Two issues, two groups:
- Authors: du Toit, Jeanne
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159299 , vital:40285 , https://hdl.handle.net/10520/EJC144677
- Description: One of the conference strategies that I found particularly valuable was that of the "syndicate teams" who met regularly to speak on focused topics. Delegates signed up for the topic they were interested in and stayed with that group for the duration of the conference. The list included topics such as the status of journalism education in the academy; the role of journalism in changing the media; adapting journalism education to a digital age, etc.
- Full Text:
- Date Issued: 2007
- Authors: du Toit, Jeanne
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159299 , vital:40285 , https://hdl.handle.net/10520/EJC144677
- Description: One of the conference strategies that I found particularly valuable was that of the "syndicate teams" who met regularly to speak on focused topics. Delegates signed up for the topic they were interested in and stayed with that group for the duration of the conference. The list included topics such as the status of journalism education in the academy; the role of journalism in changing the media; adapting journalism education to a digital age, etc.
- Full Text:
- Date Issued: 2007
Photophysical and photochemical studies of long chain-substituted zinc phthalocyanines
- Durmus, Mahmut, Ahsen, Vefa, Nyokong, Tebello
- Authors: Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281310 , vital:55711 , xlink:href="https://doi.org/10.1016/j.jphotochem.2006.08.025"
- Description: Photochemical and photophysical measurements were conducted on peripheral and non-peripheral tetra(13,17-dioxanonacosane-15-hydroxy)-substituted zinc phthalocyanines (1, 2). General trends are described for quantum yields of photodegradation, fluorescence yields, triplet lifetimes and triplet quantum yields as well as singlet quantum yields of these compounds in dimethylformamide (DMF) and toluene. The effects of the solvents on the photophysical and photochemical parameters of the zinc(II) phthalocyanines (1, 2) are reported.
- Full Text:
- Date Issued: 2007
- Authors: Durmus, Mahmut , Ahsen, Vefa , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281310 , vital:55711 , xlink:href="https://doi.org/10.1016/j.jphotochem.2006.08.025"
- Description: Photochemical and photophysical measurements were conducted on peripheral and non-peripheral tetra(13,17-dioxanonacosane-15-hydroxy)-substituted zinc phthalocyanines (1, 2). General trends are described for quantum yields of photodegradation, fluorescence yields, triplet lifetimes and triplet quantum yields as well as singlet quantum yields of these compounds in dimethylformamide (DMF) and toluene. The effects of the solvents on the photophysical and photochemical parameters of the zinc(II) phthalocyanines (1, 2) are reported.
- Full Text:
- Date Issued: 2007
Synthesis and solvent effects on the electronic absorption and fluorescence spectral properties of substituted zinc phthalocyanines
- Durmus, Mahmut, Nyokong, Tebello
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293279 , vital:57071 , xlink:href="https://doi.org/10.1016/j.poly.2007.01.018"
- Description: The synthesis and spectroscopic properties of the following tetra- and octa-substituted aryloxy zinc(II) phthalocyanines are reported for the first time: 1,(4)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (7); 2,(3)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (8); 2,3-(octabenzyloxyphenoxyphthalocyaninato) zinc(II) (9). The new compounds have been characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. Spectroscopic properties of these compounds were investigated in different solvents. Protonation of non-peripherally substituted complex 7 resulted in the splitting and red-shifting of the Q-band. The peripherally substituted derivatives 8 and 9, did not show the split in the Q-band. Fluorescence spectra of the derivatives show Stokes shifts typical of MPc complexes.
- Full Text:
- Date Issued: 2007
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293279 , vital:57071 , xlink:href="https://doi.org/10.1016/j.poly.2007.01.018"
- Description: The synthesis and spectroscopic properties of the following tetra- and octa-substituted aryloxy zinc(II) phthalocyanines are reported for the first time: 1,(4)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (7); 2,(3)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (8); 2,3-(octabenzyloxyphenoxyphthalocyaninato) zinc(II) (9). The new compounds have been characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. Spectroscopic properties of these compounds were investigated in different solvents. Protonation of non-peripherally substituted complex 7 resulted in the splitting and red-shifting of the Q-band. The peripherally substituted derivatives 8 and 9, did not show the split in the Q-band. Fluorescence spectra of the derivatives show Stokes shifts typical of MPc complexes.
- Full Text:
- Date Issued: 2007
The synthesis, fluorescence behaviour and singlet oxygen studies of new water-soluble cationic gallium (III) phthalocyanines
- Durmus, Mahmut, Nyokong, Tebello
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/280207 , vital:55586 , xlink:href="https://doi.org/10.1016/j.inoche.2006.11.012"
- Description: The preparation of cationic water-soluble gallium phthalocyanine derivatives are described for the first time. Peripheral and non-peripheral 3-hydroxypyridine tetrasubstituted gallium(III)phthalocyanines (5a, 6a) and their quaternarized derivatives (5b and 6b) have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy, electronic spectroscopy and mass spectra. The quaternarized compounds (5b and 6b) are soluble in water and not aggregated (in water and in organic solvents) within a wide concentration range. General trends are described for singlet oxygen quantum yields, fluorescence quantum yields and fluorescence lifetimes of these compounds. These complexes showed better singlet oxygen quantum yields in water than the related quarternarized porphyrazine complexes.
- Full Text:
- Date Issued: 2007
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/280207 , vital:55586 , xlink:href="https://doi.org/10.1016/j.inoche.2006.11.012"
- Description: The preparation of cationic water-soluble gallium phthalocyanine derivatives are described for the first time. Peripheral and non-peripheral 3-hydroxypyridine tetrasubstituted gallium(III)phthalocyanines (5a, 6a) and their quaternarized derivatives (5b and 6b) have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy, electronic spectroscopy and mass spectra. The quaternarized compounds (5b and 6b) are soluble in water and not aggregated (in water and in organic solvents) within a wide concentration range. General trends are described for singlet oxygen quantum yields, fluorescence quantum yields and fluorescence lifetimes of these compounds. These complexes showed better singlet oxygen quantum yields in water than the related quarternarized porphyrazine complexes.
- Full Text:
- Date Issued: 2007
Synthesis and solvent effects on the electronic absorption and fluorescence spectral properties of substituted zinc phthalocyanines
- Durmus, Mahmut, Nyokong, Tebello
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283140 , vital:55914 , xlink:href="https://doi.org/10.1016/j.poly.2007.01.018"
- Description: The synthesis and spectroscopic properties of the following tetra- and octa-substituted aryloxy zinc(II) phthalocyanines are reported for the first time: 1,(4)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (7); 2,(3)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (8); 2,3-(octabenzyloxyphenoxyphthalocyaninato) zinc(II) (9). The new compounds have been characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. Spectroscopic properties of these compounds were investigated in different solvents. Protonation of non-peripherally substituted complex 7 resulted in the splitting and red-shifting of the Q-band. The peripherally substituted derivatives 8 and 9, did not show the split in the Q-band. Fluorescence spectra of the derivatives show Stokes shifts typical of MPc complexes.
- Full Text:
- Date Issued: 2007
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283140 , vital:55914 , xlink:href="https://doi.org/10.1016/j.poly.2007.01.018"
- Description: The synthesis and spectroscopic properties of the following tetra- and octa-substituted aryloxy zinc(II) phthalocyanines are reported for the first time: 1,(4)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (7); 2,(3)-(tetrabenzyloxyphenoxyphthalocyaninato) zinc(II) (8); 2,3-(octabenzyloxyphenoxyphthalocyaninato) zinc(II) (9). The new compounds have been characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. Spectroscopic properties of these compounds were investigated in different solvents. Protonation of non-peripherally substituted complex 7 resulted in the splitting and red-shifting of the Q-band. The peripherally substituted derivatives 8 and 9, did not show the split in the Q-band. Fluorescence spectra of the derivatives show Stokes shifts typical of MPc complexes.
- Full Text:
- Date Issued: 2007
Synthesis, photophysical and photochemical properties of aryloxy tetra-substituted gallium and indium phthalocyanine derivatives
- Durmus, Mahmut, Nyokong, Tebello
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281431 , vital:55724 , xlink:href="https://doi.org/10.1016/j.tet.2006.11.089"
- Description: The synthesis, photophysical and photochemical properties of the tetra-substituted aryloxy gallium(III) and indium(III) phthalocyanines are reported for the first time. General trends are described for photodegradation, singlet oxygen, fluorescence, and triplet quantum yields and triplet lifetimes of these compounds. The introduction of phenoxy and tert-butylphenoxy substituents on the ring resulted in lowering of fluorescence quantum yields and lifetimes, and triplet quantum yields, and an increase of kIC, kISC, and kF. Photoreduction of the complexes was observed during laser flash photolysis. The singlet oxygen quantum yields (ΦΔ), which give an indication of the potential of the complexes as photosensitizers in applications where singlet oxygen is required (Type II mechanism) ranged from 0.41 to 0.91. Thus, these complexes show potential as Type II photosensitizers.
- Full Text:
- Date Issued: 2007
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281431 , vital:55724 , xlink:href="https://doi.org/10.1016/j.tet.2006.11.089"
- Description: The synthesis, photophysical and photochemical properties of the tetra-substituted aryloxy gallium(III) and indium(III) phthalocyanines are reported for the first time. General trends are described for photodegradation, singlet oxygen, fluorescence, and triplet quantum yields and triplet lifetimes of these compounds. The introduction of phenoxy and tert-butylphenoxy substituents on the ring resulted in lowering of fluorescence quantum yields and lifetimes, and triplet quantum yields, and an increase of kIC, kISC, and kF. Photoreduction of the complexes was observed during laser flash photolysis. The singlet oxygen quantum yields (ΦΔ), which give an indication of the potential of the complexes as photosensitizers in applications where singlet oxygen is required (Type II mechanism) ranged from 0.41 to 0.91. Thus, these complexes show potential as Type II photosensitizers.
- Full Text:
- Date Issued: 2007
Synthesis, photophysical and photochemical studies of new water-soluble indium (III) phthalocyanines
- Durmus, Mahmut, Nyokong, Tebello
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283976 , vital:56007 , xlink:href="https://doi.org/10.1039/b618478b"
- Description: The preparation of water-soluble indium(III)phthalocyanine complexes is described for the first time in this study. Peripherally and non-peripherally 3-hydroxypyridine tetrasubstituted indium(III) phthalocyanines (5a, 6a) and their quaternarized derivatives (5b, 6b) have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy, electronic spectroscopy and mass spectra. The quaternarized compounds (5b, 6b) show excellent solubility in water, which makes them potential photosensitizers for use in photodynamic therapy (PDT) applications. Photochemical and photophysical measurements were conducted on 3-pyridyloxy appended indium(III) phthalocyanines in dimethylsulfoxide (DMSO) for non-ionic (5b, 6b) derivatives. General trends are described for quantum yields of photodegradation, fluorescence lifetimes, fluorescence quantum yields, triplet lifetimes and triplet quantum yields as well as singlet oxygen quantum yields of these compounds. The singlet oxygen quantum yields (ΦΔ), which give an indication of the potential of the complexes as photosensitizers in applications where singlet oxygen is required (Type II mechanism) are very high (ΦΔ > 0.55). Thus, these complexes may be useful as Type II photosensitizers.
- Full Text:
- Date Issued: 2007
Synthesis, photophysical and photochemical studies of new water-soluble indium (III) phthalocyanines
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/283976 , vital:56007 , xlink:href="https://doi.org/10.1039/b618478b"
- Description: The preparation of water-soluble indium(III)phthalocyanine complexes is described for the first time in this study. Peripherally and non-peripherally 3-hydroxypyridine tetrasubstituted indium(III) phthalocyanines (5a, 6a) and their quaternarized derivatives (5b, 6b) have been synthesized and characterized by elemental analysis, IR, 1H NMR spectroscopy, electronic spectroscopy and mass spectra. The quaternarized compounds (5b, 6b) show excellent solubility in water, which makes them potential photosensitizers for use in photodynamic therapy (PDT) applications. Photochemical and photophysical measurements were conducted on 3-pyridyloxy appended indium(III) phthalocyanines in dimethylsulfoxide (DMSO) for non-ionic (5b, 6b) derivatives. General trends are described for quantum yields of photodegradation, fluorescence lifetimes, fluorescence quantum yields, triplet lifetimes and triplet quantum yields as well as singlet oxygen quantum yields of these compounds. The singlet oxygen quantum yields (ΦΔ), which give an indication of the potential of the complexes as photosensitizers in applications where singlet oxygen is required (Type II mechanism) are very high (ΦΔ > 0.55). Thus, these complexes may be useful as Type II photosensitizers.
- Full Text:
- Date Issued: 2007
Synthesis, photophysical and photochemical properties of tetra-and octa-substituted gallium and indium phthalocyanines
- Durmus, Mahmut, Nyokong, Tebello
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271276 , vital:54529 , xlink:href="https://doi.org/10.1016/j.poly.2007.03.007"
- Description: The synthesis, photophysical and photochemical properties of the tetra- and octa-[4-(benzyloxyphenoxy)] substituted gallium(III) and indium(III) phthalocyanines are reported for the first time. The new compounds have been characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. General trends are described for quantum yields of photodegredation, fluorescence quantum yields and lifetimes, triplet lifetimes and triplet quantum yields as well as singlet oxygen quantum yields of these compounds in dimethylsulfoxide (DMSO). Substituted indium phthalocyanine complexes (7b–9b) showed much higher quantum yields of triplet state and shorter triplet lifetimes, compared to the substituted GaPc derivatives due to enhanced intersystem crossing (ISC) in the former. The gallium and indium phthalocyanine complexes showed phototransformation during laser irradiation due to ring reduction. The singlet oxygen quantum yields (ΦΔ), which give an indication of the potential of the complexes as photosensitizers in applications where singlet oxygen is required (Type II mechanism) ranged from 0.51 to 0.94. Thus, these complexes show potential as photodynamic therapy of cancer.
- Full Text:
- Date Issued: 2007
- Authors: Durmus, Mahmut , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271276 , vital:54529 , xlink:href="https://doi.org/10.1016/j.poly.2007.03.007"
- Description: The synthesis, photophysical and photochemical properties of the tetra- and octa-[4-(benzyloxyphenoxy)] substituted gallium(III) and indium(III) phthalocyanines are reported for the first time. The new compounds have been characterized by elemental analysis, IR, 1H NMR spectroscopy and electronic spectroscopy. General trends are described for quantum yields of photodegredation, fluorescence quantum yields and lifetimes, triplet lifetimes and triplet quantum yields as well as singlet oxygen quantum yields of these compounds in dimethylsulfoxide (DMSO). Substituted indium phthalocyanine complexes (7b–9b) showed much higher quantum yields of triplet state and shorter triplet lifetimes, compared to the substituted GaPc derivatives due to enhanced intersystem crossing (ISC) in the former. The gallium and indium phthalocyanine complexes showed phototransformation during laser irradiation due to ring reduction. The singlet oxygen quantum yields (ΦΔ), which give an indication of the potential of the complexes as photosensitizers in applications where singlet oxygen is required (Type II mechanism) ranged from 0.51 to 0.94. Thus, these complexes show potential as photodynamic therapy of cancer.
- Full Text:
- Date Issued: 2007
Critical assessment of the quartz crystal microbalance with dissipation as an analytical tool for biosensor development and fundamental studies
- Fogel, Ronen, Mashazi, Philani N, Nyokong, Tebello, Limson, Janice
- Authors: Fogel, Ronen , Mashazi, Philani N , Nyokong, Tebello , Limson, Janice
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271204 , vital:54521 , xlink:href="https://doi.org/10.1016/j.bios.2007.03.012"
- Description: One of the challenges in electrochemical biosensor design is gaining a fundamental knowledge of the processes underlying immobilisation of the molecules onto the electrode surface. This is of particular importance in biocomposite sensors where concerns have arisen as to the nature of the interaction between the biological and synthetic molecules immobilised. We examined the use of the Quartz Crystal Microbalance with Dissipation (QCM-D) as a tool for fundamental analyses of a model sensor constructed by the immobilisation of cobalt(II) phthalocyanine (TCACoPc) and glucose oxidase (GOx) onto a gold-quartz electrode (electrode surface) for the enhanced detection of glucose. The model sensor was constructed in aqueous phase and covalently linked the gold surface to the TCACoPc, and the TCACoPc to the GOx, using the QCM-D. The aqueous metallophthalocyanine (MPc) formed a multi-layer over the surface of the electrode, which could be removed to leave a monolayer with a mass loading that compared favourably to the theoretical value expected. Analysis of frequency and dissipation plots indicated covalent attachment of glucose oxidase onto the metallophthalocyanine layer. The amount of GOx bound using the model system compared favourably to calculations derived from the maximal amperometric functioning of the electrochemical sensor (examined in previously-published literature, Mashazi, P.N., Ozoemena, K.I., Nyokong, T., 2006. Electrochim. Acta 52, 177–186), but not to theoretical values derived from dimensions of GOx as established by crystallography. The strength of the binding of the GOx film with the TCACoPc layer was tested by using 2% SDS as a denaturant/surfactant, and the GOx film was not found to be significantly affected by exposure to this. This paper thus showed that QCM-D can be used in order to model essential processes and interactions that dictate the functional parameters of a biosensor.
- Full Text:
- Date Issued: 2007
- Authors: Fogel, Ronen , Mashazi, Philani N , Nyokong, Tebello , Limson, Janice
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271204 , vital:54521 , xlink:href="https://doi.org/10.1016/j.bios.2007.03.012"
- Description: One of the challenges in electrochemical biosensor design is gaining a fundamental knowledge of the processes underlying immobilisation of the molecules onto the electrode surface. This is of particular importance in biocomposite sensors where concerns have arisen as to the nature of the interaction between the biological and synthetic molecules immobilised. We examined the use of the Quartz Crystal Microbalance with Dissipation (QCM-D) as a tool for fundamental analyses of a model sensor constructed by the immobilisation of cobalt(II) phthalocyanine (TCACoPc) and glucose oxidase (GOx) onto a gold-quartz electrode (electrode surface) for the enhanced detection of glucose. The model sensor was constructed in aqueous phase and covalently linked the gold surface to the TCACoPc, and the TCACoPc to the GOx, using the QCM-D. The aqueous metallophthalocyanine (MPc) formed a multi-layer over the surface of the electrode, which could be removed to leave a monolayer with a mass loading that compared favourably to the theoretical value expected. Analysis of frequency and dissipation plots indicated covalent attachment of glucose oxidase onto the metallophthalocyanine layer. The amount of GOx bound using the model system compared favourably to calculations derived from the maximal amperometric functioning of the electrochemical sensor (examined in previously-published literature, Mashazi, P.N., Ozoemena, K.I., Nyokong, T., 2006. Electrochim. Acta 52, 177–186), but not to theoretical values derived from dimensions of GOx as established by crystallography. The strength of the binding of the GOx film with the TCACoPc layer was tested by using 2% SDS as a denaturant/surfactant, and the GOx film was not found to be significantly affected by exposure to this. This paper thus showed that QCM-D can be used in order to model essential processes and interactions that dictate the functional parameters of a biosensor.
- Full Text:
- Date Issued: 2007
Intermediating Africa:
- Authors: Garman, Anthea
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158806 , vital:40230 , https://hdl.handle.net/10520/EJC144693
- Description: In July, Vanity Fair, based in New York, did a unique special edition. Editor Graydon Carter explained how it came about: "Earlier this year, Mark Dowley, a marketing polymath at the Endeavour talent agency who has been involved with Bono's (Red) campaign from the start, called to inquire if I would be interested in having him guest edit an issue of the magazine. Interested? I'll say!".
- Full Text:
- Date Issued: 2007
- Authors: Garman, Anthea
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158806 , vital:40230 , https://hdl.handle.net/10520/EJC144693
- Description: In July, Vanity Fair, based in New York, did a unique special edition. Editor Graydon Carter explained how it came about: "Earlier this year, Mark Dowley, a marketing polymath at the Endeavour talent agency who has been involved with Bono's (Red) campaign from the start, called to inquire if I would be interested in having him guest edit an issue of the magazine. Interested? I'll say!".
- Full Text:
- Date Issued: 2007
Antjie Krog and the accumulation of ‘media meta‐capital’:
- Authors: Garman, Anthea
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159713 , vital:40336 , DOI: 10.1080/1013929X.2007.9678272
- Description: While Krog's significant body of work in poetry, prose and journalism is undoubtedly central in her trajectory towards international renown, in this essay I explore the dynamics of her “meteoric rise in status”. The news media's role in mediating Krog to the world for nearly 40 years becomes crucial to this investigation. I use a mix of media theory and field theory to illuminate the multi‐faceted and complex relationship Krog has had with the news media and I argue that her acquisition of ‘media meta‐capital’ has played a significant role in her attainment of a unique voice and speaking platform in a postapartheid, public domain in which few white voices, and especially Afrikaner ones, are being heard.
- Full Text:
- Date Issued: 2007
- Authors: Garman, Anthea
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159713 , vital:40336 , DOI: 10.1080/1013929X.2007.9678272
- Description: While Krog's significant body of work in poetry, prose and journalism is undoubtedly central in her trajectory towards international renown, in this essay I explore the dynamics of her “meteoric rise in status”. The news media's role in mediating Krog to the world for nearly 40 years becomes crucial to this investigation. I use a mix of media theory and field theory to illuminate the multi‐faceted and complex relationship Krog has had with the news media and I argue that her acquisition of ‘media meta‐capital’ has played a significant role in her attainment of a unique voice and speaking platform in a postapartheid, public domain in which few white voices, and especially Afrikaner ones, are being heard.
- Full Text:
- Date Issued: 2007
Lazarus in the Constitutional Court: an exhumation of the exceptio doli generalis
- Authors: Glover, Graham B
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70678 , vital:29688 , https://hdl.handle.net/10520/EJC53775
- Description: A landmark moment in the history of South African contract law was the emphatic interment of the exceptio doli generalis by Joubert JA in Bank of Lisbon and South Africa v De Ornelas 1988 (3) SA580 (A). Throughout most of the twentieth century, the exceptio doli generalis had been viewed as an equitable defence that allowed a defendant to resist a claim for performance under a contract when there was something unconscionable about the plaintiff's seeking to enforce the contract (or a clause thereof) in the specific circumstances of that case (see A J Kerr Principles of the Law of Contract 6 ed (2002) 637ff; P J Aronstam 'Unconscionable contracts: The South African solution?' (1979) 42 THRHR 21; P van Warmelo 'Exceptio doli' 1981 De Jure 202).
- Full Text: false
- Date Issued: 2007
- Authors: Glover, Graham B
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70678 , vital:29688 , https://hdl.handle.net/10520/EJC53775
- Description: A landmark moment in the history of South African contract law was the emphatic interment of the exceptio doli generalis by Joubert JA in Bank of Lisbon and South Africa v De Ornelas 1988 (3) SA580 (A). Throughout most of the twentieth century, the exceptio doli generalis had been viewed as an equitable defence that allowed a defendant to resist a claim for performance under a contract when there was something unconscionable about the plaintiff's seeking to enforce the contract (or a clause thereof) in the specific circumstances of that case (see A J Kerr Principles of the Law of Contract 6 ed (2002) 637ff; P J Aronstam 'Unconscionable contracts: The South African solution?' (1979) 42 THRHR 21; P van Warmelo 'Exceptio doli' 1981 De Jure 202).
- Full Text: false
- Date Issued: 2007
Marx, Weber and NGOs:
- Authors: Helliker, Kirk D
- Date: 2012
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144738 , vital:38375 , DOI: 10.1080/21528586.2007.10419171
- Description: This article offers a sociological understanding of intermediary NGOs in the modern world. In does so by drawing on certain epistemological insights of Marx and Weber, and this entails methodologies of both deconstruction and reconstruction. In arguing against a sociological behaviourism that pervades the NGO literature, the article conceptualises intermediary NGOs as a ‘social form’ embodying contradictory relations. For analytical purposes, the contradiction between ‘the global’ and ‘the local’ is brought to the fore.
- Full Text:
- Date Issued: 2012
- Authors: Helliker, Kirk D
- Date: 2012
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144738 , vital:38375 , DOI: 10.1080/21528586.2007.10419171
- Description: This article offers a sociological understanding of intermediary NGOs in the modern world. In does so by drawing on certain epistemological insights of Marx and Weber, and this entails methodologies of both deconstruction and reconstruction. In arguing against a sociological behaviourism that pervades the NGO literature, the article conceptualises intermediary NGOs as a ‘social form’ embodying contradictory relations. For analytical purposes, the contradiction between ‘the global’ and ‘the local’ is brought to the fore.
- Full Text:
- Date Issued: 2012
South African marxist state theory: a critical overview
- Authors: Helliker, Kirk D
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144778 , vital:38378 , DOI: 10.1080/02589348808704885
- Description: The article provides a critical analysis of Marxist work on the South African state. It first examines the early Poulantzian‐State Derivationist debate on the relation between state and society, and then discusses the ‘new directions’ which focus on the state itself. The sensitivity of the ‘new directions’ to the traditional Weberian concern about state bureaucracy is important for enriching Marxist theory. But the article concludes by suggesting that a comprehensive dialectical Marxist approach to the South African state still awaits development.
- Full Text:
- Date Issued: 2007
- Authors: Helliker, Kirk D
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/144778 , vital:38378 , DOI: 10.1080/02589348808704885
- Description: The article provides a critical analysis of Marxist work on the South African state. It first examines the early Poulantzian‐State Derivationist debate on the relation between state and society, and then discusses the ‘new directions’ which focus on the state itself. The sensitivity of the ‘new directions’ to the traditional Weberian concern about state bureaucracy is important for enriching Marxist theory. But the article concludes by suggesting that a comprehensive dialectical Marxist approach to the South African state still awaits development.
- Full Text:
- Date Issued: 2007
Cognitive pharmaceutical services and the community pharmacist: are South African patients receiving them and are they willing to pay?
- Hill, Peter W, Dowse, Roslind
- Authors: Hill, Peter W , Dowse, Roslind
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156829 , vital:40054 , DOI 10.1211/ijpp.15.2.0007
- Description: The objectives of this study were to ascertain the opinions of randomly selected South African medical aid members regarding the provision by community pharmacists of patient counselling and information; member satisfaction with pharmacist services; their rating of pharmacist accessibility; and if pharmacists should be reimbursed for providing cognitive pharmaceutical services. Setting A South African private healthcare insurance company.
- Full Text:
- Date Issued: 2006
- Authors: Hill, Peter W , Dowse, Roslind
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/156829 , vital:40054 , DOI 10.1211/ijpp.15.2.0007
- Description: The objectives of this study were to ascertain the opinions of randomly selected South African medical aid members regarding the provision by community pharmacists of patient counselling and information; member satisfaction with pharmacist services; their rating of pharmacist accessibility; and if pharmacists should be reimbursed for providing cognitive pharmaceutical services. Setting A South African private healthcare insurance company.
- Full Text:
- Date Issued: 2006
Does 'African mathematics' facilitate access to mathematics?: towards an ongoing critical analysis of ethnomathematics in a South African context
- Horsthemke, Kai, Schäfer, Marc
- Authors: Horsthemke, Kai , Schäfer, Marc
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141004 , vital:37936 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC20885
- Description: Mosibudi Mangena, the Minister of Science and Technology, said in an address to the Annual Congress of the South African Mathematical Society at the University of the Potchefstroom, November 2, 2004: "There is one thing we need to address before anything else. We need to increase the number of young people, particularly blacks and women, who are able to successfully complete the first course in Mathematics at our universities." How is this to be achieved? A popular trend involves a call for the introduction and incorporation of so-called ethnomathematics, and more particularly 'African mathematics', into secondary and tertiary curricula. Although acknowledging the obvious benefits of so-called ethnomathematics, this paper critically analyses three aspects of ethnomathematics that have been neglected in past critiques. Our focus is not on the relationship as such between ethnomathematics and mathematics education. Our critique involves (1) epistemological and logical misgivings, (2) a new look at practices and skills, (3) concerns about embracing 'African mathematics' as valid and valuable - just because it is African.
- Full Text:
- Date Issued: 2007
- Authors: Horsthemke, Kai , Schäfer, Marc
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141004 , vital:37936 , https://0-hdl.handle.net.wam.seals.ac.za/10520/EJC20885
- Description: Mosibudi Mangena, the Minister of Science and Technology, said in an address to the Annual Congress of the South African Mathematical Society at the University of the Potchefstroom, November 2, 2004: "There is one thing we need to address before anything else. We need to increase the number of young people, particularly blacks and women, who are able to successfully complete the first course in Mathematics at our universities." How is this to be achieved? A popular trend involves a call for the introduction and incorporation of so-called ethnomathematics, and more particularly 'African mathematics', into secondary and tertiary curricula. Although acknowledging the obvious benefits of so-called ethnomathematics, this paper critically analyses three aspects of ethnomathematics that have been neglected in past critiques. Our focus is not on the relationship as such between ethnomathematics and mathematics education. Our critique involves (1) epistemological and logical misgivings, (2) a new look at practices and skills, (3) concerns about embracing 'African mathematics' as valid and valuable - just because it is African.
- Full Text:
- Date Issued: 2007
Excited state dynamics of zinc and aluminum phthalocyanine carboxylates
- Idowu, Mopelola, Ogunsipe, Abimbola, Nyokong, Tebello
- Authors: Idowu, Mopelola , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271228 , vital:54523 , xlink:href="https://doi.org/10.1016/j.saa.2007.01.025"
- Description: Photophysical parameters for zinc and aluminium tetracarboxylphthalocyanines (ZnTCPc and AlTCPc, respectively) and their octacarboxy substituted counterparts (ZnOCPc and AlOCPc) were studied. Data for the fluorescence quenching of the complexes by benzoquinone (BQ) were treated using the Stern–Volmer analysis, and the quenching was found to follow a diffusion-controlled (dynamic) bimolecular mechanism. Theoretical values of bimolecular rate constant for complex-BQ interactions were determined using the Stokes–Einstein–Smoluchowski model; and the values, together with the Stern–Volmer quenching constants were used in calculating the fluorescence lifetimes of the complexes. The thermodynamics of the MPc-BQ interaction, in terms of solvent reorientation energy is also discussed.
- Full Text:
- Date Issued: 2007
- Authors: Idowu, Mopelola , Ogunsipe, Abimbola , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/271228 , vital:54523 , xlink:href="https://doi.org/10.1016/j.saa.2007.01.025"
- Description: Photophysical parameters for zinc and aluminium tetracarboxylphthalocyanines (ZnTCPc and AlTCPc, respectively) and their octacarboxy substituted counterparts (ZnOCPc and AlOCPc) were studied. Data for the fluorescence quenching of the complexes by benzoquinone (BQ) were treated using the Stern–Volmer analysis, and the quenching was found to follow a diffusion-controlled (dynamic) bimolecular mechanism. Theoretical values of bimolecular rate constant for complex-BQ interactions were determined using the Stokes–Einstein–Smoluchowski model; and the values, together with the Stern–Volmer quenching constants were used in calculating the fluorescence lifetimes of the complexes. The thermodynamics of the MPc-BQ interaction, in terms of solvent reorientation energy is also discussed.
- Full Text:
- Date Issued: 2007
Photophysical and photochemical properties of zinc and aluminum phthalocyanines in the presence of magnetic fluid
- Idowu, Mopelola, Nyokong, Tebello
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281298 , vital:55710 , xlink:href="https://doi.org/10.1016/j.jphotochem.2006.12.013"
- Description: The effect of magnetic fluid (MF) on the photophysical and photochemical parameters of zinc and aluminum phthalocyanines are reported. The complexes studied are zinc (II) phthalocyanine (ZnPc), chloroaluminum phthalocyanine ((Cl)AlPc) and tetrasulfonated aluminum phthalocyanine ((Cl)AlTSPc). The parameters are studied in dimethylsulfoxide (DMSO) for all complexes and also in aqueous media for (Cl)AlTSPc. The triplet lifetimes for (Cl)AlTSPc and ZnPc decreased while the triplet quantum yields increased in the presence of MF. For (Cl)AlPc, the triplet lifetimes were found to increase with decrease in laser energy while there was photoreduction to the Pc−3 species. Singlet oxygen and photodegradation quantum yields decreased in the presence of MF, suggesting quenching.
- Full Text:
- Date Issued: 2007
- Authors: Idowu, Mopelola , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281298 , vital:55710 , xlink:href="https://doi.org/10.1016/j.jphotochem.2006.12.013"
- Description: The effect of magnetic fluid (MF) on the photophysical and photochemical parameters of zinc and aluminum phthalocyanines are reported. The complexes studied are zinc (II) phthalocyanine (ZnPc), chloroaluminum phthalocyanine ((Cl)AlPc) and tetrasulfonated aluminum phthalocyanine ((Cl)AlTSPc). The parameters are studied in dimethylsulfoxide (DMSO) for all complexes and also in aqueous media for (Cl)AlTSPc. The triplet lifetimes for (Cl)AlTSPc and ZnPc decreased while the triplet quantum yields increased in the presence of MF. For (Cl)AlPc, the triplet lifetimes were found to increase with decrease in laser energy while there was photoreduction to the Pc−3 species. Singlet oxygen and photodegradation quantum yields decreased in the presence of MF, suggesting quenching.
- Full Text:
- Date Issued: 2007
Identity in the Siyagruva Series of novels: Toward an intercultural
- Authors: Kaschula, Russell H
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175159 , vital:42548 , DOI: 10.4314/tvl.v44i2.29792
- Description: This article explores the notion of changing South African youth identity and how it is depicted in the Siyagruva [We are Grooving] Series of novels for young adults. The article highlights the need for a broadening of literary theory in order to include an appropriate theoretical approach for new South African youth literature. This theory explores intercultural literary discourse by making use of, for example, the work of intercultural theorists such as Ting-Toomey (1999), Gudykunst (2003) and others. It is argued that this form of literary discourse is now appropriate as a theoretical paradigm within multilingual South Africa where intercultural communication is becoming a reality. There is also reference to intracultural communication where differences are beginning to appear between young people who are perceived to come from the same cultural group, for example, the character Brunette in the Siyagruva Series who is perceived as a “coconut” by her friends, and thus finds herself having to justify her belonging within a particular in-group or culture. The article concentrates on selected novels, though reference is made to many of the twenty three published novels in the Siyagruva Series, twenty in English, and three translated into isiXhosa.
- Full Text:
- Date Issued: 2007
- Authors: Kaschula, Russell H
- Date: 2007
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175159 , vital:42548 , DOI: 10.4314/tvl.v44i2.29792
- Description: This article explores the notion of changing South African youth identity and how it is depicted in the Siyagruva [We are Grooving] Series of novels for young adults. The article highlights the need for a broadening of literary theory in order to include an appropriate theoretical approach for new South African youth literature. This theory explores intercultural literary discourse by making use of, for example, the work of intercultural theorists such as Ting-Toomey (1999), Gudykunst (2003) and others. It is argued that this form of literary discourse is now appropriate as a theoretical paradigm within multilingual South Africa where intercultural communication is becoming a reality. There is also reference to intracultural communication where differences are beginning to appear between young people who are perceived to come from the same cultural group, for example, the character Brunette in the Siyagruva Series who is perceived as a “coconut” by her friends, and thus finds herself having to justify her belonging within a particular in-group or culture. The article concentrates on selected novels, though reference is made to many of the twenty three published novels in the Siyagruva Series, twenty in English, and three translated into isiXhosa.
- Full Text:
- Date Issued: 2007
Microwave synthesis and photophysics of new tetrasulfonated tin (II) macrocycles
- Khene, Samson, Ogunsipe, Abimbola, Antunes, Edith M, Nyokong, Tebello
- Authors: Khene, Samson , Ogunsipe, Abimbola , Antunes, Edith M , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281269 , vital:55708 , xlink:href="https://doi.org/10.1142/S108842460700014X"
- Description: This work reports on the microwave synthesis of tetrasulfonated tin phthalocyanine and tetrasulfonated tin α,β,γ-tetrabenzcorrole. The latter was only formed at low ratios (more than 1:8) of 4-sulfophthalic acid to urea. Both complexes are aggregated in aqueous media, but can be partly or fully disaggregated by the addition of Triton X-100. The α,β,γ-tetrabenzcorrole complex has lower triplet life times and yields, while the binding constant and quenching (of bovine serum albumin) constant are lower for α,β,γ-tetrabenzcorrole compared to tetrasulfonated tin phthalocyanine.
- Full Text:
- Date Issued: 2007
- Authors: Khene, Samson , Ogunsipe, Abimbola , Antunes, Edith M , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281269 , vital:55708 , xlink:href="https://doi.org/10.1142/S108842460700014X"
- Description: This work reports on the microwave synthesis of tetrasulfonated tin phthalocyanine and tetrasulfonated tin α,β,γ-tetrabenzcorrole. The latter was only formed at low ratios (more than 1:8) of 4-sulfophthalic acid to urea. Both complexes are aggregated in aqueous media, but can be partly or fully disaggregated by the addition of Triton X-100. The α,β,γ-tetrabenzcorrole complex has lower triplet life times and yields, while the binding constant and quenching (of bovine serum albumin) constant are lower for α,β,γ-tetrabenzcorrole compared to tetrasulfonated tin phthalocyanine.
- Full Text:
- Date Issued: 2007