Early Jurassic dolerites of the Karoo Large Igneous Province ( KLIP): an analysis of their age and emplacement history from sea level to the Drakensberg Mountains in the Eastern Cape , South Africa Submitted
- Authors: Muedi, Thomas Tshifhiwa
- Date: 2019
- Subjects: Geological time , Geochemistry Geology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/41908 , vital:36608
- Description: South Africa hosts one of the largest Large Igneous Provinces (LIPs that is likely linked to the early separation of East and West Gondwana. However, despite many studies, the relationship between dolerites and volcanic basalts of this LIP (also known as the Karoo Large Igneous Province or KLIP) remains unsolved, because of poorly linked age dates (timing), geochemistry and emplacement mechanisms. This problem is in part because different unreliable dating techniques with large margin of errors have been applied This study aims to address these issues by performing new geo chemical and high resolution geochronological analyses on a number of dolerites (sills and dykes), volcanic s also referred to in the literature as the Drakensberg flood basalts) and samples from drill cores and field outcrops. This project is focused on dolerites in the Eastern Cape Province and provides results from field mapping of dolerites (sills and dykes) from the sea level to an elevation of circa 1350 metres above sea level (MASL) and their link to the volcanic in the Eastern Cape Province. The dolerite dykes observed trends from metres to hundreds of kilometres and cut across volcanic, which have similar geochemistry. The intrusive dolerites collected from the field and from d rill core samples were likely emplaced by magma infiltration through pre-existing sub vertical brittle fractures and fissures and then emplaced horizontally as sills circa 183 Ma Detailed fracture mapping across host rock to the dolerite was carried out to test if they acted as possible pathways for magmatic emplacements. The dolerite dykes and fractures mapped in the host sedimentary rocks have a dominant NW direction, especially towards volcanic basalts. The project provides tests based on the geochemical relationships of the dolerites and basalts from sixty-six (66) cores and field outcrop samples. The results confirm that the chemical analyses from the volcanic basalts an d dolerites are closely related and reveal that most samples are Ocean Island Basalt OIB), but some also reveal subduction related processes. This is consistent with models that suggest subduction along south west Gondwana may have influenced plumemagmatism derived from the lower mantle that initiated break up of this supercontinent e.g de Wit and Stern 1981 Storey et al , 1992 ; Torsvik et al., 2006 and Burke et al., 2008)
- Full Text:
- Date Issued: 2019
- Authors: Muedi, Thomas Tshifhiwa
- Date: 2019
- Subjects: Geological time , Geochemistry Geology -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/41908 , vital:36608
- Description: South Africa hosts one of the largest Large Igneous Provinces (LIPs that is likely linked to the early separation of East and West Gondwana. However, despite many studies, the relationship between dolerites and volcanic basalts of this LIP (also known as the Karoo Large Igneous Province or KLIP) remains unsolved, because of poorly linked age dates (timing), geochemistry and emplacement mechanisms. This problem is in part because different unreliable dating techniques with large margin of errors have been applied This study aims to address these issues by performing new geo chemical and high resolution geochronological analyses on a number of dolerites (sills and dykes), volcanic s also referred to in the literature as the Drakensberg flood basalts) and samples from drill cores and field outcrops. This project is focused on dolerites in the Eastern Cape Province and provides results from field mapping of dolerites (sills and dykes) from the sea level to an elevation of circa 1350 metres above sea level (MASL) and their link to the volcanic in the Eastern Cape Province. The dolerite dykes observed trends from metres to hundreds of kilometres and cut across volcanic, which have similar geochemistry. The intrusive dolerites collected from the field and from d rill core samples were likely emplaced by magma infiltration through pre-existing sub vertical brittle fractures and fissures and then emplaced horizontally as sills circa 183 Ma Detailed fracture mapping across host rock to the dolerite was carried out to test if they acted as possible pathways for magmatic emplacements. The dolerite dykes and fractures mapped in the host sedimentary rocks have a dominant NW direction, especially towards volcanic basalts. The project provides tests based on the geochemical relationships of the dolerites and basalts from sixty-six (66) cores and field outcrop samples. The results confirm that the chemical analyses from the volcanic basalts an d dolerites are closely related and reveal that most samples are Ocean Island Basalt OIB), but some also reveal subduction related processes. This is consistent with models that suggest subduction along south west Gondwana may have influenced plumemagmatism derived from the lower mantle that initiated break up of this supercontinent e.g de Wit and Stern 1981 Storey et al , 1992 ; Torsvik et al., 2006 and Burke et al., 2008)
- Full Text:
- Date Issued: 2019
A framework for designing ambient assisted living services for disabled individuals
- Authors: Kyazze, Michael
- Date: 2018
- Subjects: Assistive computer technology , Computers and people with disabilities Self-help devices for people with disabilities People with disabilities -- Means of communication -- Technological innovations Communication devices for people with disabilities
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/31240 , vital:31347
- Description: Physically disabled individuals face a number of challenges when carrying out their everyday activities such as moving around, communicating with others, and their personal care. One way of overcoming these challenges is by using personal assistants. An alternative is to enable independence through assistive technology. This research aimed to investigate how physically disabled individuals experience these challenges, and how assistive technology can enable them to be more independent. In order to achieve the goal of this research, existing literature was reviewed on disability, assisted living, and interaction techniques. The literature study on disability identified some of the challenges faced by disabled individuals in their daily lives. In order to contextualize these challenges, interview studies with eighteen disabled individuals, and twelve personal assistants were carried out in Kampala, Uganda and Port Elizabeth, South Africa. The participants from both Uganda and South Africa were limited to those living in urban areas. The Ugandan participants noted that, whereas technology may assist their daily lives, their most essential needs are basic disability support aids such as wheelchairs and better long canes. This was in contrast with the South African participants, who have access to basic disability support aids. The South African participants identified their key needs as controlling an electronic environment without assistance, e.g. house lights, using a mobile phone, and using a computer without assistance. The interviews narrowed down the scope to focus on individuals with quadriplegia, specifically individuals who have limited hand use, but can comfortably speak and move their heads, and make gestures such as head shake and nod. Literature on assisted living technologies and frameworks, provided the technical foundation for the research. The literature review of interaction techniques identified a number of possible ways in which individuals with quadriplegia can interact with technology. An appropriate set of interaction techniques, namely head shake and nod, voice, and facial feature tracking were identified. Evaluations of the interaction techniques excluded head shake and nod, because of an inconsistency in detecting an individual’s head pose in different lighting conditions, when using a Microsoft Kinect. Voice and facial feature tracking using a standard computer camera were identified as the most suitable interaction techniques for this study. A framework for designing assisted living software services was developed. The framework allows disability researchers and solution developers to understand the needs of a given disability group, and design relevant solutions. To demonstrate that the proposed framework iii | P a g e addresses the main aim of this research, a prototype was developed that enables users to control smart lights (Phillips hue), a Smart TV (Samsung), and carry out basic navigation and webbrowsing on a computer. Users could interact with the software using voice and facial feature commands. A usability study was carried out with fifteen physically disabled individuals in Port Elizabeth, South Africa. The results of the evaluation study were highly positive. The successful evaluation of the prototype provided empirical evidence that the proposed framework does assist in the design of relevant and useful software services, to meet the unique needs of physically disabled individuals.
- Full Text:
- Date Issued: 2018
- Authors: Kyazze, Michael
- Date: 2018
- Subjects: Assistive computer technology , Computers and people with disabilities Self-help devices for people with disabilities People with disabilities -- Means of communication -- Technological innovations Communication devices for people with disabilities
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/31240 , vital:31347
- Description: Physically disabled individuals face a number of challenges when carrying out their everyday activities such as moving around, communicating with others, and their personal care. One way of overcoming these challenges is by using personal assistants. An alternative is to enable independence through assistive technology. This research aimed to investigate how physically disabled individuals experience these challenges, and how assistive technology can enable them to be more independent. In order to achieve the goal of this research, existing literature was reviewed on disability, assisted living, and interaction techniques. The literature study on disability identified some of the challenges faced by disabled individuals in their daily lives. In order to contextualize these challenges, interview studies with eighteen disabled individuals, and twelve personal assistants were carried out in Kampala, Uganda and Port Elizabeth, South Africa. The participants from both Uganda and South Africa were limited to those living in urban areas. The Ugandan participants noted that, whereas technology may assist their daily lives, their most essential needs are basic disability support aids such as wheelchairs and better long canes. This was in contrast with the South African participants, who have access to basic disability support aids. The South African participants identified their key needs as controlling an electronic environment without assistance, e.g. house lights, using a mobile phone, and using a computer without assistance. The interviews narrowed down the scope to focus on individuals with quadriplegia, specifically individuals who have limited hand use, but can comfortably speak and move their heads, and make gestures such as head shake and nod. Literature on assisted living technologies and frameworks, provided the technical foundation for the research. The literature review of interaction techniques identified a number of possible ways in which individuals with quadriplegia can interact with technology. An appropriate set of interaction techniques, namely head shake and nod, voice, and facial feature tracking were identified. Evaluations of the interaction techniques excluded head shake and nod, because of an inconsistency in detecting an individual’s head pose in different lighting conditions, when using a Microsoft Kinect. Voice and facial feature tracking using a standard computer camera were identified as the most suitable interaction techniques for this study. A framework for designing assisted living software services was developed. The framework allows disability researchers and solution developers to understand the needs of a given disability group, and design relevant solutions. To demonstrate that the proposed framework iii | P a g e addresses the main aim of this research, a prototype was developed that enables users to control smart lights (Phillips hue), a Smart TV (Samsung), and carry out basic navigation and webbrowsing on a computer. Users could interact with the software using voice and facial feature commands. A usability study was carried out with fifteen physically disabled individuals in Port Elizabeth, South Africa. The results of the evaluation study were highly positive. The successful evaluation of the prototype provided empirical evidence that the proposed framework does assist in the design of relevant and useful software services, to meet the unique needs of physically disabled individuals.
- Full Text:
- Date Issued: 2018
The impact of the slum upgrading approach on the livelihoods of scheme participants in Uganda : using the sustainable livelihoods framework
- Authors: Karungi, Doreen
- Date: 2020
- Subjects: Slums -- Public welfare -- Uganda
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/48412 , vital:40874
- Description: International and local agencies recommend implementing slum upgrading projects in slum areas for slum improvement. However, with no model or guiding principles provided to slum upgrading project implementers on how to upgrade a slum, slum clearance and redevelopment are implemented rather than slum upgrading consequently projects fail to benefit the target group, slum dwellers. Data collection, took place in five areas in Uganda that implemented slum upgrading. In depth interviews were held with project beneficiaries, local council officials and association executives, and government officials at the Ministry of Lands, Housing and Urban Development. Field observation, and document analysis was carried out. Data analysis involved the use of the sustainable livelihoods framework. This study demonstrates that the slum upgrading approach adopted in Uganda exhibited low sustainability and undercut the sustainability of livelihoods of scheme participants. Slum dwellers faced vulnerabilities from loss of land, characterized by rights based actions resulting in minimal to no compensation or eviction and loss of existing livelihoods. Slum upgrading projects introduced new livelihood opportunities that were too few for slum dwellers, were not sustainable and ended during or with project implementation, leaving beneficiaries without employment or income opportunities. Increased vulnerability was observed as slum dwellers that did not benefit from the project were displaced to worse conditions while slum dwellers that benefitted, project beneficiaries remained poor and in debt, with project loans to repay. Although project beneficiaries were provided with access to assets, they were unable to draw on these to build their livelihoods. Some beneficiaries sold plots and project houses allocated to them and moved to adjacent slums, where they lived in worse conditions. At the time of the current research, good quality houses in the slum upgrading areas did not belong to the original beneficiaries old dilapidated structures were occupied by project beneficiaries. This study shows that income earning activities carried out at the time of the study were similar to those carried out prior to the introduction of slum upgrading in project areas and were destroyed during project implementation or banned by implementers. These activities were however carried out in incomplete houses, vacant plots, temporary structures in project areas and in adjacent swamps and forest. Generally, after completion of slum upgrading projects, project areas, adjacent swamps and forest were characterized by haphazard developments including: rentals, informal businesses, farming, brewing and distilling local alcohol used by beneficiaries to derive livelihoods, in other words, slums were recreated, a problem slum upgrading project implementers set out to solve - except in one study area where the project was implemented differently as a result of persist rights based actions.
- Full Text:
- Date Issued: 2020
- Authors: Karungi, Doreen
- Date: 2020
- Subjects: Slums -- Public welfare -- Uganda
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/48412 , vital:40874
- Description: International and local agencies recommend implementing slum upgrading projects in slum areas for slum improvement. However, with no model or guiding principles provided to slum upgrading project implementers on how to upgrade a slum, slum clearance and redevelopment are implemented rather than slum upgrading consequently projects fail to benefit the target group, slum dwellers. Data collection, took place in five areas in Uganda that implemented slum upgrading. In depth interviews were held with project beneficiaries, local council officials and association executives, and government officials at the Ministry of Lands, Housing and Urban Development. Field observation, and document analysis was carried out. Data analysis involved the use of the sustainable livelihoods framework. This study demonstrates that the slum upgrading approach adopted in Uganda exhibited low sustainability and undercut the sustainability of livelihoods of scheme participants. Slum dwellers faced vulnerabilities from loss of land, characterized by rights based actions resulting in minimal to no compensation or eviction and loss of existing livelihoods. Slum upgrading projects introduced new livelihood opportunities that were too few for slum dwellers, were not sustainable and ended during or with project implementation, leaving beneficiaries without employment or income opportunities. Increased vulnerability was observed as slum dwellers that did not benefit from the project were displaced to worse conditions while slum dwellers that benefitted, project beneficiaries remained poor and in debt, with project loans to repay. Although project beneficiaries were provided with access to assets, they were unable to draw on these to build their livelihoods. Some beneficiaries sold plots and project houses allocated to them and moved to adjacent slums, where they lived in worse conditions. At the time of the current research, good quality houses in the slum upgrading areas did not belong to the original beneficiaries old dilapidated structures were occupied by project beneficiaries. This study shows that income earning activities carried out at the time of the study were similar to those carried out prior to the introduction of slum upgrading in project areas and were destroyed during project implementation or banned by implementers. These activities were however carried out in incomplete houses, vacant plots, temporary structures in project areas and in adjacent swamps and forest. Generally, after completion of slum upgrading projects, project areas, adjacent swamps and forest were characterized by haphazard developments including: rentals, informal businesses, farming, brewing and distilling local alcohol used by beneficiaries to derive livelihoods, in other words, slums were recreated, a problem slum upgrading project implementers set out to solve - except in one study area where the project was implemented differently as a result of persist rights based actions.
- Full Text:
- Date Issued: 2020
Photoconductive spectroscopy of GaSb thin films
- Authors: Shura, Megersa Wodajo
- Date: 2012
- Subjects: Photoelectron spectroscopy , Photoconductivity
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10549 , http://hdl.handle.net/10948/d1019937
- Description: In this study, we have investigated the photo-response of gallium antimonide (GaSb) by measuring the spectral, injection level, as well as the temperature dependence of the steady-state photoconductivity of epitaxial films. By combining the various photo-response measurements with-galvanometric measurements, the effective excess carrier lifetimes could be calculated and described in terms of the various experimental variables considered. From a comparison of the measured and theoretical carrier lifetimes, a clear discrepancy was found for the injection dependent results. This inconsistency between the expected and measured behaviours was resolved using a two-layer model to describe the photo-conductive response of the thin film. In this model, the generation/recombination processes are considered for the bulk as well as for a depleted near-surface region. By combining these two contributions when calculating the total excess photocurrent, the various experimental results could be successfully described. The photo-response measurements revealed that the main contribution to the photocurrent came from the near-surface region, where the bandto- band and Auger recombination transitions are reduced. From the simulation of the injection level dependence of the excess carrier lifetime, some of the near-surface characteristics, such as the position of the surface Fermi-level and the surface recombination velocity, could be determined. In the case of p-type GaSb, the room temperature surface Fermi-level was found to be pinned (290±20) meV above the valence band maximum, whereas the n-type material had a pinning position of (150±20) meV above the valence band maximum. These pinning positions were shown to be independent of the doping density and relatively insensitive to the surface treatments considered. The presence of a near-surface depletion region, as well as the position of the surface Fermi-level, was corroborated by Raman spectroscopy. From a comparison of the phonon mode and the phonon-hole plasmon coupled mode, a surface Fermi-level position of (300 ± 30) meV was deduced for p-type GaSb. Finally, the effect various surface treatments have on the photo-response, and related surface properties, were investigated. Removal of the native oxide (HCl:H2O) followed by sulphur passivation (Na2S:9H2O) results in a slight decrease in the surface Fermi-level position. Aging studies however revealed that the surface characteristics reverted back to the untreated values following a few days in air. Coating the GaSb surfaces with a thin ZnS layer was found to have little effect on the surface potential, resulting only in a slight increase in the near-surface donor density. The sensitivity of the measured photocurrent to surface treatments and changes in the ambient with cooling, further validate the importance of considering the surface potential and the related space-charge when describing the photoconductive response of GaSb thin films.
- Full Text:
- Date Issued: 2012
- Authors: Shura, Megersa Wodajo
- Date: 2012
- Subjects: Photoelectron spectroscopy , Photoconductivity
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10549 , http://hdl.handle.net/10948/d1019937
- Description: In this study, we have investigated the photo-response of gallium antimonide (GaSb) by measuring the spectral, injection level, as well as the temperature dependence of the steady-state photoconductivity of epitaxial films. By combining the various photo-response measurements with-galvanometric measurements, the effective excess carrier lifetimes could be calculated and described in terms of the various experimental variables considered. From a comparison of the measured and theoretical carrier lifetimes, a clear discrepancy was found for the injection dependent results. This inconsistency between the expected and measured behaviours was resolved using a two-layer model to describe the photo-conductive response of the thin film. In this model, the generation/recombination processes are considered for the bulk as well as for a depleted near-surface region. By combining these two contributions when calculating the total excess photocurrent, the various experimental results could be successfully described. The photo-response measurements revealed that the main contribution to the photocurrent came from the near-surface region, where the bandto- band and Auger recombination transitions are reduced. From the simulation of the injection level dependence of the excess carrier lifetime, some of the near-surface characteristics, such as the position of the surface Fermi-level and the surface recombination velocity, could be determined. In the case of p-type GaSb, the room temperature surface Fermi-level was found to be pinned (290±20) meV above the valence band maximum, whereas the n-type material had a pinning position of (150±20) meV above the valence band maximum. These pinning positions were shown to be independent of the doping density and relatively insensitive to the surface treatments considered. The presence of a near-surface depletion region, as well as the position of the surface Fermi-level, was corroborated by Raman spectroscopy. From a comparison of the phonon mode and the phonon-hole plasmon coupled mode, a surface Fermi-level position of (300 ± 30) meV was deduced for p-type GaSb. Finally, the effect various surface treatments have on the photo-response, and related surface properties, were investigated. Removal of the native oxide (HCl:H2O) followed by sulphur passivation (Na2S:9H2O) results in a slight decrease in the surface Fermi-level position. Aging studies however revealed that the surface characteristics reverted back to the untreated values following a few days in air. Coating the GaSb surfaces with a thin ZnS layer was found to have little effect on the surface potential, resulting only in a slight increase in the near-surface donor density. The sensitivity of the measured photocurrent to surface treatments and changes in the ambient with cooling, further validate the importance of considering the surface potential and the related space-charge when describing the photoconductive response of GaSb thin films.
- Full Text:
- Date Issued: 2012
Chang liver cell line as a model for Type II Diabetes in the liver and possible reversal of this condition by an indigenous medicinal plant
- Authors: Williams, Saralene Iona
- Date: 2009
- Subjects: Diabetes -- Alternative treatment , Medicinal plants , Traditional medicine , Liver -- Diseases
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10339 , http://hdl.handle.net/10948/d1016179
- Description: The incidence of Type 2 Diabetes Mellittus (T2DM) is increasing world wide. In Africa the limited access to health care and the insidious course of the disease lead to more severe illness and diabetic complications. There is a need to find alternative approaches to treatment and prevention that address the problems and needs of Africa. Sutherlandia frutescens (S.frutescens) is a traditional herbal plant with known anti-diabetic properties, the precise mechanism of action of S.frutescens is not known. In order to develop new approaches for treatment and prevention of T2DM the pathophysiology of T2DM must be understood. T2DM is the final outcome of a multi-organ disease characterized by early defects in muscle, adipocytes, hepatocytes and pancreatic β-cells. In this study the role of the liver was investigated because of its central role in glucose and lipid metabolism. It is hard to differentiate between all the influences in an in vivo model, so the aim of this study was to develop an in vitro model of T2DM in Chang liver cells and to determine if S.frutescens can reverse the state of insulin resistance in this model. Different culture media conditions were screened to identify a method that can be used as the T2DM model in Chang liver cells. Serum free medium (MCBD-201) supplemented with human diabetic serum, (2.5%-10%), high insulin concentrations (0.1μM-1μM), high fructose concentrations (1-10mM). and a combination of high insulin and high fructose was used for this screening. Chang liver cells cultured in MCBD-201 medium supplemented with 1mM fructose and 0.1μM insulin showed reduced glucose uptake and increased lipid accumulation. The effect of two S.frutescens extracts, two anti-diabetic drugs, metformin and ciglitazone, and a hypolipidemic drug ciprofibrate were determined and shown to increase glucose uptake and reduce lipid accumulation. It was postulated that exposing the cells to excess nutrients in the form of high fructose would stimulate the cells to become adipogenic and accumulate lipids, which would interfere with the glucose uptake and induce insulin resistance. Gene expression of PPARγ, PPARα, and SREBP-1 transcription factors regulating lipid metabolism was determined in Chang liver cells cultured in insulin resistance inducing medium over a 48 hour time course. The expression of PPARγ, known to stimulate adipogenesis was increased after 6, 24 and 48 hours of exposure (P(H1)<0.0001). The expression of PPARα, known to stimulate β-oxidation expression, was significantly decreased after 24 hours of exposure (P(H1)<0.0001). The presence of the plant extracts in the insulin resistance inducing media protect against this increase in adipogenesis and decrease in β-oxidation after 48 hours of exposure by increasing PPARα expression and decreasing PPARγ expression. A PCR Array was performed which identified 32 more potential molecular targets of S.frutescens. Five of the 32 targets identified with the PCR Array were validated using qRT-PCR. These genes play a role in lipid and glucose metabolism and protection against oxidative stress and inflammation. In summary a cellular model of insulin resistace in hepatocytes has been established and the capacity of S.frutescens to reverse this process has been demonstrated by acting as a dual PPARγ/α agonist. New genes have been identified in the development of insulin resistance and as targets of S.frutescens.
- Full Text:
- Date Issued: 2009
- Authors: Williams, Saralene Iona
- Date: 2009
- Subjects: Diabetes -- Alternative treatment , Medicinal plants , Traditional medicine , Liver -- Diseases
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10339 , http://hdl.handle.net/10948/d1016179
- Description: The incidence of Type 2 Diabetes Mellittus (T2DM) is increasing world wide. In Africa the limited access to health care and the insidious course of the disease lead to more severe illness and diabetic complications. There is a need to find alternative approaches to treatment and prevention that address the problems and needs of Africa. Sutherlandia frutescens (S.frutescens) is a traditional herbal plant with known anti-diabetic properties, the precise mechanism of action of S.frutescens is not known. In order to develop new approaches for treatment and prevention of T2DM the pathophysiology of T2DM must be understood. T2DM is the final outcome of a multi-organ disease characterized by early defects in muscle, adipocytes, hepatocytes and pancreatic β-cells. In this study the role of the liver was investigated because of its central role in glucose and lipid metabolism. It is hard to differentiate between all the influences in an in vivo model, so the aim of this study was to develop an in vitro model of T2DM in Chang liver cells and to determine if S.frutescens can reverse the state of insulin resistance in this model. Different culture media conditions were screened to identify a method that can be used as the T2DM model in Chang liver cells. Serum free medium (MCBD-201) supplemented with human diabetic serum, (2.5%-10%), high insulin concentrations (0.1μM-1μM), high fructose concentrations (1-10mM). and a combination of high insulin and high fructose was used for this screening. Chang liver cells cultured in MCBD-201 medium supplemented with 1mM fructose and 0.1μM insulin showed reduced glucose uptake and increased lipid accumulation. The effect of two S.frutescens extracts, two anti-diabetic drugs, metformin and ciglitazone, and a hypolipidemic drug ciprofibrate were determined and shown to increase glucose uptake and reduce lipid accumulation. It was postulated that exposing the cells to excess nutrients in the form of high fructose would stimulate the cells to become adipogenic and accumulate lipids, which would interfere with the glucose uptake and induce insulin resistance. Gene expression of PPARγ, PPARα, and SREBP-1 transcription factors regulating lipid metabolism was determined in Chang liver cells cultured in insulin resistance inducing medium over a 48 hour time course. The expression of PPARγ, known to stimulate adipogenesis was increased after 6, 24 and 48 hours of exposure (P(H1)<0.0001). The expression of PPARα, known to stimulate β-oxidation expression, was significantly decreased after 24 hours of exposure (P(H1)<0.0001). The presence of the plant extracts in the insulin resistance inducing media protect against this increase in adipogenesis and decrease in β-oxidation after 48 hours of exposure by increasing PPARα expression and decreasing PPARγ expression. A PCR Array was performed which identified 32 more potential molecular targets of S.frutescens. Five of the 32 targets identified with the PCR Array were validated using qRT-PCR. These genes play a role in lipid and glucose metabolism and protection against oxidative stress and inflammation. In summary a cellular model of insulin resistace in hepatocytes has been established and the capacity of S.frutescens to reverse this process has been demonstrated by acting as a dual PPARγ/α agonist. New genes have been identified in the development of insulin resistance and as targets of S.frutescens.
- Full Text:
- Date Issued: 2009
Land use change, landslide occurrence and livelihood strategies on Mount Elgon Slopes, Eastern Uganda
- Authors: Mugagga, Frank
- Date: 2011
- Subjects: Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10646 , http://hdl.handle.net/10948/1468 , Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Description: An investigation of the relationship between the physical, pedological and anthropogenic influences on landslide occurrence on the midslopes within and outside Mt Elgon National Park was carried out. One of the landslides occurred in a protected pristine forest environment within the Park while the other two were located at sites deforested for cultivation within and outside the National Park. Field based surveys, GIS techniques and laboratory tests were used to collect and analyze the data. A household survey was undertaken to establish the main community livelihood strategies, the drivers of land use change and implications for land degradation on the mid slopes of Mt Elgon. Aerial photographs taken in 1960 and orthophoto maps formed the benchmark for the analysis of the respective land use changes between 1995 and 2006, using 30m Landsat TM and 20m SPOT MS images in IDRISI Andes GIS environment. Landslide sites were mapped using a Magellan Professional MobileMapperTMCX and terrain parameters were derived using a 15M Digital Elevation Model. A hybrid supervised/unsupervised classification approach was employed to generate land cover maps from which the areal extent of three land cover classes (agricultural fields, woodlands and forests) was calculated. Particle size distribution and atterberg limits were used to test the hypothesis that soils at the landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Shear strength parameters (internal of friction and cohesion) were used calculate the slope factor of safety to ascertain slope stability at pristine and disturbed landslide sites. Results from the socio-economic survey revealed that smallholder subsistence agriculture and encroachment on the National Park resources are the main sources of livelihoods for the communities surrounding the Park. The communities also have a strong socio-cultural attachment to the National Park, as it is the source of items used during traditional rituals like circumcision. Encroachment is driven by the high population pressure and the prevalent political climate. Farmers mainly use slash and burn technique to prepare land for cultivation and those close to the National Park are reluctant to adopt appropriate farming and soil conservation practices due to the uncertainties surrounding their future on such plots. Slash and burn iii techniques were observed to accelerate various forms of erosion including rills, gullies and sheet. Soil and water conservation techniques were mainly practiced on privately owned farms. The period 1960 and 1995 was characterized by minimal land use changes and no encroachment into the designated Mount Elgon National Park. Conversely, the period 1995 – 2006 marked a significant loss of woodlands and forest cover particularly on steep concave slopes (36º – 58º) within the National Park. The land use change trends were attributed to the prevalent land politics and exponential population growth in the region. The encroachment onto the critical slopes was noted to have induced a series of shallow and deep landslides in the area. Deforestation on Mt Elgon was reported to have both onsite and offsite climate variability and implications in the form of drought, heat waves, flash floods, economic dislocation, crop failure and associated malnutrition in surrounding low lying areas. The soils on pristine and disturbed slopes contain high amount of clay (>10 percent), are fine textured (>50 percent of the material passing the 0.075mm sieve) and highly plastic. These soil attributes imply low permeability, excessive water retention and high susceptibility to expansion and sliding. The vertic nature of soils at Nametsi was confirmed by the extremely high plasticity indices (averaging 33percent), while, high liquid limits at Buwabwala (53 percent) and Kitati (59 percent) qualified the soils as vertisols which are associated with landslides. The results point to the fact that soils at landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Therefore, the hypothesis that soils at three landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention is accepted. Notwithstanding the fact that the study was focussed on mid-altitude slopes of Mt Elgon, the results are in tandem with investigations carried out earlier on the lower densely populated slopes, thus confirming the widespread nature of problem soils on Mt Elgon. There is an urgent need to control human population growth and restore forest cover on the heavily deforested steep slopes particularly within the National Park, and restrain communities from encroaching on the pristine slopes of Mt Elgon. This will be achieved if the politicians, Park Authorities and local communities jointly participate in the design and implementation of CFMs. Future research could focus on climate change implications of deforestation of Mt Elgon environments and quantification of carbon loss related to deforestation and soil degradation in the mountain environments.
- Full Text:
- Date Issued: 2011
- Authors: Mugagga, Frank
- Date: 2011
- Subjects: Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10646 , http://hdl.handle.net/10948/1468 , Land use -- Uganda -- Mount Elgon National Park , Landslides -- Uganda -- Mount Elgon National Park , Land degradation -- Uganda -- Mount Elgon National Park
- Description: An investigation of the relationship between the physical, pedological and anthropogenic influences on landslide occurrence on the midslopes within and outside Mt Elgon National Park was carried out. One of the landslides occurred in a protected pristine forest environment within the Park while the other two were located at sites deforested for cultivation within and outside the National Park. Field based surveys, GIS techniques and laboratory tests were used to collect and analyze the data. A household survey was undertaken to establish the main community livelihood strategies, the drivers of land use change and implications for land degradation on the mid slopes of Mt Elgon. Aerial photographs taken in 1960 and orthophoto maps formed the benchmark for the analysis of the respective land use changes between 1995 and 2006, using 30m Landsat TM and 20m SPOT MS images in IDRISI Andes GIS environment. Landslide sites were mapped using a Magellan Professional MobileMapperTMCX and terrain parameters were derived using a 15M Digital Elevation Model. A hybrid supervised/unsupervised classification approach was employed to generate land cover maps from which the areal extent of three land cover classes (agricultural fields, woodlands and forests) was calculated. Particle size distribution and atterberg limits were used to test the hypothesis that soils at the landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Shear strength parameters (internal of friction and cohesion) were used calculate the slope factor of safety to ascertain slope stability at pristine and disturbed landslide sites. Results from the socio-economic survey revealed that smallholder subsistence agriculture and encroachment on the National Park resources are the main sources of livelihoods for the communities surrounding the Park. The communities also have a strong socio-cultural attachment to the National Park, as it is the source of items used during traditional rituals like circumcision. Encroachment is driven by the high population pressure and the prevalent political climate. Farmers mainly use slash and burn technique to prepare land for cultivation and those close to the National Park are reluctant to adopt appropriate farming and soil conservation practices due to the uncertainties surrounding their future on such plots. Slash and burn iii techniques were observed to accelerate various forms of erosion including rills, gullies and sheet. Soil and water conservation techniques were mainly practiced on privately owned farms. The period 1960 and 1995 was characterized by minimal land use changes and no encroachment into the designated Mount Elgon National Park. Conversely, the period 1995 – 2006 marked a significant loss of woodlands and forest cover particularly on steep concave slopes (36º – 58º) within the National Park. The land use change trends were attributed to the prevalent land politics and exponential population growth in the region. The encroachment onto the critical slopes was noted to have induced a series of shallow and deep landslides in the area. Deforestation on Mt Elgon was reported to have both onsite and offsite climate variability and implications in the form of drought, heat waves, flash floods, economic dislocation, crop failure and associated malnutrition in surrounding low lying areas. The soils on pristine and disturbed slopes contain high amount of clay (>10 percent), are fine textured (>50 percent of the material passing the 0.075mm sieve) and highly plastic. These soil attributes imply low permeability, excessive water retention and high susceptibility to expansion and sliding. The vertic nature of soils at Nametsi was confirmed by the extremely high plasticity indices (averaging 33percent), while, high liquid limits at Buwabwala (53 percent) and Kitati (59 percent) qualified the soils as vertisols which are associated with landslides. The results point to the fact that soils at landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention. Therefore, the hypothesis that soils at three landslide sites are inherently ‘problem soils’ where slope failure can occur even without human intervention is accepted. Notwithstanding the fact that the study was focussed on mid-altitude slopes of Mt Elgon, the results are in tandem with investigations carried out earlier on the lower densely populated slopes, thus confirming the widespread nature of problem soils on Mt Elgon. There is an urgent need to control human population growth and restore forest cover on the heavily deforested steep slopes particularly within the National Park, and restrain communities from encroaching on the pristine slopes of Mt Elgon. This will be achieved if the politicians, Park Authorities and local communities jointly participate in the design and implementation of CFMs. Future research could focus on climate change implications of deforestation of Mt Elgon environments and quantification of carbon loss related to deforestation and soil degradation in the mountain environments.
- Full Text:
- Date Issued: 2011
Polarization mode dispersion emulation and the impact of high first-order PMD segments in optical telecommunication systems
- Authors: Musara, Vitalis
- Date: 2009
- Subjects: Optical communications , Fiber optics , Polarization (Light)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10519 , http://hdl.handle.net/10948/1138 , Optical communications , Fiber optics , Polarization (Light)
- Description: In this study, focus is centred on the measurement and emulation of first-order (FO-) and second-order (SO-) polarization mode dispersion (PMD). PMD has deleterious effects on the performance of high speed optical transmission network systems from 10 Gb/s and above. The first step was characterising deployed fibres for PMD and monitoring the state of polarization (SOP) light experiences as it propagates through the fibre. The PMD and SOP changes in deployed fibres were stochastic due to varying intrinsic and extrinsic perturbation changes. To fully understand the PMD phenomenon in terms of measurement accuracy, its complex behaviour, its implications, mitigation and compensation, PMD emulation is crucial. This thesis presents emulator designs which fall into different emulator categories. The key to these designs were the PMD equations and background on the PMD phenomenon. The cross product from the concatenation equation was applied in order to determine the coupling angle β (between 0o and 180o) that results in the SO-PMD of the emulator designs to be either adjustable or fixed. The digital delay line (DDL) or single polarization maintaining fibre (PMF) section was used to give a certain amount of FO-PMD but negligible SO-PMD. PMF sections (birefringent sections) were concatenated together to ensure FO- and SO-PMD coexist, emulating deployed fibres. FO- and SO-PMD can be controlled by altering mode coupling (coupling angles) and birefringence distribution. Emulators with PMD statistics approaching the theoretical distributions had high random coupling and several numbers of randomly distributed PMF sections. In addition, the lengths of their PMF sections lie within 20% standard deviation of the mean emulator length. Those emulators with PMD statistics that did not approach the theoretical distributions had limited numbers of randomly distributed PMF sections and mode coupling. Results also show that even when an emulator has high random mode coupling and several numbers of randomly distributed PMFs, its PMD statistics deviates away from expected theoretical distributions in the presence of polarization dependent loss (PDL). The emulators showed that the background autocorrelation function (BACF) approaches zero with increasing number of randomly mode coupled fibre sections. A zero BACF signifies that an emulator has large numbers of randomly distributed PMF sections and its presence means the opposite. The availability of SO-PMD in the emulators made the autocorrelation function (ACF) x asymmetric. In the absence of SO-PMD the ACF for a PMD emulator is symmetric. SO-PMD has no effect on the BACF. Polarization-optical time domain reflectometry (P-OTDR) measurements have shown that certain fibre sections along fibre link lengths have higher FO-PMD (HiFO-PMD) than other sections. This study investigates the impact of a HiFO-PMD section on the overall FO- and SO-PMD, the output state of polarization (SOP) and system performance on deployed fibres (through emulation). Results show that when the wavelength-independent FO-PMD vector of the HiFO-PMD section is greater than the FO-PMD contributions from the rest of the fibre link, the mean FO-PMD of the entire link is biased towards that of the HiFO-PMD section and the SO-PMD increases (β ≠ 0o or 180o) or remains fixed (β = 0o or 180o) depending on the coupling angle β between the HiFO-PMD section and the rest of the fibre link. In addition, the FO-PMD statistics deviates away from the theoretical Maxwellian distribution. However, experimental results show that the HiFO-PMD section has negligible influence on the SOPMD statistical distribution. An increase in the amount of FO-PMD on a HiFO-PMD section reduces the output SOP spread to a given minimum, in this study the minimum was reached when the HiFO-PMD ≥ 35 ps. However, the outcome of the output SOP spread depends on the location of the HiFO-PMD section along the fibre link length. It was found that when the HiFO-PMD section introduces SO-PMD, the bit error rate (BER) is much higher compared to when it does not introduce SO-PMD.
- Full Text:
- Date Issued: 2009
- Authors: Musara, Vitalis
- Date: 2009
- Subjects: Optical communications , Fiber optics , Polarization (Light)
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10519 , http://hdl.handle.net/10948/1138 , Optical communications , Fiber optics , Polarization (Light)
- Description: In this study, focus is centred on the measurement and emulation of first-order (FO-) and second-order (SO-) polarization mode dispersion (PMD). PMD has deleterious effects on the performance of high speed optical transmission network systems from 10 Gb/s and above. The first step was characterising deployed fibres for PMD and monitoring the state of polarization (SOP) light experiences as it propagates through the fibre. The PMD and SOP changes in deployed fibres were stochastic due to varying intrinsic and extrinsic perturbation changes. To fully understand the PMD phenomenon in terms of measurement accuracy, its complex behaviour, its implications, mitigation and compensation, PMD emulation is crucial. This thesis presents emulator designs which fall into different emulator categories. The key to these designs were the PMD equations and background on the PMD phenomenon. The cross product from the concatenation equation was applied in order to determine the coupling angle β (between 0o and 180o) that results in the SO-PMD of the emulator designs to be either adjustable or fixed. The digital delay line (DDL) or single polarization maintaining fibre (PMF) section was used to give a certain amount of FO-PMD but negligible SO-PMD. PMF sections (birefringent sections) were concatenated together to ensure FO- and SO-PMD coexist, emulating deployed fibres. FO- and SO-PMD can be controlled by altering mode coupling (coupling angles) and birefringence distribution. Emulators with PMD statistics approaching the theoretical distributions had high random coupling and several numbers of randomly distributed PMF sections. In addition, the lengths of their PMF sections lie within 20% standard deviation of the mean emulator length. Those emulators with PMD statistics that did not approach the theoretical distributions had limited numbers of randomly distributed PMF sections and mode coupling. Results also show that even when an emulator has high random mode coupling and several numbers of randomly distributed PMFs, its PMD statistics deviates away from expected theoretical distributions in the presence of polarization dependent loss (PDL). The emulators showed that the background autocorrelation function (BACF) approaches zero with increasing number of randomly mode coupled fibre sections. A zero BACF signifies that an emulator has large numbers of randomly distributed PMF sections and its presence means the opposite. The availability of SO-PMD in the emulators made the autocorrelation function (ACF) x asymmetric. In the absence of SO-PMD the ACF for a PMD emulator is symmetric. SO-PMD has no effect on the BACF. Polarization-optical time domain reflectometry (P-OTDR) measurements have shown that certain fibre sections along fibre link lengths have higher FO-PMD (HiFO-PMD) than other sections. This study investigates the impact of a HiFO-PMD section on the overall FO- and SO-PMD, the output state of polarization (SOP) and system performance on deployed fibres (through emulation). Results show that when the wavelength-independent FO-PMD vector of the HiFO-PMD section is greater than the FO-PMD contributions from the rest of the fibre link, the mean FO-PMD of the entire link is biased towards that of the HiFO-PMD section and the SO-PMD increases (β ≠ 0o or 180o) or remains fixed (β = 0o or 180o) depending on the coupling angle β between the HiFO-PMD section and the rest of the fibre link. In addition, the FO-PMD statistics deviates away from the theoretical Maxwellian distribution. However, experimental results show that the HiFO-PMD section has negligible influence on the SOPMD statistical distribution. An increase in the amount of FO-PMD on a HiFO-PMD section reduces the output SOP spread to a given minimum, in this study the minimum was reached when the HiFO-PMD ≥ 35 ps. However, the outcome of the output SOP spread depends on the location of the HiFO-PMD section along the fibre link length. It was found that when the HiFO-PMD section introduces SO-PMD, the bit error rate (BER) is much higher compared to when it does not introduce SO-PMD.
- Full Text:
- Date Issued: 2009
Towards knowing through doing : improving the societal relevance of systematic conservation assessments
- Authors: Knight, Andrew Thomas
- Date: 2007
- Subjects: Conservation of natural resources -- Planning , Nature conservation -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10598 , http://hdl.handle.net/10948/711 , Conservation of natural resources -- Planning , Nature conservation -- South Africa
- Description: Systematic conservation assessments are spatially-explicit techniques for prioritising areas for the implementation of conservation action. There has been considerable reference in the peer-reviewed literature as to the usefulness of these tools, which appear to be primarily used by academics for theoretical research. A literature review and author survey reveals the peer-reviewed literature is largely theoretical, although conservation action results more frequently than reported. The effectiveness of these interventions is generally described as only ‘fairly effective’. This general trend, coupled with previous personal failures in translating systematic conservation assessments into effective conservation action triggered an explicit process of social learning implemented as action research. It examined the workings of the Subtropical Thicket Ecosystem Planning (STEP) project, which included development of a systematic conservation assessment. Systematic conservations assessments simply provide information on where action should be implemented, and so are only useful if situated within broader operational models for conservation planning. Most operational models presented in the peer-reviewed literature are primarily focused upon the testing ecological data, not upon the delivery of conservation action. A new operational model for conservation planning is presented which more accurately reflects the ‘real-world’ process of conservation planning. An implementation strategy is an essential complement to a systematic conservation assessment. It describes how specific, explicitly-stated goals will be achieved, who is accountable for undertaking these activities, and the resources required. As the Implementation Specialist for the STEP Project, I co-lead the collaborative development of an implementation strategy with stakeholders that aimed to mobilise resources towards achieving common goals. Whilst the development and initial uptake of the strategy was good, subsequent implementation has flounder. The reasons for this are explored. The ultimate pragmatic goal of a conservation planning process is the establishment of effective social learning institutions. These develop common visions, mobilise collective action, and adaptively learn and refine their conservation activities. Thicket Forum is one xi such institution established through the STEP Project. My involvement with Thicket Forum since 2004 in implementing an adaptive learning approach facilitates collaboration between land managers, government and research organisations. Systematic conservation assessments evolved in response to the ad hoc way in which protected areas were implemented, leaving unrepresentative, biased protected area networks. Most research is theoretical and without an intimate understanding of the social-ecological system of a planning region, notably opportunities and constraints for implementing conservation action. Highlighting the importance of an approach which is flexible, not only in space, but in time, which can capitalise upon implementation opportunities, is important for stemming the myth that opportunism is the nemesis of systematic conservation assessments. To this end, conservation planners have been slow to include factors influencing effective implementation in systematic conservation assessments. Many studies which identify candidate protected area networks, first, fail to identify the specific instrument(s) to be applied, and second, assume all intact land is available. Having mapped the willingness of land managers in the Albany District, South Africa, to sell their land, it is demonstrated the majority of targets fail to be achieved because land managers will not sell. Knowing this, the current focus of gathering ever-more ecological data is misplaced. Human, social and economic factors influence target achievement, efficiency and spatial configuration of priority areas. Selecting important areas for conservation, particularly at the local-scale, requires the mapping of factors which define opportunities for conservation. Land manager willingness to collaborate and participate, entrepreneurial orientation, conservation knowledge, social capital, and local champions were applied using a method of hierarchical clustering to identify land managers who represent conservation opportunities for private land conservation initiatives.
- Full Text:
- Date Issued: 2007
- Authors: Knight, Andrew Thomas
- Date: 2007
- Subjects: Conservation of natural resources -- Planning , Nature conservation -- South Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10598 , http://hdl.handle.net/10948/711 , Conservation of natural resources -- Planning , Nature conservation -- South Africa
- Description: Systematic conservation assessments are spatially-explicit techniques for prioritising areas for the implementation of conservation action. There has been considerable reference in the peer-reviewed literature as to the usefulness of these tools, which appear to be primarily used by academics for theoretical research. A literature review and author survey reveals the peer-reviewed literature is largely theoretical, although conservation action results more frequently than reported. The effectiveness of these interventions is generally described as only ‘fairly effective’. This general trend, coupled with previous personal failures in translating systematic conservation assessments into effective conservation action triggered an explicit process of social learning implemented as action research. It examined the workings of the Subtropical Thicket Ecosystem Planning (STEP) project, which included development of a systematic conservation assessment. Systematic conservations assessments simply provide information on where action should be implemented, and so are only useful if situated within broader operational models for conservation planning. Most operational models presented in the peer-reviewed literature are primarily focused upon the testing ecological data, not upon the delivery of conservation action. A new operational model for conservation planning is presented which more accurately reflects the ‘real-world’ process of conservation planning. An implementation strategy is an essential complement to a systematic conservation assessment. It describes how specific, explicitly-stated goals will be achieved, who is accountable for undertaking these activities, and the resources required. As the Implementation Specialist for the STEP Project, I co-lead the collaborative development of an implementation strategy with stakeholders that aimed to mobilise resources towards achieving common goals. Whilst the development and initial uptake of the strategy was good, subsequent implementation has flounder. The reasons for this are explored. The ultimate pragmatic goal of a conservation planning process is the establishment of effective social learning institutions. These develop common visions, mobilise collective action, and adaptively learn and refine their conservation activities. Thicket Forum is one xi such institution established through the STEP Project. My involvement with Thicket Forum since 2004 in implementing an adaptive learning approach facilitates collaboration between land managers, government and research organisations. Systematic conservation assessments evolved in response to the ad hoc way in which protected areas were implemented, leaving unrepresentative, biased protected area networks. Most research is theoretical and without an intimate understanding of the social-ecological system of a planning region, notably opportunities and constraints for implementing conservation action. Highlighting the importance of an approach which is flexible, not only in space, but in time, which can capitalise upon implementation opportunities, is important for stemming the myth that opportunism is the nemesis of systematic conservation assessments. To this end, conservation planners have been slow to include factors influencing effective implementation in systematic conservation assessments. Many studies which identify candidate protected area networks, first, fail to identify the specific instrument(s) to be applied, and second, assume all intact land is available. Having mapped the willingness of land managers in the Albany District, South Africa, to sell their land, it is demonstrated the majority of targets fail to be achieved because land managers will not sell. Knowing this, the current focus of gathering ever-more ecological data is misplaced. Human, social and economic factors influence target achievement, efficiency and spatial configuration of priority areas. Selecting important areas for conservation, particularly at the local-scale, requires the mapping of factors which define opportunities for conservation. Land manager willingness to collaborate and participate, entrepreneurial orientation, conservation knowledge, social capital, and local champions were applied using a method of hierarchical clustering to identify land managers who represent conservation opportunities for private land conservation initiatives.
- Full Text:
- Date Issued: 2007
Rhenium complexes with pontentially multidentate ligands containing the amino, imino, hydroxy and thiol groups
- Authors: Mukiza, Janvier
- Date: 2016
- Subjects: Rhenium Thiols Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/12308 , vital:27053
- Description: The chemistry of rhenium has received considerable interest due to its versatility in various catalytic applications, fixation and especially the potential use of 186Re and 188Re radionuclides in nuclear medicine. This study investigates the synthesis and characterisation of rhenium complexes with potentially multidentate ligands containing the amino, imino, hydroxyl and thiol groups. It reports new rhenium complexes in the +1, +3, +4 and +5 oxidation states, which display structural diversity, from monomers to ligand-bridged dimers as well as metal-metal multiply bonded dimers. The reaction of orotic acid (H2oa) and 2-mercapto-orotic acid (H2moa) with trans- [ReOX3(PPh3)2] (X = Cl, Br) were studied and led to the formation of ligand-bridged dimers with metal-metal multiple bonds i.e. (μ-Br)(μ-O)(μ-oa)[Re2 IVBr(OEt)2(PPh3)2], (μ-X)(μ-O)(μ-oa)[Re2 IVX2(OiPr)(PPh3)2] and (μ-Cl)(μ-O)(μ-moa)2[Re(PPh3)]2. The reaction of H2oa with [ReO2(py)4]Cl, [Re(dab)Br3(PPh3)2] (H2dab = 1,2- diaminobenzene) and [Re(CO)5Cl] were also studied and monomeric complexes [ReO(py)2(OEt)(oa)], [Re(dab)Br(oa)(PPh3)2] and (Ph4P)[Re(CO)3(H2O)(oa)] were isolated. The treatment of 5-amino-orotic acid (H2aoa) with [ReOBr3(PPh3)2] led to dimers with metal-metal triple bonds ReIV≡ReIV i.e. (μ-Br)(μ-O)(μ-oa)[Re2 IVBr(OEt)2(PPh3)2], (μ-Br)(μ-O)(μ-oa)[Re2 IVBr2(OiPr)(PPh3)2], as well as the monomer [ReV(apd)Br(aoa)(PPh3)2] (apd2− = 5-imidopyrimidine-2,4-dione). The chelating ligand 5-aminopyrimidine-2,4-dione (H2apd) was formed by oxorhenium(V)-catalysed decarboxylation of 5-amino-orotic acid (H2aoa) (see Scheme 1). The reaction of the Schiff base derivative of 5-amino-ortic acid, salicylimine-orotic acid (H2soa), with trans-[ReOI2(OEt)(PPh3)2] in ethanol was also investigated and led to the formation of the rhenium(III) complex salt [Re(coa)I(PPh3)2]I [Hcoa = 5-(2- hydroxybenzylideneamino)pyrimidine-2,4(1H,3H)-dione]. The chelating Hcoa is also formed from the oxorhenium(V)-catalysed decarboxylation of H2soa and coordinates to the rhenium(III) ion as a monoanionic tridentate N,O,O-donor chelate via the phenolate and ketonic oxygens, and the imino nitrogen atom. However, decarboxylation of H2soa was not observed in its reaction with [ReOCl3(PPh3)2], which led to the isolation of [ReOCl(soa)(PPh3)]. The reaction of the carboxamide derivative of 5-aminoorotic acid, 5-(5-aminopyrimidine-2,4(1H,3H)- dioxamido)-1,2,3,6-tetrahedro-2,6-dioxopyrimidine-4-carboxylic acid (H2ampa) with [Re(CO)5Cl] in ethanol led to the formation of a zwitterionic rhenium(I) complex [Re(CO)3(H2O)(amef)] [amef = {5-(5-ammoniumpyrimidine-2,4(1H,3H)-dioxamido)- 1,2,3,6-tetrahedro-2,6-dioxopyrimidine-4-ethylformate}]. The chelating ion amef was formed from the combined tricarbonylrhenium(I)-catalysed esterification and aminoprotonation of H2ampa (see Scheme 1) and coordinates to the fac-[Re(CO)3]+ core as a dianionic bidentate N,N-donor chelate via the amido nitrgens.
- Full Text:
- Date Issued: 2016
- Authors: Mukiza, Janvier
- Date: 2016
- Subjects: Rhenium Thiols Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/12308 , vital:27053
- Description: The chemistry of rhenium has received considerable interest due to its versatility in various catalytic applications, fixation and especially the potential use of 186Re and 188Re radionuclides in nuclear medicine. This study investigates the synthesis and characterisation of rhenium complexes with potentially multidentate ligands containing the amino, imino, hydroxyl and thiol groups. It reports new rhenium complexes in the +1, +3, +4 and +5 oxidation states, which display structural diversity, from monomers to ligand-bridged dimers as well as metal-metal multiply bonded dimers. The reaction of orotic acid (H2oa) and 2-mercapto-orotic acid (H2moa) with trans- [ReOX3(PPh3)2] (X = Cl, Br) were studied and led to the formation of ligand-bridged dimers with metal-metal multiple bonds i.e. (μ-Br)(μ-O)(μ-oa)[Re2 IVBr(OEt)2(PPh3)2], (μ-X)(μ-O)(μ-oa)[Re2 IVX2(OiPr)(PPh3)2] and (μ-Cl)(μ-O)(μ-moa)2[Re(PPh3)]2. The reaction of H2oa with [ReO2(py)4]Cl, [Re(dab)Br3(PPh3)2] (H2dab = 1,2- diaminobenzene) and [Re(CO)5Cl] were also studied and monomeric complexes [ReO(py)2(OEt)(oa)], [Re(dab)Br(oa)(PPh3)2] and (Ph4P)[Re(CO)3(H2O)(oa)] were isolated. The treatment of 5-amino-orotic acid (H2aoa) with [ReOBr3(PPh3)2] led to dimers with metal-metal triple bonds ReIV≡ReIV i.e. (μ-Br)(μ-O)(μ-oa)[Re2 IVBr(OEt)2(PPh3)2], (μ-Br)(μ-O)(μ-oa)[Re2 IVBr2(OiPr)(PPh3)2], as well as the monomer [ReV(apd)Br(aoa)(PPh3)2] (apd2− = 5-imidopyrimidine-2,4-dione). The chelating ligand 5-aminopyrimidine-2,4-dione (H2apd) was formed by oxorhenium(V)-catalysed decarboxylation of 5-amino-orotic acid (H2aoa) (see Scheme 1). The reaction of the Schiff base derivative of 5-amino-ortic acid, salicylimine-orotic acid (H2soa), with trans-[ReOI2(OEt)(PPh3)2] in ethanol was also investigated and led to the formation of the rhenium(III) complex salt [Re(coa)I(PPh3)2]I [Hcoa = 5-(2- hydroxybenzylideneamino)pyrimidine-2,4(1H,3H)-dione]. The chelating Hcoa is also formed from the oxorhenium(V)-catalysed decarboxylation of H2soa and coordinates to the rhenium(III) ion as a monoanionic tridentate N,O,O-donor chelate via the phenolate and ketonic oxygens, and the imino nitrogen atom. However, decarboxylation of H2soa was not observed in its reaction with [ReOCl3(PPh3)2], which led to the isolation of [ReOCl(soa)(PPh3)]. The reaction of the carboxamide derivative of 5-aminoorotic acid, 5-(5-aminopyrimidine-2,4(1H,3H)- dioxamido)-1,2,3,6-tetrahedro-2,6-dioxopyrimidine-4-carboxylic acid (H2ampa) with [Re(CO)5Cl] in ethanol led to the formation of a zwitterionic rhenium(I) complex [Re(CO)3(H2O)(amef)] [amef = {5-(5-ammoniumpyrimidine-2,4(1H,3H)-dioxamido)- 1,2,3,6-tetrahedro-2,6-dioxopyrimidine-4-ethylformate}]. The chelating ion amef was formed from the combined tricarbonylrhenium(I)-catalysed esterification and aminoprotonation of H2ampa (see Scheme 1) and coordinates to the fac-[Re(CO)3]+ core as a dianionic bidentate N,N-donor chelate via the amido nitrgens.
- Full Text:
- Date Issued: 2016
Biofuel, land-use tradeoffs and livelihoods in Southern Africa
- Authors: Von Maltitz, Graham Paul
- Date: 2014
- Subjects: Biomass energy -- Climatic factors -- Africa, Southern , Land use -- Environmental aspects , Jatropha -- Africa, Southern
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10643 , http://hdl.handle.net/10948/d1021005
- Description: The rapid expansion of biofuel projects in southern Africa creates an opportune issue against which to examine land-use tradeoffs within the areas of customary land tenure. For this an ecosystems services approach is used. Jatropha curcas (L), a perennial oilseed plant which has been the key focus of most of the region’s biofuel expansion to date is used as the focus biofuel crop for which case study data were obtained from Malawi, Mozambique, Zambia and South Africa. Despite the initial enthusiasm for jatropha, most projects have proven less successful than hoped, and many have collapsed. A few are, however, still showing signs of possible success and it is two of these that form the basis of the case studies. Hugely complex tradeoffs are involved when considering biofuel as a land-use option for communal areas. They range from global impacts such as biodiversity and global climate forcing, through national concerns of rural development, national food security and national fuel security, to local household concerns around improving livelihoods. Land that is converted to biofuel needs to be removed from some previous use, and in the southern African case it is typically woodlands and the multitude of services they provide, that suffer. The nature of the tradeoffs and the people affected change over the scale under consideration. For the local farmer it is only the local issues that are of concern, but national and global forces will change the policy environment and lead to new types of development such as biofuels. Change is inevitable, and in all developments there are likely to be both winners and losers. It is clear that the impacts arising from biofuel are situation dependent, and each community and location has unique social and environmental considerations that need to be taken into account. In the case of jatropha the final realised yield and the economic returns that this can generate, will be of critical importance and remain one of the main uncertainties. There are promising signs that under certain circumstances the balance of benefits from jatropha biofuel may be positive, but if implemented incorrectly or in the wrong place, there is extensive evidence of total project failure. It is clear that evidence-based data and assessment tools are needed to assist communities, developers and government departments to make sound decisions around biofuel (or other land-use based) development. A number of such tools are suggested in the thesis. Both the use of large-scale plantations or small-scale farmer centred projects have their advantages and disadvantages. It is probable that in the correct circumstances either can work. However, large-scale plantations can have huge negative social and environmental consequences if poorly implemented. Small-scale projects, though improving livelihoods, are unlikely to take the farmers out of poverty. Tradeoffs from any land-use change are inevitable. Empirical data on biofuel impacts on the environment and society are needed for the development of sound policy. A favourable policy environment can ensure that positive benefits from biofuel are obtained, whilst minimising negative impacts. To develop this policy means that southern African countries will have to clearly understand what they wish to achieve from biofuel, as well as having a clear understanding of impacts from biofuel implementation. Sound scientific knowledge needs to underpin this process. For instance governments may wish to increase the ratio of small-scale to large-scale plantation to increase the developmental benefits, ensure biofuel is used to promote national fuel security rather than being exported, or develop a medium-scale farming sector which can help move farmers out of poverty and assist in developing a market surplus of agricultural commodities. Analysing impacts from biofuel expansion is a complex and multi-dimensional problem and as such will require multi-criteria analysis tools to develop solutions. Global, national and local tradeoffs must all be considered. In addition a wide range of stakeholders are involved and participatory processes may be needed to capture their inputs. Tools to better analyse impacts, specifically at the local level are needed. These local results need to feed into national level economic assessments. The cost of biofuel introduction should be considered against the costs of not implementing biofuel, realising that doing nothing also has a cost and long-term impact. Third-party certification provides a useful tool for shifting costs of ensuring compliance with social and environmental legislation, from the state to biofuel companies. In addition ongoing monitoring and evaluation of existing projects is needed to learn from successes and failures, to identify unintended consequences, and to increase the resilience of projects, community livelihoods and the national economy. This will have to be supplemented with additional focused and ongoing research.
- Full Text:
- Date Issued: 2014
- Authors: Von Maltitz, Graham Paul
- Date: 2014
- Subjects: Biomass energy -- Climatic factors -- Africa, Southern , Land use -- Environmental aspects , Jatropha -- Africa, Southern
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10643 , http://hdl.handle.net/10948/d1021005
- Description: The rapid expansion of biofuel projects in southern Africa creates an opportune issue against which to examine land-use tradeoffs within the areas of customary land tenure. For this an ecosystems services approach is used. Jatropha curcas (L), a perennial oilseed plant which has been the key focus of most of the region’s biofuel expansion to date is used as the focus biofuel crop for which case study data were obtained from Malawi, Mozambique, Zambia and South Africa. Despite the initial enthusiasm for jatropha, most projects have proven less successful than hoped, and many have collapsed. A few are, however, still showing signs of possible success and it is two of these that form the basis of the case studies. Hugely complex tradeoffs are involved when considering biofuel as a land-use option for communal areas. They range from global impacts such as biodiversity and global climate forcing, through national concerns of rural development, national food security and national fuel security, to local household concerns around improving livelihoods. Land that is converted to biofuel needs to be removed from some previous use, and in the southern African case it is typically woodlands and the multitude of services they provide, that suffer. The nature of the tradeoffs and the people affected change over the scale under consideration. For the local farmer it is only the local issues that are of concern, but national and global forces will change the policy environment and lead to new types of development such as biofuels. Change is inevitable, and in all developments there are likely to be both winners and losers. It is clear that the impacts arising from biofuel are situation dependent, and each community and location has unique social and environmental considerations that need to be taken into account. In the case of jatropha the final realised yield and the economic returns that this can generate, will be of critical importance and remain one of the main uncertainties. There are promising signs that under certain circumstances the balance of benefits from jatropha biofuel may be positive, but if implemented incorrectly or in the wrong place, there is extensive evidence of total project failure. It is clear that evidence-based data and assessment tools are needed to assist communities, developers and government departments to make sound decisions around biofuel (or other land-use based) development. A number of such tools are suggested in the thesis. Both the use of large-scale plantations or small-scale farmer centred projects have their advantages and disadvantages. It is probable that in the correct circumstances either can work. However, large-scale plantations can have huge negative social and environmental consequences if poorly implemented. Small-scale projects, though improving livelihoods, are unlikely to take the farmers out of poverty. Tradeoffs from any land-use change are inevitable. Empirical data on biofuel impacts on the environment and society are needed for the development of sound policy. A favourable policy environment can ensure that positive benefits from biofuel are obtained, whilst minimising negative impacts. To develop this policy means that southern African countries will have to clearly understand what they wish to achieve from biofuel, as well as having a clear understanding of impacts from biofuel implementation. Sound scientific knowledge needs to underpin this process. For instance governments may wish to increase the ratio of small-scale to large-scale plantation to increase the developmental benefits, ensure biofuel is used to promote national fuel security rather than being exported, or develop a medium-scale farming sector which can help move farmers out of poverty and assist in developing a market surplus of agricultural commodities. Analysing impacts from biofuel expansion is a complex and multi-dimensional problem and as such will require multi-criteria analysis tools to develop solutions. Global, national and local tradeoffs must all be considered. In addition a wide range of stakeholders are involved and participatory processes may be needed to capture their inputs. Tools to better analyse impacts, specifically at the local level are needed. These local results need to feed into national level economic assessments. The cost of biofuel introduction should be considered against the costs of not implementing biofuel, realising that doing nothing also has a cost and long-term impact. Third-party certification provides a useful tool for shifting costs of ensuring compliance with social and environmental legislation, from the state to biofuel companies. In addition ongoing monitoring and evaluation of existing projects is needed to learn from successes and failures, to identify unintended consequences, and to increase the resilience of projects, community livelihoods and the national economy. This will have to be supplemented with additional focused and ongoing research.
- Full Text:
- Date Issued: 2014
Cheetah Acinonyx jubatus behaviour and resource use in response to other African large carnivores
- Authors: Cornhill, Kristina
- Date: 2019
- Subjects: Cheetahs -- Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/44735 , vital:38169
- Description: Competition occurs between species for shared resources. Subordinate species employ resource selection to shift their resource use away from that of dominant species in order to avoid the negative consequences of competition. Only in Africa is the post-Pleistocene large carnivore guild intact, consisting of lions Panthera leo, spotted hyaenas Crocuta crocuta, leopards Panthera pardus, cheetahs Acinonyx jubatus, and African wild dogs Lycaon pictus. Therefore, only in Africa can we explore how large carnivores co-exist with one another in a diverse community. Cheetahs are a subordinate member of the large carnivore guild due to their small stature and solitary nature. However, we still do not fully understand how competition shapes cheetah behaviour and resource use. I used cheetahs as a model subordinate predator to determine the behavioural responses and resource selection of cheetah in response to assumed competition from other large carnivores. I experimentally explored the behavioural response of cheetah to large carnivore scent sources (scats) and their presence at cheetah scent-marking sites to test for avoidance of such cues. Moreover, using unplanned experiments based on the resource use of cheetahs in the absence and then presence of lions (assessing space and time use by cheetah) and African wild dogs (assessing prey use by both species), I evaluated resource selection by cheetahs as a way to reduce competition with these large carnivores. In addition, I measured spatial and temporal partitioning between cheetahs and all four large carnivores at camera trap sites. Finally, I assessed whether cheetahs responded to competitors using a long term proactive response or a short term reactive response. I found that all four of the other large carnivores in the guild shaped cheetahs resource use, however, all did so on different axes in accordance with the niche complementarity hypothesis. Lions and spotted hyenas were avoided through time, African wild dogs through space and prey use, and lions and leopards on the spatiotemporal axis. Moreover, I show that cheetahs utilize a reactive response to competition that allows them to avoid risk while still obtaining necessary resources.
- Full Text:
- Date Issued: 2019
- Authors: Cornhill, Kristina
- Date: 2019
- Subjects: Cheetahs -- Africa
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/44735 , vital:38169
- Description: Competition occurs between species for shared resources. Subordinate species employ resource selection to shift their resource use away from that of dominant species in order to avoid the negative consequences of competition. Only in Africa is the post-Pleistocene large carnivore guild intact, consisting of lions Panthera leo, spotted hyaenas Crocuta crocuta, leopards Panthera pardus, cheetahs Acinonyx jubatus, and African wild dogs Lycaon pictus. Therefore, only in Africa can we explore how large carnivores co-exist with one another in a diverse community. Cheetahs are a subordinate member of the large carnivore guild due to their small stature and solitary nature. However, we still do not fully understand how competition shapes cheetah behaviour and resource use. I used cheetahs as a model subordinate predator to determine the behavioural responses and resource selection of cheetah in response to assumed competition from other large carnivores. I experimentally explored the behavioural response of cheetah to large carnivore scent sources (scats) and their presence at cheetah scent-marking sites to test for avoidance of such cues. Moreover, using unplanned experiments based on the resource use of cheetahs in the absence and then presence of lions (assessing space and time use by cheetah) and African wild dogs (assessing prey use by both species), I evaluated resource selection by cheetahs as a way to reduce competition with these large carnivores. In addition, I measured spatial and temporal partitioning between cheetahs and all four large carnivores at camera trap sites. Finally, I assessed whether cheetahs responded to competitors using a long term proactive response or a short term reactive response. I found that all four of the other large carnivores in the guild shaped cheetahs resource use, however, all did so on different axes in accordance with the niche complementarity hypothesis. Lions and spotted hyenas were avoided through time, African wild dogs through space and prey use, and lions and leopards on the spatiotemporal axis. Moreover, I show that cheetahs utilize a reactive response to competition that allows them to avoid risk while still obtaining necessary resources.
- Full Text:
- Date Issued: 2019
Characterisation of photovoltaic devices using large area light beam induced current measurements
- Okullo, Michael, Van Dyk, Ernes, Okullo, W
- Authors: Okullo, Michael , Van Dyk, Ernes , Okullo, W
- Date: 2017
- Subjects: Photovoltaic cells Photovoltaic power generation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/20526 , vital:29314
- Description: Photovoltaic (PV) modules are made by connecting PV cells in series in order to generate a reasonable voltage that can be used for any productive work. Inaccuracy in cell sorting during crystalline silicon module construction, or non-uniform deposition of PV material and laser scribing during thin _lm module construction, may introduce current mismatch in the module. Current mismatch is a consequence of connecting module cells which have non-identical electrical characteristics. When current mismatch occurs in a module, it is the cell generating the lowest current that determines the module output current and this leads to a decrease in the output power and lifespan of the module. Investigation of current uniformity and the different current reducing features in PV modules, which are potential sources of current mismatch, is therefore critical in optimising the performance of PV modules. In this study, a large area light beam induced current (LA-LBIC) measurement system was developed. This non-destructive technique was used to characterise crystalline silicon PV modules (mono-crystalline and multi-crystalline), thin _lm PV modules (amorphous silicon and copper indium diselenide) and a combined concentrator photovoltaic (CPV) module. A light source mounted onto a motorised x-y scanning stage was used to illuminate a PV module, or the Fresnel lens of a CPV module, point-by-point, while measuring the module output current. The measured current was mapped as a function of position and presented as an LBIC image. The point-illuminated circuit model of a PV module was designed and used to explain the variation in current between and within module cells in the LA-LBIC maps. Application of the model to crystalline silicon modules attributes the variation in photo-generated current between cells mainly to current mismatch between series connected cells. Current variation within cells is attributed to individual cell shunts. In the thin _lm modules, the model attributes the variation in photo-generated current mainly to differences in local cell shunts and series resistances originating from the scribing procedure during cell formation in the manufacturing process. In the PV modules studied, variation in photo-generated current was found to exist both between and within cells. The variation was more pronounced between cells than within cells. Module point I-V curves at different points of the module were measured in order to extract short circuit current, to quantify the variations between and within cells. A striation ring defect, causing a drop in short circuit current of 38%, was detected in the mono-crystalline module. Investigation of the striation ring defect indicated that the defect is active in the bulk (p-type) but inactive in the top (n-type) layer. Further characterisation of the defect revealed that a higher percentage loss in short circuit current occurs at lower light intensities. In the multi-crystalline silicon module, cracks were detected and found to electrically isolate the module cells into two parts, causing them to operate in parallel and consequently introducing current mismatch in the module. The I-V curve of the module at standard test condition (STC) revealed a step below the knee, which is a manifestation of current mismatch in the module. High currents, as a consequence of diffuse reflection, leading to multiple reflections by the top glass were also observed at localised points on the bus bar and cell separations. In the a-Si module, the variation in photo-current within some cells, was found to be substantial. In the copper indium diselenide (CIS) module, an electrical disconnection across the module cells was identified. A disconnection in the form of a triangular shape was also identified in this module, which completely disconnected the front contact of this area from the module. This unique disconnection feature caused current in the module to follow in a reverse direction when the light spot was incident within the boundary of the disconnection. Scans performed under different forward voltage biases were useful in identifying severely shunted module cells. A severely shunted cell was found to generate a higher photo-current than a good cell at the same forward bias voltage. This unique observation was explored further using point-illuminated module I-V measurements, and was found to be due to the crossing over of the I-V curves of the two cells. In order to explore the relationship between cell photo-current and cell shunt resistance, a method to determine the shunt resistances of the cells in an encapsulated module was devised. The method involves measuring the I-V curves of a fully illuminated module and a partially illuminated module when one of its cells is shaded and the I-V curves used to determine the short circuit current and the shunt resistance of the shaded cell. A strong correlation was found to exist between the short circuit current of the shaded cell and the cell shunt resistance, as well as between the short circuit current of the shaded cell and dark LBIC. The LA-LBIC technique was further applied to characterise a combine CPV module. Results showed that the Fresnel lens facets close to the centre generate a higher photo-current at the receiver than those towards the edges. The reduced photo-current towards the edges was attributed to losses due to di_raction, dielectric reflection and internal re_ection. About 65% of the area of the Fresnel lenses were found to be e_ective in light collection in terms of the photo-current generated at the receiver. Abrasions and scratches on the Fresnel lenses were identi_ed as some of the current limiting features in a CPV module. The LA-LBIC technique used in this study has demonstrated the potential to investigate current mismatch, current limiting and current enhancing features in PV modules. The capacity to further characterise current limiting features in order to investigate their effects on photo-current under different wavelengths and light intensities was also demonstrated. Extending the LA-LBIC technique to characterise a combined CPV module is a great achievement of this work.
- Full Text:
- Date Issued: 2017
- Authors: Okullo, Michael , Van Dyk, Ernes , Okullo, W
- Date: 2017
- Subjects: Photovoltaic cells Photovoltaic power generation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/20526 , vital:29314
- Description: Photovoltaic (PV) modules are made by connecting PV cells in series in order to generate a reasonable voltage that can be used for any productive work. Inaccuracy in cell sorting during crystalline silicon module construction, or non-uniform deposition of PV material and laser scribing during thin _lm module construction, may introduce current mismatch in the module. Current mismatch is a consequence of connecting module cells which have non-identical electrical characteristics. When current mismatch occurs in a module, it is the cell generating the lowest current that determines the module output current and this leads to a decrease in the output power and lifespan of the module. Investigation of current uniformity and the different current reducing features in PV modules, which are potential sources of current mismatch, is therefore critical in optimising the performance of PV modules. In this study, a large area light beam induced current (LA-LBIC) measurement system was developed. This non-destructive technique was used to characterise crystalline silicon PV modules (mono-crystalline and multi-crystalline), thin _lm PV modules (amorphous silicon and copper indium diselenide) and a combined concentrator photovoltaic (CPV) module. A light source mounted onto a motorised x-y scanning stage was used to illuminate a PV module, or the Fresnel lens of a CPV module, point-by-point, while measuring the module output current. The measured current was mapped as a function of position and presented as an LBIC image. The point-illuminated circuit model of a PV module was designed and used to explain the variation in current between and within module cells in the LA-LBIC maps. Application of the model to crystalline silicon modules attributes the variation in photo-generated current between cells mainly to current mismatch between series connected cells. Current variation within cells is attributed to individual cell shunts. In the thin _lm modules, the model attributes the variation in photo-generated current mainly to differences in local cell shunts and series resistances originating from the scribing procedure during cell formation in the manufacturing process. In the PV modules studied, variation in photo-generated current was found to exist both between and within cells. The variation was more pronounced between cells than within cells. Module point I-V curves at different points of the module were measured in order to extract short circuit current, to quantify the variations between and within cells. A striation ring defect, causing a drop in short circuit current of 38%, was detected in the mono-crystalline module. Investigation of the striation ring defect indicated that the defect is active in the bulk (p-type) but inactive in the top (n-type) layer. Further characterisation of the defect revealed that a higher percentage loss in short circuit current occurs at lower light intensities. In the multi-crystalline silicon module, cracks were detected and found to electrically isolate the module cells into two parts, causing them to operate in parallel and consequently introducing current mismatch in the module. The I-V curve of the module at standard test condition (STC) revealed a step below the knee, which is a manifestation of current mismatch in the module. High currents, as a consequence of diffuse reflection, leading to multiple reflections by the top glass were also observed at localised points on the bus bar and cell separations. In the a-Si module, the variation in photo-current within some cells, was found to be substantial. In the copper indium diselenide (CIS) module, an electrical disconnection across the module cells was identified. A disconnection in the form of a triangular shape was also identified in this module, which completely disconnected the front contact of this area from the module. This unique disconnection feature caused current in the module to follow in a reverse direction when the light spot was incident within the boundary of the disconnection. Scans performed under different forward voltage biases were useful in identifying severely shunted module cells. A severely shunted cell was found to generate a higher photo-current than a good cell at the same forward bias voltage. This unique observation was explored further using point-illuminated module I-V measurements, and was found to be due to the crossing over of the I-V curves of the two cells. In order to explore the relationship between cell photo-current and cell shunt resistance, a method to determine the shunt resistances of the cells in an encapsulated module was devised. The method involves measuring the I-V curves of a fully illuminated module and a partially illuminated module when one of its cells is shaded and the I-V curves used to determine the short circuit current and the shunt resistance of the shaded cell. A strong correlation was found to exist between the short circuit current of the shaded cell and the cell shunt resistance, as well as between the short circuit current of the shaded cell and dark LBIC. The LA-LBIC technique was further applied to characterise a combine CPV module. Results showed that the Fresnel lens facets close to the centre generate a higher photo-current at the receiver than those towards the edges. The reduced photo-current towards the edges was attributed to losses due to di_raction, dielectric reflection and internal re_ection. About 65% of the area of the Fresnel lenses were found to be e_ective in light collection in terms of the photo-current generated at the receiver. Abrasions and scratches on the Fresnel lenses were identi_ed as some of the current limiting features in a CPV module. The LA-LBIC technique used in this study has demonstrated the potential to investigate current mismatch, current limiting and current enhancing features in PV modules. The capacity to further characterise current limiting features in order to investigate their effects on photo-current under different wavelengths and light intensities was also demonstrated. Extending the LA-LBIC technique to characterise a combined CPV module is a great achievement of this work.
- Full Text:
- Date Issued: 2017
A combination of platinum anticancer drugs and mangiferin causes increased efficacy in cancer cell lines
- Authors: Du Plessis-Stoman, Debbie
- Date: 2010
- Subjects: Cancer -- Chemotherapy , Antineoplastic agents , Platinum compounds -- Therapeutic use , Cancer cells
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10338 , http://hdl.handle.net/10948/d1016160
- Description: This thesis mainly deals with some biochemical aspects regarding the efficacy of novel platinum anticancer compounds alone and in combination with mangiferin, as part of a broader study in which both chemistry and biochemistry are involved. Various novel diamine and N-S donor chelate compounds of platinum II and IV have been developed in which factors such as stereochemistry, ligand exchange rate and biocompatibility were considered as additional parameters. In the first order testing, each of these compounds was tested with reference to their “killing” potential by comparing their rate of killing, over a period of 48 hours with those of cisplatin and oxaliplatin. Numerous novel compounds were tested in this way, using the MTT cell viability assay and the three cancer cell lines MCF7, HT29 and HeLa. Although only a few could be regarded as equal to or even better than cisplatin, CPA7 and oxaliplatin, the testing of these compounds on cancer cells provided useful knowledge for the further development of novel compounds. Three of the better compounds, namely Yol 25, Yol 29.1 and Mar 4.1.4 were selected for further studies, together with oxaliplatin and CPA7 as positive controls, to obtain more detailed knowledge of their anticancer action, both alone and when applied in combination with mangiferin. In addition to the above, resistant cells were produced for each of the three different cell lines tested and all the selected compounds, both in the presence and absence of mangiferin. The effects of these treatments on the activation of NFĸB when applied to normal and resistant cell lines were also investigated. All the compounds induced apoptosis in the cell lines tested as well as alter the DNA cycle at one or more phase. Additionally, combination of these compounds with mangiferin enhanced the above-mentioned effects. Mangiferin decreases the IC50 values of the platinum drugs by up to 3.4 times and, although mangiferin alone did not induce cell cycle arrest, the presence of mangiferin in combination with oxaliplatin and Yol 25 shows an earlier and greatly enhanced delay in the S-phase, while cells treated with CPA7, Yol 29.1 and Mar 4.1.4 in combination with mangiferin showed a later, but greatly enhanced delay in the S-phase. It was also found that mangiferin acts as an NFĸB inhibitor when applied in combination with these drugs, which, in turn, reduces the occurrence of resistance in the cell lines. Resistance to oxaliplatin was counteracted by the combination with mangiferin in HeLa and HT29, but not in MCF7 cells, while resistance to CPA7 was only counteracted in the MCF7 cell line. Yol 25 and Mar 4.1.4 did not seem to induce resistance in HeLa and MCF7 cells, but did in HT29 cells, whereas Yol 29.1 caused resistance in HeLa and HT29 cells, but not in MCF7 cells. Finally, an effort was made to evaluate the different compounds by comparing them with respect to their properties relating to anticancer action with and without the addition of mangiferin.
- Full Text:
- Date Issued: 2010
- Authors: Du Plessis-Stoman, Debbie
- Date: 2010
- Subjects: Cancer -- Chemotherapy , Antineoplastic agents , Platinum compounds -- Therapeutic use , Cancer cells
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10338 , http://hdl.handle.net/10948/d1016160
- Description: This thesis mainly deals with some biochemical aspects regarding the efficacy of novel platinum anticancer compounds alone and in combination with mangiferin, as part of a broader study in which both chemistry and biochemistry are involved. Various novel diamine and N-S donor chelate compounds of platinum II and IV have been developed in which factors such as stereochemistry, ligand exchange rate and biocompatibility were considered as additional parameters. In the first order testing, each of these compounds was tested with reference to their “killing” potential by comparing their rate of killing, over a period of 48 hours with those of cisplatin and oxaliplatin. Numerous novel compounds were tested in this way, using the MTT cell viability assay and the three cancer cell lines MCF7, HT29 and HeLa. Although only a few could be regarded as equal to or even better than cisplatin, CPA7 and oxaliplatin, the testing of these compounds on cancer cells provided useful knowledge for the further development of novel compounds. Three of the better compounds, namely Yol 25, Yol 29.1 and Mar 4.1.4 were selected for further studies, together with oxaliplatin and CPA7 as positive controls, to obtain more detailed knowledge of their anticancer action, both alone and when applied in combination with mangiferin. In addition to the above, resistant cells were produced for each of the three different cell lines tested and all the selected compounds, both in the presence and absence of mangiferin. The effects of these treatments on the activation of NFĸB when applied to normal and resistant cell lines were also investigated. All the compounds induced apoptosis in the cell lines tested as well as alter the DNA cycle at one or more phase. Additionally, combination of these compounds with mangiferin enhanced the above-mentioned effects. Mangiferin decreases the IC50 values of the platinum drugs by up to 3.4 times and, although mangiferin alone did not induce cell cycle arrest, the presence of mangiferin in combination with oxaliplatin and Yol 25 shows an earlier and greatly enhanced delay in the S-phase, while cells treated with CPA7, Yol 29.1 and Mar 4.1.4 in combination with mangiferin showed a later, but greatly enhanced delay in the S-phase. It was also found that mangiferin acts as an NFĸB inhibitor when applied in combination with these drugs, which, in turn, reduces the occurrence of resistance in the cell lines. Resistance to oxaliplatin was counteracted by the combination with mangiferin in HeLa and HT29, but not in MCF7 cells, while resistance to CPA7 was only counteracted in the MCF7 cell line. Yol 25 and Mar 4.1.4 did not seem to induce resistance in HeLa and MCF7 cells, but did in HT29 cells, whereas Yol 29.1 caused resistance in HeLa and HT29 cells, but not in MCF7 cells. Finally, an effort was made to evaluate the different compounds by comparing them with respect to their properties relating to anticancer action with and without the addition of mangiferin.
- Full Text:
- Date Issued: 2010
Synthesis, crystal structures and molecular modelling of rare earth complexes with bis(2-pyridylmethyl)amine and its derivatives : a quantum chemical investigation of ligand conformational space, complex intramolecular rearrangement and stability
- Authors: Matthews, Cameron
- Date: 2020
- Subjects: Rare earths , Complex compounds , Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/46229 , vital:39517
- Description: Limited research has been performed on the coordination behaviour of hybrid aliphatic and heterocyclic polyamines with trivalent rare earth elements. The rare earth coordination properties of several Nalkylated derivatives of the tridentate ligand bis(2-pyridylmethyl)amine (DPA, HL1) backbone - involving the rare earth elements Y, La-Nd, Sm, Eu and Tb-Lu - have been investigated in this study However, the structural and energetic characteristics of DPA coordination with rare earth elements (REE) have not been studied thus far. Potential applications of DPA-based rare earth complexes are primarily dependent on their electronic and magnetic characteristics, which are affected weakly by the coordination environment, where potential applications may include use as Lanthanide Shift Reagents (LSR), Luminescence probes and small-molecule magnets (SMM). A systematic conformational search of DPA was carried out in this study in order to identify the global minimum conformer and for comparison of the free and coordinated geometries, using the M06(D3) functional belonging to the Density Functional Theory (DFT) family of model chemistries. An understanding of the aforementioned would play an important role in analysis of bulk characterization and the prediction of the reactivity of DPA. Final geometries and electronic energies were obtained from the ‘domain based local pair natural orbital’ (DLPNO)-Møller-Plesset and -coupled cluster theoretical methods, as follows: DLPNO-CCSD(T0)/aug-cc-pVQZ//DLPNO-MP2/aug-cc-pVTZ. Fifteen Single-crystal X-ray diffractometer (SC-XRD) crystal structures of mononuclear rare earth chloride coordination complexes with DPA (RE = La-Nd, Sm, Eu, Tb-Lu and Y) were obtained and geometrically analysed in this study. Three isostructural series of constitutional isomers were identified, consisting of one series of nine-coordinate molecule (M1) and two series of eight-coordinate ion pairs (M2 and M3). This conformational diversity is most likely due the flexible nature of the DPA backbone, as well as the additional stability gained from reduced coordination spheres as a function of decreasing rare earth ionic radii across the lanthanide series (Lanthanide contraction). A Quantum Theory of Atoms-in-Molecules (QTAIM) topological analysis was performed in order to identify and characterise potential hydrogen bonding interactions in H-optimised crystal structures. The crystal structures of five dinuclear (RE = Tb-Tm) and two tetranuclear (RE = Yb and Lu) rare earth chloride complexes with DPA have also been structurally analysed. Furthermore, one mononuclear (RE = Dy), two dinuclear complexes (RE = Dy and Lu) with EtDPA, and one mononuclear complex with the DPA-derivative HL4 (RE = Dy) were structurally characterised. A DFT study of the theoretical interconversion of one real- and two hypothetical- mononuclear lanthanum containing isostructural series (cf. aforementioned crystal structures) was undertaken in order to gain a deeper understanding of the processes involved, in terms of the participating minimum energy paths (MEPs), intermediates and transition states – as determined via the Nudged-Elastic Band (NEB) procedure. This hypothesis is supported by the well-known conformational lability of rare earth complexes, due to the weak/minor covalency of their coordination bonds. An attempt was made to determine the respective energies of one real- and two hypothetical diamagnetic or ‘closed-shell’ constitutional isomers containing the rare earth ions La3+(M1), Y3+(M2) and Lu3+ (M3). It was assumed that the most stable isomers have a greater probability of being observed as the asymmetric unit of the complex crystal structure – assuming weak contributions of lattice or intermolecular interactions towards the geometry of the asymmetric unit.
- Full Text:
- Date Issued: 2020
- Authors: Matthews, Cameron
- Date: 2020
- Subjects: Rare earths , Complex compounds , Ligands
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/46229 , vital:39517
- Description: Limited research has been performed on the coordination behaviour of hybrid aliphatic and heterocyclic polyamines with trivalent rare earth elements. The rare earth coordination properties of several Nalkylated derivatives of the tridentate ligand bis(2-pyridylmethyl)amine (DPA, HL1) backbone - involving the rare earth elements Y, La-Nd, Sm, Eu and Tb-Lu - have been investigated in this study However, the structural and energetic characteristics of DPA coordination with rare earth elements (REE) have not been studied thus far. Potential applications of DPA-based rare earth complexes are primarily dependent on their electronic and magnetic characteristics, which are affected weakly by the coordination environment, where potential applications may include use as Lanthanide Shift Reagents (LSR), Luminescence probes and small-molecule magnets (SMM). A systematic conformational search of DPA was carried out in this study in order to identify the global minimum conformer and for comparison of the free and coordinated geometries, using the M06(D3) functional belonging to the Density Functional Theory (DFT) family of model chemistries. An understanding of the aforementioned would play an important role in analysis of bulk characterization and the prediction of the reactivity of DPA. Final geometries and electronic energies were obtained from the ‘domain based local pair natural orbital’ (DLPNO)-Møller-Plesset and -coupled cluster theoretical methods, as follows: DLPNO-CCSD(T0)/aug-cc-pVQZ//DLPNO-MP2/aug-cc-pVTZ. Fifteen Single-crystal X-ray diffractometer (SC-XRD) crystal structures of mononuclear rare earth chloride coordination complexes with DPA (RE = La-Nd, Sm, Eu, Tb-Lu and Y) were obtained and geometrically analysed in this study. Three isostructural series of constitutional isomers were identified, consisting of one series of nine-coordinate molecule (M1) and two series of eight-coordinate ion pairs (M2 and M3). This conformational diversity is most likely due the flexible nature of the DPA backbone, as well as the additional stability gained from reduced coordination spheres as a function of decreasing rare earth ionic radii across the lanthanide series (Lanthanide contraction). A Quantum Theory of Atoms-in-Molecules (QTAIM) topological analysis was performed in order to identify and characterise potential hydrogen bonding interactions in H-optimised crystal structures. The crystal structures of five dinuclear (RE = Tb-Tm) and two tetranuclear (RE = Yb and Lu) rare earth chloride complexes with DPA have also been structurally analysed. Furthermore, one mononuclear (RE = Dy), two dinuclear complexes (RE = Dy and Lu) with EtDPA, and one mononuclear complex with the DPA-derivative HL4 (RE = Dy) were structurally characterised. A DFT study of the theoretical interconversion of one real- and two hypothetical- mononuclear lanthanum containing isostructural series (cf. aforementioned crystal structures) was undertaken in order to gain a deeper understanding of the processes involved, in terms of the participating minimum energy paths (MEPs), intermediates and transition states – as determined via the Nudged-Elastic Band (NEB) procedure. This hypothesis is supported by the well-known conformational lability of rare earth complexes, due to the weak/minor covalency of their coordination bonds. An attempt was made to determine the respective energies of one real- and two hypothetical diamagnetic or ‘closed-shell’ constitutional isomers containing the rare earth ions La3+(M1), Y3+(M2) and Lu3+ (M3). It was assumed that the most stable isomers have a greater probability of being observed as the asymmetric unit of the complex crystal structure – assuming weak contributions of lattice or intermolecular interactions towards the geometry of the asymmetric unit.
- Full Text:
- Date Issued: 2020
Synthesis, characterization and reactions of novel ferrocenylimidazoles as donor ligands
- Authors: Onyancha, Douglas Okerio
- Date: 2010
- Subjects: Ferrocene
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10390 , http://hdl.handle.net/10948/1150 , Ferrocene
- Description: In this project a series of ferrocenylimidazole derivatives were successfully prepared and characterized using an array of analytical techniques. Reactions of ferrocenylcarbinols with N,N′-thiocarbonyldiimidazole under both solvent-free conditions and in dichloromethane are described. The reaction of ferrocenylmethanol afforded S,S-bis(ferrocenylmethyl)dithiocarbonate, the reaction of α-substituted ferrocenylcarbinols provided ferrocenylalkylimidazolides, while ω-ferrocenylcarbinols yielded ferrocenylimidazolecarbothioates. The reactions were carried out under solvent-free conditions, consistent with the principles of Green Chemistry. Ferrocenyl benzyl ethers were successfully prepared by reacting 4-ferrocenylbenzyl-1Hcarboxylate with a series of primary alcohols under catalytic condition and under a catalyst– free environment. Refluxing a mixture of alcohol-water and 4-ferrocenylbenzyl-1Hcarboxylate provided the corresponding ethers in modest yields. The same ethers were obtained at room temperature by employing potassium tetrachloroplatinate or hydrochloric acid as catalyst. Ferrocenyl-1H-imidazole, 4-ferrocenylphenyl-1H-imidazole and their corresponding ferrocenyl-3-subsitituted imidazolium salts have been successfully synthesized. The compounds were characterized and the electrochemical properties of selected imidazolium salts were examined by cyclic voltammetry. Additionally, X-ray structures of two of the imidazolium salts were determined. The imidazolium salts were found to be good catalysts for the Heck and Suzuki cross-coupling reactions.
- Full Text:
- Date Issued: 2010
- Authors: Onyancha, Douglas Okerio
- Date: 2010
- Subjects: Ferrocene
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10390 , http://hdl.handle.net/10948/1150 , Ferrocene
- Description: In this project a series of ferrocenylimidazole derivatives were successfully prepared and characterized using an array of analytical techniques. Reactions of ferrocenylcarbinols with N,N′-thiocarbonyldiimidazole under both solvent-free conditions and in dichloromethane are described. The reaction of ferrocenylmethanol afforded S,S-bis(ferrocenylmethyl)dithiocarbonate, the reaction of α-substituted ferrocenylcarbinols provided ferrocenylalkylimidazolides, while ω-ferrocenylcarbinols yielded ferrocenylimidazolecarbothioates. The reactions were carried out under solvent-free conditions, consistent with the principles of Green Chemistry. Ferrocenyl benzyl ethers were successfully prepared by reacting 4-ferrocenylbenzyl-1Hcarboxylate with a series of primary alcohols under catalytic condition and under a catalyst– free environment. Refluxing a mixture of alcohol-water and 4-ferrocenylbenzyl-1Hcarboxylate provided the corresponding ethers in modest yields. The same ethers were obtained at room temperature by employing potassium tetrachloroplatinate or hydrochloric acid as catalyst. Ferrocenyl-1H-imidazole, 4-ferrocenylphenyl-1H-imidazole and their corresponding ferrocenyl-3-subsitituted imidazolium salts have been successfully synthesized. The compounds were characterized and the electrochemical properties of selected imidazolium salts were examined by cyclic voltammetry. Additionally, X-ray structures of two of the imidazolium salts were determined. The imidazolium salts were found to be good catalysts for the Heck and Suzuki cross-coupling reactions.
- Full Text:
- Date Issued: 2010
Characterisation and biotic classification of Eastern Cape mixed substrate shores
- Authors: Garner, Cornelia Johanna
- Date: 2013
- Subjects: Coastal sediments -- South Africa -- Eastern Cape , Coastal biodiversity --- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10641 , http://hdl.handle.net/10948/d1020825
- Description: A significant proportion of the South African coastline is composed of both soft (mostly sand) and hard (mostly bedrock) substrata, i.e. “mixed”. This study described and classified macrobenthic assemblages of 20 Eastern Cape mixed substrate shores that differed in shore topography and the extent and position of intertidal rock and sand. A stratified random approach was used. Species richness, composition, abundance and environmental variables were determined. Commonly used beach indices were calculated. A total of 78 macrofaunal and 172 macroalgal species from rock substrate assemblages and 205 macrofauna species from sediment were recorded. Total species richness and richness per substratum exceeded that of sandy beaches devoid of rock and rocky shores with no sand. Rhodophyta were the most diverse and abundant algae, dominating all low-elevation rock surfaces as midlittoral and infralittoral turfs. Chlorophyta diversity was higher than at rocky shores, contributing more to cover-abundance at study sites and in microhabitats with an increased sand load. Sessile macrofauna species richness and abundance was lower than that of rocky shores. Polychaetes and crustaceans were the most diverse and abundant beach infauna. Species richness of both substrates declined from the low shore towards the high shore, but abundance trends varied substantially. The presence and extent of an intertidal biotope/subzone at either substrate depended on substrate availability.The supralittoral fringe in both substrate types was most often affected. Zonal overlap was evident on rock substrate: assemblages of raised midlittoral rock surfaces were enriched by species from lower surfaces sometimes leading to elimination of character taxa. Classification and ordination identified three potential mixed substrate shore biotic types: Biotic type A (Jania-Corallina- Polysiphonia turf) was characterised by robustly-textured algal turfs, a lowered predominance and diversity of polychaetes and an increase in crustacean abundance and diversity in sediment. Biotic type B (Polysiphonia-Tayloriella-Caulacanthus turf) had intermediately and biotic type C (Arthrocardia-Laurencia turf) the most sheltered eulittoral zones and beaches. DCCA identified the major environmental parameters affecting the macrobiota as: the level of wave energy, geological control of waves by hard substrate, sediment grain size and sediment inundation. A strong cross-shore wave attenuation results in sheltered sediments and midshore rock surfaces. Beach macrofauna were highly variable and diverse, which directly opposes previous perceptions about the sediment-bound biota of mixed substrate shores. The hierarchical cluster analysis produced a biotic classification of mixed substrate shores that was indicative of a biotic response to the total effects of leading environmental parameters. Macrobenthos of rock surfaces and sediment therefore showed potential to be used as an alternative or complementary to physical characteristics in classifying mixed substrate shores.
- Full Text:
- Date Issued: 2013
- Authors: Garner, Cornelia Johanna
- Date: 2013
- Subjects: Coastal sediments -- South Africa -- Eastern Cape , Coastal biodiversity --- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10641 , http://hdl.handle.net/10948/d1020825
- Description: A significant proportion of the South African coastline is composed of both soft (mostly sand) and hard (mostly bedrock) substrata, i.e. “mixed”. This study described and classified macrobenthic assemblages of 20 Eastern Cape mixed substrate shores that differed in shore topography and the extent and position of intertidal rock and sand. A stratified random approach was used. Species richness, composition, abundance and environmental variables were determined. Commonly used beach indices were calculated. A total of 78 macrofaunal and 172 macroalgal species from rock substrate assemblages and 205 macrofauna species from sediment were recorded. Total species richness and richness per substratum exceeded that of sandy beaches devoid of rock and rocky shores with no sand. Rhodophyta were the most diverse and abundant algae, dominating all low-elevation rock surfaces as midlittoral and infralittoral turfs. Chlorophyta diversity was higher than at rocky shores, contributing more to cover-abundance at study sites and in microhabitats with an increased sand load. Sessile macrofauna species richness and abundance was lower than that of rocky shores. Polychaetes and crustaceans were the most diverse and abundant beach infauna. Species richness of both substrates declined from the low shore towards the high shore, but abundance trends varied substantially. The presence and extent of an intertidal biotope/subzone at either substrate depended on substrate availability.The supralittoral fringe in both substrate types was most often affected. Zonal overlap was evident on rock substrate: assemblages of raised midlittoral rock surfaces were enriched by species from lower surfaces sometimes leading to elimination of character taxa. Classification and ordination identified three potential mixed substrate shore biotic types: Biotic type A (Jania-Corallina- Polysiphonia turf) was characterised by robustly-textured algal turfs, a lowered predominance and diversity of polychaetes and an increase in crustacean abundance and diversity in sediment. Biotic type B (Polysiphonia-Tayloriella-Caulacanthus turf) had intermediately and biotic type C (Arthrocardia-Laurencia turf) the most sheltered eulittoral zones and beaches. DCCA identified the major environmental parameters affecting the macrobiota as: the level of wave energy, geological control of waves by hard substrate, sediment grain size and sediment inundation. A strong cross-shore wave attenuation results in sheltered sediments and midshore rock surfaces. Beach macrofauna were highly variable and diverse, which directly opposes previous perceptions about the sediment-bound biota of mixed substrate shores. The hierarchical cluster analysis produced a biotic classification of mixed substrate shores that was indicative of a biotic response to the total effects of leading environmental parameters. Macrobenthos of rock surfaces and sediment therefore showed potential to be used as an alternative or complementary to physical characteristics in classifying mixed substrate shores.
- Full Text:
- Date Issued: 2013
Effects of polarization in a distributed raman fibre amplifier
- Authors: Muguro, Kennedy Mwaura
- Date: 2011
- Subjects: Fiber optics , Polarization (Light) , Optical communications , Optical amplifiers , Raman effect
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10544 , http://hdl.handle.net/10948/d1014621
- Description: The need to exploit the large fibre bandwidth and increase the reach has seen the application of the Raman fibre amplifier (RFA) become indispensable in modern light wave systems. The success and resilience of RFAs in optical communication is deeply rooted in their unique optical properties and new technologies which have allowed the amplifier to come of age. However, the full potential of RFAs in optical communication and other applications are yet to be realized. More so are its polarization properties which still remain largely unexploited and have not been fully understood. In this work, fundamental issues regarding distributed RFA have been investigated with the aim of acquiring a better understanding of the amplifier polarization characteristics which have potential applications. In particular the effects of polarization mode dispersion (PMD) and polarization dependent loss (PDL) have been demonstrated both by simulation and experiment. The possibility of Raman polarization pulling in single mode fibres (SMFs) has also been addressed. Polarization sensitivity of RFA has been known for a long time but the clear manifestation of it has become evident in the advent of modern low PMD fibre. Unlike EDFAs which make use of special doped fibre, RFAs require no special fibre for operation. Besides, RFA uses a very long length of fibre and as such the fibre polarization characteristics come into play during amplification. In the demonstrations presented in this thesis a fibre of PMD coefficient < 0.05 pskm-1/2 was regarded as low PMD fibre while one having coefficient ≥ 0.05 pskm-1/2 was categorized to have high PMD unless otherwise stated. Several experiments were performed to evaluate the RFA gain characteristics with respect to fibre PMD and the system performance in the presence of noise emanating from amplified spontaneous emission (ASE). Analysis of Raman gain statistics was done for fibres of low and high PMD coefficients. The statistics of PDG and on-off gain were eventually used to demonstrate the extraction of PMD coefficients of fibres between 0.01- 0.1 pskm-1/2 using a forward pumping configuration. It was found that, at increasing pump power a linear relationship exists between forward and backward signal gain on a dB scale. The interaction of PDL and Raman PDG in the presence of PMD were observed at very fundamental level. It was found the presence of PDL serves to reduce the available on-off gain. It was also established that the presence of PMD mediates the interaction between PDG/PDL. When PMD is high it reduces PDG but the presence of PDL introduces a wavelength dependent gain tilting for WDM channels. Further analysis revealed that signal polarization is influenced by the pump SOP due to the pulling effect which is present even at moderate pump power.
- Full Text:
- Date Issued: 2011
- Authors: Muguro, Kennedy Mwaura
- Date: 2011
- Subjects: Fiber optics , Polarization (Light) , Optical communications , Optical amplifiers , Raman effect
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10544 , http://hdl.handle.net/10948/d1014621
- Description: The need to exploit the large fibre bandwidth and increase the reach has seen the application of the Raman fibre amplifier (RFA) become indispensable in modern light wave systems. The success and resilience of RFAs in optical communication is deeply rooted in their unique optical properties and new technologies which have allowed the amplifier to come of age. However, the full potential of RFAs in optical communication and other applications are yet to be realized. More so are its polarization properties which still remain largely unexploited and have not been fully understood. In this work, fundamental issues regarding distributed RFA have been investigated with the aim of acquiring a better understanding of the amplifier polarization characteristics which have potential applications. In particular the effects of polarization mode dispersion (PMD) and polarization dependent loss (PDL) have been demonstrated both by simulation and experiment. The possibility of Raman polarization pulling in single mode fibres (SMFs) has also been addressed. Polarization sensitivity of RFA has been known for a long time but the clear manifestation of it has become evident in the advent of modern low PMD fibre. Unlike EDFAs which make use of special doped fibre, RFAs require no special fibre for operation. Besides, RFA uses a very long length of fibre and as such the fibre polarization characteristics come into play during amplification. In the demonstrations presented in this thesis a fibre of PMD coefficient < 0.05 pskm-1/2 was regarded as low PMD fibre while one having coefficient ≥ 0.05 pskm-1/2 was categorized to have high PMD unless otherwise stated. Several experiments were performed to evaluate the RFA gain characteristics with respect to fibre PMD and the system performance in the presence of noise emanating from amplified spontaneous emission (ASE). Analysis of Raman gain statistics was done for fibres of low and high PMD coefficients. The statistics of PDG and on-off gain were eventually used to demonstrate the extraction of PMD coefficients of fibres between 0.01- 0.1 pskm-1/2 using a forward pumping configuration. It was found that, at increasing pump power a linear relationship exists between forward and backward signal gain on a dB scale. The interaction of PDL and Raman PDG in the presence of PMD were observed at very fundamental level. It was found the presence of PDL serves to reduce the available on-off gain. It was also established that the presence of PMD mediates the interaction between PDG/PDL. When PMD is high it reduces PDG but the presence of PDL introduces a wavelength dependent gain tilting for WDM channels. Further analysis revealed that signal polarization is influenced by the pump SOP due to the pulling effect which is present even at moderate pump power.
- Full Text:
- Date Issued: 2011
Towards the bioremediation of the hypertrophic Swartkops Solar Salt-works
- Authors: Difford, Mark
- Date: 2008
- Subjects: Salt industry and trade -- South Africa -- Port Elizabeth , Bioremediation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10606 , http://hdl.handle.net/10948/1506 , Salt industry and trade -- South Africa -- Port Elizabeth , Bioremediation
- Description: This thesis presents the results of three studies aimed at improving brine-quality at the Swartkops solar salt-works (Swartkops Sea Salt [Pty] Ltd) on the outskirts of Port Elizabeth, South Africa. This is a highly eutrophic salt-works, the management of which has become increasingly difficult in recent years. The fundamental problem is how best to operate the system at maximum capacity while limiting nutrient inputs from the nutrient-rich microtidal Swartkops Estuary. In the first study, brine-quality at several sites along the axis of the Swartkops Estuary, and the extent to which it is affected by a variety of factors, is compared. Sites were sampled on micro- and macrotidal time scales, and were selected by the management of the salt-works as possible locations for a new pump-house (for extracting brine from the estuary) for their salt-work operations at Swartkops and Missionvale. The study showed that there are incremental benefits to be had from moving the site of extraction downstream from its present position to a site closer to the mouth of the estuary, where the concentration of nutrients usually is lower and where salinity usually is higher. There is little to be gained from moving the site of extraction laterally, to the mouth of the Inlet from which brine currently is extracted, so that brine is extracted directly from the estuary itself. A set of models relating the concentrations of NH+ 4 , NO{u100000}3 , and PO34{u100000} to salinity is proposed. These take into account the influences of site and season and may be used to estimate the concentration of these nutrients from a measurement of salinity. The model for PO34{u100000} shows that it would be more damaging to the salt-works’ operations to pump “low”-salinity brine during the early months of summer than during autumn. Evidence is also presented to show that Wylde Bridge has no influence on nutrient concentrations in the estuary, with tidal flushing generally passing beyond the Wylde-Bridge break-point. The exceptionally heavy flooding of the estuary that occurred in September 2002 may, however, have biased this conclusion, because of its scouring effect. The second study concentrated on monitoring the effect of (1) decreasing pond depth and (2) increasing pond salinity—two readily available management tools—on brine quality at the salt-works. Pond depth throughout the salt-works was decreased by 40 cm, and the salinity of Pond 5, a pond in the middle of the system, was increased to 175 S. Both measures were kept in place for the duration of the study (Nov. 2002–Aug. 2004). The pond-depth experiment did not have the expected result, there being no evidence of the increase in microalgal growth in the water column that was predicted based on previous research. There was, however, a significant increase in benthic chlorophyll-a, and there was a general improvement in the condition of the sedimentary system of the salt-works. There was also a substantial decrease in particulate organic matter in the water column, with clear evidence that the remaining fraction was closely associated with living forms of particulate matter rather than with detritus. The pond-salinity experiment proves that there is a flourishing, and resilient, population of brine shrimp (Artemia salina L.) at the salt-works. Restocking the salina, or stocking it with a different strain of brine shrimp, is therefore not necessary. The results of this study show that the brine shrimp population at the salt-works needs salinities of greater than about 65–70 S to survive. As a living force they almost certainly need a protective salinity that is greater than about 120–140 S, perhaps even as great as 160 S. Brine shrimp thrived in the high salinity milieu of the experimental pond for the duration of the study, but dwindled from three other ponds of the system once their salinities fell to below 90 S, eventually to disappear from them, apparently completely, once salinity fell to below 65 S. The third and final study concentrated on establishing whether the products released by decomposing barley straw could be used in a solar salt-works to control macroalgal blooms without detrimentally affecting the benthic-mat. Previous research has shown that these products are effective inhibitors of macroalgal growth and that they remain effective under saline conditions. The results presented here show that the same products, or products released under similar conditions of decomposition, adversely effect both the structure and the function of the mat. Consequently, their use in a solar salt-works cannot be recommended.
- Full Text:
- Date Issued: 2008
- Authors: Difford, Mark
- Date: 2008
- Subjects: Salt industry and trade -- South Africa -- Port Elizabeth , Bioremediation
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10606 , http://hdl.handle.net/10948/1506 , Salt industry and trade -- South Africa -- Port Elizabeth , Bioremediation
- Description: This thesis presents the results of three studies aimed at improving brine-quality at the Swartkops solar salt-works (Swartkops Sea Salt [Pty] Ltd) on the outskirts of Port Elizabeth, South Africa. This is a highly eutrophic salt-works, the management of which has become increasingly difficult in recent years. The fundamental problem is how best to operate the system at maximum capacity while limiting nutrient inputs from the nutrient-rich microtidal Swartkops Estuary. In the first study, brine-quality at several sites along the axis of the Swartkops Estuary, and the extent to which it is affected by a variety of factors, is compared. Sites were sampled on micro- and macrotidal time scales, and were selected by the management of the salt-works as possible locations for a new pump-house (for extracting brine from the estuary) for their salt-work operations at Swartkops and Missionvale. The study showed that there are incremental benefits to be had from moving the site of extraction downstream from its present position to a site closer to the mouth of the estuary, where the concentration of nutrients usually is lower and where salinity usually is higher. There is little to be gained from moving the site of extraction laterally, to the mouth of the Inlet from which brine currently is extracted, so that brine is extracted directly from the estuary itself. A set of models relating the concentrations of NH+ 4 , NO{u100000}3 , and PO34{u100000} to salinity is proposed. These take into account the influences of site and season and may be used to estimate the concentration of these nutrients from a measurement of salinity. The model for PO34{u100000} shows that it would be more damaging to the salt-works’ operations to pump “low”-salinity brine during the early months of summer than during autumn. Evidence is also presented to show that Wylde Bridge has no influence on nutrient concentrations in the estuary, with tidal flushing generally passing beyond the Wylde-Bridge break-point. The exceptionally heavy flooding of the estuary that occurred in September 2002 may, however, have biased this conclusion, because of its scouring effect. The second study concentrated on monitoring the effect of (1) decreasing pond depth and (2) increasing pond salinity—two readily available management tools—on brine quality at the salt-works. Pond depth throughout the salt-works was decreased by 40 cm, and the salinity of Pond 5, a pond in the middle of the system, was increased to 175 S. Both measures were kept in place for the duration of the study (Nov. 2002–Aug. 2004). The pond-depth experiment did not have the expected result, there being no evidence of the increase in microalgal growth in the water column that was predicted based on previous research. There was, however, a significant increase in benthic chlorophyll-a, and there was a general improvement in the condition of the sedimentary system of the salt-works. There was also a substantial decrease in particulate organic matter in the water column, with clear evidence that the remaining fraction was closely associated with living forms of particulate matter rather than with detritus. The pond-salinity experiment proves that there is a flourishing, and resilient, population of brine shrimp (Artemia salina L.) at the salt-works. Restocking the salina, or stocking it with a different strain of brine shrimp, is therefore not necessary. The results of this study show that the brine shrimp population at the salt-works needs salinities of greater than about 65–70 S to survive. As a living force they almost certainly need a protective salinity that is greater than about 120–140 S, perhaps even as great as 160 S. Brine shrimp thrived in the high salinity milieu of the experimental pond for the duration of the study, but dwindled from three other ponds of the system once their salinities fell to below 90 S, eventually to disappear from them, apparently completely, once salinity fell to below 65 S. The third and final study concentrated on establishing whether the products released by decomposing barley straw could be used in a solar salt-works to control macroalgal blooms without detrimentally affecting the benthic-mat. Previous research has shown that these products are effective inhibitors of macroalgal growth and that they remain effective under saline conditions. The results presented here show that the same products, or products released under similar conditions of decomposition, adversely effect both the structure and the function of the mat. Consequently, their use in a solar salt-works cannot be recommended.
- Full Text:
- Date Issued: 2008
On the electrical characterisation of bulk and epitaxial n-type Te doped GaSb
- Authors: Murape, Davison Munyaradzi
- Date: 2014
- Subjects: Gallium arsenide semiconductors , Electronics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10554 , http://hdl.handle.net/10948/d1020763
- Description: Since the development of the transistor in the Bell Telephone Laboratories in 1948 [78], the semiconductor industry has transformed the world we live in. It is difficult to picture a world without the modern day cutting edge technology. Imagine performing every day functions without “trivial” devices such as computers, cell phones or microwave ovens. The ability to tailor the band gaps of various binary, ternary and quaternary semiconductor systems has opened up a whole new spectrum of potential purpose designed devices [27]. This thesis focuses on the electronic properties of gallium (III) antimonide (V). The antimonides, in general, have the smallest band gap and highest electron mobility of the III-V compound semiconductors and are well suited for long wavelength emission and detection as well as high frequency switching device applications. Furthermore, III-V ternaries and quaternaries, such as (AlGaIn)(AsSb), lattice matched to gallium antimonide (GaSb) are considered serious competitors for HgCdTe and PbSe in long-wavelength infrared (LWIR) and very long-wavelength infrared (VLWIR) technology [4, 10, 11]. Epitaxial material systems based on GaSb are suitable for a wide range of applications such as missile and surveillance systems and a host of other military and civil applications. In addition, an assortment of devices on InAs, GaSb, and AlSb, including resonant tunnelling devices, infrared detectors and mid-infrared semiconductor lasers have been demonstrated [14, 15]. Furthermore, antimonide based devices could potentially reduce optical fibre power loss by a few orders of magnitude, as their implementation can lead to use of non-silica based optical fibres that minimise Raleigh scatter related power loss [8]. GaSb related technology faces a number of challenges. A significant amount of effort is required to exploit the potential it offers. GaSb oxidises readily in the ambient, resulting in the formation of a native oxide layer as well as deposits of elemental antimony (Sb) at the oxide/substrate interface therefore it has poor surface electronic properties resulting from high surface state densities[4, 17, 18]. As grown GaSb is characterised by a high density of surface states of which many are classified as non-radiative (Auger) recombination centres. The elemental Sb layer constitutes an unwanted conduction path parallel to the active surface region [17]. The potential that GaSb and GaSb-based strained layer superlattices offer as successors to the current generation of LWIR and VLWIR optoelectronic materials has therefore been largely impeded [4]. Furthermore, processing steps in device fabrication leads to an unintentionally damaged GaSb surface exacerbating the situation. Any efforts to engineer devices of superior quality on GaSb have to address these and more material specific problems [19]. This study attempts to contribute towards an improved understanding of the structural and electrical properties of the near surface region of Te-doped bulk (100) and MOVPE grown epitaxial Te doped n- GaSb. The main focus of this study is to develop means to de-oxidise and stabilize the highly reactive GaSb surface and to develop diode structures to demonstrate the improved interface characteristics and use related current–voltage (I-V) measurements to quantify the surface state density before and after treatment. These devices were also used to probe the near surface region for electrically active deep level defects that often act as non-radiative recombination centers. Au, Pd and Al were used as metals to establish a metal semiconductor barrier and subsequent depletion region. Sulphur based chemicals, ([(NH4)2S / (NH4)2SO4] + S), not previously reported for the treatment of (100) n-GaSb surfaces, and the commonly used passivants Na2S:9H2O and (NH4)2S were compared by assessing the electrical and structural properties both before and after treatment. The effect of treatment on the electrical response of the material was determined using current-voltage, capacitance-voltage (C-V) and deep level transient spectroscopy (DLTS) measurements, while the surface morphology and composition were studied by SEM, AES and XPS.
- Full Text:
- Date Issued: 2014
- Authors: Murape, Davison Munyaradzi
- Date: 2014
- Subjects: Gallium arsenide semiconductors , Electronics
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:10554 , http://hdl.handle.net/10948/d1020763
- Description: Since the development of the transistor in the Bell Telephone Laboratories in 1948 [78], the semiconductor industry has transformed the world we live in. It is difficult to picture a world without the modern day cutting edge technology. Imagine performing every day functions without “trivial” devices such as computers, cell phones or microwave ovens. The ability to tailor the band gaps of various binary, ternary and quaternary semiconductor systems has opened up a whole new spectrum of potential purpose designed devices [27]. This thesis focuses on the electronic properties of gallium (III) antimonide (V). The antimonides, in general, have the smallest band gap and highest electron mobility of the III-V compound semiconductors and are well suited for long wavelength emission and detection as well as high frequency switching device applications. Furthermore, III-V ternaries and quaternaries, such as (AlGaIn)(AsSb), lattice matched to gallium antimonide (GaSb) are considered serious competitors for HgCdTe and PbSe in long-wavelength infrared (LWIR) and very long-wavelength infrared (VLWIR) technology [4, 10, 11]. Epitaxial material systems based on GaSb are suitable for a wide range of applications such as missile and surveillance systems and a host of other military and civil applications. In addition, an assortment of devices on InAs, GaSb, and AlSb, including resonant tunnelling devices, infrared detectors and mid-infrared semiconductor lasers have been demonstrated [14, 15]. Furthermore, antimonide based devices could potentially reduce optical fibre power loss by a few orders of magnitude, as their implementation can lead to use of non-silica based optical fibres that minimise Raleigh scatter related power loss [8]. GaSb related technology faces a number of challenges. A significant amount of effort is required to exploit the potential it offers. GaSb oxidises readily in the ambient, resulting in the formation of a native oxide layer as well as deposits of elemental antimony (Sb) at the oxide/substrate interface therefore it has poor surface electronic properties resulting from high surface state densities[4, 17, 18]. As grown GaSb is characterised by a high density of surface states of which many are classified as non-radiative (Auger) recombination centres. The elemental Sb layer constitutes an unwanted conduction path parallel to the active surface region [17]. The potential that GaSb and GaSb-based strained layer superlattices offer as successors to the current generation of LWIR and VLWIR optoelectronic materials has therefore been largely impeded [4]. Furthermore, processing steps in device fabrication leads to an unintentionally damaged GaSb surface exacerbating the situation. Any efforts to engineer devices of superior quality on GaSb have to address these and more material specific problems [19]. This study attempts to contribute towards an improved understanding of the structural and electrical properties of the near surface region of Te-doped bulk (100) and MOVPE grown epitaxial Te doped n- GaSb. The main focus of this study is to develop means to de-oxidise and stabilize the highly reactive GaSb surface and to develop diode structures to demonstrate the improved interface characteristics and use related current–voltage (I-V) measurements to quantify the surface state density before and after treatment. These devices were also used to probe the near surface region for electrically active deep level defects that often act as non-radiative recombination centers. Au, Pd and Al were used as metals to establish a metal semiconductor barrier and subsequent depletion region. Sulphur based chemicals, ([(NH4)2S / (NH4)2SO4] + S), not previously reported for the treatment of (100) n-GaSb surfaces, and the commonly used passivants Na2S:9H2O and (NH4)2S were compared by assessing the electrical and structural properties both before and after treatment. The effect of treatment on the electrical response of the material was determined using current-voltage, capacitance-voltage (C-V) and deep level transient spectroscopy (DLTS) measurements, while the surface morphology and composition were studied by SEM, AES and XPS.
- Full Text:
- Date Issued: 2014
The effect of gamma radiation on the physical and chemical properties of wool
- Authors: Rapakgadi, Jim
- Date: 2020
- Subjects: Semiconductors -- Effect of radiation on
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47668 , vital:40263
- Description: Pathogens (e.g. viruses, spores and bacteria) remain one of the biggest threats to trading and the economy of natural fibre products, such as wool, mohair and cotton. One of the means to kill or eliminate pathogens is by radiation sterilisation, involving electromagnetic radiation (e.g. gamma radiation and UV light). The research, reported in this thesis, was aimed at establishing the effect of gamma irradiation dosage on the various quality related physical and chemical characteristics of four different types of merino wool when treated in situ in scoured and greasy state in mini-bale form. Specific properties studied include wool colour (yellowness and brightness), solubility (alkali solubility and urea bisulphite solubility), fibre diameter and tensile properties (staple strength and bundle tenacity). Standard analytical and diagnostic techniques were used to assess changes, if any, in the above mentioned properties due to the radiation treatment. Nominal radiation dosages, ranging from 25 kGy to 75 kGy (actual measured from 0 kGy to 92.2 kGy) were used, 50 kGy normally being regarded as sufficient to destroy the pathogens in question. It was found that nominial gamma radiation dosages of up to 92.2 kGy did not significantly affect fibre diameter or staple length, indicating that no irreversible swelling of the wool fibres occurred as a result of gamma irradiation. Alkali and urea bisulphite solubility as well as yellowness, on the other hand, showed a systematic increase with an increase in irradiation dose, indicating that changes occurred at molecular level. Fibre tensile properties (staple strength and bundle tenacity) were also affected but to a much lesser extent than solubility and colour. The various merino wool types studied showed similar reactions to the radiation treatment, irrespective of the wool quality and type and also whether they were treated in greasy or scoured form.
- Full Text:
- Date Issued: 2020
- Authors: Rapakgadi, Jim
- Date: 2020
- Subjects: Semiconductors -- Effect of radiation on
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: http://hdl.handle.net/10948/47668 , vital:40263
- Description: Pathogens (e.g. viruses, spores and bacteria) remain one of the biggest threats to trading and the economy of natural fibre products, such as wool, mohair and cotton. One of the means to kill or eliminate pathogens is by radiation sterilisation, involving electromagnetic radiation (e.g. gamma radiation and UV light). The research, reported in this thesis, was aimed at establishing the effect of gamma irradiation dosage on the various quality related physical and chemical characteristics of four different types of merino wool when treated in situ in scoured and greasy state in mini-bale form. Specific properties studied include wool colour (yellowness and brightness), solubility (alkali solubility and urea bisulphite solubility), fibre diameter and tensile properties (staple strength and bundle tenacity). Standard analytical and diagnostic techniques were used to assess changes, if any, in the above mentioned properties due to the radiation treatment. Nominal radiation dosages, ranging from 25 kGy to 75 kGy (actual measured from 0 kGy to 92.2 kGy) were used, 50 kGy normally being regarded as sufficient to destroy the pathogens in question. It was found that nominial gamma radiation dosages of up to 92.2 kGy did not significantly affect fibre diameter or staple length, indicating that no irreversible swelling of the wool fibres occurred as a result of gamma irradiation. Alkali and urea bisulphite solubility as well as yellowness, on the other hand, showed a systematic increase with an increase in irradiation dose, indicating that changes occurred at molecular level. Fibre tensile properties (staple strength and bundle tenacity) were also affected but to a much lesser extent than solubility and colour. The various merino wool types studied showed similar reactions to the radiation treatment, irrespective of the wool quality and type and also whether they were treated in greasy or scoured form.
- Full Text:
- Date Issued: 2020