How does subjective well-being evolve with age? A literature review
- López Ulloa, Beatriz Fabiola, Moller, Valerie, Sousa-Poza, Alfonso
- Authors: López Ulloa, Beatriz Fabiola , Moller, Valerie , Sousa-Poza, Alfonso
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67185 , vital:29056 , https://doi.org/10.1007/s12062-013-9085-0
- Description: publisher version , This literature review provides an overview of the theoretical and empirical research in several disciplines on the relation between ageing and subjective well-being, i.e., how subjective well-being evolves across the lifespan. Because of the different methodologies, data sets and samples used, comparison among disciplines and studies is difficult. However, extant studies do show either a U-shaped, inverted U-shaped or linear relation between ageing and subjective well-being.
- Full Text: false
- Date Issued: 2013
- Authors: López Ulloa, Beatriz Fabiola , Moller, Valerie , Sousa-Poza, Alfonso
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67185 , vital:29056 , https://doi.org/10.1007/s12062-013-9085-0
- Description: publisher version , This literature review provides an overview of the theoretical and empirical research in several disciplines on the relation between ageing and subjective well-being, i.e., how subjective well-being evolves across the lifespan. Because of the different methodologies, data sets and samples used, comparison among disciplines and studies is difficult. However, extant studies do show either a U-shaped, inverted U-shaped or linear relation between ageing and subjective well-being.
- Full Text: false
- Date Issued: 2013
Restructuring implicational meaning through memory-based imagery: some historical notes
- Authors: Edwards, David J A
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6239 , http://hdl.handle.net/10962/d1007851
- Description: This paper provides a historical perspective on the recent increase in the clinical application of imagery techniques to restructure systems of implicational meaning that drive emotional distress or self-defeating behaviors. Janet's early application of such techniques was largely ignored except by a few hypnotherapists. Current applications in cognitive therapy were adapted and extended in the early 1980s from Perls’ Gestalt therapy methods. Some precursors to Perls are examined, as well as the work of some of those who developed and formulated the integration of his techniques into Beck's cognitive therapy. It is argued that this process amounted to a significant paradigm shift.
- Full Text:
- Date Issued: 2007
- Authors: Edwards, David J A
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6239 , http://hdl.handle.net/10962/d1007851
- Description: This paper provides a historical perspective on the recent increase in the clinical application of imagery techniques to restructure systems of implicational meaning that drive emotional distress or self-defeating behaviors. Janet's early application of such techniques was largely ignored except by a few hypnotherapists. Current applications in cognitive therapy were adapted and extended in the early 1980s from Perls’ Gestalt therapy methods. Some precursors to Perls are examined, as well as the work of some of those who developed and formulated the integration of his techniques into Beck's cognitive therapy. It is argued that this process amounted to a significant paradigm shift.
- Full Text:
- Date Issued: 2007
The Educational Journal
- Date: 1983-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/37083 , vital:34099 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1983-11
- Date: 1983-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/37083 , vital:34099 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1983-11
Of no account?: South Africa's electoral system (non) debate
- Authors: Vincent, Louise
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141657 , vital:37994 , DOI: 10.1080/02589000500513796
- Description: Accountability can be summarised simply as ‘answerability’ (James and Hadland 2002:1) and is a vital cornerstone of representative democracy. Without accountability, an electorate, once having put into power a particular representative, has no recourse to explanations, justifications or reviews of how that person has performed and whether or not they have fulfilled the promises which secured their election in the first place. In a representative democracy mechanisms of accountability are necessarily multiple and must include both formal and informal dimensions. The electoral system is but one of these. Other key lynchpins in the accountability engine include the role of opposition parties, the committee system, the media, civil society, the courts, and what in South Africa are referred to, on the basis of the 1996 Constitution, as the ‘Chapter Nine Institutions’: the Public Protector, Human Rights Commission, Commission for the Promotion and Protection of the Rights of Cultural, Religious and Linguistic Communities, Commission for Gender Equality, Auditor-General, and the Electoral Commission.
- Full Text:
- Date Issued: 2006
- Authors: Vincent, Louise
- Date: 2006
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/141657 , vital:37994 , DOI: 10.1080/02589000500513796
- Description: Accountability can be summarised simply as ‘answerability’ (James and Hadland 2002:1) and is a vital cornerstone of representative democracy. Without accountability, an electorate, once having put into power a particular representative, has no recourse to explanations, justifications or reviews of how that person has performed and whether or not they have fulfilled the promises which secured their election in the first place. In a representative democracy mechanisms of accountability are necessarily multiple and must include both formal and informal dimensions. The electoral system is but one of these. Other key lynchpins in the accountability engine include the role of opposition parties, the committee system, the media, civil society, the courts, and what in South Africa are referred to, on the basis of the 1996 Constitution, as the ‘Chapter Nine Institutions’: the Public Protector, Human Rights Commission, Commission for the Promotion and Protection of the Rights of Cultural, Religious and Linguistic Communities, Commission for Gender Equality, Auditor-General, and the Electoral Commission.
- Full Text:
- Date Issued: 2006
Local setting influences the quantity of household food waste in mid-sized South African towns
- Chakona, Gamuchirai, Shackleton, Charlie M
- Authors: Chakona, Gamuchirai , Shackleton, Charlie M
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67289 , vital:29067 , https://doi.org/10.1371/journal.pone.0189407
- Description: publisher version , From Introduction: The world faces a food security challenge with approximately 868 million people undernourished and about two billion people suffering from the negative health consequences of micronutrient deficiencies [1]. Yet, at least one-third of food produced for human consumption is lost or wasted along the food chain between farm and fork [2–7]. Food waste refers to wholesome edible material intended for human consumption, arising at any point in the food supply chain that is instead discarded, lost, degraded or consumed by pests [8]. Food loss is defined as the decrease in food quantity or quality which makes it unfit for human consumption [9]. According to the European Commission [10], food waste is composed of raw or cooked food materials such as vegetable peelings, meat trimmings and spoiled or excess ingredients or prepared food as well as bones, carcasses and organs. However, food waste can be measured only for edible products that are directed to human consumption [6]. Food losses take place at production, postharvest and processing stages in the food supply chain and the food losses that occur at the end of the food chain (retail and final consumption) are called “food waste” [11]. In our study food waste refers to food losses that occur at the end of the food chain (final consumption at household or consumer level) which include edible products that are directed to human consumption and are discarded when not consumed for various reasons. It is related to consumers’ behaviour [6,11] and it includes food loss before, during or after meal preparation in the household. , The research was funded by VW foundation under the Livelihoods Urbanisation and Natural Resources in Africa (LUNA) project through Freiburg University, Germany. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of this manuscript
- Full Text:
- Date Issued: 2013
- Authors: Chakona, Gamuchirai , Shackleton, Charlie M
- Date: 2013
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/67289 , vital:29067 , https://doi.org/10.1371/journal.pone.0189407
- Description: publisher version , From Introduction: The world faces a food security challenge with approximately 868 million people undernourished and about two billion people suffering from the negative health consequences of micronutrient deficiencies [1]. Yet, at least one-third of food produced for human consumption is lost or wasted along the food chain between farm and fork [2–7]. Food waste refers to wholesome edible material intended for human consumption, arising at any point in the food supply chain that is instead discarded, lost, degraded or consumed by pests [8]. Food loss is defined as the decrease in food quantity or quality which makes it unfit for human consumption [9]. According to the European Commission [10], food waste is composed of raw or cooked food materials such as vegetable peelings, meat trimmings and spoiled or excess ingredients or prepared food as well as bones, carcasses and organs. However, food waste can be measured only for edible products that are directed to human consumption [6]. Food losses take place at production, postharvest and processing stages in the food supply chain and the food losses that occur at the end of the food chain (retail and final consumption) are called “food waste” [11]. In our study food waste refers to food losses that occur at the end of the food chain (final consumption at household or consumer level) which include edible products that are directed to human consumption and are discarded when not consumed for various reasons. It is related to consumers’ behaviour [6,11] and it includes food loss before, during or after meal preparation in the household. , The research was funded by VW foundation under the Livelihoods Urbanisation and Natural Resources in Africa (LUNA) project through Freiburg University, Germany. The funders had no role in study design, data collection and analysis, decision to publish, or preparation of this manuscript
- Full Text:
- Date Issued: 2013
The Educational Journal
- Date: 1981-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/37073 , vital:34098 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1981-11
- Date: 1981-11
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/37073 , vital:34098 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1981-11
The Educational Journal
- Date: 1984-06
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/36906 , vital:34064 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1984-06
- Date: 1984-06
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/36906 , vital:34064 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1984-06
Unconscious influences on discourses about consciousness : ideology, state-specific science and unformulated experience
- Authors: Edwards, D J A
- Date: 2005
- Language: English
- Type: Article
- Identifier: vital:6226 , http://hdl.handle.net/10962/d1007776
- Description: Discussions about consciousness are complicated by the fact that participants do not share a common underlying “ordinary” consciousness. Everyday experience is founded on what Teasdale calls implicational cognition, much of which is not verbally formulated. An unacknowledged aspect of debate is individuals’ attempts to negotiate the expression of their unformulated experience. This is further complicated by the way in which a discourse, based on particular ontological assumptions, exercises an ideological control which limits what underlying aspects of experience can be formulated at all. Tart’s concept of state specific sciences provides a framework within which the role of unformulated experience can be acknowledged and taken into account. Unless this is done, debates will be vitiated by participants engaging in ideological struggles and talking at cross-purposes.
- Full Text:
- Date Issued: 2005
- Authors: Edwards, D J A
- Date: 2005
- Language: English
- Type: Article
- Identifier: vital:6226 , http://hdl.handle.net/10962/d1007776
- Description: Discussions about consciousness are complicated by the fact that participants do not share a common underlying “ordinary” consciousness. Everyday experience is founded on what Teasdale calls implicational cognition, much of which is not verbally formulated. An unacknowledged aspect of debate is individuals’ attempts to negotiate the expression of their unformulated experience. This is further complicated by the way in which a discourse, based on particular ontological assumptions, exercises an ideological control which limits what underlying aspects of experience can be formulated at all. Tart’s concept of state specific sciences provides a framework within which the role of unformulated experience can be acknowledged and taken into account. Unless this is done, debates will be vitiated by participants engaging in ideological struggles and talking at cross-purposes.
- Full Text:
- Date Issued: 2005
The natural history and conservation of Indian Ocean Humpback Dolphins (Sousa plumbea) in South African waters
- Plön, Stephanie, Cockcroft, Victor G, Froneman, P William
- Authors: Plön, Stephanie , Cockcroft, Victor G , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68207 , vital:29219 , https://doi.org/10.1016/bs.amb.2015.08.005
- Description: Publisher version , Although most knowledge on the biology of Sousa plumbea has primarily come from South African waters, a number of research gaps remain on the natural history and status of the species in the region. Research on two populations in South African waters for which some historical data exist may aid in highlighting long-term changes in the biology and natural history of this little known coastal delphinid. Recent studies on the age, growth and reproduction of animals incidentally caught in shark nets in Richards Bay, KwaZulu-Natal, yielded a lower maximum age estimate of 24 (previously 46) growth-layer-groups (GLGs), sexual maturity of 7.5 and 8 GLGs in males and females (previously 12–13 and 10 GLGs, respectively), an ovulation rate of 0.2 and a 5-year calving interval (previously 0.3 and 3-year calving interval) than previously reported. These differences may be due to a difference in the interpretation of GLGs between observers or a predominance of young males being caught in the shark nets. Stomach content analysis revealed a change in the relative proportions of the main prey items over the past 25 years, but no difference in species richness or diversity was found between the sexes. No change in trophic level was recorded between 1972 and 2009. Field studies in Algoa Bay, Eastern Cape, conducted 16 years apart indicated a decline in the mean group size (from 7 to 3 animals), a decline in the maximum group size (from 24 to 13 animals), an increase in solitary individuals (15.4–36%), and a change in behaviour from predominantly foraging (64–18%) to mainly travelling (24–49%). The observed changes are suggestive of a change in food availability, resulting in a range shift or a potential decline in numbers. These studies indicate the importance of long-term studies to monitor population changes and their possible causes. A number of threats, such as shark nets, pollution (noise and chemical), and coastal development and disturbance, to the humpback dolphin populations in South Africa have been identified. Urgent action is required to ensure continued existence of the species in South African waters.
- Full Text: false
- Date Issued: 2015
- Authors: Plön, Stephanie , Cockcroft, Victor G , Froneman, P William
- Date: 2015
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/68207 , vital:29219 , https://doi.org/10.1016/bs.amb.2015.08.005
- Description: Publisher version , Although most knowledge on the biology of Sousa plumbea has primarily come from South African waters, a number of research gaps remain on the natural history and status of the species in the region. Research on two populations in South African waters for which some historical data exist may aid in highlighting long-term changes in the biology and natural history of this little known coastal delphinid. Recent studies on the age, growth and reproduction of animals incidentally caught in shark nets in Richards Bay, KwaZulu-Natal, yielded a lower maximum age estimate of 24 (previously 46) growth-layer-groups (GLGs), sexual maturity of 7.5 and 8 GLGs in males and females (previously 12–13 and 10 GLGs, respectively), an ovulation rate of 0.2 and a 5-year calving interval (previously 0.3 and 3-year calving interval) than previously reported. These differences may be due to a difference in the interpretation of GLGs between observers or a predominance of young males being caught in the shark nets. Stomach content analysis revealed a change in the relative proportions of the main prey items over the past 25 years, but no difference in species richness or diversity was found between the sexes. No change in trophic level was recorded between 1972 and 2009. Field studies in Algoa Bay, Eastern Cape, conducted 16 years apart indicated a decline in the mean group size (from 7 to 3 animals), a decline in the maximum group size (from 24 to 13 animals), an increase in solitary individuals (15.4–36%), and a change in behaviour from predominantly foraging (64–18%) to mainly travelling (24–49%). The observed changes are suggestive of a change in food availability, resulting in a range shift or a potential decline in numbers. These studies indicate the importance of long-term studies to monitor population changes and their possible causes. A number of threats, such as shark nets, pollution (noise and chemical), and coastal development and disturbance, to the humpback dolphin populations in South Africa have been identified. Urgent action is required to ensure continued existence of the species in South African waters.
- Full Text: false
- Date Issued: 2015
Re-deploying Parker, post-colonially: review essay
- Macleod, Catriona I, Wilbraham, Lindy
- Authors: Macleod, Catriona I , Wilbraham, Lindy
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6275 , http://hdl.handle.net/10962/d1008275
- Description: In this paper we review two of Ian Parker’s recent books: Critical discursive psychology and Qualitative psychology: Introducing radical research. Although the books address different audiences (academics versus students) and talk to different problematics (theory versus research), taken together they represent useful resources for those wishing to take a critical stance with regards to the standard fare of psychology, to use critical theory in understanding social and psychological phenomena, and to engage in progressive research. As such, both theory and research methods appear as “tools”, and we suggest reading Parker sideways, shifting his intellectual trajectory into directions that illuminate colonial and post-colonial issues through empirical/textual application to real South African contexts. By way of illustration, we offer a post-colonial reading of Parker’s work on post-modernism. Concluding comments on tactics for a “post-colonial analysis of discourses” are offered.
- Full Text:
- Date Issued: 2006
- Authors: Macleod, Catriona I , Wilbraham, Lindy
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6275 , http://hdl.handle.net/10962/d1008275
- Description: In this paper we review two of Ian Parker’s recent books: Critical discursive psychology and Qualitative psychology: Introducing radical research. Although the books address different audiences (academics versus students) and talk to different problematics (theory versus research), taken together they represent useful resources for those wishing to take a critical stance with regards to the standard fare of psychology, to use critical theory in understanding social and psychological phenomena, and to engage in progressive research. As such, both theory and research methods appear as “tools”, and we suggest reading Parker sideways, shifting his intellectual trajectory into directions that illuminate colonial and post-colonial issues through empirical/textual application to real South African contexts. By way of illustration, we offer a post-colonial reading of Parker’s work on post-modernism. Concluding comments on tactics for a “post-colonial analysis of discourses” are offered.
- Full Text:
- Date Issued: 2006
Beyond the development impasse : the role of local economic development and community self-reliance in rural South Africa
- Authors: Binns, Tony , Nel, Etienne L
- Date: 1999
- Language: English
- Type: Article
- Identifier: vital:6673 , http://hdl.handle.net/10962/d1006647
- Description: The failure of successive generations of imported, Western development strategies and projects to deliver meaningful reductions in poverty and achieve basic needs in Africa, has provoked a deep questioning of Western concepts and methodologies of development. Non-governmental organisations and development practitioners are increasingly focusing their attention on strategies which build upon local knowledge, skills and resources. The concepts of ‘self- reliance’ and local economic development are examined in the context of development challenges which face Africa. This is followed by a detailed case study of local economic development in the rural Mpofu District of the former Ciskei Homeland, which was incorporated into the Eastern Cape province of South Africa with the demise of apartheid in 1994.
- Full Text:
- Date Issued: 1999
- Authors: Binns, Tony , Nel, Etienne L
- Date: 1999
- Language: English
- Type: Article
- Identifier: vital:6673 , http://hdl.handle.net/10962/d1006647
- Description: The failure of successive generations of imported, Western development strategies and projects to deliver meaningful reductions in poverty and achieve basic needs in Africa, has provoked a deep questioning of Western concepts and methodologies of development. Non-governmental organisations and development practitioners are increasingly focusing their attention on strategies which build upon local knowledge, skills and resources. The concepts of ‘self- reliance’ and local economic development are examined in the context of development challenges which face Africa. This is followed by a detailed case study of local economic development in the rural Mpofu District of the former Ciskei Homeland, which was incorporated into the Eastern Cape province of South Africa with the demise of apartheid in 1994.
- Full Text:
- Date Issued: 1999
Econo-Language Planning and Transformation in South Africa: From Localisation to Globalisation
- Authors: Kaschula, Russell H
- Date: 2019
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/174657 , vital:42498 , ISBN 9781108425346
- Description: This chapter seeks to create an understanding of the historical, sociopolitical and economic context within which language planning has taken place in South Africa (Alexander 1992). Furthermore, the extent to which government agencies and other stakeholder bodies have taken language planning into account when developing economic and development policies within the contemporary global reality will be assessed (Edozie 2004). Policies (if one can call them policies) such as the New Partnership for Africa’s Development (NEPAD), as well as the National Development Plan (NDP) in South Africa are analysed against the backdrop of language policy planning and implementation, to see if there are linkages between opportunity language planning on the ground (Antia 2017) and economic development. In other words does language planning create work opportunities through policy creation and implementation where our languages are seen as resources to be used appropriately in the market place?.
- Full Text:
- Date Issued: 2019
- Authors: Kaschula, Russell H
- Date: 2019
- Language: English
- Type: text , book
- Identifier: http://hdl.handle.net/10962/174657 , vital:42498 , ISBN 9781108425346
- Description: This chapter seeks to create an understanding of the historical, sociopolitical and economic context within which language planning has taken place in South Africa (Alexander 1992). Furthermore, the extent to which government agencies and other stakeholder bodies have taken language planning into account when developing economic and development policies within the contemporary global reality will be assessed (Edozie 2004). Policies (if one can call them policies) such as the New Partnership for Africa’s Development (NEPAD), as well as the National Development Plan (NDP) in South Africa are analysed against the backdrop of language policy planning and implementation, to see if there are linkages between opportunity language planning on the ground (Antia 2017) and economic development. In other words does language planning create work opportunities through policy creation and implementation where our languages are seen as resources to be used appropriately in the market place?.
- Full Text:
- Date Issued: 2019
New Unity Movement Bulletin
- Date: 2003-12
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32141 , vital:31967 , Bulk File 7
- Description: The Bulletin was the official newsletter of the New Unity Movement. It was published about twice a year and contained articles reflecting the organisation's views on resistance to the Apartheid government.
- Full Text: false
- Date Issued: 2003-12
- Date: 2003-12
- Subjects: Government, Resistance to -- South Africa , South Africa -- History -- 20th century , South Africa -- Politics and government
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10948/32141 , vital:31967 , Bulk File 7
- Description: The Bulletin was the official newsletter of the New Unity Movement. It was published about twice a year and contained articles reflecting the organisation's views on resistance to the Apartheid government.
- Full Text: false
- Date Issued: 2003-12
Tetracarboxylic acid cobalt phthalocyanine SAM on gold: Potential applications as amperometric sensor for H2O2 and fabrication of glucose biosensor
- Mashazi, Philani N, Ozoemena, Kenneth I, Nyokong, Tebello
- Authors: Mashazi, Philani N , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6578 , http://hdl.handle.net/10962/d1004141
- Description: This report describes the applications of cobalt tetracarboxylic acid phthalocyanine (CoTCAPc) self-assembled monolayer (SAM) immobilized onto a preformed 2-mercaptoethanol (Au-ME) SAM on gold surface (Au-ME-CoTCAPc SAM) as a potential amperometric sensor for the detection of hydrogen peroxide (H[subscript 2]O[subscript 2]) at neutral pH conditions. The Au-ME-CoTCAPc SAM sensor showed a very fast amperometric response time of approximately 1 s, good linearity at the studied concentration range of up to 5 μM with a coefficient R² = 0.993 and a detection limit of 0.4 μM oxidatively. Also reductively, the sensor exhibited a very fast amperometric response time (~1 s), linearity up to 5 μM with a coefficient R² = 0.986 and a detection limit of 0.2 μM. The cobalt tetracarboxylic acid phthalocyanine self-assembled monolayer was then evaluated as a mediator for glucose oxidase (GOx)-based biosensor. The GOx (enzyme) was immobilized covalently onto Au-ME-CoTCAPc SAM using coupling agents: N-ethyl-N(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxy succinimide (NHS), and the results demonstrated a good catalytic behavior. Kinetic parameters associated with the enzymatic and mediator reactions were estimated using electrochemical versions of Lineweaver–Burk and Hanes equation, and the stability of the sensor was tested. The biosensor (Au-ME-CoTCAPc-GOx SAM) electrode showed good sensitivity (7.5 nA/mM) with a good detection limit of 8.4 μM at 3σ, smaller Michaelis–Menten constant (4.8 mM from Hanes plot) and very fast response time of approximately 5 s.
- Full Text:
- Date Issued: 2006
- Authors: Mashazi, Philani N , Ozoemena, Kenneth I , Nyokong, Tebello
- Date: 2006
- Language: English
- Type: Article
- Identifier: vital:6578 , http://hdl.handle.net/10962/d1004141
- Description: This report describes the applications of cobalt tetracarboxylic acid phthalocyanine (CoTCAPc) self-assembled monolayer (SAM) immobilized onto a preformed 2-mercaptoethanol (Au-ME) SAM on gold surface (Au-ME-CoTCAPc SAM) as a potential amperometric sensor for the detection of hydrogen peroxide (H[subscript 2]O[subscript 2]) at neutral pH conditions. The Au-ME-CoTCAPc SAM sensor showed a very fast amperometric response time of approximately 1 s, good linearity at the studied concentration range of up to 5 μM with a coefficient R² = 0.993 and a detection limit of 0.4 μM oxidatively. Also reductively, the sensor exhibited a very fast amperometric response time (~1 s), linearity up to 5 μM with a coefficient R² = 0.986 and a detection limit of 0.2 μM. The cobalt tetracarboxylic acid phthalocyanine self-assembled monolayer was then evaluated as a mediator for glucose oxidase (GOx)-based biosensor. The GOx (enzyme) was immobilized covalently onto Au-ME-CoTCAPc SAM using coupling agents: N-ethyl-N(3-dimethylaminopropyl) carbodiimide (EDC) and N-hydroxy succinimide (NHS), and the results demonstrated a good catalytic behavior. Kinetic parameters associated with the enzymatic and mediator reactions were estimated using electrochemical versions of Lineweaver–Burk and Hanes equation, and the stability of the sensor was tested. The biosensor (Au-ME-CoTCAPc-GOx SAM) electrode showed good sensitivity (7.5 nA/mM) with a good detection limit of 8.4 μM at 3σ, smaller Michaelis–Menten constant (4.8 mM from Hanes plot) and very fast response time of approximately 5 s.
- Full Text:
- Date Issued: 2006
Rhodes University Graduation Ceremony 1979
- Authors: Rhodes University
- Date: 1979
- Language: English
- Type: text
- Identifier: vital:8113 , http://hdl.handle.net/10962/d1004569
- Description: Rhodes University Graduation Ceremony on Friday, 6th April, 1979 at 8 p.m. [and] on Saturday, 7th April, 1979 at 10:30 a.m. in the 1820 Settlers National Monument.
- Full Text:
- Date Issued: 1979
- Authors: Rhodes University
- Date: 1979
- Language: English
- Type: text
- Identifier: vital:8113 , http://hdl.handle.net/10962/d1004569
- Description: Rhodes University Graduation Ceremony on Friday, 6th April, 1979 at 8 p.m. [and] on Saturday, 7th April, 1979 at 10:30 a.m. in the 1820 Settlers National Monument.
- Full Text:
- Date Issued: 1979
Pre-emigration reflections : Afrikaans speakers moving to New Zealand
- De Klerk, Vivian A, Barkhuizen, Gary
- Authors: De Klerk, Vivian A , Barkhuizen, Gary
- Date: 2004
- Language: English
- Type: Article , text
- Identifier: vital:6138 , http://hdl.handle.net/10962/d1011590
- Description: This article reports on the pre-emigration reflections of 15 Afrikaans speakers, all of whom were in the final stages of preparing to emigrate to New Zealand. The study explores the linguistic histories of the participants, their attitudes to their mother tongue (Afrikaans) and to English, and their views on South Africa's language policy and how it has influenced their decisions to leave the country. The paper also offers a view on possible long-term linguistic outcomes for these families.
- Full Text:
- Date Issued: 2004
- Authors: De Klerk, Vivian A , Barkhuizen, Gary
- Date: 2004
- Language: English
- Type: Article , text
- Identifier: vital:6138 , http://hdl.handle.net/10962/d1011590
- Description: This article reports on the pre-emigration reflections of 15 Afrikaans speakers, all of whom were in the final stages of preparing to emigrate to New Zealand. The study explores the linguistic histories of the participants, their attitudes to their mother tongue (Afrikaans) and to English, and their views on South Africa's language policy and how it has influenced their decisions to leave the country. The paper also offers a view on possible long-term linguistic outcomes for these families.
- Full Text:
- Date Issued: 2004
Topographic controls on the invasion of Pteronia incana (Blue bush) onto hillslopes in Ngqushwa (formerly Peddie) district, Eastern Cape, South Africa
- Kakembo, V, Rowntree, Kate M, Palmer, Anthony R
- Authors: Kakembo, V , Rowntree, Kate M , Palmer, Anthony R
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6689 , http://hdl.handle.net/10962/d1006708
- Description: The role of topographic factors in the invasion of hillslopes by Pteronia incana, an unpalatable shrub, was investigated. The study combined field observations with image analysis based on high-resolution infrared imagery. A Digital Elevation Model (DEM) of 20 m spatial resolution was used to derive terrain parameters. The Topographic Wetness Index (WI), a component of the TOPMODEL, was derived from the DEM and its relationship with the spatial distribution of P. incana was explored. The absence/presence of P. incana was noted to be strongly influenced by slope angle and aspect. The probability for P. incana occurrence increased with slope steepness and southerly slope orientation. Abandoned and grazing lands were identified as the main invasion hotspots on hillslopes. The combined influence of slope gradient and aspect, and land use was noted to have promoted the invasion. This is borne out by the concentration of the invasion on abandoned steep slopes with a southerly orientation. The WI confirmed the bearing local topographic variations have on P. incana spatial distribution such that, P. incana was associated with the low WI values of convexities. The coupling between local topography and soil surface crusting underpins soil moisture variability. This in turn determines the competition between the patchy P. incana and grass species and the eventual replacement of the latter by the former. Restoration efforts of the invaded lands should focus on trapping of sediment and litter, and moisture retention on the inter-patch bare areas.
- Full Text:
- Date Issued: 2007
- Authors: Kakembo, V , Rowntree, Kate M , Palmer, Anthony R
- Date: 2007
- Language: English
- Type: Article
- Identifier: vital:6689 , http://hdl.handle.net/10962/d1006708
- Description: The role of topographic factors in the invasion of hillslopes by Pteronia incana, an unpalatable shrub, was investigated. The study combined field observations with image analysis based on high-resolution infrared imagery. A Digital Elevation Model (DEM) of 20 m spatial resolution was used to derive terrain parameters. The Topographic Wetness Index (WI), a component of the TOPMODEL, was derived from the DEM and its relationship with the spatial distribution of P. incana was explored. The absence/presence of P. incana was noted to be strongly influenced by slope angle and aspect. The probability for P. incana occurrence increased with slope steepness and southerly slope orientation. Abandoned and grazing lands were identified as the main invasion hotspots on hillslopes. The combined influence of slope gradient and aspect, and land use was noted to have promoted the invasion. This is borne out by the concentration of the invasion on abandoned steep slopes with a southerly orientation. The WI confirmed the bearing local topographic variations have on P. incana spatial distribution such that, P. incana was associated with the low WI values of convexities. The coupling between local topography and soil surface crusting underpins soil moisture variability. This in turn determines the competition between the patchy P. incana and grass species and the eventual replacement of the latter by the former. Restoration efforts of the invaded lands should focus on trapping of sediment and litter, and moisture retention on the inter-patch bare areas.
- Full Text:
- Date Issued: 2007
The Educational Journal
- Date: 1981-05
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35996 , vital:33878 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1981-05
- Date: 1981-05
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35996 , vital:33878 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1981-05
The Educational Journal
- Date: 1979-09
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35956 , vital:33866 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1979-09
- Date: 1979-09
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/35956 , vital:33866 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1979-09
The Educational Journal
- Date: 1985-06
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/36916 , vital:34065 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1985-06
- Date: 1985-06
- Subjects: Education –- South Africa , South Africa -- Politics and government , Government, Resistance to -- South Africa
- Language: English
- Type: text , Article
- Identifier: http://hdl.handle.net/10948/36916 , vital:34065 , Bulk File 7
- Description: The Educational Journal was the official organ of the Teachers' League of South Africa and focussed on education within the context of a racialized South Africa.
- Full Text: false
- Date Issued: 1985-06