Empirically modelled Pc3 activity based on solar wind parameters
- Heilig, B, Lotz, S I, Verő, J, Sutcliffe, P, Reda, J, Pajunpää, G, Raita, T
- Authors: Heilig, B , Lotz, S I , Verő, J , Sutcliffe, P , Reda, J , Pajunpää, G , Raita, T
- Date: 2010
- Language: English
- Type: text , Article
- Identifier: vital:6814 , http://hdl.handle.net/10962/d1004324
- Description: It is known that under certain solar wind (SW)/interplanetary magnetic field (IMF) conditions (e.g. high SW speed, low cone angle) the occurrence of ground-level Pc3–4 pulsations is more likely. In this paper we demonstrate that in the event of anomalously low SW particle density, Pc3 activity is extremely low regardless of otherwise favourable SW speed and cone angle. We re-investigate the SW control of Pc3 pulsation activity through a statistical analysis and two empirical models with emphasis on the influence of SW density on Pc3 activity. We utilise SW and IMF measurements from the OMNI project and ground-based magnetometer measurements from the MM100 array to relate SW and IMF measurements to the occurrence of Pc3 activity. Multiple linear regression and artificial neural network models are used in iterative processes in order to identify sets of SW-based input parameters, which optimally reproduce a set of Pc3 activity data. The inclusion of SW density in the parameter set significantly improves the models. Not only the density itself, but other density related parameters, such as the dynamic pressure of the SW, or the standoff distance of the magnetopause work equally well in the model. The disappearance of Pc3s during low-density events can have at least four reasons according to the existing upstream wave theory: 1. Pausing the ion-cyclotron resonance that generates the upstream ultra low frequency waves in the absence of protons, 2. Weakening of the bow shock that implies less efficient reflection, 3. The SW becomes sub-Alfvénic and hence it is not able to sweep back the waves propagating upstream with the Alfvén-speed, and 4. The increase of the standoff distance of the magnetopause (and of the bow shock). Although the models cannot account for the lack of Pc3s during intervals when the SW density is extremely low, the resulting sets of optimal model inputs support the generation of mid latitude Pc3 activity predominantly through upstream waves.
- Full Text:
- Date Issued: 2010
- Authors: Heilig, B , Lotz, S I , Verő, J , Sutcliffe, P , Reda, J , Pajunpää, G , Raita, T
- Date: 2010
- Language: English
- Type: text , Article
- Identifier: vital:6814 , http://hdl.handle.net/10962/d1004324
- Description: It is known that under certain solar wind (SW)/interplanetary magnetic field (IMF) conditions (e.g. high SW speed, low cone angle) the occurrence of ground-level Pc3–4 pulsations is more likely. In this paper we demonstrate that in the event of anomalously low SW particle density, Pc3 activity is extremely low regardless of otherwise favourable SW speed and cone angle. We re-investigate the SW control of Pc3 pulsation activity through a statistical analysis and two empirical models with emphasis on the influence of SW density on Pc3 activity. We utilise SW and IMF measurements from the OMNI project and ground-based magnetometer measurements from the MM100 array to relate SW and IMF measurements to the occurrence of Pc3 activity. Multiple linear regression and artificial neural network models are used in iterative processes in order to identify sets of SW-based input parameters, which optimally reproduce a set of Pc3 activity data. The inclusion of SW density in the parameter set significantly improves the models. Not only the density itself, but other density related parameters, such as the dynamic pressure of the SW, or the standoff distance of the magnetopause work equally well in the model. The disappearance of Pc3s during low-density events can have at least four reasons according to the existing upstream wave theory: 1. Pausing the ion-cyclotron resonance that generates the upstream ultra low frequency waves in the absence of protons, 2. Weakening of the bow shock that implies less efficient reflection, 3. The SW becomes sub-Alfvénic and hence it is not able to sweep back the waves propagating upstream with the Alfvén-speed, and 4. The increase of the standoff distance of the magnetopause (and of the bow shock). Although the models cannot account for the lack of Pc3s during intervals when the SW density is extremely low, the resulting sets of optimal model inputs support the generation of mid latitude Pc3 activity predominantly through upstream waves.
- Full Text:
- Date Issued: 2010
Differing interpretations of reconciliation in South Africa: a discussion of the home for all campaign
- Authors: Matthews, Sally
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142454 , vital:38081 , DOI:10.1353/trn.2010.0000
- Description: The theme of reconciliation remains an important one in South African politics. The issue of reconciliation was recently highlighted by South African Human Rights Commission chairperson, Jody Kollapen. According to Kollapen, in South Africa we have a problematic narrow interpretation of reconciliation, one that presents reconciliation and transformation as being in opposition to one another. This paper explores some of the debates about reconciliation as a process and then relates these to the Home for All Campaign. This Campaign was aimed at encouraging white South Africans to acknowledge the injustices of the past and to commit themselves to healing divisions and reducing inequalities in contemporary South Africa. It conceived of reconciliation as a process in which the onus is on white South Africans to take the initiative in reconciling with black South Africans. The Campaign received much publicity and provoked debate but never managed to gain the support of a significant number of white South Africans. In this paper, I explore the reasons for the Campaign's failure to meet all of its objectives, relating this to contemporary South African discourse on reconciliation. I argue that the Campaign's interpretation of reconciliation was valuable and necessary and that it remains imperative in South Africa that white South Africans critically reflect upon past and present privileges and take the initiative in processes of inter-racial reconciliation.
- Full Text:
- Date Issued: 2010
- Authors: Matthews, Sally
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/142454 , vital:38081 , DOI:10.1353/trn.2010.0000
- Description: The theme of reconciliation remains an important one in South African politics. The issue of reconciliation was recently highlighted by South African Human Rights Commission chairperson, Jody Kollapen. According to Kollapen, in South Africa we have a problematic narrow interpretation of reconciliation, one that presents reconciliation and transformation as being in opposition to one another. This paper explores some of the debates about reconciliation as a process and then relates these to the Home for All Campaign. This Campaign was aimed at encouraging white South Africans to acknowledge the injustices of the past and to commit themselves to healing divisions and reducing inequalities in contemporary South Africa. It conceived of reconciliation as a process in which the onus is on white South Africans to take the initiative in reconciling with black South Africans. The Campaign received much publicity and provoked debate but never managed to gain the support of a significant number of white South Africans. In this paper, I explore the reasons for the Campaign's failure to meet all of its objectives, relating this to contemporary South African discourse on reconciliation. I argue that the Campaign's interpretation of reconciliation was valuable and necessary and that it remains imperative in South Africa that white South Africans critically reflect upon past and present privileges and take the initiative in processes of inter-racial reconciliation.
- Full Text:
- Date Issued: 2010
Synthesis and electrochemical characterisation of new tantalum (V) alkythio phthalocyanines
- Chauke, Vongani, Nyokong, Tebello
- Authors: Chauke, Vongani , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249093 , vital:51777 , xlink:href="https://doi.org/10.1016/j.ica.2010.05.003"
- Description: The synthesis and electrochemical characterisation of octa-pentylthio (4a) and octa-octylthio (4b) – phthalocyaninato tantalum (III) hydroxide are hereby reported. These TaPc complexes absorb in the near infrared region (∼800 nm in dichloromethane). They show good solubility in most common solvents especially non-viscous solvents such as dichloromethane and chloroform. NMR, mass and infrared spectroscopy and elemental analysis confirmed the structures and purity of the synthesised complexes. The cyclic voltammograms (CVs) showed reversible reduction couples and irreversible oxidation peaks. The latter exhibited adsorption behavior. The reduction processes were observed at −0.74 and −1.13 V (versus Ag|AgCl) for 4a, and −0.67, −1.02 and −1.48 V (versus Ag|AgCl) for 4b. Spectroelectrochemistry confirmed one metal reduction, with the rest of the redox processes being centered on the phthalocyanine ring.
- Full Text:
- Date Issued: 2010
- Authors: Chauke, Vongani , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/249093 , vital:51777 , xlink:href="https://doi.org/10.1016/j.ica.2010.05.003"
- Description: The synthesis and electrochemical characterisation of octa-pentylthio (4a) and octa-octylthio (4b) – phthalocyaninato tantalum (III) hydroxide are hereby reported. These TaPc complexes absorb in the near infrared region (∼800 nm in dichloromethane). They show good solubility in most common solvents especially non-viscous solvents such as dichloromethane and chloroform. NMR, mass and infrared spectroscopy and elemental analysis confirmed the structures and purity of the synthesised complexes. The cyclic voltammograms (CVs) showed reversible reduction couples and irreversible oxidation peaks. The latter exhibited adsorption behavior. The reduction processes were observed at −0.74 and −1.13 V (versus Ag|AgCl) for 4a, and −0.67, −1.02 and −1.48 V (versus Ag|AgCl) for 4b. Spectroelectrochemistry confirmed one metal reduction, with the rest of the redox processes being centered on the phthalocyanine ring.
- Full Text:
- Date Issued: 2010
Novel, soluble, FluXoro functional substituted zinc phthalocyanines; synthesis, characterization and photophysicochemical properties
- Erdoğmuş, Ali, Nyokong, Tebello
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261258 , vital:53378 , xlink:href="https://doi.org/10.1016/j.dyepig.2010.01.001"
- Description: Three novel phthalonitriles and the respective, peripheral tetrakis zinc phthalocyanines were synthesized and characterized using elemental analysis, IR, 1H NMR, mass spectra and electronic spectroscopy. The phthalocyanines displayed good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene. The presence of a long chain fluorine substitituent was found to result in reduced aggregation. The singlet oxygen, photodegradation, fluorescence quantum yield, triplet quantum yield and triplet life time of the complexes in toluene were determined. The effect of fluoro-functional groups on the photophysical and photochemical parameters of the zinc(II) phthalocyanines are also reported. Fluorescence quantum yields for the complexes ranged from 0.021 to 0.041.
- Full Text:
- Date Issued: 2010
- Authors: Erdoğmuş, Ali , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/261258 , vital:53378 , xlink:href="https://doi.org/10.1016/j.dyepig.2010.01.001"
- Description: Three novel phthalonitriles and the respective, peripheral tetrakis zinc phthalocyanines were synthesized and characterized using elemental analysis, IR, 1H NMR, mass spectra and electronic spectroscopy. The phthalocyanines displayed good solubility in organic solvents such as CHCl3, DCM, DMSO, DMF, THF and toluene. The presence of a long chain fluorine substitituent was found to result in reduced aggregation. The singlet oxygen, photodegradation, fluorescence quantum yield, triplet quantum yield and triplet life time of the complexes in toluene were determined. The effect of fluoro-functional groups on the photophysical and photochemical parameters of the zinc(II) phthalocyanines are also reported. Fluorescence quantum yields for the complexes ranged from 0.021 to 0.041.
- Full Text:
- Date Issued: 2010
Assessment of antibiotic production by some marine actinomycetes belonging to the genera norcadia, saccharopolyspora and kibdellosporangium.
- Koba, Siziwe (https://orcid.org/0000-0002-6761-6403)
- Authors: Koba, Siziwe (https://orcid.org/0000-0002-6761-6403)
- Date: 2010
- Subjects: Actinobacteria , Bacteria , Actinomycetales
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25811 , vital:64488
- Description: Antibacterial potency of the extracts of the three marine actinomycetes strains which were isolated in the Nahoon Beach and tentatively identified as the genera Norcadia, Kibdellosporingium and Saccharopolyspora were investigated in this study against a panel of referenced, environmental and clinical bacterial strains. The ethyl acetate extracts of these marine actinomycetes were screened for activity against 32 bacterial isolates. Out of the 32 organisms, 10 were susceptible to one or all the extracts used. Antibacterial activity was mainly observed against Gram-negative organisms with Minimum inhibitory concentration (MIC) values ranging from 0.078 mg/ml to >10mg/ml. The killing rates of the active extracts were also elucidated using standard procedures. The two extracts NO64 and NO53 showed rapid bactericidal activity against B. pumilus ATCC 14884 and Serratia marcens with a 3Log10 reduction in counts within 6 hours at 3.75 mg/ml and 5 mg/ml respectively. In conclusion, the ethyl acetate extract of these marine actinomycetes strains possess strong bactericidal and bacteriostatic activities against Gram negative organisms and can be therapeutically useful in the treatment of bacterial infections which are mainly caused by Gram negative bacteria. , Thesis (MA) -- Faculty of Science and Agriculture, 2010
- Full Text:
- Date Issued: 2010
- Authors: Koba, Siziwe (https://orcid.org/0000-0002-6761-6403)
- Date: 2010
- Subjects: Actinobacteria , Bacteria , Actinomycetales
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/25811 , vital:64488
- Description: Antibacterial potency of the extracts of the three marine actinomycetes strains which were isolated in the Nahoon Beach and tentatively identified as the genera Norcadia, Kibdellosporingium and Saccharopolyspora were investigated in this study against a panel of referenced, environmental and clinical bacterial strains. The ethyl acetate extracts of these marine actinomycetes were screened for activity against 32 bacterial isolates. Out of the 32 organisms, 10 were susceptible to one or all the extracts used. Antibacterial activity was mainly observed against Gram-negative organisms with Minimum inhibitory concentration (MIC) values ranging from 0.078 mg/ml to >10mg/ml. The killing rates of the active extracts were also elucidated using standard procedures. The two extracts NO64 and NO53 showed rapid bactericidal activity against B. pumilus ATCC 14884 and Serratia marcens with a 3Log10 reduction in counts within 6 hours at 3.75 mg/ml and 5 mg/ml respectively. In conclusion, the ethyl acetate extract of these marine actinomycetes strains possess strong bactericidal and bacteriostatic activities against Gram negative organisms and can be therapeutically useful in the treatment of bacterial infections which are mainly caused by Gram negative bacteria. , Thesis (MA) -- Faculty of Science and Agriculture, 2010
- Full Text:
- Date Issued: 2010
Mobile phones, youth radio, citizen journalists: how the news is coming to Grahamstow
- Authors: Dugmore, Harry
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159412 , vital:40295 , https://hdl.handle.net/10520/EJC139343
- Description: Newspapers everywhere are being forced to rethink their role as simply providers of general news of the day. As people can access much more immediate information and news online, from a wide variety of sources, and get to "hear about things" from their friends and contacts through Facebook, Twitter and other "social media", local papers are having to find better ways to provide immediate and more useful information and news.
- Full Text:
- Date Issued: 2010
- Authors: Dugmore, Harry
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159412 , vital:40295 , https://hdl.handle.net/10520/EJC139343
- Description: Newspapers everywhere are being forced to rethink their role as simply providers of general news of the day. As people can access much more immediate information and news online, from a wide variety of sources, and get to "hear about things" from their friends and contacts through Facebook, Twitter and other "social media", local papers are having to find better ways to provide immediate and more useful information and news.
- Full Text:
- Date Issued: 2010
Factors affecting recapture rates of raggedtooth sharks Carcharias taurus tagged off the east coast of South Africa
- Dicken, Matthew L, Booth, Anthony J, Smale, Malcolm J
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124493 , vital:35618 , https://doi.10.2989/AJMS.2009.31.3.9.997
- Description: Understanding differences in the recapture rate between different tags (A-, B- and C-types), capture methods (rock-and-surf anglers, scientific divers and Natal Sharks Board protection nets) and life-history stages (juvenile and adult) is critical in evaluating the results obtained from cooperative tagging programmes (CTPs). A generalised linear modelling approach, using a log-linear model, was used to determine significant differences in the probability of recapture between these various factors using data from the Oceanographic Research Institute and Port Elizabeth Museum CTPs. Between 1984 and 2004, a total of 3 385 raggedtooth sharks Carcharias taurus was tagged by volunteers from both programmes along the east coast of South Africa. A likelihood ratio test indicated significant differences in the probability of recapture between A- and C-type and B- and C-type tags (p < 0.01), between different capture methods (p < 0.05) and between juvenile and adult sharks (p < 0.01). A comparison of recapture rates between members of the CTPs also indicated a marked variability in the performance of individual taggers. The study highlights important data-quality issues inherent in large CTPs.
- Full Text:
- Date Issued: 2010
- Authors: Dicken, Matthew L , Booth, Anthony J , Smale, Malcolm J
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/124493 , vital:35618 , https://doi.10.2989/AJMS.2009.31.3.9.997
- Description: Understanding differences in the recapture rate between different tags (A-, B- and C-types), capture methods (rock-and-surf anglers, scientific divers and Natal Sharks Board protection nets) and life-history stages (juvenile and adult) is critical in evaluating the results obtained from cooperative tagging programmes (CTPs). A generalised linear modelling approach, using a log-linear model, was used to determine significant differences in the probability of recapture between these various factors using data from the Oceanographic Research Institute and Port Elizabeth Museum CTPs. Between 1984 and 2004, a total of 3 385 raggedtooth sharks Carcharias taurus was tagged by volunteers from both programmes along the east coast of South Africa. A likelihood ratio test indicated significant differences in the probability of recapture between A- and C-type and B- and C-type tags (p < 0.01), between different capture methods (p < 0.05) and between juvenile and adult sharks (p < 0.01). A comparison of recapture rates between members of the CTPs also indicated a marked variability in the performance of individual taggers. The study highlights important data-quality issues inherent in large CTPs.
- Full Text:
- Date Issued: 2010
To be Xhosa or not to be Xhosa… that is the question:
- Authors: De Klerk, Vivian A
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158096 , vital:40148 , https://doi.org/10.1080/01434630008666401
- Description: It has long been recognised that indigenous languages are endangered because of powerful social, political and economic pressures. In South Africa, the legacy of apartheid has left its indigenous languages particularly vulnerable, and since 1994 huge efforts have been made to reverse the situation. Despite the new language policy and accompanying legislation, it would seem that many Xhosa speakers themselves want English, and not Xhosa,for their children. This paper reports on a multi-faceted quantitative and qualitative survey in and around Grahamstown in the Eastern Cape Province, which focused on the steady trickle of speakers of Xhosa into English-medium schools in thearea, and examined the reasons underlying decisions to send Xhosa children to these schools and the subsequent linguistic and psycho-social effects of the move on the children.
- Full Text:
- Date Issued: 2010
- Authors: De Klerk, Vivian A
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/158096 , vital:40148 , https://doi.org/10.1080/01434630008666401
- Description: It has long been recognised that indigenous languages are endangered because of powerful social, political and economic pressures. In South Africa, the legacy of apartheid has left its indigenous languages particularly vulnerable, and since 1994 huge efforts have been made to reverse the situation. Despite the new language policy and accompanying legislation, it would seem that many Xhosa speakers themselves want English, and not Xhosa,for their children. This paper reports on a multi-faceted quantitative and qualitative survey in and around Grahamstown in the Eastern Cape Province, which focused on the steady trickle of speakers of Xhosa into English-medium schools in thearea, and examined the reasons underlying decisions to send Xhosa children to these schools and the subsequent linguistic and psycho-social effects of the move on the children.
- Full Text:
- Date Issued: 2010
Photodynamic therapy for the Developing World
- Authors: Songca, S P
- Date: 2010
- Subjects: Skin -- Diseases -- Photochemotherapy Phototherapy Skin -- Diseases -- Treatment
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/1056 , vital:30559
- Description: This article contains some of the contributing works to the founding of the prestigious journal Tetrahedron and it describes the total synthesis of chlorophyll-a starting from Knorr's pyrrole synthesis and includes more than forty six stages required to reach the target molecule.
- Full Text:
- Date Issued: 2010
- Authors: Songca, S P
- Date: 2010
- Subjects: Skin -- Diseases -- Photochemotherapy Phototherapy Skin -- Diseases -- Treatment
- Language: English
- Type: text , Lectures
- Identifier: http://hdl.handle.net/11260/1056 , vital:30559
- Description: This article contains some of the contributing works to the founding of the prestigious journal Tetrahedron and it describes the total synthesis of chlorophyll-a starting from Knorr's pyrrole synthesis and includes more than forty six stages required to reach the target molecule.
- Full Text:
- Date Issued: 2010
Contrivance with purpose?: International relations and the reconstitution of the international
- Authors: Bischoff, Paul, 1954-
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161480 , vital:40631
- Description: In observing and plotting the dialectics of how our present world works, fragmenting as it integrates we struggle in wanting to pin down a moving target! Unlike the world of science with its physical laws, the social nature of the world and its relations across borders keep changing course with social and transnational relations constantly mutating. This makes it rather difficult to plot the complexity of human relations, also those across borders. As the late Nobel Laureate Herbert Simon once said, the social sciences are, after all, the really ‘hard’ sciences. They are so hard because they are so hard to explain.
- Full Text:
- Date Issued: 2010
- Authors: Bischoff, Paul, 1954-
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/161480 , vital:40631
- Description: In observing and plotting the dialectics of how our present world works, fragmenting as it integrates we struggle in wanting to pin down a moving target! Unlike the world of science with its physical laws, the social nature of the world and its relations across borders keep changing course with social and transnational relations constantly mutating. This makes it rather difficult to plot the complexity of human relations, also those across borders. As the late Nobel Laureate Herbert Simon once said, the social sciences are, after all, the really ‘hard’ sciences. They are so hard because they are so hard to explain.
- Full Text:
- Date Issued: 2010
Gaming culture: what lessons for pedagogy in South Africa?
- Kaschula, Russell H, Mostert, Andre
- Authors: Kaschula, Russell H , Mostert, Andre
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175189 , vital:42551 , https://hdl.handle.net/10520/EJC30895
- Description: Gaming culture is becoming increasingly ubiquitous. Whereas before it was the reserve of those who were prepared to invest in the latest gaming hardware, increasingly powerful entry level machines coupled with more powerful mobile technologies are impacting on how young learners and students assimilate information. This evolving characteristic exhibited by the learners across South Africa must generate a serious reflection of education and training methodologies. Historically, education structures have been slow to embrace the changes that are imperative if the products of the process are to be adequately prepared for the future that faces them. One of the most telling realities of the modern era, or the planetary phase as it is now being tagged, is rapid change. The question that all educators need to ask is 'how is my pedagogic approach evolving'?.
- Full Text:
- Date Issued: 2010
- Authors: Kaschula, Russell H , Mostert, Andre
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/175189 , vital:42551 , https://hdl.handle.net/10520/EJC30895
- Description: Gaming culture is becoming increasingly ubiquitous. Whereas before it was the reserve of those who were prepared to invest in the latest gaming hardware, increasingly powerful entry level machines coupled with more powerful mobile technologies are impacting on how young learners and students assimilate information. This evolving characteristic exhibited by the learners across South Africa must generate a serious reflection of education and training methodologies. Historically, education structures have been slow to embrace the changes that are imperative if the products of the process are to be adequately prepared for the future that faces them. One of the most telling realities of the modern era, or the planetary phase as it is now being tagged, is rapid change. The question that all educators need to ask is 'how is my pedagogic approach evolving'?.
- Full Text:
- Date Issued: 2010
Dialectics of dance and dress: the performative negotiation of Soli girl initiates (Moye) in Zambia
- Authors: Simbao, Ruth K
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147492 , vital:38643 , https://doi.org/10.1162/afar.2010.43.3.64
- Description: During a 2005 dance rehearsal in Nkomeshya Village near Lusaka, Zambia, a group of Soli girl initiates (moye) entered a clearing, slowly moving towards the drummer who beckoned them with her rhythmic eats. The girls per-formed a polite curtseying step, reflecting the meek modesty they are taught to display when they humbly greet elders or their future husbands with downcast eyes.
- Full Text:
- Date Issued: 2010
- Authors: Simbao, Ruth K
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147492 , vital:38643 , https://doi.org/10.1162/afar.2010.43.3.64
- Description: During a 2005 dance rehearsal in Nkomeshya Village near Lusaka, Zambia, a group of Soli girl initiates (moye) entered a clearing, slowly moving towards the drummer who beckoned them with her rhythmic eats. The girls per-formed a polite curtseying step, reflecting the meek modesty they are taught to display when they humbly greet elders or their future husbands with downcast eyes.
- Full Text:
- Date Issued: 2010
Art and Ethical Criticism, edited by Garry L. Hagberg
- Authors: Jones, Ward E
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/275612 , vital:55063 , xlink:href="https://doi.org/10.1093/mind/fzq098"
- Description: Book Review: If there is a norm that a book’s title should give a reliable indication of its contents, Art and Ethical Criticism does not quite meet it. By my judgement, only seven of its twelve essays concern either the ethical criticism of art or the criticism of ethical positions within artworks.
- Full Text:
- Date Issued: 2010
- Authors: Jones, Ward E
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/275612 , vital:55063 , xlink:href="https://doi.org/10.1093/mind/fzq098"
- Description: Book Review: If there is a norm that a book’s title should give a reliable indication of its contents, Art and Ethical Criticism does not quite meet it. By my judgement, only seven of its twelve essays concern either the ethical criticism of art or the criticism of ethical positions within artworks.
- Full Text:
- Date Issued: 2010
Vice-Chancellor's welcoming address 2010
- Authors: Badat, Saleem
- Date: 2010
- Language: English
- Type: text
- Identifier: vital:7590 , http://hdl.handle.net/10962/d1006581
- Description: From introduction: Rhodes University, which means, you and I and academics and support staff, exists to serve three purposes. The first is to produce knowledge, so that we can advance understanding of our natural and social worlds and enrich our accumulated scientific and cultural heritage. As a university our second purpose is to disseminate knowledge and to cultivate minds. Our goal is to ensure that you can think imaginatively, “effectively and critically”; that you “achieve depth in some field of knowledge”; that you can critique and construct alternatives, that you can communicate cogently, orally and in writing, and that you have a “critical appreciation of the ways in which we gain knowledge and understanding of the universe, of society, and of ourselves” Our final purpose as a university is to undertake community engagement. On the one hand this involves your voluntary participation in community projects undertaken thorough our Community Engagement office. On the other hand, it involves service-learning, in which through your academic courses you take part “in activities where both the community” and you benefit, “and where the goals are to provide a service to the community and, equally, to enhance (your) learning through rendering this service”
- Full Text:
- Date Issued: 2010
- Authors: Badat, Saleem
- Date: 2010
- Language: English
- Type: text
- Identifier: vital:7590 , http://hdl.handle.net/10962/d1006581
- Description: From introduction: Rhodes University, which means, you and I and academics and support staff, exists to serve three purposes. The first is to produce knowledge, so that we can advance understanding of our natural and social worlds and enrich our accumulated scientific and cultural heritage. As a university our second purpose is to disseminate knowledge and to cultivate minds. Our goal is to ensure that you can think imaginatively, “effectively and critically”; that you “achieve depth in some field of knowledge”; that you can critique and construct alternatives, that you can communicate cogently, orally and in writing, and that you have a “critical appreciation of the ways in which we gain knowledge and understanding of the universe, of society, and of ourselves” Our final purpose as a university is to undertake community engagement. On the one hand this involves your voluntary participation in community projects undertaken thorough our Community Engagement office. On the other hand, it involves service-learning, in which through your academic courses you take part “in activities where both the community” and you benefit, “and where the goals are to provide a service to the community and, equally, to enhance (your) learning through rendering this service”
- Full Text:
- Date Issued: 2010
Interaction between nickel hydroxy phthalocyanine derivatives with p-chlorophenol
- Khene, Samson, Lobb, Kevin, Nyokong, Tebello
- Authors: Khene, Samson , Lobb, Kevin , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/248461 , vital:51688 , xlink:href="https://doi.org/10.1016/j.electacta.2010.10.007"
- Description: In this work the interaction between peripherally (β) substituted nickel tetrahydroxyphthalocyanines (β-NiPc(OH)4 and β-Ni(O)Pc(OH)4) with p-chlorophenol is theoretically rationalised by performing calculations at B3LYP/6-31G(d) level. Density functional theory (DFT) and molecular orbital theory are used to calculate the condensed Fukui function for phthalocyanine derivatives and p-chlorophenol, in order to determine the reactive sites involved when p-chlorophenol is oxidized, and to compare theoretically predicted reactivity to experimentally determined electrocatalytic activity. Electrocatalytic activities of adsorbed NiPc derivatives: ads-α-NiPc(OH)8-OPGE (OPGE = ordinary poly graphite electrode), ads-α-NiPc(OH)4-OPGE and ads-β-NiPc(OH)4-OPGE are compared with those of the polymerized counterparts: poly-α-Ni(O)Pc(OH)8-OPGE, poly-α-NiPc(OH)4-OPGE and poly-β-NiPc(OH)4-OPGE, respectively.
- Full Text:
- Date Issued: 2010
- Authors: Khene, Samson , Lobb, Kevin , Nyokong, Tebello
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/248461 , vital:51688 , xlink:href="https://doi.org/10.1016/j.electacta.2010.10.007"
- Description: In this work the interaction between peripherally (β) substituted nickel tetrahydroxyphthalocyanines (β-NiPc(OH)4 and β-Ni(O)Pc(OH)4) with p-chlorophenol is theoretically rationalised by performing calculations at B3LYP/6-31G(d) level. Density functional theory (DFT) and molecular orbital theory are used to calculate the condensed Fukui function for phthalocyanine derivatives and p-chlorophenol, in order to determine the reactive sites involved when p-chlorophenol is oxidized, and to compare theoretically predicted reactivity to experimentally determined electrocatalytic activity. Electrocatalytic activities of adsorbed NiPc derivatives: ads-α-NiPc(OH)8-OPGE (OPGE = ordinary poly graphite electrode), ads-α-NiPc(OH)4-OPGE and ads-β-NiPc(OH)4-OPGE are compared with those of the polymerized counterparts: poly-α-Ni(O)Pc(OH)8-OPGE, poly-α-NiPc(OH)4-OPGE and poly-β-NiPc(OH)4-OPGE, respectively.
- Full Text:
- Date Issued: 2010
Global resonance, local amplification: Antjie Krog on a world stage
- Authors: Garman, Anthea
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159736 , vital:40338 , https://doi.org/10.1080/02533950903562468
- Description: As a result of the publication of Country of my Skull, an extraordinary literary enactment of witness and confession, Antjie Krog has become internationally known as a writer profoundly engaged with the events and human drama uncovered by the South African Truth and Reconciliation Commission. Her voice is read as that of an expert witness of trauma, forgiveness and the means by which the horrors of the past may be addressed. In seeking to understand how Krog came to be taken up internationally as a representative voice of the South African transition, I focus on a particular global–local nexus for an explanation. I theorise that dealing with the past via truth commissions, a global publishing context and the work of a local writer with a record of excellent literary output and political action enabled a fit which resulted in Krog coming to prominence on a world stage.
- Full Text:
- Date Issued: 2010
- Authors: Garman, Anthea
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159736 , vital:40338 , https://doi.org/10.1080/02533950903562468
- Description: As a result of the publication of Country of my Skull, an extraordinary literary enactment of witness and confession, Antjie Krog has become internationally known as a writer profoundly engaged with the events and human drama uncovered by the South African Truth and Reconciliation Commission. Her voice is read as that of an expert witness of trauma, forgiveness and the means by which the horrors of the past may be addressed. In seeking to understand how Krog came to be taken up internationally as a representative voice of the South African transition, I focus on a particular global–local nexus for an explanation. I theorise that dealing with the past via truth commissions, a global publishing context and the work of a local writer with a record of excellent literary output and political action enabled a fit which resulted in Krog coming to prominence on a world stage.
- Full Text:
- Date Issued: 2010
In search of critical engagement: a history of South African university based journalism
- du Toit, Jeanne, de Beer, Arnold S
- Authors: du Toit, Jeanne , de Beer, Arnold S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159453 , vital:40299 , https://hdl.handle.net/10520/EJC139372
- Description: Historical discussions of South African journalism education (Tomaselli 1991: 167; De Beer and Tomaselli 2000; Steenveld 2006) refer to examples of teaching practice which have served as critical interventions into political process. They occur primarily in the late 1970s and 1980s and it is arguable that the social circumstances that existed during this period presented unique opportunities for critical education. The literature suggests, however, that these examples represent the exception rather than the rule. It would seem, in fact, that a critical approach to journalism education has never been realised in South Africa in any substantive way. It is with this argument in mind that I explore, in this paper, the historical construction of journalism as a subject of university education in South Africa.
- Full Text:
- Date Issued: 2010
- Authors: du Toit, Jeanne , de Beer, Arnold S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/159453 , vital:40299 , https://hdl.handle.net/10520/EJC139372
- Description: Historical discussions of South African journalism education (Tomaselli 1991: 167; De Beer and Tomaselli 2000; Steenveld 2006) refer to examples of teaching practice which have served as critical interventions into political process. They occur primarily in the late 1970s and 1980s and it is arguable that the social circumstances that existed during this period presented unique opportunities for critical education. The literature suggests, however, that these examples represent the exception rather than the rule. It would seem, in fact, that a critical approach to journalism education has never been realised in South Africa in any substantive way. It is with this argument in mind that I explore, in this paper, the historical construction of journalism as a subject of university education in South Africa.
- Full Text:
- Date Issued: 2010
The geochemistry and evolution of Palaeogene phonolites, central Namibia:
- Authors: Marsh, Julian S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145000 , vital:38399 , https://doi.org/10.1016/j.lithos.2010.02.012
- Description: Phonolites of Palaeogene age occur at two different localities in central Namibia, occurring as clusters of eroded monogenetic lava domes. Six phonolites at Aris collectively exhibit a narrow compositional range and represent a single magma system of highly evolved phonolite with high concentrations of Na2O, Rb, Th, Zr, Zn, Pb, and REE and very low abundances of MgO, P2O5, Sr and Ba. No mafic rocks are associated with the Aris phonolites and their ultimate petrogenetic origin remains obscure. The more abundant Staalhart phonolites exhibit more variable but scattered compositional variation consistent with fractional crystallization dominated by sanidine (and nepheline) and pyroxene. The behaviour of REE is decoupled from Zr, Nb, and Th in this suite indicating a controlling role for minor phases in their evolution. The least evolved phonolites have initial 87Sr/86Sr 0.7043, which is identical to a small occurrence of associated plagioclase-bearing nephelinite indicating a possible petrogenetic link.
- Full Text:
- Date Issued: 2010
- Authors: Marsh, Julian S
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145000 , vital:38399 , https://doi.org/10.1016/j.lithos.2010.02.012
- Description: Phonolites of Palaeogene age occur at two different localities in central Namibia, occurring as clusters of eroded monogenetic lava domes. Six phonolites at Aris collectively exhibit a narrow compositional range and represent a single magma system of highly evolved phonolite with high concentrations of Na2O, Rb, Th, Zr, Zn, Pb, and REE and very low abundances of MgO, P2O5, Sr and Ba. No mafic rocks are associated with the Aris phonolites and their ultimate petrogenetic origin remains obscure. The more abundant Staalhart phonolites exhibit more variable but scattered compositional variation consistent with fractional crystallization dominated by sanidine (and nepheline) and pyroxene. The behaviour of REE is decoupled from Zr, Nb, and Th in this suite indicating a controlling role for minor phases in their evolution. The least evolved phonolites have initial 87Sr/86Sr 0.7043, which is identical to a small occurrence of associated plagioclase-bearing nephelinite indicating a possible petrogenetic link.
- Full Text:
- Date Issued: 2010
Econometric determinants of liquidity of the South African bond market
- Mingiri, Kapingura Forget https://orcid.org/0000-0002-5808-5612
- Authors: Mingiri, Kapingura Forget https://orcid.org/0000-0002-5808-5612
- Date: 2010
- Subjects: Economic indicators , Economic forecasting -- Africa , Bond market
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26346 , vital:65243
- Description: The importance of the bond market to the financial system and broader economy of a country cannot be underestimated. It is important to analyse factors which determine liquidity in this essential market. This study seeks to establish the determinants of liquidity in the South African bond market using monthly data covering the period 1995 to 2009. It begins by providing an updated overview of the South African bond market and an analysis of the relevant literature. Two models linking bond market liquidity to its theoretical determinants were specified. In contrast to the available literature, this study analyses liquidity at both macroeconomic and market microstructure level using two measures of liquidity, volume and the bid-ask spread, applying the VAR approach and two-stage least squares for robust check. All macroeconomic variables (except stock market) were identified to have an impact on bond market liquidity in the long-run. As far as market microstructure factors are concerned, both volume and volatility were established to be important determinants of liquidity in the South African bond market. The study recommended that, as for macroeconomic factors, authorities should keep inflation at low and stables levels as well as a stable currency. Also, offering bond investors certain facilities and the removal of restrictions on foreign investor activities are other important conditions to improve bond market liquidity. As far as market microstructure factors are concerned, we suggest that, ways to safe-guard against excessive volatility include the creation of a vibrant derivative market, development of a more active and well-functioning repurchase market./ , Thesis (MCom) -- Faculty of Management and Commerce, 2010
- Full Text:
- Date Issued: 2010
- Authors: Mingiri, Kapingura Forget https://orcid.org/0000-0002-5808-5612
- Date: 2010
- Subjects: Economic indicators , Economic forecasting -- Africa , Bond market
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26346 , vital:65243
- Description: The importance of the bond market to the financial system and broader economy of a country cannot be underestimated. It is important to analyse factors which determine liquidity in this essential market. This study seeks to establish the determinants of liquidity in the South African bond market using monthly data covering the period 1995 to 2009. It begins by providing an updated overview of the South African bond market and an analysis of the relevant literature. Two models linking bond market liquidity to its theoretical determinants were specified. In contrast to the available literature, this study analyses liquidity at both macroeconomic and market microstructure level using two measures of liquidity, volume and the bid-ask spread, applying the VAR approach and two-stage least squares for robust check. All macroeconomic variables (except stock market) were identified to have an impact on bond market liquidity in the long-run. As far as market microstructure factors are concerned, both volume and volatility were established to be important determinants of liquidity in the South African bond market. The study recommended that, as for macroeconomic factors, authorities should keep inflation at low and stables levels as well as a stable currency. Also, offering bond investors certain facilities and the removal of restrictions on foreign investor activities are other important conditions to improve bond market liquidity. As far as market microstructure factors are concerned, we suggest that, ways to safe-guard against excessive volatility include the creation of a vibrant derivative market, development of a more active and well-functioning repurchase market./ , Thesis (MCom) -- Faculty of Management and Commerce, 2010
- Full Text:
- Date Issued: 2010
Ethics-oriented learning in environmental education workplaces: An activity theory approach
- Authors: Olvitt, Lausanne L
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/370961 , vital:66398 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122874"
- Description: In the context of increasing national and global environmental challenges and their implications for the working world, new ethics and practices are being introduced into workplaces that take better account of socio-ecological relations. Little is understood, however, about the nature of ethics-oriented workplace learning. Drawing on Cultural Historical Activity Theory (CHAT), which enables historically and contextually situated relational perspectives to emerge, this paper explores contradictions in the activity systems of two young environmental education learner-practitioners struggling to engage with the ethical dimensions of their professional work and the professional development course they are studying. The study focuses in particular on the environmental values and ethics component of their course – a year-long Learnership in Environmental Education, Training and Development Practices (EETDP). The paper reflects how tensions and contradictions within and between the interacting activity systems of the workplace, the course, and its regulating qualifications authority influence the teaching and learning of the environmental ethics component of the course. Ethics-oriented teaching and learning processes are found to be strongly influenced by the ‘rules’ and ‘mediating tools’ of these interacting systems, but these are often at odds with the ethical perspectives, socio-cultural context and skills of the ‘subject’ and ‘community’. These systemic contradictions can be more fully understood when their cultural and historical origins are made explicit. The analytical process has led to a more nuanced understanding of ethics-oriented teaching and learning in a workplace-based course, and has revealed several areas needing more careful research (particularly the area of environmental discourses) and the explicit and implicit language of ethics.
- Full Text:
- Date Issued: 2010
- Authors: Olvitt, Lausanne L
- Date: 2010
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/370961 , vital:66398 , xlink:href="https://www.ajol.info/index.php/sajee/article/view/122874"
- Description: In the context of increasing national and global environmental challenges and their implications for the working world, new ethics and practices are being introduced into workplaces that take better account of socio-ecological relations. Little is understood, however, about the nature of ethics-oriented workplace learning. Drawing on Cultural Historical Activity Theory (CHAT), which enables historically and contextually situated relational perspectives to emerge, this paper explores contradictions in the activity systems of two young environmental education learner-practitioners struggling to engage with the ethical dimensions of their professional work and the professional development course they are studying. The study focuses in particular on the environmental values and ethics component of their course – a year-long Learnership in Environmental Education, Training and Development Practices (EETDP). The paper reflects how tensions and contradictions within and between the interacting activity systems of the workplace, the course, and its regulating qualifications authority influence the teaching and learning of the environmental ethics component of the course. Ethics-oriented teaching and learning processes are found to be strongly influenced by the ‘rules’ and ‘mediating tools’ of these interacting systems, but these are often at odds with the ethical perspectives, socio-cultural context and skills of the ‘subject’ and ‘community’. These systemic contradictions can be more fully understood when their cultural and historical origins are made explicit. The analytical process has led to a more nuanced understanding of ethics-oriented teaching and learning in a workplace-based course, and has revealed several areas needing more careful research (particularly the area of environmental discourses) and the explicit and implicit language of ethics.
- Full Text:
- Date Issued: 2010