The relationship between debtors policies and recovery of debtors on the Nelson Mandela University financial statements
- Authors: Jiba, Mncedikazi Felicelle
- Date: 2021-04
- Subjects: Financial statements , Accounting -- Standards , Debtor and creditor -- South Africa -- Eastern Cape
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/51864 , vital:43379
- Description: The purpose of the study was to investigate the relationship between the debt collection process in terms of the debtors polices and the recovery of debtors on the annual financial statements at Nelson Mandela University. A related goal was to determine if the debt collection as per debtor’s policy is effective enough to recover debtors in time as debtors affects in financial operations of the university. The student fees are one of the sources of income of the university. When there is an increase in debtors it means debt collection is decreasing, which ultimately affects the cash flow income that is increased through the debtors of the university. The results showed that Nelson Mandela University is collecting debt as per the debtor’s policy, however the recovery of debtors is not in the benefits of the university as large amounts of debtors are tied up to handed over to clients. , Thesis (MTech) -- Faculty of Business and Economic Sciences, Cost management accounting, 2021
- Full Text: false
- Date Issued: 2021-04
- Authors: Jiba, Mncedikazi Felicelle
- Date: 2021-04
- Subjects: Financial statements , Accounting -- Standards , Debtor and creditor -- South Africa -- Eastern Cape
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/51864 , vital:43379
- Description: The purpose of the study was to investigate the relationship between the debt collection process in terms of the debtors polices and the recovery of debtors on the annual financial statements at Nelson Mandela University. A related goal was to determine if the debt collection as per debtor’s policy is effective enough to recover debtors in time as debtors affects in financial operations of the university. The student fees are one of the sources of income of the university. When there is an increase in debtors it means debt collection is decreasing, which ultimately affects the cash flow income that is increased through the debtors of the university. The results showed that Nelson Mandela University is collecting debt as per the debtor’s policy, however the recovery of debtors is not in the benefits of the university as large amounts of debtors are tied up to handed over to clients. , Thesis (MTech) -- Faculty of Business and Economic Sciences, Cost management accounting, 2021
- Full Text: false
- Date Issued: 2021-04
A compliance framework for IT governance adoption and use by state-owned entities in South Africa
- Authors: Nxozi, Monelo
- Date: 2023-03-31
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/419244 , vital:71628
- Description: Embargoed. Possible release date in early 2025. , Thesis (PhD) -- Faculty of Commerce, Information Systems, 2023
- Full Text:
- Date Issued: 2023-03-31
- Authors: Nxozi, Monelo
- Date: 2023-03-31
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Doctoral theses , text
- Identifier: http://hdl.handle.net/10962/419244 , vital:71628
- Description: Embargoed. Possible release date in early 2025. , Thesis (PhD) -- Faculty of Commerce, Information Systems, 2023
- Full Text:
- Date Issued: 2023-03-31
The distribution and perceptions of invasive alien plants in small towns in the Eastern Cape province, South Africa
- Authors: Seboko, Tshepiso Collen
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/${Handle} , vital:65669
- Description: Invasive alien plants (IAP) of different life forms have major effects on biodiversity, ecosystem functioning, economies, and livelihoods worldwide. There is evidence that IAP are rapidly increasing around the world, and the negative impacts associated with them are expected to worsen due to continuing land transformation, climate change, and urbanisation. Yet, information on the distribution, abundance, knowledge, and perceptions of IAP is limited, especially in small towns. Most previous research has largely focused on rural settings and larger cities, thus hindering the effective control and management of IAP in smaller urban settings. It is therefore important to assess the distribution of IAP to provide useful information to guide clearing and mitigation efforts to reduce the impacts and proliferation of IAP in smaller urban settings. Consequently, the aim of the study was to determine the distribution, composition, abundance, and perceptions of woody IAP in small towns in the Eastern Cape province of South Africa and assess how and why they may differ within and between towns. To achieve this aim, a drive by road survey was undertaken across all suburbs and land use types in 12 small towns located in the Eastern Cape province of South Africa. The 12 randomly selected small towns were, Adelaide, Alexandria, Barkley East, Bedford, Burgersdorp, Cathcart, Kirkwood, Middelburg, Paterson, Somerset East, St. Francis Bay and Willowmore. All woody IAP visible from the surveyed roads were counted across all suburbs and land use types within each town. A total of 38 427 woody IAP were enumerated, with 56 species across different land use types and suburbs in all towns. Affluent suburbs accounted for 58% of the IAP enumerated, while the Reconstructed Development Programme (RDP) suburbs accounted for only 5%. In terms of the land use type, most of the IAP were encountered in the residential areas (54%), as compared to, road verges (32%) and public urban green spaces (PUGS) (14%). Of the 12 towns, Middleburg had the highest number of woody IAP, with 5 573 individuals, while Paterson had the lowest number with 947. The most common IAP species across all towns was Melia azedarach with 4 384 individuals, followed by Pinus elliotti (4 051), and Jacaranda mimosifolia (3 640). Spathodea campanulata, Ardisia crenata, and Parkinsonia aculeata had the lowest number of individuals with only two individuals each across all towns. This study also assessed the knowledge, perceptions, and willingness of urban residents to control IAP in their home yards using household surveys. A total of 240 household surveys were administered in the 12 towns. The results showed that more than half of the respondents (59%) had no knowledge of IAP, while 14% had neutral knowledge and only 2% had high knowledge. Forty percent of the respondents agreed that IAP pose a problem to the environment whilst 11% did not think IAP posed a problem to the environment, and 49% stated that they do not know. Most of the respondents (91%) perceived IAP positively, and stated that they benefit from the IAP, with the most mentioned benefit being shade (50%). Almost two-thirds of the respondents (65%) were willing to report on the IAP in their yards to the relevant authorities that deal with the control and management of IAP. Over half (56%) of the respondents were willing to have the IAP removed from their gardens, with the most stated reason for removal was because the IAP caused damage to property (13%). Respondents thought that the local government (35%) or district government (30%) should be responsible for the control and management of IAP. Overall, the study showed that IAP species were most common in residential land use type and affluent suburbs. These findings can assist the relevant authorities that deal with IAP, regarding which plant species, suburbs, and land use types to prioritise regarding awareness and investment for control and management. This will also help explore alternative indigenous species that can be used as replacements that may offer the same benefits derived from IAP by urban residents. , Thesis (MSc) -- Faculty of Science, Environmental Science, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Seboko, Tshepiso Collen
- Date: 2022-10-14
- Subjects: Uncatalogued
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/${Handle} , vital:65669
- Description: Invasive alien plants (IAP) of different life forms have major effects on biodiversity, ecosystem functioning, economies, and livelihoods worldwide. There is evidence that IAP are rapidly increasing around the world, and the negative impacts associated with them are expected to worsen due to continuing land transformation, climate change, and urbanisation. Yet, information on the distribution, abundance, knowledge, and perceptions of IAP is limited, especially in small towns. Most previous research has largely focused on rural settings and larger cities, thus hindering the effective control and management of IAP in smaller urban settings. It is therefore important to assess the distribution of IAP to provide useful information to guide clearing and mitigation efforts to reduce the impacts and proliferation of IAP in smaller urban settings. Consequently, the aim of the study was to determine the distribution, composition, abundance, and perceptions of woody IAP in small towns in the Eastern Cape province of South Africa and assess how and why they may differ within and between towns. To achieve this aim, a drive by road survey was undertaken across all suburbs and land use types in 12 small towns located in the Eastern Cape province of South Africa. The 12 randomly selected small towns were, Adelaide, Alexandria, Barkley East, Bedford, Burgersdorp, Cathcart, Kirkwood, Middelburg, Paterson, Somerset East, St. Francis Bay and Willowmore. All woody IAP visible from the surveyed roads were counted across all suburbs and land use types within each town. A total of 38 427 woody IAP were enumerated, with 56 species across different land use types and suburbs in all towns. Affluent suburbs accounted for 58% of the IAP enumerated, while the Reconstructed Development Programme (RDP) suburbs accounted for only 5%. In terms of the land use type, most of the IAP were encountered in the residential areas (54%), as compared to, road verges (32%) and public urban green spaces (PUGS) (14%). Of the 12 towns, Middleburg had the highest number of woody IAP, with 5 573 individuals, while Paterson had the lowest number with 947. The most common IAP species across all towns was Melia azedarach with 4 384 individuals, followed by Pinus elliotti (4 051), and Jacaranda mimosifolia (3 640). Spathodea campanulata, Ardisia crenata, and Parkinsonia aculeata had the lowest number of individuals with only two individuals each across all towns. This study also assessed the knowledge, perceptions, and willingness of urban residents to control IAP in their home yards using household surveys. A total of 240 household surveys were administered in the 12 towns. The results showed that more than half of the respondents (59%) had no knowledge of IAP, while 14% had neutral knowledge and only 2% had high knowledge. Forty percent of the respondents agreed that IAP pose a problem to the environment whilst 11% did not think IAP posed a problem to the environment, and 49% stated that they do not know. Most of the respondents (91%) perceived IAP positively, and stated that they benefit from the IAP, with the most mentioned benefit being shade (50%). Almost two-thirds of the respondents (65%) were willing to report on the IAP in their yards to the relevant authorities that deal with the control and management of IAP. Over half (56%) of the respondents were willing to have the IAP removed from their gardens, with the most stated reason for removal was because the IAP caused damage to property (13%). Respondents thought that the local government (35%) or district government (30%) should be responsible for the control and management of IAP. Overall, the study showed that IAP species were most common in residential land use type and affluent suburbs. These findings can assist the relevant authorities that deal with IAP, regarding which plant species, suburbs, and land use types to prioritise regarding awareness and investment for control and management. This will also help explore alternative indigenous species that can be used as replacements that may offer the same benefits derived from IAP by urban residents. , Thesis (MSc) -- Faculty of Science, Environmental Science, 2022
- Full Text:
- Date Issued: 2022-10-14
Spatial and temporal analysis of the critical zone in the Western rift valley corridor: towards earth stewardship science in East Africa
- Authors: Miller, Warren David
- Date: 2022-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/59771 , vital:62423
- Description: Over the coming decades, Africa is expected to experience disturbing effects due to climate change and increased land cover change due to human influences presenting a significant concern for the future well-being of human and biological systems, the latter being the foundation of ecosystem services supplied to humanity. Therefore, unprecedented transdisciplinary cooperation, coordination, and integration amongst researchers, government, and civil society are necessary to increase the resiliency of these systems. This study aims to provide an outline of the Africa Alive Corridors (AAC) as an essential model for the encouragement of sustainable development through Earth Stewardship science. These aims are accompanied by the quantification and forward modelling for land cover change of the Critical Zone over 10 Great Lake Basins across one of the AAC, the Western Rift Valley Corridor (WRVC), in East Africa between the years 2018 and 2060. This approach provides the foundation for implementing improved regional governance, better encouragement of sustainable development beyond the 2030 United Nations Sustainable Development Goals, and education programs, such as the AAC, that promote socio-ecological resilience through Earth Stewardship Science. The AAC archives a portion of East Africa as the WRVC, a corridor along the western branch of the East African Rift System that highlights twenty heritage nodes, primarily great lakes, mountain ranges, national parks, and biological hotspots. These heritage entities are associated with ca. 12-million-years of evolution and transformation of the East African topography and related African Great Lake (AGL) systems. The thesis defines the study area by delineating AGL basins intersected by the WRVC. Across these basins, land cover change analysis provides a platform for an integrated assessment of the projected health of the corridor region. Existing land cover datasets provide the initial conditions of the study area for 2008 and 2013. Land cover between 2008 and 2013 is cross-tabulated using the Land Cover Module in the Terrset software, followed by the iii delineation of sub-models and driver variable identification. The Multi-Layer Perceptron algorithm provides the transition potentials between tree cover, urban area, cropland, wetland, and open area classes. Change quantification and prediction using Markov Chain analysis are then established for 2018, 2030, and 2060. The model successfully simulated future land cover change and concluded that: (1) proximity to existing human activity, proximity to existing tree cover, and population are the primary drivers of change; (2) the dominant land cover of the ten lake basins for 2018 was cropland at ca. 48%, followed by tree cover at ca. 33%; (3) total anthropogenic change over the coming four decades equates to over ca. 52 000 km2 (5 200 000 ha), and particularly (4) an urban area is expected to increase by >130%. This assessment ultimately provides a platform for regional governance development at the basin scale and Earth Stewardship science in East Africa. These changes require transdisciplinary action from researchers to civil society. The AAC provides the foundation for understanding the dynamics of the systems that support life across broader spatial and temporal resolutions in Africa, highlighting the need for future generations to build socio-ecological resilience to anticipate challenges such as biodiversity loss posed by climate change and excessive land cover change. , Thesis (DSc) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-12
- Authors: Miller, Warren David
- Date: 2022-12
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Doctoral theses , text
- Identifier: http://hdl.handle.net/10948/59771 , vital:62423
- Description: Over the coming decades, Africa is expected to experience disturbing effects due to climate change and increased land cover change due to human influences presenting a significant concern for the future well-being of human and biological systems, the latter being the foundation of ecosystem services supplied to humanity. Therefore, unprecedented transdisciplinary cooperation, coordination, and integration amongst researchers, government, and civil society are necessary to increase the resiliency of these systems. This study aims to provide an outline of the Africa Alive Corridors (AAC) as an essential model for the encouragement of sustainable development through Earth Stewardship science. These aims are accompanied by the quantification and forward modelling for land cover change of the Critical Zone over 10 Great Lake Basins across one of the AAC, the Western Rift Valley Corridor (WRVC), in East Africa between the years 2018 and 2060. This approach provides the foundation for implementing improved regional governance, better encouragement of sustainable development beyond the 2030 United Nations Sustainable Development Goals, and education programs, such as the AAC, that promote socio-ecological resilience through Earth Stewardship Science. The AAC archives a portion of East Africa as the WRVC, a corridor along the western branch of the East African Rift System that highlights twenty heritage nodes, primarily great lakes, mountain ranges, national parks, and biological hotspots. These heritage entities are associated with ca. 12-million-years of evolution and transformation of the East African topography and related African Great Lake (AGL) systems. The thesis defines the study area by delineating AGL basins intersected by the WRVC. Across these basins, land cover change analysis provides a platform for an integrated assessment of the projected health of the corridor region. Existing land cover datasets provide the initial conditions of the study area for 2008 and 2013. Land cover between 2008 and 2013 is cross-tabulated using the Land Cover Module in the Terrset software, followed by the iii delineation of sub-models and driver variable identification. The Multi-Layer Perceptron algorithm provides the transition potentials between tree cover, urban area, cropland, wetland, and open area classes. Change quantification and prediction using Markov Chain analysis are then established for 2018, 2030, and 2060. The model successfully simulated future land cover change and concluded that: (1) proximity to existing human activity, proximity to existing tree cover, and population are the primary drivers of change; (2) the dominant land cover of the ten lake basins for 2018 was cropland at ca. 48%, followed by tree cover at ca. 33%; (3) total anthropogenic change over the coming four decades equates to over ca. 52 000 km2 (5 200 000 ha), and particularly (4) an urban area is expected to increase by >130%. This assessment ultimately provides a platform for regional governance development at the basin scale and Earth Stewardship science in East Africa. These changes require transdisciplinary action from researchers to civil society. The AAC provides the foundation for understanding the dynamics of the systems that support life across broader spatial and temporal resolutions in Africa, highlighting the need for future generations to build socio-ecological resilience to anticipate challenges such as biodiversity loss posed by climate change and excessive land cover change. , Thesis (DSc) -- Faculty of Science, School of Environmental Sciences, 2022
- Full Text:
- Date Issued: 2022-12
Photoreduction of tin (IV) phthalocyanines
- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293413 , vital:57083 , xlink:href="https://doi.org/10.1016/S0277-5387(00)83491-9"
- Description: Photolysis of Sn(IV)Pc(OH)2 (Pc = phthalocyanine dianion) and Sn(IV)Pc(Cl)2 using a tungsten lamp, and in the presence of SnCl2·2H2O as an electron donor results in the reduction of these complexes of π anion radical species. The reduction shows second order dependence on the concentration of the Sn(IV)Pc complexes and a first order dependence on SnCl2·H2O.
- Full Text:
- Date Issued: 1994
- Authors: Nyokong, Tebello
- Date: 1994
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/293413 , vital:57083 , xlink:href="https://doi.org/10.1016/S0277-5387(00)83491-9"
- Description: Photolysis of Sn(IV)Pc(OH)2 (Pc = phthalocyanine dianion) and Sn(IV)Pc(Cl)2 using a tungsten lamp, and in the presence of SnCl2·2H2O as an electron donor results in the reduction of these complexes of π anion radical species. The reduction shows second order dependence on the concentration of the Sn(IV)Pc complexes and a first order dependence on SnCl2·H2O.
- Full Text:
- Date Issued: 1994
Hop as an anti-cancer drug target
- Vaaltyn, Michaelone Chantelle
- Authors: Vaaltyn, Michaelone Chantelle
- Date: 2020
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/164704 , vital:41156 , doi:10.21504/10962/164704
- Description: Thesis (PhD)--Rhodes University, Biochemistry and Microbiology, 2020
- Full Text:
- Date Issued: 2020
- Authors: Vaaltyn, Michaelone Chantelle
- Date: 2020
- Subjects: Uncatalogued
- Language: English
- Type: thesis , text , Doctoral , PhD
- Identifier: http://hdl.handle.net/10962/164704 , vital:41156 , doi:10.21504/10962/164704
- Description: Thesis (PhD)--Rhodes University, Biochemistry and Microbiology, 2020
- Full Text:
- Date Issued: 2020
Synthesis, photophysical and nonlinear optical properties of microwave synthesized 4-tetra and octa-substituted lead phthalocyanines
- Modibane, Desmond K, Nyokong, Tebello
- Authors: Modibane, Desmond K , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263452 , vital:53629 , xlink:href="https://doi.org/10.1016/j.poly.2009.03.013"
- Description: This work presents the photophysical and nonlinear optical behaviour of newly synthesized complexes: 2,(3)-tetrakis(4-benzyloxyphenoxyphthalocyaninato) lead (5a) and 2,3-octakis(4-benzyloxyphenoxyphthalocyaninato) lead (6a). The nonlinear optical behaviour of complexes 5a and 6a are compared with those of 2,(3)-tetraphenoxyphthalocyaninato lead (5b), 2,(3)-tetrakis(4-t-butylphenoxyphthalocyaninato) lead (5c), 2,3-octaphenoxyphthalocyaninato lead (6b) and 2,3-octakis(4-t-butylphenoxyphthalocyaninato) lead (6c). The synthesis of 5a and 6a was performed using microwave irradiation. Photophysical properties were studied for these complexes in dimethylsulfoxide, dimethylformamide, toluene, tetrahydrofuran and chloroform. The fluorescence spectra were different from excitation spectra due to demetallation upon excitation. High triplet quantum yields ranging from 0.80 to 0.86 (in DMSO, DMF and toluene) and low triplet lifetimes (20–50 μs in DMSO, and more than 10 μs in the rest of the solvents) were observed due to the presence of heavy atom. Nonlinear optical properties were studied in dimethylsulfoxide. The optical limiting threshold intensity (Ilim) for the PbPc derivatives were calculated and ranged from 2.1 to 6.6 W/cm2.
- Full Text:
- Date Issued: 2009
- Authors: Modibane, Desmond K , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263452 , vital:53629 , xlink:href="https://doi.org/10.1016/j.poly.2009.03.013"
- Description: This work presents the photophysical and nonlinear optical behaviour of newly synthesized complexes: 2,(3)-tetrakis(4-benzyloxyphenoxyphthalocyaninato) lead (5a) and 2,3-octakis(4-benzyloxyphenoxyphthalocyaninato) lead (6a). The nonlinear optical behaviour of complexes 5a and 6a are compared with those of 2,(3)-tetraphenoxyphthalocyaninato lead (5b), 2,(3)-tetrakis(4-t-butylphenoxyphthalocyaninato) lead (5c), 2,3-octaphenoxyphthalocyaninato lead (6b) and 2,3-octakis(4-t-butylphenoxyphthalocyaninato) lead (6c). The synthesis of 5a and 6a was performed using microwave irradiation. Photophysical properties were studied for these complexes in dimethylsulfoxide, dimethylformamide, toluene, tetrahydrofuran and chloroform. The fluorescence spectra were different from excitation spectra due to demetallation upon excitation. High triplet quantum yields ranging from 0.80 to 0.86 (in DMSO, DMF and toluene) and low triplet lifetimes (20–50 μs in DMSO, and more than 10 μs in the rest of the solvents) were observed due to the presence of heavy atom. Nonlinear optical properties were studied in dimethylsulfoxide. The optical limiting threshold intensity (Ilim) for the PbPc derivatives were calculated and ranged from 2.1 to 6.6 W/cm2.
- Full Text:
- Date Issued: 2009
Drifting towards death: a South African patient safety incident through an HFE Systems lens
- Authors: Agar, Sarah Leigh
- Date: 2022-10-14
- Subjects: Patients Safety measures , Medical errors Prevention , Human engineering , Medical care South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362716 , vital:65356
- Description: Patient Safety Incidents (PSI) are a frequent occurrence within the South African public healthcare system wherein a patient is unnecessarily maimed, harmed, killed, or put through significant trauma, emotional or physical. These incidents have a significant impact on the performance of the system and the well-being of individuals involved. Often PSI are the result of multiple system failings that provide the necessary preconditions for the PSI to occur. Thus, to provide appropriate patient safety recommendations to address and aid in the prevention of future PSI it is necessary to apply a systems approach to PSI analysis. A systems approach supports a ‘bigger picture’ view of an incident which includes looking beyond the immediate causes of a PSI and taking the different levels of the healthcare system into consideration during incident analysis. Human Factors and Ergonomics (HFE) is at its core a systems discipline and has been successfully applied to multiple fields including healthcare. HFE offers multiple incident analysis tools grounded in systems theory. The Life Esidimeni incident, a PSI that resulted in the death of 144 MHCU, is the biggest PSI in recent South African history and is therefore an important potential case study for the application of HFE systems tools within the South African healthcare context (an area that is lacking in existing literature). The objectives of this research were to (i) Systematically uncover the causal factors that led to the outcome of the of the Life Esidimeni incident; (ii) Identify critical faults, and gaps within the healthcare system that led to the Life Esidimeni PSI; and (iii) Provide proactive recommendations for future prevention of PSI. To fulfil these objectives a descriptive case study research method design was adopted using a qualitative systems-based tool, AcciMap. The application of AcciMap to Life Esidimeni enabled both the sharp end and blunt end causal factors that contributed to the outcome of the incident to be identified. Importantly this provided insight into the critical faults and gaps of the South African public healthcare system. The results of the AcciMap indicated that there were four main broad systemic faults in the system. These broad areas were categorized as key themes, which include: (i) competency, (ii) safeguards, (iii) time pressures, and (iv) vertical integration. From these key themes recommendations aimed at addressing the critical faults and gaps in the system and preventing future PSI were made. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2022
- Full Text:
- Date Issued: 2022-10-14
- Authors: Agar, Sarah Leigh
- Date: 2022-10-14
- Subjects: Patients Safety measures , Medical errors Prevention , Human engineering , Medical care South Africa
- Language: English
- Type: Academic theses , Master's theses , text
- Identifier: http://hdl.handle.net/10962/362716 , vital:65356
- Description: Patient Safety Incidents (PSI) are a frequent occurrence within the South African public healthcare system wherein a patient is unnecessarily maimed, harmed, killed, or put through significant trauma, emotional or physical. These incidents have a significant impact on the performance of the system and the well-being of individuals involved. Often PSI are the result of multiple system failings that provide the necessary preconditions for the PSI to occur. Thus, to provide appropriate patient safety recommendations to address and aid in the prevention of future PSI it is necessary to apply a systems approach to PSI analysis. A systems approach supports a ‘bigger picture’ view of an incident which includes looking beyond the immediate causes of a PSI and taking the different levels of the healthcare system into consideration during incident analysis. Human Factors and Ergonomics (HFE) is at its core a systems discipline and has been successfully applied to multiple fields including healthcare. HFE offers multiple incident analysis tools grounded in systems theory. The Life Esidimeni incident, a PSI that resulted in the death of 144 MHCU, is the biggest PSI in recent South African history and is therefore an important potential case study for the application of HFE systems tools within the South African healthcare context (an area that is lacking in existing literature). The objectives of this research were to (i) Systematically uncover the causal factors that led to the outcome of the of the Life Esidimeni incident; (ii) Identify critical faults, and gaps within the healthcare system that led to the Life Esidimeni PSI; and (iii) Provide proactive recommendations for future prevention of PSI. To fulfil these objectives a descriptive case study research method design was adopted using a qualitative systems-based tool, AcciMap. The application of AcciMap to Life Esidimeni enabled both the sharp end and blunt end causal factors that contributed to the outcome of the incident to be identified. Importantly this provided insight into the critical faults and gaps of the South African public healthcare system. The results of the AcciMap indicated that there were four main broad systemic faults in the system. These broad areas were categorized as key themes, which include: (i) competency, (ii) safeguards, (iii) time pressures, and (iv) vertical integration. From these key themes recommendations aimed at addressing the critical faults and gaps in the system and preventing future PSI were made. , Thesis (MSc) -- Faculty of Science, Human Kinetics and Ergonomics, 2022
- Full Text:
- Date Issued: 2022-10-14
Effect of bromination on the optical limiting properties at 532 nm of BODIPY dyes with p-benzyloxystyryl groups at the 3, 5-positions
- Ngoy, Bokolombe P, May, Aviwe K, Mack, John, Nyokong, Tebello
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187507 , vital:44665 , xlink:href="https://doi.org/10.1016/j.molstruc.2018.08.012"
- Description: The optical limiting (OL) properties of 3,5-di-p-benzyloxystyrylBODIPY dyes that contain both protons and bromine atoms at the 2,6-positions have been investigated by using the Z-scan technique at 532 nm on the nanosecond timescale. There is relatively weak absorbance at 532 nm under ambient light conditions, because the incorporation of p-benzyloxystyryl groups at the 3,5-positions results in a ca. 140 nm red shift of the main BODIPY spectral band to the 640–670 nm range. Reverse saturable absorbance (RSA) profiles that are consistent with an excited state absorption (ESA) mechanism involving the T1 and/or S1 states are observed in CH2Cl2 solution. Second order hyperpolarizability values of ca. 8 × 10−30 esu are obtained and this demonstrates that the dyes are potentially suitable for use in OL applications at 532 nm. There is a slight enhancement of the OL properties upon bromination, due to increased intersystem crossing to the triplet manifold, but the enhancement of the OL properties is less significant than has been observed with metal phthalocyanine complexes.
- Full Text:
- Date Issued: 2019
- Authors: Ngoy, Bokolombe P , May, Aviwe K , Mack, John , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187507 , vital:44665 , xlink:href="https://doi.org/10.1016/j.molstruc.2018.08.012"
- Description: The optical limiting (OL) properties of 3,5-di-p-benzyloxystyrylBODIPY dyes that contain both protons and bromine atoms at the 2,6-positions have been investigated by using the Z-scan technique at 532 nm on the nanosecond timescale. There is relatively weak absorbance at 532 nm under ambient light conditions, because the incorporation of p-benzyloxystyryl groups at the 3,5-positions results in a ca. 140 nm red shift of the main BODIPY spectral band to the 640–670 nm range. Reverse saturable absorbance (RSA) profiles that are consistent with an excited state absorption (ESA) mechanism involving the T1 and/or S1 states are observed in CH2Cl2 solution. Second order hyperpolarizability values of ca. 8 × 10−30 esu are obtained and this demonstrates that the dyes are potentially suitable for use in OL applications at 532 nm. There is a slight enhancement of the OL properties upon bromination, due to increased intersystem crossing to the triplet manifold, but the enhancement of the OL properties is less significant than has been observed with metal phthalocyanine complexes.
- Full Text:
- Date Issued: 2019
Employee performance, leadership style and emotional intelligence
- Hayward, Brett A, Amos, Trevor L, Baxter, Jeremy
- Authors: Hayward, Brett A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270077 , vital:54393 , xlink:href="https://hdl.handle.net/10520/EJC17031"
- Description: Purpose: The purpose of this research is to explore the relationship between employee performance, leadership style and emotional intelligence in the context of a South African parastatal. Problem Investigated: There is a lack of literature and empirical research on the type of leadership required to achieve high levels of employee performance within South African parastatals. Methodology: The Multifactor Leadership Questionnaire (MLQ) was used to determine leadership style, while the Emotional Competency Profiler (ECP) was used to determine the emotional intelligence of the sample of leaders. Employee performance data was provided by the parastatal, based on their performance management system. Data was analysed using correlation analysis, multiple regression analysis, the standard regression ANOVA/F-test, t-tests and Cronbach alpha reliability coefficient. Findings: The findings of the research show that the ECP is a reliable measure of emotional intelligence and that while the MLQ is a reliable measure of transformational leadership, it is not a reliable measure of transactional leadership. The results of the correlation analysis show a positive significant relationship between emotional intelligence and transformational leadership and a negative significant relationship between employee performance and emotional intelligence. The results of regressing employee performance on emotional intelligence and transformational leadership show that emotional intelligence and transformational leadership have no significant effect on employee performance. The results of the regression models of the research could be biased by the lack of variance in employee performance data. Value of the Research: The value of the research lies in it confirming the MLQ as a reliable measure of transformational leadership and the ECP as a reliable measure of emotional intelligence. The finding of a positive significant relationship between emotional intelligence and transformational leadership is a valuable contribution to the literature. Conclusion: Although a positive significant relationship between emotional intelligence and transformational leadership was found, there is a need for further research to determine the type of leadership best suited to achieve high levels of employee performance within the parastatal.
- Full Text:
- Date Issued: 2008
- Authors: Hayward, Brett A , Amos, Trevor L , Baxter, Jeremy
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/270077 , vital:54393 , xlink:href="https://hdl.handle.net/10520/EJC17031"
- Description: Purpose: The purpose of this research is to explore the relationship between employee performance, leadership style and emotional intelligence in the context of a South African parastatal. Problem Investigated: There is a lack of literature and empirical research on the type of leadership required to achieve high levels of employee performance within South African parastatals. Methodology: The Multifactor Leadership Questionnaire (MLQ) was used to determine leadership style, while the Emotional Competency Profiler (ECP) was used to determine the emotional intelligence of the sample of leaders. Employee performance data was provided by the parastatal, based on their performance management system. Data was analysed using correlation analysis, multiple regression analysis, the standard regression ANOVA/F-test, t-tests and Cronbach alpha reliability coefficient. Findings: The findings of the research show that the ECP is a reliable measure of emotional intelligence and that while the MLQ is a reliable measure of transformational leadership, it is not a reliable measure of transactional leadership. The results of the correlation analysis show a positive significant relationship between emotional intelligence and transformational leadership and a negative significant relationship between employee performance and emotional intelligence. The results of regressing employee performance on emotional intelligence and transformational leadership show that emotional intelligence and transformational leadership have no significant effect on employee performance. The results of the regression models of the research could be biased by the lack of variance in employee performance data. Value of the Research: The value of the research lies in it confirming the MLQ as a reliable measure of transformational leadership and the ECP as a reliable measure of emotional intelligence. The finding of a positive significant relationship between emotional intelligence and transformational leadership is a valuable contribution to the literature. Conclusion: Although a positive significant relationship between emotional intelligence and transformational leadership was found, there is a need for further research to determine the type of leadership best suited to achieve high levels of employee performance within the parastatal.
- Full Text:
- Date Issued: 2008
“Turn on” fluorescence enhancement of Zn octacarboxyphthaloyanine-graphene oxide conjugates by hydrogen peroxide
- Shumba, Munyaradzi, Mashazi, Philani N, Nyokong, Tebello
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240875 , vital:50881 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
- Authors: Shumba, Munyaradzi , Mashazi, Philani N , Nyokong, Tebello
- Date: 2016
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/240875 , vital:50881 , xlink:href="https://doi.org/10.1016/j.jlumin.2015.11.001"
- Description: Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates were characterized by absorption spectroscopy, transmission electron microscopy, fluorescence spectroscopy, X-ray diffraction, thermo gravimetric analysis and X-ray photon spectroscopy. The presence of reduced graphene oxide or graphene oxide resulted in the quenching (turn on) of Zn octacarboxy phthalocyanine fluorescence which can be explained by photoinduced electron transfer. Zn octacarboxy phthalocyanine-reduced graphene oxide or graphene oxide conjugates “turned on” fluorescence showed a linear response to hydrogen peroxide hence their potential to be used as sensors. The nanoprobe developed showed high selectivity towards hydrogen peroxide in the presence of physiological interferences.
- Full Text:
- Date Issued: 2016
An information privacy compliance model based on configurable software objects
- Authors: Kandeh, Agbor Takang
- Date: 2022-04
- Subjects: Software protection , Software configuration management
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/58374 , vital:59052
- Description: South Africa’s Protection of Personal Information Act (POPIA), Act 4 of 2013 requires that organisations enforce information privacy rules in technology systems handling personally identifiable information (PII). This is in line with other national and regional information privacy legislations across the world. However, the absence of a coherent way to implement this legislation, in the form of software objects in technology systems, has created a gap in organisations around the world. To bridge this gap, this thesis proposes a compliance model based on a conceptual framework, a design framework, and a software-based prototype. The objective of this model is to test how best to enforce information privacy regulations in technology systems handling personally identifiable information. The proposed conceptual framework views information privacy compliance as a context-driven reality enforced by configurable software objects. To refine the conceptual framework, a design framework and a software-based prototype was developed using the design science research methodology as the theoretical construct and the UML ontology language and object-oriented programming paradigms as the underpinning practical construct. This prototype will assist organisational stakeholders in understanding and visualising the theoretical and practical constructs of handling personally identifiable information as software objects in technology systems. The design and implementation of this prototype resulted in some practical and theoretical recommendations. These include the adoption of a decision model notation (DMN) as a formal standard to manage privacy rules and the creation of a context-aware privacy compliance zone (CAP). However, the main contribution of this thesis is a reusable conceptual and contextual design framework and a prototype through which POPIA rules, or those of any similar information privacy law, such as the European General Data Protection Regulation (GDPR), can be encapsulated into software objects used in technology systems to ease compliance with information privacy regulations. , Thesis (PhD) -- Faculty of Engineering, the Built Environment, and Technology, 2022
- Full Text:
- Date Issued: 2022-04
- Authors: Kandeh, Agbor Takang
- Date: 2022-04
- Subjects: Software protection , Software configuration management
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/58374 , vital:59052
- Description: South Africa’s Protection of Personal Information Act (POPIA), Act 4 of 2013 requires that organisations enforce information privacy rules in technology systems handling personally identifiable information (PII). This is in line with other national and regional information privacy legislations across the world. However, the absence of a coherent way to implement this legislation, in the form of software objects in technology systems, has created a gap in organisations around the world. To bridge this gap, this thesis proposes a compliance model based on a conceptual framework, a design framework, and a software-based prototype. The objective of this model is to test how best to enforce information privacy regulations in technology systems handling personally identifiable information. The proposed conceptual framework views information privacy compliance as a context-driven reality enforced by configurable software objects. To refine the conceptual framework, a design framework and a software-based prototype was developed using the design science research methodology as the theoretical construct and the UML ontology language and object-oriented programming paradigms as the underpinning practical construct. This prototype will assist organisational stakeholders in understanding and visualising the theoretical and practical constructs of handling personally identifiable information as software objects in technology systems. The design and implementation of this prototype resulted in some practical and theoretical recommendations. These include the adoption of a decision model notation (DMN) as a formal standard to manage privacy rules and the creation of a context-aware privacy compliance zone (CAP). However, the main contribution of this thesis is a reusable conceptual and contextual design framework and a prototype through which POPIA rules, or those of any similar information privacy law, such as the European General Data Protection Regulation (GDPR), can be encapsulated into software objects used in technology systems to ease compliance with information privacy regulations. , Thesis (PhD) -- Faculty of Engineering, the Built Environment, and Technology, 2022
- Full Text:
- Date Issued: 2022-04
Service dogs for Autism Spectrum Disorder: the experiences of caregivers in South Africa
- Authors: Martin, Emma Jeanne
- Date: 2022-04-07
- Subjects: Autism spectrum disorders South Africa , Service dogs South Africa , Animals Therapeutic use South Africa , Caregivers South Africa , Animals Therapeutic use Public opinion , Animal welfare South Africa , Children with autism spectrum disorders South Africa
- Language: English
- Type: Master's thesis , text
- Identifier: http://hdl.handle.net/10962/232855 , vital:50032
- Description: Autism spectrum disorder (ASD) is a neurodevelopmental disorder, most frequently diagnosed in childhood, with symptoms including deficits in social communication and interaction as well as restricted, repetitive patterns of behaviours, interests and activities. There is no known cure for ASD, with current treatment methods focussing upon reducing symptom severity. One such treatment method is the use of autism service dogs. Internationally, autism service dogs have been available for over two decades, while in South Africa they have only been available since 2015. A fair amount of internationally published data is available on autism service dogs, however, at the time of this research study, no data was available within South Africa. This study aimed to provide a baseline for research on autism service dogs within South Africa, by documenting the experiences of caregivers whose ASD children had been supplied with autism service dogs, with regard to the uses, effects, accessibility and public perception of the autism service dogs, as well as recommendations for future improvements of autism service dogs within South Africa. Lastly, inquiry into the welfare of the autism service dogs was sought. This study was qualitative in nature, with eight families who had been supplied with autism service dogs having chosen to participate. Data collection was achieved through one semi-structured interview with each family, which was then transcribed and thematically analysed using a hermeneutic phenomenological approach. Results indicated that autism service dogs were perceived as generally accessible, useful and beneficial for ASD children and their caregivers in a variety of ways, however, they were not without their challenges, with lifestyle adjustments and public perception being especially problematic. Participants also noted recommendations for possible future improvements. Lastly, welfare concerns for the autism service dogs relating to violent behaviour exhibited by ASD children was identified, raising the question of the suitability of service dogs for the ASD population. , Thesis (MA) -- Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-04-07
- Authors: Martin, Emma Jeanne
- Date: 2022-04-07
- Subjects: Autism spectrum disorders South Africa , Service dogs South Africa , Animals Therapeutic use South Africa , Caregivers South Africa , Animals Therapeutic use Public opinion , Animal welfare South Africa , Children with autism spectrum disorders South Africa
- Language: English
- Type: Master's thesis , text
- Identifier: http://hdl.handle.net/10962/232855 , vital:50032
- Description: Autism spectrum disorder (ASD) is a neurodevelopmental disorder, most frequently diagnosed in childhood, with symptoms including deficits in social communication and interaction as well as restricted, repetitive patterns of behaviours, interests and activities. There is no known cure for ASD, with current treatment methods focussing upon reducing symptom severity. One such treatment method is the use of autism service dogs. Internationally, autism service dogs have been available for over two decades, while in South Africa they have only been available since 2015. A fair amount of internationally published data is available on autism service dogs, however, at the time of this research study, no data was available within South Africa. This study aimed to provide a baseline for research on autism service dogs within South Africa, by documenting the experiences of caregivers whose ASD children had been supplied with autism service dogs, with regard to the uses, effects, accessibility and public perception of the autism service dogs, as well as recommendations for future improvements of autism service dogs within South Africa. Lastly, inquiry into the welfare of the autism service dogs was sought. This study was qualitative in nature, with eight families who had been supplied with autism service dogs having chosen to participate. Data collection was achieved through one semi-structured interview with each family, which was then transcribed and thematically analysed using a hermeneutic phenomenological approach. Results indicated that autism service dogs were perceived as generally accessible, useful and beneficial for ASD children and their caregivers in a variety of ways, however, they were not without their challenges, with lifestyle adjustments and public perception being especially problematic. Participants also noted recommendations for possible future improvements. Lastly, welfare concerns for the autism service dogs relating to violent behaviour exhibited by ASD children was identified, raising the question of the suitability of service dogs for the ASD population. , Thesis (MA) -- Humanities, Psychology, 2022
- Full Text:
- Date Issued: 2022-04-07
A Critical Analysis of the Role of School Governing Bodies in the Recruitment, Selection and Transfer of Educators in the Butterworth District
- Authors: Sifuba, Mpilo
- Date: 2011
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/11260/3495 , vital:43616
- Description: Recruitment, selection and transfer of educators were decentralized after South Africa became a democratic state in 1994 and shifted to School Governing Bodies. The legislation promoted a shared governance and participation of parents in issues that are related to recruitment, selection and transfer of educators, but parents are struggling and facing challenges in performing these tasks as School Governing Body members especially in the Butterworth district, as a result of that Butterworth district is experiencing problems with increasing number of disputes resulting from the appointment of educators after they have been recommended by the School Governing Bodies. This study focuses on the recruitment, selection and transfer of educators in the Butterworth district of the Eastern Cape Province of South Africa. The study sought to reveal the thinking behind government insistence on giving the School Governing Bodies a responsibility to recruit, select and transfer educators knowing fully well that they do not perform this responsibility. A qualitative approach was used to explore and challenge this phenomenon. This approach is concerned with understanding social phenomenon from the participant’s perspective. In depth semi – structured interviews with open ended questions were used to bring the researcher more closer to a more plausible perspective of this phenomenon. Moreover, they were used because they are the most appropriate method to capture the data. The findings revealed that School Governing Bodies are faced with challenges such as: high level of illiteracy, manipulation of School Governing Bodies by school management, unions and candidates, the issue of regionalism and kickbacks, capacity building and empowerment and role played by the Departmental Officials. By conducting this study, we hope that the findings might contribute in identifying the disjuncture between the policy and the practice in issues pertaining to educator recruitment, selection and transfers. , Thesis (MMED) -- Faculty of Educational Sciences, 2011
- Full Text:
- Date Issued: 2011
- Authors: Sifuba, Mpilo
- Date: 2011
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/11260/3495 , vital:43616
- Description: Recruitment, selection and transfer of educators were decentralized after South Africa became a democratic state in 1994 and shifted to School Governing Bodies. The legislation promoted a shared governance and participation of parents in issues that are related to recruitment, selection and transfer of educators, but parents are struggling and facing challenges in performing these tasks as School Governing Body members especially in the Butterworth district, as a result of that Butterworth district is experiencing problems with increasing number of disputes resulting from the appointment of educators after they have been recommended by the School Governing Bodies. This study focuses on the recruitment, selection and transfer of educators in the Butterworth district of the Eastern Cape Province of South Africa. The study sought to reveal the thinking behind government insistence on giving the School Governing Bodies a responsibility to recruit, select and transfer educators knowing fully well that they do not perform this responsibility. A qualitative approach was used to explore and challenge this phenomenon. This approach is concerned with understanding social phenomenon from the participant’s perspective. In depth semi – structured interviews with open ended questions were used to bring the researcher more closer to a more plausible perspective of this phenomenon. Moreover, they were used because they are the most appropriate method to capture the data. The findings revealed that School Governing Bodies are faced with challenges such as: high level of illiteracy, manipulation of School Governing Bodies by school management, unions and candidates, the issue of regionalism and kickbacks, capacity building and empowerment and role played by the Departmental Officials. By conducting this study, we hope that the findings might contribute in identifying the disjuncture between the policy and the practice in issues pertaining to educator recruitment, selection and transfers. , Thesis (MMED) -- Faculty of Educational Sciences, 2011
- Full Text:
- Date Issued: 2011
Voltammetric characterisation of the self-assembled monolayers (SAMs) of benzyl-and dodecyl-mercapto tetra substituted metallophthalocyanines complexes
- Agboola, Bolade, Westbroek, Philippe, Ozoemena, Kenneth I, Nyokong, Tebello
- Authors: Agboola, Bolade , Westbroek, Philippe , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281414 , vital:55723 , xlink:href="https://doi.org/10.1016/j.elecom.2006.08.047"
- Description: Voltammetric characterisations of cobalt, iron, manganese, nickel and zinc phthalocyanine complexes tetra substituted with benzyl- and dodecyl-mercapto ring substituents and immobilisation on gold electrodes via the self-assembling technique are presented. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, under potential deposition of copper and solution redox chemistry of [Fe(H2O)6 3+ ]/[Fe(H2O)6 2+ ]. The solution chemistry of [Fe(CN)6]−3/[Fe(CN)6]−4 redox process was used to study the orientation of the CoPcs-SAMs and this revealed a possible deviation from flat orientation of the complexes on the gold electrodes when the SAM formation times were greater than 24 h. For SAM formation time at 24 and 48 h, CoTDMPc-SAM showed more inhibition of the [Fe(CN)6]−3/[Fe(CN)6]−4 redox process than the CoTBMPc-SAM counterpart, indicating more blocking characteristics of the dodecylmercapto ring substituents compared to the benzylmercapto counterpart. To avoid SAM desorption, the potential application should be limited to −0.2 to +0.8 V vs. Ag∣AgCl (NaCl, sat’d) in acidic and neutral pH.
- Full Text:
- Date Issued: 2007
- Authors: Agboola, Bolade , Westbroek, Philippe , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2007
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281414 , vital:55723 , xlink:href="https://doi.org/10.1016/j.elecom.2006.08.047"
- Description: Voltammetric characterisations of cobalt, iron, manganese, nickel and zinc phthalocyanine complexes tetra substituted with benzyl- and dodecyl-mercapto ring substituents and immobilisation on gold electrodes via the self-assembling technique are presented. The self-assembled films are stable and showed blocking characteristics towards the following Faradaic processes; gold surface oxidation, under potential deposition of copper and solution redox chemistry of [Fe(H2O)6 3+ ]/[Fe(H2O)6 2+ ]. The solution chemistry of [Fe(CN)6]−3/[Fe(CN)6]−4 redox process was used to study the orientation of the CoPcs-SAMs and this revealed a possible deviation from flat orientation of the complexes on the gold electrodes when the SAM formation times were greater than 24 h. For SAM formation time at 24 and 48 h, CoTDMPc-SAM showed more inhibition of the [Fe(CN)6]−3/[Fe(CN)6]−4 redox process than the CoTBMPc-SAM counterpart, indicating more blocking characteristics of the dodecylmercapto ring substituents compared to the benzylmercapto counterpart. To avoid SAM desorption, the potential application should be limited to −0.2 to +0.8 V vs. Ag∣AgCl (NaCl, sat’d) in acidic and neutral pH.
- Full Text:
- Date Issued: 2007
Outcomes of Drug Resistant Tuberculosis in Two Rural District Hospitals, Eastern Cape Province, South Africa
- Authors: Lotz, John-D Knipe
- Date: 2021-02
- Subjects: Medicinal plants
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/11260/6834 , vital:51018
- Description: Tuberculosis (TB) is still rampant in South Africa, and drug resistant tuberculosis (DR-TB) forms a significant part of this burden on both the health care system and economy. A number of interventions have recently been introduced to help curb the growing epidemic of DR-TB, including increasing access to novel and repurposed drugs, decentralisation of care, and a new shorter (9-11 month) treatment regimen recently endorsed by the World Health Organization (WHO). Significantly, this new regimen has now also become injectable-free (also known as an all-oral regimen). However, at the time of implementation in 2017, the shorter regimen was yet to be proven effective in a programmatic setting in South Africa. This is a retrospective cohort study to describe the outcomes in patients on short and long DR-TB treatment regimens, over five years, at two treatment sites in a rural setting in the Eastern Cape province of South Africa. It is the hope that elucidation of factors involved in affecting outcomes in DR-TB may direct future interventions in these two facilities, and the wider DR-TB program in South Africa , Thesis (Masters) -- Faculty of Health Sciences, 2021
- Full Text:
- Date Issued: 2021-02
- Authors: Lotz, John-D Knipe
- Date: 2021-02
- Subjects: Medicinal plants
- Language: English
- Type: Masters theses , text
- Identifier: http://hdl.handle.net/11260/6834 , vital:51018
- Description: Tuberculosis (TB) is still rampant in South Africa, and drug resistant tuberculosis (DR-TB) forms a significant part of this burden on both the health care system and economy. A number of interventions have recently been introduced to help curb the growing epidemic of DR-TB, including increasing access to novel and repurposed drugs, decentralisation of care, and a new shorter (9-11 month) treatment regimen recently endorsed by the World Health Organization (WHO). Significantly, this new regimen has now also become injectable-free (also known as an all-oral regimen). However, at the time of implementation in 2017, the shorter regimen was yet to be proven effective in a programmatic setting in South Africa. This is a retrospective cohort study to describe the outcomes in patients on short and long DR-TB treatment regimens, over five years, at two treatment sites in a rural setting in the Eastern Cape province of South Africa. It is the hope that elucidation of factors involved in affecting outcomes in DR-TB may direct future interventions in these two facilities, and the wider DR-TB program in South Africa , Thesis (Masters) -- Faculty of Health Sciences, 2021
- Full Text:
- Date Issued: 2021-02
Symmetry effect of cobalt phthalocyanines on the aluminium corrosion inhibition in hydrochloric acid
- Nnaji, Nnaemeka, Sen, Pinar, Nyokong, Tebello
- Authors: Nnaji, Nnaemeka , Sen, Pinar , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231323 , vital:49877 , xlink:href="https://doi.org/10.1016/j.matlet.2021.130892"
- Description: The aluminium corrosion retardation potentials of phthalocyanine-based dyes, cobalt (II) 2,9,16-tris(4-(tert-butyl)phenoxy)-23-(pyridin-4-yloxy)phthalocyanine (D1) and cobalt (II) 2,9,16,24-tetrakis(4-(tert-butyl)phenoxy)phthalocyanine (D2) in 1 M hydrochloric acid were evaluated. Results from potentiodynamic polarization measurements show that inhibition efficiency increased with inhibitor concentration at 28 °C with values of 91.9 % and 87.0 % values respectively for D1 and D2 at 10 μM.
- Full Text:
- Date Issued: 2022
Symmetry effect of cobalt phthalocyanines on the aluminium corrosion inhibition in hydrochloric acid
- Authors: Nnaji, Nnaemeka , Sen, Pinar , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/231323 , vital:49877 , xlink:href="https://doi.org/10.1016/j.matlet.2021.130892"
- Description: The aluminium corrosion retardation potentials of phthalocyanine-based dyes, cobalt (II) 2,9,16-tris(4-(tert-butyl)phenoxy)-23-(pyridin-4-yloxy)phthalocyanine (D1) and cobalt (II) 2,9,16,24-tetrakis(4-(tert-butyl)phenoxy)phthalocyanine (D2) in 1 M hydrochloric acid were evaluated. Results from potentiodynamic polarization measurements show that inhibition efficiency increased with inhibitor concentration at 28 °C with values of 91.9 % and 87.0 % values respectively for D1 and D2 at 10 μM.
- Full Text:
- Date Issued: 2022
Investigating the role of the South African Schools Choral Eisteddfod in introducing learners to music career
- Authors: Sibene, Vuyelwa
- Date: 2016
- Subjects: Choral music -- South Africa , Choral singing -- Instruction and study -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26382 , vital:65298
- Description: This research investigates the role of South African Schools Choral Eisteddfod (SASCE) in introducing learners in high schools to music career. It attempts to identify learners in grade 12 who want to study music at university and students who were involved in SASCE and are now in university. These learners and students have limited music background and are/were involved in the South African Schools Choral Eisteddfod (SASCE) program. Within the study, I felt to also include a graduated music student to validate the study. The study proceeds with the investigation by exploring numerous areas such as SASCE as a music program, music education, music careers, national curriculum, music literacy etc. Also, I write about the background to the study in which I share my motivation and experiences about the SASCE programme and how it influenced me and other former SASCE participants’ decisions about musical careers. Data collection is executed through the involvement of the sampled learner and students through participating in semi-structured interview, document analysis and personal observations. Four interviews which were in qualitative method were conducted with 4 participants, one interview each participant was in a semi-structure form. Interviews were aimed in recognizing the current status of the learner/students in music literacy and are they coping in their respected places of study. The data is analyzed using a qualitative analyses technique. Further, the study outlines problems and one research question of the investigation, 'To which extent do University music students with limited music background succeed or fail to obtain their music degrees?’. , Thesis (BMUS) -- Faculty of Humanities, 2016
- Full Text:
- Date Issued: 2016
- Authors: Sibene, Vuyelwa
- Date: 2016
- Subjects: Choral music -- South Africa , Choral singing -- Instruction and study -- South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10353/26382 , vital:65298
- Description: This research investigates the role of South African Schools Choral Eisteddfod (SASCE) in introducing learners in high schools to music career. It attempts to identify learners in grade 12 who want to study music at university and students who were involved in SASCE and are now in university. These learners and students have limited music background and are/were involved in the South African Schools Choral Eisteddfod (SASCE) program. Within the study, I felt to also include a graduated music student to validate the study. The study proceeds with the investigation by exploring numerous areas such as SASCE as a music program, music education, music careers, national curriculum, music literacy etc. Also, I write about the background to the study in which I share my motivation and experiences about the SASCE programme and how it influenced me and other former SASCE participants’ decisions about musical careers. Data collection is executed through the involvement of the sampled learner and students through participating in semi-structured interview, document analysis and personal observations. Four interviews which were in qualitative method were conducted with 4 participants, one interview each participant was in a semi-structure form. Interviews were aimed in recognizing the current status of the learner/students in music literacy and are they coping in their respected places of study. The data is analyzed using a qualitative analyses technique. Further, the study outlines problems and one research question of the investigation, 'To which extent do University music students with limited music background succeed or fail to obtain their music degrees?’. , Thesis (BMUS) -- Faculty of Humanities, 2016
- Full Text:
- Date Issued: 2016
Exploring visual probability teaching strategies for enhancing mathematical thinking in grade 11 classrooms
- Nghidinwa, Lavinia Tangi-Jehova
- Authors: Nghidinwa, Lavinia Tangi-Jehova
- Date: 2021-10-29
- Subjects: Mathematics Study and teaching (Secondary) Namibia , Probabilities , Visualization , Learning models (Stochastic processes) , VIPROMaths project
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/192002 , vital:45187
- Description: This Namibian case study aimed to explore the use of visualisation tools associated with different teaching strategies in the teaching of probability concepts in Grade 11 by selected teachers, to promote mathematical thinking. This research project is an integral component of the VIPROMaths project whose goal is to research the effective use of visualisation strategies in the mathematics classroom in the Southern African region. As a mathematics teacher, I have observed that mathematics teaching practices in our classrooms have relatively little connection with actual mathematics and as a result, teaching misses opportunities to promote mathematical thinking. This qualitative case study is underpinned by an interpretive paradigm and it is informed by the dual coding theory. Data was collected through survey questionnaires, reflective journals, field notes, observation schedules and stimulus-recall interviews. Firstly, I piloted my study by conducting a survey with the Grade 10-12 mathematics teachers in the Khomas region. The aim of this survey was to understand and explore how teachers in the Khomas region taught probability prior to the intervention programme. The data was analysed quantitatively using descriptive statistics such as tables and bar graphs. The findings from the survey necessitated the need for an intervention programme with some teachers in the region, focused on the use of visual tools to promote mathematical thinking. Lastly, three schools were selected from which three Grade 11 mathematics teachers were chosen to take part in an intervention programme. The goal was to observe how these three teachers use visual probability teaching strategies to enhance mathematical thinking after participating in an intervention programme. Lesson observations showed that all observed teachers used visual models to generate images and used models to develop a probability idea as well as to create platforms for classroom discussions. Interviews revealed that teachers’ views towards probability have shifted from that of being the centre of knowledge to that of a facilitator. As a result, teachers used different models to build on learners’ prior knowledge, to assess whether they grasped the probability concept and extend their teaching to real-life situations. This study concluded that the teachers need to consider using mathematical models for creating a platform for discussion to ensure that their verbal explanations are in line with the visuals incorporated. Coupled with that, the teachers’ correct use of visual probability teaching strategies has the potential of enhancing learners’ mathematical thinking. Therefore, teachers need to teach the learners how to create visuals for enhancing maximise understanding of probability concepts in mathematics. Furthermore, it is hoped that the findings will be useful to mathematics teachers, scholars and educators to improve the teaching of probability. , Thesis (MEd) -- Faculty of Education, Education, 2021
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- Date Issued: 2021-10-29
- Authors: Nghidinwa, Lavinia Tangi-Jehova
- Date: 2021-10-29
- Subjects: Mathematics Study and teaching (Secondary) Namibia , Probabilities , Visualization , Learning models (Stochastic processes) , VIPROMaths project
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10962/192002 , vital:45187
- Description: This Namibian case study aimed to explore the use of visualisation tools associated with different teaching strategies in the teaching of probability concepts in Grade 11 by selected teachers, to promote mathematical thinking. This research project is an integral component of the VIPROMaths project whose goal is to research the effective use of visualisation strategies in the mathematics classroom in the Southern African region. As a mathematics teacher, I have observed that mathematics teaching practices in our classrooms have relatively little connection with actual mathematics and as a result, teaching misses opportunities to promote mathematical thinking. This qualitative case study is underpinned by an interpretive paradigm and it is informed by the dual coding theory. Data was collected through survey questionnaires, reflective journals, field notes, observation schedules and stimulus-recall interviews. Firstly, I piloted my study by conducting a survey with the Grade 10-12 mathematics teachers in the Khomas region. The aim of this survey was to understand and explore how teachers in the Khomas region taught probability prior to the intervention programme. The data was analysed quantitatively using descriptive statistics such as tables and bar graphs. The findings from the survey necessitated the need for an intervention programme with some teachers in the region, focused on the use of visual tools to promote mathematical thinking. Lastly, three schools were selected from which three Grade 11 mathematics teachers were chosen to take part in an intervention programme. The goal was to observe how these three teachers use visual probability teaching strategies to enhance mathematical thinking after participating in an intervention programme. Lesson observations showed that all observed teachers used visual models to generate images and used models to develop a probability idea as well as to create platforms for classroom discussions. Interviews revealed that teachers’ views towards probability have shifted from that of being the centre of knowledge to that of a facilitator. As a result, teachers used different models to build on learners’ prior knowledge, to assess whether they grasped the probability concept and extend their teaching to real-life situations. This study concluded that the teachers need to consider using mathematical models for creating a platform for discussion to ensure that their verbal explanations are in line with the visuals incorporated. Coupled with that, the teachers’ correct use of visual probability teaching strategies has the potential of enhancing learners’ mathematical thinking. Therefore, teachers need to teach the learners how to create visuals for enhancing maximise understanding of probability concepts in mathematics. Furthermore, it is hoped that the findings will be useful to mathematics teachers, scholars and educators to improve the teaching of probability. , Thesis (MEd) -- Faculty of Education, Education, 2021
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- Date Issued: 2021-10-29
Women's and health workers’ Voices in open, inclusive communities and effective spaces (VOICES)
- Kuhlmann, Serbert, Gullo, Sara, Galavotti, Christine, Grant, Carolyn, Cavatore, Maria, Posnock, Samuel
- Authors: Kuhlmann, Serbert , Gullo, Sara , Galavotti, Christine , Grant, Carolyn , Cavatore, Maria , Posnock, Samuel
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281190 , vital:55700 , xlink:href="https://doi.org/10.1111/dpr.12209"
- Description: Given the growing popularity of the social accountability approach to governance, we developed and tested measures of governance outcomes to evaluate maternal and reproductive health social accountability interventions. We articulate a theory of change for how CARE's Community Score Card©, a social accountability approach, 1) empowers women, 2) empowers health workers and 3) creates expanded, inclusive and effective spaces for the two to interact. Our measures worked well in surveys of women and health workers. For women, eight of 13 scales had alphas ≥.70. For health workers, five of 11 scales were ≥.70; four were .60–.69. To our knowledge, this is the first attempt to develop comprehensive measures of governance outcomes to evaluate a social accountability approach for maternal and reproductive health.
- Full Text:
- Date Issued: 2017
- Authors: Kuhlmann, Serbert , Gullo, Sara , Galavotti, Christine , Grant, Carolyn , Cavatore, Maria , Posnock, Samuel
- Date: 2017
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/281190 , vital:55700 , xlink:href="https://doi.org/10.1111/dpr.12209"
- Description: Given the growing popularity of the social accountability approach to governance, we developed and tested measures of governance outcomes to evaluate maternal and reproductive health social accountability interventions. We articulate a theory of change for how CARE's Community Score Card©, a social accountability approach, 1) empowers women, 2) empowers health workers and 3) creates expanded, inclusive and effective spaces for the two to interact. Our measures worked well in surveys of women and health workers. For women, eight of 13 scales had alphas ≥.70. For health workers, five of 11 scales were ≥.70; four were .60–.69. To our knowledge, this is the first attempt to develop comprehensive measures of governance outcomes to evaluate a social accountability approach for maternal and reproductive health.
- Full Text:
- Date Issued: 2017