More than just fields: Reframing deagrarianisation in landscapes and livelihoods
- Hebinck, Paul, Mtati, Nosiseko, Shackleton, Charlie M
- Authors: Hebinck, Paul , Mtati, Nosiseko , Shackleton, Charlie M
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180322 , vital:43353 , xlink:href="https://doi.org/10.1016/j.jrurstud.2018.01.004"
- Description: This paper discusses the emergent properties of deagrarianisation processes in two villages in the central Eastern Cape, South Africa. The claim of is that much of the deagrarianisation literature and debate does not acknowledge the importance of landscapes and the interaction between their constituent elements, notably people, forests, grasslands, fields, grazing lands, open spaces, built environments and homesteads, all of which contribute to shaping and, in turn, are shaped by livelihoods. Conceptualising a landscape as a spatial entity and associated assemblage of practices, discourses and history, this paper dissects the landscape in terms of land uses for residential and cultural purposes, growing, grazing and gathering. These land use categories together represent the rural domain to which the villagers are attached as a place and a home. Their use of the land is not necessarily oriented to fully exploring its productive potential. The article explores the transformation from a productive landscape to one which largely hinges on consumption. The blurring of boundaries between the formally designated land use categories signifies the transformations occurring in many of the rural areas in the former homelands of South Africa.
- Full Text:
- Date Issued: 2018
- Authors: Hebinck, Paul , Mtati, Nosiseko , Shackleton, Charlie M
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/180322 , vital:43353 , xlink:href="https://doi.org/10.1016/j.jrurstud.2018.01.004"
- Description: This paper discusses the emergent properties of deagrarianisation processes in two villages in the central Eastern Cape, South Africa. The claim of is that much of the deagrarianisation literature and debate does not acknowledge the importance of landscapes and the interaction between their constituent elements, notably people, forests, grasslands, fields, grazing lands, open spaces, built environments and homesteads, all of which contribute to shaping and, in turn, are shaped by livelihoods. Conceptualising a landscape as a spatial entity and associated assemblage of practices, discourses and history, this paper dissects the landscape in terms of land uses for residential and cultural purposes, growing, grazing and gathering. These land use categories together represent the rural domain to which the villagers are attached as a place and a home. Their use of the land is not necessarily oriented to fully exploring its productive potential. The article explores the transformation from a productive landscape to one which largely hinges on consumption. The blurring of boundaries between the formally designated land use categories signifies the transformations occurring in many of the rural areas in the former homelands of South Africa.
- Full Text:
- Date Issued: 2018
Shakespeare's Victorian Stage: performing history in the theatre of Charles Kean, Richard W. Schoch: book review
- Authors: Wright, Laurence
- Date: 2004
- Language: English
- Type: text , article
- Identifier: vital:7050 , http://hdl.handle.net/10962/d1007393 , http://hdl.handle.net/10520/EJC48030
- Description: preprint , This book is a primarily a study of Charles Kean’s productions of Shakespeare’s English chronicle plays at the Princess’s Theatre between 1852 and 1859, a period crucial to the development of ideas of English nationalism. Schoch focuses on these particular stagings as more than drama; as performances of nineteenth century theories of history and historical representation. His project operates under the aegis of the so-called ‘linguistic turn’ in cultural theory, and is suspicious of neo-marxian fundamentalism.
- Full Text:
- Date Issued: 2004
- Authors: Wright, Laurence
- Date: 2004
- Language: English
- Type: text , article
- Identifier: vital:7050 , http://hdl.handle.net/10962/d1007393 , http://hdl.handle.net/10520/EJC48030
- Description: preprint , This book is a primarily a study of Charles Kean’s productions of Shakespeare’s English chronicle plays at the Princess’s Theatre between 1852 and 1859, a period crucial to the development of ideas of English nationalism. Schoch focuses on these particular stagings as more than drama; as performances of nineteenth century theories of history and historical representation. His project operates under the aegis of the so-called ‘linguistic turn’ in cultural theory, and is suspicious of neo-marxian fundamentalism.
- Full Text:
- Date Issued: 2004
Improved Photophysical and Photochemical Properties of Thiopheneethoxy Substituted Metallophthalocyanines on Immobilization onto Gold‐speckled Silica Nanoparticles
- Dube, Edith, Oluwole, David O, Nyokong, Tebello
- Authors: Dube, Edith , Oluwole, David O , Nyokong, Tebello
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187699 , vital:44688 , xlink:href="https://doi.org/10.1111/php.12879"
- Description: This work reports on the synthesis of tetrakis-[(thiophineethoxy) phthalocyaninato] indium(II) chloride (3). The photophysical behavior of complex 3 was compared to that of the Zn derivative (tetrakis-[(thiophineethoxy) phthalocyaninato] zinc(II) (complex 2)). The compounds were interacted with gold-speckled silica (GSS) nanoparticles via Au–S self assembly to afford the conjugates (2–GSS and 3–GSS). The photophysicochemical behavior of the compounds and their conjugates were assessed. The conjugates afforded a decrease in fluorescence quantum yields and lifetimes with improved triplet and singlet oxygen quantum yields in comparison with complexes 2 and 3 alone. The complexes and their conjugates could serve as good candidates for photodynamic therapy.
- Full Text:
- Date Issued: 2018
- Authors: Dube, Edith , Oluwole, David O , Nyokong, Tebello
- Date: 2018
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/187699 , vital:44688 , xlink:href="https://doi.org/10.1111/php.12879"
- Description: This work reports on the synthesis of tetrakis-[(thiophineethoxy) phthalocyaninato] indium(II) chloride (3). The photophysical behavior of complex 3 was compared to that of the Zn derivative (tetrakis-[(thiophineethoxy) phthalocyaninato] zinc(II) (complex 2)). The compounds were interacted with gold-speckled silica (GSS) nanoparticles via Au–S self assembly to afford the conjugates (2–GSS and 3–GSS). The photophysicochemical behavior of the compounds and their conjugates were assessed. The conjugates afforded a decrease in fluorescence quantum yields and lifetimes with improved triplet and singlet oxygen quantum yields in comparison with complexes 2 and 3 alone. The complexes and their conjugates could serve as good candidates for photodynamic therapy.
- Full Text:
- Date Issued: 2018
Semi-submersible rigs: a vector transporting entire marine communities around the world
- Wanless, Ross M, Scott, Sue, Sauer, Warwick H H, Andrew, Timothy G, Glass, James P, Godfrey, Brian, Griffiths, Charles, Yeld, Eleanor
- Authors: Wanless, Ross M , Scott, Sue , Sauer, Warwick H H , Andrew, Timothy G , Glass, James P , Godfrey, Brian , Griffiths, Charles , Yeld, Eleanor
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126920 , vital:35935 , https://doi.10.1007/s10530-009-9666-2
- Description: A virtually intact subtropical reef community (14 phyla, 40 families and 62 non-native taxa) was associated with a rig under tow from Brazil that became stranded on the remote island of Tristan da Cunha. This exposes rigs as a significant vector spreading alien marine organisms, and includes the first records of free-swimming marine finfish populations becoming established after unintentional movement. With relatively trivial effort, a pre-tow clean would have obviated the need to salvage and dispose of the rig (undertaken largely to address concerns about invasive species), at a cost of *US$20 million. Our findings show that towing biofouled structures across biogeographic boundaries present unexcelled opportunities for invasion to a wide diversity of marine species. Better control and management of this vector is required urgently. Simultaneous, unintentional introductions of viable populations of multiple marine organisms are rare events, and we develop a basic framework for rapid assessment of invasion risks.
- Full Text:
- Date Issued: 2010
- Authors: Wanless, Ross M , Scott, Sue , Sauer, Warwick H H , Andrew, Timothy G , Glass, James P , Godfrey, Brian , Griffiths, Charles , Yeld, Eleanor
- Date: 2010
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126920 , vital:35935 , https://doi.10.1007/s10530-009-9666-2
- Description: A virtually intact subtropical reef community (14 phyla, 40 families and 62 non-native taxa) was associated with a rig under tow from Brazil that became stranded on the remote island of Tristan da Cunha. This exposes rigs as a significant vector spreading alien marine organisms, and includes the first records of free-swimming marine finfish populations becoming established after unintentional movement. With relatively trivial effort, a pre-tow clean would have obviated the need to salvage and dispose of the rig (undertaken largely to address concerns about invasive species), at a cost of *US$20 million. Our findings show that towing biofouled structures across biogeographic boundaries present unexcelled opportunities for invasion to a wide diversity of marine species. Better control and management of this vector is required urgently. Simultaneous, unintentional introductions of viable populations of multiple marine organisms are rare events, and we develop a basic framework for rapid assessment of invasion risks.
- Full Text:
- Date Issued: 2010
Sequence and domain conservation of the coelacanth Hsp40 and Hsp90 chaperones suggests conservation of function
- Tastan Bishop, Özlem, Edkins, Adrienne L, Blatch, Gregory L
- Authors: Tastan Bishop, Özlem , Edkins, Adrienne L , Blatch, Gregory L
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126932 , vital:35936 , https://doi.10.1002/jez.b.22541
- Description: Molecular chaperones and their associated co‐chaperones play an important role in preserving and regulating the active conformational state of cellular proteins. The chaperone complement of the Indonesian Coelacanth, Latimeria menadoensis, was elucidated using transcriptomic sequences. Heat shock protein 90 (Hsp90) and heat shock protein 40 (Hsp40) chaperones, and associated cochaperones were focused on, and homologous human sequences were used to search the sequence databases. Coelacanth homologs of the cytosolic, mitochondrial and endoplasmic reticulum (ER) homologs of human Hsp90 were identified, as well as all of the major co‐chaperones of the cytosolic isoform. Most of the human Hsp40s were found to have coelacanth homologs, and the data suggested that all of the chaperone machinery for protein folding at the ribosome, protein translocation to cellular compartments such as the ER and protein degradation were conserved. Some interesting similarities and differences were identified when interrogating human, mouse, and zebrafish homologs. For example, DnaJB13 is predicted to be a non‐functional Hsp40 in humans, mouse, and zebrafish due to a corrupted histidine‐proline‐aspartic acid (HPD) motif, while the coelacanth homolog has an intact HPD. These and other comparisons enabled important functional and evolutionary questions to be posed for future experimental studies.
- Full Text:
- Date Issued: 2014
- Authors: Tastan Bishop, Özlem , Edkins, Adrienne L , Blatch, Gregory L
- Date: 2014
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/126932 , vital:35936 , https://doi.10.1002/jez.b.22541
- Description: Molecular chaperones and their associated co‐chaperones play an important role in preserving and regulating the active conformational state of cellular proteins. The chaperone complement of the Indonesian Coelacanth, Latimeria menadoensis, was elucidated using transcriptomic sequences. Heat shock protein 90 (Hsp90) and heat shock protein 40 (Hsp40) chaperones, and associated cochaperones were focused on, and homologous human sequences were used to search the sequence databases. Coelacanth homologs of the cytosolic, mitochondrial and endoplasmic reticulum (ER) homologs of human Hsp90 were identified, as well as all of the major co‐chaperones of the cytosolic isoform. Most of the human Hsp40s were found to have coelacanth homologs, and the data suggested that all of the chaperone machinery for protein folding at the ribosome, protein translocation to cellular compartments such as the ER and protein degradation were conserved. Some interesting similarities and differences were identified when interrogating human, mouse, and zebrafish homologs. For example, DnaJB13 is predicted to be a non‐functional Hsp40 in humans, mouse, and zebrafish due to a corrupted histidine‐proline‐aspartic acid (HPD) motif, while the coelacanth homolog has an intact HPD. These and other comparisons enabled important functional and evolutionary questions to be posed for future experimental studies.
- Full Text:
- Date Issued: 2014
Urban fuelwood demand and markets in a small town in South Africa: Livelihood vulnerability and alien plant control
- Shackleton, Charlie M, McConnachie, Matthew M, Chauke, Maphambe I, Mentz, J, Sutherland, F, Gambiza, James, Jones, R
- Authors: Shackleton, Charlie M , McConnachie, Matthew M , Chauke, Maphambe I , Mentz, J , Sutherland, F , Gambiza, James , Jones, R
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181224 , vital:43710 , xlink:href="https://doi.org/10.1080/13504500609469697"
- Description: Fuelwood is the primary energy for most households throughout the developing world. With increasing urbanization and declining local availability of fuelwood, a growing proportion of households obtain their fuelwood by purchasing it. These fuelwood markets are the key nexus in supply and demand scenarios and can be potentially significant points for intervention to address energy security amongst the urban poor. This paper reports on the fuelwood demand and marketing in a small town in South Africa. Despite the availability of more modern fuels and state subsidization of electricity, fuelwood was still used by half the households. Annual demand was 1.2 t per household. Over half of the households bought their fuelwood requirements because local stocks were limited. Those households that did collect their own fuelwood were significantly poorer than households that purchased fuelwood, as well as households that did not use fuelwood at all. Fuelwood markets operated through 45-60 vendors who transported fuelwood from further afield. Income from the fuelwood trade was low, but was strongly linked to hours worked. Thus, vendors working a full week did earn a meaningful income, especially in the context of high unemployment in the area. Fuelwood vendors also provided casual employment opportunities for unskilled labour. Most vendors harvested fuelwood from commonage lands, with most of the wood being from alien species. Local stocks of wood are declining in the face of constant transformation of commonage to residential areas, and a national water and biodiversity conservation programme to eradicate alien plants. This decline poses a threat to the financial viability of fuelwood markets. Yet, an opportunity exists to incorporate the vendors into the alien plant clearing programme, since they already perform such a function.
- Full Text:
- Date Issued: 2006
- Authors: Shackleton, Charlie M , McConnachie, Matthew M , Chauke, Maphambe I , Mentz, J , Sutherland, F , Gambiza, James , Jones, R
- Date: 2006
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181224 , vital:43710 , xlink:href="https://doi.org/10.1080/13504500609469697"
- Description: Fuelwood is the primary energy for most households throughout the developing world. With increasing urbanization and declining local availability of fuelwood, a growing proportion of households obtain their fuelwood by purchasing it. These fuelwood markets are the key nexus in supply and demand scenarios and can be potentially significant points for intervention to address energy security amongst the urban poor. This paper reports on the fuelwood demand and marketing in a small town in South Africa. Despite the availability of more modern fuels and state subsidization of electricity, fuelwood was still used by half the households. Annual demand was 1.2 t per household. Over half of the households bought their fuelwood requirements because local stocks were limited. Those households that did collect their own fuelwood were significantly poorer than households that purchased fuelwood, as well as households that did not use fuelwood at all. Fuelwood markets operated through 45-60 vendors who transported fuelwood from further afield. Income from the fuelwood trade was low, but was strongly linked to hours worked. Thus, vendors working a full week did earn a meaningful income, especially in the context of high unemployment in the area. Fuelwood vendors also provided casual employment opportunities for unskilled labour. Most vendors harvested fuelwood from commonage lands, with most of the wood being from alien species. Local stocks of wood are declining in the face of constant transformation of commonage to residential areas, and a national water and biodiversity conservation programme to eradicate alien plants. This decline poses a threat to the financial viability of fuelwood markets. Yet, an opportunity exists to incorporate the vendors into the alien plant clearing programme, since they already perform such a function.
- Full Text:
- Date Issued: 2006
Electrocatalytic and photosensitizing behavior of metallophthalocyanine complexes
- Authors: Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265908 , vital:53899 , xlink:href="https://doi.org/10.1142/S1088424608000388"
- Description: Electrocatalytic or photosensitizing (photocatalytic) properties of metallophthalocyanine (MPc) complexes are dependent on the central metal. Electrocatalytic behavior is observed for electroactive central metals such as Co, Mn and Fe, whereas photosensitizing behavior is observed for diamagnetic metals such as Al, Zn and Si. In the presence of nanoparticles such as quantum dots, the photosensitizing behavior of MPc complexes is improved. Carbon nanotubes enhance the electrocatalytic behavior of MPc complexes.
- Full Text:
- Date Issued: 2008
- Authors: Nyokong, Tebello
- Date: 2008
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/265908 , vital:53899 , xlink:href="https://doi.org/10.1142/S1088424608000388"
- Description: Electrocatalytic or photosensitizing (photocatalytic) properties of metallophthalocyanine (MPc) complexes are dependent on the central metal. Electrocatalytic behavior is observed for electroactive central metals such as Co, Mn and Fe, whereas photosensitizing behavior is observed for diamagnetic metals such as Al, Zn and Si. In the presence of nanoparticles such as quantum dots, the photosensitizing behavior of MPc complexes is improved. Carbon nanotubes enhance the electrocatalytic behavior of MPc complexes.
- Full Text:
- Date Issued: 2008
Discorhabdin N, a South African Natural Compound, for Hsp72 and Hsc70 Allosteric Modulation: combined study of molecular modeling and dynamic residue network analysis
- Amusengeri, Arnold, Tastan Bishop, Özlem
- Authors: Amusengeri, Arnold , Tastan Bishop, Özlem
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/162949 , vital:40999 , https://doi.org/10.3390/molecules24010188
- Description: The human heat shock proteins (Hsps), predominantly Hsp72 and Hsp90, have been strongly implicated in various critical stages of oncogenesis and progression of human cancers. While drug development has extensively focused on Hsp90 as a potential anticancer target, much less effort has been put against Hsp72. This work investigated the therapeutic potential of Hsp72 and its constitutive isoform, Hsc70, via in silico-based screening against the South African Natural Compounds Database (SANCDB). A comparative modeling approach was used to obtain nearly full-length 3D structures of the closed conformation of Hsp72 and Hsc70 proteins. Molecular docking of SANCDB compounds identified one potential allosteric modulator, Discorhabdin N, binding to the allosteric β substrate binding domain (SBDβ) back pocket, with good binding affinities in both cases.
- Full Text:
- Date Issued: 2019
- Authors: Amusengeri, Arnold , Tastan Bishop, Özlem
- Date: 2019
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/162949 , vital:40999 , https://doi.org/10.3390/molecules24010188
- Description: The human heat shock proteins (Hsps), predominantly Hsp72 and Hsp90, have been strongly implicated in various critical stages of oncogenesis and progression of human cancers. While drug development has extensively focused on Hsp90 as a potential anticancer target, much less effort has been put against Hsp72. This work investigated the therapeutic potential of Hsp72 and its constitutive isoform, Hsc70, via in silico-based screening against the South African Natural Compounds Database (SANCDB). A comparative modeling approach was used to obtain nearly full-length 3D structures of the closed conformation of Hsp72 and Hsc70 proteins. Molecular docking of SANCDB compounds identified one potential allosteric modulator, Discorhabdin N, binding to the allosteric β substrate binding domain (SBDβ) back pocket, with good binding affinities in both cases.
- Full Text:
- Date Issued: 2019
Spectral properties and photophysical behaviour of water soluble cationic Mg (II) and Al (III) phthalocyanines
- Idowu, Mopelola A, Arslanoğlu, Yasin, Nyokong, Tebello
- Authors: Idowu, Mopelola A , Arslanoğlu, Yasin , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241549 , vital:50949 , xlink:href="https://doi.org/10.2478/s11532-013-0388-z"
- Description: Peripherally and non-peripherally tetrasubstituted-[(N-methyl-2-pyridylthio)]phthalocyaninato magnesium (II) (5 and 6) and chloro aluminium (III) (7 and 8) tetraiodide have been synthesized and characterized. The photophysical properties of the complexes in dimethyl sulfoxide (DMSO) and aqueous medium in the presence and absence of cremophore EL have been studied. These complexes show high solubility in aqueous medium though they were aggregated. The triplet state quantum yields (FT) and the triplet lifetimes (tT) were found to be higher in DMSO with ΦT ranging from 0.32 to 0.51, while tT ranged from 282 to 622 ms in DMSO, compared to aqueous medium (pH 7.4 buffer) where ΦT ranged from 0.15 to 0.19 and tT from 26 to 35 ms. Addition of cremophore EL in aqueous solution resulted in partial disaggregation and increased photoactivity. The fluorescence lifetimes of the complexes showed strong dependence on their immediate environment. The ionic magnesium(II) and aluminium(III) phthalocyanines strongly bind to bovine serum albumin (BSA).
- Full Text:
- Date Issued: 2014
- Authors: Idowu, Mopelola A , Arslanoğlu, Yasin , Nyokong, Tebello
- Date: 2014
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/241549 , vital:50949 , xlink:href="https://doi.org/10.2478/s11532-013-0388-z"
- Description: Peripherally and non-peripherally tetrasubstituted-[(N-methyl-2-pyridylthio)]phthalocyaninato magnesium (II) (5 and 6) and chloro aluminium (III) (7 and 8) tetraiodide have been synthesized and characterized. The photophysical properties of the complexes in dimethyl sulfoxide (DMSO) and aqueous medium in the presence and absence of cremophore EL have been studied. These complexes show high solubility in aqueous medium though they were aggregated. The triplet state quantum yields (FT) and the triplet lifetimes (tT) were found to be higher in DMSO with ΦT ranging from 0.32 to 0.51, while tT ranged from 282 to 622 ms in DMSO, compared to aqueous medium (pH 7.4 buffer) where ΦT ranged from 0.15 to 0.19 and tT from 26 to 35 ms. Addition of cremophore EL in aqueous solution resulted in partial disaggregation and increased photoactivity. The fluorescence lifetimes of the complexes showed strong dependence on their immediate environment. The ionic magnesium(II) and aluminium(III) phthalocyanines strongly bind to bovine serum albumin (BSA).
- Full Text:
- Date Issued: 2014
Violence, postcolonial fiction, and the limits of sympathy:
- Authors: Marais, Mike
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143993 , vital:38301 , DOI: 10.1353/sdn.2011.0034
- Description: In this article, I consider the implications for fiction of Slavo Zizek’s argument that the violence of individual subjects is informed by ‘symbolic violence’ (1-2), that is, the distortions concomitant on languages’s constitutive, rather than merely referential, relation to the world.
- Full Text:
- Date Issued: 2011
- Authors: Marais, Mike
- Date: 2011
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/143993 , vital:38301 , DOI: 10.1353/sdn.2011.0034
- Description: In this article, I consider the implications for fiction of Slavo Zizek’s argument that the violence of individual subjects is informed by ‘symbolic violence’ (1-2), that is, the distortions concomitant on languages’s constitutive, rather than merely referential, relation to the world.
- Full Text:
- Date Issued: 2011
Protection of development-induced internally displaced persons under the African Charter: the case of the Endorois community of Northern Kenya
- Authors: Juma, Laurence
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127100 , vital:35955 , https://heinonline.org./HOL/Page?handle=hein.journals/ciminsfri46amp;div=15amp;g_sent=1amp;casa_token=amp;collection=journals
- Description: The discourse on development-induced displacement has highlighted the enormity of problems faced by communities who are forcefully removed to create room for development projects, while at the same time, exposed the insularity of national and international legal frameworks for their protection. Using the case of Centre for Minority Rights Development (CEMIRIDE) on behalf of the Endorois Community v Kenya (No 276/200), decided by the African Commission on Human and People's Rights in November 2009, this article analyses the support that regional and continental rights enforcement mechanisms could provide to the protection of IDPs, particularly those displaced by development projects.
- Full Text:
- Date Issued: 2013
- Authors: Juma, Laurence
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/127100 , vital:35955 , https://heinonline.org./HOL/Page?handle=hein.journals/ciminsfri46amp;div=15amp;g_sent=1amp;casa_token=amp;collection=journals
- Description: The discourse on development-induced displacement has highlighted the enormity of problems faced by communities who are forcefully removed to create room for development projects, while at the same time, exposed the insularity of national and international legal frameworks for their protection. Using the case of Centre for Minority Rights Development (CEMIRIDE) on behalf of the Endorois Community v Kenya (No 276/200), decided by the African Commission on Human and People's Rights in November 2009, this article analyses the support that regional and continental rights enforcement mechanisms could provide to the protection of IDPs, particularly those displaced by development projects.
- Full Text:
- Date Issued: 2013
New Unity Movement Presidential Address
- Date: 2004-03
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32492 , vital:32118 , Bulk File 7
- Description: Presidential Addresses were delivered at each Annual conference of the New Unity Movement. This collection, though incomplete, has 18 items ranging from 1989 to 2013.
- Full Text: false
- Date Issued: 2004-03
- Date: 2004-03
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32492 , vital:32118 , Bulk File 7
- Description: Presidential Addresses were delivered at each Annual conference of the New Unity Movement. This collection, though incomplete, has 18 items ranging from 1989 to 2013.
- Full Text: false
- Date Issued: 2004-03
Indium phthalocyanines
- Pinar, Sen, Mack, John, Nyokong, Tebello
- Authors: Pinar, Sen , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229998 , vital:49731 , xlink:href="https://doi.org/10.1016/j.molstruc.2021.131850"
- Description: In this study, the photodynamic antimicrobial activities of a series of new tetra-substituted indium phthalocyanine (InPc) complexes are assessed. An aldehyde substituted complex (2) was initially prepared, which was converted through a condensatioreaction to an imine-pyrrolidine substituted complex (3), which in turn was quaternized to form a tetracationic species (4). Favorable photophysicochemical properties were obtained by incorporating a heavy In(III) ion into the central cavity. Aggregation studies revealed that 2–4 remain non-aggregated in DMSO at concentration below 25 µM. The photodeactivation of S.aureus and E.coli was studied. Log reduction values > 9.0 were obtained for cationic InPc 4 after 30 min of incubation and exposure to light for 75 min.
- Full Text:
- Date Issued: 2022
- Authors: Pinar, Sen , Mack, John , Nyokong, Tebello
- Date: 2022
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/229998 , vital:49731 , xlink:href="https://doi.org/10.1016/j.molstruc.2021.131850"
- Description: In this study, the photodynamic antimicrobial activities of a series of new tetra-substituted indium phthalocyanine (InPc) complexes are assessed. An aldehyde substituted complex (2) was initially prepared, which was converted through a condensatioreaction to an imine-pyrrolidine substituted complex (3), which in turn was quaternized to form a tetracationic species (4). Favorable photophysicochemical properties were obtained by incorporating a heavy In(III) ion into the central cavity. Aggregation studies revealed that 2–4 remain non-aggregated in DMSO at concentration below 25 µM. The photodeactivation of S.aureus and E.coli was studied. Log reduction values > 9.0 were obtained for cationic InPc 4 after 30 min of incubation and exposure to light for 75 min.
- Full Text:
- Date Issued: 2022
Synthesis and photophysicochemical properties of novel axially di-substituted silicon (IV) phthalocyanines and their photodynamic antimicrobial chemotherapy (PACT) activity against Staphylococcus aureus
- Sen, Pinar, Sindelo, Azole, Mafukidze, Donovan M, Nyokong, Tebello
- Authors: Sen, Pinar , Sindelo, Azole , Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186757 , vital:44531 , xlink:href="https://doi.org/10.1016/j.synthmet.2019.116203"
- Description: In this study, novel silicon (IV) phthalocyanine axially di-substituted with benzimidazole moieties (3) and its quaternized derivative (4) have been synthesized and fully characterized. The photophysical and photochemical properties of both phthalocyanines such as absorption, fluorescence and, singlet oxygen quantum yields, triplet state quantum yields and exited state lifetimes were investigated in solutions. These new silicon phthalocyanines exhibited low fluorescence but produced high singlet oxygen yields in both DMSO (compound 3 and 4) and aqueous media (compound 4). The quaternization of Si(IV)Pc (3) improved the triplet state quantum yield (ΦT) 0.61 to 0.83, consequently singlet oxygen generation (ΦΔ) increased to 0.69 from 0.42. Photodynamic antimicrobial chemotherapy activities (PACT) of Si(IV)Pc photosensitizers were determined towards Staphylococcus aureus. The higher efficiency was obtained with cationic derivative (4) giving reduction percentage value of 99.75%.
- Full Text:
- Date Issued: 2019
- Authors: Sen, Pinar , Sindelo, Azole , Mafukidze, Donovan M , Nyokong, Tebello
- Date: 2019
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/186757 , vital:44531 , xlink:href="https://doi.org/10.1016/j.synthmet.2019.116203"
- Description: In this study, novel silicon (IV) phthalocyanine axially di-substituted with benzimidazole moieties (3) and its quaternized derivative (4) have been synthesized and fully characterized. The photophysical and photochemical properties of both phthalocyanines such as absorption, fluorescence and, singlet oxygen quantum yields, triplet state quantum yields and exited state lifetimes were investigated in solutions. These new silicon phthalocyanines exhibited low fluorescence but produced high singlet oxygen yields in both DMSO (compound 3 and 4) and aqueous media (compound 4). The quaternization of Si(IV)Pc (3) improved the triplet state quantum yield (ΦT) 0.61 to 0.83, consequently singlet oxygen generation (ΦΔ) increased to 0.69 from 0.42. Photodynamic antimicrobial chemotherapy activities (PACT) of Si(IV)Pc photosensitizers were determined towards Staphylococcus aureus. The higher efficiency was obtained with cationic derivative (4) giving reduction percentage value of 99.75%.
- Full Text:
- Date Issued: 2019
Effects of the number of ring substituents of cobalt carboxyphthalocyanines on the electrocatalytic detection of nitrite, cysteine and melatonin
- Matemadombo, Fungisai, Sehlotho, Nthapo, Nyokong, Tebello
- Authors: Matemadombo, Fungisai , Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263408 , vital:53625 , xlink:href="https://doi.org/10.1142/S108842460900125X"
- Description: Cobalt phthalocyanine (CoPc), cobalt tetracarboxy phthalocyanine (CoTCPc) and cobalt octacarboxy phthalocyanine (CoOCPc), adsorbed onto glassy carbon electrodes, have been used for the electrocatalytic detection of nitrite, L-cysteine and melatonin. The modified electrodes electrocatalytically detected nitrite around 800 mV vs.Ag|AgCl, a value less positive compared to that of an unmodified glassy carbon electrode (at 950 mV vs.Ag|AgCl) and also gave detection limits in the 10-7 M range for nitrite detection. L-cysteine was detected by the modified electrodes at potentials between 0.50 to 0.65 V vs.Ag|AgCl, with L-cysteine detection limits also in the 10-7 M range. The detection limits for melatonin ranged from 10-7 to 10-6 M. CoPc-modified electrodes displayed good separation of interferents (tryptophan and ascorbic acid) in the presence of melatonin. Analyses of commercial melatonin tablets using modified electrodes gave excellent agreement with manufacturer's value for all modified electrodes of this work.
- Full Text:
- Date Issued: 2009
- Authors: Matemadombo, Fungisai , Sehlotho, Nthapo , Nyokong, Tebello
- Date: 2009
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/263408 , vital:53625 , xlink:href="https://doi.org/10.1142/S108842460900125X"
- Description: Cobalt phthalocyanine (CoPc), cobalt tetracarboxy phthalocyanine (CoTCPc) and cobalt octacarboxy phthalocyanine (CoOCPc), adsorbed onto glassy carbon electrodes, have been used for the electrocatalytic detection of nitrite, L-cysteine and melatonin. The modified electrodes electrocatalytically detected nitrite around 800 mV vs.Ag|AgCl, a value less positive compared to that of an unmodified glassy carbon electrode (at 950 mV vs.Ag|AgCl) and also gave detection limits in the 10-7 M range for nitrite detection. L-cysteine was detected by the modified electrodes at potentials between 0.50 to 0.65 V vs.Ag|AgCl, with L-cysteine detection limits also in the 10-7 M range. The detection limits for melatonin ranged from 10-7 to 10-6 M. CoPc-modified electrodes displayed good separation of interferents (tryptophan and ascorbic acid) in the presence of melatonin. Analyses of commercial melatonin tablets using modified electrodes gave excellent agreement with manufacturer's value for all modified electrodes of this work.
- Full Text:
- Date Issued: 2009
The criminal justice response to human trafficking: Exploring the investigative and prosecutorial hurdles
- Mugari, Ishmael, Obioha, Emeka E
- Authors: Mugari, Ishmael , Obioha, Emeka E
- Date: 2021-06-30
- Subjects: Human trafficking Human trafficking Computer File , Prosecution Prosecution Computer File
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7416 , vital:53964 , https://doi.org/10.55058/adrrijass.v18i1(6),%20April,%202021-%20June.659
- Description: Much has been written on the scourge of human trafficking, with majority of previous research focussing on trends, forms, as well as the regulatory framework for countering the scourge. Despite the presence of a vast body of knowledge on human trafficking, less attention has been given to the operational dynamics that are involved in the investigation and prosecution of human trafficking cases. This paper, which is based on a literature and documentary survey, evaluates the challenges that are encountered by the criminal justice players in responding to human trafficking. The paper specifically focuses on the challenges that are faced by law enforcement agencies in the investigation of human trafficking, as well as the challenges that are faced in the prosecution of human trafficking offenders. Whilst the paper takes a global approach to the problem, much attention is given to South Africa and Zimbabwe- two neighbouring Southern African nations. Keywords: human trafficking, investigations, prosecution, victim protection
- Full Text:
- Date Issued: 2021-06-30
- Authors: Mugari, Ishmael , Obioha, Emeka E
- Date: 2021-06-30
- Subjects: Human trafficking Human trafficking Computer File , Prosecution Prosecution Computer File
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/11260/7416 , vital:53964 , https://doi.org/10.55058/adrrijass.v18i1(6),%20April,%202021-%20June.659
- Description: Much has been written on the scourge of human trafficking, with majority of previous research focussing on trends, forms, as well as the regulatory framework for countering the scourge. Despite the presence of a vast body of knowledge on human trafficking, less attention has been given to the operational dynamics that are involved in the investigation and prosecution of human trafficking cases. This paper, which is based on a literature and documentary survey, evaluates the challenges that are encountered by the criminal justice players in responding to human trafficking. The paper specifically focuses on the challenges that are faced by law enforcement agencies in the investigation of human trafficking, as well as the challenges that are faced in the prosecution of human trafficking offenders. Whilst the paper takes a global approach to the problem, much attention is given to South Africa and Zimbabwe- two neighbouring Southern African nations. Keywords: human trafficking, investigations, prosecution, victim protection
- Full Text:
- Date Issued: 2021-06-30
Electrochemical, microscopic and spectroscopic characterization of benzene diamine functionalized single walled carbon nanotube-cobalt (II) tetracarboxy-phthalocyanine conjugates
- Mugadza, Tawanda, Nyokong, Tebello
- Authors: Mugadza, Tawanda , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247859 , vital:51624 , xlink:href="https://doi.org/10.1016/j.jcis.2010.10.057"
- Description: In this paper we report on the synthesis and characterization of 1,4-benzene diamine (BDA) functionalized single walled carbon nanotubes linked to cobalt (II) tetracarboxy-phthalocyanine. The characterization of the conjugate was through UV–vis, FTIR and X-ray diffraction (XRD) spectroscopies and by transmission electron microscope (TEM) and electrochemical methods. The conjugate is used for the electrochemical characterization of diuron. The catalytic rate constant for diuron was 4.4 × 103 M−1 s−1 and the apparent electron transfer rate constant was 18.5 × 10−6 cm s−1. The linear dynamic range was 1.0 × 10−5–2.0 × 10−4 M, with a sensitivity of ∼0.42 A mol−1L cm−2 and a limit of detection of 0.18 μM using the 3δ notation.
- Full Text:
- Date Issued: 2011
- Authors: Mugadza, Tawanda , Nyokong, Tebello
- Date: 2011
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/247859 , vital:51624 , xlink:href="https://doi.org/10.1016/j.jcis.2010.10.057"
- Description: In this paper we report on the synthesis and characterization of 1,4-benzene diamine (BDA) functionalized single walled carbon nanotubes linked to cobalt (II) tetracarboxy-phthalocyanine. The characterization of the conjugate was through UV–vis, FTIR and X-ray diffraction (XRD) spectroscopies and by transmission electron microscope (TEM) and electrochemical methods. The conjugate is used for the electrochemical characterization of diuron. The catalytic rate constant for diuron was 4.4 × 103 M−1 s−1 and the apparent electron transfer rate constant was 18.5 × 10−6 cm s−1. The linear dynamic range was 1.0 × 10−5–2.0 × 10−4 M, with a sensitivity of ∼0.42 A mol−1L cm−2 and a limit of detection of 0.18 μM using the 3δ notation.
- Full Text:
- Date Issued: 2011
Reimag [in] ing the village as a portrait of a nation-state in Uganda:
- Authors: Kakande, Angelo
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145642 , vital:38454 , https://doi.org/10.1162/AFAR_a_00343
- Description: In this article I reexamine the ways in which certain contemporary artists based in Uganda problematize the narrative that the ruling National Resistance Movement (the NRM) party is the party of the rural poor (Cheeseman, Lynch, and Willis 2016) in their work while using it as a metaphor to inform their visual expression. I focus on the contest between tradition (imagined as a village) and modernity (imagined as a modern state), as well as the dilemma such a contest causes for a contemporary artist. Cornelius Adepegba (1995) argues that this dilemma influenced the African novel. Agreeing with Adepegba, Freeborn Odiboh (2009) observes that the same dilemma has shaped African visual artists, such as Abayomi Barber, and formal art education institutions like the Barber School in Nigeria; Odiboh then assesses the historical context in which this dilemma evolved as African nationalists struggled to forge postcolonial states based on a national consciousness amid competing ethnic, religious, and ideological interests.
- Full Text:
- Date Issued: 2017
- Authors: Kakande, Angelo
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/145642 , vital:38454 , https://doi.org/10.1162/AFAR_a_00343
- Description: In this article I reexamine the ways in which certain contemporary artists based in Uganda problematize the narrative that the ruling National Resistance Movement (the NRM) party is the party of the rural poor (Cheeseman, Lynch, and Willis 2016) in their work while using it as a metaphor to inform their visual expression. I focus on the contest between tradition (imagined as a village) and modernity (imagined as a modern state), as well as the dilemma such a contest causes for a contemporary artist. Cornelius Adepegba (1995) argues that this dilemma influenced the African novel. Agreeing with Adepegba, Freeborn Odiboh (2009) observes that the same dilemma has shaped African visual artists, such as Abayomi Barber, and formal art education institutions like the Barber School in Nigeria; Odiboh then assesses the historical context in which this dilemma evolved as African nationalists struggled to forge postcolonial states based on a national consciousness amid competing ethnic, religious, and ideological interests.
- Full Text:
- Date Issued: 2017
New directions in Maritime and Fisheries Anthropology:
- Authors: Aswani, Shankar
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/179028 , vital:40101 , https://0-doi.org.wam.seals.ac.za/10.1111/aman.13380
- Description: Maritime and fisheries anthropology is a mixture of different themes couched under various theoretical frameworks that straddle the humanities and the sciences. In this subject survey, I explore different thematic and theoretical strands of maritime and fisheries anthropology and illustrate broader changes in this subdiscipline since around the mid‐1990s. I also review developing and future thematic and theoretical research frontiers, and discuss their potential contribution to a public and actionable anthropology/scholarship that can better inform fisheries management and conservation. This is important because in the twenty‐first century, coastal peoples are facing socioeconomic and environmental challenges that are increasingly becoming hazardous. To create a more actionable discipline, anthropology needs to be more accessible, inform innovation, and recapture a more pluralistic scholarship that champions interdisciplinary work. This will require the consilience between the humanities and natural sciences for studying human–marine interactions more broadly and for protecting the marine environment.
- Full Text:
- Date Issued: 2020
- Authors: Aswani, Shankar
- Date: 2020
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/179028 , vital:40101 , https://0-doi.org.wam.seals.ac.za/10.1111/aman.13380
- Description: Maritime and fisheries anthropology is a mixture of different themes couched under various theoretical frameworks that straddle the humanities and the sciences. In this subject survey, I explore different thematic and theoretical strands of maritime and fisheries anthropology and illustrate broader changes in this subdiscipline since around the mid‐1990s. I also review developing and future thematic and theoretical research frontiers, and discuss their potential contribution to a public and actionable anthropology/scholarship that can better inform fisheries management and conservation. This is important because in the twenty‐first century, coastal peoples are facing socioeconomic and environmental challenges that are increasingly becoming hazardous. To create a more actionable discipline, anthropology needs to be more accessible, inform innovation, and recapture a more pluralistic scholarship that champions interdisciplinary work. This will require the consilience between the humanities and natural sciences for studying human–marine interactions more broadly and for protecting the marine environment.
- Full Text:
- Date Issued: 2020
Shifting the priority from giving voice to listening: journalism new
- Garman, Anthea, Malila, Vanessa
- Authors: Garman, Anthea , Malila, Vanessa
- Date: 2015
- Language: English
- Type: text , article
- Identifier: vital:38355 , http://hdl.handle.net/10520/EJC175773
- Description: If, as the critics have argued, the South African media prioritise the voices of elite, middleclass South Africans, then the majority of South Africans are certainly invisible in the mainstream media. Kate Lacey argues that "listening is at the heart of what it means to be in the world, to be active, to be political" (2013: 163), and as such more than just providing a 'voice' for citizens, the media needs to be engaged in active listening to allow audiences to feel 'heard'. Servaes and Malikhao argue that people are 'voiceless' not because they have nothing to say, but because "nobody cares to listen to them" (2005: 91).
- Full Text:
- Date Issued: 2015
- Authors: Garman, Anthea , Malila, Vanessa
- Date: 2015
- Language: English
- Type: text , article
- Identifier: vital:38355 , http://hdl.handle.net/10520/EJC175773
- Description: If, as the critics have argued, the South African media prioritise the voices of elite, middleclass South Africans, then the majority of South Africans are certainly invisible in the mainstream media. Kate Lacey argues that "listening is at the heart of what it means to be in the world, to be active, to be political" (2013: 163), and as such more than just providing a 'voice' for citizens, the media needs to be engaged in active listening to allow audiences to feel 'heard'. Servaes and Malikhao argue that people are 'voiceless' not because they have nothing to say, but because "nobody cares to listen to them" (2005: 91).
- Full Text:
- Date Issued: 2015