollar, Euro, Pound and Yen, were obtained and various forms of our Log Linear-Trend Bradley-Terry Model are used to forecast the exchange rate for one day ahead for each month in 2006 until 2008. One of the features of this study is that we apply our time series models for paired comparisons to areas which comprise non-standard paired comparisons; and we want to encourage the use of the method of paired comparisons in a broader sense than what it is traditionally used for. The results of this study can be used in various other areas, like for example, in sports statistics, to rank the strength of sports players and predict their future scores; in Physics, to calculate weather risks of electricity generation, particularly risks related to nuclear power plants, and so forth, as well as in many other areas. It is hoped that this research will open the door to much more research in combining time series analysis with the method of paired comparisons.
- Full Text:
- Date Issued: 2011
- Authors: Sjolander, Morne Rowan
- Date: 2011
- Subjects: Paired comparisons (Statistics)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10577 , http://hdl.handle.net/10948/d1012858
- Description: The method of paired comparisons is seen as a technique used to rank a set of objects with respect to an abstract or immeasurable property. To do this, the objects get to be compared two at a time. The results are input into a model, resulting in numbers known as weights being assigned to the objects. The weights are then used to rank the objects. The method of paired comparisons was first used for psychometric investigations. Various other applications of the method are also present, for example economic applications, and applications in sports statistics. This study involves taking paired comparison models and making them time-dependent. Not much research has been done in this area. Three new time series models for paired comparisons are created. Simulations are done to support the evidence obtained, and theoretical as well as practical examples are given to illustrate the results and to verify the efficiency of the new models. A literature study is given on the method of paired comparisons, as well as on the areas in which we apply our models. Our first two time series models for paired comparisons are the Linear-Trend Bradley- Terry Model and the Sinusoidal Bradley-Terry Model. We use the maximum likelihood approach to solve these models. We test our models using exact and randomly simulated data for various time periods and various numbers of objects. We adapt the Linear-Trend Bradley-Terry Model and received our third time series model for paired comparisons, the Log Linear-Trend Bradley-Terry Model. The daily maximum and minimum temperatures were received for Port Elizabeth, Uitenhage and Coega for 2005 until 2009. To evaluate the performance of the Linear-Trend Bradley-Terry Model and the Sinusoidal Bradley-Terry Model on estimating missing temperature data, we artificially remove observations of temperature from Coega’s temperature dataset for 2006 until 2008, and use various forms of these models to estimate the missing data points. The exchange rates for 2005 until 2008 between the following currencies: the Rand, Dollar, Euro, Pound and Yen, were obtained and various forms of our Log Linear-Trend Bradley-Terry Model are used to forecast the exchange rate for one day ahead for each month in 2006 until 2008. One of the features of this study is that we apply our time series models for paired comparisons to areas which comprise non-standard paired comparisons; and we want to encourage the use of the method of paired comparisons in a broader sense than what it is traditionally used for. The results of this study can be used in various other areas, like for example, in sports statistics, to rank the strength of sports players and predict their future scores; in Physics, to calculate weather risks of electricity generation, particularly risks related to nuclear power plants, and so forth, as well as in many other areas. It is hoped that this research will open the door to much more research in combining time series analysis with the method of paired comparisons.
- Full Text:
- Date Issued: 2011
Development of MgZnO-grown MOCVD for UV Photonic applications
- Authors: Talla, Kharouna
- Date: 2011
- Subjects: Photoluminescence , Photonics , Zinc oxide
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10537 , http://hdl.handle.net/10948/d1012585 , Photoluminescence , Photonics , Zinc oxide
- Description: MgxZn1-xO has emerged as a material of great technological importance. Having a direct energy band gap that is tunable throughout much of the ultraviolet (UV) region of the spectrum from the near-UV (~370 nm) to the deep-UV (~176 nm), this compound is of interest for a variety of optoelectronic devices operating in this part of the electromagnetic spectrum. MgxZn1-xO offers advantages over the more mature compound semiconductor AlGaN which stem mainly from the unusually high exciton binding energy (60 meV in ZnO). In this study the growth of ZnO and MgxZn1-xO thin films using metal organic chemical vapour deposition (MOCVD) is systematically investigated. The films are mainly grown on c-Al2O3 and Si (100) and characterized using various techniques, such as photoluminescence (PL), x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and auger electron spectroscopy (AES). The optical and the structural properties are essentially inspected in order to improve their quality. In this thesis the optimisation of ZnO grown using oxygen gas as a new oxidant in our reactor is investigated. The growth temperature and VI/II ratio are varied in order to find optimum parameters giving high quality layers. The effects of Si (100), Si (111), c- and r-sapphire, glass, GaAs and ZnO substrates on the optical, structural and morphological properties of ZnO thin films grown with tert-butanol (TBOH) is examined. Similar morphologies are observed for all substrates, with the films comprising hexagonal columns having cone shaped ends. The photoluminescence spectra are similar, but the various transitions have different relative intensities. It is clear that the different substrates influence neither the orientation of the films, nor the surface morphology, significantly. The photoluminescence hints at larger stacking fault densities in films grown on silicon and glass, however, as evidenced by stronger basal plane stacking fault-related luminescence at ~3.319 eV in the relevant low temperature photoluminescence spectra. The morphology changes with Mg incorporation, from hexagonal columnar structures to cubic faceted columns. From PL, the full with at half maximum is found to gradually increase with Mg content due to alloy broadening. The deep level emission (DLE) is observed to shift with Mg content. By changing the Mg content, the band gap of MgxZn1-xO film is tuned by ~450 meV, which provides an excellent opportunity for band gap engineering for optoelectronic applications. The c-lattice constant of ZnO (5.205 Å) decreases by only 0.6% when the Mg content reaches x=0.39. The introduction of Mg into ZnO is shown to increase the relative PL intensity of stacking fault-related transitions (at 3.314 eV for ZnO). This becomes the dominant near band edge emission. Using TEM a thin Mg rich layer is observed at the interface between the film and the Si or Al2O3. Temperature dependent PL measurements on layers with low Mg concentration (x=0.05 and 0.1) show that the main bound exciton peak exhibits an “s-shaped” temperature dependence, characteristic of localization in a disordered alloy. The origin of the PL line broadening of MgxZn1-xO (x≤0.04) is also analyzed with respect to alloy broadening, taking into account a random cation distribution and alloy clustering. The influence of various MOCVD growth parameters such as growth temperature and VI/II ratio is studied. Varying the temperature from 280 ˚C to 580 ˚C reveals strong morphological changes and optical degradation of the films. Low (<280 ˚C) and high (>580 ˚C) growth temperatures reduce the Mg incorporation. High VI/II ratios also decrease the Mg incorporation, as evidenced by the red-shift of the donor bound exciton (D°X) line. This is ascribed to a stronger premature reaction between (MeCp)2Mg and the oxidant or a preferential heterogeneous interaction between the Mg and oxygen species on the growth front. For both oxidizing agents (O2 and TBOH), the growth at 420 ˚C and a VI-II ratio of 60 on c-Al2O3 gave optimal quality layers in terms of their optical and structural quality. A comparison of films grown using TBOH and O2 gas as oxidizing agent shows no major difference in terms of Mg incorporation. The effect of annealing, the inclusion of a buffer layer and the influence of growth rate on the properties MgxZn1-xO thin films are also reported.
- Full Text:
- Date Issued: 2011
- Authors: Talla, Kharouna
- Date: 2011
- Subjects: Photoluminescence , Photonics , Zinc oxide
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10537 , http://hdl.handle.net/10948/d1012585 , Photoluminescence , Photonics , Zinc oxide
- Description: MgxZn1-xO has emerged as a material of great technological importance. Having a direct energy band gap that is tunable throughout much of the ultraviolet (UV) region of the spectrum from the near-UV (~370 nm) to the deep-UV (~176 nm), this compound is of interest for a variety of optoelectronic devices operating in this part of the electromagnetic spectrum. MgxZn1-xO offers advantages over the more mature compound semiconductor AlGaN which stem mainly from the unusually high exciton binding energy (60 meV in ZnO). In this study the growth of ZnO and MgxZn1-xO thin films using metal organic chemical vapour deposition (MOCVD) is systematically investigated. The films are mainly grown on c-Al2O3 and Si (100) and characterized using various techniques, such as photoluminescence (PL), x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and auger electron spectroscopy (AES). The optical and the structural properties are essentially inspected in order to improve their quality. In this thesis the optimisation of ZnO grown using oxygen gas as a new oxidant in our reactor is investigated. The growth temperature and VI/II ratio are varied in order to find optimum parameters giving high quality layers. The effects of Si (100), Si (111), c- and r-sapphire, glass, GaAs and ZnO substrates on the optical, structural and morphological properties of ZnO thin films grown with tert-butanol (TBOH) is examined. Similar morphologies are observed for all substrates, with the films comprising hexagonal columns having cone shaped ends. The photoluminescence spectra are similar, but the various transitions have different relative intensities. It is clear that the different substrates influence neither the orientation of the films, nor the surface morphology, significantly. The photoluminescence hints at larger stacking fault densities in films grown on silicon and glass, however, as evidenced by stronger basal plane stacking fault-related luminescence at ~3.319 eV in the relevant low temperature photoluminescence spectra. The morphology changes with Mg incorporation, from hexagonal columnar structures to cubic faceted columns. From PL, the full with at half maximum is found to gradually increase with Mg content due to alloy broadening. The deep level emission (DLE) is observed to shift with Mg content. By changing the Mg content, the band gap of MgxZn1-xO film is tuned by ~450 meV, which provides an excellent opportunity for band gap engineering for optoelectronic applications. The c-lattice constant of ZnO (5.205 Å) decreases by only 0.6% when the Mg content reaches x=0.39. The introduction of Mg into ZnO is shown to increase the relative PL intensity of stacking fault-related transitions (at 3.314 eV for ZnO). This becomes the dominant near band edge emission. Using TEM a thin Mg rich layer is observed at the interface between the film and the Si or Al2O3. Temperature dependent PL measurements on layers with low Mg concentration (x=0.05 and 0.1) show that the main bound exciton peak exhibits an “s-shaped” temperature dependence, characteristic of localization in a disordered alloy. The origin of the PL line broadening of MgxZn1-xO (x≤0.04) is also analyzed with respect to alloy broadening, taking into account a random cation distribution and alloy clustering. The influence of various MOCVD growth parameters such as growth temperature and VI/II ratio is studied. Varying the temperature from 280 ˚C to 580 ˚C reveals strong morphological changes and optical degradation of the films. Low (<280 ˚C) and high (>580 ˚C) growth temperatures reduce the Mg incorporation. High VI/II ratios also decrease the Mg incorporation, as evidenced by the red-shift of the donor bound exciton (D°X) line. This is ascribed to a stronger premature reaction between (MeCp)2Mg and the oxidant or a preferential heterogeneous interaction between the Mg and oxygen species on the growth front. For both oxidizing agents (O2 and TBOH), the growth at 420 ˚C and a VI-II ratio of 60 on c-Al2O3 gave optimal quality layers in terms of their optical and structural quality. A comparison of films grown using TBOH and O2 gas as oxidizing agent shows no major difference in terms of Mg incorporation. The effect of annealing, the inclusion of a buffer layer and the influence of growth rate on the properties MgxZn1-xO thin films are also reported.
- Full Text:
- Date Issued: 2011
Repulsive-attractive models for the impact of two predators on prey species varying in anti-predator response
- Authors: Ddumba, Hassan
- Date: 2011
- Subjects: Predation (Biology) -- Mathematical models , Wildlife management -- Mathematical models , Pattern formation (Biology) , Predatory animals -- Ecology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10506 , http://hdl.handle.net/10948/d1010995 , Predation (Biology) -- Mathematical models , Wildlife management -- Mathematical models , Pattern formation (Biology) , Predatory animals -- Ecology
- Description: This study considers the dynamical interaction of two predatory carnivores (Lions (Panthera leo) and Spotted Hyaenas (Crocuta crocuta)) and three of their common prey (Buffalo (Syncerus caffer), Warthog (Phacochoerus africanus) and Kudu (Tragelaphus strepsiceros)). The dependence on spatial structure of species’ interaction stimulated the author to formulate reaction-diffusion models to explain the dynamics of predator-prey relationships in ecology. These models were used to predict and explain the effect of threshold populations, predator additional food and prey refuge on the general species’ dynamics. Vital parameters that model additional food to predators, prey refuge and population thresholds were given due attention in the analyses. The stability of a predator-prey model for an ecosystem faced with a prey out-flux which is analogous to and modelled as an Allee effect was investigated. The results highlight the bounds for the conversion efficiency of prey biomass to predator biomass (fertility gain) for which stability of the three species ecosystem model can be attained. Global stability analysis results showed that the prey (warthog) population density should exceed the sum of its carrying capacity and threshold value minus its equilibrium value i.e., W >(Kw + $) −W . This result shows that the warthog’s equilibrium population density is bounded above by population thresholds, i.e., W < (Kw+$). Besides showing the occurrence under parameter space of the so-called paradox of enrichment, early indicators of chaos can also be deduced. In addition, numerical results revealed stable oscillatory behaviour and stable spirals of the species as predator fertility rate, mortality rate and prey threshold were varied. The stabilising effect of prey refuge due to variations in predator fertility and proportion of prey in the refuge was studied. Formulation and analysis of a robust mathematical model for two predators having an overlapping dietary niche were also done. The Beddington-DeAngelis functional and numerical responses which are relevant in addressing the Principle of Competitive Exclusion as species interact were incorporated in the model. The stabilizing effect of additional food in relation to the relative diffusivity D, and wave number k, was investigated. Stability, dissipativity, permanence, persistence and periodicity of the model were studied using the routine and limit cycle perturbation methods. The periodic solutions (b 1 and b 3), which influence the dispersal rate (') of the interacting species, have been shown to be controlled by the wave number. For stability, and in order to overcome predator natural mortality, the nutritional value of predator additional food has been shown to be of high quality that can enhance predator fertility gain. The threshold relationships between various ecosystem parameters and the carrying capacity of the game park for the prey species were also deduced to ensure ecosystem persistence. Besides revealing irregular periodic travelling wave behaviour due to predator interference, numerical results also show oscillatory temporal dynamics resulting from additional food supplements combined with high predation rates.
- Full Text:
- Date Issued: 2011
- Authors: Ddumba, Hassan
- Date: 2011
- Subjects: Predation (Biology) -- Mathematical models , Wildlife management -- Mathematical models , Pattern formation (Biology) , Predatory animals -- Ecology
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10506 , http://hdl.handle.net/10948/d1010995 , Predation (Biology) -- Mathematical models , Wildlife management -- Mathematical models , Pattern formation (Biology) , Predatory animals -- Ecology
- Description: This study considers the dynamical interaction of two predatory carnivores (Lions (Panthera leo) and Spotted Hyaenas (Crocuta crocuta)) and three of their common prey (Buffalo (Syncerus caffer), Warthog (Phacochoerus africanus) and Kudu (Tragelaphus strepsiceros)). The dependence on spatial structure of species’ interaction stimulated the author to formulate reaction-diffusion models to explain the dynamics of predator-prey relationships in ecology. These models were used to predict and explain the effect of threshold populations, predator additional food and prey refuge on the general species’ dynamics. Vital parameters that model additional food to predators, prey refuge and population thresholds were given due attention in the analyses. The stability of a predator-prey model for an ecosystem faced with a prey out-flux which is analogous to and modelled as an Allee effect was investigated. The results highlight the bounds for the conversion efficiency of prey biomass to predator biomass (fertility gain) for which stability of the three species ecosystem model can be attained. Global stability analysis results showed that the prey (warthog) population density should exceed the sum of its carrying capacity and threshold value minus its equilibrium value i.e., W >(Kw + $) −W . This result shows that the warthog’s equilibrium population density is bounded above by population thresholds, i.e., W < (Kw+$). Besides showing the occurrence under parameter space of the so-called paradox of enrichment, early indicators of chaos can also be deduced. In addition, numerical results revealed stable oscillatory behaviour and stable spirals of the species as predator fertility rate, mortality rate and prey threshold were varied. The stabilising effect of prey refuge due to variations in predator fertility and proportion of prey in the refuge was studied. Formulation and analysis of a robust mathematical model for two predators having an overlapping dietary niche were also done. The Beddington-DeAngelis functional and numerical responses which are relevant in addressing the Principle of Competitive Exclusion as species interact were incorporated in the model. The stabilizing effect of additional food in relation to the relative diffusivity D, and wave number k, was investigated. Stability, dissipativity, permanence, persistence and periodicity of the model were studied using the routine and limit cycle perturbation methods. The periodic solutions (b 1 and b 3), which influence the dispersal rate (') of the interacting species, have been shown to be controlled by the wave number. For stability, and in order to overcome predator natural mortality, the nutritional value of predator additional food has been shown to be of high quality that can enhance predator fertility gain. The threshold relationships between various ecosystem parameters and the carrying capacity of the game park for the prey species were also deduced to ensure ecosystem persistence. Besides revealing irregular periodic travelling wave behaviour due to predator interference, numerical results also show oscillatory temporal dynamics resulting from additional food supplements combined with high predation rates.
- Full Text:
- Date Issued: 2011
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