Exploring the perceptions and attitudes of University of Fort Hare students towards seeking psychological counselling services
- Authors: Pantshwa, Siziphiwe
- Date: 2022-09
- Subjects: Counseling , Helping behavior , Psychology, Applied
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23809 , vital:60807
- Description: The purpose of this study was to explore and examine the perceptions and attitudes of Fort Hare students towards seeking psychological help. It provided an understanding of factors that influence the help-seeking behaviours of university students. The study used an explorative qualitative approach in collecting data to find problems frequently encountered by students, their preferred sources of help for those problems, and their attitudes towards seeking psychological help. The sample was selected through a non-probability convenience sampling technique. Six participants, undergraduate and post-graduate students from the University of Fort Hare, East London campus, participated in the study. The data was collected in face-to-face semi-structured individual interviews in which participants were questioned orally. The interviews were recorded and transcribed verbatim. Data collected from the semi-structured interviews were thematically analysed by employing Braun and Clarke’s six steps of thematic analysis. Social constructionism as a meta-theory and Ecosystems theory provided the theoretical underpinning for the interpretation of the study. The study results revealed that close friends and family members were the preferred sources of help chosen by students. Five significant problems were experienced by students. Financial issues, difficulty adjusting to the university environment, academic stress, being away from home and managing time were at the top list of the challenges experienced by students. The factors that inhibited -seeking for psychological help were social stigma, access to a psychologist, financial constraints, and viewing a psychologist as a stranger. However the study further found that students had a positive attitude toward professional psychological help. This indicates a slight shift from previous studies, which reported negative attitudes among university students. Participants also reported on the influence of their socio-cultural background, the opinions held by their family and community members towards seeking psychological help. This study recommends specific interventions in which seeking psychological help can be reinforced, such as holding workshops to psycho-educate students about the benefits of using counselling services and the negative implications of not seeking professional help when experiencing psychological distress. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2022
- Full Text:
- Date Issued: 2022-09
- Authors: Pantshwa, Siziphiwe
- Date: 2022-09
- Subjects: Counseling , Helping behavior , Psychology, Applied
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/23809 , vital:60807
- Description: The purpose of this study was to explore and examine the perceptions and attitudes of Fort Hare students towards seeking psychological help. It provided an understanding of factors that influence the help-seeking behaviours of university students. The study used an explorative qualitative approach in collecting data to find problems frequently encountered by students, their preferred sources of help for those problems, and their attitudes towards seeking psychological help. The sample was selected through a non-probability convenience sampling technique. Six participants, undergraduate and post-graduate students from the University of Fort Hare, East London campus, participated in the study. The data was collected in face-to-face semi-structured individual interviews in which participants were questioned orally. The interviews were recorded and transcribed verbatim. Data collected from the semi-structured interviews were thematically analysed by employing Braun and Clarke’s six steps of thematic analysis. Social constructionism as a meta-theory and Ecosystems theory provided the theoretical underpinning for the interpretation of the study. The study results revealed that close friends and family members were the preferred sources of help chosen by students. Five significant problems were experienced by students. Financial issues, difficulty adjusting to the university environment, academic stress, being away from home and managing time were at the top list of the challenges experienced by students. The factors that inhibited -seeking for psychological help were social stigma, access to a psychologist, financial constraints, and viewing a psychologist as a stranger. However the study further found that students had a positive attitude toward professional psychological help. This indicates a slight shift from previous studies, which reported negative attitudes among university students. Participants also reported on the influence of their socio-cultural background, the opinions held by their family and community members towards seeking psychological help. This study recommends specific interventions in which seeking psychological help can be reinforced, such as holding workshops to psycho-educate students about the benefits of using counselling services and the negative implications of not seeking professional help when experiencing psychological distress. , Thesis (MSoc) -- Faculty of Social Sciences and Humanities, 2022
- Full Text:
- Date Issued: 2022-09
Formulation development and in vitro evaluation of didanosine-loaded nanostructured lipid carriers for the potential treatment of AIDS dementia complex
- Wa Kasongo, Kasongo, Shegokar, Ranjita, Müller, Rainer H, Walker, Roderick B
- Authors: Wa Kasongo, Kasongo , Shegokar, Ranjita , Müller, Rainer H , Walker, Roderick B
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184210 , vital:44190 , xlink:href="https://doi.org/10.3109/03639045.2010.516264"
- Description: The purpose of this article was to investigate the feasibility of incorporating didanosine (DDI) into nanostructured lipid carriers (NLC) for potential treatment of AIDS dementia complex. Aqueous DDI-free and DDI-loaded NLC were manufactured using hot high-pressure homogenization. The lipid matrix contained a mixture of Precirol ® ATO 5 and Transcutol ® HP. Photon correlation spectroscopy revealed that the mean particle size for all formulations was below 250 nm with narrow polydispersity indices. In addition, the d99% values for all formulations determined using laser diffractometry were below 400 nm with the span values ranging from 0.84 to 1.0. The zeta potential values ranged from −18.4 to −11.4 mV and the encapsulation efficiency of NLC for DDI ranged from 33.02% to 78.34%. These parameters remained relatively constant for all formulations tested following storage for 2 months at 25°C indicating that all the formulations were relatively stable. Differential scanning calorimetry revealed a decrease in the degree of crystallinity of NLC in all formulations developed relative to the bulk lipid material. In addition, wide-angle X-ray scattering showed that NLC in all formulations tested existed in a single β-modification form and that DDI that had been incorporated into the NLC appeared to be molecularly dispersed in the lipid matrices. Images of the NLC formulations obtained using transmission electron microscopy revealed that all formulations contained a mixture of spherical and nonspherical particles irrespective of the amount of DDI that was added during the manufacture of the formulations.
- Full Text:
- Date Issued: 2011
- Authors: Wa Kasongo, Kasongo , Shegokar, Ranjita , Müller, Rainer H , Walker, Roderick B
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184210 , vital:44190 , xlink:href="https://doi.org/10.3109/03639045.2010.516264"
- Description: The purpose of this article was to investigate the feasibility of incorporating didanosine (DDI) into nanostructured lipid carriers (NLC) for potential treatment of AIDS dementia complex. Aqueous DDI-free and DDI-loaded NLC were manufactured using hot high-pressure homogenization. The lipid matrix contained a mixture of Precirol ® ATO 5 and Transcutol ® HP. Photon correlation spectroscopy revealed that the mean particle size for all formulations was below 250 nm with narrow polydispersity indices. In addition, the d99% values for all formulations determined using laser diffractometry were below 400 nm with the span values ranging from 0.84 to 1.0. The zeta potential values ranged from −18.4 to −11.4 mV and the encapsulation efficiency of NLC for DDI ranged from 33.02% to 78.34%. These parameters remained relatively constant for all formulations tested following storage for 2 months at 25°C indicating that all the formulations were relatively stable. Differential scanning calorimetry revealed a decrease in the degree of crystallinity of NLC in all formulations developed relative to the bulk lipid material. In addition, wide-angle X-ray scattering showed that NLC in all formulations tested existed in a single β-modification form and that DDI that had been incorporated into the NLC appeared to be molecularly dispersed in the lipid matrices. Images of the NLC formulations obtained using transmission electron microscopy revealed that all formulations contained a mixture of spherical and nonspherical particles irrespective of the amount of DDI that was added during the manufacture of the formulations.
- Full Text:
- Date Issued: 2011
Factors that influence customers’ spaza shopping experience
- Authors: Yase, Tembelihle
- Date: 2022-04
- Subjects: Home-based businesses--South Africa-Port Elizabeth
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55780 , vital:53877
- Description: Spaza shops, originating in South Africa during the 1970’s, often operate in townships, selling products and services to customers who live mostly within walking distance of the shop. Almost five decades later, and spaza shops abound across most townships in South Africa. These businesses not only provide grocery items and services to customers in the township community but are a means for people to earn a livelihood for themselves and also contribute economically through creating employment opportunities in the informal sector. Research about spaza shops shows that there is a growing customer interest in purchasing products and services from spaza shops, and that if spaza shops are to continue growing, they need to be more competitive. Research by renowned authors in the field of experience marketing, Pine and Gilmore (2013) puts forward that experiences are the new relevant economic offering, and an essential value creating platform for businesses to be more competitive. However, before customer experience can be enhanced in spaza shops, it is important to first identify the factors that influence customer experience in a spaza shop context. Considering the latter, the primary objective of this study was to measure factors that influence customer experience in spaza shops. A descriptive research design was selected for this study, followed by a positivistic research paradigm and quantitative research methodology. Secondary data was collected through articles, journals, books and from newspapers. Primary data was collected using a survey in the form of a self-administered questionnaire. The target population for this study was customers who are older than 18 years, who had bought grocery items (products and services) in spaza shops located in Nelson Mandela Bay townships specifically in Walmer Township, KwaZakhele, Zwide, Motherwell, KwaMagxaki and New Brighton. A non-probability sampling method and convenience sampling technique were used to distribute a total of 200 selfadministered questionnaires. Once the data collection phase was completed, the data from the questionnaires was recorded, coded, and cleaned on a single excel spreadsheet. After the latter was done, a total of 185 questionnaires were deemed useable and considered for data analysis, which was conducted with the aid of IBM SPSS Statistics version 27 (computer software). , Thesis (MCom) -- Faculty of Business and Economic Sciences, School of Management Sciences, 2022
- Full Text:
- Date Issued: 2022-04
- Authors: Yase, Tembelihle
- Date: 2022-04
- Subjects: Home-based businesses--South Africa-Port Elizabeth
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55780 , vital:53877
- Description: Spaza shops, originating in South Africa during the 1970’s, often operate in townships, selling products and services to customers who live mostly within walking distance of the shop. Almost five decades later, and spaza shops abound across most townships in South Africa. These businesses not only provide grocery items and services to customers in the township community but are a means for people to earn a livelihood for themselves and also contribute economically through creating employment opportunities in the informal sector. Research about spaza shops shows that there is a growing customer interest in purchasing products and services from spaza shops, and that if spaza shops are to continue growing, they need to be more competitive. Research by renowned authors in the field of experience marketing, Pine and Gilmore (2013) puts forward that experiences are the new relevant economic offering, and an essential value creating platform for businesses to be more competitive. However, before customer experience can be enhanced in spaza shops, it is important to first identify the factors that influence customer experience in a spaza shop context. Considering the latter, the primary objective of this study was to measure factors that influence customer experience in spaza shops. A descriptive research design was selected for this study, followed by a positivistic research paradigm and quantitative research methodology. Secondary data was collected through articles, journals, books and from newspapers. Primary data was collected using a survey in the form of a self-administered questionnaire. The target population for this study was customers who are older than 18 years, who had bought grocery items (products and services) in spaza shops located in Nelson Mandela Bay townships specifically in Walmer Township, KwaZakhele, Zwide, Motherwell, KwaMagxaki and New Brighton. A non-probability sampling method and convenience sampling technique were used to distribute a total of 200 selfadministered questionnaires. Once the data collection phase was completed, the data from the questionnaires was recorded, coded, and cleaned on a single excel spreadsheet. After the latter was done, a total of 185 questionnaires were deemed useable and considered for data analysis, which was conducted with the aid of IBM SPSS Statistics version 27 (computer software). , Thesis (MCom) -- Faculty of Business and Economic Sciences, School of Management Sciences, 2022
- Full Text:
- Date Issued: 2022-04
Synthesis and evaluation of the medicinal potential of novel 4-hydroxycoumarin derivatives
- Authors: Manyeruke, Meloddy Hlatini
- Date: 2022-04-08
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/164458 , vital:41120 , doi:10.21504/10962/164458
- Description: This research has focused on the synthesis and biological evaluation of a broad range of compounds characterised by the presence of the pharmacologically significant 4-hydroxycoumalin scaffold. The compounds were designed to contain additional pharmachophoric centres to enhance bioactivity and generate lead compounds with dualaction potential. The use of 4-hydroxycoumarin as the primary synthon enabled access to various series of 4-hydroxycoumarin conjugates, the reactive 3-position on the 4-hydroxycoumarin moiety being exploited for regioselective construction of the targeted compounds in several steps. Some of the reactants required in the construction of these compounds were specially synthesised and included propargyloxy benzaldehydes, benzyloxy benzaldehydes and 2,3-dihydroxysuccino-dihydride. Overall, eight different families of novel compounds were accessed, comprising conjugates of 4-hydroxycoumarin with bisethylidenesuccinohyrazide, trifluoroacetamide, amino, benzyloxyphenyl-iminoethyl, benzylidenehyrazinyl-thiazoyl, benzylidenehydrazonoethyl, propargyloxybenzylidenehydrazonoethyl and phenylacryloyl moieties using protocols that required minimal work-up and purification. The eighty novel compounds synthesised in the study were fully characterised using HMRS and advanced NMR techniques. Cytotoxicity, HIV-1 IN and PR inhibitory, and antitrypanosomal, antimalarial and anti-Mtb assays were conducted on the synthesised coumarin derivatives. Several compounds exhibited activity against HIV-1 IN, the most potent being a bis-ethylidenesuccinohyrazide with an IC50 value of 3.5 μM. Various compounds exhibited anti-malarial activity (% pLDH viability in the range 62-77%), anti-trypanosomal activity (the most potent with an IC50 = 0.9 μM against T.b. brucei) and a measure of anti-Mtb activity. Apart from two chalconyl derivatives, none of the synthesised compounds exhibited significant cytotoxicity. Conflicting results were obtained from the in silico docking studies; in some cases supporting the observed in vitro assay data while, in others, exhibiting no correlation. , Thesis (PhD) -- Faculty of Science, Chemistry, 2020
- Full Text:
- Date Issued: 2022-04-08
- Authors: Manyeruke, Meloddy Hlatini
- Date: 2022-04-08
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/164458 , vital:41120 , doi:10.21504/10962/164458
- Description: This research has focused on the synthesis and biological evaluation of a broad range of compounds characterised by the presence of the pharmacologically significant 4-hydroxycoumalin scaffold. The compounds were designed to contain additional pharmachophoric centres to enhance bioactivity and generate lead compounds with dualaction potential. The use of 4-hydroxycoumarin as the primary synthon enabled access to various series of 4-hydroxycoumarin conjugates, the reactive 3-position on the 4-hydroxycoumarin moiety being exploited for regioselective construction of the targeted compounds in several steps. Some of the reactants required in the construction of these compounds were specially synthesised and included propargyloxy benzaldehydes, benzyloxy benzaldehydes and 2,3-dihydroxysuccino-dihydride. Overall, eight different families of novel compounds were accessed, comprising conjugates of 4-hydroxycoumarin with bisethylidenesuccinohyrazide, trifluoroacetamide, amino, benzyloxyphenyl-iminoethyl, benzylidenehyrazinyl-thiazoyl, benzylidenehydrazonoethyl, propargyloxybenzylidenehydrazonoethyl and phenylacryloyl moieties using protocols that required minimal work-up and purification. The eighty novel compounds synthesised in the study were fully characterised using HMRS and advanced NMR techniques. Cytotoxicity, HIV-1 IN and PR inhibitory, and antitrypanosomal, antimalarial and anti-Mtb assays were conducted on the synthesised coumarin derivatives. Several compounds exhibited activity against HIV-1 IN, the most potent being a bis-ethylidenesuccinohyrazide with an IC50 value of 3.5 μM. Various compounds exhibited anti-malarial activity (% pLDH viability in the range 62-77%), anti-trypanosomal activity (the most potent with an IC50 = 0.9 μM against T.b. brucei) and a measure of anti-Mtb activity. Apart from two chalconyl derivatives, none of the synthesised compounds exhibited significant cytotoxicity. Conflicting results were obtained from the in silico docking studies; in some cases supporting the observed in vitro assay data while, in others, exhibiting no correlation. , Thesis (PhD) -- Faculty of Science, Chemistry, 2020
- Full Text:
- Date Issued: 2022-04-08
Assessing the technologies transforming the logistics Industry in Nelson Mandela Bay
- Authors: Ruiters, Byron
- Date: 2022-04
- Subjects: Business logistics -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/58168 , vital:58616
- Description: Supply chain disruptions such as those emanating from the current Covid 19 pandemic have made the logistics industry to undergo fast and unprecedented change. In such unpredictable times, innovation and technology adoption has emerged as one of the major trends and key solutions to lead the way for the future of logistics. This is also because a successful and efficient logistics strategy requires the use of technology, as well as the strategic value derived from a firm's capacity. This in turn enables firms to recognise possibilities and challenges resulting from technological advancement in order to attain long-term competitiveness. The industry is implementing these technologies with caution in order to provide faster, cheaper, more dependable and long-term supply. This study sought to investigate whether Nelson Mandela Bay (NMB) is keeping up with the current logistics technology trends and systems that are transforming logistics firms in South Africa, the African continent and the rest of the world. To achieve this primary objective, the study also sought to achieve the following sub-objectives, namely: to identify the logistics technologies transforming logistics firms in NMB; to assess the role of logistics technologies affecting logistics firms in NMB. The study also sought to ascertain the challenges of using logistics technologies transforming the logistics firms in NMB; and examine the effect of logistics technology adoption and use on business performance of logistics firms in NMB. The study used an online closed-ended questionnaire distributed via google forms to collect primary data from a sample of 132 respondents across all the logistics firms (which consisted of warehousing, transport and packaging firms) in NMB. The study targeted those respondents involved in the management of the targeted logistics firms. The empirical results show that technology use in logistics firms has advanced a lot to vehicle tracking, packaging, inventory control, and communication systems, as well as robotics among logistics firms in NMB. The results also identified logistics technologies such as the Internet of Things, Robotic Process automation, Digital Supply Chain Twins, Vendor managed system and RFID as some of the major technologies currently transforming the logistics firms in NMB. The study found that many challenges exist with logistics technology adoption, and cited lack of investment towards logistics technology; the fear of iii losing jobs as people get replaced by technology such as machines and robots; high logistics costs as some of the major challenges. More so, the study results reveal that logistics technology adoption and use play a positive and significant role in logistics firms. The study further reports a significant and positive effect of logistics technology adoption and use on business performance of logistics firms. This study concludes that though still at infancy stage, logistics firms in NMB are keeping upbreast with the current logistics technological trends. The study suggests that firms need to speed up the adoption of the needed logistics technologies available to their respective business in order to remain efficient and effective. , Thesis (MA) --Faculty of Business and Economic science, 2022
- Full Text:
- Date Issued: 2022-04
- Authors: Ruiters, Byron
- Date: 2022-04
- Subjects: Business logistics -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/58168 , vital:58616
- Description: Supply chain disruptions such as those emanating from the current Covid 19 pandemic have made the logistics industry to undergo fast and unprecedented change. In such unpredictable times, innovation and technology adoption has emerged as one of the major trends and key solutions to lead the way for the future of logistics. This is also because a successful and efficient logistics strategy requires the use of technology, as well as the strategic value derived from a firm's capacity. This in turn enables firms to recognise possibilities and challenges resulting from technological advancement in order to attain long-term competitiveness. The industry is implementing these technologies with caution in order to provide faster, cheaper, more dependable and long-term supply. This study sought to investigate whether Nelson Mandela Bay (NMB) is keeping up with the current logistics technology trends and systems that are transforming logistics firms in South Africa, the African continent and the rest of the world. To achieve this primary objective, the study also sought to achieve the following sub-objectives, namely: to identify the logistics technologies transforming logistics firms in NMB; to assess the role of logistics technologies affecting logistics firms in NMB. The study also sought to ascertain the challenges of using logistics technologies transforming the logistics firms in NMB; and examine the effect of logistics technology adoption and use on business performance of logistics firms in NMB. The study used an online closed-ended questionnaire distributed via google forms to collect primary data from a sample of 132 respondents across all the logistics firms (which consisted of warehousing, transport and packaging firms) in NMB. The study targeted those respondents involved in the management of the targeted logistics firms. The empirical results show that technology use in logistics firms has advanced a lot to vehicle tracking, packaging, inventory control, and communication systems, as well as robotics among logistics firms in NMB. The results also identified logistics technologies such as the Internet of Things, Robotic Process automation, Digital Supply Chain Twins, Vendor managed system and RFID as some of the major technologies currently transforming the logistics firms in NMB. The study found that many challenges exist with logistics technology adoption, and cited lack of investment towards logistics technology; the fear of iii losing jobs as people get replaced by technology such as machines and robots; high logistics costs as some of the major challenges. More so, the study results reveal that logistics technology adoption and use play a positive and significant role in logistics firms. The study further reports a significant and positive effect of logistics technology adoption and use on business performance of logistics firms. This study concludes that though still at infancy stage, logistics firms in NMB are keeping upbreast with the current logistics technological trends. The study suggests that firms need to speed up the adoption of the needed logistics technologies available to their respective business in order to remain efficient and effective. , Thesis (MA) --Faculty of Business and Economic science, 2022
- Full Text:
- Date Issued: 2022-04
The effects of carbon nanotubes on the electrocatalysis of hydrogen peroxide by metallo-phthalocyanines
- Mashazi, Philani N, Mugadza, Tawanda, Sosibo, Ndabenhle, Mdluli, Phumlani, Vilakazi, Sibulelo, Nyokong, Tebello
- Authors: Mashazi, Philani N , Mugadza, Tawanda , Sosibo, Ndabenhle , Mdluli, Phumlani , Vilakazi, Sibulelo , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247174 , vital:51553 , xlink:href="https://doi.org/10.1016/j.talanta.2011.07.069"
- Description: The pre-grafted screen-printed gold electrode modified with phenyl-amino monolayer was investigated for covalent immobilization of phenyl-amine functionalized single-walled carbon nanotubes (PA-SWCNT) and metal tetra-amino phthalocyanine (MTAPc) using Schiff-base reactions with benzene-1,4-dicarbaldehyde (BDCA) as cross-linker. The PA-SWCNT and MTAPc modified electrodes were applied as hybrids for electrochemical sensing of H2O2. The step-by-step fabrication of the electrode was followed using electrochemistry, impedance spectroscopy, scanning electron microscopy and Raman spectroscopy and all these techniques confirmed the fabrication and the immobilization of PA-SWCNT, MnTAPc and CoTAPc onto gold surfaces. The apparent electron transfer constant (kapp) showed that the carbon nanotubes and metallo-phthalocyanines hybrids possess good electron transfer properties compared to the bare, pre-grafted and the MTAPc modified gold electrode surfaces without PA-SWCNT. The electrochemical sensing of hydrogen peroxide was successful with PA-SWCNT–MTAPc hybrid systems showing higher electrocatalytic currents compared to the other electrodes. The analytical parameters obtained using chronoamperometry gave good linearity at H2O2 concentrations ranging from 1.0 to 30.0 μmol L−1. The values for the limit of detection (LoD) were found to be of the orders of 10−7 M using the 3δ for all the electrodes. The PA-SWCNT–MTAPc modified SPAuEs were much more sensitive compared to PA–MTAPc modified SPAuEs.
- Full Text:
- Date Issued: 2011
- Authors: Mashazi, Philani N , Mugadza, Tawanda , Sosibo, Ndabenhle , Mdluli, Phumlani , Vilakazi, Sibulelo , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247174 , vital:51553 , xlink:href="https://doi.org/10.1016/j.talanta.2011.07.069"
- Description: The pre-grafted screen-printed gold electrode modified with phenyl-amino monolayer was investigated for covalent immobilization of phenyl-amine functionalized single-walled carbon nanotubes (PA-SWCNT) and metal tetra-amino phthalocyanine (MTAPc) using Schiff-base reactions with benzene-1,4-dicarbaldehyde (BDCA) as cross-linker. The PA-SWCNT and MTAPc modified electrodes were applied as hybrids for electrochemical sensing of H2O2. The step-by-step fabrication of the electrode was followed using electrochemistry, impedance spectroscopy, scanning electron microscopy and Raman spectroscopy and all these techniques confirmed the fabrication and the immobilization of PA-SWCNT, MnTAPc and CoTAPc onto gold surfaces. The apparent electron transfer constant (kapp) showed that the carbon nanotubes and metallo-phthalocyanines hybrids possess good electron transfer properties compared to the bare, pre-grafted and the MTAPc modified gold electrode surfaces without PA-SWCNT. The electrochemical sensing of hydrogen peroxide was successful with PA-SWCNT–MTAPc hybrid systems showing higher electrocatalytic currents compared to the other electrodes. The analytical parameters obtained using chronoamperometry gave good linearity at H2O2 concentrations ranging from 1.0 to 30.0 μmol L−1. The values for the limit of detection (LoD) were found to be of the orders of 10−7 M using the 3δ for all the electrodes. The PA-SWCNT–MTAPc modified SPAuEs were much more sensitive compared to PA–MTAPc modified SPAuEs.
- Full Text:
- Date Issued: 2011
The meanings of the social media practices of African women engaged in multi-level marketing in Makhanda
- Authors: Tembani, Khuselwa Anda
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365588 , vital:65762
- Description: In their efforts for a place in the economy, many South African women have embraced opportunities in the informal sector such as selling products for big Multi-Level Marketers (MLMs), who generally operate on a pyramid structure of commissions. This qualitative study investigates the meanings African women engaged in MLMs in Makhanda make of such work and examines how they construct notions of progress and success through their social media practices. The study was conducted in the strictest lockdown period and pioneered a research method that used Zoom to facilitate screen sharing on mobile phones to create an online version of the scroll-back method for Facebook. As expected for women working in a society increasingly integrated in a global neoliberal order, many of the meanings the women construct are rooted in neoliberal discourses that celebrate hyper-individualism and competition. This firstly includes constructing success through personal stories of self-appreciation, through which these women embody the MLM’s brand, while simultaneously improving their position in the market as sellers. Secondly, the women invest considerable effort on social media in constructing MLM work as epitomising stability in the context of the growing precarity that characterises their everyday lives. However, other meanings draw on the local African context. Here the women make sense of the inequalities that characterise the MLM pyramid structures, by constructing top players in the upline as a symbolic vanguard trailblazing freedom from a racist past through showcasing paths out of poverty. More interestingly, success is constructed as both resulting from and serving collective ways of being rooted in the discourse of African humanism. Here success is recognised as emerging from dense place-based networks in the neighbourhood built on trust and obligation, now replicated on social media. In conclusion, the study speculates that the worlds of meaning facilitated by MLMs might provide ways for neoliberal and traditional discourses to find points of synergy, and so serve as entry points into a neoliberal order that interestingly nevertheless draws on communal cultures of obligation and patronage. , Thesis (MA) -- Faculty of Humanities, School of Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Tembani, Khuselwa Anda
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/365588 , vital:65762
- Description: In their efforts for a place in the economy, many South African women have embraced opportunities in the informal sector such as selling products for big Multi-Level Marketers (MLMs), who generally operate on a pyramid structure of commissions. This qualitative study investigates the meanings African women engaged in MLMs in Makhanda make of such work and examines how they construct notions of progress and success through their social media practices. The study was conducted in the strictest lockdown period and pioneered a research method that used Zoom to facilitate screen sharing on mobile phones to create an online version of the scroll-back method for Facebook. As expected for women working in a society increasingly integrated in a global neoliberal order, many of the meanings the women construct are rooted in neoliberal discourses that celebrate hyper-individualism and competition. This firstly includes constructing success through personal stories of self-appreciation, through which these women embody the MLM’s brand, while simultaneously improving their position in the market as sellers. Secondly, the women invest considerable effort on social media in constructing MLM work as epitomising stability in the context of the growing precarity that characterises their everyday lives. However, other meanings draw on the local African context. Here the women make sense of the inequalities that characterise the MLM pyramid structures, by constructing top players in the upline as a symbolic vanguard trailblazing freedom from a racist past through showcasing paths out of poverty. More interestingly, success is constructed as both resulting from and serving collective ways of being rooted in the discourse of African humanism. Here success is recognised as emerging from dense place-based networks in the neighbourhood built on trust and obligation, now replicated on social media. In conclusion, the study speculates that the worlds of meaning facilitated by MLMs might provide ways for neoliberal and traditional discourses to find points of synergy, and so serve as entry points into a neoliberal order that interestingly nevertheless draws on communal cultures of obligation and patronage. , Thesis (MA) -- Faculty of Humanities, School of Journalism and Media Studies, 2022
- Full Text:
- Date Issued: 2022-10-14
A comparative study of the singlet oxygen generation capability of a zinc phthalocyanine linked to graphene quantum dots through π-π stacking and covalent conjugation when embedded in asymmetric polymer membranes
- Mafukidze, Donovan M, Nyokong, Tebello
- Authors: Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187461 , vital:44655 , xlink:href="https://doi.org/10.1016/j.molstruc.2018.11.096"
- Description: Following the establishment of graphene quantum dots as potential phthalocyanine supports in photoactive membrane preparation for phthalocyanines lacking linkage functional groups, the practical efficiency of p-p stacking versus covalent linkage was investigated. Synthesized materials were characterized using FT-IR, Raman, powder X-ray diffraction, and UVeVis spectroscopies and also by transmission electron and scanning electron microscopies. Phthalocyanine loadings onto graphene quantum dots of 0.40 mg/mg and 0.14 mg/mg (Pc mass/conjugate mass) for the p-p stacked and covalent linked conjugates respectively were observed. Covalent linkage to graphene quantum dots proved to be functionally superior to p-p linkage, where singlet oxygen quantum yield value of the phthalocyanine in the membrane for the covalent linked conjugate was approximately twice that of the p-p stacked membrane.
- Full Text:
- Date Issued: 2019
- Authors: Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187461 , vital:44655 , xlink:href="https://doi.org/10.1016/j.molstruc.2018.11.096"
- Description: Following the establishment of graphene quantum dots as potential phthalocyanine supports in photoactive membrane preparation for phthalocyanines lacking linkage functional groups, the practical efficiency of p-p stacking versus covalent linkage was investigated. Synthesized materials were characterized using FT-IR, Raman, powder X-ray diffraction, and UVeVis spectroscopies and also by transmission electron and scanning electron microscopies. Phthalocyanine loadings onto graphene quantum dots of 0.40 mg/mg and 0.14 mg/mg (Pc mass/conjugate mass) for the p-p stacked and covalent linked conjugates respectively were observed. Covalent linkage to graphene quantum dots proved to be functionally superior to p-p linkage, where singlet oxygen quantum yield value of the phthalocyanine in the membrane for the covalent linked conjugate was approximately twice that of the p-p stacked membrane.
- Full Text:
- Date Issued: 2019
DSC screening of potential prochlorperazine-excipient interactions in preformulation studies
- Brown, Michael E, Antunes, Edith M, Glass, Beverley M, Lebete, Mosimotsana L, Walker, Roderick B
- Authors: Brown, Michael E , Antunes, Edith M , Glass, Beverley M , Lebete, Mosimotsana L , Walker, Roderick B
- Date: 1999
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184367 , vital:44212 , xlink:href="https://doi.org/10.1023/A:1010150305542"
- Description: Differential scanning calorimetry was used to examine the thermal behaviour of mixtures of the drug prochlorperazine with standard excipients, to assess potential interactions, and of mixtures with cyclodextrins, to investigate inclusion complexation which could increase the photostability of the drug. For most of the excipients (magnesium stearate, stearic acid, Explotab®, Ac-Di-Sol®, Encompress® and Ludipress®, lactose and Starch 1500) disappearance or broadening of the melting endotherm of the drug indicated interactions. Lubritab® was the only 'inert' excipient tested. Mixtures of prochlorperazine and the cyclodextrins gave incomplete inclusion complexation as shown by only partial disappearance of the melting endotherm of the drug.
- Full Text: false
- Date Issued: 1999
- Authors: Brown, Michael E , Antunes, Edith M , Glass, Beverley M , Lebete, Mosimotsana L , Walker, Roderick B
- Date: 1999
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184367 , vital:44212 , xlink:href="https://doi.org/10.1023/A:1010150305542"
- Description: Differential scanning calorimetry was used to examine the thermal behaviour of mixtures of the drug prochlorperazine with standard excipients, to assess potential interactions, and of mixtures with cyclodextrins, to investigate inclusion complexation which could increase the photostability of the drug. For most of the excipients (magnesium stearate, stearic acid, Explotab®, Ac-Di-Sol®, Encompress® and Ludipress®, lactose and Starch 1500) disappearance or broadening of the melting endotherm of the drug indicated interactions. Lubritab® was the only 'inert' excipient tested. Mixtures of prochlorperazine and the cyclodextrins gave incomplete inclusion complexation as shown by only partial disappearance of the melting endotherm of the drug.
- Full Text: false
- Date Issued: 1999
Effectiveness of housing delivery in the Reconstruction and Development Programme in Duncan Village
- Authors: Millie, Lindile Churchill
- Date: 2012
- Subjects: Housing development -- South Africa , Public housing -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24199 , vital:62441
- Description: The primary objective of this study was to determine the effectiveness of Housing delivery in the Reconstruction and Development Programme in Duncan Village. This thesis has tried to answer to why there are still places like Duncan Village, situated at the heart of Buffalo City Metropolitan Local Municipality, in the Eastern Cape Province with alarming rate at which the “shanty resident” has been growing and showing no signs of coming to an end? The researcher used both qualitative and quantitative approaches in this research. The researcher conducted the research using officials from the Department of Human Settlements, officials from Buffalo City Metropolitan Municipality, Ward Councillor, and Duncan Village community. , Thesis (MPA) -- Faculty of Management and Commerce, 2012
- Full Text:
- Date Issued: 2012
- Authors: Millie, Lindile Churchill
- Date: 2012
- Subjects: Housing development -- South Africa , Public housing -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24199 , vital:62441
- Description: The primary objective of this study was to determine the effectiveness of Housing delivery in the Reconstruction and Development Programme in Duncan Village. This thesis has tried to answer to why there are still places like Duncan Village, situated at the heart of Buffalo City Metropolitan Local Municipality, in the Eastern Cape Province with alarming rate at which the “shanty resident” has been growing and showing no signs of coming to an end? The researcher used both qualitative and quantitative approaches in this research. The researcher conducted the research using officials from the Department of Human Settlements, officials from Buffalo City Metropolitan Municipality, Ward Councillor, and Duncan Village community. , Thesis (MPA) -- Faculty of Management and Commerce, 2012
- Full Text:
- Date Issued: 2012
Linking agrochemical pollution with the aquatic ecological integrity of the Twee River Catchment, Western Cape
- Authors: Brink, Zanné
- Date: 2021-04
- Subjects: Gqeberha (South Africa) , Eastern Cape (South Africa) , Ecological integrity
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52326 , vital:43588
- Description: This study was initiated in the Twee River system due to the threat posed by agrochemicals on the occurrence of the endemic and endangered fish species found within the catchment. Poor knowledge and understanding of the environmental effects of fertilizers, pesticides and other agrochemicals among small and large commercial farmers within the study area, in combination with their intensive use may have resulted in chemical contamination above environmentally safe concentrations. Numerous studies have highlighted the fact that more research needs to be conducted to identify the key threats to the continued existence of specifically the Critically Endangered Sedercypris erubescens. The overall aim of this study was to determine the spatial and temporal patterns in aquatic ecosystem diversity in the Twee River catchment as indicated by macroinvertebrate and native fish distribution and abundance. It was further investigated if there was a link between agrochemical pollution and the aquatic ecological integrity of the Twee River catchment. Selected sampling sites were identified and sampled to determine the presence and concentration of pesticides entering the water of the Twee River system during run-off and event-based spraying. Furthermore, the effect of these pesticides on the distribution and abundance of the aquatic biota were determined using SASS5 for the macroinvertebrate populations and visually sampling the distribution of the native and non-native fish in the Twee River catchment. This study supports suggestions made by previous studies, that sub-lethal to lethal concentrations of insecticides could be a threat to the long-term survival of benthic macroinvertebrates and potentially the more sensitive endemic fish species within the Twee River system. More focussed research is needed to address impacts of pesticides within this catchment. Agricultural and conservation efforts should be aimed at developing of a shared vision amongst stakeholders, to allow for the longterm conservation of the endemic fish of the Twee River. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text: false
- Date Issued: 2021-04
- Authors: Brink, Zanné
- Date: 2021-04
- Subjects: Gqeberha (South Africa) , Eastern Cape (South Africa) , Ecological integrity
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/52326 , vital:43588
- Description: This study was initiated in the Twee River system due to the threat posed by agrochemicals on the occurrence of the endemic and endangered fish species found within the catchment. Poor knowledge and understanding of the environmental effects of fertilizers, pesticides and other agrochemicals among small and large commercial farmers within the study area, in combination with their intensive use may have resulted in chemical contamination above environmentally safe concentrations. Numerous studies have highlighted the fact that more research needs to be conducted to identify the key threats to the continued existence of specifically the Critically Endangered Sedercypris erubescens. The overall aim of this study was to determine the spatial and temporal patterns in aquatic ecosystem diversity in the Twee River catchment as indicated by macroinvertebrate and native fish distribution and abundance. It was further investigated if there was a link between agrochemical pollution and the aquatic ecological integrity of the Twee River catchment. Selected sampling sites were identified and sampled to determine the presence and concentration of pesticides entering the water of the Twee River system during run-off and event-based spraying. Furthermore, the effect of these pesticides on the distribution and abundance of the aquatic biota were determined using SASS5 for the macroinvertebrate populations and visually sampling the distribution of the native and non-native fish in the Twee River catchment. This study supports suggestions made by previous studies, that sub-lethal to lethal concentrations of insecticides could be a threat to the long-term survival of benthic macroinvertebrates and potentially the more sensitive endemic fish species within the Twee River system. More focussed research is needed to address impacts of pesticides within this catchment. Agricultural and conservation efforts should be aimed at developing of a shared vision amongst stakeholders, to allow for the longterm conservation of the endemic fish of the Twee River. , Thesis (MSc) -- Faculty of Science, School of Natural Resource Management, 2021
- Full Text: false
- Date Issued: 2021-04
Collaborative learning of water conservation practices: cultivation and expansion of a learning network around rainwater harvesting demonstration sites in the Eastern Cape, South Africa
- Pesanayi, Tichaona V, Weaver, Kim N
- Authors: Pesanayi, Tichaona V , Weaver, Kim N
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/392086 , vital:68720 , xlink:href="https://www.ajol.info/index.php/sajae/article/view/138570"
- Description: Learning together in mediated voluntary networks can mobilise skills and innovations that help to facilitate learning and uptake of rainwater harvesting and conservation practices. It boosts extension capacity while at the same time growing farmer capabilities, tapping on the distributed cognition. These practices help to heal wicked problems of drought and global change challenges affecting marginalised farmers in South Africa. South Africa has water, nutrition and food security challenges, especially the Eastern Cape Province where there is a relatively high level of poverty. These challenges place heavy pressure on the agricultural sector as it is the main user of the allocated water in the country. In this paper, the learning of and agency for rainwater harvesting and conservation practices are explored as responses to these challenges. Despite existing cultural histories of such practices among the amaXhosa people, information on these practices is not readily available to small-scale rural farmers who thus struggle for the want of knowing. This research forms part of a Water Research Commission project, Amanzi for Food, whose intention is to mediate collaborative and co-engaged learning among networked farmers, extension workers, researchers and agricultural educators through course-mediated use of Water Research Commission rainwater harvesting and conservation materials.
- Full Text:
- Date Issued: 2016
- Authors: Pesanayi, Tichaona V , Weaver, Kim N
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/392086 , vital:68720 , xlink:href="https://www.ajol.info/index.php/sajae/article/view/138570"
- Description: Learning together in mediated voluntary networks can mobilise skills and innovations that help to facilitate learning and uptake of rainwater harvesting and conservation practices. It boosts extension capacity while at the same time growing farmer capabilities, tapping on the distributed cognition. These practices help to heal wicked problems of drought and global change challenges affecting marginalised farmers in South Africa. South Africa has water, nutrition and food security challenges, especially the Eastern Cape Province where there is a relatively high level of poverty. These challenges place heavy pressure on the agricultural sector as it is the main user of the allocated water in the country. In this paper, the learning of and agency for rainwater harvesting and conservation practices are explored as responses to these challenges. Despite existing cultural histories of such practices among the amaXhosa people, information on these practices is not readily available to small-scale rural farmers who thus struggle for the want of knowing. This research forms part of a Water Research Commission project, Amanzi for Food, whose intention is to mediate collaborative and co-engaged learning among networked farmers, extension workers, researchers and agricultural educators through course-mediated use of Water Research Commission rainwater harvesting and conservation materials.
- Full Text:
- Date Issued: 2016
Social protection and secondary education in Zimbabwe: the case of Masvingo District in Masvingo Province
- Authors: Mago, David
- Date: 2015-01
- Subjects: Zimbabwe--Economic conditions , Elementary school dropouts , Zimbabwe--Social conditions
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24554 , vital:63170
- Description: The study sought to examine the role of social protection in reducing school dropouts in secondary education in Masvingo District of Zimbabwe. The study was motivated by the idea that despite the social assistance interventions that are in place, the school dropout phenomenon is still continuing among secondary school learners in the Masvingo District. This was achieved by discussing various programmes delivered by Non-Governmental Organisations (NGOs) and the government in reducing the number of school dropouts. The thesis also outlined various economic, social and political depressions that affected secondary education since Zimbabwe’s gaining of independence. From 1962 until 1980 the colonial government catered for the European child, this meant that secondary education was difficult to be accessed by blacks. Education maintained a bottleneck structure that favoured whites more than black people. After gaining independence, the Zimbabwe African Union Patriotic Front (ZANU PF) party introduced laws that allowed the black majority an opportunity to proceed with their education. Over the years the number of school dropouts is still increasing. This was curtailed by the introduction of the Structural Adjustment Programmes (SAPs) in 1991 to 1995. The introduction of the SAPs led to the introduction of user fees in education and health. This raised poverty levels which were curtailed by the macroeconomic situation in Zimbabwe. This was beyond the reach of many and led to the increase of school dropouts in Zimbabwe. The major objective of the study was to assess the effectiveness of social assistance in the reduction of school dropouts in Zimbabwe. The specific objectives are to analyse the role played by social assistance on the provision of secondary education and reduction of school dropouts and examining the impact of assistance on the education of the girl child. The last objective in the study was to identify a more comprehensive social assistance intervention for the support of secondary education. A more comprehensive social assistance intervention is intervention that provides support to secondary learners that includes among them uniforms, transport food and school fees. The study adopted the qualitative research methodology. The qualitative research methodology was used because it seeks to go deeper in what people experience on day to day activities. In-depth information helps to understand the successes and failures faced by NGOs and government in reducing the number of school dropouts. The study looked at how effective government and NGO assistance has been in reducing the number of school dropouts. Today there are a majority of NGOs, private organisations and government programmes that are working in secondary education assistance in Masvingo District. What matters most is that despite the growing rate of assistance by NGOs, individual help and government assistance the number of school dropouts is still increasing. The study’s theoretical framework is based on the Human rights based approach and the Transformative paradigm. The analysis relates to social assistance programmes focusing on the Basic Education Assistance Module (BEAM) and NGOs and their contribution in reducing the number of school dropouts. From the research findings, the research established the way forward that can be used to reduce the rate of school dropouts in Masvingo District and Zimbabwe at large. Lack of school fees, school uniforms, food and transport are the major causes of school dropouts in Masvingo District. The findings of the study revealed that Zimbabwe’s social assistance programmes are not adequate in reducing the number of school dropouts. The way forward that was proposed in the study in that the assistance to children at secondary education should be holistic approach. NGOs and government should work together to educate parents and children on the importance of secondary education. , Thesis (MSoc Dev.) -- Faculty of Management and Commerce, 2015
- Full Text:
- Date Issued: 2015-01
- Authors: Mago, David
- Date: 2015-01
- Subjects: Zimbabwe--Economic conditions , Elementary school dropouts , Zimbabwe--Social conditions
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/24554 , vital:63170
- Description: The study sought to examine the role of social protection in reducing school dropouts in secondary education in Masvingo District of Zimbabwe. The study was motivated by the idea that despite the social assistance interventions that are in place, the school dropout phenomenon is still continuing among secondary school learners in the Masvingo District. This was achieved by discussing various programmes delivered by Non-Governmental Organisations (NGOs) and the government in reducing the number of school dropouts. The thesis also outlined various economic, social and political depressions that affected secondary education since Zimbabwe’s gaining of independence. From 1962 until 1980 the colonial government catered for the European child, this meant that secondary education was difficult to be accessed by blacks. Education maintained a bottleneck structure that favoured whites more than black people. After gaining independence, the Zimbabwe African Union Patriotic Front (ZANU PF) party introduced laws that allowed the black majority an opportunity to proceed with their education. Over the years the number of school dropouts is still increasing. This was curtailed by the introduction of the Structural Adjustment Programmes (SAPs) in 1991 to 1995. The introduction of the SAPs led to the introduction of user fees in education and health. This raised poverty levels which were curtailed by the macroeconomic situation in Zimbabwe. This was beyond the reach of many and led to the increase of school dropouts in Zimbabwe. The major objective of the study was to assess the effectiveness of social assistance in the reduction of school dropouts in Zimbabwe. The specific objectives are to analyse the role played by social assistance on the provision of secondary education and reduction of school dropouts and examining the impact of assistance on the education of the girl child. The last objective in the study was to identify a more comprehensive social assistance intervention for the support of secondary education. A more comprehensive social assistance intervention is intervention that provides support to secondary learners that includes among them uniforms, transport food and school fees. The study adopted the qualitative research methodology. The qualitative research methodology was used because it seeks to go deeper in what people experience on day to day activities. In-depth information helps to understand the successes and failures faced by NGOs and government in reducing the number of school dropouts. The study looked at how effective government and NGO assistance has been in reducing the number of school dropouts. Today there are a majority of NGOs, private organisations and government programmes that are working in secondary education assistance in Masvingo District. What matters most is that despite the growing rate of assistance by NGOs, individual help and government assistance the number of school dropouts is still increasing. The study’s theoretical framework is based on the Human rights based approach and the Transformative paradigm. The analysis relates to social assistance programmes focusing on the Basic Education Assistance Module (BEAM) and NGOs and their contribution in reducing the number of school dropouts. From the research findings, the research established the way forward that can be used to reduce the rate of school dropouts in Masvingo District and Zimbabwe at large. Lack of school fees, school uniforms, food and transport are the major causes of school dropouts in Masvingo District. The findings of the study revealed that Zimbabwe’s social assistance programmes are not adequate in reducing the number of school dropouts. The way forward that was proposed in the study in that the assistance to children at secondary education should be holistic approach. NGOs and government should work together to educate parents and children on the importance of secondary education. , Thesis (MSoc Dev.) -- Faculty of Management and Commerce, 2015
- Full Text:
- Date Issued: 2015-01
The implementation of national health strategy (2009-2013) in Vungu District clinics, Midlands Province in Zimbabwe
- Mangwanya, M G https://orcid.org/0000-0002-0362-5546
- Authors: Mangwanya, M G https://orcid.org/0000-0002-0362-5546
- Date: 2019-08
- Subjects: Medical care -- Zimbabwe
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19914 , vital:44454
- Description: The practice of strategy implementation is key to the public sector in Zimbabwe because it helps the government to be up to speed in providing services to the public. This research focused on the National Health Strategy 2009-2013 and its impact on health service delivery in Vungu Rural District Council Clinics. The research was based on qualitative desk study design which made use of existing data and semi structured interviews to understand the effect of the National Health Strategy on health service delivery in Vungu Rural Districts Council Clinics. From the literature reviewed and the data collected, it can be noted that lack of resources has had a huge effect on the execution of the strategy. The findings from the study show that the National Health Strategy was a good initiative. However, it lacked financial resources which posed challenges to the health workers in Vungu Rural District Council Clinics. The health workers were not very familiar with the National Health Strategy and this had a negative impact on its execution because they cannot execute a strategy that they are not familiar with. The study highlighted the importance of resources for the execution of the National Health Strategy. The study therefore sought to find ways the Zimbabwean Health System may formulate the health strategy with the limited resources in order to achieve desired goals. The Health Workers echoed the same sentiments that they needed resources for the implementation of the strategy. It is hoped that the findings would provide guidelines for the formulation and implementation of future health strategies. Recommendations given would ensure that there is utilisation of available resources, which would help in the execution of other health strategies to ensure efficient and effective health care service delivery. The recommendations are also intended to enhance the performance of health workers. Though the study was limited to Vungu Rural District Council Clinics the findings and recommendations would provide guidelines for other rural clinics as they use the National Health Strategy. , Thesis (PhD) -- Faculty of Management and Commerce, 2019
- Full Text:
- Date Issued: 2019-08
- Authors: Mangwanya, M G https://orcid.org/0000-0002-0362-5546
- Date: 2019-08
- Subjects: Medical care -- Zimbabwe
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/19914 , vital:44454
- Description: The practice of strategy implementation is key to the public sector in Zimbabwe because it helps the government to be up to speed in providing services to the public. This research focused on the National Health Strategy 2009-2013 and its impact on health service delivery in Vungu Rural District Council Clinics. The research was based on qualitative desk study design which made use of existing data and semi structured interviews to understand the effect of the National Health Strategy on health service delivery in Vungu Rural Districts Council Clinics. From the literature reviewed and the data collected, it can be noted that lack of resources has had a huge effect on the execution of the strategy. The findings from the study show that the National Health Strategy was a good initiative. However, it lacked financial resources which posed challenges to the health workers in Vungu Rural District Council Clinics. The health workers were not very familiar with the National Health Strategy and this had a negative impact on its execution because they cannot execute a strategy that they are not familiar with. The study highlighted the importance of resources for the execution of the National Health Strategy. The study therefore sought to find ways the Zimbabwean Health System may formulate the health strategy with the limited resources in order to achieve desired goals. The Health Workers echoed the same sentiments that they needed resources for the implementation of the strategy. It is hoped that the findings would provide guidelines for the formulation and implementation of future health strategies. Recommendations given would ensure that there is utilisation of available resources, which would help in the execution of other health strategies to ensure efficient and effective health care service delivery. The recommendations are also intended to enhance the performance of health workers. Though the study was limited to Vungu Rural District Council Clinics the findings and recommendations would provide guidelines for other rural clinics as they use the National Health Strategy. , Thesis (PhD) -- Faculty of Management and Commerce, 2019
- Full Text:
- Date Issued: 2019-08
The Scope of Teaching and Learning in Environmental Education
- Authors: Lotz-Sisitka, Heila
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183037 , vital:43906 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/172809"
- Description: Environmental Education involves a variety of teaching and learning processes which are diversely situated in a range of social and educational contexts. The diversity of scope is an interesting 'contour' of a field like environmental education. Contemporary environmental sciences and complexity studies draw our attention to an ever-changing world and to increasingly complex social-ecological issues, patterns and risks that require our attention. These too influence the scope of environmental education teaching and learning processes. This edition of the Southern African Journal of Environmental Education provides a window through which we may see some of the scope of environmental education activities, research questions, learning and teaching settings, and educational activity. It provides insight into the range of research methodologies that are being deployed to investigate the educational processes that are needed for re-orientation towards sustainability, equity, adaptability and transformation at the people-environment interface.
- Full Text: false
- Date Issued: 2010
- Authors: Lotz-Sisitka, Heila
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183037 , vital:43906 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/172809"
- Description: Environmental Education involves a variety of teaching and learning processes which are diversely situated in a range of social and educational contexts. The diversity of scope is an interesting 'contour' of a field like environmental education. Contemporary environmental sciences and complexity studies draw our attention to an ever-changing world and to increasingly complex social-ecological issues, patterns and risks that require our attention. These too influence the scope of environmental education teaching and learning processes. This edition of the Southern African Journal of Environmental Education provides a window through which we may see some of the scope of environmental education activities, research questions, learning and teaching settings, and educational activity. It provides insight into the range of research methodologies that are being deployed to investigate the educational processes that are needed for re-orientation towards sustainability, equity, adaptability and transformation at the people-environment interface.
- Full Text: false
- Date Issued: 2010
Electro-oxidation of phenol and its derivatives on poly-Ni (OH) TPhPyPc modified vitreous carbon electrodes
- Obirai, Joseph, Bedioui, Fethi, Nyokong, Tebello
- Authors: Obirai, Joseph , Bedioui, Fethi , Nyokong, Tebello
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289353 , vital:56625 , xlink:href="https://doi.org/10.1016/j.jelechem.2004.11.006"
- Description: The electrochemical oxidation of phenol and its derivatives using poly-nickel hydroxy tetraphenoxypyrrolephthalocyanine (poly-Ni(OH)TPhPyPc) modified vitreous carbon electrodes are described. The films were formed by the electro-transformation of the electropolymerized pyrrole-substituted phenoxyphthalocyanine poly-NiTPhPyPc modified electrode in aqueous 0.1 M NaOH solution. The poly-Ni(OH)TPhPyPc films showed better stability and resistance to electrode fouling compared to poly-NiTPhPyPc and unmodified electrodes. The resistance to surface fouling and stability can be attributed to the structure of the ring substituent on the phthalocyanine macrocycle and to the particular O–Ni–O bridged architecture of the nickel phthalocyanine film.
- Full Text:
- Date Issued: 2005
- Authors: Obirai, Joseph , Bedioui, Fethi , Nyokong, Tebello
- Date: 2005
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289353 , vital:56625 , xlink:href="https://doi.org/10.1016/j.jelechem.2004.11.006"
- Description: The electrochemical oxidation of phenol and its derivatives using poly-nickel hydroxy tetraphenoxypyrrolephthalocyanine (poly-Ni(OH)TPhPyPc) modified vitreous carbon electrodes are described. The films were formed by the electro-transformation of the electropolymerized pyrrole-substituted phenoxyphthalocyanine poly-NiTPhPyPc modified electrode in aqueous 0.1 M NaOH solution. The poly-Ni(OH)TPhPyPc films showed better stability and resistance to electrode fouling compared to poly-NiTPhPyPc and unmodified electrodes. The resistance to surface fouling and stability can be attributed to the structure of the ring substituent on the phthalocyanine macrocycle and to the particular O–Ni–O bridged architecture of the nickel phthalocyanine film.
- Full Text:
- Date Issued: 2005
The quantification of Pinus patula recovery and productivity of manually orientated biomass collection in post mechanised full tree and semi mechanised tree length harvesting operations
- Authors: Ncongwane, Thandekile Hazel
- Date: 2023-04
- Subjects: Pinus patula – south Africa , Forest ecology , Biomass energy
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/61511 , vital:70692
- Description: The use of biomass as an alternate source of energy has grown in popularity. Different types of biomass are obtained from a variety of sources including natural forests, forestry plantations and agriculture residues. However, forestry residues have been identified as the most promising source, due to the wide variety of plant products including leaves, twigs, branches, merchantable stem, stumps and roots. The main sources of plantation forest biomass are residues from thinning, clearfell and conventional products such as pulpwood and sawn timber operations. These residues can accumulate between 4.3 to 9.4 billion tonnes annually around the world. The biomass availability in plantation forests has led to the development of different harvesting systems to help collect the products from infield to sawmill. Biomass harvesting has mainly been achieved through mechanised systems because of their high yields. However, the use of manual systems has been neglected due to technical limitations and financial viability. Thus, in South Africa, there is no scientific research looking at manual systems of collecting biomass from plantations. Because of this, different forestry stakeholders, including small growers and contractors using manual systems for biomass harvesting have limited knowledge regarding what to expect in terms of recoverable amounts, productivity and cost. This research examines the productivity of the manual biomass collection and the quantification of recovered and unrecovered residues after mechanised full tree (FT) and semi mechanised tree length (TL) harvesting operations in Pinus patula compartments. A total number of 8 plots with +/-200 standing trees were marked in each system. The diameter and height of all marked trees were measured to determine tree volume. Moreover, the quantification of recoverable woody biomass was determined, where after, a residues assessment method using plots and line transects was used to determine the amount of unrecovered residues. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2023
- Full Text:
- Date Issued: 2023-04
- Authors: Ncongwane, Thandekile Hazel
- Date: 2023-04
- Subjects: Pinus patula – south Africa , Forest ecology , Biomass energy
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/61511 , vital:70692
- Description: The use of biomass as an alternate source of energy has grown in popularity. Different types of biomass are obtained from a variety of sources including natural forests, forestry plantations and agriculture residues. However, forestry residues have been identified as the most promising source, due to the wide variety of plant products including leaves, twigs, branches, merchantable stem, stumps and roots. The main sources of plantation forest biomass are residues from thinning, clearfell and conventional products such as pulpwood and sawn timber operations. These residues can accumulate between 4.3 to 9.4 billion tonnes annually around the world. The biomass availability in plantation forests has led to the development of different harvesting systems to help collect the products from infield to sawmill. Biomass harvesting has mainly been achieved through mechanised systems because of their high yields. However, the use of manual systems has been neglected due to technical limitations and financial viability. Thus, in South Africa, there is no scientific research looking at manual systems of collecting biomass from plantations. Because of this, different forestry stakeholders, including small growers and contractors using manual systems for biomass harvesting have limited knowledge regarding what to expect in terms of recoverable amounts, productivity and cost. This research examines the productivity of the manual biomass collection and the quantification of recovered and unrecovered residues after mechanised full tree (FT) and semi mechanised tree length (TL) harvesting operations in Pinus patula compartments. A total number of 8 plots with +/-200 standing trees were marked in each system. The diameter and height of all marked trees were measured to determine tree volume. Moreover, the quantification of recoverable woody biomass was determined, where after, a residues assessment method using plots and line transects was used to determine the amount of unrecovered residues. , Thesis (MSc) -- Faculty of Science, School of Environmental Sciences, 2023
- Full Text:
- Date Issued: 2023-04
Municipal governance and the space for meaningful engagement: local government, citizenship and public participation in Amahlati and great Kei Municipalities
- Sokupa, Thabile https://orcid.org/0000-0003-2265-477X
- Authors: Sokupa, Thabile https://orcid.org/0000-0003-2265-477X
- Date: 2015-01
- Subjects: Municipal government--South Africa--Eastern Cape , Local government--South Africa--Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25107 , vital:63978
- Description: Since the dawn of democracy in 1994 and the subsequent adoption of the Constitution of the Republic of South Africa in 1996, new forms of “wall to wall” municipalities were created throughout South Africa in 2000 and given a mandate of a local developmental sphere. The founding blocks of this was through the creation of the three spheres of government mechanism, namely national, provincial and local, each sphere of government was regarded as distinctive, interrelated and interdependent from one another. The local government sphere however has since mid-2000’s been marred by persistent service delivery protests throughout the country, in recent years the service delivery protests have been accompanied by violence and intimidation. The Eastern Cape Province has not been spared from this phenomenon, media reports, independent monitoring think tanks and yearly statistical results released by the South African Police Service (SAPS) through the ‘Gatherings Act’ indicates that service delivery protests in the province has been on an upward trend on yearly basis since the mid-2000’s. But much more detail is required in understanding the causes behind what are sometimes termed “civil unrest.” The thesis attempts to highlight trends regarding reasons for protest, methods of protest, and the profiling of areas where the protests occur. The findings would meaningfully contribute to the local government discourse and foster alternative mechanisms of engaging communities through better governance and development mechanism by local authorities. The ultimate goal is to create alternative solutions in addressing communities’ needs at local level for policy makers. Currently there is an existing gap in investigating service delivery protests especialy in rural municipalities, most of the municipal research findings and policies are predominantly urban oriented and are not tailor made in addressing rural community’s needs on governance and development. Although the South African Constitution makes provision on steps to be followed on governance and development at local level both vertical and horizontal integration, the Constitution is however silent on addressing governance and development needs of rural communities. As a result of this silence, rural municipalities are confined to develop policies that are not specific to their local needs. Hence the research was conducted in rural communities of Amahlathi and Great Kei municipalities respectively through mixed methods between quantitative and qualitative research. The thesis primarily sought to assess the actual nature and content of forms of engagement in the current public participation discourse at the two municipalities and perceptions thereof of communities on this matter. The information gathered in this research is intended to provide policy makers and those with interests on local government with a better understanding on the dynamics of public participation involvement and service delivery protests on rural based municipalities. The research also seeks to generate new information, insights and perspectives on service delivery protests in order to develop alternative strategies in addressing and minimising service delivery protests. This would assist local government practitioners on the one hand, with planning and implementing a focused approach on governance and development for communities while on the other, introduce an alternative perspective that is evidence based for policy makers. , Thesis (PhD) -- Faculty of Social Sciences and Humanities, 2015
- Full Text:
- Date Issued: 2015-01
- Authors: Sokupa, Thabile https://orcid.org/0000-0003-2265-477X
- Date: 2015-01
- Subjects: Municipal government--South Africa--Eastern Cape , Local government--South Africa--Eastern Cape
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10353/25107 , vital:63978
- Description: Since the dawn of democracy in 1994 and the subsequent adoption of the Constitution of the Republic of South Africa in 1996, new forms of “wall to wall” municipalities were created throughout South Africa in 2000 and given a mandate of a local developmental sphere. The founding blocks of this was through the creation of the three spheres of government mechanism, namely national, provincial and local, each sphere of government was regarded as distinctive, interrelated and interdependent from one another. The local government sphere however has since mid-2000’s been marred by persistent service delivery protests throughout the country, in recent years the service delivery protests have been accompanied by violence and intimidation. The Eastern Cape Province has not been spared from this phenomenon, media reports, independent monitoring think tanks and yearly statistical results released by the South African Police Service (SAPS) through the ‘Gatherings Act’ indicates that service delivery protests in the province has been on an upward trend on yearly basis since the mid-2000’s. But much more detail is required in understanding the causes behind what are sometimes termed “civil unrest.” The thesis attempts to highlight trends regarding reasons for protest, methods of protest, and the profiling of areas where the protests occur. The findings would meaningfully contribute to the local government discourse and foster alternative mechanisms of engaging communities through better governance and development mechanism by local authorities. The ultimate goal is to create alternative solutions in addressing communities’ needs at local level for policy makers. Currently there is an existing gap in investigating service delivery protests especialy in rural municipalities, most of the municipal research findings and policies are predominantly urban oriented and are not tailor made in addressing rural community’s needs on governance and development. Although the South African Constitution makes provision on steps to be followed on governance and development at local level both vertical and horizontal integration, the Constitution is however silent on addressing governance and development needs of rural communities. As a result of this silence, rural municipalities are confined to develop policies that are not specific to their local needs. Hence the research was conducted in rural communities of Amahlathi and Great Kei municipalities respectively through mixed methods between quantitative and qualitative research. The thesis primarily sought to assess the actual nature and content of forms of engagement in the current public participation discourse at the two municipalities and perceptions thereof of communities on this matter. The information gathered in this research is intended to provide policy makers and those with interests on local government with a better understanding on the dynamics of public participation involvement and service delivery protests on rural based municipalities. The research also seeks to generate new information, insights and perspectives on service delivery protests in order to develop alternative strategies in addressing and minimising service delivery protests. This would assist local government practitioners on the one hand, with planning and implementing a focused approach on governance and development for communities while on the other, introduce an alternative perspective that is evidence based for policy makers. , Thesis (PhD) -- Faculty of Social Sciences and Humanities, 2015
- Full Text:
- Date Issued: 2015-01
Measuring the effectiveness of road Infrastructure support in the OR Tambo Region
- Authors: Malotana, Sinesipho
- Date: 2022-04
- Subjects: Roads -- Maintenance and repair , Municipal services
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/57819 , vital:58273
- Description: The term "road infrastructure" refers to the roads and structures that are used to convey commuters and goods. In the numerous road facilities, structures, road classifications, electronic traffic systems, signage, and markings, the mission of road infrastructure is to assist efficiency by providing safety and trouble-free transportation. There are fundamental elements that determine the availability of resources required in society and the efficiency with which they are used to accomplish economic growth. Investment in public capital, such as road infrastructure, which is a major economic engine, is critical because infrastructure helps an economy thrive. The importance of road infrastructure and the major role it plays in economic growth can be seen in studies in developed European nations, New Zealand and the Slovak Republic, where road infrastructure is regarded as a catalyst for economic progress. Investment in public capital, such as road infrastructure, has economic benefits since it acts as the economy's backbone. The Eastern Cape's growth has been acknowledged and included in South Africa's national development strategies and efforts; nonetheless, based on deliverables and results, the province ranks among South Africa's least developed provinces. The Eastern Cape has long been designated by development programmes such as the Spatial Development Initiative (SDI) as an area that will not only generate development and progress for the province, but also for South Africa as a whole. This is sought to be achieved by the Spatial Development Initiative for the Wild-Coast in OR Tambo District Municipality, which states that "integrated sustainable rural development in the context of community, public, and private partnership initiatives.”, p. 2) This research contributes to the goal of research, which includes testing, the identification of causes and consequences, the building of a foundation for future research, and the growth of knowledge (Apuke, 2017, p. 40). The study follows a quantitative research approach and uses two main methodological procedures in order to complete this study; namely a literature review and questionnaire survey. Employees of the South African Department of Transport's National Road Infrastructure implementing agent SANRAL make up the research population in this study. The study concludes that the delivery of an effective road network in the OR v Tambo Region can serve as the base for the establishment of innovative PPP policies, the pillar of socio-economic development and transformation. , Thesis (MA) -- Faculty of Business and Economic science, 2022
- Full Text:
- Date Issued: 2022-04
- Authors: Malotana, Sinesipho
- Date: 2022-04
- Subjects: Roads -- Maintenance and repair , Municipal services
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/57819 , vital:58273
- Description: The term "road infrastructure" refers to the roads and structures that are used to convey commuters and goods. In the numerous road facilities, structures, road classifications, electronic traffic systems, signage, and markings, the mission of road infrastructure is to assist efficiency by providing safety and trouble-free transportation. There are fundamental elements that determine the availability of resources required in society and the efficiency with which they are used to accomplish economic growth. Investment in public capital, such as road infrastructure, which is a major economic engine, is critical because infrastructure helps an economy thrive. The importance of road infrastructure and the major role it plays in economic growth can be seen in studies in developed European nations, New Zealand and the Slovak Republic, where road infrastructure is regarded as a catalyst for economic progress. Investment in public capital, such as road infrastructure, has economic benefits since it acts as the economy's backbone. The Eastern Cape's growth has been acknowledged and included in South Africa's national development strategies and efforts; nonetheless, based on deliverables and results, the province ranks among South Africa's least developed provinces. The Eastern Cape has long been designated by development programmes such as the Spatial Development Initiative (SDI) as an area that will not only generate development and progress for the province, but also for South Africa as a whole. This is sought to be achieved by the Spatial Development Initiative for the Wild-Coast in OR Tambo District Municipality, which states that "integrated sustainable rural development in the context of community, public, and private partnership initiatives.”, p. 2) This research contributes to the goal of research, which includes testing, the identification of causes and consequences, the building of a foundation for future research, and the growth of knowledge (Apuke, 2017, p. 40). The study follows a quantitative research approach and uses two main methodological procedures in order to complete this study; namely a literature review and questionnaire survey. Employees of the South African Department of Transport's National Road Infrastructure implementing agent SANRAL make up the research population in this study. The study concludes that the delivery of an effective road network in the OR v Tambo Region can serve as the base for the establishment of innovative PPP policies, the pillar of socio-economic development and transformation. , Thesis (MA) -- Faculty of Business and Economic science, 2022
- Full Text:
- Date Issued: 2022-04
"Burnout" in children's home houseparents
- Authors: Bath, Peter John
- Date: 1983
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/193118 , vital:45300
- Description: Aimed at replicating the results of an American study into "Burnout" in Group Home houseparents, this research had the following aims: 1) To ascertain the validity and reliability of the instrument used in the original study and presented as a "useful measure of burnout”. 2) To establish whether this line of research, within a highly problematic research field, can at present offer any guidelines in the resolution of the current staffing crisis faced by South African children's homes. 3} To describe more closely the burnout syndrome. 4) To study possible etiological factors within a local context. Sixty three houseparents completed questionaires and three independent measures of burnout were obtained. The results were regarded as having failed to replicate those of the original study. The reason for this was found to be the low validity of the original instrument. The main conclusion drawn was that the line of research adopted in the original study can offer only very tentative guidelines towards the resolution of the staffing crisis faced until such time as valid and reliable instruments to measure burnout have been developed. Many of the suggested relationships between situational variables and ones of personal characteristics were confirmed for the local population of houseparents. , Thesis (MSocSci) -- Faculty of Humanities, Psychology, 1983
- Full Text:
- Date Issued: 1983
- Authors: Bath, Peter John
- Date: 1983
- Subjects: Uncatalogued
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/193118 , vital:45300
- Description: Aimed at replicating the results of an American study into "Burnout" in Group Home houseparents, this research had the following aims: 1) To ascertain the validity and reliability of the instrument used in the original study and presented as a "useful measure of burnout”. 2) To establish whether this line of research, within a highly problematic research field, can at present offer any guidelines in the resolution of the current staffing crisis faced by South African children's homes. 3} To describe more closely the burnout syndrome. 4) To study possible etiological factors within a local context. Sixty three houseparents completed questionaires and three independent measures of burnout were obtained. The results were regarded as having failed to replicate those of the original study. The reason for this was found to be the low validity of the original instrument. The main conclusion drawn was that the line of research adopted in the original study can offer only very tentative guidelines towards the resolution of the staffing crisis faced until such time as valid and reliable instruments to measure burnout have been developed. Many of the suggested relationships between situational variables and ones of personal characteristics were confirmed for the local population of houseparents. , Thesis (MSocSci) -- Faculty of Humanities, Psychology, 1983
- Full Text:
- Date Issued: 1983