Synthesis and anti-parasitic activity of C-benzylated (N-arylcarbamoyl) alkylphosphonate esters
- Adeyemi, Christiana Modupe, Isaacs, Michelle, Mnkandhla, Dumisani, Krause, Rui W M, Klein, Rosalyn, Hoppe, Heinrich C, Lobb, Kevin A, Kaye, Perry T
- Authors: Adeyemi, Christiana Modupe , Isaacs, Michelle , Mnkandhla, Dumisani , Krause, Rui W M , Klein, Rosalyn , Hoppe, Heinrich C , Lobb, Kevin A , Kaye, Perry T
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125641 , vital:35803 , https://doi.org/10.1016/j.tet.2017.01.045
- Description: Unexpected substituent-dependent regioselectivty challenges in the synthesis of C-benzylated (N-arylcarbamoyl)phosphonate esters have been resolved. The C-benzylated N-furfurylcarbamoyl derivative showed low micromolar PfLDH inhibition, while one of the C-benzylated N-arylcarbamoyl analogues was active against Nagana Trypanosoma brucei parasites which are responsible for African trypanosomiasis in cattle.
- Full Text:
- Date Issued: 2017
- Authors: Adeyemi, Christiana Modupe , Isaacs, Michelle , Mnkandhla, Dumisani , Krause, Rui W M , Klein, Rosalyn , Hoppe, Heinrich C , Lobb, Kevin A , Kaye, Perry T
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/125641 , vital:35803 , https://doi.org/10.1016/j.tet.2017.01.045
- Description: Unexpected substituent-dependent regioselectivty challenges in the synthesis of C-benzylated (N-arylcarbamoyl)phosphonate esters have been resolved. The C-benzylated N-furfurylcarbamoyl derivative showed low micromolar PfLDH inhibition, while one of the C-benzylated N-arylcarbamoyl analogues was active against Nagana Trypanosoma brucei parasites which are responsible for African trypanosomiasis in cattle.
- Full Text:
- Date Issued: 2017
Musical expressivity in choral singing
- Authors: Agenbag, Gustel
- Date: 2017
- Subjects: Choral singing , Choirs (Music) , Music -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: http://hdl.handle.net/10948/13614 , vital:27257
- Description: This qualitative mini-treatise explores Musical expressivity in choral singing with reference to three High School choirs in the Port Elizabeth area. Singing with emotions is not only a facial expression of some sort. There are so many more aspects which could be applied in order for the choral performance to be of an outstanding nature and not merely a performance. The researcher questioned the possibility of introducing expressiveness into rehearsals and performance through the application of more expressive conducting techniques, more detailed musical aspects and a general sense of unity within the group. The choral conductor plays a primary role and should therefore be considered as the most important link between choir and excellence. Focus is put on specific warm up exercises and suggestions are put forward regarding the development of your own, personalized exercises which suits your own unique setup. Data was collected through open-ended interviewees of the three school choir conductors as well as data from current and past studies on various topics. The perceptions of these conductors were noted and the manner in which they apply Musical knowledge during their rehearsals. Research findings indicate that not enough emphasis is put on expressive singing during rehearsals. More research done by the conductors and attending workshops are recommended for personal growth and development.
- Full Text:
- Date Issued: 2017
- Authors: Agenbag, Gustel
- Date: 2017
- Subjects: Choral singing , Choirs (Music) , Music -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MMus
- Identifier: http://hdl.handle.net/10948/13614 , vital:27257
- Description: This qualitative mini-treatise explores Musical expressivity in choral singing with reference to three High School choirs in the Port Elizabeth area. Singing with emotions is not only a facial expression of some sort. There are so many more aspects which could be applied in order for the choral performance to be of an outstanding nature and not merely a performance. The researcher questioned the possibility of introducing expressiveness into rehearsals and performance through the application of more expressive conducting techniques, more detailed musical aspects and a general sense of unity within the group. The choral conductor plays a primary role and should therefore be considered as the most important link between choir and excellence. Focus is put on specific warm up exercises and suggestions are put forward regarding the development of your own, personalized exercises which suits your own unique setup. Data was collected through open-ended interviewees of the three school choir conductors as well as data from current and past studies on various topics. The perceptions of these conductors were noted and the manner in which they apply Musical knowledge during their rehearsals. Research findings indicate that not enough emphasis is put on expressive singing during rehearsals. More research done by the conductors and attending workshops are recommended for personal growth and development.
- Full Text:
- Date Issued: 2017
Evaluation of the physicochemical qualities and heavy metal regimes of the final effluents of some wastewater treatment facilties in Berlin, Alice and Bedford communities in the Eastern Cape, South Africa
- Authors: Agoro, Mojeed Adedoyin
- Date: 2017
- Subjects: Water -- Purification -- South Africa -- Eastern Cape Sewage -- Purification -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5003 , vital:28924
- Description: Wastewater treatment facilities have been identified as potential source of surface water pollution worldwide. In this study, the physicochemical qualities and heavy metal (including Zinc, Cadmium, Iron, Lead and Copper) concentrations in the final effluents, as well as the reduction efficiencies of three municipal wastewater plants in the Eastern Cape, South Africa were evaluated from September 2015 to February 2016 using standard methods. Wastewater effluent and sludge samples were collected from the selected plants on monthly basis over a period of six months from September 2015 to February 2016. Standard analytical method (Atomic absorption spectroscopy [AAS]) was used to assess the concentration levels of heavy metals. The physicochemical parameters assessed include pH, Temperature, Total Dissolved Solid, Turbidity, Biochemical Oxygen Demand, Chemical Oxygen Demand, Alkalinity, Dissolved Oxygen, Free chlorine, Chloride, Sulphate, Phosphate, Ammonium and Electrical Conductivity. The results of the evaluation showed that temperature ranges from 19 to 36 °C, Electrical Conductivity from 60-1095 mS/m, Alkalinity from 2.6-20.9 mg/L, Nitrate from 0.24-26.5 mg/L, Nitrite from 0.01-90 mg/L, Phosphate from 0.02-5.12 mg/L, Ammonium from 0.06-112 mg/L, Sulphate from 3-72 mg/L, Chloride from 3.25-224 mg/L, Chemical Oxygen Demand from 17-394 mg/L and Turbidity from 1.96-715 NTU. Free chlorine concentrations and dissolved oxygen were within the recommended limits for most part of the sampling period and ranged between 0.17-0.48 mg/L and 0.19-21.9 mg/L respectively. The pH, Phosphate, Sulphate and Free chlorine were within acceptable limits while Electrical Conductivity, Temperature, Total Dissolved Solid, Turbidity, Chemical Oxygen Demand, Chloride, Ammonium, Nitrate and Nitrite were not within specified limits. The reduction efficiencies observed generally ranged between 43.9 and 100 percent at all sampling points while zinc and lead were not detected throughout the sampling period. Cadmium showed low reduction rate ranging from 0 to 11.7 percent, while the rate of Copper reduction ranged from 0 to25 percent in January and February 2016. Zinc, lead and cadmium were generally not detected in the sludge samples except in January and February which could be due to the prevailing atmospheric conditions during the sampling period. Cu and Fe were detected through the sampling months of the study. We conclude that these municipal sewage plants are sources of pollution to their receiving watersheds and threats to public and environmental health.
- Full Text:
- Date Issued: 2017
- Authors: Agoro, Mojeed Adedoyin
- Date: 2017
- Subjects: Water -- Purification -- South Africa -- Eastern Cape Sewage -- Purification -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10353/5003 , vital:28924
- Description: Wastewater treatment facilities have been identified as potential source of surface water pollution worldwide. In this study, the physicochemical qualities and heavy metal (including Zinc, Cadmium, Iron, Lead and Copper) concentrations in the final effluents, as well as the reduction efficiencies of three municipal wastewater plants in the Eastern Cape, South Africa were evaluated from September 2015 to February 2016 using standard methods. Wastewater effluent and sludge samples were collected from the selected plants on monthly basis over a period of six months from September 2015 to February 2016. Standard analytical method (Atomic absorption spectroscopy [AAS]) was used to assess the concentration levels of heavy metals. The physicochemical parameters assessed include pH, Temperature, Total Dissolved Solid, Turbidity, Biochemical Oxygen Demand, Chemical Oxygen Demand, Alkalinity, Dissolved Oxygen, Free chlorine, Chloride, Sulphate, Phosphate, Ammonium and Electrical Conductivity. The results of the evaluation showed that temperature ranges from 19 to 36 °C, Electrical Conductivity from 60-1095 mS/m, Alkalinity from 2.6-20.9 mg/L, Nitrate from 0.24-26.5 mg/L, Nitrite from 0.01-90 mg/L, Phosphate from 0.02-5.12 mg/L, Ammonium from 0.06-112 mg/L, Sulphate from 3-72 mg/L, Chloride from 3.25-224 mg/L, Chemical Oxygen Demand from 17-394 mg/L and Turbidity from 1.96-715 NTU. Free chlorine concentrations and dissolved oxygen were within the recommended limits for most part of the sampling period and ranged between 0.17-0.48 mg/L and 0.19-21.9 mg/L respectively. The pH, Phosphate, Sulphate and Free chlorine were within acceptable limits while Electrical Conductivity, Temperature, Total Dissolved Solid, Turbidity, Chemical Oxygen Demand, Chloride, Ammonium, Nitrate and Nitrite were not within specified limits. The reduction efficiencies observed generally ranged between 43.9 and 100 percent at all sampling points while zinc and lead were not detected throughout the sampling period. Cadmium showed low reduction rate ranging from 0 to 11.7 percent, while the rate of Copper reduction ranged from 0 to25 percent in January and February 2016. Zinc, lead and cadmium were generally not detected in the sludge samples except in January and February which could be due to the prevailing atmospheric conditions during the sampling period. Cu and Fe were detected through the sampling months of the study. We conclude that these municipal sewage plants are sources of pollution to their receiving watersheds and threats to public and environmental health.
- Full Text:
- Date Issued: 2017
Perceptions and livelihood uses of an invasive alien tree (acacia dealbata) by rural communities in the Eastern Cape
- Authors: Agripa, Ngorima
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/5326 , vital:20813
- Description: The negative impacts which invasive alien species have on ecosystems are well documented but there is paucity of information on their impacts on rural communities. Due to ecological impacts that may be associated with Acacia dealbata invasions the Agricultural Research Council Plant Protection Institute is considering releasing a biocontrol agent for A. dealbata. The actual social impacts of A. dealbata invasion and control are likely to be related to its importance in rural livelihoods. This thesis reports on the perceptions and livelihood uses of A. dealbata in the Eastern Cape. Three study sites were assessed, Matatiele, Mount Fletcher and Maclear. The study involved 150 household surveys, one focus group discussion and one transect walk at each site, key informant interviews and frequent house visits to acquire reliable data. Results show that 100 % of households in the three sites use Silver Wattle extensively for firewood. In Matatiele 64 %, 72 % in Mount Fletcher and 84 % of households in Maclear use Silver Wattle for fencing. To carve tools 76 % in Matatiele, 76 % in Mount Fletcher and 84 % households in Maclear use Silver Wattle. For medicinal purposes 18 % in Matatiele, 20 % in Mount Fletcher and 16 % in Maclear use Silver Wattle, whilst 78 % in Matatiele, 80 % in Mount Fletcher and 80 % in Maclear use it for fodder purposes. Many respondents felt that Silver Wattle is too abundant within their areas such that it now has many negative impacts associated with it. Perceptions of local people towards A. dealbata are neither static nor uniform, but are influenced by time since the invasion and now abundance of the species. There are no alternatives which provide the same services provided by Silver Wattle. Benefits and constraints due to A. dealbata invasion are experienced by everyone irrespective of wealth and gender. In conclusion, Silver Wattle is a valuable resource to these rural communities, but increasing abundance is incurring high costs to grazing resources and landscape accessibility.
- Full Text:
- Date Issued: 2017
- Authors: Agripa, Ngorima
- Date: 2017
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/5326 , vital:20813
- Description: The negative impacts which invasive alien species have on ecosystems are well documented but there is paucity of information on their impacts on rural communities. Due to ecological impacts that may be associated with Acacia dealbata invasions the Agricultural Research Council Plant Protection Institute is considering releasing a biocontrol agent for A. dealbata. The actual social impacts of A. dealbata invasion and control are likely to be related to its importance in rural livelihoods. This thesis reports on the perceptions and livelihood uses of A. dealbata in the Eastern Cape. Three study sites were assessed, Matatiele, Mount Fletcher and Maclear. The study involved 150 household surveys, one focus group discussion and one transect walk at each site, key informant interviews and frequent house visits to acquire reliable data. Results show that 100 % of households in the three sites use Silver Wattle extensively for firewood. In Matatiele 64 %, 72 % in Mount Fletcher and 84 % of households in Maclear use Silver Wattle for fencing. To carve tools 76 % in Matatiele, 76 % in Mount Fletcher and 84 % households in Maclear use Silver Wattle. For medicinal purposes 18 % in Matatiele, 20 % in Mount Fletcher and 16 % in Maclear use Silver Wattle, whilst 78 % in Matatiele, 80 % in Mount Fletcher and 80 % in Maclear use it for fodder purposes. Many respondents felt that Silver Wattle is too abundant within their areas such that it now has many negative impacts associated with it. Perceptions of local people towards A. dealbata are neither static nor uniform, but are influenced by time since the invasion and now abundance of the species. There are no alternatives which provide the same services provided by Silver Wattle. Benefits and constraints due to A. dealbata invasion are experienced by everyone irrespective of wealth and gender. In conclusion, Silver Wattle is a valuable resource to these rural communities, but increasing abundance is incurring high costs to grazing resources and landscape accessibility.
- Full Text:
- Date Issued: 2017
A best-practice guideline for facilitating adherence to anti-retroviral therapy for persons attending public hospitals in Ghana
- Authors: Agyeman-Yeboah, Joana
- Date: 2017
- Subjects: HIV infections -- Treatment -- Ghana , Health services administration -- Ghana Public health -- Ghana Hospital care -- Ghana
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/13603 , vital:27256
- Description: The retention of persons on an HIV programme has been a global challenge. The success of any strategy to optimize adherence to anti-retroviral therapy (ART) depends on the intensive and effective adherence counselling and strategies. It is important to research whether persons receiving anti-retroviral therapy in public hospitals in Ghana are receiving the needed service that would optimize their adherence to the anti-retroviral therapy. Therefore, this study explored and described the experiences of healthcare professionals providing care, support and guidance to persons on ART at public hospitals in Ghana, as well as the best-practice guideline that could contribute to facilitating the ART adherence of patients. This study also explored and described the experiences of persons living with Human Immunodeficiency Virus/Acquired Immunodeficiency Syndrome (HIV/AIDS) on ART, regarding their adherence to the therapy. The study was organized into three phases. In Phase One: a qualitative, exploratory, descriptive and contextual design was employed. The research population included healthcare professionals, providing services at the HIV clinic at the public hospitals in Ghana, namely the Korle-Bu Teaching Hospital; the 37 Military Hospital and the Ridge Hospital. The healthcare professionals comprised of doctors, nurses, pharmacists and trained counsellors employed in any of the three public hospitals. Persons receiving ART at any of the three public hospitals were also part of the research population. Semi-structured interviews were conducted with healthcare professionals and persons receiving ART. Data were collected from healthcare professionals in relation to their experiences regarding the provision of ART services, their understanding of evidence-based practice and best-practice guidelines, as well as data on the experiences of persons receiving ART in relation to their adherence to the therapy. The data were analysed using Creswell’s six steps of data analysis; and the coding of the data was done according to Tesch’s eight steps of coding. Trustworthiness was ensured by using Lincoln and Guba’s framework which comprised credibility, transferability, dependability, confirmability and authenticity. Ethical principles such as beneficence and non-maleficence, respect for human dignity, justice, veracity, privacy and confidentiality were considered in the study. In phase two, the literature was searched by using an integrative literature review approach and critically appraising the methodological quality of the guidelines in order to identify the best available evidence related to adherence to ART. In Phase Three, a best-practice guideline for facilitating adherence to ART was developed for public hospitals in Ghana based on the findings of the empirical research of Phase One and the integrative literature review in Phase Two. The guideline was submitted to an expert panel for review; and it was modified, according to the recommendations of the panel.
- Full Text:
- Date Issued: 2017
- Authors: Agyeman-Yeboah, Joana
- Date: 2017
- Subjects: HIV infections -- Treatment -- Ghana , Health services administration -- Ghana Public health -- Ghana Hospital care -- Ghana
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/13603 , vital:27256
- Description: The retention of persons on an HIV programme has been a global challenge. The success of any strategy to optimize adherence to anti-retroviral therapy (ART) depends on the intensive and effective adherence counselling and strategies. It is important to research whether persons receiving anti-retroviral therapy in public hospitals in Ghana are receiving the needed service that would optimize their adherence to the anti-retroviral therapy. Therefore, this study explored and described the experiences of healthcare professionals providing care, support and guidance to persons on ART at public hospitals in Ghana, as well as the best-practice guideline that could contribute to facilitating the ART adherence of patients. This study also explored and described the experiences of persons living with Human Immunodeficiency Virus/Acquired Immunodeficiency Syndrome (HIV/AIDS) on ART, regarding their adherence to the therapy. The study was organized into three phases. In Phase One: a qualitative, exploratory, descriptive and contextual design was employed. The research population included healthcare professionals, providing services at the HIV clinic at the public hospitals in Ghana, namely the Korle-Bu Teaching Hospital; the 37 Military Hospital and the Ridge Hospital. The healthcare professionals comprised of doctors, nurses, pharmacists and trained counsellors employed in any of the three public hospitals. Persons receiving ART at any of the three public hospitals were also part of the research population. Semi-structured interviews were conducted with healthcare professionals and persons receiving ART. Data were collected from healthcare professionals in relation to their experiences regarding the provision of ART services, their understanding of evidence-based practice and best-practice guidelines, as well as data on the experiences of persons receiving ART in relation to their adherence to the therapy. The data were analysed using Creswell’s six steps of data analysis; and the coding of the data was done according to Tesch’s eight steps of coding. Trustworthiness was ensured by using Lincoln and Guba’s framework which comprised credibility, transferability, dependability, confirmability and authenticity. Ethical principles such as beneficence and non-maleficence, respect for human dignity, justice, veracity, privacy and confidentiality were considered in the study. In phase two, the literature was searched by using an integrative literature review approach and critically appraising the methodological quality of the guidelines in order to identify the best available evidence related to adherence to ART. In Phase Three, a best-practice guideline for facilitating adherence to ART was developed for public hospitals in Ghana based on the findings of the empirical research of Phase One and the integrative literature review in Phase Two. The guideline was submitted to an expert panel for review; and it was modified, according to the recommendations of the panel.
- Full Text:
- Date Issued: 2017
The entrepreneurial orientation and performance of African immigrant-owned small businesses in the Eastern Cape
- Authors: Akah Ndang, William
- Date: 2017
- Subjects: Small business -- South Africa -- Eastern Cape , Economic development -- South Africa -- Eastern Cape Family-owned business enterprises -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/13868 , vital:27315
- Description: Given the rapid inflow of African immigrant entrepreneurs into South Africa, as well as the lack of understanding and research attention given to African immigrant entrepreneurial orientation, the failure rate of their businesses in South Africa is very high. The purpose of this study is to contribute to more effective and robust African immigrant entrepreneurship in South Africa by investigating the impact of African immigrant entrepreneurial orientation on business performance. With this purpose in mind, the primary objective of this study is to establish the level of entrepreneurial orientation of African immigrant-owned small businesses in the Eastern Cape Province, and to determine the influence of this orientation on business performance. This study sets out to pull together previous findings and theories on the relationship between entrepreneurial orientation, and business performance, to find support for the theories on the determinants of entrepreneurial orientation in the literature, and to combine these findings into a simple model. An overview of small businesses was first conducted, in which the nature of small businesses and African immigrant-owned small businesses was taken into consideration, as well as the role small businesses play within the economy and the different challenges small businesses face. The dimensions of entrepreneurial orientation were discussed. These included Innovativeness, Pro-activeness, Risk-taking, Competitive aggressiveness, and Autonomy. Business performance was discussed and was measured in terms of financial and non-financial measures. The resource based view was also discussed and human, social, and financial capitals were taken into consideration. A proposed theoretical framework was established to show the relationship between entrepreneurial orientation and business performance of African immigrant-owned small businesses and this was later tested by developing a hypothesis. A structured questionnaire was developed and data was collected through these self-administered questionnaires. They were made available to the respondents by a means of the snowball technique and data was collected from 218 respondents. Each construct was defined and operationalised. This was done by using themes from previous studies, as well as self developed themes. Cronbach‟s alpha coefficients were used to confirm reliability and validity of the measuring instruments. Completed questionnaires were subject to different statistical tests. A descriptive analysis was carried out, as well as an exploratory factor analysis, multiple regression and an analysis of variance. The findings of this study showed that Innovativeness has a negative relationship to Business performance whilst Competitive aggressiveness, Proactiveness, Risk-taking, and Autonomy have a significant positive relationship to Business performance. Furthermore, the findings established that Financial capital has a significant relationship to Competitive aggressiveness, Innovativeness, and Proactiveness, whilst there is no relationship to Risk-taking and Autonomy. In addition, it was established that there is a significant relationship between Human capital and Competitive aggressiveness, Proactiveness, and Autonomy, whilst there is no relationship to Innovativeness and Risk-taking. Moreover, the study also showed that a relationship exists between some selected demographic variables of the African immigrant-owned small business and entrepreneurial orientation, as measured by Innovativeness (H1a), Pro-activeness (H1b), Risk-taking (H1c), Competitive aggressiveness (H1d) and Autonomy (H1e). An exception was the demographic variable, the Level of education, which was not found to be as stipulated in the hypothesis. In the context of this study, it was found that 62% of change in African immigrant-owned small business performance is affected by entrepreneurial orientation while other factors accounted for the remaining 38%. Management should revisit its entrepreneurial orientation capabilities and determine whether these are delivering values. This will require a review of policies and procedures in addition to benchmarking these activities to identify whether the business is committing an unwarranted and misplaced amount of resources to a given entrepreneurial orientation activity. Blind pursuit of the uniform implementation of an entrepreneurial dimension is not an effective way for African immigrant-owned small businesses to create an advantage.
- Full Text:
- Date Issued: 2017
- Authors: Akah Ndang, William
- Date: 2017
- Subjects: Small business -- South Africa -- Eastern Cape , Economic development -- South Africa -- Eastern Cape Family-owned business enterprises -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MCom
- Identifier: http://hdl.handle.net/10948/13868 , vital:27315
- Description: Given the rapid inflow of African immigrant entrepreneurs into South Africa, as well as the lack of understanding and research attention given to African immigrant entrepreneurial orientation, the failure rate of their businesses in South Africa is very high. The purpose of this study is to contribute to more effective and robust African immigrant entrepreneurship in South Africa by investigating the impact of African immigrant entrepreneurial orientation on business performance. With this purpose in mind, the primary objective of this study is to establish the level of entrepreneurial orientation of African immigrant-owned small businesses in the Eastern Cape Province, and to determine the influence of this orientation on business performance. This study sets out to pull together previous findings and theories on the relationship between entrepreneurial orientation, and business performance, to find support for the theories on the determinants of entrepreneurial orientation in the literature, and to combine these findings into a simple model. An overview of small businesses was first conducted, in which the nature of small businesses and African immigrant-owned small businesses was taken into consideration, as well as the role small businesses play within the economy and the different challenges small businesses face. The dimensions of entrepreneurial orientation were discussed. These included Innovativeness, Pro-activeness, Risk-taking, Competitive aggressiveness, and Autonomy. Business performance was discussed and was measured in terms of financial and non-financial measures. The resource based view was also discussed and human, social, and financial capitals were taken into consideration. A proposed theoretical framework was established to show the relationship between entrepreneurial orientation and business performance of African immigrant-owned small businesses and this was later tested by developing a hypothesis. A structured questionnaire was developed and data was collected through these self-administered questionnaires. They were made available to the respondents by a means of the snowball technique and data was collected from 218 respondents. Each construct was defined and operationalised. This was done by using themes from previous studies, as well as self developed themes. Cronbach‟s alpha coefficients were used to confirm reliability and validity of the measuring instruments. Completed questionnaires were subject to different statistical tests. A descriptive analysis was carried out, as well as an exploratory factor analysis, multiple regression and an analysis of variance. The findings of this study showed that Innovativeness has a negative relationship to Business performance whilst Competitive aggressiveness, Proactiveness, Risk-taking, and Autonomy have a significant positive relationship to Business performance. Furthermore, the findings established that Financial capital has a significant relationship to Competitive aggressiveness, Innovativeness, and Proactiveness, whilst there is no relationship to Risk-taking and Autonomy. In addition, it was established that there is a significant relationship between Human capital and Competitive aggressiveness, Proactiveness, and Autonomy, whilst there is no relationship to Innovativeness and Risk-taking. Moreover, the study also showed that a relationship exists between some selected demographic variables of the African immigrant-owned small business and entrepreneurial orientation, as measured by Innovativeness (H1a), Pro-activeness (H1b), Risk-taking (H1c), Competitive aggressiveness (H1d) and Autonomy (H1e). An exception was the demographic variable, the Level of education, which was not found to be as stipulated in the hypothesis. In the context of this study, it was found that 62% of change in African immigrant-owned small business performance is affected by entrepreneurial orientation while other factors accounted for the remaining 38%. Management should revisit its entrepreneurial orientation capabilities and determine whether these are delivering values. This will require a review of policies and procedures in addition to benchmarking these activities to identify whether the business is committing an unwarranted and misplaced amount of resources to a given entrepreneurial orientation activity. Blind pursuit of the uniform implementation of an entrepreneurial dimension is not an effective way for African immigrant-owned small businesses to create an advantage.
- Full Text:
- Date Issued: 2017
Cost and return analysis of smallholder organic crop farms in the Eastern Cape province of South Africa
- Authors: Akharume, Celestine Ohi
- Date: 2017
- Subjects: Farms, Small -- South Africa -- Eastern Cape Profit -- South Africa -- Eastern Cape Organic farming -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/13730 , vital:39703
- Description: Agriculture remains an influential sector in South Africa in terms of its contributions to economic development and poverty reduction, notably in the rural areas. These include providing sufficient and affordable food for the constantly increasing population, providing cheap food for the developing industrial labor force, providing employment and livelihoods and supplying raw materials to the country’s rising domestic industrial sector. Despite phenomenal progress in integrating smallholder farmers into the mainstream economy since democratic reforms in the country, deteriorating soil quality through poor agricultural practices, land erosion, acidification and concerns about production and productivity and compliance with food safety standards are beginning to loom high. Hence, organic farming is identified as one of the sustainable approaches to farming. It is also believed to guarantee substantial net gains and to promote sustainable natural resource management with the possibility of enhancing overall agricultural productivity. Notwithstanding, organic farming is still being perceived negatively in South Africa and there is shortage of empirical studies which focus on cost and return of smallholder organic crop farms. It is in this regard that the study therefore seeks to analyze cost and return of smallholder organic crop farms in the Eastern Cape Province to contribute to knowledge on the relative economic advantages of organic agriculture at the smallholder sector. Specifically, the study profiled the socioeconomic characteristics of smallholder organic crop farmers, determined costs and returns, and estimated profitability and factors that constrain profitability of the smallholder organic crop farms. The research design used in this study was cross-sectional where data were collected at a single point in time. A multi- stage random sampling technique was used to obtain primary data from one hundred and sixty smallholder organic crop farmers (160) with the aid of structured questionnaires. Primary data were collected on demographic and socioeconomic characteristics, variable costs and fixed costs, and returns from the organic crop farms. Data collected were analyzed by Statistical Package for Social Sciences (SPSS) and the descriptive and inferential statistics involved were mean, frequency proportion, gross margin and net income analysis as well as OLS regression analysis. The results of the descriptive analysis showed that the proportions of women involved in organic crop farming were higher than that of men and many of the farmers cultivated on less than 1.0ha. The analysis of the data also showed that smallholder organic crop farms are undoubtedly profitable farm business, with attractive net farm income and lower production costs. The findings further affirmed that factors such as household size, gender, farming experience, number of years in school, farm size, source of labor and access to credit affect profitability and net farm income. Therefore, government is advised to encourage the practice of organic farming by giving short-term loans to smallholder farmers, to enable them invest more in their organic crop farms. There is also need for government to organize workshops and lectures, educating and enlightening individual smallholder organic crop farmers on modern organic farming techniques to enhance profitability of smallholder organic crop farms.
- Full Text:
- Date Issued: 2017
- Authors: Akharume, Celestine Ohi
- Date: 2017
- Subjects: Farms, Small -- South Africa -- Eastern Cape Profit -- South Africa -- Eastern Cape Organic farming -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/13730 , vital:39703
- Description: Agriculture remains an influential sector in South Africa in terms of its contributions to economic development and poverty reduction, notably in the rural areas. These include providing sufficient and affordable food for the constantly increasing population, providing cheap food for the developing industrial labor force, providing employment and livelihoods and supplying raw materials to the country’s rising domestic industrial sector. Despite phenomenal progress in integrating smallholder farmers into the mainstream economy since democratic reforms in the country, deteriorating soil quality through poor agricultural practices, land erosion, acidification and concerns about production and productivity and compliance with food safety standards are beginning to loom high. Hence, organic farming is identified as one of the sustainable approaches to farming. It is also believed to guarantee substantial net gains and to promote sustainable natural resource management with the possibility of enhancing overall agricultural productivity. Notwithstanding, organic farming is still being perceived negatively in South Africa and there is shortage of empirical studies which focus on cost and return of smallholder organic crop farms. It is in this regard that the study therefore seeks to analyze cost and return of smallholder organic crop farms in the Eastern Cape Province to contribute to knowledge on the relative economic advantages of organic agriculture at the smallholder sector. Specifically, the study profiled the socioeconomic characteristics of smallholder organic crop farmers, determined costs and returns, and estimated profitability and factors that constrain profitability of the smallholder organic crop farms. The research design used in this study was cross-sectional where data were collected at a single point in time. A multi- stage random sampling technique was used to obtain primary data from one hundred and sixty smallholder organic crop farmers (160) with the aid of structured questionnaires. Primary data were collected on demographic and socioeconomic characteristics, variable costs and fixed costs, and returns from the organic crop farms. Data collected were analyzed by Statistical Package for Social Sciences (SPSS) and the descriptive and inferential statistics involved were mean, frequency proportion, gross margin and net income analysis as well as OLS regression analysis. The results of the descriptive analysis showed that the proportions of women involved in organic crop farming were higher than that of men and many of the farmers cultivated on less than 1.0ha. The analysis of the data also showed that smallholder organic crop farms are undoubtedly profitable farm business, with attractive net farm income and lower production costs. The findings further affirmed that factors such as household size, gender, farming experience, number of years in school, farm size, source of labor and access to credit affect profitability and net farm income. Therefore, government is advised to encourage the practice of organic farming by giving short-term loans to smallholder farmers, to enable them invest more in their organic crop farms. There is also need for government to organize workshops and lectures, educating and enlightening individual smallholder organic crop farmers on modern organic farming techniques to enhance profitability of smallholder organic crop farms.
- Full Text:
- Date Issued: 2017
Negotiating the line between information and panic: a case study of vanguard’s coverage of the ebola outbreak in Nigeria
- Authors: Akingbade, Olutobi Elijah
- Date: 2017
- Subjects: Digital media -- Marketing , Marketing -- Technological innovations , Internet marketing , Carbonated beverages -- Marketing , Coca Cola (Trademark) -- Marketing , Social media -- Economic aspects , Soft drink industry -- Internet marketing , Health behavior in adolescence , Advertising -- Carbonated beverages , Obesity in adolescence , Drinking behavior
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/5903 , vital:20986
- Description: This study titled ‘Negotiating the line between information and panic: A case study of Vanguard’s coverage of the Ebola Outbreak in Nigeria’ investigates and evaluates Vanguard’s coverage of the 2014 Ebola Virus Disease (EVD) outbreak in Nigeria. This study was conducted to understand how Vanguard negotiated the line between the dissemination of actual EVD information and the possibility of creating panic and fear during the coverage of the outbreak. Using qualitative content analysis and interview embedded within a qualitative research design, the study was carried out against the backdrop of relevant literature that asserts that the mass media is an important carrier, prime mover and producer of tensions, anxieties, fears and panics while the print media specifically is argued to have as part of its history the business of irrational fear mongering and the creation of panic about social problems. Vanguard, rated as one of the ten largest newspapers in Nigeria, was purposively selected for this study. Vanguard did substantial reporting and dissemination of the 2014 EVD outbreak and it was possible to draw on the availability and accessibility of the electronic archives of the EVD articles. Using the theory of moral panic, the normative theories of the media and theories about essential constituents of journalism culture as a theoretical framework, the study reveals that Vanguard’s coverage of the 2014 EVD outbreak was challenging and more demanding compared to coverage of previous outbreaks of viral diseases in Nigeria by the print medium. The study shows that lack of sufficient understanding of the science that underlies EVD, the initial exclusion of the media from the national response to contain the outbreak, and the lack of sufficient proactive measures by government and the print medium were powerful factors in how the epidemic was reported. The study also shows an interesting dimension in Vanguard’s early and latter coverage of the EVD outbreak while it lasted in Nigeria. This dimension reveals a high number of EVD articles with the propensity to inspire fear and panic in the early days of the coverage compared to EVD articles with the propensity to douse fear and panic in the early and latter days of the outbreak. The study shows that while the challenges encountered stem from Ebola’s mode of transmission, lack of scientific and medically proven cure and early coverage amidst uncertainties, the inherent tensions and anxieties that characterised the outbreak coupled with Vanguard’s fire brigade approach led to the relatively high number of EVD articles with the propensity to inspire fear and panic. The study recommends the mass media’s inclusion in national responses to epidemics and ongoing training for health journalists to update their knowledge base about emerging and infectious diseases. The study also recommends for further study a reception analysis to enhance the socio-cultural understanding of how the EVD articles were received.
- Full Text:
- Date Issued: 2017
- Authors: Akingbade, Olutobi Elijah
- Date: 2017
- Subjects: Digital media -- Marketing , Marketing -- Technological innovations , Internet marketing , Carbonated beverages -- Marketing , Coca Cola (Trademark) -- Marketing , Social media -- Economic aspects , Soft drink industry -- Internet marketing , Health behavior in adolescence , Advertising -- Carbonated beverages , Obesity in adolescence , Drinking behavior
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10962/5903 , vital:20986
- Description: This study titled ‘Negotiating the line between information and panic: A case study of Vanguard’s coverage of the Ebola Outbreak in Nigeria’ investigates and evaluates Vanguard’s coverage of the 2014 Ebola Virus Disease (EVD) outbreak in Nigeria. This study was conducted to understand how Vanguard negotiated the line between the dissemination of actual EVD information and the possibility of creating panic and fear during the coverage of the outbreak. Using qualitative content analysis and interview embedded within a qualitative research design, the study was carried out against the backdrop of relevant literature that asserts that the mass media is an important carrier, prime mover and producer of tensions, anxieties, fears and panics while the print media specifically is argued to have as part of its history the business of irrational fear mongering and the creation of panic about social problems. Vanguard, rated as one of the ten largest newspapers in Nigeria, was purposively selected for this study. Vanguard did substantial reporting and dissemination of the 2014 EVD outbreak and it was possible to draw on the availability and accessibility of the electronic archives of the EVD articles. Using the theory of moral panic, the normative theories of the media and theories about essential constituents of journalism culture as a theoretical framework, the study reveals that Vanguard’s coverage of the 2014 EVD outbreak was challenging and more demanding compared to coverage of previous outbreaks of viral diseases in Nigeria by the print medium. The study shows that lack of sufficient understanding of the science that underlies EVD, the initial exclusion of the media from the national response to contain the outbreak, and the lack of sufficient proactive measures by government and the print medium were powerful factors in how the epidemic was reported. The study also shows an interesting dimension in Vanguard’s early and latter coverage of the EVD outbreak while it lasted in Nigeria. This dimension reveals a high number of EVD articles with the propensity to inspire fear and panic in the early days of the coverage compared to EVD articles with the propensity to douse fear and panic in the early and latter days of the outbreak. The study shows that while the challenges encountered stem from Ebola’s mode of transmission, lack of scientific and medically proven cure and early coverage amidst uncertainties, the inherent tensions and anxieties that characterised the outbreak coupled with Vanguard’s fire brigade approach led to the relatively high number of EVD articles with the propensity to inspire fear and panic. The study recommends the mass media’s inclusion in national responses to epidemics and ongoing training for health journalists to update their knowledge base about emerging and infectious diseases. The study also recommends for further study a reception analysis to enhance the socio-cultural understanding of how the EVD articles were received.
- Full Text:
- Date Issued: 2017
Antidiabetic and toxicological properties of Dianthus thunbergii (Caryophyllaceae) roots and Hypoxis argentea (Hypoxidaceae) corms
- Authors: Akinrinde, Akinleye Stephen
- Date: 2017
- Subjects: Medicinal plants--South Africa--Eastern Cape Traditional medicine--South Africa--Eastern Cape Diabetics--Alternative treatment--South Africa
- Language: English
- Type: Thesis , Doctoral , Biochemistry
- Identifier: http://hdl.handle.net/10353/16036 , vital:40606
- Description: Diabetes mellitus is a chronic metabolic disorder primarily characterized by elevated blood glucose levels. Its rapidly increasing prevalence as a major non-communicable disease is now a growing concern for both developed and developing countries. The development of safe, cost-effective and pharmacologically-effective medications continues to a major challenge of antidiabetic management. Since most conventional antidiabetic drugs are costly and present with numerous adverse effects, alternatives are increasingly being sought from natural sources, most notably medicinal plants, as viable approaches to tackling the scourge of this disease. In the Eastern Cape Province of South Africa, the roots of Dianthus thunbergii and corms of Hypoxis argentea are frequently used traditionally for the treatment of diabetes mellitus, although no scientific evidence exists to validate their effectiveness for diabetes management. The studies conducted in the resent research were, therefore, aimed at investigating the antidiabetic and toxicological properties of these plants, in an attempt to providing data towards validating their use in traditional management of diabetes mellitus. Aqueous and ethanol extracts of the underground parts of D. thunbergii and H. argentea were initially subjected to analysis of their phytochemical composition, relative to standard compounds, and the nature of their in-vitro antioxidant activities using standard spectrophotometric methods. The potentials of these extracts for cytotoxicity and/or cell proliferation were evaluated using MTT assay in HepG2 cells and Crystal violet assay in INS-1 cells. These activities were further examined in INS-1 cells using live cell fluorescence imaging techniques. To evaluate the antidiabetic properties of the extracts, they were screened for their inhibitory effects on the activities of different enzymes including α-amylase, α-glucosidase, porcine pancreatic lipase, Dipeptidyl peptidase IV (DPP-IV), collagenase and the drug metabolizing enzyme, CYP3A4, while also assessing their effects on protein glycation using in- vitro visible and fluorescence spectrophotometric approaches. Cell culture procedures were carried out to evaluate the effects of the extracts on glucose utilization in HepG2 cells and L6 myotubes; nitric oxide production in RAW 264.7 macrophages; glucose metabolism in INS-1 cells, as well as triglyceride accumulation in 3T3-L1 pre-adipocytes. Furthermore, identification of compounds present in the aqueous and ethanol extracts was carried out by Liquid chromatography- Mass spectrometry (LC-MS), while volatile oils extracted from fresh and dried parts of the two plants by hydrodistillation were also analyzed by Gas chromatography-Mass spectrometry (GC-MS). The ethanol extracts of both D. thunbergii and H. argentea contained higher amounts of total phenols, flavonoids, tannins, proanthocyanidins and alkaloids, when compared with the aqueous extracts. This finding was in direct correlation with the antioxidant activities of the extracts, with the ethanol extracts of both plants demonstrating stronger scavenging activities against hydrogen peroxide, nitric oxide, ABTS and DPPH radicals, while also exhibiting higher ferric reducing antioxidant potentials, when compared with the aqueous extracts, and in some cases, the standard antioxidants, Vitamin C, butylated hydroxytoluene and rutin. The aqueous extracts of D. thunbergii exhibited the highest toxicity in HepG2 cells with IC50 < 50 μg/ml, while also producing a concentration-dependent reduction in the viability of INS-1 cells up to 41.81percent at 50 μg/ml. Both extracts of H. argentea, however, did not produce any significant toxicity in these cells. Fluorescence imaging of live INS-1 cells using Hoechst and propidium iodide staining revealed stimulation of cell proliferation by H. argentea, while the cytotoxicity of D. thunbergii was further confirmed. H. argentea caused stimulation of glucose uptake in HepG2 cells up to 119.58 percent at 100 μg/ml and as much as 116.96 percent in L6 myotubes at 50 μg/ml, without showing toxicity to these cells. D. thunbergii produced 18.39 percent increase in L6 glucose uptake above untreated control; although its effect on HepG2 glucose uptake was irrelevant as significant toxicity was produced in these cells. H. argentea produced a concentration-dependent reduction in nitric oxide production in RAW macrophages, although not as effectively as the positive control, aminoguanidine. Again, the toxicity of D. thunbergii to this cell line precludes the relevance of nitric oxide inhibition as an antidiabetic mechanism for this plant. D. thunbergii produced a concentration-dependent increase in 3T3-L1 triglyceride accumulation, as measured by Oil red O staining, compared to untreated cells, while H. argentea exerted no significant alterations in pre- adipocyte differentiation. Generally, the two plants produced weak inhibition of the activities of the various enzymes measured, suggesting that this mechanism may not play a major role in the activities of these plants as possible antidiabetic agents. GC-MS analysis revealed major differences in the volatile oil composition between fresh and dried plant parts for both plants. Most notably, total terpenoid content of D. thunbergii oils reduced significantly from 77.17 percent in the fresh root oil to 47.58 percent in the dried root oil. Total terpenoid content was much lower in H. argentea oils, but similarly reduced from 10.58 percent in the fresh corm oil to 4.00 percent in the dried corm oil. LC-MS analysis enabled the tentative identification of compounds including phenolic glycosides, flavonoids, alkaloids, terpenoids saponins and sapogenins, many of which have been reported in literature to exert bioactivities relevant to the ones elucidated in the present study. Overall, H. argentea exhibited antidiabetic properties that may be mediated by its stimulation of glucose uptake in HepG2 and L6 cells; stimulation of proliferation in INS-1 cells; lack of stimulation of 3T3-L1 triglyceride accumulation and a tendency to reduce nitric oxide production in RAW macrophages. These activities suggest that H. argentea has promise for further investigations as an antidiabetic agent. On the contrary, D. thunbergii exhibited significant toxicity to HepG2 cells, INS-1 cells and RAW macrophages. Its cytotoxicity at the concentrations investigated in the present studies raises significant concerns about any potential antidiabetic applications for this plant.
- Full Text:
- Date Issued: 2017
- Authors: Akinrinde, Akinleye Stephen
- Date: 2017
- Subjects: Medicinal plants--South Africa--Eastern Cape Traditional medicine--South Africa--Eastern Cape Diabetics--Alternative treatment--South Africa
- Language: English
- Type: Thesis , Doctoral , Biochemistry
- Identifier: http://hdl.handle.net/10353/16036 , vital:40606
- Description: Diabetes mellitus is a chronic metabolic disorder primarily characterized by elevated blood glucose levels. Its rapidly increasing prevalence as a major non-communicable disease is now a growing concern for both developed and developing countries. The development of safe, cost-effective and pharmacologically-effective medications continues to a major challenge of antidiabetic management. Since most conventional antidiabetic drugs are costly and present with numerous adverse effects, alternatives are increasingly being sought from natural sources, most notably medicinal plants, as viable approaches to tackling the scourge of this disease. In the Eastern Cape Province of South Africa, the roots of Dianthus thunbergii and corms of Hypoxis argentea are frequently used traditionally for the treatment of diabetes mellitus, although no scientific evidence exists to validate their effectiveness for diabetes management. The studies conducted in the resent research were, therefore, aimed at investigating the antidiabetic and toxicological properties of these plants, in an attempt to providing data towards validating their use in traditional management of diabetes mellitus. Aqueous and ethanol extracts of the underground parts of D. thunbergii and H. argentea were initially subjected to analysis of their phytochemical composition, relative to standard compounds, and the nature of their in-vitro antioxidant activities using standard spectrophotometric methods. The potentials of these extracts for cytotoxicity and/or cell proliferation were evaluated using MTT assay in HepG2 cells and Crystal violet assay in INS-1 cells. These activities were further examined in INS-1 cells using live cell fluorescence imaging techniques. To evaluate the antidiabetic properties of the extracts, they were screened for their inhibitory effects on the activities of different enzymes including α-amylase, α-glucosidase, porcine pancreatic lipase, Dipeptidyl peptidase IV (DPP-IV), collagenase and the drug metabolizing enzyme, CYP3A4, while also assessing their effects on protein glycation using in- vitro visible and fluorescence spectrophotometric approaches. Cell culture procedures were carried out to evaluate the effects of the extracts on glucose utilization in HepG2 cells and L6 myotubes; nitric oxide production in RAW 264.7 macrophages; glucose metabolism in INS-1 cells, as well as triglyceride accumulation in 3T3-L1 pre-adipocytes. Furthermore, identification of compounds present in the aqueous and ethanol extracts was carried out by Liquid chromatography- Mass spectrometry (LC-MS), while volatile oils extracted from fresh and dried parts of the two plants by hydrodistillation were also analyzed by Gas chromatography-Mass spectrometry (GC-MS). The ethanol extracts of both D. thunbergii and H. argentea contained higher amounts of total phenols, flavonoids, tannins, proanthocyanidins and alkaloids, when compared with the aqueous extracts. This finding was in direct correlation with the antioxidant activities of the extracts, with the ethanol extracts of both plants demonstrating stronger scavenging activities against hydrogen peroxide, nitric oxide, ABTS and DPPH radicals, while also exhibiting higher ferric reducing antioxidant potentials, when compared with the aqueous extracts, and in some cases, the standard antioxidants, Vitamin C, butylated hydroxytoluene and rutin. The aqueous extracts of D. thunbergii exhibited the highest toxicity in HepG2 cells with IC50 < 50 μg/ml, while also producing a concentration-dependent reduction in the viability of INS-1 cells up to 41.81percent at 50 μg/ml. Both extracts of H. argentea, however, did not produce any significant toxicity in these cells. Fluorescence imaging of live INS-1 cells using Hoechst and propidium iodide staining revealed stimulation of cell proliferation by H. argentea, while the cytotoxicity of D. thunbergii was further confirmed. H. argentea caused stimulation of glucose uptake in HepG2 cells up to 119.58 percent at 100 μg/ml and as much as 116.96 percent in L6 myotubes at 50 μg/ml, without showing toxicity to these cells. D. thunbergii produced 18.39 percent increase in L6 glucose uptake above untreated control; although its effect on HepG2 glucose uptake was irrelevant as significant toxicity was produced in these cells. H. argentea produced a concentration-dependent reduction in nitric oxide production in RAW macrophages, although not as effectively as the positive control, aminoguanidine. Again, the toxicity of D. thunbergii to this cell line precludes the relevance of nitric oxide inhibition as an antidiabetic mechanism for this plant. D. thunbergii produced a concentration-dependent increase in 3T3-L1 triglyceride accumulation, as measured by Oil red O staining, compared to untreated cells, while H. argentea exerted no significant alterations in pre- adipocyte differentiation. Generally, the two plants produced weak inhibition of the activities of the various enzymes measured, suggesting that this mechanism may not play a major role in the activities of these plants as possible antidiabetic agents. GC-MS analysis revealed major differences in the volatile oil composition between fresh and dried plant parts for both plants. Most notably, total terpenoid content of D. thunbergii oils reduced significantly from 77.17 percent in the fresh root oil to 47.58 percent in the dried root oil. Total terpenoid content was much lower in H. argentea oils, but similarly reduced from 10.58 percent in the fresh corm oil to 4.00 percent in the dried corm oil. LC-MS analysis enabled the tentative identification of compounds including phenolic glycosides, flavonoids, alkaloids, terpenoids saponins and sapogenins, many of which have been reported in literature to exert bioactivities relevant to the ones elucidated in the present study. Overall, H. argentea exhibited antidiabetic properties that may be mediated by its stimulation of glucose uptake in HepG2 and L6 cells; stimulation of proliferation in INS-1 cells; lack of stimulation of 3T3-L1 triglyceride accumulation and a tendency to reduce nitric oxide production in RAW macrophages. These activities suggest that H. argentea has promise for further investigations as an antidiabetic agent. On the contrary, D. thunbergii exhibited significant toxicity to HepG2 cells, INS-1 cells and RAW macrophages. Its cytotoxicity at the concentrations investigated in the present studies raises significant concerns about any potential antidiabetic applications for this plant.
- Full Text:
- Date Issued: 2017
The design of a boarding school for displaced children near Graaff-Reinet
- Authors: Akom, Chelcie Jade
- Date: 2017
- Subjects: School buildings -- South Africa -- Eastern Cape , School buildings -- Specifications -- South Africa -- Eastern Cape Architecture -- Designs and plans Graaff-Reinet (South Africa)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/17888 , vital:28479
- Description: The treatise developed from a preoccupation with regards to the theories rooted around the human need for a sense of embeddedness in a specific place. This need lies deep within the human heart, as humans have a psychological and phenomenological need for a sense of comfort and security. The preoccupation lead to the notions pertaining to place to place making. The treatise acknowledges that certain places have the ability to evoke certain moods in human beings as a result of their extension and character, and when a place possesses a certain character it becomes meaningful to man. In order for man to fulfill his need to dwell amid the earth and sky, he has to orientate himself and identify with the natural place in which he is located.
- Full Text:
- Date Issued: 2017
- Authors: Akom, Chelcie Jade
- Date: 2017
- Subjects: School buildings -- South Africa -- Eastern Cape , School buildings -- Specifications -- South Africa -- Eastern Cape Architecture -- Designs and plans Graaff-Reinet (South Africa)
- Language: English
- Type: Thesis , Masters , MA
- Identifier: http://hdl.handle.net/10948/17888 , vital:28479
- Description: The treatise developed from a preoccupation with regards to the theories rooted around the human need for a sense of embeddedness in a specific place. This need lies deep within the human heart, as humans have a psychological and phenomenological need for a sense of comfort and security. The preoccupation lead to the notions pertaining to place to place making. The treatise acknowledges that certain places have the ability to evoke certain moods in human beings as a result of their extension and character, and when a place possesses a certain character it becomes meaningful to man. In order for man to fulfill his need to dwell amid the earth and sky, he has to orientate himself and identify with the natural place in which he is located.
- Full Text:
- Date Issued: 2017
The adoption of employee share ownership plans (ESOPs) in Nigeria
- Authors: Akponah, Voke Blessing
- Date: 2017
- Subjects: Employee ownership -- Nigeria , Profit-sharing -- Nigeria Management -- Employee participation -- Nigeria Nigeria -- Economic aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/13834 , vital:27312
- Description: This study investigated the factors that influence the adoption of ESOPs in Nigeria. Furthermore, the study investigated the influence of the adoption of ESOPs on organisational performance, employee retention and employee commitment. The study results reveal that trade union responsiveness, reforms, awareness of employee benefits and taxation implication positively influence the adoption of ESOPs based on transparency. The results in this study further reveal that trade union responsiveness, takeovers, reforms, awareness of employee benefits and taxation implication effectively influence the adoption of ESOPs based on two-way communication. In addition, the study results reveal that trade union responsiveness, takeovers, reforms, awareness of employee benefits and trust positively influence the adoption of ESOPs based on empowerment. The study further reveals that adoption of ESOPs based on transparency, two-way communication and empowerment leads to organisational performance, employee retention and employee commitment. This study, being the first of its kind in Nigeria, filled the gap that existed in the Nigerian literature in respect of the awareness and adoption of ESOPs. This study provides literature and theoretical model that can be used as a foundation by organisations and the government to start up the adoption of ESOPs. This study showed that ESOPs is beneficial to boost the economy, enhance desired organisational outcomes (organisational performance, employee retention and employee commitment) and meet the financial and retirement needs of employees. However, for organisations and employees to enjoy the full benefits of ESOPs, underlying forces such as, trade union responsiveness, takeovers, reforms, awareness of employee benefits, trusts and taxation implication must be taken into account. Furthermore, the adoption, implementation and operations of ESOPs will be successful management, trade union leaders and employees utilise strategies such as, transparency, two-way communication and empowerment.
- Full Text:
- Date Issued: 2017
- Authors: Akponah, Voke Blessing
- Date: 2017
- Subjects: Employee ownership -- Nigeria , Profit-sharing -- Nigeria Management -- Employee participation -- Nigeria Nigeria -- Economic aspects
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/13834 , vital:27312
- Description: This study investigated the factors that influence the adoption of ESOPs in Nigeria. Furthermore, the study investigated the influence of the adoption of ESOPs on organisational performance, employee retention and employee commitment. The study results reveal that trade union responsiveness, reforms, awareness of employee benefits and taxation implication positively influence the adoption of ESOPs based on transparency. The results in this study further reveal that trade union responsiveness, takeovers, reforms, awareness of employee benefits and taxation implication effectively influence the adoption of ESOPs based on two-way communication. In addition, the study results reveal that trade union responsiveness, takeovers, reforms, awareness of employee benefits and trust positively influence the adoption of ESOPs based on empowerment. The study further reveals that adoption of ESOPs based on transparency, two-way communication and empowerment leads to organisational performance, employee retention and employee commitment. This study, being the first of its kind in Nigeria, filled the gap that existed in the Nigerian literature in respect of the awareness and adoption of ESOPs. This study provides literature and theoretical model that can be used as a foundation by organisations and the government to start up the adoption of ESOPs. This study showed that ESOPs is beneficial to boost the economy, enhance desired organisational outcomes (organisational performance, employee retention and employee commitment) and meet the financial and retirement needs of employees. However, for organisations and employees to enjoy the full benefits of ESOPs, underlying forces such as, trade union responsiveness, takeovers, reforms, awareness of employee benefits, trusts and taxation implication must be taken into account. Furthermore, the adoption, implementation and operations of ESOPs will be successful management, trade union leaders and employees utilise strategies such as, transparency, two-way communication and empowerment.
- Full Text:
- Date Issued: 2017
Extended use of grey water for irrigating home gardens in an arid environment
- Al-Ismaili, Abdulrahim M, Ahmed, Mushtaque, Al-Busaidi, Ahmed, Al-Adawi, Seif, Tandlich, Roman, Al-Amri, Mohammed
- Authors: Al-Ismaili, Abdulrahim M , Ahmed, Mushtaque , Al-Busaidi, Ahmed , Al-Adawi, Seif , Tandlich, Roman , Al-Amri, Mohammed
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/76048 , vital:30497 , https://doi.org/10.1007/s11356-017-8963-z
- Description: The use of treated grey water (GW) for home gardens, peri-urban agriculture and landscaping is becoming popular in many water stressed countries such as Oman. This study aims to investigate the treatment efficacy, health and chemical concerns, cost-benefits and maintenance protocol of a GW treatment system as well as the effect of irrigation with GW on crop yield. Therefore, a decentralized homemade GW treatment system was installed in a newly constructed house in Muscat, Oman and studied over a 2-year period. The treated GW was found to be suitable for irrigation as per Omani standards. GW when mixed with kitchen effluent substituted the use of nutrient supplements for plants and did not show any harmful chemical or biological contamination. The capital cost of the system was around US $980, and the annual operating cost was US $78 with annual income and savings from the system being around US $572 indicating a payback period of nearly 2 years. It was found that the system required simple but regular maintenance particularly cleaning of the top layer of the filter. It can be concluded from this study that such a GW system should be technically, economically and environmentally feasible in Oman. Also, wider acceptance by the general public to the idea of GW reuse will help in mitigating the water shortage problem of the country to some extent.
- Full Text:
- Date Issued: 2017
- Authors: Al-Ismaili, Abdulrahim M , Ahmed, Mushtaque , Al-Busaidi, Ahmed , Al-Adawi, Seif , Tandlich, Roman , Al-Amri, Mohammed
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/76048 , vital:30497 , https://doi.org/10.1007/s11356-017-8963-z
- Description: The use of treated grey water (GW) for home gardens, peri-urban agriculture and landscaping is becoming popular in many water stressed countries such as Oman. This study aims to investigate the treatment efficacy, health and chemical concerns, cost-benefits and maintenance protocol of a GW treatment system as well as the effect of irrigation with GW on crop yield. Therefore, a decentralized homemade GW treatment system was installed in a newly constructed house in Muscat, Oman and studied over a 2-year period. The treated GW was found to be suitable for irrigation as per Omani standards. GW when mixed with kitchen effluent substituted the use of nutrient supplements for plants and did not show any harmful chemical or biological contamination. The capital cost of the system was around US $980, and the annual operating cost was US $78 with annual income and savings from the system being around US $572 indicating a payback period of nearly 2 years. It was found that the system required simple but regular maintenance particularly cleaning of the top layer of the filter. It can be concluded from this study that such a GW system should be technically, economically and environmentally feasible in Oman. Also, wider acceptance by the general public to the idea of GW reuse will help in mitigating the water shortage problem of the country to some extent.
- Full Text:
- Date Issued: 2017
Contribution of home gardens to rural household income in Raymond Mhlaba Local Municipality, Eastern Cape Province, South Africa
- Authors: Alaka, Kolawole O
- Date: 2017
- Subjects: Gardens Food security Sustainable agriculture -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/8176 , vital:31826
- Description: For decades, home gardens have proved to be significant to rural inhabitants by providing a wide range of useful products such as fruits, vegetables and medicine, but there is lack of quantitative information on its benefits and its contributions to income of rural household. The main objective of this study is to investigate contributions of home garden to income of rural household in Raymond Mhlaba Local Municipality, formerly Nkonkobe Local Municipality of Eastern Cape Province South Africa. The stratified random sampling method was applied in order to choose a sample of 160 household that were interviewed by means of semi-structured questionnaires. The study was conducted among 80 households engaging in home gardens and 80 non- participating households in the study area. Frequencies and mean were used to describe the general characteristics of the households as well as ownership patterns of home gardens. In order to determine the factors that influence home gardens ownership binary logistic regression model was used. The overall model show that level of education, total household income and access to land significantly affects ownership of the home garden positively. Social grant has the highest contributions to total household income for both category while income generated from home garden has the second largest share to total household income, this show that the majority of rural households in the study area rely on social grant as their source of income. Cabbage, spinach, potatoes and carrots were the dominant crops in home gardens. In view of research findings, there is still a wide room for further improvement in home gardens practises in study area. Contrary to expectations, home gardens have the potential to improve livelihood significantly if the rural households take the necessary steps to make the production more sustainable. Based on research findings several policy proposals are suggested. These include investment in agricultural programmes that will empower the rural households like Massive food projects, Siyazondla and related home garden initiatives. Home garden is the major source of food and income generation in Raymond Mhlaba Municipality. Therefore, government should provide sufficient credit facilities, extension services together with marketing arrangement in the area.
- Full Text:
- Date Issued: 2017
- Authors: Alaka, Kolawole O
- Date: 2017
- Subjects: Gardens Food security Sustainable agriculture -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MAgric
- Identifier: http://hdl.handle.net/10353/8176 , vital:31826
- Description: For decades, home gardens have proved to be significant to rural inhabitants by providing a wide range of useful products such as fruits, vegetables and medicine, but there is lack of quantitative information on its benefits and its contributions to income of rural household. The main objective of this study is to investigate contributions of home garden to income of rural household in Raymond Mhlaba Local Municipality, formerly Nkonkobe Local Municipality of Eastern Cape Province South Africa. The stratified random sampling method was applied in order to choose a sample of 160 household that were interviewed by means of semi-structured questionnaires. The study was conducted among 80 households engaging in home gardens and 80 non- participating households in the study area. Frequencies and mean were used to describe the general characteristics of the households as well as ownership patterns of home gardens. In order to determine the factors that influence home gardens ownership binary logistic regression model was used. The overall model show that level of education, total household income and access to land significantly affects ownership of the home garden positively. Social grant has the highest contributions to total household income for both category while income generated from home garden has the second largest share to total household income, this show that the majority of rural households in the study area rely on social grant as their source of income. Cabbage, spinach, potatoes and carrots were the dominant crops in home gardens. In view of research findings, there is still a wide room for further improvement in home gardens practises in study area. Contrary to expectations, home gardens have the potential to improve livelihood significantly if the rural households take the necessary steps to make the production more sustainable. Based on research findings several policy proposals are suggested. These include investment in agricultural programmes that will empower the rural households like Massive food projects, Siyazondla and related home garden initiatives. Home garden is the major source of food and income generation in Raymond Mhlaba Municipality. Therefore, government should provide sufficient credit facilities, extension services together with marketing arrangement in the area.
- Full Text:
- Date Issued: 2017
The morale and motivation of government employees in a science environment
- Authors: Alberts, Lauren Erna
- Date: 2017
- Subjects: Employee morale -- South Africa -- Cape Town Employee motivation -- South Africa -- Cape Town , Civil service -- Personnel management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/46262 , vital:39541
- Description: This study investigated the problem of low morale and motivation of government employees in a scientific environment. There is not a significant amount of research about morale and motivation of government or public sector employees, specifically in the scientific environment. The emphasis of this study was to establish those factors contributing to the causes of low morale in government employees through identifying motivational factors that impact their morale. This quantitative study of a sample of 74 respondents develops a framework to foster morale and motivation in government employees working at the Forensic Science Laboratory in Cape Town, South Africa. Extrinsic motivational factors (working environment, salary and job security) and intrinsic motivational factors (recognition, responsibility and training) were measured against morale. In identifying the key areas relating to those of the motivation factors and morale in government employees, the issue can be addressed and measures implemented to meet the needs of these employees. The findings demonstrated evidence of the presence of a significant relationship between morale and the extrinsic motivational factor, job security, as well as the intrinsic motivation factors of recognition, responsibility and training.
- Full Text:
- Date Issued: 2017
- Authors: Alberts, Lauren Erna
- Date: 2017
- Subjects: Employee morale -- South Africa -- Cape Town Employee motivation -- South Africa -- Cape Town , Civil service -- Personnel management
- Language: English
- Type: Thesis , Masters , MBA
- Identifier: http://hdl.handle.net/10948/46262 , vital:39541
- Description: This study investigated the problem of low morale and motivation of government employees in a scientific environment. There is not a significant amount of research about morale and motivation of government or public sector employees, specifically in the scientific environment. The emphasis of this study was to establish those factors contributing to the causes of low morale in government employees through identifying motivational factors that impact their morale. This quantitative study of a sample of 74 respondents develops a framework to foster morale and motivation in government employees working at the Forensic Science Laboratory in Cape Town, South Africa. Extrinsic motivational factors (working environment, salary and job security) and intrinsic motivational factors (recognition, responsibility and training) were measured against morale. In identifying the key areas relating to those of the motivation factors and morale in government employees, the issue can be addressed and measures implemented to meet the needs of these employees. The findings demonstrated evidence of the presence of a significant relationship between morale and the extrinsic motivational factor, job security, as well as the intrinsic motivation factors of recognition, responsibility and training.
- Full Text:
- Date Issued: 2017
Investigating the use of models to develop Grade 8 learners’ conceptual understanding of and procedural fluency with fractions
- Authors: Albin, Simon
- Date: 2017
- Subjects: Fractions -- Study and teaching (Secondary) -- Namibia , Mathematics -- Study and teaching (Secondary) -- Namibia , Information visualization , Visual learning -- Case studies
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/36288 , vital:24537
- Description: Both my teaching experience and literature of this research study strongly suggested that fractions are difficult to teach and learn across the globe generally, and Namibia in particular. One of the identified contributing factors was teaching fractions by focusing on procedures and not the conceptual understanding. Therefore, this research project developed and implemented an intervention in order to experiment and suggest an alternative teaching approach of fractions using models. The purpose of this research was to: “Investigate the use of models to develop Grade 8 learners’ conceptual understanding of and procedural fluency with fractions”. This investigation had three areas of focus. Firstly, the study investigated the nature of learners’ conceptual understanding of and procedural fluency with fractions before the teaching intervention, by means of administering a pre-test and pre-interview and analysing learners’ responses. Secondly, the study investigated the changes in learners’ conceptual understanding of and procedural fluency with fractions after the teaching intervention, by means of administering a post-test, post-interviews and recall interviews, and analysing learners’ responses. Thirdly, this study investigated the possible influence of the teaching intervention on the changes in learners’ conceptual understanding of and procedural fluency with fractions by analysing the lesson videos and learners’ worksheets, and describe their critical interaction. This study was conducted at a multicultural urban secondary school located in the Oshikoto Region, Namibia. The sample consisted of 12 Grade 8 mathematics learners whose age ranged from 13-16 years old. A purposive sampling method was employed to select both the research site and participants. This research is framed as a case study, and is grounded within the interpretive paradigm and qualitative research. This research revealed that these learners displayed conceptual and procedural difficulties in their engagement with fraction models and fraction symbols, before the teaching intervention. Conceptually, the study found that these learners read fractions using inappropriate names; and learners did not identify the whole unit in the models and therefore identified fractions represented by the fraction models using different forms of inappropriate fraction symbols. Procedurally, the study found that these learners compared and ordered fractions inappropriately using the sizes of the numerators and denominators separately; and learners used the lowest common denominator method inappropriately for adding fractions with different denominators. The research also suggested conceptual and procedural changes in learners’ conceptual understanding of and procedural fluency with fractions and that the intervention seemed to help learners to engage better with fraction models and fraction symbols. Conceptually, the findings suggested that the intervention using area models and number lines, seemed to help these learners to read fractions using appropriate names; to identify the whole unit in the fraction models and to develop a sense of the size of fractions in relation to one whole unit. Procedurally, the learners compared and ordered fractions appropriately using either equal fraction bars, equal number lines, benchmarking or rules for comparing and ordering fractions with the same numerator or denominator; and learners used equal fraction bars to visually represent the lowest common denominator method and to recognise that only equally sized units can be counted together. This research identified four factors as possible influences of the teaching intervention. These factors are namely: identifying both fraction symbols and appropriate fraction names to see fractions as relational numbers; prompting to partition whole units of the fraction models and graphically illustrating fraction symbols to identify the whole unit in the fraction models and to develop a sense of the size of fractions in relation to one whole unit; graphically illustrating fraction symbols using the models to use equal fraction bars and number lines, benchmarking and rules for comparing; and graphically illustrating fraction denominations using equal fraction bars to recognise that only equally sized units can be counted together. This research strongly suggests that the effective use of models has the potential to develop learners’ conceptual understanding of and procedural fluency with fractions in a number of ways.
- Full Text:
- Date Issued: 2017
- Authors: Albin, Simon
- Date: 2017
- Subjects: Fractions -- Study and teaching (Secondary) -- Namibia , Mathematics -- Study and teaching (Secondary) -- Namibia , Information visualization , Visual learning -- Case studies
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/36288 , vital:24537
- Description: Both my teaching experience and literature of this research study strongly suggested that fractions are difficult to teach and learn across the globe generally, and Namibia in particular. One of the identified contributing factors was teaching fractions by focusing on procedures and not the conceptual understanding. Therefore, this research project developed and implemented an intervention in order to experiment and suggest an alternative teaching approach of fractions using models. The purpose of this research was to: “Investigate the use of models to develop Grade 8 learners’ conceptual understanding of and procedural fluency with fractions”. This investigation had three areas of focus. Firstly, the study investigated the nature of learners’ conceptual understanding of and procedural fluency with fractions before the teaching intervention, by means of administering a pre-test and pre-interview and analysing learners’ responses. Secondly, the study investigated the changes in learners’ conceptual understanding of and procedural fluency with fractions after the teaching intervention, by means of administering a post-test, post-interviews and recall interviews, and analysing learners’ responses. Thirdly, this study investigated the possible influence of the teaching intervention on the changes in learners’ conceptual understanding of and procedural fluency with fractions by analysing the lesson videos and learners’ worksheets, and describe their critical interaction. This study was conducted at a multicultural urban secondary school located in the Oshikoto Region, Namibia. The sample consisted of 12 Grade 8 mathematics learners whose age ranged from 13-16 years old. A purposive sampling method was employed to select both the research site and participants. This research is framed as a case study, and is grounded within the interpretive paradigm and qualitative research. This research revealed that these learners displayed conceptual and procedural difficulties in their engagement with fraction models and fraction symbols, before the teaching intervention. Conceptually, the study found that these learners read fractions using inappropriate names; and learners did not identify the whole unit in the models and therefore identified fractions represented by the fraction models using different forms of inappropriate fraction symbols. Procedurally, the study found that these learners compared and ordered fractions inappropriately using the sizes of the numerators and denominators separately; and learners used the lowest common denominator method inappropriately for adding fractions with different denominators. The research also suggested conceptual and procedural changes in learners’ conceptual understanding of and procedural fluency with fractions and that the intervention seemed to help learners to engage better with fraction models and fraction symbols. Conceptually, the findings suggested that the intervention using area models and number lines, seemed to help these learners to read fractions using appropriate names; to identify the whole unit in the fraction models and to develop a sense of the size of fractions in relation to one whole unit. Procedurally, the learners compared and ordered fractions appropriately using either equal fraction bars, equal number lines, benchmarking or rules for comparing and ordering fractions with the same numerator or denominator; and learners used equal fraction bars to visually represent the lowest common denominator method and to recognise that only equally sized units can be counted together. This research identified four factors as possible influences of the teaching intervention. These factors are namely: identifying both fraction symbols and appropriate fraction names to see fractions as relational numbers; prompting to partition whole units of the fraction models and graphically illustrating fraction symbols to identify the whole unit in the fraction models and to develop a sense of the size of fractions in relation to one whole unit; graphically illustrating fraction symbols using the models to use equal fraction bars and number lines, benchmarking and rules for comparing; and graphically illustrating fraction denominations using equal fraction bars to recognise that only equally sized units can be counted together. This research strongly suggests that the effective use of models has the potential to develop learners’ conceptual understanding of and procedural fluency with fractions in a number of ways.
- Full Text:
- Date Issued: 2017
Positioning 'the self': comparative case studies of first generation students' academic identities when home meets campus in a rapidly transforming higher education context
- Authors: Alcock, Andrea
- Date: 2017
- Subjects: First-generation college students -- South Africa , First-generation college students -- South Africa -- Case studies , Social perception -- South Africa , Educational equalization -- South Africa , College students -- South Africa -- Attitudes , College students, Black -- South Africa -- Attitudes , College students, Black -- South Africa -- Psychology
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/6897 , vital:21198
- Description: This research offers an in-depth view of the self-positioning of a sample of seven first generation students in an extended curriculum programme for Arts and Design at the Durban University of Technology. This comparative case study aims to examine how these participants took up, held or resisted positions, during the transitional process of entering a university. The students' responses were elicited in order to explore the development of student academic identity in this stage of late adolescence. Using positioning theory as an analytical framework, a visual methodology was employed to generate data during photo-elicitation interviews. For these, participants were invited to take metaphorical and non-mimetic photographs, in response to the prompt "Take photographs that show you as a student at home and on campus". Themes that surfaced were examined using positioning theory where the storylines, speech acts and rights and duties form the apex points of the positioning triangle that acts as a framework to analyse the participants' narratives. The study revealed the ways in which participants positioned their home communities and thereby developed their own agency. The majority of the participants used their self-positioning in relation to these home communities to build their academic identities. It was evident in the data that certain role models and peers played a significant part in such self-positioning. The rural to urban migration described by some of the participants indicated that the transition students navigated as they developed their academic identities was profound. The university was often perceived in this process as a powerful structure which offered opportunities but could simultaneously be experienced as alienating. Financial challenges added to the complexity of this experience. The development of student academic identity was evident in positioning statements of the participants and, in some cases, a professional identity was revealed. The analysis indicated that the participants were able to use their self-positioning to overcome many of their challenges through the creation of agential power and resilience. Furthermore the emergence of academic identity seemed to give rise to a positive view of 'the self' in relation to the period of transition to university.
- Full Text:
- Date Issued: 2017
- Authors: Alcock, Andrea
- Date: 2017
- Subjects: First-generation college students -- South Africa , First-generation college students -- South Africa -- Case studies , Social perception -- South Africa , Educational equalization -- South Africa , College students -- South Africa -- Attitudes , College students, Black -- South Africa -- Attitudes , College students, Black -- South Africa -- Psychology
- Language: English
- Type: Thesis , Masters , MEd
- Identifier: http://hdl.handle.net/10962/6897 , vital:21198
- Description: This research offers an in-depth view of the self-positioning of a sample of seven first generation students in an extended curriculum programme for Arts and Design at the Durban University of Technology. This comparative case study aims to examine how these participants took up, held or resisted positions, during the transitional process of entering a university. The students' responses were elicited in order to explore the development of student academic identity in this stage of late adolescence. Using positioning theory as an analytical framework, a visual methodology was employed to generate data during photo-elicitation interviews. For these, participants were invited to take metaphorical and non-mimetic photographs, in response to the prompt "Take photographs that show you as a student at home and on campus". Themes that surfaced were examined using positioning theory where the storylines, speech acts and rights and duties form the apex points of the positioning triangle that acts as a framework to analyse the participants' narratives. The study revealed the ways in which participants positioned their home communities and thereby developed their own agency. The majority of the participants used their self-positioning in relation to these home communities to build their academic identities. It was evident in the data that certain role models and peers played a significant part in such self-positioning. The rural to urban migration described by some of the participants indicated that the transition students navigated as they developed their academic identities was profound. The university was often perceived in this process as a powerful structure which offered opportunities but could simultaneously be experienced as alienating. Financial challenges added to the complexity of this experience. The development of student academic identity was evident in positioning statements of the participants and, in some cases, a professional identity was revealed. The analysis indicated that the participants were able to use their self-positioning to overcome many of their challenges through the creation of agential power and resilience. Furthermore the emergence of academic identity seemed to give rise to a positive view of 'the self' in relation to the period of transition to university.
- Full Text:
- Date Issued: 2017
Gypsum deposits associated with the Whitehill Formation (Ecca Group) in the Steytlerville-Jansenville Area, Southern Karoo, South Africa
- Authors: Almanza, Roberto Daniel
- Date: 2017
- Subjects: Gypsum -- South Africa Concretions -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/15292 , vital:28215
- Description: The Steyterville-Jansenville gypsum field is one of South Africa’s smaller deposits, yet plays host to several gypsum mines, both past and present. This study aims to deconstruct the processes involved in the precipitation of various quantities and grades of gypsum in the lower Ecca Group of the Karoo Supergroup. The calcium and sulphate ions required to form the gypsum mineral (CaSO4•2H2O) are derived from the mid- to lower-shale of the Whitehill Formation, which is carbonate- and pyrite-rich. Gypsum formation is dependent on the availability of pyrite as opposed to calcite, which is in abundance throughout the 30m thick, Early Ufimian (late Permian) Whitehill Formation. Weathered shale, which has been folded and faulted, forms the host environment in which gypsum has precipitated. Folding of the shale occurs as a series of large- and medium-scale anticlines and synclines that strike east to west. These structures, which formed during the Cape Orogeny indicate that stresses were exerted from the south-southwest towards the north-northeast. Folded calcite veins surrounded by amorphous pyrite, observed in thin section suggest that pyrite and calcite were precipitated together prior to a deformation event. Oxidation of pyrite following these deformation events results in the concentration of sulphides within the hinge zones of the folds (weakest zone) and this is where the larger gypsum deposits are found at the surface. Carbonate concretions in the Whitehill Formation up to 5m in length and 3m in width are common in the study area, and suggest a relationship with the deposition of the shale whereby calcium-rich nuclei grew in a concentric fashion during a non-depositional hiatus period. This period is also associated with a higher concentration of pyrite and could explain the occurrence of concretions together with adjacent gypsum-rich shale. Pyrite framboids observed under the Scanning Electron Microscope (SEM) provide evidence to suggest concentric growth of initially deposited microcrystals including nucleation and growth of nodules and concretions observed within the Whitehill Formation. Prerequisites for gypsum formation also include restricted drainage such as a pan, a clay layer in the drainage area and an arid climate where evaporation exceeds precipitation. The preferred surface conditions for gypsum formation would be low-lying areas which are surrounded by gently-sloping topography promoting the concentration of aqueous solutions in a calcite- and pyrite-rich area. Groundwater solution would initially dissolve the calcite and clay minerals, and pyrite and the quartz minerals would remain in the host rock. Areas with greater calcite and clay pores would accommodate more groundwater and thus promote a greater surface area for chemical reactions. This enhances the potential for the oxidation of pyrite to form sulphate ions, which can later combine with calcium ions to precipitate gypsum crystals. Alternatively, the oxidation of pyrite, which produces acidity, dissolves the carbonate host and the calcium- and sulphate-rich solution then precipitates gypsum. The combination of the structural and geomorphological processes is key to the formation of economic gypsum deposits. The potential for extensive gypsum reserves within the Steytlerville-Jansenville field remains valid, provided the target is located over a predominantly weathered Whitehill Formation outcrop, preferably in an area which has undergone extensive deformation (such as a fold hinge zone), and is favourable for the concentration of ground and surface water within a low-lying area.
- Full Text:
- Date Issued: 2017
- Authors: Almanza, Roberto Daniel
- Date: 2017
- Subjects: Gypsum -- South Africa Concretions -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/15292 , vital:28215
- Description: The Steyterville-Jansenville gypsum field is one of South Africa’s smaller deposits, yet plays host to several gypsum mines, both past and present. This study aims to deconstruct the processes involved in the precipitation of various quantities and grades of gypsum in the lower Ecca Group of the Karoo Supergroup. The calcium and sulphate ions required to form the gypsum mineral (CaSO4•2H2O) are derived from the mid- to lower-shale of the Whitehill Formation, which is carbonate- and pyrite-rich. Gypsum formation is dependent on the availability of pyrite as opposed to calcite, which is in abundance throughout the 30m thick, Early Ufimian (late Permian) Whitehill Formation. Weathered shale, which has been folded and faulted, forms the host environment in which gypsum has precipitated. Folding of the shale occurs as a series of large- and medium-scale anticlines and synclines that strike east to west. These structures, which formed during the Cape Orogeny indicate that stresses were exerted from the south-southwest towards the north-northeast. Folded calcite veins surrounded by amorphous pyrite, observed in thin section suggest that pyrite and calcite were precipitated together prior to a deformation event. Oxidation of pyrite following these deformation events results in the concentration of sulphides within the hinge zones of the folds (weakest zone) and this is where the larger gypsum deposits are found at the surface. Carbonate concretions in the Whitehill Formation up to 5m in length and 3m in width are common in the study area, and suggest a relationship with the deposition of the shale whereby calcium-rich nuclei grew in a concentric fashion during a non-depositional hiatus period. This period is also associated with a higher concentration of pyrite and could explain the occurrence of concretions together with adjacent gypsum-rich shale. Pyrite framboids observed under the Scanning Electron Microscope (SEM) provide evidence to suggest concentric growth of initially deposited microcrystals including nucleation and growth of nodules and concretions observed within the Whitehill Formation. Prerequisites for gypsum formation also include restricted drainage such as a pan, a clay layer in the drainage area and an arid climate where evaporation exceeds precipitation. The preferred surface conditions for gypsum formation would be low-lying areas which are surrounded by gently-sloping topography promoting the concentration of aqueous solutions in a calcite- and pyrite-rich area. Groundwater solution would initially dissolve the calcite and clay minerals, and pyrite and the quartz minerals would remain in the host rock. Areas with greater calcite and clay pores would accommodate more groundwater and thus promote a greater surface area for chemical reactions. This enhances the potential for the oxidation of pyrite to form sulphate ions, which can later combine with calcium ions to precipitate gypsum crystals. Alternatively, the oxidation of pyrite, which produces acidity, dissolves the carbonate host and the calcium- and sulphate-rich solution then precipitates gypsum. The combination of the structural and geomorphological processes is key to the formation of economic gypsum deposits. The potential for extensive gypsum reserves within the Steytlerville-Jansenville field remains valid, provided the target is located over a predominantly weathered Whitehill Formation outcrop, preferably in an area which has undergone extensive deformation (such as a fold hinge zone), and is favourable for the concentration of ground and surface water within a low-lying area.
- Full Text:
- Date Issued: 2017
New spaces and old stories: the Luminance woman, black womanhood and the illusion of the “new” South Africa
- Alweendo, Ndapwa Magano Nelao
- Authors: Alweendo, Ndapwa Magano Nelao
- Date: 2017
- Subjects: Luminance stores (South Africa) , Dhlomo, Khanyi , Dlamini, Judy , Women, Black -- South Africa -- Social life and customes , Women, Black -- South Africa -- Social conditions , Clothing trade -- South Africa , Social classes -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/42619 , vital:25220
- Description: This study examines ideas of black womanhood in post-apartheid South Africa. The opening of the Luminance boutique in 2013, previously owned by South African businesswoman and media mogul Khanyi Dhlomo in Johannesburg’s ultra-exclusive Hyde Park Corner, has been articulated as representing a rupture in the public and private performance of black womanhood. Luminance has positioned itself as a provider of world-class style and beauty and has embraced a narrative of black women’s empowerment in the process. The study is based on narrative semistructured interviews conducted Johannesburg with black women who have shopped at the boutique and women who believe themselves as having a meaningful connection to the store. The literature on black women, both internationally and in South Africa, acknowledges that black women experience multiple and intersecting oppressions of race, class and gender, among others. Located within black feminist theory, the study argues that the Luminance woman does represent some rupture in the historic understanding of black womanhood in South Africa. This woman is an elite player in both the corporate world and the world of luxury consumption, and is certainly entering spaces to which black women have historically been denied access. However, this study argues that there is a danger in reducing this woman to an oversimplified character, allowing responses to her to ignore the complexities of her reality in favour of the simplicity of her story, and ignore the structural socioeconomic challenges that continue to shape the lives of all black women in postapartheid South Africa. In this regard, the Luminance woman, while on the surface appearing to be an empowering new iteration of womanhood that should inspire other black woman, contributes to the erasure of her particular marginal experiences, and the oppression of black women in general. The story of the Luminance women contributes to a narrative of individual hard work and determination that frames her as a respectable example of what the “new” South Africa has delivered for its citizens. This woman is a model example of a South African who has succeeded because she took advantage of the opportunities supposedly afforded to all in the post-1994 era. It is therefore argued that praise of the Luminance woman serves a dual purpose: to reinforce the myth of equal opportunity in South Africa, and to lessen the legitimacy of marginalised groups’ experiences of oppression, especially black women who continue to constitute the poor majority.
- Full Text:
- Date Issued: 2017
- Authors: Alweendo, Ndapwa Magano Nelao
- Date: 2017
- Subjects: Luminance stores (South Africa) , Dhlomo, Khanyi , Dlamini, Judy , Women, Black -- South Africa -- Social life and customes , Women, Black -- South Africa -- Social conditions , Clothing trade -- South Africa , Social classes -- South Africa
- Language: English
- Type: Thesis , Masters , MSocSc
- Identifier: http://hdl.handle.net/10962/42619 , vital:25220
- Description: This study examines ideas of black womanhood in post-apartheid South Africa. The opening of the Luminance boutique in 2013, previously owned by South African businesswoman and media mogul Khanyi Dhlomo in Johannesburg’s ultra-exclusive Hyde Park Corner, has been articulated as representing a rupture in the public and private performance of black womanhood. Luminance has positioned itself as a provider of world-class style and beauty and has embraced a narrative of black women’s empowerment in the process. The study is based on narrative semistructured interviews conducted Johannesburg with black women who have shopped at the boutique and women who believe themselves as having a meaningful connection to the store. The literature on black women, both internationally and in South Africa, acknowledges that black women experience multiple and intersecting oppressions of race, class and gender, among others. Located within black feminist theory, the study argues that the Luminance woman does represent some rupture in the historic understanding of black womanhood in South Africa. This woman is an elite player in both the corporate world and the world of luxury consumption, and is certainly entering spaces to which black women have historically been denied access. However, this study argues that there is a danger in reducing this woman to an oversimplified character, allowing responses to her to ignore the complexities of her reality in favour of the simplicity of her story, and ignore the structural socioeconomic challenges that continue to shape the lives of all black women in postapartheid South Africa. In this regard, the Luminance woman, while on the surface appearing to be an empowering new iteration of womanhood that should inspire other black woman, contributes to the erasure of her particular marginal experiences, and the oppression of black women in general. The story of the Luminance women contributes to a narrative of individual hard work and determination that frames her as a respectable example of what the “new” South Africa has delivered for its citizens. This woman is a model example of a South African who has succeeded because she took advantage of the opportunities supposedly afforded to all in the post-1994 era. It is therefore argued that praise of the Luminance woman serves a dual purpose: to reinforce the myth of equal opportunity in South Africa, and to lessen the legitimacy of marginalised groups’ experiences of oppression, especially black women who continue to constitute the poor majority.
- Full Text:
- Date Issued: 2017
Improving fold resistance prediction of HIV-1 against protease and reverse transcriptase inhibitors using artificial neural networks:
- Amamuddy, Olivier S, Bishop, Nigel T, Tastan Bishop, Özlem
- Authors: Amamuddy, Olivier S , Bishop, Nigel T , Tastan Bishop, Özlem
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148261 , vital:38724 , https://0-doi.org.wam.seals.ac.za/10.1186/s12859-017-1782-x
- Description: Drug resistance in HIV treatment is still a worldwide problem. Predicting resistance to antiretrovirals (ARVs) before starting any treatment is important. Prediction accuracy is essential, as low-accuracy predictions increase the risk of prescribing sub-optimal drug regimens leading to patients developing resistance sooner. Artificial Neural Networks (ANNs) are a powerful tool that would be able to assist in drug resistance prediction. In this study, we constrained the dataset to subtype B, sacrificing generalizability for a higher predictive performance, and demonstrated that the predictive quality of the ANN regression models have definite improvement for most ARVs.
- Full Text:
- Date Issued: 2017
- Authors: Amamuddy, Olivier S , Bishop, Nigel T , Tastan Bishop, Özlem
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/148261 , vital:38724 , https://0-doi.org.wam.seals.ac.za/10.1186/s12859-017-1782-x
- Description: Drug resistance in HIV treatment is still a worldwide problem. Predicting resistance to antiretrovirals (ARVs) before starting any treatment is important. Prediction accuracy is essential, as low-accuracy predictions increase the risk of prescribing sub-optimal drug regimens leading to patients developing resistance sooner. Artificial Neural Networks (ANNs) are a powerful tool that would be able to assist in drug resistance prediction. In this study, we constrained the dataset to subtype B, sacrificing generalizability for a higher predictive performance, and demonstrated that the predictive quality of the ANN regression models have definite improvement for most ARVs.
- Full Text:
- Date Issued: 2017
A theoretical model for successful management of revenue for beneficiary communities of renewable energy companies in South Africa
- Authors: Amansure, Ricardo Julian
- Date: 2017
- Subjects: Strategic planning -- South Africa , Social responsibility of business -- South Africa , Renewable energy sources -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/7408 , vital:21351
- Description: The Renewable Energy (RE) sector is one of the fastest growing new industries in the Republic of South Africa (RSA). The Bloomberg New Energy Finance Climate Scope Report recently ranked RSA third globally, behind China and Brazil, and first among African countries for investment in clean energy (Glickman, 2014). However, one of the main benefits to be derived from the industry, that of socio-economic and enterprise development, is not being achieved owing to unsuccessful management of revenue for beneficiary communities in the renewable energy sector in RSA. Challenges relating to good governance and long-term planning are causing significant harm to communities that are already vulnerable, and are threatening to have a negative effect on the industry’s ability to fulfil its obligation to alleviate and, ultimately, eradicate poverty in some of the poorest communities in RSA.The primary objective of this study is to develop a model for the successful management of revenue for beneficiary communities in the renewable energy sector in South Africa. The model will provide guidance for enterprises, stakeholders, industry experts and community development practitioners within the renewable energy sector towards a pro-active, effective, and relevant decision-making process to achieve success in managing revenue for beneficiary communities. To address the primary objective, a number of secondary objectives were established by developing a conceptual model comprising variables identified in a comprehensive survey of the related literature. A path diagram, based on the formulation of appropriate hypotheses, was constructed between the independent variable and subsequent intervening and dependent variables. Primary data sourced from the identified national and international population of project management practitioners were collected by means of an electronic measuring instrument. The data were analysed and tested empirically by means of Structural Equation Modelling (SEM). The determinants that were identified through a review of the literature as influencing the success of managing revenue for beneficiary communities of renewable energy companies in South Africa included: the use of outside advice, strategic financial services, strategic planning, strategic partnerships, infrastructure development and project management. In order to achieve the objective, the following research questions were formulated: What is the influence of external factors such as outside advisers and support services on the perceived success of managing revenue for beneficiary communities of renewable energy companies in South Africa? The purpose of this research, therefore, was to evaluate and recommend new methodologies to the renewable energy sector by introducing a model of perceived success in managing revenue for beneficiary communities of renewable energy companies in South Africa. The study provided new insight into managing revenue for beneficiary communities in RSA. With the renewable energy sector being one of the fastest growing sectors in the RSA, and the RSA Government being determined to link the location of renewable energy facilities to economic development, this research has given new insight into managing revenue for SED and ED. The objectives of multi-sector participation, transformational change and sustainable initiatives for beneficiary communities could ensure greater consideration and care when managing beneficiary revenue. Thereby, the opportunity presented by the RE industry for beneficiary communities can change these communities dramatically for the better. The study makes a valuable contribution to the body of knowledge about managing revenue for beneficiary communities. The proposed model has led to a better understanding of the determinants that influence the success of managing revenue for beneficiary communities, namely: distinctive benefits (a combination of two variables: outside advice and support services), financial management, developmental benefits (a combination of two variables: infrastructure development and education), human development, project management and strategic planning. The study has also opened up new avenues of research into this subject.
- Full Text:
- Date Issued: 2017
- Authors: Amansure, Ricardo Julian
- Date: 2017
- Subjects: Strategic planning -- South Africa , Social responsibility of business -- South Africa , Renewable energy sources -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/7408 , vital:21351
- Description: The Renewable Energy (RE) sector is one of the fastest growing new industries in the Republic of South Africa (RSA). The Bloomberg New Energy Finance Climate Scope Report recently ranked RSA third globally, behind China and Brazil, and first among African countries for investment in clean energy (Glickman, 2014). However, one of the main benefits to be derived from the industry, that of socio-economic and enterprise development, is not being achieved owing to unsuccessful management of revenue for beneficiary communities in the renewable energy sector in RSA. Challenges relating to good governance and long-term planning are causing significant harm to communities that are already vulnerable, and are threatening to have a negative effect on the industry’s ability to fulfil its obligation to alleviate and, ultimately, eradicate poverty in some of the poorest communities in RSA.The primary objective of this study is to develop a model for the successful management of revenue for beneficiary communities in the renewable energy sector in South Africa. The model will provide guidance for enterprises, stakeholders, industry experts and community development practitioners within the renewable energy sector towards a pro-active, effective, and relevant decision-making process to achieve success in managing revenue for beneficiary communities. To address the primary objective, a number of secondary objectives were established by developing a conceptual model comprising variables identified in a comprehensive survey of the related literature. A path diagram, based on the formulation of appropriate hypotheses, was constructed between the independent variable and subsequent intervening and dependent variables. Primary data sourced from the identified national and international population of project management practitioners were collected by means of an electronic measuring instrument. The data were analysed and tested empirically by means of Structural Equation Modelling (SEM). The determinants that were identified through a review of the literature as influencing the success of managing revenue for beneficiary communities of renewable energy companies in South Africa included: the use of outside advice, strategic financial services, strategic planning, strategic partnerships, infrastructure development and project management. In order to achieve the objective, the following research questions were formulated: What is the influence of external factors such as outside advisers and support services on the perceived success of managing revenue for beneficiary communities of renewable energy companies in South Africa? The purpose of this research, therefore, was to evaluate and recommend new methodologies to the renewable energy sector by introducing a model of perceived success in managing revenue for beneficiary communities of renewable energy companies in South Africa. The study provided new insight into managing revenue for beneficiary communities in RSA. With the renewable energy sector being one of the fastest growing sectors in the RSA, and the RSA Government being determined to link the location of renewable energy facilities to economic development, this research has given new insight into managing revenue for SED and ED. The objectives of multi-sector participation, transformational change and sustainable initiatives for beneficiary communities could ensure greater consideration and care when managing beneficiary revenue. Thereby, the opportunity presented by the RE industry for beneficiary communities can change these communities dramatically for the better. The study makes a valuable contribution to the body of knowledge about managing revenue for beneficiary communities. The proposed model has led to a better understanding of the determinants that influence the success of managing revenue for beneficiary communities, namely: distinctive benefits (a combination of two variables: outside advice and support services), financial management, developmental benefits (a combination of two variables: infrastructure development and education), human development, project management and strategic planning. The study has also opened up new avenues of research into this subject.
- Full Text:
- Date Issued: 2017