Economic feasibility of an experimental octopus fishery in South Africa
- Authors: Oosthuizen, Ané
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6760 , http://hdl.handle.net/10962/d1007773
- Description: Octopus vulgaris was identified as a new marine resource to be commercially exploited through an experimental fishery. A recent policy on developing fisheries in South Africa emphasizes the importance of investigating the economic feasibility of a fishery as part of its management framework. The study reported here generated baseline information necessary in the design of the experimental fishery, giving guidelines as to which vessels, fishing gear and markets would be most feasible. The proposed fishery, gear and vessel type, fishing techniques and expected catch rates are described, the results of market research are outlined, and the cost of fishing is estimated. The potential business should consist of small and medium-sized vessels deploying unbaited pots attached to long lines. The longline pot fishery could be economically feasible, provided a 30 percent catch in 6600 pots/month is attained. Only existing, debt-free vessels should be used. The minimum catch per unit effort (CPUE) for various fishing operation scenarios was calculated to determine economic feasibility. This is an estimated minimum CPUE, based on assumptions that cannot be confirmed until the fishery starts. Furthermore, this economic analysis also needs to be assessed by stakeholders with experience of fishery operations , Rhodes Centenary issue of: South African Journal of Science.
- Full Text:
- Date Issued: 2004
- Authors: Oosthuizen, Ané
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6760 , http://hdl.handle.net/10962/d1007773
- Description: Octopus vulgaris was identified as a new marine resource to be commercially exploited through an experimental fishery. A recent policy on developing fisheries in South Africa emphasizes the importance of investigating the economic feasibility of a fishery as part of its management framework. The study reported here generated baseline information necessary in the design of the experimental fishery, giving guidelines as to which vessels, fishing gear and markets would be most feasible. The proposed fishery, gear and vessel type, fishing techniques and expected catch rates are described, the results of market research are outlined, and the cost of fishing is estimated. The potential business should consist of small and medium-sized vessels deploying unbaited pots attached to long lines. The longline pot fishery could be economically feasible, provided a 30 percent catch in 6600 pots/month is attained. Only existing, debt-free vessels should be used. The minimum catch per unit effort (CPUE) for various fishing operation scenarios was calculated to determine economic feasibility. This is an estimated minimum CPUE, based on assumptions that cannot be confirmed until the fishery starts. Furthermore, this economic analysis also needs to be assessed by stakeholders with experience of fishery operations , Rhodes Centenary issue of: South African Journal of Science.
- Full Text:
- Date Issued: 2004
Here come Chris and the Blue Notes
- Unknown
- Authors: Unknown
- Subjects: McGregor, Chris--1936-1990 , Blue Notes (Musical group : South Africa) , Pukwana, Dudu , Dyani, Johnny Mbizo , Moholo, Louis T.--1940- , Moyake, Nikele , Feza, Mongezi
- Language: English
- Type: Article
- Identifier: vital:13712 , http://hdl.handle.net/10962/d1012723
- Description: Photocopied article from the newspaper The Post about Chris McGregor's Blue Notes playing in Durban before the band leaves for France and the Antibes jazz festival. There is a picture of (from left to right) Dudu Pukwana, Johnny Dyani, CHris McGregor, Louis Moholo, Nick Moyake and Mongezi Feza with this article.
- Full Text:
- Authors: Unknown
- Subjects: McGregor, Chris--1936-1990 , Blue Notes (Musical group : South Africa) , Pukwana, Dudu , Dyani, Johnny Mbizo , Moholo, Louis T.--1940- , Moyake, Nikele , Feza, Mongezi
- Language: English
- Type: Article
- Identifier: vital:13712 , http://hdl.handle.net/10962/d1012723
- Description: Photocopied article from the newspaper The Post about Chris McGregor's Blue Notes playing in Durban before the band leaves for France and the Antibes jazz festival. There is a picture of (from left to right) Dudu Pukwana, Johnny Dyani, CHris McGregor, Louis Moholo, Nick Moyake and Mongezi Feza with this article.
- Full Text:
The Educational Journal
- Date: 1980-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/36310 , vital:33919 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1980-02
- Date: 1980-02
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/36310 , vital:33919 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1980-02
NOS-Jazz Festival
- Authors: Van Leeuwen, Rans
- Language: Dutch
- Type: Article
- Identifier: vital:13662 , http://hdl.handle.net/10962/d1012574
- Description: Photocopied article from the Dutch newspaper N.R.C. Moandag about the NOS-Jazz Festival. There are 3 pictures with this article. The top left picture shows Chris McGregor playing piano with Annie Whitehead playing trombone, the top right picture shows the saxophonist Paul van Kemenade and the clarinetist John Carter is on the bottom picture.
- Full Text:
- Authors: Van Leeuwen, Rans
- Language: Dutch
- Type: Article
- Identifier: vital:13662 , http://hdl.handle.net/10962/d1012574
- Description: Photocopied article from the Dutch newspaper N.R.C. Moandag about the NOS-Jazz Festival. There are 3 pictures with this article. The top left picture shows Chris McGregor playing piano with Annie Whitehead playing trombone, the top right picture shows the saxophonist Paul van Kemenade and the clarinetist John Carter is on the bottom picture.
- Full Text:
In the groove
- Authors: Rachilo, Sol
- Language: English
- Type: Article
- Identifier: vital:13643 , http://hdl.handle.net/10962/d1012547
- Description: Photocopied article from the newspaper Elethu Mirror about the recordings by Chris McGregor and The Castle Lager Big Band. There is a picture of Chris McGregor with the article.
- Full Text:
- Authors: Rachilo, Sol
- Language: English
- Type: Article
- Identifier: vital:13643 , http://hdl.handle.net/10962/d1012547
- Description: Photocopied article from the newspaper Elethu Mirror about the recordings by Chris McGregor and The Castle Lager Big Band. There is a picture of Chris McGregor with the article.
- Full Text:
Applications of social media and web 2.0 for research support in selected African academic institutions
- Owusu-Ansah, Christopher M, Gontshi, Vuyokazi, Mutibwa, Lois, Ukwoma, Scholarstica
- Authors: Owusu-Ansah, Christopher M , Gontshi, Vuyokazi , Mutibwa, Lois , Ukwoma, Scholarstica
- Date: 2015
- Subjects: Social networks , Web 2.0. , Research -- Study and teaching
- Language: English
- Type: Article
- Identifier: vital:6996 , http://hdl.handle.net/10962/d1018520
- Description: This study examined the use of Social Media/Web 2.0 for research support and it is guided by three objectives namely: a) to ascertain the uses of social media in academic institutions; b) to identify the challenges associated with social media use for research purposes and c) to provide experiences of social media application in selected African academic institutions. The study makes use of literature analysis in combination with personal and professional work experiences on the use of social media from librarians in four different countries. Institutional experiences of the four librarians showed that it is only Rhodes University Library that uses social media in its library, which is as a result of a formal social media strategy. For the other three universities, University of Education, Winneba Library in Ghana, Makerere University Library in Uganda and the University of Nigeria Library, the use of social media is not encouraging. They use it mostly for communication and interaction with colleagues. It was also discovered that there is no social media strategy available in these university libraries. Based on these findings, the study recommended the implementation of a social media strategy, appointment of social media librarians in these libraries, and continuing professional development of librarians to keep abreast with current trends. Web 2.0/Social Media is a new technology offering new options for African academic librarians in their research support role
- Full Text:
- Date Issued: 2015
- Authors: Owusu-Ansah, Christopher M , Gontshi, Vuyokazi , Mutibwa, Lois , Ukwoma, Scholarstica
- Date: 2015
- Subjects: Social networks , Web 2.0. , Research -- Study and teaching
- Language: English
- Type: Article
- Identifier: vital:6996 , http://hdl.handle.net/10962/d1018520
- Description: This study examined the use of Social Media/Web 2.0 for research support and it is guided by three objectives namely: a) to ascertain the uses of social media in academic institutions; b) to identify the challenges associated with social media use for research purposes and c) to provide experiences of social media application in selected African academic institutions. The study makes use of literature analysis in combination with personal and professional work experiences on the use of social media from librarians in four different countries. Institutional experiences of the four librarians showed that it is only Rhodes University Library that uses social media in its library, which is as a result of a formal social media strategy. For the other three universities, University of Education, Winneba Library in Ghana, Makerere University Library in Uganda and the University of Nigeria Library, the use of social media is not encouraging. They use it mostly for communication and interaction with colleagues. It was also discovered that there is no social media strategy available in these university libraries. Based on these findings, the study recommended the implementation of a social media strategy, appointment of social media librarians in these libraries, and continuing professional development of librarians to keep abreast with current trends. Web 2.0/Social Media is a new technology offering new options for African academic librarians in their research support role
- Full Text:
- Date Issued: 2015
Chemistry Department: we are chemicals all over
- Authors: Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7173 , http://hdl.handle.net/10962/d1006080
- Description: National University of Lesotho publication: The Light in the Night article by Tebello Nyokong on the Chemistry Department
- Full Text:
- Authors: Nyokong, Tebello
- Language: English
- Type: Article
- Identifier: vital:7173 , http://hdl.handle.net/10962/d1006080
- Description: National University of Lesotho publication: The Light in the Night article by Tebello Nyokong on the Chemistry Department
- Full Text:
The Educational Journal
- Date: 1962-12
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34642 , vital:33403 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1962-12
- Date: 1962-12
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/34642 , vital:33403 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1962-12
Responsive integrative treatment of PTSD and trauma related disorders : an expanded evidence-based model
- Authors: Edwards, David J A
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6223 , http://hdl.handle.net/10962/d1007679
- Description: In this article a practitioner oriented review of the literature on the treatment of post-traumatic stress disorder is used to construct a phase-based model that can serve as a basis for case formulation and treatment planning. Treatments shown to be efficacious in randomized controlled trials are listed and two discourses about them are contrasted. One calls for therapists to implement treatments scrupulously according to the manual, the other calls for flexibility and responsiveness to contextual understanding of the situation and personality of individual clients. Evidence for the centrality of the principles of this latter discourse for professional practice is summarized from work on case formulation, standards for therapist competence, and the concept of evidence-based practice. This provides the foundation for a model for treatment of PTSD, both simple and complex, that has five levels which represent increasing degrees of depth of clinical work. In accordance with the phased approach, conditions at one level need to be satisfied before proceeding to work on a deeper level. At each level specific areas of clinical focus are highlighted including risk management (at level 1), building the therapeutic alliance (at level 2) and trauma-focused work (at level 3). The model serves as a broad structured summary of accumulated clinical knowledge about PTSD and its treatment that provides an evidence-based foundation for assessment and treatment planning.
- Full Text:
- Date Issued: 2013
- Authors: Edwards, David J A
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6223 , http://hdl.handle.net/10962/d1007679
- Description: In this article a practitioner oriented review of the literature on the treatment of post-traumatic stress disorder is used to construct a phase-based model that can serve as a basis for case formulation and treatment planning. Treatments shown to be efficacious in randomized controlled trials are listed and two discourses about them are contrasted. One calls for therapists to implement treatments scrupulously according to the manual, the other calls for flexibility and responsiveness to contextual understanding of the situation and personality of individual clients. Evidence for the centrality of the principles of this latter discourse for professional practice is summarized from work on case formulation, standards for therapist competence, and the concept of evidence-based practice. This provides the foundation for a model for treatment of PTSD, both simple and complex, that has five levels which represent increasing degrees of depth of clinical work. In accordance with the phased approach, conditions at one level need to be satisfied before proceeding to work on a deeper level. At each level specific areas of clinical focus are highlighted including risk management (at level 1), building the therapeutic alliance (at level 2) and trauma-focused work (at level 3). The model serves as a broad structured summary of accumulated clinical knowledge about PTSD and its treatment that provides an evidence-based foundation for assessment and treatment planning.
- Full Text:
- Date Issued: 2013
Critical literacy in South Africa : possibilities and constraints in 2002
- Authors: Prinsloo, J , Janks, H
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6330 , http://hdl.handle.net/10962/d1008475
- Description: This article examines the Curriculum documents produced in South Africa since the election of a democratic government in 1994 in order to consider the possibilities they create for the inclusion of critical literacy in the teaching of home languages. This discussion is set against an analysis of the apartheid curriculum documents prior to 1994 and a consideration of the ongoing inequalities in the provision of human and material resources across the system. Despite real constraints with regard to implementation, it is argued that the new Curriculum effects a significant break with the past and makes a positive contribution to transforming language education.
- Full Text:
- Date Issued: 2002
- Authors: Prinsloo, J , Janks, H
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6330 , http://hdl.handle.net/10962/d1008475
- Description: This article examines the Curriculum documents produced in South Africa since the election of a democratic government in 1994 in order to consider the possibilities they create for the inclusion of critical literacy in the teaching of home languages. This discussion is set against an analysis of the apartheid curriculum documents prior to 1994 and a consideration of the ongoing inequalities in the provision of human and material resources across the system. Despite real constraints with regard to implementation, it is argued that the new Curriculum effects a significant break with the past and makes a positive contribution to transforming language education.
- Full Text:
- Date Issued: 2002
Effects of substituents on the photochemical and photophysical properties of main group metal phthalocyanines
- Authors: Nyokong, Tebello
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6581 , http://hdl.handle.net/10962/d1004146
- Description: The review focuses on the photochemical (singlet oxygen and photobleaching quantum yields) and photophysical (triplet quantum yields and lifetimes and fluorescence lifetimes) properties of metallophthalocyanine complexes containing main group metals (Zn, Al, Ge, Si, Sn, Ga and In) and some unmetallated phthalocyanine complexes. Five tables containing photophysical and photochemical data for sulfonated phthalocyanines, tetra-, octa-substituted and unsubstituted phthalocyanines in a variety of solvents, are included in the review.
- Full Text:
- Date Issued: 2007
- Authors: Nyokong, Tebello
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6581 , http://hdl.handle.net/10962/d1004146
- Description: The review focuses on the photochemical (singlet oxygen and photobleaching quantum yields) and photophysical (triplet quantum yields and lifetimes and fluorescence lifetimes) properties of metallophthalocyanine complexes containing main group metals (Zn, Al, Ge, Si, Sn, Ga and In) and some unmetallated phthalocyanine complexes. Five tables containing photophysical and photochemical data for sulfonated phthalocyanines, tetra-, octa-substituted and unsubstituted phthalocyanines in a variety of solvents, are included in the review.
- Full Text:
- Date Issued: 2007
APDUSA Views
- Date: 1991-08
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/32688 , vital:32309 , Bulk File 7
- Description: APDUSA Views was published by the African People’s Democratic Union of Southern Africa (Natal), an affiliate of the New Unity Movement.
- Full Text: false
- Date Issued: 1991-08
- Date: 1991-08
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/32688 , vital:32309 , Bulk File 7
- Description: APDUSA Views was published by the African People’s Democratic Union of Southern Africa (Natal), an affiliate of the New Unity Movement.
- Full Text: false
- Date Issued: 1991-08
Written out, writing in : orature in the South African literary canon
- Authors: Seddon, Deborah Ann
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:2263 , http://hdl.handle.net/10962/d1004695
- Description: As described by Duncan Brown, South African orature represents "our truly original contribution to world literature" (Brown, Voicing the Text 1). This paper explores how orature might be successfully 'written into' the South African literary canon whilst promoting recognition of its existence as an oral form. My recent experiences of the difficulties, challenges, and benefits of teaching South African orature within the Rhodes University English department, have alerted me to the urgent need for the creation of a student- and teacher-friendly anthology which would collect, re-voice, and adequately contextualise a selection of the seminal works of South African oral poets from the colonial to the post-apartheid periods. Much of this poetry already exists in print-form but, despite an increasing recognition of oral poetry through a number of endeavours such the Poetry Africa Festival, the Lentswe Poetry Project on SABC 2, the Timbila Poetry Project and others, South African orature remains marginal in the country's literary canon. It is largely absent from the curriculum in the literature departments of its universities. The need to redress this situation is crucial, but the process of setting up and teaching an undergraduate course in South African oral poetry, while possible, is complicated. The works of our most important oral poets are scattered in a variety of books, libraries, and collections. The usual process of drawing up a booklist of set texts is undermined by the stark reality that many of the books are out of print. Fully giving voice to these texts is even harder to achieve - CD and video recordings of performances (if they exist at all) are not easily accessed or disseminated.
- Full Text:
- Date Issued: 2008
- Authors: Seddon, Deborah Ann
- Date: 2008
- Language: English
- Type: Article
- Identifier: vital:2263 , http://hdl.handle.net/10962/d1004695
- Description: As described by Duncan Brown, South African orature represents "our truly original contribution to world literature" (Brown, Voicing the Text 1). This paper explores how orature might be successfully 'written into' the South African literary canon whilst promoting recognition of its existence as an oral form. My recent experiences of the difficulties, challenges, and benefits of teaching South African orature within the Rhodes University English department, have alerted me to the urgent need for the creation of a student- and teacher-friendly anthology which would collect, re-voice, and adequately contextualise a selection of the seminal works of South African oral poets from the colonial to the post-apartheid periods. Much of this poetry already exists in print-form but, despite an increasing recognition of oral poetry through a number of endeavours such the Poetry Africa Festival, the Lentswe Poetry Project on SABC 2, the Timbila Poetry Project and others, South African orature remains marginal in the country's literary canon. It is largely absent from the curriculum in the literature departments of its universities. The need to redress this situation is crucial, but the process of setting up and teaching an undergraduate course in South African oral poetry, while possible, is complicated. The works of our most important oral poets are scattered in a variety of books, libraries, and collections. The usual process of drawing up a booklist of set texts is undermined by the stark reality that many of the books are out of print. Fully giving voice to these texts is even harder to achieve - CD and video recordings of performances (if they exist at all) are not easily accessed or disseminated.
- Full Text:
- Date Issued: 2008
From panic disorder to complex traumatic stress disorder : retrospective reflections on the case of Tariq
- Authors: Edwards, David J A
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6234 , http://hdl.handle.net/10962/d1007784
- Description: This is a phenomenological-hermeneutic case study of Tariq who initially presented with panic disorder. It documents how, as therapy proceeded, the underlying meaning of his initial panic deepened as its roots in traumatic memories of childhood emerged. There were four spaced phases of treatment over four years. The first focused on anxiety management; the second was conceptualized within schema-focused therapy, and evoked and worked with childhood memories using inner child guided imagery; in the third and fourth phases insights gained led to an authentic re-engagement with family members in relationships that had been problematic. The panic attacks resolved and there were two dreams representing a reconfiguring of his relationship with his deceased father. The first two phases were the focus of an unpublished case study presented at a conference in 1995. This article incorporates material from that study and looks back at the case both in light of developments in phases two and three and also in light of theoretical developments in our understanding of complex trauma since the initial presentation.
- Full Text:
- Date Issued: 2013
- Authors: Edwards, David J A
- Date: 2013
- Language: English
- Type: Article
- Identifier: vital:6234 , http://hdl.handle.net/10962/d1007784
- Description: This is a phenomenological-hermeneutic case study of Tariq who initially presented with panic disorder. It documents how, as therapy proceeded, the underlying meaning of his initial panic deepened as its roots in traumatic memories of childhood emerged. There were four spaced phases of treatment over four years. The first focused on anxiety management; the second was conceptualized within schema-focused therapy, and evoked and worked with childhood memories using inner child guided imagery; in the third and fourth phases insights gained led to an authentic re-engagement with family members in relationships that had been problematic. The panic attacks resolved and there were two dreams representing a reconfiguring of his relationship with his deceased father. The first two phases were the focus of an unpublished case study presented at a conference in 1995. This article incorporates material from that study and looks back at the case both in light of developments in phases two and three and also in light of theoretical developments in our understanding of complex trauma since the initial presentation.
- Full Text:
- Date Issued: 2013
(Ferrocenylpyrazolyl)zinc(II) benzoates as catalysts for the ring opening polymerization of ε-caprolactone
- Obuah, Collins, Lochee, Yemanlall, Jordaan, Johan H.L., Otto, Daniel P., Nyokong, Tebello, Darkwa, James
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H.L. , Otto, Daniel P. , Nyokong, Tebello , Darkwa, James
- Language: English
- Type: Article
- Identifier: vital:7264 , http://hdl.handle.net/10962/d1020273
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of ɛ-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol−1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 × 10−7 h−1 mol−1 at 110 °C. , Original publication is available at http://dx.doi.org/10.1016/j.poly.2015.02.007
- Full Text: false
- Authors: Obuah, Collins , Lochee, Yemanlall , Jordaan, Johan H.L. , Otto, Daniel P. , Nyokong, Tebello , Darkwa, James
- Language: English
- Type: Article
- Identifier: vital:7264 , http://hdl.handle.net/10962/d1020273
- Description: The reaction of Zn(OAc)2 and C6H5COOH or 3,5-NO2-C6H3COOH with 3-ferrocenylpyrazolyl-methylenepyridine (L1), 3-ferrocenyl-5-methylpyrazolyl-methylenepyridine (L2), 3-ferrocenylpyrazolyl-ethylamine (L3) and 3-ferrocenyl-5-pyrazolyl-ethylamine (L4) afford the corresponding complexes [Zn(C6H5COO)2(L1)] (1), [Zn(C6H5COO)2(L2)] (2), [Zn(3,5-NO2-C6H3COO)2(L1)] (3), [Zn(3,5-NO2-C6H3COO)2(L2)] (4), [Zn(C6H5COO)2(L3)] (5), [Zn(C6H5COO)2(L4)] (6), [Zn(3,5-NO2-C6H3COO)2(L3)] (7) and [Zn(3,5-NO2-C6H3COO)2(L4)] (8). These complexes behave as catalysts for the ring opening polymerization of ɛ-caprolactone to produce polymers with molecular weight that range from 1480 to 7080 g mol−1 and exhibited moderate to broad PDIs. Evidence of these complexes acting as catalysts was obtained from both the polymerization data and kinetic studies. The polymerization data show that variation of the [CL]/[C] from 100 to 800 produced PCL with relatively the same molecular weight indicative of a catalyst behavior. The appearance of induction period in kinetic plots strengthens the fact that these complexes are catalysts rather than initiators. MALDI-TOF MS and 1H NMR data show di-hydroxy end groups, which support the coordination mechanism rather than insertion mechanism. To understand the broad PDIs obtained for some of the polymer, the electronic properties of the zinc complexes were investigated using cyclic voltammetry. The results show that the zinc complexes containing amine based ligands are highly electrophilic therefore making them unstable, hence the broad PDIs observed for zinc complexes containing amine based ligands. Among the eight complexes investigated, complex 7 is the most active catalyst with kp value of 1.18 × 10−7 h−1 mol−1 at 110 °C. , Original publication is available at http://dx.doi.org/10.1016/j.poly.2015.02.007
- Full Text: false
Jazz Informations
- Unknown
- Authors: Unknown
- Subjects: McGregor, Chris--1936-1990 , Brotherhood of Breath (Musical group) , Blue Notes (Musical group : South Africa) , Feza, Mongezi
- Language: English
- Type: Article
- Identifier: vital:13713 , http://hdl.handle.net/10962/d1012725
- Description: Photocopied article from Jazz magazine about Mongezi Feza's death. There is a photo of Mongezi Feza with this article.
- Full Text:
- Authors: Unknown
- Subjects: McGregor, Chris--1936-1990 , Brotherhood of Breath (Musical group) , Blue Notes (Musical group : South Africa) , Feza, Mongezi
- Language: English
- Type: Article
- Identifier: vital:13713 , http://hdl.handle.net/10962/d1012725
- Description: Photocopied article from Jazz magazine about Mongezi Feza's death. There is a photo of Mongezi Feza with this article.
- Full Text:
Live Wire
- Authors: Lake, Steve , Him, Christian
- Subjects: McGregor, Chris--1936-1990 , Brotherhood of Breath (Musical group) , Pukwana, Dudu , Dyani, Johnny Mbizo , Jazz musicians
- Language: English
- Type: Article
- Identifier: vital:13558 , http://hdl.handle.net/10962/d1006442 , McGregor, Chris--1936-1990 , Brotherhood of Breath (Musical group) , Pukwana, Dudu , Dyani, Johnny Mbizo , Jazz musicians
- Description: Photocopied article from the English magazine The Wire about the Moers 15th music festival in Germamy, where Chris McGregor’s Brotherhood of Breath played amongst other bands. The author of this article gives a rather negative critique on the performances.
- Full Text:
- Authors: Lake, Steve , Him, Christian
- Subjects: McGregor, Chris--1936-1990 , Brotherhood of Breath (Musical group) , Pukwana, Dudu , Dyani, Johnny Mbizo , Jazz musicians
- Language: English
- Type: Article
- Identifier: vital:13558 , http://hdl.handle.net/10962/d1006442 , McGregor, Chris--1936-1990 , Brotherhood of Breath (Musical group) , Pukwana, Dudu , Dyani, Johnny Mbizo , Jazz musicians
- Description: Photocopied article from the English magazine The Wire about the Moers 15th music festival in Germamy, where Chris McGregor’s Brotherhood of Breath played amongst other bands. The author of this article gives a rather negative critique on the performances.
- Full Text:
John Jolly : the Grahamstown bell founder
- Authors: Lewis, Colin A
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6173 , http://hdl.handle.net/10962/d1012364 , http://www.ringingworld.co.uk
- Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa.
- Full Text:
- Date Issued: 2002
- Authors: Lewis, Colin A
- Date: 2002
- Language: English
- Type: Article
- Identifier: vital:6173 , http://hdl.handle.net/10962/d1012364 , http://www.ringingworld.co.uk
- Description: Colin Lewis was Professor of Geography at Rhodes University, Grahamstown, South Africa from 1989 until his retirement at the end of 2007. In 1990, with the strong support of the incumbent Vice-Chancellor, Dr Derek Henderson, he instigated the Certificate in Change Ringing (Church Bell Ringing) in the Rhodes University Department of Music and Musicology - the first such course to be offered in Africa. Since that date he has lectured in the basic theory, and taught the practice of change ringing. He is the Ringing Master of the Cathedral of St Michael and St George, Grahamstown, South Africa.
- Full Text:
- Date Issued: 2002
Nuclear translocation of the Hsp70/Hsp90 organizing protein mSTI1 is regulated by cell cycle kinases
- Longshaw, Victoria M, Chapple, J Paul, Cheetham, Michael E, Blatch, Gregory L
- Authors: Longshaw, Victoria M , Chapple, J Paul , Cheetham, Michael E , Blatch, Gregory L
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6488 , http://hdl.handle.net/10962/d1006271 , https://dx.doi.org/10.1242/jcs.00905
- Description: The co-chaperone murine stress-inducible protein 1 (mSTI1), an Hsp70/Hsp90 organizing protein (Hop) homologue, mediates the assembly of the Hsp70/Hsp90 chaperone heterocomplex. The mSTI1 protein can be phosphorylated in vitro by cell cycle kinases proximal to a putative nuclear localization signal (NLS), which substantiated a predicted casein kinase II (CKII)-cdc2 kinase-NLS (CcN) motif at position 180-239 and suggested that mSTI1 might move between the cytoplasm and the nucleus under certain cell cycle conditions. The mechanism responsible for the cellular localization of mSTI1 was probed using NIH3T3 fibroblasts to investigate the localization of endogenous mSTI1 and enhanced green fluorescent protein (EGFP)-tagged mSTI1 mutants. Localization studies on cell lines stably expressing NLS(mSTI1)-EGFP and EGFP demonstrated that the NLS(mSTI1) was able to promote a nuclear localization of EGFP. The mSTI1 protein was exclusively cytoplasmic in most cells under normal conditions but was present in the nucleus of a subpopulation of cells and accumulated in the nucleus following inhibition of nuclear export (leptomycin B treatment). G1/S-phase arrest (using hydroxyurea) and inhibition of cdc2 kinase (using olomoucine) but not inhibition of casein kinase II (using 5,6-dichlorobenzimidazole riboside), increased the proportion of cells with endogenous mSTI1 nuclear staining. mSTI1-EGFP behaved identically to endogenous mSTI1. The functional importance of key residues was tested using modified mSTI1-EGFP proteins. Inactivation and phosphorylation mimicking of potential phosphorylation sites in mSTI1 altered the nuclear translocation. Mimicking of phosphorylation at the mSTI1 CKII phosphorylation site (S189E) promoted nuclear localization of mSTI1-EGFP. Mimicking phosphorylation at the cdc2 kinase phosphorylation site (T198E) promoted cytoplasmic localization of mSTI1-EGFP at the G1/S-phase transition,whereas removal of this site (T198A) promoted the nuclear localization of mSTI1-EGFP under the same conditions. These data provide the first evidence of nuclear import and export of a major Hsp70/Hsp90 co-chaperone and the regulation of this nuclear-cytoplasmic shuttling by cell cycle status and cell cycle kinases.
- Full Text:
- Date Issued: 2004
Nuclear translocation of the Hsp70/Hsp90 organizing protein mSTI1 is regulated by cell cycle kinases
- Authors: Longshaw, Victoria M , Chapple, J Paul , Cheetham, Michael E , Blatch, Gregory L
- Date: 2004
- Language: English
- Type: Article
- Identifier: vital:6488 , http://hdl.handle.net/10962/d1006271 , https://dx.doi.org/10.1242/jcs.00905
- Description: The co-chaperone murine stress-inducible protein 1 (mSTI1), an Hsp70/Hsp90 organizing protein (Hop) homologue, mediates the assembly of the Hsp70/Hsp90 chaperone heterocomplex. The mSTI1 protein can be phosphorylated in vitro by cell cycle kinases proximal to a putative nuclear localization signal (NLS), which substantiated a predicted casein kinase II (CKII)-cdc2 kinase-NLS (CcN) motif at position 180-239 and suggested that mSTI1 might move between the cytoplasm and the nucleus under certain cell cycle conditions. The mechanism responsible for the cellular localization of mSTI1 was probed using NIH3T3 fibroblasts to investigate the localization of endogenous mSTI1 and enhanced green fluorescent protein (EGFP)-tagged mSTI1 mutants. Localization studies on cell lines stably expressing NLS(mSTI1)-EGFP and EGFP demonstrated that the NLS(mSTI1) was able to promote a nuclear localization of EGFP. The mSTI1 protein was exclusively cytoplasmic in most cells under normal conditions but was present in the nucleus of a subpopulation of cells and accumulated in the nucleus following inhibition of nuclear export (leptomycin B treatment). G1/S-phase arrest (using hydroxyurea) and inhibition of cdc2 kinase (using olomoucine) but not inhibition of casein kinase II (using 5,6-dichlorobenzimidazole riboside), increased the proportion of cells with endogenous mSTI1 nuclear staining. mSTI1-EGFP behaved identically to endogenous mSTI1. The functional importance of key residues was tested using modified mSTI1-EGFP proteins. Inactivation and phosphorylation mimicking of potential phosphorylation sites in mSTI1 altered the nuclear translocation. Mimicking of phosphorylation at the mSTI1 CKII phosphorylation site (S189E) promoted nuclear localization of mSTI1-EGFP. Mimicking phosphorylation at the cdc2 kinase phosphorylation site (T198E) promoted cytoplasmic localization of mSTI1-EGFP at the G1/S-phase transition,whereas removal of this site (T198A) promoted the nuclear localization of mSTI1-EGFP under the same conditions. These data provide the first evidence of nuclear import and export of a major Hsp70/Hsp90 co-chaperone and the regulation of this nuclear-cytoplasmic shuttling by cell cycle status and cell cycle kinases.
- Full Text:
- Date Issued: 2004
Pseudopolydora species associated with mollusc shells on the south coast of South Africa, with the description of Ps. dayii, sp nov
- Authors: Simon, Carol A
- Date: 2009
- Language: English
- Type: text , Article
- Identifier: vital:6875 , http://hdl.handle.net/10962/d1011623
- Description: Two species of the genus Pseudopolydora, Ps. dayii, sp. nov. and Ps. antennata, were associated with gastropods on the south and south-east coasts of South Africa. Pseudopolydora dayii is characterized by prominent post-chaetal notopodial lobes on chaetiger 1 with very long chaetae, a prominent occipital tentacle, having hooded hooks that start on chaetiger 9, branchiae that start on chaetiger 6, stout hooks and lobes placed latero-posteriorly to the hooded hooks in posterior chaetigers. It is a surface-fouler and was found on several species of wild gastropods at four of the five sites sampled and from additional material from the south-west coast and on cultured abalone (Haliotis midae) at a farm on the south-west coast. Three individuals of Ps. antennata were found only with oysters at the easternmost site. This was the first record of this species outside of the Western Cape Province and it is possible that their association with the oysters was fortuitous.
- Full Text:
- Date Issued: 2009
- Authors: Simon, Carol A
- Date: 2009
- Language: English
- Type: text , Article
- Identifier: vital:6875 , http://hdl.handle.net/10962/d1011623
- Description: Two species of the genus Pseudopolydora, Ps. dayii, sp. nov. and Ps. antennata, were associated with gastropods on the south and south-east coasts of South Africa. Pseudopolydora dayii is characterized by prominent post-chaetal notopodial lobes on chaetiger 1 with very long chaetae, a prominent occipital tentacle, having hooded hooks that start on chaetiger 9, branchiae that start on chaetiger 6, stout hooks and lobes placed latero-posteriorly to the hooded hooks in posterior chaetigers. It is a surface-fouler and was found on several species of wild gastropods at four of the five sites sampled and from additional material from the south-west coast and on cultured abalone (Haliotis midae) at a farm on the south-west coast. Three individuals of Ps. antennata were found only with oysters at the easternmost site. This was the first record of this species outside of the Western Cape Province and it is possible that their association with the oysters was fortuitous.
- Full Text:
- Date Issued: 2009